The problems or issues faced by typical larger SSE batteries are solved by providing an interface or interfacial layer at least between the anode, which comprises Li or Na, and the solid state electrolyte (SSE). In some other embodiments, an interfacial layer may be provided between the anode, which comprises Li or Na, and the SSE, and an interface or interfacial layer may also be provided between the cathode and the SSE. In at least selected embodiments, aspects or objects, the interfacial layer may act as a shock absorber between a SSE (e.g., a sulfide glass SSE) and an anode material that is soft compared to the SSE (e.g., Li metal). In other embodiments, the interfacial layer may act as a shock absorber between the SSE and a cathode material that is softer than the SSE. In at least certain embodiments, the interfacial layer may improve ionic conductance between the anode and the SSE and/or the SSE and the cathode. In at least certain selected embodiments, the interfacial layer may prevent or deter lithium deposition and dendrite growth at the interface between the anode and the SSE. Interface defects at the interface between the anode and the SSE may allow lithium deposition and dendrite growth. The dendrites may continue to grow through cracks in the SSE causing a short, which is a safety issue. The inventive interfacial layer between the anode and the SSE may prevent or deter this. In at least some embodiments, the interfacial layer may be a porous polymer layer filled with liquid electrolyte and may improve ionic conductance between the anode and the SSE and/or the SSE and the cathode. In certain embodiments, the anode interface or interfacial layer may be a porous polymer layer filled with liquid electrolyte. In some embodiments, the cathode interface or interfacial layer may be a porous polymer layer filled with liquid, gel or polymer electrolyte.
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
Disclosed herein are battery separators that include a microporous membrane and a coating. The coating may comprise, consist, or consist essentially of polymeric components, inorganic components, or combinations thereof. The battery separators described herein are, among other things, thinner, stronger, and more wettable with electrolyte than some prior battery separators. The battery separators may be used in secondary or rechargeable batteries, including lithium ion batteries. The batteries may be used in vehicles or devices such as cell phones, tablets, laptops, and e-vehicles.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
A composite for forming an improved semi-solid state electrolyte. The composite has a layer formed including lithium metaphosphate (LiPOs). The layer may include a mixture of LiPOs and PEO. The composite may be wet with liquid electrolyte to form the semi-solid state electrolyte. When used in a semi-solid state battery, the semi-solid state electrolyte provides beneficial results, including improved cycle life and less lithium dendrite growth. Another composite for forming an improved semi-solid state electrolyte has a layer formed including LiTaOs and LiNbOs. Yet another composite has a single layer formed to include a mixture of a polyethylene oxide and a lithium-containing salt, including a lithium salt including niobium, tantalum, or mixtures thereof. Such composites may be wet with liquid electrolyte to form the semi-solid state electrolyte. When used in a semi-solid state battery, the semi-solid state electrolyte provides beneficial results, including improved cycle life and less lithium dendrite growth.
Described are dry process microporous membranes for filtration, wherein at least one layer of the membrane has an average pore size less than 0.035 microns. The membrane may be used in an ultra-filtration or nano-filtration process such as for processing microelectronics or semiconductor processing fluids.
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
5.
SEPARATORS FOR HIGH VOLTAGE RECHARGEABLE LITHIUM BATTERIES AND RELATED METHODS
In accordance with at least selected embodiments, the present disclosure or invention is directed to improved or novel separators, cells, batteries, and/or methods of manufacture and/or use. In accordance with at least certain embodiments, the present disclosure or invention is directed to improved or novel separators such as a separator for a high energy and/or high voltage lithium ion battery which is stable up to a 4.5 volt, or preferably up to a 5.0 volt or higher charging voltage, such as a novel or improved single or multilayer or multiply microporous separator membrane. In accordance with at least selected embodiments, the present application or invention is directed to novel or improved porous membranes or substrates, separator membranes, separators, composites, electrochemical devices, batteries, cells, methods of making such membranes or substrates, separators, cells, and/or batteries, and/or methods of using such membranes or substrates, separators, cells, and/or batteries. In accordance with at least certain embodiments, the present application is directed to novel or improved microporous membranes, battery separator membranes, separators, energy storage devices, batteries including such separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries. In accordance with at least certain selected embodiments, the present invention is directed to a novel or improved separator membrane or separator with or without embedded particles or materials, such as ceramic particles or materials, for example, aluminum oxide, boehmite, and/or barium, and/or with or without novel polymers, such as PVDF or PMP, and/or with or without one or more ceramic coatings, for a battery which is stable up to at least 5 volts in a battery, a novel or improved polymer membrane, or polymeric microporous membrane, adapted for use in a 4.5 volt, 4.7 volt, or 5 volt or higher rechargeable or secondary lithium battery and/or which provides for the energy density of a battery to be increased and/or has excellent oxidation resistance. In accordance with at least particular embodiments, the battery separator membrane described herein is directed to a single or multilayer or composite microporous membrane battery separator which may have excellent oxidation resistance and/or may be stable in a high voltage lithium battery system up to 5 volts or more.
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
Disclosed is an improved non-continuous and water-based adhesive coating containing large polymeric particles or agglomerate with an average particle size (D50) greater than 5 microns. The coating may be applied onto one or both sides of a porous film or membrane. A method of forming the coating involves applying an aqueous slurry containing the large polymeric particles with a D50 greater than 5 microns onto a porous membrane. The method of application may be a spray coating method. The coated porous film or membrane may be a battery separator. The coated porous film or membrane may include a fiber layer on at least one side. The fiber layer can be adhered to a porous film or membrane (such as a wet PE, dry PR, dry PP/PE/PP trilayer, etc.) by coating layers with pressure activated at different temperature from 25 deg C to 110 deg C or may be extruded, electrospun, laminated, co-extruded, or the like to or on the porous film or membrane or to, in, or on the coating.
Disclosed herein are battery separators that include a microporous membrane and a coating. The coating may comprise, consist, or consist essentially of polymeric components, inorganic components, or combinations thereof. The battery separators described herein are, among other things, thinner, stronger, and more wettable with electrolyte than some prior battery separators. The battery separators may be used in secondary or rechargeable batteries, including lithium ion batteries. The batteries may be used in vehicles or devices such as cell phones, tablets, laptops, and e-vehicles.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
Disclosed is a new or improved polyolefin separator for use in secondary batteries, especially sodium-ion batteries and high-density lithium ion batteries. The battery separator comprises a porous polyolefin membrane. The membrane may have a surfactant, e.g., a cross-linkable surfactant, provided on or impregnated into at least one surface thereof to improve wettability with respect to polar solvents like propylene carbonate (PC). Also, at least one surface of the membrane may be treated to improve wettability with respect to polar solvents like propylene carbonate (PC). In another embodiment, an organic solvent based PVDF or PVDF:HFP copolymer coating is coated on and into a high porosity separator or base film. This PVDF or PVDF:HFP layer can function as a 3D sub film intercalated to the base film to increase wettability and mechanical strength.
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
A ceramic-coated battery separator exhibiting improved safety has the following structure: a battery separator; and a ceramic coating that comprises ceramic micro-wires. The ceramic coating may comprise ceramic micro-wires as the only ceramic material, or may comprise a mixture of ceramic micro-wires and ceramic particles.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
10.
COATED BATTERY SEPARATOR COMPRISING POROUS POLYMERIC COATING, AND BATTERY COMPRISING THE SAME
A coated battery separator, comprising the battery separator; and a porous coating on at least one side of the battery separator, wherein the porous coating comprises a polymer comprising an amide functional group.
Systems and methods of evaluating the electrochemical stability of material are provided comprising providing an electrochemical cell having a tube cell, electrolyte material, and at least one reference electrode and at least one working electrode. The working electrode can be at least one of aluminum and copper foil. In some instances, the working electrode can be coated with a test material. In some other instances, the electrolyte material can be pretreated with a test material. The electrochemical cell can be subjected to a cyclic voltammetry procedure in part to determine physical and/or chemical attributes of the test material.
Disclosed is an improved non-continuous and water-based adhesive coating containing large polymeric particles or agglomerate with an average particle size (D50) greater than 5 microns. The coating may be applied onto one or both sides of a porous film. A method of forming the coating involves applying an aqueous slurry containing the large polymeric particles with a D50 greater than 5 microns onto a porous membrane. The method of application may be a spray coating method.
A microporous film having at least one of the following properties: unrestrained MD shrinkage, when the film is baked unrestrained at 90° C. for 1 hour, of 2% or more; unrestrained MD shrinkage, when the film is baked unrestrained at 105° C. for 1 hour, of 2.5% or more; MD restrained growth, when measured using the MD restrained growth test, of less than or equal to 0.2%; rebound or recovery of 5% or greater when measured by the compressibility test; a max compression greater than or equal to 18% when measured by the compressibility test; swelling in DEC when measured according to the swelling in DEC test of 0.95% or less; the film exhibits a round-shaped, not a slit-shaped opening when subjected to the puncture test; the lamellae of the film have a thickness no greater than 250 nm; a normalized puncture strength above 350 g/16 micron; and having higher modulus and lower elongation before break of less than 40% in the machine direction. Also disclosed is a battery separator, battery, or device comprising at least one microporous film as described herein.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
In accordance with at least selected embodiments, a battery separator or separator membrane comprises one or more co-extruded multi-microlayer membranes optionally laminated or adhered to another polymer membrane. The separators described herein may provide improved strength, for example, improved puncture strength, particularly at a certain thickness, and may exhibit improved shutdown and/or a reduced propensity to split.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
17 - Rubber and plastic; packing and insulating materials
Goods & Services
Microporous extruded plastic film and sheet, low friction polymer laminates, extruded plastic film and sheet, and insulating liquid blocking, vapor transmitting membranes, breathable insulating waterproofing membranes for use in the manufacture of textiles and textile goods; Microporous extruded plastic film and sheet, low friction polymer laminates, extruded plastic film and sheet, and insulating liquid blocking, vapor transmitting membranes, breathable insulating waterproofing membranes for use in the manufacture of clothing, headgear, and footwear goods; Extruded plastic in the form of films and sheets, manmade microporous extruded plastic film and sheet, microporous extruded plastic film and sheet, for use in manufacturing degassing machines, medical devices, sterile packaging, and control release machines; Microporous extruded plastic film for separate applications, namely, for use in the manufacture of textiles, clothing, medical devices, sterile packaging and control release devices; Microporous extruded plastic film and sheet for separations applications, namely, for use in manufacturing medical devices, sterile packaging, and control release devices; Extruded plastic film and sheet, and insulating, liquid blocking, vapor transmitting, breathable membranes for textiles and textile goods
A membrane is a microporous sheet made of a blend of a first ultra high molecular weight polyolefin and a second ultra high molecular weight polyolefin. Each polyolefin has a molecular weight, both of those molecular weights are greater than 1 million, and one molecular weight is greater than the other. Additionally, the intrinsic viscosity (IV) of the membrane may be greater than or equal to 6.3.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
Disclosed are embossed microporous membranes, as well as articles (e.g., battery separators, materials, textiles, composites, and laminates) comprising the embossed microporous membranes. Also provided are methods of making and/or using embossed microporous membranes.
B29C 55/00 - Shaping by stretching, e.g. drawing through a dieApparatus therefor
B29C 55/02 - Shaping by stretching, e.g. drawing through a dieApparatus therefor of plates or sheets
B29C 55/06 - Shaping by stretching, e.g. drawing through a dieApparatus therefor of plates or sheets uniaxial, e.g. oblique parallel with the direction of feed
B29C 55/16 - Shaping by stretching, e.g. drawing through a dieApparatus therefor of plates or sheets multiaxial biaxial simultaneously
B29C 59/02 - Surface shaping, e.g. embossingApparatus therefor by mechanical means, e.g. pressing
B29K 23/00 - Use of polyalkenes as moulding material
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/463 - Separators, membranes or diaphragms characterised by their shape
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
A microporous membrane is made by a dry-stretch process and has substantially round shaped pores and a ratio of machine direction tensile strength to transverse direction tensile strength in the range of 0.5 to 5.0. The method of making the foregoing microporous membrane includes the steps of: extruding a polymer into a nonporous precursor, and biaxially stretching the nonporous precursor, the biaxial stretching including a machine direction stretching and a transverse direction stretching, the transverse direction stretching including a simultaneous controlled machine direction relax.
B32B 5/32 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by the presence of two or more layers which comprise fibres, filaments, granules, or powder, or are foamed or specifically porous both layers being foamed or specifically porous
B01D 67/00 - Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
B29C 48/00 - Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired formApparatus therefor
B29C 48/08 - Flat, e.g. panels flexible, e.g. films
B29C 55/00 - Shaping by stretching, e.g. drawing through a dieApparatus therefor
B29C 55/14 - Shaping by stretching, e.g. drawing through a dieApparatus therefor of plates or sheets multiaxial biaxial successively
B29K 105/04 - Condition, form or state of moulded material cellular or porous
B32B 3/26 - Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layerLayered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a layer with cavities or internal voids
H01M 50/414 - Synthetic resins, e.g. .thermoplastics or thermosetting resins
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
A two-side coated battery separator that has an adhesive layer on each side is described. The adhesive layer on one side is formed from a different coating formulation than the adhesive layer on an opposite side. In some embodiment, an adhesive layer on one side is formed on top of a ceramic layer and an adhesive layer on the other side is formed directly on the battery separator. A battery comprising this two-side coated battery separator is also described.
Disclosed herein are new or improved method for measuring battery separators that are more suitable for modern battery separators and may more accurately predict performance in the battery. Also disclosed are characteristics of an ideal separator that may be measured according to the new or improved methods herein. The ideal separator may comprise one of more of the following properties: low electrical resistance (ER)/σi approaching infinity; σe approaching zero when the separator is dry or wet with electrolyte; low or no volume (higher Wh/l); low or no weight (high Wh/kg); anti-compression (z-performance, wet); super strong (XYZ direction strength for processing when dry and wet); all temperature stability (mechanical, electrical, and electro-chemical when wet and dry); and ability to apply infinite force when measuring ISR.
Disclosed or provided are non-shutdown high melt temperature or ultra high melt temperature microporous battery separators, high melt temperature separators, battery separators, membranes, composites, and the like that preferably prevent contact between the anode and cathode when the battery is maintained at elevated temperatures for a period of time and preferably continue to provide a substantial level of battery function (ionic transfer, discharge) when the battery is maintained at elevated temperatures for a period of time, methods of making, testing and/or using such separators, membranes, composites, and the like, and/or batteries, high temperature batteries, and/or Lithium-ion rechargeable batteries including one or more such separators, membranes, composites, and the like.
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
A battery separator is provided comprising a microporous membrane comprising one or more layers of a polyolefin and a heat dissipation layer affixed to a surface of the microporous membrane, wherein the heat dissipation layer is configured to dissipate heat and reduce thermal propagation within a battery cell. The heat dissipation layer can comprise at least one of a polymer, a phase change material, and/or a high thermal conduction material configured to dissipate heat in or above a normal battery cell operating range.
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 10/653 - Means for temperature control structurally associated with the cells characterised by electrically insulating or thermally conductive materials
H01M 10/654 - Means for temperature control structurally associated with the cells located inside the innermost case of the cells, e.g. mandrels, electrodes or electrolytes
H01M 10/6551 - Surfaces specially adapted for heat dissipation or radiation, e.g. fins or coatings
H01M 10/659 - Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
In accordance with at least selected embodiments, aspects or objects, there are disclosed or provided new or improved pins adapted for use with high or higher COF polymer membranes or separator membranes (also known as sheets or films), polymer tension measuring, and/or related methods of use, of cell or battery manufacture, and/or the like. In certain embodiments, the new or improved pins are especially well suited for use with dry process polyolefin microporous membranes, separator membranes, or separators. In certain selected embodiments, the new or improved pins are especially well suited for use with dry process polyolefin microporous membranes, separator membranes, or separators in Z-fold or S-fold machines for the production of lithium ion pouch cells, lithium polymer pouch cells, lithium prismatic cells, and/or the like.
In one aspect, microporous membranes are described herein demonstrating composite architectures and properties suitable for electronic and/or optical applications. In some embodiments, a composite membrane described herein includes a microporous polymeric matrix or substrate having an interconnected pore structure and an index of refraction and an electrically conductive coating deposited over one or more surfaces of the microporous polymeric matrix. In other embodiments, the pores are filled and the membranes are substantially transparent.
Novel or improved microporous single or multilayer battery separator membranes, separators, batteries including such membranes or separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries are provided. In accordance with at least certain embodiments, a multilayer dry process polyethylene/polypropylene/polyethylene microporous separator which is manufactured using the inventive process which includes machine direction stretching followed by transverse direction stretching and a subsequent calendering step as a means to reduce the thickness of the multilayer microporous membrane, to reduce the percent porosity of the multilayer microporous membrane in a controlled manner and/or to improve transverse direction tensile strength. In a very particular embodiment, the inventive process produces a thin multilayer microporous membrane that is easily coated with polymeric-ceramic coatings, has excellent mechanical strength properties due to its polypropylene layer or layers and a thermal shutdown function due to its polyethylene layer or layers. The ratio of the thickness of the polypropylene and polyethylene layers in the inventive multilayer microporous membrane can be tailored to balance mechanical strength and thermal shutdown properties.
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
B29C 48/00 - Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired formApparatus therefor
B29C 48/08 - Flat, e.g. panels flexible, e.g. films
B29C 48/21 - Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
B29C 55/00 - Shaping by stretching, e.g. drawing through a dieApparatus therefor
B29C 55/02 - Shaping by stretching, e.g. drawing through a dieApparatus therefor of plates or sheets
B29C 55/14 - Shaping by stretching, e.g. drawing through a dieApparatus therefor of plates or sheets multiaxial biaxial successively
B29C 65/00 - Joining of preformed partsApparatus therefor
B29C 65/02 - Joining of preformed partsApparatus therefor by heating, with or without pressure
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 37/14 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
B32B 37/16 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
B32B 38/00 - Ancillary operations in connection with laminating processes
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/463 - Separators, membranes or diaphragms characterised by their shape
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
A dry-process microporous membrane for filtration, wherein at least one layer of the membrane has an average pore size less than 0.035 microns, preferably between about 0.010 microns to about 0.020 microns, and a thickness less than 14 microns. The membrane may be used in an ultra-filtration or nano-filtration process. The membrane exhibits high dimensional stability.
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
Disclosed is a membrane with one or more dry-process porous layers that comprise (1) a polyolefin and (2) a product formed by reacting two components, which may be a compound with one or more carboxy groups and a compound with one or more epoxy groups. The product may be a reaction network, a three-dimensional reaction network, or a cross-linked network The resulting membrane has improved strength, reduced splittiness, or both improved strength and reduced splittiness. The membrane may be used in a battery, capacitor, HVAC, filtering device, or textile. Methods for making the membrane are also disclosed.
A battery separator is provided comprising a microporous membrane comprising one or more layers of a polyolefin and a heat absorption layer affixed to a surface of the microporous membrane, wherein the heat absorption layer is configured to absorb heat and reduce thermal propagation within a battery cell. The heat absorption layer can comprise at least one of a phase change material or a high heat capacity material configured to absorb heat in or above a normal battery cell operating range.
H01M 10/653 - Means for temperature control structurally associated with the cells characterised by electrically insulating or thermally conductive materials
H01M 10/6551 - Surfaces specially adapted for heat dissipation or radiation, e.g. fins or coatings
In one aspect, a method of measuring the internal short resistance of a battery separator comprising one or more layers of a polyolefin is provided. A method comprises applying a force via a force component comprising a ball to a test stack, the test stack comprising an anode, a separator, and a cathode, deforming the test stack until an electrical short occurs, and determining an ISR value for the separator, the value corresponding to an overall ISR, or at least in one of the MD, TD, or Z-direction.
In one aspect, a battery separator comprises a microporous membrane having one or more layers of a polyolefin, wherein the microporous membrane has an electrical resistance (ER) of less than 10 Ω/mm at a compression pressure of 1,000 lbs. In some embodiments, the microporous membrane has an electrical resistance of less than 25 Ω/mm at a compression pressure of 5,000 lbs, an electrical resistance of less than 37 Ω/mm at a compression pressure of 7,500 lbs, and/or an electrical resistance of less than 47 Ω/mm at a compression pressure of 10,000 lbs. In some embodiments, the microporous membrane exhibits a compression from about 5% to about 10% under a stress of 8 N/mm2, and wherein the microporous membrane exhibits an elastic recovery from 50% to 100%.
H01M 50/107 - Primary casingsJackets or wrappings characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
A battery separator is provided comprising a low temperature shutdown layer, and the battery separator has a shutdown temperature of less than about 130°C, less than about 120°C, less than about 110°C, less than about 100°C, less than about 90°C, or less than about 80°C. The low temperature shutdown layer can contain a first and second polymeric component. For example, it may contain an ultrahigh molecular weight polyethylene and a low molecular weight polyolefin and/or wax.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 50/414 - Synthetic resins, e.g. .thermoplastics or thermosetting resins
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
Equipment or methods are provided for addressing the failure mode that thermal runaway cell emits flammable smoke, igniting the flammable smoke causes an EDV fire and providing new or proprietary solutions, components, materials or chemicals, to achieve the following: non-flammable smoke can be generated during cell thermal runaway resulting in smoke only, cell reaction strength is reduced by dropping Tmax for the reaction, and/or thermal-propagation can be prevented, whereby many EDV and ESS fires may be prevented and safe EDVs and ESSs may be possible. Novel or improved batteries, anodes, separators, solutions on li ion battery fires, and/or fire suppression systems, chemicals, etc.; in addition, exemplary embodiments disclosed herein are directed to novel or improved lithium ion batteries, cells, electrodes, separators, and/or similar batteries incorporating the same, and/or related methods of manufacturing and/or of using the same, and/or combinations thereof; improvements or solutions as shown and/or described herein.
Equipment or methods are provided for addressing the failure mode that thermal runaway cell emits flammable smoke, igniting the flammable smoke causes an EDV fire and providing new or proprietary solutions, components, materials or chemicals, to achieve the following: non-flammable smoke can be generated during cell thermal runaway resulting in smoke only, cell reaction strength is reduced by dropping Tmax for the reaction, and/or thermal-propagation can be prevented, whereby many EDV and ESS fires may be prevented and safe EDVs and ESSs may be possible. Novel or improved batteries, anodes, separators, solutions on li ion battery fires, and/or fire suppression systems, chemicals, etc.; in addition, exemplary embodiments disclosed herein are directed to novel or improved lithium ion batteries, cells, electrodes, separators, and/or similar batteries incorporating the same, and/or related methods of manufacturing and/or of using the same, and/or combinations thereof; improvements or solutions as shown and/or described herein.
Equipment or methods are provided for addressing the failure mode that
Thermal runaway cell emits flammable smoke
Igniting the flammable smoke causes an EDV fire
and providing new or proprietary solutions, components, materials or chemicals, to achieve the following: Non-flammable smoke can be generated during cell thermal runaway resulting in smoke only. Cell reaction strength is reduced by dropping Tmax for the reaction, and/or thermal-propagation can be prevented, whereby many EDV and ESS fires may be prevented and safe EDVs and ESSs may be possible.
New and/or improved coatings, layers or treatments for porous substrates, including battery separators or separator membranes, and/or coated or treated porous substrates, including coated battery separators, and/or batteries or cells including such coatings or coated separators, and/or related methods including methods of manufacture and/or of use thereof are disclosed. Also, new or improved coatings for porous substrates, including battery separators, which comprise at least a matrix material or a polymeric binder, and heat-resistant particles with additional additives, materials or components, and/or to new or improved coated or treated porous substrates, including battery separators, where the coating comprises at least a matrix material or a polymeric binder, and heat-resistant particles with additional additives, materials or components are disclosed. Further, new or improved coatings for porous substrates, including battery separators, and new and/or improved coated porous substrates, including battery separators, new or improved coatings for porous substrates, including battery separators, which comprise at least (i) a matrix material or a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, and a thickener, and new and/or improved coated porous substrates, including battery separators, where the coating comprises at least (i) a matrix material or a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, a thickener, a friction-reducing agent, and a high-temperature shutdown agent are disclosed.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
A novel or improved base film for impregnation, impregnated base film, product incorporating the impregnated base film, and/or related methods as shown, claimed or described herein.
H01M 50/414 - Synthetic resins, e.g. .thermoplastics or thermosetting resins
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
Described herein is a multilayer microporous film or membrane that may exhibit improved properties, including improved dielectric break down and strength, compared to prior monolayer or tri-layer microporous membranes of the same thickness. The preferred multilayer microporous membrane comprises microlayers and one or more lamination interfaces or barriers. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. The inventive battery and battery separator is preferably safer and more robust than batteries and battery separators using prior monolayer and tri-layer microporous membranes. Also, described herein is a method for making the multilayer microporous separators, membranes or films described herein.
B29C 48/21 - Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
B01D 67/00 - Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
B29C 48/08 - Flat, e.g. panels flexible, e.g. films
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/454 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising a non-fibrous layer and a fibrous layer superimposed on one another
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
2. A composite for forming an improved semi-solid state electrolyte. The composite has a layer formed including lithium metaphosphate (LiPO3). The layer may include a mixture of LiPO3 and PEO. The composite may be wet with liquid electrolyte to form the semi-solid state electrolyte. When used in a semi-solid state battery, the semi-solid state electrolyte provides beneficial results, including improved cycle life and less lithium dendrite growth. Another composite for forming an improved semi-solid state electrolyte has a layer formed including LiTaO3 and LiNbO3. Yet another composite has a single layer formed to include a mixture of a polyethylene oxide and a lithium-containing salt, including a lithium salt including niobium, tantalum, or mixtures thereof. Such composites may be wet with liquid electrolyte to form the semi-solid state electrolyte. When used in a semi-solid state battery, the semi-solid state electrolyte provides beneficial results, including improved cycle life and less lithium dendrite growth.
A dry-process microporous membrane for filtration, wherein at least one layer of the membrane has an average pore size less than 0.035 microns, preferably between about 0.010 microns to about 0.020 microns, and a thickness less than 14 microns. The membrane may be used in an ultra-filtration or nano-filtration process. The membrane exhibits high dimensional stability.
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
A heat-resistant sticky coating for use on a membrane or lithium ion battery separator is disclosed. The coating has at least improved dry adhesion to an electrode for a lithium ion battery. The coating includes heat-resistant particles with a water-soluble sticky polymer on their surface. The water-soluble sticky polymer may be a polyethylene oxide (PEO). The coating may also include particles of water-insoluble sticky polymer. The water-insoluble sticky polymer may be a polyvinylidene fluoride (PVDF) homopolymer, copolymer, or terpolymer. The water-insoluble sticky polymer may be in the same layer of the coating as the heat-resistant particles with the water-soluble sticky polymer on their surface, or it may be in a different layer. A method for forming the heat-resistant sticky coating is also disclosed.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
40.
ADDITIVES FOR IMPROVED BATTERY PERFORMANCE, IMPROVED ADDITIVE-CONTAINING MEMBRANES, IMPROVED BATTERY SEPARATORS, IMPROVED BATTERIES, AND RELATED METHODS
Described herein, are battery separators, comprising the following: a microporous polymeric film; and an optional coating layer on at least one side of the microporous polymeric film, wherein at least one of the microporous polymeric film and the optional coating comprises an additive. The additive is selected from the group consisting of a lubricating agent, a plasticizing agent, a nucleating agent, a shrinkage reducing agent, a surfactant, an SEI improving agent, a cathode protection agent, a flame retardant additive, LiPF6 salt stabilizer, an overcharge protector, an aluminum corrosion inhibitor, a lithium deposition agent or improver, or a solvation enhancer, an aluminum corrosion inhibitor, a wetting agent, and a viscosity improver. Also, described herein are batteries, including lithium-ion batteries, comprising one or more of the described separators. Methods for making the battery separators are also described.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/454 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising a non-fibrous layer and a fibrous layer superimposed on one another
A composite for forming an improved semi-solid state electrolyte. The composite has a single layer formed to include a mixture of a polyethylene oxide and a lithium-containing salt, including a lithium salt including niobium, tantalum, or mixtures thereof. The composite may be wet with liquid electrolyte to form the semi-solid state electrolyte. When used in a semi- solid state battery, the semi-solid state electrolyte provides beneficial results, including improved cycle life and less lithium dendrite growth.
H01M 10/0564 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
A monolayer, bilayer, trilayer, or multilayer porous membrane having at least one layer that contains a thermoplastic resin and a polymer that is incompatible with the thermoplastic resin. One structure is a multilayer porous membrane where at least one internal layer of the multilayer porous membrane contains the thermoplastic resin and the polymer that is incompatible with the thermoplastic resin. Higher amounts of incompatible polymer may be used in an internal layer. This structure has improved properties, including improved puncture strength. Another structure includes at least one layer containing polyethylene and a polymer that is incompatible with polyethylene. The at least one layer containing polyethylene and a polymer that is incompatible with polyethylene may be an internal layer or an external layer. An internal layer may include more incompatible polymer than an external layer. The porous membranes may be used as battery separators. For example, they may be used as battery separators in secondary batteries such as lithium ion secondary batteries.
New and/or improved coatings for porous substrates, including battery separators or separator membranes, and/or coated porous substrates, including coated battery separators, and/or batteries or cells including such coatings or coated separators, and/or related methods including methods of manufacture and/or of use thereof are disclosed. Also, new or improved coatings for porous substrates, including battery separators, which comprise at least a polymeric binder and heat-resistant particles with or without additional additives, materials or components, and/or to new or improved coated porous substrates, including battery separators, where the coating comprises at least a polymeric binder and heat-resistant particles with or without additional additives, materials or components are disclosed. Further, new or improved coatings for porous substrates, including battery separators, and new and/or improved coated porous substrates, including battery separators, new or improved coatings for porous substrates, including battery separators, which comprise at least (i) a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, and a thickener, and new and/or improved coated porous substrates, including battery separators, where the coating comprises at least (i) a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, a thickener, a friction-reducing agent, a high-temperature shutdown agent are disclosed.
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
In one aspect, a wide microporous film comprises one or more layers comprising a polyolefin, wherein the microporous film has a width of at least 50 inches and comprises one or more non-porous regions. In some embodiments, the microporous film is at least 55 inches or at least 60 inches. Moreover, in some embodiments, the non-porous region is located along a creased region of the microporous film.
B29D 99/00 - Subject matter not provided for in other groups of this subclass
B29K 105/04 - Condition, form or state of moulded material cellular or porous
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
In accordance with at least selected aspects, objects or embodiments, optimized, novel or improved membranes, battery separators, batteries, and/or systems and/or related methods of manufacture, use and/or optimization are provided. In accordance with at least selected embodiments, the present invention is related to novel or improved battery separators that prevent dendrite growth, prevent internal shorts due to dendrite growth, or both, batteries incorporating such separators, systems incorporating such batteries, and/or related methods of manufacture, use and/or optimization thereof. In accordance with at least certain embodiments, the present invention is related to novel or improved ultra thin or super thin membranes or battery separators, and/or lithium primary batteries, cells or packs incorporating such separators, and/or systems incorporating such batteries, cells or packs. In accordance with at least particular certain embodiments, the present invention is related to shutdown membranes or battery separators, and/or lithium primary batteries, cells or packs incorporating such separators, and/or systems incorporating such batteries, cells or packs.
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
A dry-process porous membrane having an oxygen induction time (OIT) greater than 3 minutes, greater than 5 minutes, greater than 10 minutes, greater than 15 minutes, greater than 20 minutes, or greater than 25 minutes where OIT is measured at 215° C. and 100% O2. The dry-process porous membrane may be a microporous polyolefin membrane.
B01D 67/00 - Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
B01D 71/76 - Macromolecular material not specifically provided for in a single one of groups
B32B 5/02 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments
B32B 27/12 - Layered products essentially comprising synthetic resin next to a fibrous or filamentary layer
The present disclosure provides a separator for an electric storage device, which separator is capable of reducing clogging and has an excellent thermal stability, and an electric storage device using the same. The above-described separator for an electric storage device includes a microporous layer (A) and a microporous layer (B) that contain 70 wt % or more of polypropylene, and the area average major pore diameter in an ND-MD cross section of the microporous layer (B) is not more than 0.95 times the area average major pore diameter in an ND-MD cross section of the microporous layer (A). Alternatively, the separator for an electric storage device contains 70% by weight or more of a polyolefin, and the area average major pore diameter of a first porous surface (X) of the separator is not less than 1.05 times and not more than 10 times the area average major pore diameter of a second porous surface (Y) on the side opposite thereto.
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
53.
Separators, batteries, systems, vehicles, and related methods
Improved battery separators, base films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of making and/or using such separators, films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of enhancing battery or cell charge rates, charge capacity, and/or discharge rates, and/or methods of improving batteries, systems including such batteries, vehicles including such batteries and/or systems, and/or the like; biaxially oriented porous membranes, composites including biaxially oriented porous membranes, biaxially oriented microporous membranes, biaxially oriented macroporous membranes, battery separators with improved charge capacities and the related methods and methods of manufacture, methods of use, and the like; flat sheet membranes, liquid retention media; dry process separators; biaxially stretched separators; dry process biaxially stretched separators having a thickness range between about 5 μm and 50 μm, preferably between about 10 μm and 25 μm, having improved strength, high porosity, and unexpectedly and/or surprisingly high charge capacity, such as, for example, high 10C rate charge capacity; separators or membranes with high charge capacity and high porosity, excellent charge rate and/or charge capacity performance in a rechargeable and/or secondary lithium battery, such as a lithium ion battery, for high power and/or high energy applications, cells, devices, systems, and/or vehicles, and/or the like; single or multiple ply or layer separators, monolayer separators, trilayer separators, composite separators, laminated separators, co-extruded separators, coated separators, 1 C or higher separators, at least 1 C separators, batteries, cells, systems, devices, vehicles, and/or the like; improved microporous battery separators for secondary lithium batteries, improved microporous battery separators with enhanced or high charge (C) rates, discharge (C) rates, and/or enhanced or high charge capacities in or for secondary lithium batteries, and/or related methods of manufacture, use, and/or the like, and/or combinations thereof are disclosed or provided.
This application is directed to dry-process porous membranes comprising polyethylene and to methods for forming such membranes. Some of the dry-process porous membranes may comprise polyethylene that has been irradiated with electron-beam irradiation. The dry-process porous membranes disclosed herein may be used in the following: lithium ion batteries, including those utilizing nickel manganese cobalt oxide (NMC), lithium metal, or lithium iron phosphate (LFP) chemistries, and/or large format lithium ion batteries, textiles, garments, PPE, filters, medical products, house products, fragrance devices, and/or disposable lighters. In at least one embodiment, a multilayer porous membrane, comprises a dry-process polyethylene layer that has been treated with electron-beam radiation; and, an additional layer that has not been treated with electron-beam irradiation; and, optionally: wherein a dosage of the electron-beam radiation is from 20 kGy to 250 kGy, 50 kGy to 250 kGy, from 60 kGy to 200 kGy, from 70 kGy to 150 kGy, or from 80 kGy to 140 kGy; wherein the additional layer is laminated to the dry-process polyethylene layer that has been treated with electron-beam radiation; or wherein a blocking layer is laminated with a dry-process polyethylene layer and the additional layer to form a structure with the blocking layer between the dry-process polyethylene layer and the additional layer, and wherein the dry-process polyethylene layer is treated with electron beam irradiation to form the dry-process polyethylene layer that has been treated with electron-beam radiation. Also described is a textile, garment, PPE, filter, medical product, house product, fragrance device, or disposable lighter comprising the inventive membrane.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
In one aspect, a device for absorbing a liquid is provided, the device comprising one or more layers of a polyolefin. The device may be configured as a microporous membrane comprising one or more layers of a polyolefin and can further be configured to absorb an oil while also allowing water to pass through or to absorb oil while repelling or not allowing water to pass through. The device may be configured as at least one of a sheet, a strip, a roll, pleated, embossed, ribbed, and patterned. The device may further be configured as a floor covering or mat.
C08J 9/00 - Working-up of macromolecular substances to porous or cellular articles or materialsAfter-treatment thereof
C08L 23/00 - Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bondCompositions of derivatives of such polymers
Battery separators and methods are disclosed. The battery separator may be used in a lithium battery. The separator may include a microporous membrane laminated to a coated nonwoven. The coating may contain a polymer and optionally, a filler or particles. The methods may include the steps of: unwinding the microporous membrane and the nonwoven, laminating the nonwoven and microporous membrane, and coating the nonwoven before or after lamination.
B32B 3/26 - Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layerLayered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a layer with cavities or internal voids
B32B 5/02 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments
B32B 27/12 - Layered products essentially comprising synthetic resin next to a fibrous or filamentary layer
B32B 5/08 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments the fibres or filaments of a layer being specially arranged or being of different substances
B32B 27/20 - Layered products essentially comprising synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 50/454 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising a non-fibrous layer and a fibrous layer superimposed on one another
H01M 50/414 - Synthetic resins, e.g. .thermoplastics or thermosetting resins
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
57.
Functionalized porous membranes and methods of manufacture and use
A functionalized microporous, mesoporous, or nanoporous membrane, material, textile, composite, laminate, or the like, and/or a method of making or using such functionalized membranes. The functionalized porous membrane may be a functionalized microporous, mesoporous, or nanoporous membrane that has a functional molecule attached, such as a functional polymer, to the surface and/or internal fibrillar structure of the membrane.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
An improved multilayer laminated microporous battery separator for a lithium ion secondary battery, and/or a method of making or using this separator is provided. The preferred inventive dry process separator is a tri-layer laminated Polypropylene/Polyethylene/Polypropylene microporous membrane with a thickness range of 12 μm to 30 μm having improved puncture strength and low electrical resistance for improved cycling and charge performance in a lithium ion battery. In addition, the preferred inventive separator's or membrane's low Electrical Resistance and high porosity provides superior charge rate performance in a lithium battery for high power applications.
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
The present invention relates in at least selected embodiments to novel or improved microporous battery separators for lithium rechargeable batteries and/or related methods of making and/or using such separators. A particular inventive dry process battery separator or membrane separator exhibits a thickness that is less than about 14 μm and has increased strength performance as defined by reduced splittiness. The mode of splitting failure has been investigated, and the improvement in splittiness quantified by a novel test method known as the Composite Splittiness Index (CSI).
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
Described herein is a coated battery separator where the coating is provided on one or both sides of the battery separator. The coating comprises polytetrafluoroethylene (PTFE) particles and the coating is an outermost coating layer. In some cases, the coating may also comprise ceramic particles.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
Textile fabrics for use in making clothing and household furnishings; Textile fabrics for the manufacture of clothing; Textile substitute materials made from synthetic materials; Textile fabrics for use in the manufacture of garments, bags, jackets, gloves, and apparel Clothing, namely, shirts, shorts, pants, and knit face masks being headwear, ski masks, masks in the nature of balaclavas; headwear; footwear
Textile fabrics for use in making clothing and household furnishings; Textile fabrics for the manufacture of clothing; Textile substitute materials made from synthetic materials; Textile fabrics for use in the manufacture of garments, bags, jackets, gloves, and apparel
63.
Microlayer membranes, improved battery separators, and methods of manufacture and use
In accordance with at least selected embodiments, a battery separator or separator membrane comprises one or more co-extruded multi-microlayer membranes optionally laminated or adhered to another polymer membrane. The separators described herein may provide improved strength, for example, improved puncture strength, particularly at a certain thickness, and may exhibit improved shutdown and/or a reduced propensity to split.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
2. The inventive battery separator membrane may provide a means to achieve an improved level of battery performance in a rechargeable or secondary lithium battery based on a possibly synergistic combination of low Electrical resistance, low Gurley, low tortuosity, and/or a unique trapezoid shaped pore. Certain multilayer embodiments (by way of example only, a trilayer membrane made of two polypropylene layers with a polyethylene layer in between), the inventive microporous membrane or battery separator may have excellent onset and rate of thermal shutdown performance.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 3/26 - Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layerLayered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a layer with cavities or internal voids
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
The present invention relates to surface modifying agents for polymeric and/or textile materials, methods of making and/or using a surface modifying agent to modify and functionalize polymeric and/or textile materials, and/or methods of using surface modified or functionalized polymeric and textile materials, and/or products using or incorporating surface modified or functionalized polymeric and textile materials. For example, the surface modifying agent in precursor form can be styrene sulfonyl azide monomer, polymer or copolymer capable of undergoing a chemical reaction in the presence of heat or light to form one or more styrene sulfonated nitrene monomers, polymers or copolymers, which are capable of chemically reacting with the surface of a polymeric or textile material to endow a specific or desired chemical surface functionality to the surface of a polymeric or textile material. Furthermore, the present invention is possibly preferably directed to a surface modifying agent which comprises a styrene sulfonated nitrene monomer, polymer or polymer containing one or more nitrene functional groups, which are capable of chemically reacting via an insertion reaction into one or more carbon-hydrogen bonds on the surface of a polymeric or textile material in order to chemically attach a specific or desired chemical functionality to the surface of a polymeric or textile material.
A porous membrane having a cross-linked ceramic coating on at least one side thereof is disclosed. The coated porous membrane may be used as a battery separator, particularly a battery separator for a lithium ion battery. The coating includes at least a cross-linker and a ceramic. The cross-linker may be a particulate polymeric binder cross-linker, a PEO (PEG) cross-linker, or a POSS cross-linker. The coated membrane exhibits improved properties that may be favorable for its use as a battery separator. For example, the coated porous membrane may exhibit improved shrinkage properties and high temperature resistance.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
C09D 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C07D 303/16 - Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
[Problem] To provide a separator for electric storage devices that suppresses dendrite short circuits and has excellent thermal stability.
[Problem] To provide a separator for electric storage devices that suppresses dendrite short circuits and has excellent thermal stability.
[Solution] Provided is a separator for electric storage devices including: (A) a microporous layer mainly composed of (X) polypropylene; and (B) a microporous layer containing (Y) polypropylene identical or different from the polypropylene (X) and a thermoplastic elastomer that is incompatible with the polypropylene (Y). In an ND-MD sectional observation of the microporous layer (B), the area-averaged long pore diameter of pores present in the microporous layer (B) is from 150 nm to 500 nm.
A multilayer battery separator comprises a first outer layer comprising a blend of a polypropylene and a first nanoparticle inorganic filler; and a second outer layer laminated to the first outer layer.
To provide a separator for electric storage devices that suppresses dendrite short circuits and has excellent thermal stability.
To provide a separator for electric storage devices that suppresses dendrite short circuits and has excellent thermal stability.
A separator for electric storage devices, including a separator substrate having one or more (A) microporous layers mainly composed of polypropylene and one or more (B) microporous layers mainly composed of polypropylene, wherein the ratio MtA/MtB of the melt tension MtA of the microporous layer (A) at 240° C. to the melt tension MtB of the microporous layer (B) at 240° C. is from 1.05 to 4.0.
A coated battery separator, comprising the battery separator; and a porous coating on at least one side of the battery separator, wherein the porous coating comprises a polymer comprising an amide functional group.
A ceramic-coated battery separator having a microporous polyolefin membrane and a ceramic coating on at least one surface of the microporous polyolefin membrane, wherein the ceramic-coated separator exhibits a strain shrinkage of 0% at temperatures greater than or equal to 120 degrees Celsius is provided.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
A ceramic-coated battery separator exhibiting improved safety has the following structure: a battery separator; and a ceramic coating that comprises ceramic micro-wires. The ceramic coating may comprise ceramic micro-wires as the only ceramic material, or may comprise a mixture of ceramic micro-wires and ceramic particles.
A multilayer membrane comprising at least two co-extruded layers where the two co-extruded layer contain different polymers and one of the two co-extruded layers contains an extrusion additive. Examples of useful extrusion additives may include a nucleating agent or a pore-forming particulate. A method for making the membrane is also disclosed. Using an extrusion additive when co-extruding two different polymers avoids some of the drawbacks associated with processes involving the co-extrusion of different polymers, particularly processes where a co-extruded non-porous precursor is later stretched to form pores. For example, the drawback of lower permeability, difficulty to make lower Gurley, and splittiness may be improved.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 27/20 - Layered products essentially comprising synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
B32B 37/15 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
Systems and methods of evaluating the electrochemical stability of material are provided comprising providing an electrochemical cell having a tube cell, electrolyte material, and at least one reference electrode and at least one working electrode. The working electrode can be at least one of aluminum and copper foil. In some instances, the working electrode can be coated with a test material. In some other instances, the electrolyte material can be pretreated with a test material. The electrochemical cell can be subjected to a cyclic voltammetry procedure in part to determine physical and/or chemical attributes of the test material.
[Problem] To provide a separator for electric storage devices that suppresses dendrite short circuits and has excellent thermal stability.
[Problem] To provide a separator for electric storage devices that suppresses dendrite short circuits and has excellent thermal stability.
[Solution] Provided is a separator for electric storage devices including: (A) a microporous layer mainly composed of (X) isotactic polypropylene; and (B) a microporous layer containing (Y) isotactic polypropylene identical or different from the isotactic polypropylene (X), and (Z) thermoplastic resin different from the isotactic polypropylene (Y). The microporous layer (B) has a lower isotactic polypropylene content than the microporous layer (A), and the thermoplastic resin (Z) has a tensile modulus of from 3 MPa to 500 MPa.
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 50/46 - Separators, membranes or diaphragms characterised by their combination with electrodes
A secondary battery that generates or includes metal-ion contaminants selected from copper ions, manganese ions, nickel ions, cobalt ions, iron ions, aluminum ions, chrome ions, molybdenum ions, tin ions or combinations thereof, the battery comprising: an anode; a cathode; a coated or uncoated battery separator between the anode and the cathode, wherein the coated or uncoated battery separator comprises a trap layer; and an electrolyte. The battery improve yield rate of initial charge and aging process and exhibits prolonged useful life due to the separator, which reduces or eliminates metal-ion contamination in the battery.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/403 - Manufacturing processes of separators, membranes or diaphragms
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 50/414 - Synthetic resins, e.g. .thermoplastics or thermosetting resins
Novel or improved microporous single or multilayer battery separator membranes, separators, batteries including such membranes or separators, methods of making such membranes, separators, and/or batteries, and/or methods of using such membranes, separators and/or batteries are provided. In accordance with at least certain embodiments, a multilayer dry process polyethylene/polypropylene/polyethylene microporous separator which is manufactured using the inventive process which includes machine direction stretching followed by transverse direction stretching and a subsequent calendering step as a means to reduce the thickness of the multilayer microporous membrane, to reduce the percent porosity of the multilayer microporous membrane in a controlled manner and/or to improve transverse direction tensile strength. In a very particular embodiment, the inventive process produces a thin multilayer microporous membrane that is easily coated with polymeric-ceramic coatings, has excellent mechanical strength properties due to its polypropylene layer or layers and a thermal shutdown function due to its polyethylene layer or layers. The ratio of the thickness of the polypropylene and polyethylene layers in the inventive multilayer microporous membrane can be tailored to balance mechanical strength and thermal shutdown properties.
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
B29C 48/00 - Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired formApparatus therefor
B29C 48/21 - Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
B29C 65/02 - Joining of preformed partsApparatus therefor by heating, with or without pressure
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 37/16 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
B32B 38/00 - Ancillary operations in connection with laminating processes
H01M 50/446 - Composite material consisting of a mixture of organic and inorganic materials
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/463 - Separators, membranes or diaphragms characterised by their shape
B29C 48/08 - Flat, e.g. panels flexible, e.g. films
B29C 55/00 - Shaping by stretching, e.g. drawing through a dieApparatus therefor
B29C 55/02 - Shaping by stretching, e.g. drawing through a dieApparatus therefor of plates or sheets
B29C 55/14 - Shaping by stretching, e.g. drawing through a dieApparatus therefor of plates or sheets multiaxial biaxial successively
B29C 65/00 - Joining of preformed partsApparatus therefor
B32B 37/14 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
Described herein is a multilayer microporous film or membrane that may exhibit improved properties, including improved dielectric break down and strength, compared to prior monolayer or tri-layer microporous membranes of the same thickness. The preferred multilayer microporous membrane comprises microlayers and one or more lamination barriers. Also disclosed is a battery separator or battery comprising one or more of the multilayer microporous films or membranes. The inventive battery and battery separator is preferably safer and more robust than batteries and battery separators using prior monolayer and tri-layer microporous membranes. Also, described herein is a method for making the multilayer microporous separators, membranes or films described herein.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
Disclosed herein is a battery separator comprising two porous or microporous layers and a heat-resistant layer between the two porous or microporous layers. The heat-resistant layer may be a ceramic layer or a layer containing a high melt integrity polymer. In some embodiments, the battery separator may further comprise one or more adhesive layers between the two porous or microporous layers. The resulting battery separator may be safer, have more integrity, and/or have shutdown function.
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
80.
IMPROVED MICROPOROUS MEMBRANE AND DEVICES COMPRISING THE SAME
A multilayer porous membrane with two exterior layers and at least one interior layer. The average pore size of the interior layer is greater than that of either of the two exterior layers. The multilayer porous membrane may be used, for example, as or as part of a battery separator. Compared to prior multilayer porous membranes for battery separators, the multilayer porous membrane herein may exhibit at least one of improved thermal properties, improved anti-metal contamination properties, improved ease of manufacture, and combinations thereof.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
A microporous membrane wipe and a method of using such microporous membrane wipe are disclosed. The microporous membrane wipe may be uniaxially or biaxially oriented microporous membrane. The uniaxially or biaxially oriented microporous membrane may be made from one or more block and/or impact copolymers of polyethylene and/or polypropylene. A method of using such a microporous membrane wipe for skin oil blotting is also disclosed. Further disclosed is a method of using such a microporous membrane wipe for cleaning a surface for the removal of fingerprints, smudges and the like, where such surfaces may include, for example, eyeglasses, electronics, cell phones, displays, optical devices, camera lenses, microscope lenses and other precision optics, and/or the like.
In accordance with at least selected aspects, objects or embodiments, optimized, novel or improved membranes, battery separators, batteries, and/or systems and/or related methods of manufacture, use and/or optimization are provided. In accordance with at least selected embodiments, the present invention is related to novel or improved battery separators that prevent dendrite growth, prevent internal shorts due to dendrite growth, or both, batteries incorporating such separators, systems incorporating such batteries, and/or related methods of manufacture, use and/or optimization thereof. In accordance with at least certain embodiments, the present invention is related to novel or improved ultra thin or super thin membranes or battery separators, and/or lithium primary batteries, cells or packs incorporating such separators, and/or systems incorporating such batteries, cells or packs. In accordance with at least particular certain embodiments, the present invention is related to shutdown membranes or battery separators, and/or lithium primary batteries, cells or packs incorporating such separators, and/or systems incorporating such batteries, cells or packs.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
A two-side coated battery separator that has an adhesive layer on each side is described. The adhesive layer on one side is formed from a different coating formulation than the adhesive layer on an opposite side. In some embodiment, an adhesive layer on one side is formed on top of a ceramic layer and an adhesive layer on the other side is formed directly on the battery separator. A battery comprising this two-side coated battery separator is also described.
Materials for personal protective equipment (PPE) that is water resistant, blood resistant, and virus resistant are disclosed. The materials described herein are also highly breathable adding to the comfort of PPE made from these materials. The materials for PPE described herein contain one or more uniaxially or biaxially stretched microporous films.
A41D 13/12 - Surgeons' or patients' gowns or dresses
B32B 5/02 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments
B32B 27/12 - Layered products essentially comprising synthetic resin next to a fibrous or filamentary layer
A polyolefin-containing seam tape is described herein. The polyolefin may be at least one of a homopolymer, copolymer, terpolymer, or a polymer blend of polyethylene, polypropylene, or a combination of the two. The seam tape may be used to form a bonded, reinforced, or waterproofed seam. The seam tape may be used in equipment or apparel that may or may not be recyclable.
iee approaching zero when the separator is dry or wet with electrolyte; low or no volume (higher Wh/l); low or no weight (high Wh/kg); anti-compression (z -performance, wet); super strong (XYZ direction strength for processing when dry and wet); all temperature stability (mechanical, electrical, and electro-chemical when wet and dry); and ability to apply infinite force when measuring ISR.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/46 - Separators, membranes or diaphragms characterised by their combination with electrodes
Disclosed herein is an asymmetric porous membrane having two outer layers and at least one inner layers. The outer layers may be asymmetric in thickness, pore size, porosity, tortuosity, or combinations thereof. In some embodiments, the asymmetric porous membrane has two outer layers and no inner layers. The thickness of one of the outer layers to the other of the outer layers is from 1.1 to 25:1, preferably from 1.1:1 to 10:1, 1.1:1 to 5:1 or 4:1 to 10:1. In some embodiments, both outer layers are PP-containing layers and in some embodiments, one outermost layer may be a PE-containing layer and the other may be a PP-containing layer. The asymmetric porous membrane may be used as or to make a battery separator. In some embodiments, the battery separator may include an asymmetric porous membrane having the thinner of the two outer layers or the layer facing the anode coated with a coating such as a ceramic coating. The battery separator may be used in a liquid electrolyte secondary battery. In the battery, the thicker of the outer layers and/or the PP-containing layer faces or is closest to the cathode and the thinner of the two outer layers and/or the PE-containing layer faces or is closest to the anode. The outer layer facing the anode may be coated with a coating such as a ceramic coating. The battery separators described herein may have electrochemical stability voltage equal to or above 4.2 v.s. Li/Li+.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
A wide microporous film comprises one or more layers comprising a polyolefin; wherein the film has a width of a least 40 inches, at least 45 inches, at least 50 inches, at least 55 inches, at least 60 inches, at least 65 inches, or at least 70 inches.
H01M 50/454 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising a non-fibrous layer and a fibrous layer superimposed on one another
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B32B 27/12 - Layered products essentially comprising synthetic resin next to a fibrous or filamentary layer
B32B 5/02 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
In accordance with at least selected embodiments, aspects or objects, there are disclosed or provided new or improved pins adapted for use with high or higher COF polymer membranes or separator membranes (also known as sheets or films), polymer tension measuring, and/or related methods of use, of cell or battery manufacture, and/or the like. In certain embodiments, the new or improved pins are especially well suited for use with dry process polyolefin microporous membranes, separator membranes, or separators. In certain selected embodiments, the new or improved pins are especially well suited for use with dry process polyolefin microporous membranes, separator membranes, or separators in Z-fold or S-fold machines for the production of lithium ion pouch cells, lithium polymer pouch cells, lithium prismatic cells, and/or the like.
H01M 50/403 - Manufacturing processes of separators, membranes or diaphragms
H01M 50/414 - Synthetic resins, e.g. .thermoplastics or thermosetting resins
H01M 10/0583 - Construction or manufacture of accumulators with folded construction elements except wound ones, i.e. folded positive or negative electrodes or separators, e.g. with ‘’Z’’-shaped electrodes or separators
H01M 50/14 - Primary casingsJackets or wrappings for protecting against damage caused by external factors
H01M 10/48 - Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
This application is directed to new and/or improved MD and/or TD stretched and optionally calendered membranes, separators, base films, microporous membranes, battery separators including said separator, base film or membrane, batteries including said separator, and/or methods for making and/or using such membranes, separators, base films, microporous membranes, battery separators and/or batteries. For example, new and/or improved methods for making microporous membranes, and battery separators including the same, that have a better balance of desirable properties than prior microporous membranes and battery separators. The methods disclosed herein comprise the following steps: 1.) obtaining a non-porous membrane precursor; 2.) forming a porous biaxially-stretched membrane precursor from the non-porous membrane precursor; 3.) performing at least one of (a) calendering, (b) an additional machine direction (MD) stretching, (c) an additional transverse direction (TD) stretching, and (d) a pore-filling on the porous biaxially stretched precursor to form the final microporous membrane. The microporous membranes or battery separators described herein may have the following desirable balance of properties, prior to application of any coating: a TD tensile strength greater than 200 or 250 kg/cm2, a puncture strength greater than 200, 250, 300, or 400 gf, and a JIS Gurley greater than 20 or 50 s.
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
Improved battery separators, base films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of making and/or using such separators, films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of enhancing battery or cell charge rates, charge capacity, and/or discharge rates, and/or methods of improving batteries, systems including such batteries, vehicles including such batteries and/or systems, and/or the like; biaxially oriented porous membranes, composites including biaxially oriented porous membranes, biaxially oriented microporous membranes, biaxially oriented macroporous membranes, battery separators with improved charge capacities and the related methods and methods of manufacture, methods of use, and the like; flat sheet membranes, liquid retention media; dry process separators; biaxially stretched separators; dry process biaxially stretched separators having a thickness range between about 5 μm and 50 μm, preferably between about 10 μm and 25 μm, having improved strength, high porosity, and unexpectedly and/or surprisingly high charge capacity, such as, for example, high 10 C rate charge capacity; separators or membranes with high charge capacity and high porosity, excellent charge rate and/or charge capacity performance in a rechargeable and/or secondary lithium battery, such as a lithium ion battery, for high power and/or high energy applications, cells, devices, systems, and/or vehicles, and/or the like; single or multiple ply or layer separators, monolayer separators, trilayer separators, composite separators, laminated separators, co-extruded separators, coated separators, 1 C or higher separators, at least 1 C separators, batteries, cells, systems, devices, vehicles, and/or the like; improved microporous battery separators for secondary lithium batteries, improved microporous battery separators with enhanced or high charge (C) rates, discharge (C) rates, and/or enhanced or high charge capacities in or for secondary lithium batteries, and/or related methods of manufacture, use, and/or the like, and/or combinations thereof are disclosed or provided.
A dry-process microporous membrane for filtration, wherein at least one layer of the membrane has an average pore size less than 0.035 microns, preferably between about 0.010 microns to about 0.020 microns, and a thickness less than 14 microns. The membrane may be used in an ultra-filtration or nano-filtration process. The membrane exhibits high dimensional stability.
Coating compositions for porous substrates, and/or related methods including methods of manufacture and/or of use thereof are disclosed. Also, coating compositions for porous substrates, where the coating comprises at least a polymeric binder and heat-resistant particles with or without additional additives, materials or components are disclosed. Further, coating compositions for porous substrates which comprise at least (i) a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, and a thickener, and coated porous substrates, including battery separators, where the coating composition comprises at least (i) a polymeric binder, (ii) heat-resistant particles, and (iii) at least one component selected from the group consisting of a cross-linker, a low-temperature shutdown agent, an adhesion agent, a thickener, a friction-reducing agent, a high-temperature shutdown agent are disclosed.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 50/414 - Synthetic resins, e.g. .thermoplastics or thermosetting resins
H01M 50/457 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
In one aspect, a method of measuring the internal short resistance of a battery separator comprising one or more layers of a polyolefin is provided. A method comprises applying a force via a force component comprising a ball to a test stack, the test stack comprising an anode, a separator, and a cathode, deforming the test stack until an electrical short occurs, and determining an ISR value for the separator, the value corresponding to an overall ISR, or at least in one of the MD, TD, or Z-direction.
H01M 50/569 - Constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals
H01M 50/586 - Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries inside the batteries, e.g. incorrect connections of electrodes
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
A lithium ion rechargeable battery comprises: a negative electrode adapted to give up electrons during discharge, a positive electrode adapted to gain electrons during discharge, a microporous separator sandwiched between said positive electrode and said negative electrode, an organic electrolyte being contained within said separator and being in electrochemical communication with said positive electrode and said negative electrode, and an oxidative barrier interposed between said separator and said positive electrode, and thereby preventing oxidation of said separator.
In one aspect, a battery separator comprises a microporous membrane having one or more layers of a polyolefin, wherein the microporous membrane has an electrical resistance (ER) of less than 10 Ω/mm at a compression pressure of 1,000 lbs. In some embodiments, the microporous membrane has an electrical resistance of less than 25 Ω/mm at a compression pressure of 5,000 lbs, an electrical resistance of less than 37 Ω/mm at a compression pressure of 7,500 lbs, and/or an electrical resistance of less than 47 Ω/mm at a compression pressure of 10,000 lbs. In some embodiments, the microporous membrane exhibits a compression from about 5% to about 10% under a stress of 8 N/mm2, and wherein the microporous membrane exhibits an elastic recovery from 50% to 100%.
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/107 - Primary casingsJackets or wrappings characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
97.
LAMINATE MATERIAL AND DESICCANT BAGS COMPRISING THE SAME
A laminate material for use in desiccant packets or bags is disclosed herein. At least one layer of the laminate material is a dry-process porous polyolefin films. Another layer of the laminate may include or be a polyolefin membrane, a polyolefin net, or a polyolefin non-woven. The laminate material may exhibit one or more of the following properties: is non-dusting; is mold resistant; is mildew resistant; higher dimensional stability as indicated by a MD shrinkage less than 30% at 120°C and/or a TD shrinkage less than 15% at 120°C; chemically inert; high moisture vapor transmission rate (MVTR) as indicated by a value greater than or equal to 500 g/(m222O, when measured according to AATC 127; and heat sealability.
B32B 5/02 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments
Disclosed is a membrane with one or more dry-process porous layers that comprise (1) a polyolefin and (2) a product formed by reacting two components, which may be a compound with one or more carboxy groups and a compound with one or more epoxy groups. The product may be a reaction network, a three-dimensional reaction network, or a cross-linked network The resulting membrane has improved strength, reduced splittiness, or both improved strength and reduced splittiness. The membrane may be used in a battery, capacitor, HVAC, filtering device, or textile. Methods for making the membrane are also disclosed.
In one aspect, a wide microporous film comprises one or more layers comprising a polyolefin, wherein the microporous film has a width of at least 50 inches and comprises one or more non-porous regions. In some embodiments, the microporous film is at least 55 inches or at least 60 inches. Moreover, in some embodiments, the non-porous region is located along a creased region of the microporous film.
B32B 5/26 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by the presence of two or more layers which comprise fibres, filaments, granules, or powder, or are foamed or specifically porous one layer being a fibrous or filamentary layer another layer also being fibrous or filamentary
100.
SEPARATOR FOR ELECTRIC STORAGE DEVICE AND ELECTRIC STORAGE DEVICE
The present disclosure provides a separator for an electric storage device, which separator is capable of reducing clogging and has an excellent thermal stability, and an electric storage device using the same. The above-described separator for an electric storage device includes a microporous layer (A) and a microporous layer (B) that contain 70 wt% or more of polypropylene, and the area average major pore diameter in an ND-MD cross section of the microporous layer (B) is not more than 0.95 times the area average major pore diameter in an ND-MD cross section of the microporous layer (A). Alternatively, the separator for an electric storage device contains 70% by weight or more of a polyolefin, and the area average major pore diameter of a first porous surface (X) of the separator is not less than 1.05 times and not more than 10 times the area average major pore diameter of a second porous surface (Y) on the side opposite thereto.
H01M 50/449 - Separators, membranes or diaphragms characterised by the material having a layered structure
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
