A supported catalyst for hydroprocessing, hydrotreating or hydrocracking hydrocarbon feedstocks, the supported catalyst comprising at least one metal from Group 6 and at least one metal from Groups 8, 9, or 10 of the Periodic Table of the Elements, and optionally comprising phosphorous. The Group 6 metal comprises about 30 to about 45 wt. % and the total of Group 6 and Group 8, 9, or 10 or mixtures thereof metal components comprise about 35 to about 55 wt. %, calculated as oxides and based on the total weight of the catalyst composition. The metals, and phosphorous when present, are carried on and/or within a porous inorganic oxide carrier or support, the support prior to incorporation of the metals and phosphorus, having a total pore volume (TPV) of about 0.8 cc/g to about 1.5 cc/g and comprising a defined pore size distribution and wherein the supported catalyst comprises a defined pore size distribution.
C10G 49/04 - Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups , , , , or characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
A method of producing a support, and supported catalyst, the method comprising: (a) combining a porous inorganic oxide catalyst carrier or carrier extrudate with an aqueous solution, dispersion or suspension comprising: (i) a boron-containing source; and (ii) an organic compound or organic chelating agent selected from organic compounds comprising at least two oxygen atoms and 2-10 carbon atoms; (b) calcining the composition (a) to reduce its Loss on Ignition (LOI) volatiles content to greater than 0 wt % to less than about 5 wt %; (c) impregnating the calcined composition an aqueous composition comprising at least one each of a Group VIB and Group VIIIB metal-containing source; and (d) calcining, to reduce its LOI volatiles content greater than 0 wt % to less than about 30 wt %; wherein the boron content of a supported catalyst is in the range of about 1 wt % to about 13 wt B2O3 based on the total weight of the catalyst.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
(1) Catalysts for chemical processes; catalysts for petroleum refining and refining of biofeeds; Chemicals, namely silicas, aluminas and zeolites used as carriers for hydroprocessing catalysts used in refining crude oils and biofeeds in the manufacturing of renewable fuels; Hydrotreating catalyst used in refining crude oil and biofeeds; hydrogenation catalysts for use in the chemical process industry; chemicals, namely, metal tolerance, deoxygenation, desulfurization and denitrogenation; catalysts for isomerization; chemicals for use in industry, namely, catalysts for biofuel production
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
Catalysts for chemical processes; catalysts for petroleum refining and refining of biofeeds; Chemicals, namely, silicas, aluminas and zeolites used as carriers for hydroprocessing catalysts used in refining crude oils and biofeeds in the manufacturing of renewable fuels; Hydrotreating catalyst used in refining crude oil and biofeeds; hydrogenation catalysts for use in the chemical process industry; chemicals, namely, metal tolerance, deoxygenation, desulfurization and denitrogenation; catalysts for isomerization; chemicals for use in industry, namely, catalysts for biofuel production.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
Catalysts for chemical processes; catalysts for petroleum refining and refining of biofeeds; Chemicals, namely, silicas, aluminas and zeolites used as carriers for hydroprocessing catalysts used in refining crude oils and biofeeds in the manufacturing of renewable fuels; Hydrotreating catalyst used in refining crude oil and biofeeds; hydrogenation catalysts for use in the chemical process industry; chemicals, namely, metal tolerance, deoxygenation, desulfurization and denitrogenation; catalysts for isomerization; chemicals for use in industry, namely, catalysts for biofuel production
6.
HIGH ACTIVITY HYDROTREATING CATALYSTS AND PROCESSES USING SAME
A supported catalyst for hydroprocessing, hydrotreating or hydrocracking hydrocarbon feedstocks, the supported catalyst comprising at least one metal from Group 6 and at least one metal from Groups 8, 9, or 10 of the Periodic Table of the Elements, and optionally comprising phosphorous. The Group 6 metal comprises about 30 to about 45 wt.% and the total of Group 6 and Group 8, 9, or 10 or mixtures thereof metal components comprise about 35 to about 55 wt.%, calculated as oxides and based on the total weight of the catalyst composition. The metals, and phosphorous when present, are carried on and/or within a porous inorganic oxide carrier or support, the support prior to incorporation of the metals and phosphorus, having a total pore volume (TPV) of about 0.8 cc/g to about 1.5 cc/g and comprising a defined pore size distribution and wherein the supported catalyst comprises a defined pore size distribution.
A supported catalyst for hydroprocessing, hydrotreating or hydrocracking hydrocarbon feedstocks, the supported catalyst comprising at least one metal from Group 6 and at least one metal from Groups 8, 9, or 10 of the Periodic Table of the Elements, and optionally comprising phosphorous. The Group 6 metal comprises about 30 to about 45 wt.% and the total of Group 6 and Group 8, 9, or 10 or mixtures thereof metal components comprise about 35 to about 55 wt.%, calculated as oxides and based on the total weight of the catalyst composition. The metals, and phosphorous when present, are carried on and/or within a porous inorganic oxide carrier or support, the support prior to incorporation of the metals and phosphorus, having a total pore volume (TPV) of about 0.8 cc/g to about 1.5 cc/g and comprising a defined pore size distribution and wherein the supported catalyst comprises a defined pore size distribution.
A method of producing a support, and supported catalyst, the method comprising: (a) combining a porous inorganic oxide catalyst carrier or carrier extrudate with an aqueous solution, dispersion or suspension comprising: (i) a boron-containing source; and (ii) an organic compound or organic chelating agent selected from organic compounds comprising at least two oxygen atoms and 2-10 carbon atoms; (b) calcining the composition (a) to reduce its Loss on Ignition (LOI) volatiles content to greater than 0 wt% to less than about 5 wt%; (c) impregnating the calcined composition an aqueous composition comprising at least one each of a Group VIB and Group VIIIB metal-containing source; and (d) calcining, to reduce its LOI volatiles content greater than 0 wt% to less than about 30 wt%; wherein the boron content of a supported catalyst is in the range of about 1 wt% to about 13 wt B2O3 based on the total weight of the catalyst.
A method of producing a support, and supported catalyst, the method comprising: (a) combining a porous inorganic oxide catalyst carrier or carrier extrudate with an aqueous solution, dispersion or suspension comprising: (i) a boron-containing source; and (ii) an organic compound or organic chelating agent selected from organic compounds comprising at least two oxygen atoms and 2-10 carbon atoms; (b) calcining the composition (a) to reduce its Loss on Ignition (LOI) volatiles content to greater than 0 wt% to less than about 5 wt%; (c) impregnating the calcined composition an aqueous composition comprising at least one each of a Group VIB and Group VIIIB metal-containing source; and (d) calcining, to reduce its LOI volatiles content greater than 0 wt% to less than about 30 wt%; wherein the boron content of a supported catalyst is in the range of about 1 wt% to about 13 wt B2O3 based on the total weight of the catalyst.
Alumina support compositions comprising at least 0.1 wt % of silica are disclosed. The alumina support are characterized by a pore volume of greater than 0.60 cc/g, a median pore size ranging from about 70 to about 120, a pore size distribution such that at least 90% of the total pore volume falls within the range of about 20 to about 250, and a pore size distribution width of no less than about 40. Alumina compositions of the present invention exhibit a primary peak mode at a pore diameter less than the median pore diameter. Also provided are catalysts made from the alumina supports, and processes of preparing and using the supports and catalysts.
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
B01J 35/10 - Solids characterised by their surface properties or porosity
B01J 37/02 - Impregnation, coating or precipitation
C10G 45/12 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
11.
Hydroprocessing catalyst for the reduction of metals and sulfur in heavy feeds
A catalyst comprising a carrier and a metals component impregnated in the carrier, the carrier comprising alumina; and the metals component comprising a first metals fraction and a second metals fraction, the first metals fraction comprising at least one metal selected from chromium, molybdenum, or tungsten, and the second metals fraction comprising at least two metals selected from cobalt, rhodium, iridium, nickel, palladium, or platinum, wherein the catalyst has a first pore volume of 0.28 to 0.45 mL/g for pores having a pore diameter of 12 nm to less than 16 nm, and a second pore volume of 0.15 to 0.28 mL/g for pores of 2.0 nm to less than 12.0 nm.
B01J 23/84 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
A catalyst comprising a carrier and a metals component impregnated in the carrier, the carrier comprising alumina; and the metals component comprising a first metals fraction and a second metals fraction, the first metals fraction comprising at least one metal selected from chromium, molybdenum, or tungsten, and the second metals fraction comprising at least two metals selected from cobalt, rhodium, iridium, nickel, palladium, or platinum, wherein the catalyst has a first pore volume of 0.28 to 0.45 mL/g for pores having a pore diameter of 12 nm to less than 16 nm, and a second pore volume of 0.15 to 0.28 mL/g for pores of 2.0 nm to less than 12.0 nm.
Spheroidal catalyst support, supported catalyst, and method of preparing and using the catalyst for hydrodemetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 30% percent of their pore volume in pores having a diameter of between 200 and 500 Å. Catalysts prepared from the supports contain Group 6, 9 and 10 metals or metal compounds supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydrotreating process. The catalysts also provide increased sulfur and MCR conversion during a hydrotreating process.
B01J 35/10 - Solids characterised by their surface properties or porosity
B01J 37/02 - Impregnation, coating or precipitation
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks is prepared, the catalyst comprising a metal from Group 6 of the Periodic Table, a metal from Groups 8, 9 or 10 and optionally phosphorous, wherein the metals, and phosphorous when present, are carried on a foraminous carrier or support, the carrier or support, preferably comprises porous alumina having a total pore volume (TPV) of about 0.6 cc/g to about 1.1 cc/g and comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (Å); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 (Å) to less than about 1000 Å; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 Å; and (d) a pore mode equal to or greater than about 90 Å and less than about 160 Å. Preferably the support exhibits a d50 greater than about 100 Å and less than about 150 Å.
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
B01J 37/02 - Impregnation, coating or precipitation
C10G 45/10 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
C10G 47/14 - Inorganic carriers the catalyst containing platinum group metals or compounds thereof
C10G 65/12 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
C10G 65/00 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only
C10G 47/10 - Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
Improved supported hydroprocessing catalysts, and their method of preparation useful for the hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) of a petroleum feedstock, including a residuum hydrocarbon feedstock are disclosed. The Catalysts contain at least one Groups VIB metal component, at least one Group VIII metal component, and a phosphorus component, supported on a foraminous support such as alumina. The supported catalysts are characterized by a specific combination of properties, namely, the Group VIII metal to Phosphorous molar ratio, the Group VIII metal to Group VIB metal molar ratio, the phosphorous component to Group VIB component molar ratio and the median pore diameter. The resulting catalysts exhibit enhanced HDN without sacrificing to any significant degree the HDS activity.
C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
C10G 45/50 - Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metal, or compounds thereof
Improved supported hydroprocessing catalysts, and their method of preparation useful for the hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) of a petroleum feedstock, including a residuum hydrocarbon feedstock are disclosed. The Catalysts contain at least one Groups VIB metal component, at least one Group VIII metal component, and a phosphorus component, supported on a foraminous support such as alumina. The supported catalysts are characterized by a specific combination of properties, namely, the Group VIII metal to Phosphorous molar ratio, the Group VIII metal to Group VIB metal molar ratio, the phosphorous component to Group VIB component molar ratio and the median pore diameter. The resulting catalysts exhibit enhanced HDN without sacrificing to any significant degree the HDS activity.
C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
C10G 45/50 - Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metal, or compounds thereof
Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 Å and 130 Å and less than 2% in pores having a diameter above 1000 Å. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.
B01J 35/10 - Solids characterised by their surface properties or porosity
B01J 37/00 - Processes, in general, for preparing catalystsProcesses, in general, for activation of catalysts
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 Å and 130 Å and less than 2% in pores having a diameter above 1000 Å. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.
B01J 35/10 - Solids characterised by their surface properties or porosity
B01J 37/00 - Processes, in general, for preparing catalystsProcesses, in general, for activation of catalysts
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
A chelated hydroprocessing catalyst exhibiting low moisture is obtained by heating an impregnated, calcined carrier to a temperature higher than 200° C. and less than a temperature and for a period of time that would cause substantial decomposition of the chelating agent.
B01J 37/02 - Impregnation, coating or precipitation
B01J 31/34 - Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups of chromium, molybdenum or tungsten
C10G 45/10 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise precipitated alumina prepared by a low temperature pH swing process. A large portion of the pore volume of the catalyst supports has pores with a diameter in the range of about 200 Å to about 500 Å. Catalysts prepared from the supports of the invention exhibit improved catalytic activity and stability to remove metals from heavy hydrocarbon feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion during the hydroconversion process.
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise alumina and 5 wt % or less titania. Catalyst prepared from the supports have at least 30 to 80 volume percent of its pore volume in pores having a diameter of between 200 and 500 angstroms. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion.
C10G 45/10 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
B01J 21/06 - Silicon, titanium, zirconium or hafniumOxides or hydroxides thereof
B01J 35/10 - Solids characterised by their surface properties or porosity
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
C10G 45/06 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
This disclosure relates to supported multi-metallic catalysts for use in the hydrotreating of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIB metal, at least one Group VIII metal and an organic acid. The catalyst precursor is thermally treated to partially decompose the organic acid, then sulfided. The catalysts have a high carbon-as-carboxyl to total carbon ratio (C carboxy /C total ) as a result of a unique post-metal calcination method employed during the manufacture of the catalyst. As a result, the hydrotreating catalysts have lower percent weight loss-on-ignition, higher activity and longer catalyst life.
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
C10G 45/12 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
23.
Method of preparing high activity hydrotreating catalysts
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
total) as a result of a unique post-metal calcination method employed during the manufacture of the catalyst. As a result, the hydrotreating catalysts have lower percent weight loss-on-ignition, higher activity and longer catalyst life.
B01J 23/00 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group
B01J 31/28 - Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups of the platinum group metals, iron group metals or copper
B01J 31/02 - Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
B01J 23/00 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
This disclosure relates to supported multi-metallic catalysts for use in the hydrotreating of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIB metal, at least one Group VIII metal and an organic acid. The catalyst precursor is thermally treated to partially decompose the organic acid, then sulfided. The catalysts have a high carbon-as-carboxyl to total carbon ratio (Ccarboxy/Ctotal) as a result of a unique post-metal calcination method employed during the manufacture of the catalyst. As a result, the hydrotreating catalysts have lower percent weight loss-on-ignition, higher activity and longer catalyst life.
B01J 31/04 - Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
Spheroidal catalyst support, supported catalyst, and method of preparing and using the catalyst for hydrodemetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 30% percent of their pore volume in pores having a diameter of between 200 and 500 Å. Catalysts prepared from the supports contain Group 6, 9 and 10 metals or metal compounds supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydrotreating process. The catalysts also provide increased sulfur and MCR conversion during a hydrotreating process.
B01J 35/10 - Solids characterised by their surface properties or porosity
B01J 37/02 - Impregnation, coating or precipitation
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks is prepared, the catalyst comprising a metal from Group 6 of the Periodic Table, a metal from Groups 8, 9 or 10 and optionally phosphorous, wherein the metals, and phosphorous when present, are carried on a foraminous carrier or support, the carrier or support, preferably comprises porous alumina having a total pore volume (TPV) of about 0.6 cc/g to about 1.1 cc/g and comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (Å); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 (Å) to less than about 1000 Å; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 Å; and (d) a pore mode equal to or greater than about 90 Å and less than about 160 Å. Preferably the support exhibits a d50 greater than about 100 Å and less than about 150 Å.
C10G 45/10 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
C10G 47/14 - Inorganic carriers the catalyst containing platinum group metals or compounds thereof
C10G 65/12 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 and 130 and less than 2% in pores having a diameter above 1000. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.
B01J 35/10 - Solids characterised by their surface properties or porosity
B01J 37/00 - Processes, in general, for preparing catalystsProcesses, in general, for activation of catalysts
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
A chelated hydroprocessing catalyst exhibiting low moisture is obtained by heating an impregnated, calcined carrier to a temperature higher than 200° C. and less than a temperature and for a period of time that would cause substantial decomposition of the chelating agent.
B01J 31/34 - Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups of chromium, molybdenum or tungsten
B01J 37/02 - Impregnation, coating or precipitation
C10G 45/10 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
31.
Silica containing alumina supports, catalysts made therefrom and processes using the same
Alumina support compositions comprising at least 0.1 wt % of silica are disclosed. The alumina support are characterized by a pore volume of greater than 0.60 cc/g, a median pore size ranging from about 70 to about 120, a pore size distribution such that at least 90% of the total pore volume falls within the range of about 20 to about 250, and a pore size distribution width of no less than about 40. Alumina compositions of the present invention exhibit a primary peak mode at a pore diameter less than the median pore diameter. Also provided are catalysts made from the alumina supports, and processes of preparing and using the supports and catalysts.
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
B01J 35/10 - Solids characterised by their surface properties or porosity
B01J 37/02 - Impregnation, coating or precipitation
C10G 45/12 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise precipitated alumina prepared by a low temperature pH swing process. A large portion of the pore volume of the catalyst supports has pores with a diameter in the range of about 200 to about 500. Catalysts prepared from the supports of the invention exhibit improved catalytic activity and stability to remove metals from heavy hydrocarbon feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion during the hydroconversion process.
Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise precipitated alumina prepared by a low temperature pH swing process. A large portion of the pore volume of the catalyst supports has pores with a diameter in the range of about 200 to about 500. Catalysts prepared from the supports of the invention exhibit improved catalytic activity and stability to remove metals from heavy hydrocarbon feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion during the hydroconversion process.
Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise precipitated alumina prepared by a low temperature pH swing process. A large portion of the pore volume of the catalyst supports has pores with a diameter in the range of about 200 Å to about 500 Å. Catalysts prepared from the supports of the invention exhibit improved catalytic activity and stability to remove metals from heavy hydrocarbon feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion during the hydroconversion process.
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
C10G 45/08 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A.
B01J 35/10 - Solids characterised by their surface properties or porosity
C10G 45/10 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
C10G 47/14 - Inorganic carriers the catalyst containing platinum group metals or compounds thereof
C10G 65/12 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 and 130 and less than 2% in pores having a diameter above 1000. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.
Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 and 130 and less than 2% in pores having a diameter above 1000. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.
B01J 37/00 - Processes, in general, for preparing catalystsProcesses, in general, for activation of catalysts
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise alumina and 5 wt% or less titania. Catalyst prepared from the supports have at least 30 to 80 volume percent of its pore volume in pores having a diameter of between 200 and 500 angstroms. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion.
Catalyst supports, supported catalysts, and a method of preparing and using the catalysts for the demetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise alumina and 5 wt% or less titania. Catalyst prepared from the supports have at least 30 to 80 volume percent of its pore volume in pores having a diameter of between 200 and 500 angstroms. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydroconversion process. The catalysts also exhibit increased sulfur and MCR conversion.
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
Spheroidal catalyst support, supported catalyst, and method of preparing and using the catalyst for hydrodemetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise titania alumina having 5 wt% or less titania and have greater than 30% percent of their pore volume in pores having a diameter of between 200 and 500. Catalysts prepared from the supports contain Group 6, 9 and 10 metals or metal compounds supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydrotreating process. The catalysts also provide increased sulfur and MCR conversion during a hydrotreating process.
C10G 45/04 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used
Spheroidal catalyst support, supported catalyst, and method of preparing and using the catalyst for hydrodemetallation of metal-containing heavy oil feedstocks are disclosed. The catalyst supports comprise titania alumina having 5 wt% or less titania and have greater than 30% percent of their pore volume in pores having a diameter of between 200 and 500. Catalysts prepared from the supports contain Group 6, 9 and 10 metals or metal compounds supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved catalytic activity and stability to remove metals from heavy feedstocks during a hydrotreating process. The catalysts also provide increased sulfur and MCR conversion during a hydrotreating process.
Alumina support compositions comprising at least 0.1 wt % of silica are disclosed. The alumina support are characterized by a pore volume of greater than 0.60 cc/g, a median pore size ranging from about 70 to about 120, a pore size distribution such that at least 90% of the total pore volume falls within the range of about 20 to about 250, and a pore size distribution width of no less than about 40. Alumina compositions of the present invention exhibit a primary peak mode at a pore diameter less than the median pore diameter. Also provided are catalysts made from the alumina supports, and processes of preparing and using the supports and catalysts.
C10G 45/12 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
43.
SILICA CONTAINING ALUMINA SUPPORTS, CATALYSTS MADE THEREFROM AND PROCESSES USING THE SAME
Alumina support compositions comprising at least 0.1 wt % of silica are disclosed. The alumina support are characterized by a pore volume of greater than 0.60 cc/g, a median pore size ranging from about 70 to about 120, a pore size distribution such that at least 90% of the total pore volume falls within the range of about 20 to about 250, and a pore size distribution width of no less than about 40. Alumina compositions of the present invention exhibit a primary peak mode at a pore diameter less than the median pore diameter. Also provided are catalysts made from the alumina supports, and processes of preparing and using the supports and catalysts.
B01J 20/00 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof
A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78 % to about 95 % of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2 % to less than about 19 % of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3 % to less than 12 % of the TPV in pores having a diameter equal to or greater than about 1000 A.
A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78 % to about 95 % of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2 % to less than about 19 % of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3 % to less than 12 % of the TPV in pores having a diameter equal to or greater than about 1000 A.
A chelated hydroprocessing catalyst exhibiting low moisture is obtained by hearing an impregnated, calcined carrier to a temperature higher than 200° C. and less than a temperature and for a period of time that would cause substantial decomposition of the chelating agent.
01 - Chemical and biological materials for industrial, scientific and agricultural use
40 - Treatment of materials; recycling, air and water treatment,
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemical catalysts used in the petroleum and refining industries; Chemicals, namely, hydroprocessing and hydrotreating catalysts for use in the petroleum and refining industries [ Providing technical information in the field of petroleum refining ] [ Providing research information and related research consultation in the field of chemicals and chemical catalysts via the Internet; Chemical analysis and research services ]
49.
Hydroconversion catalysts and methods of making and using same
Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks. High conversion can be achieved at reduced levels of sediment, especially in comparison to standard commercial catalysts.
C10G 47/02 - Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, to obtain lower boiling fractions characterised by the catalyst used
C10G 45/00 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
A chelated hydroprocessing catalyst exhibiting low moisture is obtained by heating an impregnated, calcined carrier to a temperature higher than 200 °C and less than a temperature and for a period of time that would cause substantial decomposition of the chelating agent.
A chelated hydroprocessing catalyst exhibiting low moisture is obtained by heating an impregnated, calcined carrier to a temperature higher than 200 °C and less than a temperature and for a period of time that would cause substantial decomposition of the chelating agent.
01 - Chemical and biological materials for industrial, scientific and agricultural use
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemicals for use in science and industry; chemical catalysts used in the petroleum and refining industries; hydroprocessing and hydrotreating catalysts for use in the petroleum and refining industries. Providing consultation, technical assistance and information in the field of chemicals and chemical catalysts; chemical analysis and research services; providing technical information in the field of chemicals, catalysts and the petroleum refining industry via the Internet.
53.
HYDROCONVERSION CATALYSTS AND METHODS OF MAKING AND USING SAME
Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at low concentration, provided that the Group VIII metal is in a substantially water?insoluble form and a particular sequence of addition of the components is followed, even when a substantially water insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water?soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks. High conversion can be achieved at reduced levels of sediment, especially in comparison to standard commercial catalysts.
01 - Chemical and biological materials for industrial, scientific and agricultural use
42 - Scientific, technological and industrial services, research and design
Goods & Services
(1) Chemical catalysts used in the petroleum and refining industries; chemicals, namely, hydroprocessing and hydrotreating catalysts for use in the petroleum and refining industries. (1) Providing consultation, technical assistance and information in the field of chemicals and chemical catalysts; chemical analysis and research services; providing technical information in the field of chemicals, catalysts and the petroleum refining industry via the Internet.
01 - Chemical and biological materials for industrial, scientific and agricultural use
42 - Scientific, technological and industrial services, research and design
Goods & Services
(1) Chemical catalysts used in the petroleum and refining industries; chemicals, namely hydroprocessing and hydrotreating catalysts for use in the petroleum and refining industries. (1) Providing consultation, technical assistance and information in the field of chemicals and chemical catalysts; chemical analysis and research services; providing technical information in the field of chemicals, catalysts and the petroleum refining industry via the Internet.
01 - Chemical and biological materials for industrial, scientific and agricultural use
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemicals for use in science and industry; chemical catalysts used in the petroleum and refining industries; hydroprocessing and hydrotreating catalysts for use in the petroleum and refining industries. Providing consultation, technical assistance and information in the field of chemicals and chemical catalysts; chemical analysis and research services; providing technical information in the field of chemicals, catalysts and the petroleum refining industry via the Internet.
01 - Chemical and biological materials for industrial, scientific and agricultural use
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemical catalysts used in the petroleum and refining industries; chemicals, namely, hydroprocessing and hydrotreating catalysts for use in the petroleum and refining industries Providing consultation, technical assistance and information in the field of chemicals and chemical catalysts; chemical analysis and research services; providing technical information in the field of chemicals, catalysts and the petroleum refining industry via the internet
01 - Chemical and biological materials for industrial, scientific and agricultural use
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemical catalysts used in the petroleum and refining industries; chemicals, namely, hydroprocessing and hydrotreating catalysts for use in the petroleum and refining industries Providing information, technical assistance and information in the field of chemicals and chemical catalysts; chemical analysis and research services; providing technical information in the field of chemicals, catalysts and the petroleum refining industry via the internet
01 - Chemical and biological materials for industrial, scientific and agricultural use
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemical catalysts used in the petroleum and refining industries; chemicals, namely, hydroprocessing and hydrotreating catalysts for use in the petroleum and refining industries Providing consultation, technical assistance and information in the field of chemicals and chemical catalysts; chemical analysis and research services; providing technical information in the field of chemicals, catalysts and the petroleum refining industry via the internet
