Disclosed are methods and systems for removing reactive carbonyl monomers which can polymerize to produce red oil. In an embodiment the method may include cracking a hydrocarbon stream in a fluidized catalytic cracker to produce a cracked hydrocarbon stream comprising carbonyl compounds; separating hydrocarbon components from the cracked hydrocarbon stream in a debutanizer column to form a debutanizer overhead LPG stream comprising the carbonyl compounds; introducing the debutanizer LPG overhead stream into a carbonyl removal unit comprising a metal bisulfite bed; reacting the carbonyl compounds in the debutanizer overhead LPG stream to form a carbonyl adduct with the metal bisulfite; and withdrawing a first LPG product stream from the carbonyl removal unit.
C10G 61/06 - Treatment of naphtha by at least one reforming process and at least one process of refining in the absence of hydrogen plural serial stages only the refining step being a sorption process
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
A method may include: introducing triglycerides, hydrogen, and a sulfiding agent into a hydroprocessing reactor; reacting the triglycerides with the hydrogen in the hydroprocessing reactor to form at least paraffins; separating at least a portion of a hydroprocessing reactor effluent from the hydroprocessing reactor in a first phase separator to produce a first sour water stream comprising water and a first quantity of hydrogen sulfide and a paraffin stream comprising at least a portion of the paraffins; introducing the first sour water stream into a sour water stripper and stripping the first sour water stream to form a gaseous stream comprising at least a portion of the first quantity of the hydrogen sulfide from the first sour water stream; and contacting the gaseous stream with an acidified wash water in an ammonia removal unit to produce an aqueous ammonia solution stream and a treated gaseous hydrogen sulfide stream; and introducing the treated hydrogen sulfide stream into the hydroprocessing reactor. The aqueous ammonia solution stream is neutralized with an acid to form an ammonium salt solution product.
C10G 67/14 - Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including at least two different refining steps in the absence of hydrogen
C02F 1/20 - Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
C02F 1/469 - Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
C02F 103/36 - Nature of the water, waste water, sewage or sludge to be treated from the chemical industry not provided for in groups from the manufacture of organic compounds
A method may comprise: feeding a backend deethanizer overhead stream comprising ethylene, ethane, and acetylene to a hydrogenation reactor; hydrogenating at least a portion of the acetylene in the backend deethanizer overhead stream to form a reactor effluent stream comprising ethylene, ethane, and green oil; feeding the reactor effluent stream to a gas/liquid coalescer; and removing at least a portion of the green oil from the reactor effluent stream to produce a cleaned effluent stream.
C07C 7/04 - Purification, separation or stabilisation of hydrocarbonsUse of additives by distillation
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C07C 7/167 - Purification, separation or stabilisation of hydrocarbonsUse of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation for removal of compounds containing a triple carbon-to-carbon bond
C07C 7/11 - Purification, separation or stabilisation of hydrocarbonsUse of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
C10G 45/32 - Selective hydrogenation of the diolefin or acetylene compounds
C10G 69/06 - Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
C10G 9/36 - Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
4.
Dissolved oil removal from quench water of gas cracker ethylene plants
A method for removing dissolved hydrocarbons from water may comprise: cracking a mixed hydrocarbon stream in a cracking furnace to produce a cracked gas effluent; quenching the cracked gas effluent in a quench water tower with quench water to produce a quenched gas stream and a spent quench water stream comprising water, tars, heavy aromatic hydrocarbons, gasoline, dissolved oil, and dispersed oil; feeding the spent quench water stream to a liquid-liquid extraction unit wherein the liquid-liquid extraction unit removes at least a portion of the dissolved oil and produce an extracted effluent stream.
Disclosed are methods and systems for removing a highly reactive polymer precursor such as acetaldehyde and acetone from a hydrocarbon gas stream. Embodiments may disclose a method for removal of carbonyls comprising providing a hydrocarbon gas stream comprising a carbonyl, providing a liquid bisulfite stream, and contacting the hydrocarbon gas stream and liquid bisulfite stream in a mass transfer device wherein at least a portion of the carbonyl reacts with the bisulfite to form a solid adduct that is soluble in the liquid bisulfite stream.
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C07C 7/148 - Purification, separation or stabilisation of hydrocarbonsUse of additives by treatment giving rise to a chemical modification of at least one compound
Disclosed are methods and systems for removing a highly reactive polymer precursor such as carbonyls from a liquid hydrocarbon stream. Embodiments may disclose a method for removal of carbonyls from a liquid hydrocarbon stream comprising the steps of providing a liquid hydrocarbon stream containing carbonyls, providing a liquid bisulfite stream comprising an alkali metal bisulfite, and contacting the liquid hydrocarbon stream and the liquid bisulfite stream in a mass transfer device wherein at least a portion of the carbonyl reacts with the alkali metal bisulfite to form a solid adduct that is soluble in the bisulfite solution.
C07C 7/152 - Purification, separation or stabilisation of hydrocarbonsUse of additives by treatment giving rise to a chemical modification of at least one compound by forming adducts or complexes
C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
C10G 19/02 - Refining hydrocarbon oils, in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
C10G 53/12 - Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one alkaline-treatment step
C10L 3/06 - Natural gasSynthetic natural gas obtained by processes not covered by , or
C10G 19/00 - Refining hydrocarbon oils, in the absence of hydrogen, by alkaline treatment
7.
Removal of carbonyls from gaseous hydrocarbon streams
Disclosed are methods and systems for removing a highly reactive polymer precursor such as acetaldehyde and acetone from a hydrocarbon gas stream. Embodiments may disclose a method for removal of carbonyls comprising providing a hydrocarbon gas stream comprising a carbonyl, providing a liquid bisulfite stream, and contacting the hydrocarbon gas stream and liquid bisulfite stream in a mass transfer device wherein at least a portion of the carbonyl reacts with the bisulfite to form a solid adduct that is soluble in the liquid bisulfite stream.
C07C 7/148 - Purification, separation or stabilisation of hydrocarbonsUse of additives by treatment giving rise to a chemical modification of at least one compound
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
patents