Public Stock Company "vsmpo-avisma Corporation"

Russian Federation

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Date
2024 October 1
2024 5
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IPC Class
C22C 14/00 - Alloys based on titanium 22
C22F 1/18 - High-melting or refractory metals or alloys based thereon 13
C22B 9/20 - Arc remelting 4
B21C 1/00 - Manufacture of metal sheets, wire, rods, tubes or like semi-manufactured products by drawing 2
B33Y 10/00 - Processes of additive manufacturing 2
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NICE Class
06 - Common metals and ores; objects made of metal 2
11 - Environmental control apparatus 2
12 - Land, air and water vehicles; parts of land vehicles 2
Status
Pending 5
Registered / In Force 23

1.

HIGH-STRENGTH TITANIUM-BASED ALLOY AND ARTICLE MANUFACTURED FROM SAME

      
Application Number RU2024000103
Publication Number 2024/210770
Status In Force
Filing Date 2024-03-28
Publication Date 2024-10-10
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Kalienko, Maksim Sergeevich
  • Leder, Mikhail Ottovich
  • Volkov, Anatoliy Vladimirovich
  • Pankratov, Aleksei Nikolaevich
  • Shushakova, Elena Andreevna
  • Pastukhov, Dmitry Sergeevich
  • Volkova, Natalya Pavlovna

Abstract

The invention relates to metallurgy, and more particularly to titanium-based alloys that can be used for manufacturing a wide range of high-strength semi-finished products, preferably stamped or forged parts, sheets, plates, billets and bars, inter alia, those having large dimensions, as well as semi-finished products for the manufacture of parts for use at high temperatures, which can be used in the aerospace, energy and chemical industries, as well as in mechanical engineering and other industrial sectors. A high-strength titanium-based alloy contains: 5.0-7.0 wt% aluminium, 6.0-12.0 wt% molybdenum, 2.0-6.5 wt% niobium, 2.5-4.5 wt% tungsten, 0.1-0.3 wt% silicon, not more than 0.2 wt% iron, not more than 0.17 wt% oxygen, not more than 0.05 wt% carbon, not more than 0.01 wt% nitrogen, not more than 0.01 wt% hydrogen, and the balance titanium and incidental impurities. The alloy is characterized in that it exhibits high strength together with satisfactory plasticity, as well as improved creep resistance and oxidation resistance.

IPC Classes  ?

2.

TITANIUM-BASED ALLOY AND ARTICLE MANUFACTURED FROM SAME

      
Application Number 18693978
Status Pending
Filing Date 2022-09-19
First Publication Date 2024-07-25
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Leder, Mikhail Ottovich
  • Kalienko, Maksim Sergeevich
  • Volkov, Anatoliy Vladimirovich
  • Lavrova, Tatyana Aleksandrovna
  • Grebenshchikov, Aleksandr Sergeyevich
  • Mihailov, Vitalii Anatolevich
  • Plaksina, Elizaveta Aleksandrovna

Abstract

The invention relates to nonferrous metallurgy, namely to the development of low-alloyed titanium alloys characterized by high-temperature strength and thermal stability, and can be used for manufacture of articles intended for long-term operation at high temperatures, namely components of exhaust systems of vehicle engines. titanium alloy containing aluminum, molybdenum, silicon, oxygen, nitrogen, iron, hydrogen, with the alloy components taken in the following ratio, % wt.: The invention relates to nonferrous metallurgy, namely to the development of low-alloyed titanium alloys characterized by high-temperature strength and thermal stability, and can be used for manufacture of articles intended for long-term operation at high temperatures, namely components of exhaust systems of vehicle engines. titanium alloy containing aluminum, molybdenum, silicon, oxygen, nitrogen, iron, hydrogen, with the alloy components taken in the following ratio, % wt.: Aluminum 1.5 to 3.0 Molybdenum 0.1 to 0.5 Silicon 0.1 to 0.6 Iron 0.2 max Oxygen 0.15 max Carbon 0.1 max Nitrogen 0.03 max Hydrogen 0.015 max Titanium and inevitable impurities—balance, which in one embodiment additionally contains copper 0.5 to 1.5% wt., and article made thereof. The invention relates to nonferrous metallurgy, namely to the development of low-alloyed titanium alloys characterized by high-temperature strength and thermal stability, and can be used for manufacture of articles intended for long-term operation at high temperatures, namely components of exhaust systems of vehicle engines. titanium alloy containing aluminum, molybdenum, silicon, oxygen, nitrogen, iron, hydrogen, with the alloy components taken in the following ratio, % wt.: Aluminum 1.5 to 3.0 Molybdenum 0.1 to 0.5 Silicon 0.1 to 0.6 Iron 0.2 max Oxygen 0.15 max Carbon 0.1 max Nitrogen 0.03 max Hydrogen 0.015 max Titanium and inevitable impurities—balance, which in one embodiment additionally contains copper 0.5 to 1.5% wt., and article made thereof. A technical result of the embodiment of invention is the production of titanium alloy characterized by a combination of high mechanical and performance properties, including a higher level of creep resistance, with capability of cold forming.

IPC Classes  ?

3.

TITANIUM-BASED ALLOY AND ARTICLE MADE OF SAME

      
Application Number 18688869
Status Pending
Filing Date 2022-06-28
First Publication Date 2024-07-11
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Leder, Mikhail Ottovich
  • Kalienko, Maksim Sergeevich
  • Volkov, Anatoliy Vladimirovich
  • Lavrova, Tatyana Aleksandrovna
  • Grebenshchikov, Aleksandr Sergeyevich
  • Mihailov, Vitalii Anatolevich

Abstract

The invention relates to the field of nonferrous metallurgy and particularly to development of titanium-based alloys that are resistant to high-temperature oxidation, and can be used for manufacture of articles operating under conditions of prolonged exposure to high temperatures, in particular for manufacture of components of vehicle engine exhaust systems. The titanium-based alloy consists of aluminum, zirconium, niobium, molybdenum, silicon, oxygen, nitrogen, iron, hydrogen, and carbon, and is characterized in that the components of the alloy are in the following ratio, in weight %. The invention relates to the field of nonferrous metallurgy and particularly to development of titanium-based alloys that are resistant to high-temperature oxidation, and can be used for manufacture of articles operating under conditions of prolonged exposure to high temperatures, in particular for manufacture of components of vehicle engine exhaust systems. The titanium-based alloy consists of aluminum, zirconium, niobium, molybdenum, silicon, oxygen, nitrogen, iron, hydrogen, and carbon, and is characterized in that the components of the alloy are in the following ratio, in weight %. Aluminum 0.7-1.5 Zirconium 0.5-1.5 Niobium 0.5-1.5 Molybdenum 0.1-0.5 Silicon 0.5 max Iron 0.2 max Oxygen 0.15 max Carbon 0.1 max Nitrogen 0.03 max Hydrogen 0.015 max Titanium and inevitable impurities being the balance; and an article made of this alloy. The invention relates to the field of nonferrous metallurgy and particularly to development of titanium-based alloys that are resistant to high-temperature oxidation, and can be used for manufacture of articles operating under conditions of prolonged exposure to high temperatures, in particular for manufacture of components of vehicle engine exhaust systems. The titanium-based alloy consists of aluminum, zirconium, niobium, molybdenum, silicon, oxygen, nitrogen, iron, hydrogen, and carbon, and is characterized in that the components of the alloy are in the following ratio, in weight %. Aluminum 0.7-1.5 Zirconium 0.5-1.5 Niobium 0.5-1.5 Molybdenum 0.1-0.5 Silicon 0.5 max Iron 0.2 max Oxygen 0.15 max Carbon 0.1 max Nitrogen 0.03 max Hydrogen 0.015 max Titanium and inevitable impurities being the balance; and an article made of this alloy. The technical result achieved in the implementation of the invention is obtaining of a titanium alloy with the set of high mechanical and performance properties including increased level of high-temperature oxidation resistance.

IPC Classes  ?

4.

MATERIAL FOR THE MANUFACTURE OF HIGH-STRENGTH FASTENERS AND METHOD FOR PRODUCING SAME

      
Application Number 18552343
Status Pending
Filing Date 2021-03-26
First Publication Date 2024-05-09
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Leder, Mikhail Ottovich
  • Volkov, Anatoliy Vladimirovich
  • Grebenshchikov, Aleksandr Sergeyevich
  • Shchetnikov, Nikolay Vasilyevich

Abstract

The invention relates to metallurgy, and more particularly to producing titanium alloy-based materials with specific mechanical properties for the manufacture of fasteners for use in various fields of industry and preferably in the aerospace industry. The claimed material for the manufacture of high-strength fasteners is made from a titanium alloy containing alloying elements in the form of α-stabilizers, #-stabilizers and neutral strengthening elements, the rest being titanium and unavoidable impurities. The size of a beta-subgrain in the structure of the material, which is subjected to solution annealing and aging, does not exceed 15 μm. The material for the manufacture of high-strength fasteners is produced in the form of round bar with a diameter of up to 40 mm or round wire with a diameter of up to 18 mm, which are subjected to solution annealing and aging After solution annealing and aging, the material has an ultimate tensile strength of greater than 1400 MPa, an elongation of greater than 11%, a reduction in area of greater than 35% and a double shear strength of greater than 750 MPa. An intermediate blank for drawing is obtained by melting an ingot of titanium alloy, thermomechanically processing the ingot to obtain a forged billet and then rolling same. An intermediate blank for drawing is also obtainable using a powder metallurgy method.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • C22F 1/18 - High-melting or refractory metals or alloys based thereon

5.

TITANIUM ALLOY SHEET MATERIAL AND EXHAUST SYSTEM COMPONENT

      
Application Number RU2023000248
Publication Number 2024/043804
Status In Force
Filing Date 2023-08-14
Publication Date 2024-02-29
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Leder, Mikhail Ottovich
  • Volkov, Anatoliy Vladimirovich
  • Kalienko, Maksim Sergeevich
  • Lavrova, Tatiana Aleksandrovna
  • Grebenshchikov, Aleksandr Sergeevich
  • Plaksina, Elizaveta Aleksandrovna

Abstract

The invention relates to metallurgy, and more particularly to a sheet material made of titanium alloys that are resistant to high heat and oxidation and exhibit structural stability under prolonged operational exposure to temperatures in a range of up to 800°С, and can be used for manufacturing components of a vehicle exhaust system. The present titanium alloy sheet material for the manufacture of components contains: 1.5-3.0 wt% aluminium, 0.1-0.5 wt% molybdenum, 0.1-0.6 wt% silicon, not more than 0.2 wt% iron, not more than 0.15 wt% oxygen, not more than 0.1 wt% carbon, not more than 0.03 wt% nitrogen, not more than 0.015 wt% hydrogen, and the balance titanium. The sheet material has high creep resistance and oxidation resistance values, as well as a stable structure under prolonged operational exposure to temperatures in a range of up to 800°С. The material is suitable for cold forming.

IPC Classes  ?

6.

TITANIUM-BASED ALLOY AND ARTICLE MANUFACTURED FROM SAME

      
Application Number RU2022000285
Publication Number 2023/048593
Status In Force
Filing Date 2022-09-19
Publication Date 2023-03-30
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Leder, Mikhail Ottovich
  • Kalienko, Maksim Sergeevich
  • Volkov, Anatoliy Vladimirovich
  • Lavrova, Tatyana Aleksandrovna
  • Grebenshchikov, Aleksandr Sergeyevich
  • Mikhailov, Vitalii Anatolevich
  • Plaksina, Elizaveta Aleksandrovna

Abstract

The invention relates to non-ferrous metallurgy, and more particularly to the creation of low-alloy titanium-based alloys that are heat resistant and thermally stable, and can be used for manufacturing articles subject to long-term exposure to high temperatures, in particular components of vehicle engine exhaust systems. Claimed is a titanium-based alloy containing aluminium, molybdenum, silicon, iron, oxygen, carbon, nitrogen and hydrogen, wherein the ingredients of the alloy are present in the following proportions, in weight percent: aluminium 1.5-3.0, molybdenum 0.1-0.5, silicon 0.1-0.6, iron not more than 0.2, oxygen not more than 0.15, carbon not more than 0.1, nitrogen not more than 0.03 and hydrogen not more than 0.015, the balance being titanium and unavoidable impurities, and the alloy further contains, in one embodiment, copper 0.5-1.5 wt%. Also claimed is an article made from the present alloy. The technical result achieved by the invention is the production of a titanium alloy that exhibits a combination of high mechanical and performance properties, including an increased level of resistance to creep, which is capable of being cold formed.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • F01N 13/00 - Exhaust or silencing apparatus characterised by constructional features

7.

TITANIUM-BASED ALLOY AND ARTICLE MADE OF SAME

      
Application Number RU2022000201
Publication Number 2023/009030
Status In Force
Filing Date 2022-06-28
Publication Date 2023-02-02
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Leder, Mikhail Ottovich
  • Kalienko, Maksim Sergeevich
  • Volkov, Anatoliy Vladimirovich
  • Lavrova, Tatyana Aleksandrovna
  • Grebenshchikov, Aleksandr Sergeyevich
  • Mihailov, Vitalii Anatolevich

Abstract

The invention relates to non-ferrous metallurgy, and more particularly to the creation of titanium-based alloys that are resistant to oxidation at high temperatures, and can be used for manufacturing articles subject to long-term exposure to high temperatures, in particular components of vehicle engine exhaust systems. Claimed is a titanium-based alloy containing aluminium, zirconium, niobium, molybdenum, silicon, oxygen, nitrogen, iron, hydrogen and carbon, characterized in that the ingredients of the alloy are present in the following proportions: 0.7-1.5 wt% aluminium, 0.5-1.5 wt% zirconium, 0.5-1.5 wt% niobium, 0.1-0.5 wt% molybdenum, not more than 0.5 wt% silicon, not more than 0.2 wt% iron, not more than 0.15 wt% oxygen, not more than 0.1 wt% carbon, not more than 0.03 wt% nitrogen, not more than 0.015 wt% hydrogen, the balance being titanium and unavoidable impurities. Further claimed is an article made of this alloy. The technical result achieved by the invention is the production of a titanium alloy that exhibits a combination of high mechanical and performance properties, including an increased level of resistance to oxidation at high temperatures.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • F01N 13/00 - Exhaust or silencing apparatus characterised by constructional features

8.

MATERIAL FOR THE MANUFACTURE OF HIGH-STRENGTH FASTENERS AND METHOD FOR PRODUCING SAME

      
Document Number 03215094
Status Pending
Filing Date 2021-03-26
Open to Public Date 2022-09-29
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Leder, Mikhail Ottovich
  • Volkov, Anatoliy Vladimirovich
  • Grebenshchikov, Aleksandr Sergeyevich
  • Shchetnikov, Nikolay Vasilyevich

Abstract

The invention relates to metallurgy, and more particularly to producing titanium alloy-based materials with specific mechanical properties for the manufacture of fasteners for use in various fields of industry and preferably in the aerospace industry. The claimed material for the manufacture of high-strength fasteners is made from a titanium alloy containing alloying elements in the form of a-stabilizers, ?-stabilizers and neutral strengthening elements, the rest being titanium and unavoidable impurities. The size of a beta-subgrain in the structure of the material, which is subjected to solution annealing and aging, does not exceed 15 µm. The material for the manufacture of high-strength fasteners is produced in the form of round bar with a diameter of up to 40 mm or round wire with a diameter of up to 18 mm, which are subjected to solution annealing and aging. After solution annealing and aging, the material has an ultimate tensile strength of greater than 1400 MPa, an elongation of greater than 11%, a reduction in area of greater than 35% and a double shear strength of greater than 750 MPa. An intermediate blank for drawing is obtained by melting an ingot of titanium alloy, thermomechanically processing the ingot to obtain a forged billet and then rolling same. An intermediate blank for drawing is also obtainable using a powder metallurgy method.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • B21C 1/00 - Manufacture of metal sheets, wire, rods, tubes or like semi-manufactured products by drawing
  • C22F 1/18 - High-melting or refractory metals or alloys based thereon

9.

MATERIAL FOR THE MANUFACTURE OF HIGH-STRENGTH FASTENERS AND METHOD FOR PRODUCING SAME

      
Application Number RU2021000128
Publication Number 2022/203535
Status In Force
Filing Date 2021-03-26
Publication Date 2022-09-29
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Leder, Mikhail Ottovich
  • Volkov, Anatoliy Vladimirovich
  • Grebenshchikov, Aleksandr Sergeyevich
  • Shchetnikov, Nikolay Vasilyevich

Abstract

The invention relates to metallurgy, and more particularly to producing titanium alloy-based materials with specific mechanical properties for the manufacture of fasteners for use in various fields of industry and preferably in the aerospace industry. The claimed material for the manufacture of high-strength fasteners is made from a titanium alloy containing alloying elements in the form of α-stabilizers, ꞵ-stabilizers and neutral strengthening elements, the rest being titanium and unavoidable impurities. The size of a beta-subgrain in the structure of the material, which is subjected to solution annealing and aging, does not exceed 15 μm. The material for the manufacture of high-strength fasteners is produced in the form of round bar with a diameter of up to 40 mm or round wire with a diameter of up to 18 mm, which are subjected to solution annealing and aging. After solution annealing and aging, the material has an ultimate tensile strength of greater than 1400 MPa, an elongation of greater than 11%, a reduction in area of greater than 35% and a double shear strength of greater than 750 MPa. An intermediate blank for drawing is obtained by melting an ingot of titanium alloy, thermomechanically processing the ingot to obtain a forged billet and then rolling same. An intermediate blank for drawing is also obtainable using a powder metallurgy method.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • C22F 1/18 - High-melting or refractory metals or alloys based thereon
  • B21C 1/00 - Manufacture of metal sheets, wire, rods, tubes or like semi-manufactured products by drawing

10.

HIGH-STRENGTH TITANIUM ALLOY FOR ADDITIVE MANUFACTURING

      
Document Number 03109213
Status In Force
Filing Date 2018-08-31
Open to Public Date 2020-03-05
Grant Date 2023-05-02
Owner
  • THE BOEING COMPANY (USA)
  • PUBLIC STOCK COMPANY VSMPO-AVISMA CORPORATION (Russia)
Inventor
  • Mitropolskaya, Natalia Georgievna
  • Leder, Michael Ottovich
  • Puzakov, Igor Yurievich
  • Zaitsev, Alexey Sergeevich
  • Tarenkova, Natalia Yuryevna
  • Briggs, Robert David
  • Ghabchi, Arash
  • Catherine, Jane Parrish
  • Matthew, Jon Crill

Abstract

A titanium alloy for additive manufacturing that includes 5.5 to 6.5 wt% aluminum (Al); 3.0 to 4.5 wt% vanadium (V); 1.0 to 2.0 wt% molybdenum (Mo); 0.3 to 1.5 wt% iron (Fe); 0.3 to 1.5 wt% chromium (Cr); 0.05 to 0.5 wt% zirconium (Zr); 0.2 to 0.3 wt% oxygen (O); maximum of 0.05 wt% nitrogen (N); maximum of 0.08 wt% carbon (C); maximum of 0.25 wt% silicon (Si); and balance titanium, wherein a value of an aluminum structural equivalent [Al]eq ranges from 7.5 to 9.5 wt%, and is defined by the following equation: [Al]eq = [Al] + [O]×10 + [Zr]/6, and wherein a value of a molybdenum structural equivalent [Mo]eq ranges from 6.0 to 8.5 wt%, and is defined by the following equation: [Mo]eq = [Mo] + [V]/1.5 + [Cr]×1.25 + [Fe]x2.5.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • B33Y 10/00 - Processes of additive manufacturing
  • C22F 1/18 - High-melting or refractory metals or alloys based thereon

11.

HIGH STRENGTH FASTENER STOCK OF WROUGHT TITANIUM ALLOY AND METHOD OF MANUFACTURING THE SAME

      
Document Number 03110188
Status In Force
Filing Date 2018-08-31
Open to Public Date 2020-03-05
Grant Date 2023-06-27
Owner
  • THE BOEING COMPANY (USA)
  • PUBLIC STOCK COMPANY VSMPO-AVISMA CORPORATION (Russia)
Inventor
  • Mitropolskaya, Natalia Georgievna
  • Leder, Michael Ottovich
  • Puzakov, Igor Yurievich
  • Zaitsev, Alexey Sergeevich
  • Tarenkova, Natalia Yuryevna
  • Briggs, Robert David

Abstract

This invention generally relates to the field of nonferrous metallurgy, namely to titanium alloy materials with specified mechanical properties for manufacturing the aircraft fasteners. A stock for high strength fastener is manufactured from wrought titanium alloy containing, in weight percentages, 5.5 to 6.5 Al, 3.0 to 4.5 V, 1.0 to 2.0 Mo, 0.3 to 1.5 Fe, 0.3 tol.5 Cr, 0.05 to 0.5 Zr, 0.15 to 0.3 O, 0.05 max. N, 0.08 max. C, 0.25 max. Si, balance titanium and inevitable impurities, having the value of aluminum structural equivalent [Al]eq in the range of 7.5 to 9.5, and the value of molybdenum structural equivalent [Mo]eq in the range of 6.0 to 8.5, where the equivalents are defined by the following equations: [Al]eq =[Al]+[O]x l0+ [Zr]/6; [Mo]eq =[Mo]+[V]/1.5+[Cr]xl.25+[Fe]x2.5. A manufacturing method for a stock for high strength fastener includes melting of titanium alloy ingot, production of forged billed from ingot at beta and/or alpha-beta phase field temperatures, hot rolling at a heating temperature of beta and/or alpha-beta phase field to produce a round stock, subsequent annealing of a rolled stock at a temperature of 550°C to 705°C (1022°F to 1300°F) for at least 0.5 hour followed by drawing to produce a wire with diameter up to 10 mm (0.394 inches) and subsequent annealing at a temperature of 550°C to 705°C (1022°F to 1300°F) for at least 0.5 hour. A technical result is production of a titanium alloy stock for high strength fastener having high ultimate tensile strength and double shear strength while maintaining a high level of plastic properties in the annealed condition.12 claims, 5 illustrations.

IPC Classes  ?

  • C22F 1/18 - High-melting or refractory metals or alloys based thereon
  • C22C 14/00 - Alloys based on titanium
  • F16B 33/00 - Features common to bolt and nut

12.

HIGH-STRENGTH TITANIUM ALLOY FOR ADDITIVE MANUFACTURING

      
Application Number RU2018000577
Publication Number 2020/046160
Status In Force
Filing Date 2018-08-31
Publication Date 2020-03-05
Owner
  • THE BOEING COMPANY (USA)
  • PUBLIC STOCK COMPANY VSMPO-AVISMA CORPORATION (Russia)
Inventor
  • Mitropolskaya, Natalia Georgievna
  • Leder, Michael Ottovich
  • Puzakov, Igor Yurievich
  • Zaitsev, Alexey Sergeevich
  • Tarenkova, Natalia Yuryevna
  • Briggs, Robert David
  • Ghabchi, Arash
  • Catherine, Jane Parrish
  • Matthew, Jon Crill

Abstract

eqeqeqeqeq = [Mo] + [V]/1.5 + [Cr]×1.25 + [Fe]x2.5.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • C22F 1/18 - High-melting or refractory metals or alloys based thereon
  • B33Y 10/00 - Processes of additive manufacturing

13.

HIGH STRENGTH FASTENER STOCK OF WROUGHT TITANIUM ALLOY AND METHOD OF MANUFACTURING THE SAME

      
Application Number RU2018000578
Publication Number 2020/046161
Status In Force
Filing Date 2018-08-31
Publication Date 2020-03-05
Owner
  • THE BOEING COMPANY (USA)
  • PUBLIC STOCK COMPANY VSMPO-AVISMA CORPORATION (Russia)
Inventor
  • Mitropolskaya, Natalia Georgievna
  • Leder, Michael Ottovich
  • Puzakov, Igor Yurievich
  • Zaitsev, Alexey Sergeevich
  • Tarenkova, Natalia Yuryevna
  • Briggs, Robert David

Abstract

This invention generally relates to the field of nonferrous metallurgy, namely to titanium alloy materials with specified mechanical properties for manufacturing the aircraft fasteners. A stock for high strength fastener is manufactured from wrought titanium alloy containing, in weight percentages, 5.5 to 6.5 Al, 3.0 to 4.5 V, 1.0 to 2.0 Mo, 0.3 to 1.5 Fe, 0.3 tol.5 Cr, 0.05 to 0.5 Zr, 0.15 to 0.3 O, 0.05 max. N, 0.08 max. C, 0.25 max. Si, balance titanium and inevitable impurities, having the value of aluminum structural equivalent [Al]eq in the range of 7.5 to 9.5, and the value of molybdenum structural equivalent [Mo]eq in the range of 6.0 to 8.5, where the equivalents are defined by the following equations: [Al]eq =[Al]+[O]x l0+ [Zr]/6; [Mo]eq =[Mo]+[V]/1.5+[Cr]xl.25+[Fe]x2.5. A manufacturing method for a stock for high strength fastener includes melting of titanium alloy ingot, production of forged billed from ingot at beta and/or alpha-beta phase field temperatures, hot rolling at a heating temperature of beta and/or alpha-beta phase field to produce a round stock, subsequent annealing of a rolled stock at a temperature of 550°C to 705°C (1022°F to 1300°F) for at least 0.5 hour followed by drawing to produce a wire with diameter up to 10 mm (0.394 inches) and subsequent annealing at a temperature of 550°C to 705°C (1022°F to 1300°F) for at least 0.5 hour. A technical result is production of a titanium alloy stock for high strength fastener having high ultimate tensile strength and double shear strength while maintaining a high level of plastic properties in the annealed condition.12 claims, 5 illustrations.

IPC Classes  ?

  • C22F 1/18 - High-melting or refractory metals or alloys based thereon
  • C22C 14/00 - Alloys based on titanium
  • F16B 33/00 - Features common to bolt and nut

14.

TITANIUM ALLOY-BASED SHEET MATERIAL FOR LOW- TEMPERATURE SUPERPLASTIC DEFORMATION

      
Document Number 03062762
Status Pending
Filing Date 2017-04-25
Open to Public Date 2019-11-28
Owner
  • PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
  • THE BOEING COMPANY (USA)
Inventor
  • Leder, Mikhail Ottovich
  • Puzakov, Igor Yurievich
  • Tarenkova, Natalia Yuryevna
  • Berestov, Alexander Vladimirovich
  • Mitropolskaya, Natalia Georgievna
  • Briggs, Robert David

Abstract

Herein disclosed includes the manufacture of sheets from a titanium alloy having a chemical composition efficiently balanced with manufacturability based on known conventional manufacturing techniques for finished products exhibiting low temperature superplastic forming properties. The result is achieved by a sheet material for low temperature superplastic made of titanium alloy with the following content of element by % wt.: 4.5-5.5A1, 4.5-5.5V, 0.1-1.0Mo, 0.8-1.5Fe, 0.1-0.5Cr, 0.1-0.5Ni, 0.16-0.250, remainder is titanium and residual elements and having molybdenum structural equivalent [Mo]eqiv. > 5 and aluminium structural equivalent [Al]equiv. < 8; the equivalent values are calculated from the expressions: [Mo]eqiv. =[Mo]+[V]/1.5+[Cr] x1.25+[Fe] x2.5+[Ni]/0.8 [Al]eqiv. =[A1]+[O] x10+ [Zr]/6. Dependent claim 4, Table 8.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • C22F 1/18 - High-melting or refractory metals or alloys based thereon

15.

TITANIUM ALLOY-BASED SHEET MATERIAL FOR LOW-TEMPERATURE SUPERPLASTIC DEFORMATION

      
Application Number RU2017000266
Publication Number 2018/199791
Status In Force
Filing Date 2017-04-25
Publication Date 2018-11-01
Owner
  • PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
  • THE BOEING COMPANY (USA)
Inventor
  • Leder, Mikhail Ottovich
  • Puzakov, Igor Yurievich
  • Tarenkova, Natalia Yuryevna
  • Berestov, Alexander Vladimirovich
  • Mitropolskaya, Natalia Georgievna
  • Briggs, Robert David

Abstract

The technical result achieved by performing this invention is the production of sheets from a titanium alloy, the chemical composition of which is optimally balanced with the production capabilities of the known current technologies of the final product with the low-temperature superplastic deformation properties. The result is achieved by a sheet material for low-temperature superplastic deformation, which is based on a titanium alloy comprising, wt %: 4.5-5.5 Al; 4.5-5.5 V; 0.1-1.0 Mo; 0.8-1.5 Fe; 0.1-0.5 Cr, 0.1-0.5 Ni; 0.16-0.250 the remainder being titanium and impurities, wherein the value of the structural molybdenum equivalent, [Mo]eq. is higher than 5, and the aluminium structural equivalent, [Al]eq. is lower than 8; the equivalents are determined using the following formulae: [Mo]eq.=[Mo] + [V]/1.5 + [Cr]1.25 + [Fe]2.5 +[Ni]/0.8 [Al]eq.=[Al] + [O]10 + [Zr]/6.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • C22F 1/18 - High-melting or refractory metals or alloys based thereon

16.

ECONOMICALLY ALLOYED TITANIUM ALLOY WITH PREDICTABLE PROPERTIES

      
Application Number RU2015000555
Publication Number 2016/043625
Status In Force
Filing Date 2015-09-02
Publication Date 2016-03-24
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Tarenkova, Natalia Yuryevna
  • Kornilova, Maria Anatolievna
  • Rymkevich, Dmitriy Anatolievich

Abstract

The invention relates to the field of non-ferrous metallurgy, and more particularly to the creation of titanium alloys which, by virtue of their properties, are economical to use not only in traditional, particularly military, fields, but also in civilian fields of industry. The alloy contains 0.1-3.0 Al, 0.3-3.0 Fe, 0.1-1.0 Cr, 0.05-1.0 Ni, 0.02-0.3 Si, 0.02-0.2 N, 0.05-0.5 О, 0.02-0.1 C, and the remainder Ti. The technical result is the production of a commercially viable titanium alloy with guaranteed stable, predictable properties which is manufactured using low-grade titanium sponge. This result is achieved in that the alloying elements used include impurity elements contained in the low-grade sponge, as well as alloying additives separately added to the charge. The titanium-based alloy has a lower price compared to existing commercial alloys and, furthermore, the composition of the alloy is selected in accordance with a prescribed level of physical and mechanical properties and fabrication characteristics.

IPC Classes  ?

17.

METHOD FOR MANUFACTURING COLD ROLLED PIPES FROM ALPHA- AND PSEUDO-ΑLPHA TITANIUM ALLOYS

      
Application Number RU2014000890
Publication Number 2015/088388
Status In Force
Filing Date 2014-11-26
Publication Date 2015-06-18
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Poludin, Aleksandr Vital'Evich
  • Beloborodova, Evgeniya Anatol`evna
  • Krokhin, Boris Glebovich
  • Kalinin, Vladimir Sergeevich
  • Shushakov, Sergey Viktorovich

Abstract

The invention relates to pipe production, and specifically to the cold rolling of pipes made from α- and pseudo-α titanium alloys. The technical result which is achieved in carrying out the invention is the creation of an economically-viable technique for manufacturing pipes from α- and pseudo-α titanium alloys, in which operations for forming the geometric dimensions and the quality of the surface of the product are combined with processes for forming a regulated micro-structure, providing advanced technological and operational product characteristics. A method for manufacturing cold-worked pipes from α- and pseudo-α titanium alloys includes melting an ingot, forging the ingot in the β- and (α+β)-region and completing the forging in the (α+β)-region in an intermediate billet with a forging reduction ratio of from 2 to 3, piercing is carried out at a temperature which is 30-50°С higher than the polymorphic transition temperature, using multi-tapered rollers and a mandrel having given dimensions, with the feeding of water to the deformation zone, expanding is conducted at 10-90° lower than the polymorphic transition temperature, pipe billet correction is carried out at between 350 and 400°С, cold rolling is carried out with an elongation ratio of between 1.5 and 4.5 over numerous stages, alternated with intermediate annealing at a temperature equal to 600-750°С, after which heat treatment is carried out on a product having finalized dimensions at a temperature of 580-650°С.

IPC Classes  ?

  • C22F 1/18 - High-melting or refractory metals or alloys based thereon
  • B21B 23/00 - Tube-rolling not restricted to methods provided for in only one of groups , e.g. combined processes
  • B21C 37/06 - Manufacture of metal sheets, rods, wire, tubes, profiles or like semi-manufactured products, not otherwise provided forManufacture of tubes of special shape of tubes or metal hosesCombined procedures for making tubes, e.g. for making multi-wall tubes

18.

Method for the melting of near-beta titanium alloy consisting of (4.0-6.0) wt % Al-(4.5-6.0) wt % Mo-(4.5-6.0) wt % V-(2.0-3.6) wt % Cr-(0.2-0.5) wt % Fe-(0.1-2.0) wt % Zr

      
Application Number 13876025
Grant Number 09234261
Status In Force
Filing Date 2011-09-23
First Publication Date 2013-12-26
Grant Date 2016-01-12
Owner Public Stock Company, “VSMPO-AVISMA Corporation ” (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Levin, Igor Vasilievich

Abstract

This invention relates to nonferrous metallurgy, namely to manufacture of near-beta titanium alloys containing titanium and such alloying elements as molybdenum, vanadium, chromium, zirconium, iron and aluminum. The provided alloy contains the following components, in weight percentages: molybdenum—25 to 27; vanadium—25 to 27; chromium—14 to 16; titanium—9 to 11; with balance aluminum and iron and zirconium in the form of commercially pure metals. The technical result of this invention is capability to produce a near-beta titanium alloy with high chemical homogeneity alloyed by refractory elements and having aluminum content ≦6 wt %, wherein the alloy is characterized by a combination of stable high strength and high impact strength.

IPC Classes  ?

  • C22C 14/00 - Alloys based on titanium
  • C22F 1/18 - High-melting or refractory metals or alloys based thereon
  • C22B 9/20 - Arc remelting
  • C22C 1/03 - Making non-ferrous alloys by melting using master alloys

19.

Method for the manufacture of wrought articles of near-beta titanium alloys

      
Application Number 13876017
Grant Number 09297059
Status In Force
Filing Date 2011-09-23
First Publication Date 2013-09-12
Grant Date 2016-03-29
Owner Public Stock Company, “VSMPO-AVISMA Corporation” (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Levin, Igor Vasilievich

Abstract

1C, over 70 MPa√m with ultimate tensile strength not less than 1100 MPa.

IPC Classes  ?

  • C22F 1/18 - High-melting or refractory metals or alloys based thereon
  • C22C 14/00 - Alloys based on titanium

20.

METHOD FOR MANUFACTURING A HOLLOW FAN BLADE

      
Application Number RU2011000984
Publication Number 2012/173512
Status In Force
Filing Date 2011-12-14
Publication Date 2012-12-20
Owner
  • INSTITUTE FOR METALS SUPERPLASTICITY PROBLEMS OF THE RUSSIAN ACADEMY OF SCIENCES (IMSP RAS) (Russia)
  • AVIADVIGATEL OPEN JOINT STOCK COMPANY (Russia)
  • UFA ENGINE INDUSTRIAL ASSOCIATION OJSC (Russia)
  • PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Mulyukov, Radik Rafikovich
  • Inozemtsev, Alexander Alexandrovich
  • Safiullin, Rinat Vladikovich
  • Kharin, Sergey Alexandrovich
  • Kozlov, Alexander Nikolaevich
  • Koksharov, Nikolay Leonidovich
  • Kropotov, Vladimir Alexeevich
  • Kruglov, Alexey Anatolievich
  • Levin, Igor Vasilievich
  • Manapov, Irek Usmanovich
  • Morozov, Mikhail Alexandrovich
  • Pavlinich, Sergey Petrovich
  • Perepelitsa, Sergey Illarionovich
  • Trifonov, Vadim Gennadievich

Abstract

The invention is intended for manufacturing a hollow fan blade for a gas-turbine engine. A joint-preventing coating is applied to the surface of sections of blanks not undergoing welding. The blanks are assembled into a stack and hermetically sealed along the edges. Cavities in the stack are evacuated and filled with an inert gas. A binder of the coating is removed by heating. Diffusion welding of the blanks is carried out. The blank is then arranged such that adjacent surfaces of blank linings and a filler are located in a horizontal plane, and adhesive bonds between the blanks and the coating are torn in sections where no joint had been formed, thereby producing a pressure in the cavities in the blank for elastic deformation of the blank linings and filler. The cavities in the blank are sequentially evacuated and filled with an inert gas in order to remove oxygen therefrom and, after evacuation, are subsequently hermetically sealed. A trough, a blade back and a blade body are formed from the blank by hot deformation. The blank is heated and a working medium is fed into the cavities, thereby producing a pressure for superplastic moulding to produce the hollow blade body and reinforcing ribs. The invention makes it possible to extend the technological possibilities for manufacturing a hollow fan blade.

IPC Classes  ?

  • B21D 53/78 - Making other particular articles propeller bladesMaking other particular articles turbine blades
  • B23K 20/18 - Zonal welding by interposing weld-preventing substances between zones not to be welded
  • B23K 103/14 - Titanium or alloys thereof
  • B21D 26/02 - Shaping without cutting otherwise than by using rigid devices or tools or yieldable or resilient pads, e.g. shaping by applying fluid pressure or magnetic forces by applying fluid pressure
  • B23K 101/02 - Honeycomb structures

21.

METHOD FOR MELTING A PSEUDO β-TITANIUM ALLOY COMPRISING (4.0-6.0)% АL - (4.5-6.0)% МО - (4.5-6.0)% V - (2.0-3.6)% СR, (0.2-0.5)% FE - (0.1-2.0)% ZR

      
Application Number RU2011000731
Publication Number 2012/044205
Status In Force
Filing Date 2011-09-23
Publication Date 2012-04-05
Owner PUBLIC STOCK COMPANY " VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Levin, Igor Vasilievich

Abstract

The invention relates to the field of nonferrous metallurgy, and specifically to the production of pseudo β-titanium alloys comprising titanium and also the following alloying elements: molybdenum, vanadium, chromium, zirconium, iron and aluminium. The proposed alloy comprises the following components: 25-27% by mass of molybdenum; 25-27% by mass of vanadium; 14-16% by mass of chromium; 9-11% by mass of titanium; aluminium as the base, and iron and zirconium in the form of technically pure metals. The technical result of the invention is the possibility of producing a pseudo β-titanium alloy with a highly homogeneous chemical composition, which is alloyed with high-melting elements, has a ≤6% content of aluminium and has stable high-impact properties in combination with high-impact strength.

IPC Classes  ?

22.

METHOD FOR MANUFACTURING DEFORMED ARTICLES FROM PSEUDO-β-TITANIUM ALLOYS

      
Application Number RU2011000730
Publication Number 2012/044204
Status In Force
Filing Date 2011-09-23
Publication Date 2012-04-05
Owner PUBLIC STOCK COMPANY " VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Levin, Igor Vasilievich

Abstract

The invention relates to the processing of pseudo-β-titanium alloys and can be used for manufacturing structural parts and assemblies in aerospace engineering. In the manufacture of deformed articles from pseudo-β-titanium alloys, an ingot of a titanium alloy comprising aluminium, vanadium, molybdenum, chromium, iron, zirconium, oxygen and nitrogen is produced. The ingot is subjected to thermomechanical processing by means of repeated heating, deformation and cooling. High-precision stamped articles with a thickness in cross section of 100 mm or greater and a length of greater than 6 m are produced with stable, high values for ultimate tensile strength and fracture toughness.

IPC Classes  ?

  • C22F 1/18 - High-melting or refractory metals or alloys based thereon

23.

SECONDARY TITANIUM ALLOY AND METHOD FOR MANUFACTURING SAME

      
Document Number 02787980
Status In Force
Filing Date 2010-12-31
Open to Public Date 2011-07-28
Grant Date 2019-07-16
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Levin, Igor Vasilievich
  • Puzakov, Igor Jurievich
  • Tarenkova, Natalia Jurievna

Abstract

This invention relates to production of .alpha.-, near .alpha.- and .alpha.+.beta.-titanium alloys from secondary raw materials, which are used mainly in manufacture of sheet material, structural parts and structural armor for defense and civil sectors. This alloy is characterized by the following chemical composition (% weight): 0.01% to 6.5% Al, 0.01% to 5.5% V, 0.05% to 2.0% Mo, 0.01% to 1.5% Cr, 0.1% to 2.5% Fe, 0.01% to 0.5% Ni, 0.01% to 0.5% Zr, 0.01% to 0.25% Si, up to 0.3% oxygen, up to 0.1% carbon, up to 0.07% nitrogen, and the remainder being titanium. The alloy blend is formulated based on the required tensile strength, while contents of alloying elements are calculated based on the design value of aluminum and molybdenum strength equivalents.

IPC Classes  ?

24.

SECONDARY TITANIUM ALLOY AND METHOD FOR MANUFACTURING SAME

      
Application Number RU2010000816
Publication Number 2011/090402
Status In Force
Filing Date 2010-12-31
Publication Date 2011-07-28
Owner PUBLIC STOCK COMPANY "VSMPO-AVISMA CORPORATION" (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Levin, Igor Vasilievich
  • Puzakov, Igor Jurievich
  • Tarenkova, Natalia Jurievna

Abstract

The invention relates to the field for producing α, pseudo α and α+β titanium alloys from a secondary raw material, preferably for manufacturing sheet-like semifinished products, construction products and structural armor and can be used in the defense and civil sectors of industry. The alloy has the following composition, in mass%: 0.01 - 6.5 Аl, 0.01-5.5 V, 0.05 - 2.0 Мо, 0.01 - 1.5 Сr, 0.1 - 2.5 Fe, 0.01-0.5 Ni, 0.01 - 0.5 Zr, 0.01-0.25 Si, up to 0.3 oxygen, up to 0.1 carbon, up to 0.07 nitrogen, and the remainder titanium. The charge is composed depending on the required value for the durability of the alloy over time, and the content of the alloying elements in the alloy is determined from the calculated values for the aluminium and molybdenum strength equivalents. The proposed alloy and method for manufacturing same make it possible to solve the problem of involving a broad spectrum of waste materials of titanium alloys so as to produce an end product having set technological and structural properties.

IPC Classes  ?

25.

ALUMINIUM-BASED ALLOY

      
Application Number RU2007000155
Publication Number 2007/114737
Status In Force
Filing Date 2007-04-02
Publication Date 2007-10-11
Owner PUBLIC STOCK COMPANY 'VSMPO-AVISMA CORPORATION' (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Sukhikh, Alexander Yuvenalievich
  • Dekun, Ivan Ivanovich
  • Efremov, Igor Vladimirovich
  • Ivanov, Vitaly Vyacheslavovich

Abstract

The invention relates to metallurgy, in particular to producing aluminium-based alloys used for obtaining pressed wheel disks. The inventive alloy comprises the following components: 0.8÷2.2 mass % copper, 1.2÷2.6 mass % magnesium, 0.2÷0.6 mass % manganese, ≤0.2 5mass % iron, ≤0.20 mass % silicon, 5.0÷6.8 mass % zinc, ≤0.1 titanium, 0.08-1.7 mass % chromium, 0.01÷0.12 mass % zirconium, 0.0008÷0.005 mass % bore, (0.3-4.1)10 -5 mass % hydrogen, the rest being aluminium, wherein ≤0.25 mass % Ti+Zr+Cr and ≤8.6 mass % Cu+Mg+Zn. Said invention makes it possible to produce an alloy optimally combining strength and plasticity properties which provide wheel disks with required performance characteristics, reduce the mass thereof in combination with the high processabilty in die forging, in particular of irregular-shaped articles.

IPC Classes  ?

  • C22C 21/10 - Alloys based on aluminium with zinc as the next major constituent

26.

TITANIUM-BASED ALLOY

      
Application Number RU2006000234
Publication Number 2006/123968
Status In Force
Filing Date 2006-05-06
Publication Date 2006-11-23
Owner PUBLIC STOCK COMPANY 'VSMPO-AVISMA CORPORATION (Russia)
Inventor
  • Tetyukhin, Vladislav Valentinovich
  • Levin, Igor Vasilievich
  • Puzakov, Igor Jurievich

Abstract

The invention relates to non-ferrous metallurgy, in particular to producing modern titanium alloys exhibiting a high degree of genericity. The inventive titanium-based alloy comprises aluminium, vanadium, molybdenum, chromium, iron, zirconium, oxygen and nitrogen at the following component ratio: 4.0-6.0 mass % aluminium, 4.5-6.0 mass % molybdenum, 2.0-3.6 mass % chromium, 0.2-0.2 mass % iron, 0.1- less than 0.7 mass % zirconium, less than 0.2 mass % oxygen, less than 0.05 mass % nitrogen, the rest being titanium. Said invention makes it possible to develop a titanium alloy exhibiting required strength and plastic characteristics. The inventive alloy can be used for producing a large range of products, including large-sized pressed and forged products and a small cross-section semiproducts such as rods and plates whose thickens is equal to or less than 75 mm.

IPC Classes  ?

27.

VSMPO

      
Application Number 003725108
Status Registered
Filing Date 2004-03-24
Registration Date 2005-06-20
Owner Public Stock Company "VSMPO-AVISMA Corporation" (Russia)
NICE Classes  ?
  • 06 - Common metals and ores; objects made of metal
  • 11 - Environmental control apparatus
  • 12 - Land, air and water vehicles; parts of land vehicles

Goods & Services

Common metals and their alloys; ores; undressed and partly processed castings; metal building materials, metal components and metal constructions; materials of metal for railway tracks; pipes, tubes and receptacles of metal; non-electric cables and wires of common metal; ironmongery and small items of metal hardware; safes; packing material, ie containers, boxes, cases, cans and foils of metal; goods of common metal (included in class 6), particularly semifinished products, ingots, slabs, billets, plates, sheets, sheet metals, stampings, die forgings, forgings, tubes, bars, wires, profiles of base metals, particularly ferrotitan. Apparatus for lighting, heating, steam generating, cooking, refrigerating, drying, ventilating, air-conditioning and water supply as well as sanitary purposes, particularly radiators for central heating and heat exchanger. Vehicles; apparatus for locomotion by land, air or water; motors, turbines, couplings and transmissions for land vehicles; parts of all above goods (included in class 12), particularly wheels for transport vehicles, hub caps.

28.

TIRUS

      
Application Number 003117843
Status Registered
Filing Date 2003-04-01
Registration Date 2004-04-20
Owner Public Stock Company "VSMPO-AVISMA Corporation" (Russia)
NICE Classes  ?
  • 06 - Common metals and ores; objects made of metal
  • 11 - Environmental control apparatus
  • 12 - Land, air and water vehicles; parts of land vehicles

Goods & Services

Common metals and their alloys, ores; cast iron, unwrouthg or semi-wrouthg; building materials, parts for buildings and buildings of metal; materials of metal for railway tracks; metal tubes and pipes; containers of metal; non electric cables and wires of common metal; ironmongery, small items of metal hardware; safes; material for packaging, namely containers, cases, drums and films of metal; goods of metal (included in class 6), in particular semi-finished goods, plates, sheets, stampings, pipes, wires, profiles of common metals, in particular ferrotitanium. Apparatus for lighting, heating, steam generating, cooking, refrigerating, drying, ventilating, air conditioning, water supply and sanitary purposes, in particular central heating radiators and heat exchangers. Vehicles, except bicycles; vehicles for the transportation of passengers to and from airports and aircraft; engines and motors, turbines, couplings and gears for land vehicles; parts for all the aforesaid goods (included in class 12), in particular vehicle wheels and hub caps therefor, except bicycle parts.