Filtration apparatus including Graphene Oxide (GO) membranes are described herein. The GO membranes exhibit durability under harsh operation conditions including elevated temperatures, high pressure, and/or non-neutral pH. The filtration apparatus can include a GO membrane and a functionalized support including surface functional groups grafted to the functionalized support via a free radical co-polymerization approach. The filtration apparatus can exhibit improved performance (e.g., high rejection) in applications such as pulp and paper processing, which facilitates achieving permeate quality targets. The filtration apparatus described herein can also offer a more stable replacement for reverse osmosis membranes which are known to degrade under strongly alkaline conditions and high temperatures.
A system for processing a feed includes a membrane system configured to receive the feed and produce a concentrate and a permeate, wherein the membrane system includes an active cooling system, a passive cooling system, or a combination thereof. Further, the system includes a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system, such that the feed enters the heat exchanger prior to entering the membrane system, wherein the heat exchanger is configured to cool the feed and heat the concentrate by transferring heat from the feed to the concentrate.
Embodiments described herein relate generally to systems, apparatus, and methods for using graphene oxide-containing membranes for separation and concentration processes. In some embodiments, a fluid component having a first concentration in a fluid mixture can be concentrated using a first distillation process to a second concentration. In some embodiments, the fluid component can be concentrated from the second concentration to a third concentration using a graphene oxide-containing membrane. In some embodiments, the fluid component can be concentrated from the third concentration to a fourth concentration using a second distillation process. In some embodiments, the fluid component can have an azeotropic concentration between the second concentration and the third concentration.
Filtration apparatus comprising Graphene Oxide (GO) membranes modified by incorporation of polymeric components are described herein. The GO membranes include graphene oxide sheets covalently coupled to one or more polymeric components. Incorporation of polymeric components may increase d-spacing of the graphene oxide sheets resulting in improved filtration apparatus performance with respect to prior art membranes (e.g., high flux and rejection rate). In some embodiments the polymeric components may comprise branched polymers with primary amine functionalities which can act as efficient handles for covalent attachment to graphene oxide, resulting in the formation of new, robust amide bonds. The filtration apparatus described herein can exhibit improved performance in applications such as pulp and paper processing, which facilitates achieving permeate quality targets.
Filtration apparatus including Graphene Oxide (GO) are described herein. The GO membranes include a plurality of graphene oxide sheets, each of the graphene oxide sheets covalently bound to a chemical spacer. The filtration apparatus can include a GO membrane and a sulfonated polyethersulfone (S-PES). The filtration apparatus can exhibit improved performance with respect to prior art membranes (e.g., high flux and rejection rate) in applications such as pulp and paper processing, which facilitates achieving permeate quality targets. The filtration apparatus described herein can also offer a more stable replacement for reverse osmosis membranes which are known to degrade under strongly alkaline conditions and high temperatures.
B01D 67/00 - Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
Systems and methods for concentrating black liquor solutions using pressure driven filtration processes are disclosed herein. The systems and methods described herein integrate multiple unit operations with graphene oxide membranes filtration devices to accomplish concentration of black liquor streams. These systems and methods provide a lower energy, more economical solution than the currently deployed technology of thermal evaporation.
C02F 1/44 - Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
C02F 103/28 - Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof from the paper or cellulose industry
A system for processing a feed includes a membrane system configured to receive the feed and produce a concentrate and a permeate, wherein the membrane system includes an active cooling system, a passive cooling system, or a combination thereof. Further, the system includes a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system, such that the feed enters the heat exchanger prior to entering the membrane system, wherein the heat exchanger is configured to cool the feed and heat the concentrate by transferring heat from the feed to the concentrate.
Filtration apparatus including Graphene Oxide (GO) membranes are described herein. The GO membranes exhibit durability under harsh operation conditions including elevated temperatures, high pressure, and/or non-neutral pH. The filtration apparatus can include a GO membrane and a functionalized support including surface functional groups grafted to the functionalized support via a free radical co-polymerization approach. The filtration apparatus can exhibit improved performance (e.g., high rejection) in applications such as pulp and paper processing, which facilitates achieving permeate quality targets. The filtration apparatus described herein can also offer a more stable replacement for reverse osmosis membranes which are known to degrade under strongly alkaline conditions and high temperatures.
B01D 71/82 - Macromolecular material not specifically provided for in a single one of groups characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
A system for processing a feed includes a membrane system configured to receive the feed and produce a concentrate and a permeate, wherein the membrane system includes an active cooling system, a passive cooling system, or a combination thereof. Further, the system includes a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system, such that the feed enters the heat exchanger prior to entering the membrane system, wherein the heat exchanger is configured to cool the feed and heat the concentrate by transferring heat from the feed to the concentrate.
The present disclosure relates to an alkylated graphene oxide membrane comprising a plurality of graphene oxide layers, each graphene oxide layer including at least one graphene oxide sheet covalently coupled to a chemical spacer, the chemical spacer being of Formula I:
The present disclosure relates to an alkylated graphene oxide membrane comprising a plurality of graphene oxide layers, each graphene oxide layer including at least one graphene oxide sheet covalently coupled to a chemical spacer, the chemical spacer being of Formula I:
The present disclosure relates to an alkylated graphene oxide membrane comprising a plurality of graphene oxide layers, each graphene oxide layer including at least one graphene oxide sheet covalently coupled to a chemical spacer, the chemical spacer being of Formula I:
The present disclosure also relates to a filtration apparatus comprising an alkylated graphene oxide membrane disposed on a support substrate.
B01J 20/20 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbonSolid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising carbon obtained by carbonising processes
B01J 20/28 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof characterised by their form or physical properties
B01J 20/30 - Processes for preparing, regenerating or reactivating
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
B01D 67/00 - Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
11.
APPARATUS FOR CHARACTERIZATION OF GRAPHENE OXIDE COATINGS
An apparatus for measuring the thickness of graphene oxide coatings deposited on a support substrate are described. The apparatus includes a light source and a photodetector which can be placed directly into a coating line to provide continuous feedback on the thickness of a fabricated graphene oxide coating, enabling fabrication of controlled thickness coatings and real-time quality monitoring.
An apparatus for measuring the thickness of graphene oxide coatings deposited on a support substrate are described. The apparatus includes a light source and a photodetector which can be placed directly into a coating line to provide continuous feedback on the thickness of a fabricated graphene oxide coating, enabling fabrication of controlled thickness coatings and real-time quality monitoring.
Embodiments described herein relate generally to durable graphene oxide membranes for fluid filtration. For example, the graphene oxide membranes can be durable under high temperatures non-neutral pH, and/or high pressures. One aspect of the present disclosure relates to a filtration apparatus comprising: a support substrate, and a graphene oxide membrane disposed on the support substrate. The graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt % lactose solution at room temperature. The graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt % lactose solution at room temperature after the graphene oxide membrane is contacted with a solution that is at least 80° C. for a period of time.
A system for processing a feed includes a membrane system configured to receive the feed and produce a concentrate and a permeate, wherein the membrane system includes an active cooling system, a passive cooling system, or a combination thereof. Further, the system includes a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system, such that the feed enters the heat exchanger prior to entering the membrane system, wherein the heat exchanger is configured to cool the feed and heat the concentrate by transferring heat from the feed to the concentrate.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 61/00 - Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltrationApparatus, accessories or auxiliary operations specially adapted therefor
C02F 1/44 - Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
15.
HEAT EXCHANGER INTEGRATION WITH MEMBRANE SYSTEM FOR EVAPORATOR PRE-CONCENTRATION
A system for processing a feed includes a membrane system configured to receive the feed and produce a concentrate and a permeate, wherein the membrane system includes an active cooling system, a passive cooling system, or a combination thereof. Further, the system includes a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system, such that the feed enters the heat exchanger prior to entering the membrane system, wherein the heat exchanger is configured to cool the feed and heat the concentrate by transferring heat from the feed to the concentrate.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 61/00 - Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltrationApparatus, accessories or auxiliary operations specially adapted therefor
C02F 1/44 - Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
The present disclosure relates to an alkylated graphene oxide membrane comprising a plurality of graphene oxide layers, each graphene oxide layer including at least one graphene oxide sheet covalently coupled to a chemical spacer, the chemical spacer being of Formula I. The present disclosure also relates to a filtration apparatus comprising an alkylated graphene oxide membrane disposed on a support substrate.
Embodiments described herein relate generally to graphene oxide membranes for fluid filtration and more specifically to graphene oxide membranes having tunable permeability, rejection rate, and flux. Some embodiments of the graphene oxide membranes disclosed herein are characterized as having a flux of at least about 2.5×10−4 gallons per square foot per day per psi with a 1 wt % lactose solution at room temperature, and a lactose rejection rate of at least 50% with a 1 wt % lactose solution.
Embodiments described herein relate generally to durable graphene oxide membranes for fluid filtration. For example, the graphene oxide membranes can be durable under high temperatures non-neutral pH, and/or high pressures. One aspect of the present disclosure relates to a filtration apparatus comprising: a support substrate, and a graphene oxide membrane disposed on the support substrate. The graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt % lactose solution at room temperature. The graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt % lactose solution at room temperature after the graphene oxide membrane is contacted with a solution that is at least 80° C. for a period of time.
Embodiments described herein relate generally to durable graphene oxide membranes for fluid filtration. For example, the graphene oxide membranes can be durable under high temperatures non-neutral pH, and/or high pressures. One aspect of the present disclosure relates to a filtration apparatus comprising: a support substrate, and a graphene oxide membrane disposed on the support substrate. The graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt% lactose solution at room temperature. The graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt% lactose solution at room temperature after the graphene oxide membrane is contacted with a solution that is at least 80 °C for a period of time.
Embodiments described herein relate generally to graphene oxide membranes for fluid filtration and more specifically to graphene oxide membranes having tunable permeability, rejection rate, and flux. Some embodiments of the graphene oxide membranes disclosed herein are characterized as having a flux of at least about 2.5x10-4 gallons per square foot per day per psi with a 1 wt% lactose solution at room temperature, and a lactose rejection rate of at least 50% with a 1 wt% lactose solution.
−4 gallons per square foot per day per psi with a 1 wt % lactose solution at room temperature, and a lactose rejection rate of at least 50% with a 1 wt % lactose solution.
Embodiments described herein relate generally to durable graphene oxide membranes for fluid filtration. For example, the graphene oxide membranes can be durable under high temperatures non-neutral pH, and/or high pressures. One aspect of the present disclosure relates to a filtration apparatus comprising: a support substrate, and a graphene oxide membrane disposed on the support substrate. The graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt % lactose solution at room temperature. The graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt % lactose solution at room temperature after the graphene oxide membrane is contacted with a solution that is at least 80° C. for a period of time.
Embodiments described herein relate generally to graphene oxide membranes for fluid filtration and more specifically to graphene oxide membranes having tunable permeability, rejection rate, and flux. Some embodiments of the graphene oxide membranes disclosed herein are characterized as having a flux of at least about 2.5x10-4 gallons per square foot per day per psi with a 1 wt% lactose solution at room temperature, and a lactose rejection rate of at least 50% with a 1 wt% lactose solution.
Embodiments described herein relate generally to durable graphene oxide membranes for fluid filtration. For example, the graphene oxide membranes can be durable under high temperatures non-neutral pH, and/or high pressures. One aspect of the present disclosure relates to a filtration apparatus comprising: a support substrate, and a graphene oxide membrane disposed on the support substrate. The graphene oxide membrane has a first lactose rejection rate of at least 50% with a first 1 wt% lactose solution at room temperature. The graphene oxide membrane has a second lactose rejection rate of at least 50% with a second 1 wt% lactose solution at room temperature after the graphene oxide membrane is contacted with a solution that is at least 80 °C for a period of time.
Embodiments described herein relate generally to systems, apparatus, and methods for using graphene oxide-containing membranes for separation and concentration processes. In some embodiments, a fluid component having a first concentration in a fluid mixture can be concentrated using a first distillation process to a second concentration. In some embodiments, the fluid component can be concentrated from the second concentration to a third concentration using a graphene oxide-containing membrane. In some embodiments, the fluid component can be concentrated from the third concentration to a fourth concentration using a second distillation process. In some embodiments, the fluid component can have an azeotropic concentration between the second concentration and the third concentration.
Embodiments described herein relate generally to systems, apparatus, and methods for using graphene oxide-containing membranes for separation and concentration processes. In some embodiments, a fluid component having a first concentration in a fluid mixture can be concentrated using a first distillation process to a second concentration. In some embodiments, the fluid component can be concentrated from the second concentration to a third concentration using a graphene oxide-containing membrane. In some embodiments, the fluid component can be concentrated from the third concentration to a fourth concentration using a second distillation process. In some embodiments, the fluid component can have an azeotropic concentration between the second concentration and the third concentration.
