A lightweight radiation shielding material. A carbon nanotube forest is embedded in a matrix comprising nanoparticulates, such as nanoparticles, carbon nanotubes, or graphene nanosheets. The nanoparticulates can be low atomic number (low-Z) or high atomic number (high-Z). The matrix can be a solidified polymer, epoxy, resin, or ceramic precursor, for example silicon carbide. The radiation shield can shield an object from radio frequency interference (RFI), lightning, electromagnetic interference (EMI), an electromagnetic pulse (EMP), gamma rays, X-rays, neutrons, and/or protons. The nanoforest is disposed on a conductive base with sufficient in-plane electrical conductivity to provide an effective conductive path for currents induced by radiation absorption. The base can be a second nanoforest comprising horizontally-oriented carbon nanotubes, which makes the shield particularly lightweight, as low as 10% of the mass of aluminum that provides equivalent shielding. The base can be adhered to an object to be shielded.
Methods and apparatuses for continuous, large scale, commercially viable production of nanoforests. A roll-to-roll process passes a flexible substrate, including fibers and fabrics, through a furnace. Precursors are introduced in a growth zone in which a vertical or horizontal nanoforest of nanotubes or nanowires is grown on the substrate. Sensors and actuators with feedback control are provided for parameters such as substrate speed, substrate tension, furnace temperature, precursor flow rate, nanoforest thickness, and nanoforest. The furnace is preferably enclosed for environmental and safety purposes. The feed roll and take-up roll are disposed in housings can be attached to the furnace via airlocks, which enables rapid loading and unloading of the rolls using techniques well known in the industry while maintaining furnace conditions. The furnace can encompass flattening rollers and a second growth zone to enable manufacture of orthogonal nanoforests comprising a vertical nanoforest grown on a horizontal nanoforest.
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
C23C 16/54 - Apparatus specially adapted for continuous coating
F27B 9/24 - Furnaces through which the charge is moved mechanically, e.g. of tunnel type Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatmentFurnaces through which the charge is moved mechanically, e.g. of tunnel type Similar furnaces in which the charge moves by gravity characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path being carried by a conveyor
Methods and apparatuses for continuous, large scale, commercially viable production of nanoforests. A roll-to-roll process passes a flexible substrate, including fibers and fabrics, through a furnace. Precursors are introduced in a growth zone in which a vertical or horizontal nanoforest of nanotubes or nanowires is grown on the substrate. Sensors and actuators with feedback control are provided for parameters such as substrate speed, substrate tension, furnace temperature, precursor flow rate, nanoforest thickness, and nanoforest. The furnace is preferably enclosed for environmental and safety purposes. The feed roll and take-up roll are disposed in housings can be attached to the furnace via airlocks, which enables rapid loading and unloading of the rolls using techniques well known in the industry while maintaining furnace conditions. The furnace can encompass flattening rollers and a second growth zone to enable manufacture of orthogonal nanoforests comprising a vertical nanoforest grown on a horizontal nanoforest.
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
C23C 16/54 - Apparatus specially adapted for continuous coating
F27B 9/24 - Furnaces through which the charge is moved mechanically, e.g. of tunnel type Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatmentFurnaces through which the charge is moved mechanically, e.g. of tunnel type Similar furnaces in which the charge moves by gravity characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path being carried by a conveyor
4.
ORTHOGONAL CARBON-NANOTUBE-BASED NANOFOREST FOR HIGH-PERFORMANCE HIERARCHICAL MULTIFUNCTIONAL NANOCOMPOSITES
A reinforcement for increasing the strength and toughness and other properties in both transverse and in-piano directions for a composite material, and methods of manufacture therefor. The reinforcement has a layer of a nanoforest of vertical nanotubes or nanowires and a layer of horizontal nanotubes or nanowires. The reinforcement can be made by rolling a vertical nanoforest to produce a collapsed layer of horizontal nanofubes or nanowires, then growing a vertical nanoforest on the collapsed layer. The reinforcement can be grown directly on fibers which are used to reinforce the composite material, or alternatively Interleaved with layers of those fibers before the composite part is cured. The reinforcement and manufacturing method are compatible with almost any composite material in any shape, including epoxy, polymer, or ceramic matrix composites, or any manufacturing method, including prepreg, wet-layup and matrix film stacking. The present invention reduces scrap, rework, and repair hours for composites manufacturing.
B32B 5/12 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments characterised by the relative arrangement of fibres or filaments of adjacent layers
B32B 5/26 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by the presence of two or more layers which comprise fibres, filaments, granules, or powder, or are foamed or specifically porous one layer being a fibrous or filamentary layer another layer also being fibrous or filamentary
B32B 1/00 - Layered products having a non-planar shape
B32B 7/02 - Physical, chemical or physicochemical properties
A method of making a ceramic matrix composite (CMC) part such as armor, in which a mixture, including a preceramic polymer, particles such as ceramic microparticles and/or nanoparticles, and organic compounds such as a surfactant and a solvent, are mixed to form a paste and printed or molded. The part is then cured and densified by polymer infiltration and pyrolysis (PIP) using the preceramic polymer with a varying amount and size of ceramic particles and different temperatures in some of the cycles. The CMC can contain silicon carbide, boron carbide, boron suboxide, alumina, or any other ceramic. The process is compatible with sacrificial materials, enabling the creation of parts with hollow portions or overhangs. The mixture preferably has a high loading of particles, for example between 70 wt % and 90 wt % of the mixture, in order to minimize shrinkage. Curing and pyrolyzing the part can be performed by microwaving. Two such CMC parts can be joined together by using the paste, having the same or a different concentration of particles, as an adhesive.
C04B 35/563 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxides based on carbides based on boron carbide
C04B 35/626 - Preparing or treating the powders individually or as batches
C04B 35/565 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxides based on carbides based on silicon carbide
F41H 5/04 - Plate construction composed of more than one layer
Methods and apparatuses for continuous, large scale, commercially viable production of nanoforests. A roll-to-roll process passes a flexible substrate, including fibers and fabrics, through a furnace. Precursors are introduced in a growth zone in which a vertical or horizontal nanoforest of nanotubes or nanowires is grown on the substrate. Sensors and actuators with feedback control are provided for parameters such as substrate speed, substrate tension, furnace temperature, precursor flow rate, nanoforest thickness, and nanoforest. The furnace is preferably enclosed for environmental and safety purposes. The feed roll and take-up roll are disposed in housings can be attached to the furnace via airlocks, which enables rapid loading and unloading of the rolls using techniques well known in the industry while maintaining furnace conditions. The furnace can encompass flattening rollers and a second growth zone to enable manufacture of orthogonal nanoforests comprising a vertical nanoforest grown on a horizontal nanoforest.
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
A reinforcement for increasing the strength and toughness and other properties in both transverse and in-piano directions for a composite material, and methods of manufacture therefor. The reinforcement has a layer of a nanoforost of vertical nanotubes or nanowires and a layer of horizontal nanotubes or nanowires. The reinforcement can be made by rolling a vertical nanoforest to produce a collapsed layer of horizontal nanofubes or nanowires, then growing a vertical nanoforest on the collapsed layer. The reinforcement can be grown directly on fibers which are used to reinforce the composite material, or alternatively Interleaved with layers of those fibers before the composite part is cured. The reinforcement and manufacturing method are compatible with almost any composite material in any shape, including epoxy, polymer, or ceramic matrix composites, or any manufacturing method, including prepreg, wet-layup and matrix film stacking. The present invention reduces scrap, rework, and repair hours for composites manufacturing.
B32B 5/10 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments characterised by a fibrous layer reinforced with filaments
B32B 5/12 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments characterised by the relative arrangement of fibres or filaments of adjacent layers
A method of making a ceramic matrix composite (CMC) article by combining a preceramic polymer with one or more sized nanopowders and optional surfactants and/or solvents to form a mixture suitable for 3D printing, depositing the mixture on a mandrel, curing it to form a green body, and pyrolyzing the green body such thai the nanocrystalline surface of the CIVIC article has sufficiently the same surface roughness and figure accuracy of the mandrel to enable the CMC article to be used without further polishing. The mixture can be a paste or slurry that is self supporting and exhibit pseudoplastic rheology. The preceramic polymer is preferably a precursor to SiC, and the nanopowders preferably comprise SiC. The article can be densified by using polymer infiltration pyrolysis, with or without nanoparticies. The curing and pyrolysis of the article can be performed with microwave radiation. An example structure is a gradient density lattice with a mirror surface for use In a cryogenically cooled infrared optical system such as an orbiting space telescope.
A method of making a ceramic matrix composite (CMC) article by combining a preceramic polymer with one or more sized nanopowders and optional surfactants and/or solvents to form a mixture suitable for 3D printing, depositing the mixture on a mandrel, curing it to form a green body, and pyrolyzing the green body such that the nanocrystalline surface of the CMC article has sufficiently the same surface roughness and figure accuracy of the mandrel to enable the CMC article to be used without further polishing. The mixture can be a paste or slurry that is self supporting and exhibit pseudoplastic rheology. The preceramic polymer is preferably a precursor to SiC, and the nanopowders preferably comprise SiC. The article can be densified by using polymer infiltration pyrolysis, with or without nanoparticles. The curing and pyrolysis of the article can be performed with microwave radiation. An example structure is a gradient density lattice with a mirror surface for use in a cryogenically cooled infrared optical system such as an orbiting space telescope.
C04B 37/00 - Joining burned ceramic articles with other burned ceramic articles or other articles by heating
C04B 35/565 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxides based on carbides based on silicon carbide
C04B 35/573 - Fine ceramics obtained by reaction sintering
G02B 23/02 - Telescopes, e.g. binocularsPeriscopesInstruments for viewing the inside of hollow bodiesViewfindersOptical aiming or sighting devices involving prisms or mirrors
