A fluorine-containing pyrazole compound represented by general formula (1), wherein R represents a hydrocarbon group having 1 to 12 carbon atoms; X represents a heterocyclic group containing at least one heteroatom selected from the group consisting of a halogen atom, nitrogen and oxygen as a ring atom, —OA1, and —NA1A2; and A1 and A2 each independently represents a hydrogen atom or an organic group having 1 to 10 carbon atoms.
A fluorine-containing pyrazole compound represented by general formula (1), wherein R represents a hydrocarbon group having 1 to 12 carbon atoms; X represents a heterocyclic group containing at least one heteroatom selected from the group consisting of a halogen atom, nitrogen and oxygen as a ring atom, —OA1, and —NA1A2; and A1 and A2 each independently represents a hydrogen atom or an organic group having 1 to 10 carbon atoms.
C07D 417/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 231/20 - One oxygen atom attached in position 3 or 5
C07D 231/52 - Oxygen atom in position 3 and nitrogen atom in position 5, or vice-versa
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 405/12 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 413/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
2.
METHOD FOR USING PHENOTHIAZINE DERIVATIVE COMPOUND
Provided is a method for using a phenothiazine derivative compound, wherein when producing a synthetic polymer material produced by addition polymerization of a polymerizable unsaturated monomer, the polymerizable unsaturated monomer constituting the synthetic polymer material is copolymerized with a phenothiazine derivative compound represented by a general formula (R1is a C1-10 monovalent aliphatic hydrocarbon group, and R2 is a hydrogen atom or a methyl group) to prevent the oxidative deterioration of the synthetic polymer material. This compound can be copolymerized with various polymerizable unsaturated monomers because the polymerization inhibiting effect characteristic of phenothiazine compounds is reduced.
C08F 228/06 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a heterocyclic ring containing sulfur
A crosslinkable acrylic rubber composition containing: (A) acrylic rubber containing a carbamic acid ester group and a carboxyl group; (B) a phenothiazine-based antioxidant represented by formula [I], wherein R3 is a hydrogen atom, a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or an acyl group represented by formula II, wherein R4 is a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, and R5 is an aralkyl group having 7 to 20 carbon atoms; and (C) a crosslinking accelerator.
A crosslinkable acrylic rubber composition containing: (A) acrylic rubber containing a carbamic acid ester group and a carboxyl group; (B) a phenothiazine-based antioxidant represented by formula [I], wherein R3 is a hydrogen atom, a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or an acyl group represented by formula II, wherein R4 is a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, and R5 is an aralkyl group having 7 to 20 carbon atoms; and (C) a crosslinking accelerator.
The present invention provides: a 3-isoxazolone compound having a trifluoromethyl group at position 4 of an isoxazolone ring and having a specific substituent at position 2 and position 5 of the isoxazolone ring; and a 5-isoxazolone compound having a trifluoromethyl group at position 4 of an isoxazolone ring and having a specific substituent at position 2 and position 3. The present invention also provides a production method with which it is possible to produce, in a simplified manner, a 3-isoxazolone compound and a 5-isoxazolone compound without generating, as a by-product, an O-substitution product through reaction of a specific material. This fluorine-containing isoxazolone compound is represented by general formula (1).
C07D 419/06 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen, oxygen, and sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
Provided are: a novel fluorinated 1,2-disubstituted-3-pyrazolone compound having a trifluoromethyl group at position-4 and also having a specific substituent at position-5; and a production method whereby it becomes possible to produce the fluorinated pyrazolone compound in a simple manner without producing an O-substituted product as a byproduct. The fluorinated pyrazolone compound is represented by general formula (1). (In general formula (1), X represents a halogen atom, -OA1ll)A1(wherein l represents an integer of 0 to 2), -O-NA1A2, -NA1A2, -NA3-NA1A2, or -N=A4; Y and Z each independently represent an aromatic hydrocarbon group having 1 to 12 carbon atoms, an alkyl group, -COA1, -COOA1, a benzyl group, or a carbamoyl group, or Y and Z are bound to each other to form a ring; and A1, A2, A3and A4 each independently represent an organic group having 1 to 12 carbon atoms.)
C07D 231/20 - One oxygen atom attached in position 3 or 5
C07D 231/22 - One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
C07D 401/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
A fluorine-containing elastomer composition comprising 0.4 to 4.0 parts by weight of a pigment that is a perylene-based compound, a naphthalenecarboxamide-based compound, a pyrimidinetrione-based compound, or a benzimidazolone-based compound, and 0.2 to 5.0 parts by weight of a bisamidoxime compound or 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane, based on 100 parts by weight of a fluorine-containing elastomer having a copolymer composition of (A) 60.0 to 80.0 mol % of tetrafluoroethylene, (B) 19.8 to 39.8 mol % of perfluoro(lower alkyl vinyl ether) or perfluoro(lower alkoxy lower alkyl vinyl ether), and (C) 0.2 to 5.0 mol % of a perfluoro unsaturated nitrile compound.
32m36n24o2p24q2r2s32s33; and R is a C1-3 alkyl group). This surface modifier has excellent water and oil repellency, antifouling properties, weather resistance, and durability (wear resistance), as well as good coating film transparency and liquid storage stability.
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
8.
FLUORINE-CONTAINING PYRAZOLE COMPOUND AND PRODUCTION METHOD THEREFOR
A fluorine-containing pyrazole compound represented by the following general formula (1):
A fluorine-containing pyrazole compound represented by the following general formula (1):
A fluorine-containing pyrazole compound represented by the following general formula (1):
wherein in the general formula (1) above, R represents a hydrocarbon group having 1 to 12 carbon atoms; and a ring Z represents a phenyl group having a substituent, or a condensed ring containing no heteroatom as a ring atom.
01 - Chemical and biological materials for industrial, scientific and agricultural use
04 - Industrial oils and greases; lubricants; fuels
17 - Rubber and plastic; packing and insulating materials
Goods & Services
Chemicals; inorganic salts; ammonium salts; sodium salts; surface-active chemical agents; mold-release preparations; chemical agents; chemical reagents, other than for medical or veterinary purposes; vulcanising preparations; vulcanisation accelerators; chemical intensifiers for paper; chemical substances for analyses in laboratories, other than for medical or veterinary purposes; iodine for industrial purposes; anti-reflection coating chemicals; fluorspar compounds; acrylic monomer in the nature of fluorine monomers; acrylic polymer; adhesives, not for stationery or household purposes; adhesives for industrial purposes; higher fatty acids; unprocessed plastics; polymerization plastics; acrylic resins, unprocessed; fluorine resins, unprocessed; polyurethane resins, unprocessed; synthetic resins, unprocessed; inorganic chemicals; organic chemicals; plant growth regulating preparations; fertilizers; ceramic glazings; non-metallic minerals; artificial sweeteners; flour and starch for industrial purposes; groundwood pulp or chemical pulps for manufacturing purposes; cross-linking agents Industrial oils; industrial fats; lubricants; industrial greases; fuels; industrial waxes; lighting waxes; dust removers Plastic semi-worked products; rubber, raw or semi-worked; synthetic rubber; packings of rubber; packings of plastics; gaskets of
plastics; oil seals of rubber; oil seals of plastics; O-rings of rubber; O-rings of plastics; mica, raw or partly processed; valves of
rubber or vulcanized fiber, not including machine elements; gaskets; junctions for pipes, not of metal; packings; asbestos fire
curtains; floating anti-pollution barriers; chemical fiber, not for textile use; asbestos; rock wool; slag wool; rubber thread and
covered rubber yarn, not for textile use; chemical fiber yarn and thread, not for textile use; asbestos yarn; asbestos fabrics;
asbestos felt; insulating gloves; rubber cords and laces; asbestos cords and strings; asbestos nets; industrial packaging
containers of rubber; rubber stoppers for industrial packaging containers; rubber lids and caps for industrial packaging containers;
plastic sheeting for agricultural purposes; soundproofing materials of rock wool, not for building purposes; asbestos boards;
asbestos powder; acrylic rubber; nitrile rubber; fluoro rubber; latex, rubber; liquid rubber; pipe gaskets; sealant compounds for
joints; joint packings; packings as sealing devices; oil seals; O-rings; rings of rubber; seal washers; insulating materials
01 - Chemical and biological materials for industrial, scientific and agricultural use
04 - Industrial oils and greases; lubricants; fuels
17 - Rubber and plastic; packing and insulating materials
Goods & Services
Chemicals; inorganic salts; ammonium salts; sodium salts; surface-active chemical agents; mold-release preparations; chemical agents; chemical reagents, other than for medical or veterinary purposes; vulcanising preparations; vulcanisation accelerators; chemical intensifiers for paper; chemical substances for analyses in laboratories, other than for medical or veterinary purposes; iodine for industrial purposes; anti-reflection coating chemicals; fluorspar compounds; acrylic monomer in the nature of fluorine monomers; acrylic polymer; adhesives [not for stationery or household purposes]; adhesives for industrial purposes; higher fatty acids; unprocessed plastics; polymerization plastics; acrylic resins, unprocessed; fluorine resins, unprocessed; polyurethane resins, unprocessed; synthetic resins, unprocessed; inorganic chemicals; organic chemicals; plant growth regulating preparations; fertilizers; ceramic glazings; non-metallic minerals, namely phosphorus, sulfur, potassium salts, magnesium salts, synthetic quartz and graphite; artificial sweeteners for industrial purposes; flour and starch for industrial purposes; groundwood pulp or chemical pulps for manufacturing purposes; cross-linking agents. Industrial oils; industrial fats; lubricants; Industrial greases; fuels; industrial waxes; lighting waxes; dust removing preparations. Plastic semi-worked products; rubber, raw or semi-worked; Synthetic rubber; packings of rubber; packings of plastics; gaskets of plastics; oil seals of rubber; oil seals of plastics; O-rings of rubber; O-rings of plastics; mica (raw or partly processed); valves of rubber or vulcanized fiber (not including machine elements); gaskets; junctions for pipes (not of metal); asbestos fire curtains; floating anti-pollution barriers; asbestos; rock wool; slag wool; rubber thread and covered rubber yarn (not for textile use); asbestos yarn; asbestos fabrics; asbestos felt; rubber cords and laces; asbestos cords and strings; asbestos nets; industrial packaging containers of rubber; rubber stoppers (for industrial packaging containers); rubber lids and caps (for industrial packaging containers); plastic sheeting for agricultural purposes; soundproofing materials of rock wool (not for building purposes); asbestos boards; asbestos powder; acrylic rubber; nitrile rubber; fluoro rubber; latex [rubber]; liquid rubber; pipe gaskets; sealant compounds for joints; joint packings; joint packings for sealing purposes; oil seals; O-rings; rings of rubber; insulating materials.
11.
ETHYLENE-(METH)ACRYLATE-BASED ELASTOMER AND METHOD FOR PRODUCING THE SAME
An ethylene-(meth)acrylate-based elastomer having a structure in which 40 to 79.9 mol % of ethylene, 20.0 to 50.0 mol % of an alkyl (meth)acrylate containing an alkyl group having 1 to 8 carbon atoms and/or an alkoxy (meth)acrylate containing an alkoxyalkyl group having 2 to 8 carbon atoms, 0.05 to 20.0 mol % of an unsaturated dicarboxylic acid monosaturated ester, and 0 to 20.0 mol % of an unsaturated dicarboxylic anhydride are copolymerized, and having a monosaturated esterification rate of the acid anhydride of 70% or more as measured by IR. The ethylene-(meth)acrylate-based elastomer gives a vulcanizate having excellent heat resistance, and molding processability.
C08F 234/02 - Copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring in a ring containing oxygen
12.
FLUORINATED PYRIMIDINE COMPOUND AND METHOD FOR PRODUCING SAME
A fluorinated pyrimidine compound represented by the following general formula (1a) or (1b):
A fluorinated pyrimidine compound represented by the following general formula (1a) or (1b):
A fluorinated pyrimidine compound represented by the following general formula (1a) or (1b):
wherein R1 represents a hydrocarbon group having 1 to 12 carbon atoms, R2 represents a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1, a nitro group, a boronic acid group, a cyano group, —OA1, —O1SOmA1, —NA1A2, —O1COOA1, or —O1CONA1A2, A1 and A2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, A1 and A2 may be bonded to form a ring structure, and when a plurality of R2 is present, the plurality of R2 may be the same or different from each other, and a ring Z is a 5-membered aromatic heterocyclic ring containing one oxygen atom and one or more nitrogen atoms.
C07D 413/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
13.
FLUORINE-CONTAINING ISOXAZOLE COMPOUND AND METHOD FOR PRODUCING SAME
The present invention relates to a fluorine-containing isoxazole compound represented by general formula (A). (In general formula (A), R represents a hydrogen atom or a substituted or unsubstituted C1-12 hydrocarbon group, X represents a halogen atom, -OA1, -O-NA1A2, -NA1A2, -NA1(OA2), -NA3-NA1A2, -NA4, or a heterocycle, A1, A2, and A3each independently represent a substituted or unsubstituted C1-12 hydrocarbon group or a heterocycle, A4n2n2n, n is an integer of 1-20, and Y1and Y2 each independently represent N or O and are different from each other.)
C07D 413/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
01 - Chemical and biological materials for industrial, scientific and agricultural use
09 - Scientific and electric apparatus and instruments
17 - Rubber and plastic; packing and insulating materials
Goods & Services
(1) Chemicals; inorganic salts; ammonium salts; sodium salts; surface-active chemical agents; mold-release preparations; chemical agents; chemical reagents, other than for medical or veterinary purposes; vulcanising preparations; vulcanisation accelerators; chemical intensifiers for paper; chemical substances for analyses in laboratories, other than for medical or veterinary purposes; iodine for industrial purposes; anti-reflection coating chemicals; fluorspar compounds; acrylic monomer in the nature of fluorine monomers; acrylic polymer; adhesives [not for stationery or household purposes]; adhesives for industrial purposes; higher fatty acids; unprocessed plastics; polymerization plastics; acrylic resins, unprocessed; fluorine resins, unprocessed; polyurethane resins, unprocessed; synthetic resins, unprocessed; inorganic chemicals; organic chemicals; plant growth regulating preparations; fertilizers; ceramic glazings; non-metallic minerals; artificial sweeteners; flour and starch for industrial purposes; groundwood pulp or chemical pulps for manufacturing purposes; cross-linking agents.
(2) Plastic semi-worked products; rubber, raw or semi-worked; Synthetic rubber; packings of rubber; packings of plastics; gaskets of plastics; oil seals of rubber; oil seals of plastics; O-rings of rubber; O-rings of plastics; mica (raw or partly processed); valves of rubber or vulcanized fiber (not including machine elements); gaskets; junctions for pipes (not of metal); packings; asbestos fire curtains; floating anti-pollution barriers; chemical fiber (not for textile use); asbestos; rock wool; slag wool; rubber thread and covered rubber yarn (not for textile use); chemical fiber yarn and thread (not for textile use); asbestos yarn; asbestos fabrics; asbestos felt; insulating gloves; rubber cords and laces; asbestos cords and strings; asbestos nets; industrial packaging containers of rubber; rubber stoppers (for industrial packaging containers); rubber lids and caps (for industrial packaging containers); plastic sheeting for agricultural purposes; soundproofing materials of rock wool (not for building purposes); asbestos boards; asbestos powder; acrylic rubber; nitrile rubber; fluoro rubber; latex [rubber]; liquid rubber; pipe gaskets; sealant compounds for joints; joint packings; packings as sealing devices; oil seals; O-rings; rings of rubber; seal washers; insulating materials.
15.
FLUORINE-CONTAINING PYRIDONE COMPOUND AND METHOD FOR PRODUCING SAME
mmR2nmmR2mmR2llR322, Y represents R4, OR4, or NR4R5, R1to R5 each independently represent a C1 to 12 hydrocarbon group, l and m each independently are 0 or 1, and n is 1 or 2.)
An ethylene-(meth)acrylate-based elastomer having a structure in which 40 to 79.9 mol % of ethylene, 20.0 to 50.0 mol % of an alkyl (meth)acrylate containing an alkyl group having 1 to 8 carbon atoms and/or an alkoxy (meth)acrylate containing an alkoxyalkyl group having 2 to 8 carbon atoms, 0.05 to 20.0 mol % of an unsaturated dicarboxylic acid, and 0.001 to 20.0 mol % of an unsaturated dicarboxylic anhydride are copolymerized, and having a melt flow rate of 0.01 to 100 g/10 min measured under the conditions of a temperature of 190° C. and a load of 2.16 kg. The ethylene-(meth)acrylate-based elastomer gives a vulcanizate having excellent heat resistance, oil resistance, and molding processability.
A fluorine-containing pyrimidine compound is represented by the following formula (1) or (2):
A fluorine-containing pyrimidine compound is represented by the following formula (1) or (2):
A fluorine-containing pyrimidine compound is represented by the following formula (1) or (2):
wherein R represents a hydrocarbon group having 1 to 12 carbon atoms; and X and Y each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1 where n is an integer of 1 to 10, a nitro group, a boronic acid group, —OA1, —SOmA1 where m is an integer of 0 to 3, —NA1A2, —COOA1, or —CONA1A2, where A1 and A2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms.
C07D 405/04 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
18.
FLUORINE-CONTAINING PYRIMIDINE COMPOUND AND METHOD FOR PRODUCING SAME
A fluorine-containing pyrimidine compound represented by formula (1), (2) or (3) is provided:
A fluorine-containing pyrimidine compound represented by formula (1), (2) or (3) is provided:
A fluorine-containing pyrimidine compound represented by formula (1), (2) or (3) is provided:
wherein in formulae (1) to (3), R represents a hydrocarbon group having 1 to 12 carbon atoms, X and Y each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1, a nitro group, a boronic acid group, —OA1, —SOmA1, —NA1A2, —COOA1 or —CONA1A2, Z represents CW or N, W represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1, a nitro group, a boronic acid group, —OA1, —SOmA1, —NA1A2, —COOA1 or —CONA1A2, n is an integer of 1 to 10 and m is an integer of 0 to 3, and A1 and A2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms.
C07D 417/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 409/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
19.
FLUORINE-CONTAINING PYRAZOLE COMPOUND AND METHOD FOR PRODUCING SAME
A fluorine-containing pyrazole compound is represented by the following general formula (1):
A fluorine-containing pyrazole compound is represented by the following general formula (1):
wherein in formula (1) above, R represents a hydrocarbon group having 1 to 12 carbon atoms, and a ring Z represents an aromatic heterocyclic ring containing at least one heteroatom selected from the group consisting of a nitrogen atom, an oxygen atom, and a sulfur atom.
C07D 417/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
A01P 1/00 - DisinfectantsAntimicrobial compounds or mixtures thereof
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
In the present invention, when converting the phenothiazine carbaldehyde derivative compound or phenothiazine acetyl derivative compound represented by general formula (b) (wherein, R1is a monovalent aliphatic hydrocarbon group having 1-10 carbon atoms, and R2is a hydrogen atom or methyl group) into the phenothiazine derivative compound represented by general formula (I) (wherein, R1and R2 are the same as the above definitions) by a Wittig reaction, the phenothiazine derivative compound (I) is crystallized, by using ethanol, from a reaction mixture containing the phenothiazine derivative compound (I) after the Wittig reaction and triphenylphosphine oxide, thereby isolating the phenothiazine derivative compound.
2323a2b32c3277 or larger perfluoroalkyl group, that lacks the potential to decompose into bioaccumulative and toxic perfluorooctanoic acid, and that has two polymerizable unsaturated bonds in each molecule.
This crosslinkable acrylic rubber composition is obtained by containing: (A) an acrylic elastomer copolymer constituted from a copolymerizable anti-aging agent represented by general formula [I] (R1is a monovalent aliphatic hydrocarbon group having 1-20 carbon atoms, R2 is a hydrogen atom or a methyl group, and A is a direct bond, an oxygen atom or a sulfur atom), an alkyl (meth)acrylate monomer and/or an alkoxyalkyl (meth)acrylate monomer, and an α,β-unsaturated carboxylic acid monomer; (B) a phenothiazine-based anti-aging agent; (C) a polyvalent amine crosslinking agent; and (D) a crosslinking accelerator.
An acrylic elastomer copolymer that is a copolymer of (A) an alkyl (meth)acrylate and/or alkoxyalkyl (meth)acrylate monomer, (B) an α,β-unsaturated carboxylic acid monomer, and (C) a (meth)acrylate monomer having a carbamic acid ester group represented by the general formula:
An acrylic elastomer copolymer that is a copolymer of (A) an alkyl (meth)acrylate and/or alkoxyalkyl (meth)acrylate monomer, (B) an α,β-unsaturated carboxylic acid monomer, and (C) a (meth)acrylate monomer having a carbamic acid ester group represented by the general formula:
An acrylic elastomer copolymer that is a copolymer of (A) an alkyl (meth)acrylate and/or alkoxyalkyl (meth)acrylate monomer, (B) an α,β-unsaturated carboxylic acid monomer, and (C) a (meth)acrylate monomer having a carbamic acid ester group represented by the general formula:
(wherein R1 is a hydrogen atom or a methyl group, and R2 is a divalent aliphatic hydrocarbon group having 1 to 10 carbon atoms). A crosslinkable composition in which a crosslinking accelerator is compounded with the acrylic elastomer copolymer.
A phenothiazine derivative represented by the general formula:
A phenothiazine derivative represented by the general formula:
A phenothiazine derivative represented by the general formula:
(wherein R1 is a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms or an aralkyl group having 7 to 20 carbon atoms, and R2.Ar is an aralkyl group, wherein R2 is a divalent aliphatic hydrocarbon group having 1 to 10 carbon atoms, and Ar is a monovalent aromatic hydrocarbon group having 6 to 10 carbon atoms), and
a carboxyl group-containing acrylic rubber composition comprising, based on 100 parts by weight of carboxyl group-containing acrylic rubber:
(A) 0.1 to 5 parts by weight of the phenothiazine derivative represented by the formula [I];
(B) 0.1 to 3 parts by weight of a crosslinking agent for carboxyl group-containing acrylic rubber; and
(C) 0.1 to 5 parts by weight of a crosslinking accelerator for carboxyl group-containing acrylic rubber.
A fluorine-containing fused ring pyrimidine compound is provided represented by the following formula (1):
A fluorine-containing fused ring pyrimidine compound is provided represented by the following formula (1):
A fluorine-containing fused ring pyrimidine compound is provided represented by the following formula (1):
wherein in the above formula (1): R represents a hydrocarbon group having 1 to 12 carbon atoms; X, Y and Z each independently represent a carbon atom or a nitrogen atom; X and Y optionally form ring Q1 with a carbon atom or a nitrogen atom bonded to each other; Y and Z optionally form ring Q2 with a carbon atom or a nitrogen atom bonded to each other; and ring Q1 and ring Q2 each represent a monocyclic ring or fused ring having 6,10 or 14 π electrons constituting the ring and optionally comprise a heteroatom.
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
An acrylic elastomer copolymer constituted by containing a copolymerizable anti-aging agent represented by general formula (I) (R1: C1-20 aliphatic hydrocarbon group, C7-20 aralkyl group, or C2-20 acyl group, R2: hydrogen atom or methyl group, A: direct bond or divalent organic group, B: direct bond, oxygen atom, sulfur atom, sulfoxide group, or sulfone group, x: 0 or 1), an alkyl (meth)acrylate monomer and/or alkoxyalkyl (meth)acrylate monomer, and a crosslinking site monomer. This acrylic elastomer copolymer is stabilized against thermo-oxidative degradation.
C08L 31/06 - Homopolymers or copolymers of esters of polycarboxylic acids
C09K 15/32 - Anti-oxidant compositionsCompositions inhibiting chemical change containing organic compounds containing boron, silicon, phosphorus, selenium, tellurium or a metal
29.
Ionic liquid including fluorine-containing phosphate ester anions, and lubricating oil composition
Provided are: an ionic liquid including the fluorine-containing phosphate ester anions represented by formula (1); and a lubricating oil composition including said ionic liquid.
1 represents a C1-8 alkyl group.)
m2m+12m+1, a nitro group, -OA1llA1, -SA1, -NA1A2, -B(OA1)(OA2), -COA1, -COOA1, or -CONA1A2, Y represents a halogen atom or -OA3m2m+12m+1, a nitro group, -OA1llA1, -SA1, or -NA1A2, A1and A2each independently represent a hydrogen atom or a C1-10 hydrocarbon group, A3 represents a C1-12 hydrocarbon group, m represents an integer of 1-10, l represents an integer of 1-3, and n represents an integer of 0-3.)
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
Provided are: a novel fluorine-containing pyrazole compound having a halogen atom, an oxygen-containing substituent, or a nitrogen-containing substituent at the 3-position, a trifluoromethyl group at the 4-position, and an oxygen-containing substituent at the 5-position; and a production method by which said fluorine-containing pyrazole compound can be simply produced.Provided are: a novel fluorine-containing pyrazole compound having a halogen atom, an oxygen-containing substituent, or a nitrogen-containing substituent at the 3-position, a trifluoromethyl group at the 4-position, and an oxygen-containing substituent at the 5-position; and a production method by which said fluorine-containing pyrazole compound can be simply produced. The fluorine-containing pyrazole compound is represented by general formula (1). (In general formula (1), R represents a C1-C12 hydrocarbon group, X represents a halogen atom, a heterocyclic group containing, as a ring atom, at least one heteroatom selected from the group consisting of nitrogen and oxygen, -OA1, or -NA1A2, and A1and A2 each independently represent a hydrogen atom or a C1-C10 organic group)
C07D 231/20 - One oxygen atom attached in position 3 or 5
C07D 231/52 - Oxygen atom in position 3 and nitrogen atom in position 5, or vice-versa
C07D 405/12 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 417/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
32.
FLUORINE-CONTAINING PYRIMIDINE COMPOUND, AND METHOD FOR PRODUCING SAME
A fluorine-containing pyrimidine compound represented by the following formula (1) is provided:
A fluorine-containing pyrimidine compound represented by the following formula (1) is provided:
wherein
R represents a hydrocarbon group having 1 to 12 carbon atoms,
B1 represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1, a nitro group, a boronic acid group, —OA1, —SOmA1, —NA1A2, —COOA1 or —CONA1A2,
W, X, Y and Z each independently represent CV or N, provided that at least one of W, X, Y and Z is N,
V represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1, a nitro group, a boronic acid group, —OA1, —SOmA1, —NA1A2, —COOA1 or —CONA1A2,
n is an integer of 1 to 10,
m is an integer of 0 to 3, and
A1 and A2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms.
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
33.
FLUORINE-CONTAINING PYRIMIDINE COMPOUND AND PRODUCTION METHOD THEREFOR
A fluorine-containing pyrimidine compound represented by the following formula (1):
A fluorine-containing pyrimidine compound represented by the following formula (1):
A fluorine-containing pyrimidine compound represented by the following formula (1):
wherein in the general formula (1) above, R represents a hydrocarbon group having 1 to 12 carbon atoms, and a ring Z represents a fused heterocyclic ring containing a heteroatom.
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 417/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 405/04 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
A fluorine-containing alcohol composite comprising a condensate of a fluorine-containing alcohol represented by the general formula: HO-A-RF-A-OH [I] (wherein RF is a group containing a perfluoroalkylene group or a polyfluoroalkylene group having 6 or less carbon atoms and an ether bond, and A is an alkylene group having 1 to 3 carbon atoms), a hydroxyl group-containing polymer, and a zirconium compound. The fluorine-containing alcohol composite, using a fluorine-containing alcohol, does not produce perfluorooctanoic acid and the like when released into the environment and that has a unit easily decomposed into short chain compounds. And also, it exhibits hydrophilic oil repellency.
This fluorine-containing elastomer composition is obtained by blending 0.2-0.9 parts by weight of quinacridone and 0.2-5 parts by weight of a bis-amidoxime compound or 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoro propane, with respect to 100 parts by weight of a fluorine-containing elastomer having a copolymerization compositional makeup comprising (A) 60.0-80.0 mol% of tetrafluoroethylene, (B) 19.8-35.0 mol% of perfluoro(lower alkyl vinyl ether) or perfluoro(lower alkoxy lower alkyl vinyl ether), and (C) 0.2-5.0 mol% of a perfluoro unsaturated nitrile compound. In a case where a cyano group is used as a crosslinkable group in the fluorine-containing elastomer, a vulcanizate of the fluorine-containing elastomer composition exhibits excellent heat resistance even when being placed in a high temperature condition of at least 300℃ and used in a plasma irradiation condition.
A soft water- and oil-repellent comprising, as an active ingredient, a copolymer of a perfluoropolyether alcohol (meth)acrylic acid derivative represented by the general formula:
A soft water- and oil-repellent comprising, as an active ingredient, a copolymer of a perfluoropolyether alcohol (meth)acrylic acid derivative represented by the general formula:
CH2═CR1COOCH2CF(CF3)[OCF2CF(CF3)]nOC3F7 [I]
A soft water- and oil-repellent comprising, as an active ingredient, a copolymer of a perfluoropolyether alcohol (meth)acrylic acid derivative represented by the general formula:
CH2═CR1COOCH2CF(CF3)[OCF2CF(CF3)]nOC3F7 [I]
(wherein R1 is a hydrogen atom or a methyl group, and n is an integer of 1 to 20), and a (meth)acrylic acid ester represented by the general formula:
A soft water- and oil-repellent comprising, as an active ingredient, a copolymer of a perfluoropolyether alcohol (meth)acrylic acid derivative represented by the general formula:
CH2═CR1COOCH2CF(CF3)[OCF2CF(CF3)]nOC3F7 [I]
(wherein R1 is a hydrogen atom or a methyl group, and n is an integer of 1 to 20), and a (meth)acrylic acid ester represented by the general formula:
CH2═CR1COOR2 [II]
A soft water- and oil-repellent comprising, as an active ingredient, a copolymer of a perfluoropolyether alcohol (meth)acrylic acid derivative represented by the general formula:
CH2═CR1COOCH2CF(CF3)[OCF2CF(CF3)]nOC3F7 [I]
(wherein R1 is a hydrogen atom or a methyl group, and n is an integer of 1 to 20), and a (meth)acrylic acid ester represented by the general formula:
CH2═CR1COOR2 [II]
(wherein R1 is a hydrogen atom or a methyl group, and R2 is an alkyl group, an alkoxyalkyl group, a cycloalkyl group, an aryl group, or an aralkyl group) and having a glass transition temperature Tg of 51 to 120° C. The soft water- and oil-repellent gives a coating film formed from a coating agent which closely follows the deformation of rubber or resin, and exhibits water- and oil-repellency.
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
C09D 133/16 - Homopolymers or copolymers of esters containing halogen atoms
Provided is a crosslinkable acrylic rubber composition containing: (A) an acrylic rubber containing a carbamate group and a carboxyl group; (B) a phenothiazine-based antioxidant represented by general formula [I] [where R3represents a hydrogen atom, a monovalent aliphatic hydrocarbon group having 1-20 carbon atoms, an aralkyl group having 7-20 carbon atoms, or an acyl group represented by general formula [II] (where R4represents a monovalent aliphatic hydrocarbon group having 1-20 carbon atoms); and R5 represents an aralkyl group having 7-20 carbon atoms]; and (C) a crosslinking promoter. This crosslinkable acrylic rubber composition is capable of suppressing significant softening degradation of an acrylic rubber crosslinked product, observed in the early stage of thermooxidative degradation thereof, and hardening degradation thereof observed in the late stage of the thermooxidative degradation, thereby minimizing a decrease in the mechanical strength thereof.
n2n+122a22b22c222=CRCOOR1(where R is a hydrogen atom or methyl group, and R12pp(R2qq (where R is a hydrogen atom or methyl group, p and q are each 0 or 1, p+q equals 1, R222=CRCOOR322 (where R is a hydrogen atom or methyl group, and R3 is two C1-30 linear, branched, or cyclic hydrocarbon groups optionally containing oxygen atoms) as copolymer units, the fluorine-containing copolymer being obtained by copolymerizing component (B) in a proportion of 1-50 wt%, component (C) in a proportion of 0.01-5 wt%, and component (D) in a proportion of 0.01-2 wt%. This fluorine-containing copolymer yields a substrate surface modification film having exceptional water and oil repellency, rust prevention properties, etc.
C09D 133/16 - Homopolymers or copolymers of esters containing halogen atoms
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
a fluororubber composition includes (a) a peroxide-crosslinkable fluorine-containing elastomer; (b) a spherical particle of a silica/cured melamine resin composite; (c) carbon black; (d) an organic peroxide as a crosslinking agent; and (e) a co-crosslinking agent.
A fluorine-containing pyrimidine compound is provided represented by formula (1):
A fluorine-containing pyrimidine compound is provided represented by formula (1):
A fluorine-containing pyrimidine compound is provided represented by formula (1):
wherein in the above formula (1), R represents a hydrocarbon group having 1 to 12 carbon atoms, B1 and B2 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1 where n is an integer of 1 to 10, a nitro group, a boronic acid group, —OA1, —SOmA1 where m is an integer of 0 to 3, —NA1A2, —COOA1 or —CONA1A2, W, X, Y and Z each independently represent CV or N, V represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1 where n is an integer of 1 to 10, a nitro group, a boronic acid group, —OA1, —SOmA1 where m is an integer of 0 to 3, —NA1A2, —COOA1 or —CONA1A2, and A1 and A2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms.
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
41.
FLUORINE-CONTAINING PYRAZOLE COMPOUND AND PRODUCTION METHOD THEREFOR
The present invention provides: a novel fluorine-containing pyrazole compound in which a prescribed ring structure that does not have a heteroatom as a ring atom is present at the 1-position, a trifluoromethyl group is present at the 4-position, and prescribed substituent groups are present at the 3-position and the 5-position; and a production method by which the fluorine-containing pyrazole compound can be conveniently produced. The fluorine-containing pyrazole compound is represented by general formula (1). (In general formula (1), R represents a C1-C12 hydrocarbon group, and the ring Z represents a substituted phenyl group or a condensed ring that does not contain a heteroatom as a ring atom.)
An acrylic rubber that is a copolymer in which 1 to 3 wt. % of a fumaric acid monoalkyl ester monomer containing an alkyl group having 1 to 8 carbon atoms is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 12 to 32 wt. % of 2-methoxyethyl acrylate, and 11 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value.
A fluorinated pyrimidine compound represented by general formula (1a) or (1b). (In general formulae (1a) and (1b), R1represents a hydrocarbon group having 1 to 12 carbon atoms; R2n2n+12n+1 (wherein n represents an integer of 1 to 10), a nitro group, a boronic acid group, a cyano group, -OA1lmmA1(wherein l represents an integer of 0 to 1, and m represents an integer of 0 to 3), -NA1A2llCOOA1llCONA1A2(wherein l represents an integer of 0 to 1); A1and A2independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; Aland A2may be bound to each other to form a cyclic structure, in which, when there are a plurality of R2's, they may be the same as or different from each other; and the ring Z represents a 5-membered aromatic heterocyclic ring containing one oxygen atom and one or more nitrogen atoms.)
C07D 413/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
A61K 31/506 - PyrimidinesHydrogenated pyrimidines, e.g. trimethoprim not condensed and containing further heterocyclic rings
44.
ETHYLENE/(METH)ACRYLATE-BASED ELASTOMER AND PRODUCTION METHOD THEREFOR
An ethylene/(meth)acrylate-based elastomer which has a structure obtained by copolymerizing 40-79.9 mol% ethylene, 20.0-50.0 mol% alkyl (meth)acrylate in which the alkyl group has 1-8 carbon atoms and/or alkoxy (meth)acrylate having a C2-C8 alkoxyalkyl group, 0.05-20.0 mol% monosaturated ester of an unsaturated dicarboxylic acid, and 0-20.0 mol% unsaturated dicarboxylic acid anhydride and in which the acid anhydride has a degree of monoesterification with saturated compound, as determined by IR, of 70% or higher. This ethylene/(meth)acrylate-based elastomer gives vulcanized objects excellent in terms of heat resistance and moldability.
An ethylene-(meth)acrylate elastomer having a structure that has been copolymerized at the proportions 40-79.9 mol% of ethylene, 20.0-50.0 mol% of an alkyl(meth)acrylate with a C1-8 alkyl group and/or an alkoxy(meth)acrylate with a C2-8 alkoxyalkyl group, 0.05-20.0 mol% of an unsaturated dicarboxylic acid, and 0.001-20.0 mol% of an unsaturated dicarboxylic acid anhydride, wherein the melt flow rate as measured under a load of 2.16 kg and at a temperature of 190°C is 0.01-100 g/10 minutes. This ethylene-(meth)acrylate elastomer provides a vulcanized product with superior heat resistance, oil resistance, and moldability.
A rubber composition comprising a diurethane compound and a basic vulcanization accelerator that are indicated by general formula R22m2nnOCONH-R12n2mmR2(where R112020 straight chain or branched divalent aliphatic alkylene group, a divalent alicyclic cycloalkylene group, or a divalent aromatic group, R2 is a group that can decompose by the action of a basic vulcanizing agent and generate diamine, when it has a carbamate structure, n is 0, 1, or 2, and m is 0 or 1) contained, as vulcanizing agents, in an ethylene–(meth) acrylate-based copolymer that has been copolymerized at a ratio of 40-79.9 mol% ethylene, 20.00–50.00 mol% alkyl (meth) acrylate having a C1–8 alkyl group and/or an alkoxy alkyl (meth) acrylate having a C2–8 alkoxy alkyl group, and 0.05–20.0 mol% unsaturated dicarboxylic acid anhydride. This rubber composition can provide a vulcanized product having excellent thermal resistance, oil resistance, and moldability.
A phenothiazine derivative represented by the general formula (where, R1is a C1-20 monovalent aliphatic hydrocarbon group or a C7-20 aralkyl group, R2∙Ar is an aralkyl group, R2 thereof is a C1-10 divalent aliphatic hydrocarbon group, and Ar is a C6-10 monovalent aromatic hydrocarbon group) and a carboxyl group-containing acrylic rubber composition containing (A) 0.1-5 weight parts of a phenothiazine derivative represented by formula [I], (B) 0.1-3 weight parts of a crosslinking agent for carboxyl group-containing acrylic rubber, and (C) 0.1-5 weight parts of a crosslinking accelerator for carboxyl group-containing acrylic rubber per 100 weight parts of carboxyl group-containing acrylic rubber.
Provided is an acrylic elastomer copolymer which is a copolymer of: (A) an alkyl(meth)acrylate and/or alkoxyalkyl(meth)acrylate monomer(s), (B) an α,β-unsaturated carboxylic acid monomer, and (C) a (meth)acrylate monomer having a carbamic acid ester group represented by a general formula (where, R1is a hydrogen atom or a methyl group, and R2 is a divalent aliphatic hydrocarbon group having 1-10 carbon atoms). Also provided is a crosslinkable composition in which a crosslink accelerating agent is mixed with said acrylic elastomer copolymer.
wherein Z is [i], [ii], or [iii] below, and n is an integer of 2 to 10,
3 is a hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms, and a is 1 or 2). The carbamate ester compound is used as a vulcanizing agent for carboxyl group-containing acrylic rubber and improves the delay of the vulcanization rate by scorch suppression.
B29C 39/00 - Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressureApparatus therefor
B29C 48/00 - Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired formApparatus therefor
C07C 271/10 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
C07C 271/12 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
C08K 5/205 - Compounds containing groups, e.g. carbamates
A fluorine-containing pyrimidine compound is provided represented by general formula (1), (2), (3), (4), (5), or (6) below.
2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms.
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
56.
FLUORINE-CONTAINING FUSED RING PYRIMIDINE COMPOUND AND METHOD FOR PRODUCING SAME
n2n+12n+1 (n is an integer of 1-10), a nitro group, -OA1mmA1(m is an integer of 1-3), -SA1, -NA1A2, -B(OA1)(OA2), -COA1, -COOA1, or -CONA1A2n2n+12n+1 (n is an integer of 1-10), a cyano group, a nitro group, -OA1mmA1(m is an integer of 1-3), -SA1, -NA1A2, -B(OA1)(OA2), -COA1, -COOA1, or -CONA1A2; Z represents a halogen atom or -OA3; A1and A2each independently represent a hydrogen atom or a hydrocarbon group having 1-10 carbon atoms; and A3 represents a hydrocarbon group having 1-12 carbon atoms.)
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
58.
IONIC LIQUID INCLUDING FLUORINE-CONTAINING PHOSPHATE ESTER ANIONS, AND LUBRICATING OIL COMPOSITION
Provided are: an ionic liquid including the fluorine-containing phosphate ester anions represented by formula (1); and a lubricating oil composition including said ionic liquid. (In the formula, Rf represents a C1-14 perfluoroalkyl group. R1 represents a C1-8 alkyl group.)
C10M 105/70 - Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen as ring hetero atom
C10M 105/74 - Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing phosphorus
The present invention relates to a fluorine-containing pyrimidine compound represented by general formula (1). (In formula (1): R represents a hydrocarbon group having 1-12 carbon atoms; B1n2n+12n+1, a nitro group, a boronic acid group, -OA1mmA1, -NA1A2, -COOA1,or -CONA1A2n2n+12n+1, a nitro group, a boronic acid group, -OA1mmA1, -NA1A2, -COOA1, or -CONA1A2; n is an integer of 1-10; m is an integer of 0-3; and A1and A2 are each independently represent a hydrogen atom or a hydrocarbon group having 1-10 carbon atoms.)
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
A61K 31/506 - PyrimidinesHydrogenated pyrimidines, e.g. trimethoprim not condensed and containing further heterocyclic rings
FFF indicating a C6 or lower perfluoro alkylene group or polyfluoro alkylene group and an ether bond-containing group; A indicating a C1–3 alkylene group), a hydroxyl group-containing polymer, and a zirconium compound. This fluorine-containing alcohol composite: uses a fluorine-containing alcohol that does not generate perfluoro octanoic acid, etc., even when discharged into the environment and has a unit that is readily broken down into a short-chain compound; and exhibits oil repellency.
C08G 77/42 - Block- or graft-polymers containing polysiloxane sequences
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
C08G 79/00 - Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon
61.
Perfluoropolyether phosphate ester, method for producing the same, and surface treatment agent comprising the same as active ingredient
(wherein n is an integer of 1 to 20). Moreover, the perfluoropolyether phosphate ester or a salt thereof forms a surface treatment agent comprising the perfluoropolyether phosphate ester or a salt thereof as an active ingredient.
C08G 65/327 - Polymers modified by chemical after-treatment with inorganic compounds containing phosphorus
B29C 33/60 - Releasing, lubricating or separating agents
C08G 65/00 - Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
C09D 5/00 - Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects producedFilling pastes
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
62.
SOFT WATER- AND OIL-REPELLENT INCLUDING FLUORINE-CONTAINING POLYMER AS ACTIVE INGREDIENT
212323n371212122 is an alkyl group, an alkoxyalkyl group, a cycloalkyl group, an aryl group, or an aralkyl group), and having a glass transition temperature Tg of 51-120 °C. This soft water- and oil-repellent has a film formed from a coating agent and closely following the deformation of a rubber or a resin, and exhibits water- and oil-repellency.
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
Provided are: a novel fluorine-containing pyrimidine compound having a fluorine-containing substituent at position 5, substituents at position 4 and position 6, and a heteroatom-containing fused heterocycle as a substituent at position 2; and a production method capable of easily producing a fluorine-containing pyrimidine compound. A fluorine-containing pyrimidine compound represented by general formula (1). (In general formula (1), R represents a C-12 hydrocarbon group, and the ring Z represents a heteroatom-containing fused heterocycle.)
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 405/04 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 417/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
A fluorine-containing pyrimidine compound represented by general formula (1). (In general formulas (1): R represents a C1-12 hydrocarbon group; B1and B2n2n+12n+1 (where n is an integer from 1 to 10), a nitro group, a boric acid group, -OA1mmA1(where m is an integer from 0 to 3), -NA1A2, -COOA1, or -CONA1A2n2n+12n+1 (where n is an integer from 1 to 10), a nitro group, a boric acid group, -OA1mmA1(wherem m is an integer from 0 to 3), -NA1A2, -COOA1, or -CONA1A2; and A1and A2 each independently represent a hydrogen atom or a C1-10 hydrocarbon group.)
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
65.
Acrylic rubber and crosslinkable composition thereof
An acrylic rubber that is a copolymer in which 1 to 4 wt. % of a reactive halogen group-containing vinyl monomer is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 10 to 35 wt. % of 2-methoxyethyl acrylate and 8 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This ethoxyethoxyethyl acrylate-copolymerized acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value, and by compounding it with a vulcanizing agent corresponding to the crosslinkable group thereof, a crosslinkable composition is formed.
The present invention provides: a novel fluorine-containing pyrazole compound which has a heterocyclic structure at the 1-position, a trifluoromethyl group at the 4-position, and specific substituents at the 3-position and the 5-position; and a production method by which the fluorine-containing pyrazole compound is able to be easily produced. A fluorine-containing pyrazole compound which is represented by general formula (1). (In general formula (1), R represents a hydrocarbon group having from 1 to 12 carbon atoms; and ring Z represents an aromatic heterocyclic ring that contains at least one heteroatom that is selected from the group consisting of a nitrogen atom, an oxygen atom and a sulfur atom.)
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 417/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
67.
FLUORINE-CONTAINING PYRIMIDINE COMPOUND AND MANUFACTURING METHOD FOR SAME
n2n+12n+1 (where n is an integer from 1 to 10), a nitro group, a boric acid group, -OA1mmA1(where m is an integer from 0 to 3), -NA1A2, -COOA1, or -CONA1A2, and A1and A2 each independently represent a hydrogen atom or a hydrocarbon group with 1–10 carbons.)
A61P 1/18 - Drugs for disorders of the alimentary tract or the digestive system for pancreatic disorders, e.g. pancreatic enzymes
A61P 9/10 - Drugs for disorders of the cardiovascular system for treating ischaemic or atherosclerotic diseases, e.g. antianginal drugs, coronary vasodilators, drugs for myocardial infarction, retinopathy, cerebrovascula insufficiency, renal arteriosclerosis
A61P 13/12 - Drugs for disorders of the urinary system of the kidneys
A61P 35/02 - Antineoplastic agents specific for leukemia
A61P 35/04 - Antineoplastic agents specific for metastasis
C07D 405/04 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
A61K 31/506 - PyrimidinesHydrogenated pyrimidines, e.g. trimethoprim not condensed and containing further heterocyclic rings
68.
FLUORINATED PYRIMIDINE COMPOUND AND METHOD FOR MANUFACTURING SAME
n2n+12n+1, a nitro group, a boric acid group, -OA1mmA1, -NA1A2, -COOA1, or -CONA1A2n2n+12n+1, a nitro group, a boric acid group, -OA1mmA1, -NA1A2, -COOA1, or -CONA1A2; n is an integer from 1 to 10; m is an integer from 0 to 3; and A1and A2 each independently represent a hydrogen atom or a C1-10 hydrocarbon group.)
C07D 409/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 417/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
Provided is a non-adhesive composition that exhibits excellent release properties, water repellency and oil repellency. This non-adhesive composition contains a rubber component or a resin and a fluorine-containing copolymer at a quantity of 0.05-10 parts by mass relative to 100 parts by mass of the rubber component or resin. The fluorine-containing copolymer is a copolymer of: a fluoroalkyl alcohol (meth)acrylic acid derivative; and a (meth)acrylic ester, a fumaric acid monoalkyl ester or dialkyl ester, or a maleic acid monoalkyl ester or dialkyl ester.
The present invention relates to a fluororubber composition comprising (a) a fluorine-containing elastomer allowing for peroxide crosslinking, (b) silica composite spherical cured melamine resin particles, (c) carbon black, (d) an organic peroxide crosslinking agent, and (e) a co-crosslinking agent.
This acrylic rubber is a copolymer provided by the copolymerization, as a crosslinkable comonomer, of 1-3 wt% in the copolymer of a monoalkyl fumarate ester monomer having a C1-8 alkyl group, and the copolymerization of n-butyl acrylate, 2-methoxyethyl acrylate, and ethoxyethoxyethyl acrylate in proportions, respectively, of 45-65 wt%, 12-32 wt%, and 11-30 wt%, in 100 wt% for the comonomer other than the crosslinkable comonomer. This acrylic rubber is capable of resisting reductions in oil resistance while providing an improved cold resistance as indicated by the TR-10 value.
An acrylic rubber contains a copolymer of a monomer mixture of: 25 to 46 wt. % of alkoxyalkyl acrylate, 23 to 37 wt. % of 2-ethylhexyl acrylate, 9 to 17 wt. % of alkyl methacrylate, 1 to 3 wt. % of monoalkyl fumarate and the remaining amount is ethyl acrylate. This acrylic rubber improves hydrolysis resistance by introducing a specific alkyl acrylic monomer with extremely low hydrolysis property i.e. low hydrophilicity, and at the same time satisfies all of oil resistance, cold resistance, and hydrolysis resistance in a well-balanced manner.
n2n+12n+1 (n represents an integer of 1-10), a nitro group, a boronic acid group, -OA1mmA1(m represents an integer of 0-3), -NA1A2, -COOA1, or -CONA1A2, and A1and A2 each independently represent a hydrogen atom or a hydrocarbon group having 1-10 carbon atoms.)
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
2nnNHCOO-Z [I] wherein Z is [i], [ii], or [iii] and n is an integer from 2 to 10 (wherein R1and R2are each independently a C1-5 lower alkyl group, R3 is a hydrogen atom or a C1-5 lower alkyl group, and a is 1 or 2). The carbamate ester compound is used as vulcanizing agents for carboxyl group-containing acrylic rubbers and provides improvement of the retardation of the vulcanization rate caused by scorch inhibition.
C07C 271/20 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by nitrogen atoms not being part of nitro or nitroso groups
C07D 207/333 - Radicals substituted by oxygen or sulfur atoms
C08K 5/205 - Compounds containing groups, e.g. carbamates
3732n3223732n323732n3222POCl. This perfluoropolyether phosphate ester or a salt thereof forms a surface treatment agent containing the same as an active ingredient.
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
76.
ACRYLIC RUBBER AND CROSSLINKABLE COMPOSITION THEREOF
An acrylic rubber that is a copolymer obtained by copolymerizing 1-4% by weight of a reactive halogen-group-containing vinyl monomer as a crosslinkable comonomer in the copolymer, wherein n-butyl acrylate in a proportion of 45-65% by weight, 2-methoxyethyl acrylate in a proportion of 10-35% by weight, and ethoxyethoxyethyl acrylate in a proportion of 8-30% by weight are copolymerized in 100% by weight of comonomers other than crosslinkable comonomers. This ethoxyethoxyethyl acrylate copolymer acrylic rubber can suppress a decrease in oil resistance while improving the cold resistance represented by the TR-10 value, and a crosslinkable composition is formed by compounding with a vulcanizing agent that corresponds to the crosslinkable groups in the acrylic rubber.
This acrylic rubber comprises a copolymer obtained from a monomer mixture of 25-46 wt% of an alkoxyalkyl acrylate, 23-37 wt% of 2-ethylhexyl acrylate, 9-17 wt% of an alkyl methacrylate, and 1-3 wt% of a monoalkyl fumarate, the remaining portion being ethyl acrylate. By including a specific alkyl acrylic monomer having very low hydrolysis resistance, i.e., low hydrophilicity, and therefore having improved hydrolysis resistance, this acrylic rubber has satisfactory oil resistance, cold resistance, and hydrolysis resistance, all of which are well balanced.
4COOR. The method is a process for producing the carboxylic acid ester compound, characterized by that any one of an isocyanulate derivative, a phthalic acid derivative and a cycloalkane dialcohol modified (meth)acrylate each having a terminal hydroxyl group is made to react with a perfluoropolyether carboxylic acid halide.
A polyfluoroalkyl phosphoric acid ester represented by the general formula CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cO〕mP(O)(OH)3-m [I] (n: 1-6, a: 1-4, b: 1-3, c: 1-3, m: 1-3) or a salt thereof. A polyfluoroalkyl phosphoric acid ester represented by general formula [I] is produced by subjecting a polyfluoroalkyl alcohol represented by the general formula CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)2OH [II] (n: 1-6, a: 1-4, b: 1-3, c: 1-3) and phosphoric acid to a dehydration-condensation reaction. This polyfluoroalkyl phosphoric acid ester can be synthesized easily without going through a dialkyl ester as in the case of phosphonic acid, and the compound itself or a salt thereof can be used as an active ingredient of a release agent.
C07C 69/14 - Acetic acid esters of monohydroxylic compounds
C07C 17/361 - Preparation of halogenated hydrocarbons by reactions involving a decrease in the number of carbon atoms
C07C 67/293 - Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisationPreparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by change of size of the carbon skeleton
C07C 17/363 - Preparation of halogenated hydrocarbons by reactions involving a decrease in the number of carbon atoms by elimination of carboxyl groups
81.
CARBOXYL-GROUP-CONTAINING ACRYLIC RUBBER COMPOSITION AND RUBBER LAMINATE IN WHICH SAME IS USED
Provided is a carboxyl-group-containing acrylic rubber composition containing (A) a carboxyl-group-containing acrylic rubber, (B) 1,4-diazabicyclo[2.2.2]octane, (D) a crosslinking agent for carboxyl-group-containing acrylic rubber, and (E) a guanidine-, thiuram-, or thiourea-based crosslinking accelerator. The carboxyl-group-containing acrylic rubber composition can crosslink with and adhere to a fluororubber composition and can form an acrylic rubber layer having excellent adhesive strength with the fluororubber layer. The interlayer adhesion can also be increased by also adding (C) a primary amine represented by the general formula RNH2 (where R is a C1-30 aliphatic hydrocarbon group) to the carboxyl-group-containing acrylic rubber composition.
A fluorocopolymer which comprises comonomer units derived from (A) a polyfluoroalkyl alcohol/(meth)acrylic acid derivative represented by the general formula CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR=CH2 [I] (R is a hydrogen atom or methyl group, n is 1-6, a is 1-4, b is 1-3, and c is 1-3), (B) a non-fluorinated (meth)acrylic ester represented by the general formula CH2=CRCOOR3 [III] (R is a hydrogen atom or methyl group and R3 is a linear, branched, or cyclic C1-30 hydrocarbon group optionally containing an oxygen atom), and (C) a functional-group-containing (meth)acrylic acid represented by the general formula CH2=CRCOO(H)p(R4Y)q [IV] (R is a hydrogen atom or methyl group; p and q are each 0 or 1, p+q being 1; R4 is a linear, branched, or cyclic C1-30 hydrocarbon group optionally containing an oxygen atom; and Y is a phosphate group or epoxy group) or an ester thereof, the ingredient (C) having been copolymerized in a proportion of 0.01-5 wt% of the whole copolymer.
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
wherein k is 1 or 2; when k is 1, Rf is a perfluoroalkyl group having 6 or less carbon atoms, a polyfluoroalkyl group in which some of the fluorine atom or atoms of the perfluoroalkyl group are replaced by hydrogen atom or atoms, a polyfluoroalkyl group containing a terminal perfluoroalkyl group having 6 or less carbon atoms and a perfluoroalkylene group having 6 or less carbon atoms, or a linear or branched, perfluoroalkyl group containing a terminal perfluoroalkyl group having 6 or less carbon atoms, a perfluoroalkylene group having 6 or less carbon atoms and ether bonds; when k is 2, Rf is a linear or branched, perfluoroalkylene group or polyfluoroalkylene group, containing a perfluoroalkylene group having 6 or less carbon atoms and ether bonds; and A is an alkylene group having 1 to 6 carbon atoms.
2: an alkyl group having 1 to 10 carbon atoms, d: 1 to 3, e: 1 to 3). The surface-modifying agent comprising this fluorine-containing copolymer as an active ingredient have an excellent dynamic slip angle after washing with hexadecane, and anti-corrosive properties.
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
C09D 133/16 - Homopolymers or copolymers of esters containing halogen atoms
C09D 143/04 - Homopolymers or copolymers of monomers containing silicon
C08F 230/08 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
85.
Fluorine-containing ether monocarboxylic acid aminoalkyl ester and a method for producing the same
C07C 219/06 - Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having the hydroxy groups esterified by carboxylic acids having the esterifying carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms of an acyclic saturated carbon skeleton
C07C 213/06 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton from hydroxy amines by reactions involving the etherification or esterification of hydroxy groups
C07C 213/10 - SeparationPurificationStabilisationUse of additives
86.
Fluorine-containing alkylsilane compound, and method for producing the same
a chlorosilane, followed by a reaction with lower alcohol or metal alkenyl. The production method gives a fluorine-containing alkylsilane compound that can remove free iodine derived from the raw material compound, before a hydrosilylation reaction is performed, without using a metal reagent having a high environmental load, and that also has excellent handling properties.
C07F 7/08 - Compounds having one or more C—Si linkages
C07F 7/18 - Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
C08G 65/00 - Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
C03C 17/30 - Surface treatment of glass, e.g. of devitrified glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
C09D 183/08 - Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
C08G 77/24 - Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen halogen-containing groups
to a dehydrofluorination reaction in the presence of a nitrogen-containing heterocyclic compound catalyst, and has a lower critical micelle concentration and less surface tension at that time, therefore, the mixture of polyfluoroalkene carboxylic acids or salts thereof can be effectively used as a surfactant in the polymerization of fluorine-containing monomers.
C07C 51/377 - Preparation of carboxylic acids or their salts, halides, or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groupsPreparation of carboxylic acids or their salts, halides, or anhydrides by reactions not involving formation of carboxyl groups by hydrogenolysis of functional groups
C07C 57/52 - Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen
88.
CARBOXYLIC ACID ESTER COMPOUND HAVING POLYMERIZABLE FUNCTIONAL GROUP AND FLUORINE ATOM GROUP, AND METHOD FOR PRODUCING SAME
Provided are a fluorine-containing monomer having excellent water repellency and oil repellency that can be dissolved in common organic solvents such as hydrocarbon solvents, and a method for producing the same. A carboxylic acid ester compound having a polymerizable functional group and a fluorine atom group represented by the following general formula. CaF2a+1O-(CbF2bO)c-C2F4COOR Also, a method for producing the carboxylic acid ester compound characterized by reacting any one of an isocyanurate derivative having an end hydroxyl group, a phthalic acid derivative, and a cycloalkane dialcohol-modified (meth)acrylate, with a perfluoropolyether carboxylic acid halide.
F is a perfluoroalkyl group having 6 or less carbon atoms, or a polyfluoroalkyl group, in which some of the fluorine atom or atoms of the perfluoroalkyl group are replaced by a hydrogen atom or hydrogen atoms, and which contains a terminal perfluoroalkyl group having 6 or less carbon atoms and a perfluoroalkylene group having 6 or less carbon atoms; and A is an alkylene group having 1 to 6 carbon atoms, or comprising a resin, and a condensate of boric acid, the said fluorine-containing alcohol and an alkoxysilane at a molar ratio of 1.0 or less based on the fluorine-containing alcohol. These composite materials of resin—fluorine-containing boric acid composite particles has good adhesion to inorganic substrates, and the like.
C08L 53/00 - Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bondsCompositions of derivatives of such polymers
C08L 33/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
wherein R is an alkyl group having 1 to 12 carbon atoms, a is an integer of 1 to 6, and b+c is an integer of 0 to 6; to hydrolysis or solvolysis in the presence of an alkali metal hydroxide.
Provided is a fluorine-containing diblock copolymer having good water and oil repellency by using, as a raw material, a fluorine-containing (meth)acrylic ester having low bioaccumulation potential. The fluorine-containing diblock copolymer is produced by: process (A) a process for producing a fluorine-containing diblock copolymer by polymerizing a fluorine-containing (meth)acrylic ester represented by the following formula (1) in the presence of a trithiocarbonic ester compound and a radical polymerization initiator and then polymerizing a non-fluorine vinyl-based monomer, or process (B) a process for producing a fluorine-containing diblock copolymer by polymerizing a non-fluorine vinyl-based monomer in the presence of a trithiocarbonic ester compound and a radical polymerization initiator and then polymerizing a fluorine-containing (meth)acrylic ester represented by the following formula (1).
C08F 293/00 - Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
A fluorine-containing boric acid/polyvinyl butyral (PVB) composite which comprises a product of condensation of a fluorine-containing alcohol, boric acid, and PVB, the fluorine-containing alcohol being represented by the general formula Rf(A-OH)k (wherein k is 1 or 2; when k is 1, then Rf is a polyfluoroalkyl group configured so as to include a C6 or lower perfluoroalkyl group, a polyfluoroalkyl group obtained by replacing some of the fluorine atoms of the perfluoroalkyl group with hydrogen atoms, a C6 or lower terminal-perfluorinated alkyl group, and a C6 or lower perfluoroalkylene group or is a linear or branched perfluoroalkyl group including a C6 or lower terminal-perfluorinated alkyl group, a C6 or lower perfluoroalkylene group, and an ether bond, and when k is 2, then Rf is a linear or branched perfluoroalkylene group or polyfluoroalkylene group which includes a C6 or lower perfluoroalkylene group and an ether bond; and A is a C1-6 alkylene group).
C08L 29/14 - Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
95.
FLUORINATED COPOLYMER, AND SURFACE MODIFIER CONTAINING SAME AS ACTIVE INGREDIENT
A fluorinated copolymer which is a copolymer of a polyfluoroalkyl alcohol (meth)acrylate represented by general formula [I]: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR=CH2 (wherein R: a hydrogen atom or a methyl group; n: 1 to 6; a: 1 to 4; b: 1 to 3; c: 1 to 3), benzyl (meth)acrylate or styrene, and an Si group-containing crosslinkable (meth)acrylate represented by general formula [II]: CH2=CRCOO(CH2)dSi(OR1)eR23-e (wherein R: a hydrogen atom or a methyl group; R1 and R2: independently an alkyl group having 1 to 10 carbon atoms; d: 1 to 3; e: 1 to 3). A surface modifier containing the fluorinated copolymer as an active ingredient can exhibit an excellent dynamic sliding angle and excellent anti-corrosive properties after washing with hexadecane.
C09K 3/18 - Materials not provided for elsewhere for application to surface to minimize adherence of ice, mist or water theretoThawing or antifreeze materials for application to surfaces
96.
FLUORINE-CONTAINING ETHER MONOCARBOXYLIC ACID AMINOALKYL ESTER AND MANUFACTURING METHOD THEREFOR
A fluorine-containing ether monocarboxylic acid aminoalkyl ester represented by the general formula CnF2n+1O[CF(CF3)CF2O]aCF(CF3)COO(CH2)bNR1R2 (here, R1 is a hydrogen atom or C1 to C12 alkyl group, aryl group or aralkyl group, preferably a C1 to C6 alkyl group or aryl group, R2 is a C1 to C12 alkyl group, aryl group or aralkyl group, preferably a C1 to C6 alkyl group or aryl group, n is an integer 1-3, a is an integer 2-20, preferably an integer 4-10, and b is an integer 1-12, preferably an integer 1-3). Said fluorine-containing ether monocarboxylic acid ester, which has an amino group on the ester group end, is manufactured by reacting a perfluoroether carboxylic acid fluoride compound CnF2n+1O[CF(CF3)CF2O]aCF(CF3)COF with a hydroxyalkyl amine compound HO(CH2)bNR1R2 in the presence of an alkali metal fluoride.
C07C 219/06 - Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having the hydroxy groups esterified by carboxylic acids having the esterifying carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms of an acyclic saturated carbon skeleton
C07C 213/06 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton from hydroxy amines by reactions involving the etherification or esterification of hydroxy groups
C07C 213/10 - SeparationPurificationStabilisationUse of additives
97.
Bis(perfluoroether carboxylic acid alkyl)amino ester and method for producing the same
C07C 219/06 - Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having the hydroxy groups esterified by carboxylic acids having the esterifying carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms of an acyclic saturated carbon skeleton
C07C 213/06 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton from hydroxy amines by reactions involving the etherification or esterification of hydroxy groups
98.
Aqueous dispersion of fluorine-containing copolymer
2, (C) benzyl(meth)acrylate, (D) a fluorine-free polymerizable monomer other than components (A) and (C), and (E) a crosslinkable group-containing polymerizable monomer. The aqueous dispersion can improve the dispersion stability of an aqueous dispersion of a water- and oil-repellent when used as a water- and oil-repellent comprising the fluorine-containing copolymer as an active component.
d. The method for manufacturing the carboxylic acid ester/carbamate compound is comprised of the steps of making an isocyanate compound having a polymerizable functional group react with an alcohol such as a polyalkylene glycol, a cycloalkane dimethanol, or a polyhydric alcohol to produce a hydroxycarbamate, and subsequently making the resulting hydroxycarbamate react with a perfluoropolyether carboxylic acid halide.
C07C 271/16 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
C07C 269/02 - Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups the nitrogen atom not being part of nitro or nitroso groups from isocyanates with formation of carbamate groups
C07C 269/06 - Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups the nitrogen atom not being part of nitro or nitroso groups by reactions not involving the formation of carbamate groups
