Electrolytes and electrolyte additives for energy storage devices comprising crown ether based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a crown ether based compound.
Systems and methods for sulfur-containing chemicals as cathode additives for silicon-based lithium ion batteries may include a silicon-based anode, an electrolyte, and a cathode. The cathode may include an active material and a sulfur-containing additive. The cathode active material may include one or more of nickel cobalt aluminum oxide (NCA), nickel cobalt manganese oxide (NCM), lithium iron phosphate (LFP), lithium cobalt oxide (LCO), and lithium manganese oxide (LMO). The sulfur-containing additive may include elemental sulfur and/or Li2S. The sulfur-containing additive may include one or more of lithium polysulfides (Li2Sn, where n=2-8), polysulfides, and organic polysulfides. The sulfur-containing additive may include one or more of metal sulfides, transition metal polysulfide complexes, S-containing organic polymers or copolymer, polymeric sulfur, and transition metal sulfides. The sulfur-containing additive may include 5% or less by weight of the active material, or 1% or less by weight of the active material.
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
3.
FUNCTIONAL ALIPHATIC AND/OR AROMATIC AMINE COMPOUNDS OR DERIVATIVES AS ELECTROLYTE ADDITIVES TO REDUCE GAS GENERATION IN LI-ION BATTERIES
Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein functional aliphatic and/or aromatic amine compounds or derivatives are used as electrolyte additives to reduce gas generation in Li-ion batteries.
Systems and methods are provided for carbon additives for direct coating of silicon-dominant anodes. An example composition for use in directly coated anodes may include a silicon-dominated anode active material, a carbon-based binder, and a carbon-based additive, with the composition being configured for low-temperature pyrolysis. The low-temperature pyrolysis may be conducted at <600° C. An anode may be formed using a direct coating process of the composition on a current collector. The anode active material yields silicon constituting between 86% and 97% of weight of the formed anode after pyrolysis. The carbon-based additive yields carbon constituting between 2% and 6% of weight of the formed anode after pyrolysis.
Methods of forming electrochemical cells are described. In some embodiments, the method can include providing an electrochemical cell having an electrode with at least about 20% to about 99% by weight of silicon. The method can include providing a formation charge current at greater than about 1C to the electrochemical cell. Alternatively or additionally, the method can include providing a formation charge current at a substantially constant charge voltage to the electrochemical cell.
Electrolyte compositions comprising electrolyte additives and/or solvents for reduction of thermal propagation in lithium-ion batteries are disclosed. Energy storage devices comprising the electrolyte compositions comprise a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode may be a Si-based electrode, a separator between the first electrode and the second electrode, and the electrolyte composition.
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
H01M 10/658 - Means for temperature control structurally associated with the cells by thermal insulation or shielding
H01M 10/659 - Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
H01M 10/6595 - Means for temperature control structurally associated with the cells by chemical reactions other than electrochemical reactions of the cells, e.g. catalytic heaters or burners
7.
SILICON-BASED ENERGY STORAGE DEVICES WITH CYCLIC CARBONATE CONTAINING ELECTROLYTE ADDITIVES
A pouched energy storage device can include a cell housing portion and a sealed portion. The device can also include a stack of electrodes housed within an inner region of the cell housing portion. Each electrode can have dimensions of width, length, and thickness. One or more electrodes can have at least one of the dimensions smaller than a corresponding dimension of other electrodes in the stack of electrodes. The device can also include an indentation on the cell housing portion adjacent the sealed portion. The indentation can form a stepped region in the inner region that is complimentary to the one or more electrodes having at least one of the dimensions smaller than a corresponding dimension of other electrodes in the stack of electrodes. The sealed portion can be folded onto the cell housing portion so that at least a part of the sealed portion resides in the indentation.
In various embodiments, a method of forming an electrode includes providing a current collector, providing a substantially solid layer of electrode attachment substance on a side of the current collector, providing electrochemically active material adjacent the substantially solid layer of the electrode attachment substance, and adhering the electrochemically active material to the side of the current collector via the electrode attachment substance. In some examples, the electrochemically active material is provided in powder form. In some examples, the electrochemically active material is provided between the substantially solid layer of electrode attachment substance and the current collector.
An energy storage device comprising a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode comprises a self-supporting composite material film, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator, wherein the electrolyte comprises at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. The composite material film having greater than 0% and less than about 90% by weight of silicon particles, and greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases can be a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.
The disclosure herein pertains to a pressure regulation system for use in a silicon dominate anode lithium-ion cell. The pressure regulation system regulates a lifetime pressure on the lithium-ion cell in order to correct for capacity loss and mechanical failure due the expansion of silicon during operation. The pressure regulation system along with a housing maintains a certain pressure range on the lithium-ion cells during the cycling and the operational life of the energy storage device.
Systems and methods utilizing aqueous-based polymer binders for silicon-based anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from a silicon carbon composite or SiOx-based or Si- Carbon-SiOx-based powder and a water soluble polymer and may comprise one or more additional materials. The anode may be in a lithium ion battery.
Systems and methods utilizing aqueous-based polymer binders for silicon-dominant anodes containing pyrolyzed carbon may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a water soluble polymer and may comprise one or more additional materials. The electrode coating layer may include more than 70% silicon and the anode may be in a lithium ion battery.
Systems and methods utilizing aqueous-based polymer binders for silicon-based anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from a silicon carbon composite or SiOx-based or Si-Carbon-SiOx-based powder and a water soluble polymer and may comprise one or more additional materials. The anode may be in a lithium ion battery.
This disclosure describes safety-enhancement state-of-charge (SOC) reduction devices for propagation resistant lithium-ion batteries. The SOC reduction device is added between the electrodes of a lithium-ion cell. Before thermal runaway can occur, the SOC reduction device shorts the electrodes according to a trigger temperature.
This disclosure describes a battery device with one or more battery cells and an insulation layer that reduces and/or delays thermal propagation. The insulating layer may be hermetically sealed into the cell. The insulating layer may be thermally stable up to 1800° C. The insulating layer may have a thermal conductivity less than 1 W/(m·K). The insulating layer may comprise a ceramic material. For example, the insulating layer may comprise a porous ceramic paper that is saturated or coated with another material.
H01M 10/658 - Means for temperature control structurally associated with the cells by thermal insulation or shielding
H01M 10/659 - Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
H01M 10/6595 - Means for temperature control structurally associated with the cells by chemical reactions other than electrochemical reactions of the cells, e.g. catalytic heaters or burners
Electrolyte compositions comprising electrolyte additives and/or solvents for reduction of thermal propagation in lithium-ion batteries are disclosed. Energy storage devices comprising the electrolyte compositions comprise a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode may be a Si-based electrode, a separator between the first electrode and the second electrode, and the electrolyte composition.
Systems and methods for anisotropic expansion of silicon-dominant anodes may include forming an anode by pyrolyzing an active material layer comprising a binder and silicon particles in a temperature range of 600 to 800° C.; and forming a battery cell comprising a cathode, an electrolyte, and the anode, where the anode comprises the pyrolyzed active material layer on a current collector. A lateral expansion of the anode during operation may be less than 2%, less than 1%, or less than 0.6%. The active material layer may be pyrolyzed on the current collector or may be pyrolyzed on a substrate before laminating on the current collector. The anode active material layer may be pyrolyzed using a 1 hour dwell time or less or using a 2 hour dwell time or less. The active material layer may be pyrolyzed in a temperature range of 650 to 800° C.
This disclosure describes a battery device with one or more battery cells and an insulation layer that reduces and/or delays thermal propagation. The insulating layer may be hermetically sealed into the cell. The insulating layer may be thermally stable up to 1800° C. The insulating layer may have a thermal conductivity less than 1 W/(m·K). The insulating layer may comprise a ceramic material. For example, the insulating layer may comprise a porous ceramic paper that is saturated or coated with another material.
H01M 10/658 - Means for temperature control structurally associated with the cells by thermal insulation or shielding
H01M 10/659 - Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
H01M 10/6595 - Means for temperature control structurally associated with the cells by chemical reactions other than electrochemical reactions of the cells, e.g. catalytic heaters or burners
20.
SAFETY-ENHANCEMENT STATE-OF-CHARGE REDUCTION DEVICES FOR PROPAGATION RESISTANT LITHIUM-ION BATTERIES
This disclosure describes safety-enhancement state-of-charge (SOC) reduction devices for propagation resistant lithium-ion batteries. The SOC reduction device is added between the electrodes of a lithium-ion cell. Before thermal runaway can occur, the SOC reduction device shorts the electrodes according to a trigger temperature.
Electrolyte compositions comprising electrolyte additives and/or solvents for reduction of thermal propagation in lithium-ion batteries are disclosed. Energy storage devices comprising the electrolyte compositions comprise a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode may be a Si-based electrode, a separator between the first electrode and the second electrode, and the electrolyte composition.
This disclosure describes a battery device with one or more battery cells and an insulation layer that reduces and/or delays thermal propagation. The insulating layer may be hermetically sealed into the cell. The insulating layer may be thermally stable up to 1800°C. The insulating layer may have a thermal conductivity less than 1 W/(m·K). The insulating layer may comprise a ceramic material. For example, the insulating layer may comprise a porous ceramic paper that is saturated or coated with another material.
H01M 50/116 - Primary casingsJackets or wrappings characterised by the material
H01M 10/653 - Means for temperature control structurally associated with the cells characterised by electrically insulating or thermally conductive materials
H01M 10/658 - Means for temperature control structurally associated with the cells by thermal insulation or shielding
H01M 50/24 - MountingsSecondary casings or framesRacks, modules or packsSuspension devicesShock absorbersTransport or carrying devicesHolders characterised by physical properties of casings or racks, e.g. dimensions adapted for protecting batteries from their environment, e.g. from corrosion
23.
HIGH HEAT CAPACITY MATERIALS FOR IMPROVED SAFETY OF HIGH ENERGY DENSITY BATTERIES
This disclosure describes designs for improving the safety profile of a Li-ion, Na-ion or other electrochemical device. These designs improve heat capacity and reduce or delay the triggering of thermal runaway in addition to reducing the temperature rise during thermal runaway.
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
C09K 5/06 - Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice-versa
H01M 10/617 - Types of temperature control for achieving uniformity or desired distribution of temperature
H01M 10/653 - Means for temperature control structurally associated with the cells characterised by electrically insulating or thermally conductive materials
24.
HIGH HEAT CAPACITY MATERIALS FOR IMPROVED SAFETY OF HIGH ENERGY DENSITY BATTERIES
This disclosure describes designs for improving the safety profile of a Li-ion, Na-ion or other electrochemical device. These designs improve heat capacity and reduce or delay the triggering of thermal runaway in addition to reducing the temperature rise during thermal runaway.
H01M 10/659 - Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01M 10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
25.
SAFETY-ENHANCEMENT STATE-OF-CHARGE REDUCTION DEVICES FOR PROPAGATION RESISTANT LITHIUM-ION BATTERIES
This disclosure describes safety-enhancement state-of-charge (SOC) reduction devices for propagation resistant lithium-ion batteries. The SOC reduction device is added between the electrodes of a lithium-ion cell. Before thermal runaway can occur, the SOC reduction device shorts the electrodes according to a trigger temperature.
G01R 31/382 - Arrangements for monitoring battery or accumulator variables, e.g. SoC
G01R 31/392 - Determining battery ageing or deterioration, e.g. state of health
H01M 10/65 - Means for temperature control structurally associated with the cells
H01M 50/46 - Separators, membranes or diaphragms characterised by their combination with electrodes
H01M 50/489 - Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
H01M 50/581 - Devices or arrangements for the interruption of current in response to temperature
Methods of forming a composite material film can include providing a mixture comprising a carbon precursor and silicon particles. The methods can also include pyrolysing the carbon precursor to convert the precursor into one or more types of carbon phases to form the composite material film such that the precursor has a char yield of greater than about 0% to about 60% and the composite material film comprises the silicon particles at about 90% to about 99% by weight.
Systems and methods for all-conductive battery electrodes may include an electrode coating layer on a current collector, where the electrode coating layer comprises more than 50% silicon, and where each material in the electrode has a resistivity of less than 100 Ω-cm. The silicon may have a resistivity of less than 10 Ω-cm, less than 1 Ω-cm, or less than 1 mΩ-cm. The electrode coating layer may comprise pyrolyzed carbon and/or conductive additives. The current collector comprises a metal foil. The metal current collector may comprise one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer. The electrode coating layer comprises more than 70% silicon. The electrode may be in electrical and physical contact with an electrolyte. The electrolyte may comprise a liquid, solid, or gel. The battery electrode may be in a lithium ion battery.
Systems and methods utilizing aqueous-based polymer binders for silicon-dominant anodes containing pyrolyzed carbon may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a water soluble polymer and may comprise one or more additional materials. The electrode coating layer may include more than 70% silicon and the anode may be in a lithium ion battery.
Systems and methods are provided for high volume roll-to-roll direct coating of electrodes for silicon-dominant anode cells. A system for continuous roll-to-roll electrode processing may include one or more components configured for receiving a plurality of precursor composite rolls, with each precursor composite roll including a precursor composite film coated on a current collector, and a heat treatment oven configured for applying heat treatment concurrently to the plurality of precursor composite rolls, to convert the precursor composite film in each precursor composite roll into a pyrolyzed composite film on the current collector. The system is configured for processing the plurality of precursor composite rolls in a continuous manner.
A method of managing battery performance may include obtaining, via a measurement device, measurements of one or more parameters relating to one or more cells; generating or updating, based on the measurements, a machine learning model; and generating, using the machine learning model, cell performance prediction data for use in managing at least one cell. Each cell includes a cathode, a separator, and a silicon-dominant anode. The measurements of the one or more parameters correspond to a plurality of different types of data. The measurements include one or more of: measurements of cells or cell components before formation or cycling, measurements from formation cycles for one or more cells, measurements from a number of cycles after formation for one or more cells, and measurements of characteristics of cell components prior to cell assembly.
H01M 10/48 - Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
A clamping device for an electrochemical cell stack is provided. The clamping device can include a first plate and a second plate. The second plate can be positionable relative to the first plate such that a space between the first plate and the second plate can be sized to receive an electrochemical cell stack. The device also can include a coupling member coupling the first plate to the second plate. At least one of the first and second plates can be movable away from the other plate. The coupling member can have a first end portion and a second end portion. The device further can include an elastic member disposed between the first end portion and the second end portion.
Systems and methods for silicon dominant lithium-ion cells with controlled lithiation of silicon may include a cathode, an electrolyte, and an anode. The anode may include silicon lithiated at a level after discharge that is configured to be above a minimum threshold level, where the minimum threshold lithiation is 3% silicon lithiation. The lithiation level of the silicon after charging the battery may range between 30% and 95% silicon lithiation, between 30% and 75% silicon lithiation, between 30% and 65% silicon lithiation, or between 30% and 50% silicon lithiation. The lithiation level of the silicon after discharging the battery may range between 3% and 50% silicon lithiation, between 3% and 30% silicon lithiation, or between 3% and 10% silicon lithiation. The minimum threshold level may be a lithiation level below which a cycle life of the battery degrades. The electrolyte may include a liquid, solid, or gel.
Systems and methods for water soluble weak acidic resins as carbon precursors for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a primary resin carbon precursor; wherein the primary resin carbon precursor comprises a water-soluble acidic polyamide imide functionalized with acidic groups and one or more polymeric stabilizing additives. The electrode coating layer may also include a base and/or a surfactant. The electrode coating layer may be more than 70% silicon.
Systems and methods are provided for forming of batteries using carbon compositions as conductive additives for dense and conductive cathodes. An example battery may include an anode, an electrolyte, and a cathode including an active material, with the active material including 0D conductive carbon particles with nanoscale structure in three dimensions, and 1D conductive carbon particles with nanoscale structure in two dimensions. A ratio of the 1D conductive carbon particles to the 0D conductive carbon particles in the active material may be between 0.5 and 2. For example, the ratio of the 1D conductive carbon particles to the 0D conductive carbon particles may be approximately 1. The 1D carbon particles have a diameter of less than 120 nm, a surface area of 30 m2/g, and/or a dispersive surface energy of more than 180 mJ/m2. The 0D and 1D particles may comprise between 1% and 10% of the active material.
H01M 4/134 - Electrodes based on metals, Si or alloys
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
Systems and methods for high speed formation of cells for configuring anisotropic expansion of silicon-dominant anodes may include a cathode, an electrolyte, and an anode, where the anode may include a current collector and an active material on the current collector. An expansion of the anode may be configured by a charge rate during formation of the battery. The expansion of the anode may be less than 1.5% in lateral dimensions of the anode for higher charge rates during formation with the active material being more than 50% silicon, where the higher charge rate may be 1 C or higher, and perpendicular expansion may be higher for charge rates below 1 C during formation. The expansion of the anode may be lower in lateral dimensions for thicker current collectors, which may be 10 μm or thicker, and may be lower in lateral dimensions for more rigid materials for the current collector.
Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein sacrificial salts and prelithiation reagents are added to the cathode as functional additives for electrochemical prelithiation.
Systems and methods are provided for managing anisotropic expansion of silicon-dominant anodes. An example battery may include a cathode, an electrolyte, and an anode, with the anode including a current collector and an active material on a surface of the current collector. One or more characteristics of the current collector may ensure meeting particular expansion criteria. The expansion criteria may include expanding less in one of x-y directions and z-direction while expanding more in other one of the x-y directions and the z-direction, the x-y directions being parallel to the surface of the current collector and perpendicular to a thickness of the active material. The one or more characteristics include at least material of the current collector.
Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight of silicon particles. The silicon particles have an average particle size between about 0.1 μm and about 30 μm and a surface including nanometer-sized features. The composite material also includes greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases is a substantially continuous phase.
Methods of forming electrochemical cells are described. An electrochemical cell may be provided, with the electrochemical cell including a first electrode and a second electrode, wherein at least the first electrode includes up to about 99% by weight of silicon, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator. During a formation process, a formation charge current may be at a first rate of constant current and at a second rate of constant current to the electrochemical cell. The first rate is less than the second rate. The providing may include providing the formation charge current at the first rate of constant current until a rate switching condition is met; and providing the formation charge current at the second rate of constant current after the rate switching condition is met.
Electrolytes and electrolyte additives for energy storage devices comprising benzoyl peroxide based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a benzoyl peroxide based compound.
Electrolytes and electrolyte additives for energy storage devices comprising a carboxylic ether, a carboxylic acid based salt, or an acrylate electrolyte are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive selected from carboxylic ethers, carboxylic acid based salts, and acrylates.
Methods and system for forming electrochemical cells are provided. An electrochemical cell may be formed by providing an electrochemical cell that includes a first electrode and a second electrode, a separator between the first electrode and the second electrode, and an electrolyte, with at least the first electrode is a silicon-dominant electrode. A formation process may then performed, with the formation processing including charging the electrochemical cell by providing a formation charge current at about 1 C or greater to the electrochemical cell, and discharging the electrochemical cell after a rest step between the charging and the discharging.
Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight of silicon particles. The silicon particles have an average particle size between about 0.1 μm and about 30 μm and a surface including nanometer-sized features. The composite material also includes greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases is a substantially continuous phase.
H01M 4/134 - Electrodes based on metals, Si or alloys
B28B 3/02 - Producing shaped articles from the material by using pressesPresses specially adapted therefor wherein a ram exerts pressure on the material in a moulding spaceRam heads of special form
B29C 48/08 - Flat, e.g. panels flexible, e.g. films
B29C 48/154 - Coating solid articles, i.e. non-hollow articles
B29C 48/88 - Thermal treatment of the stream of extruded material, e.g. cooling
C04B 35/515 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxides
C04B 35/524 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxides based on carbon, e.g. graphite obtained from polymer precursors, e.g. glass-like carbon material
C04B 35/626 - Preparing or treating the powders individually or as batches
H01M 4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M 4/1393 - Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M 4/1395 - Processes of manufacture of electrodes based on metals, Si or alloys
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 4/587 - Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
44.
Silicon anodes with water-soluble maleic anhydride-, and/or maleic acid-containing polymers/copolymers, derivatives, and/or combinations (with or without additives) as binders
Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein the anode is a Si-dominant anode that utilizes water-soluble maleic anhydride- and/or maleic acid-containing polymers/co-polymers, derivatives, and/or combinations (with or without additives) as binders.
Electrolytes and electrolyte additives for energy storage devices comprising phosphorus based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a phosphorus based compound.
H01M 10/0569 - Liquid materials characterised by the solvents
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01M 10/0567 - Liquid materials characterised by the additives
H01M 10/0568 - Liquid materials characterised by the solutes
46.
SYMMETRICAL OR ASYMMETRICAL ALKYLSULFONYL IMIDE OR CYCLIC ALKYLENE SULFONYLIMIDE SALTS AS CATHODE ADDITIVES, ELECTROLYTE ADDITIVES, OR SI ANODE ADDITIVES FOR SI ANODE-BASED LI-ION CELLS
Electrode or electrolyte additives for energy storage devices comprising symmetrical or asymmetrical alkylsulfonyl imide or cyclic alkylene sulfonylimide salts are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte composition. Symmetrical or asymmetrical alkylsulfonyl imide or cyclic alkylene sulfonylimide salts may serve as additives to the electrodes or to the electrolyte composition, or both.
H01M 10/0567 - Liquid materials characterised by the additives
C07C 317/28 - SulfonesSulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01M 10/0569 - Liquid materials characterised by the solvents
47.
Silicon-Based Energy Storage Devices With Electrolyte Containing Cyanate Based Compounds
Electrolytes and electrolyte additives for energy storage devices comprising cyanate based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a cyanate based compound.
Electrolyte formulations for energy storage devices are disclosed. The energy storage device comprises a first electrode and a second electrode, where one or both of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte composition. Electrolyte formulations as described herein are electrolyte compositions comprising two or more components such as solvents, co-solvents, salts and/or additives. In some embodiments, three or more, four or more, five or more, six or more, seven or more, or eight or more components are included in the electrolyte composition.
An example method of reducing short circuits from occurring in a battery can include providing a current collector coated with a safety layer. The method can include providing an electrochemically active material film on the safety layer such that the safety layer is configured to reduce exposure of the current collector to an opposing electrode. The method can also include adhering the electrochemically active material film to the current collector via the safety layer.
Systems and methods for all-conductive battery electrodes may include an electrode coating layer on a current collector, where the electrode coating layer comprises more than 50% silicon, and where each material in the electrode has a resistivity of less than 100 Ω-cm. The silicon may have a resistivity of less than 10 Ω-cm, less than 1 Ω-cm, or less than 1 mΩ-cm. The electrode coating layer may comprise pyrolyzed carbon and/or conductive additives. The current collector comprises a metal foil. The metal current collector may comprise one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer. The electrode coating layer comprises more than 70% silicon. The electrode may be in electrical and physical contact with an electrolyte. The electrolyte may comprise a liquid, solid, or gel. The battery electrode may be in a lithium ion battery.
Systems and methods for water soluble weak acidic resins as carbon precursors for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and pyrolyzed water-soluble acidic polyamide imide as a primary resin carbon precursor. The electrode coating layer may include a pyrolyzed water-based acidic polymer solution additive. The polymer solution additive may include one or more of: polyacrylic acid (PAA) solution, poly (maleic acid, methyl methacrylate/methacrylic acid, butadiene/maleic acid) solutions, and water soluble polyacrylic acid. The electrode coating layer may include conductive additives. The current collector may include a metal foil, where the metal current collector includes one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer. The electrode coating layer may be more than 70% silicon.
New electrolyte compositions for lithium-ion energy storage devices with silicon-based electrode materials having improved stability. The electrolyte compositions may be used in an energy storage device comprising a first electrode and a second electrode, where at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and the electrolyte composition.
New electrolyte compositions for lithium-ion energy storage devices with siliconbased electrode materials having improved stability. The electrolyte compositions may be used in an energy storage device comprising a first electrode and a second electrode, where at least one of the first electrode and the second electrode is a Sibased electrode, a separator between the first electrode and the second electrode, and the electrolyte composition.
C08G 65/02 - Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
C08G 65/04 - Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
C08G 65/22 - Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
H01M 10/05 - Accumulators with non-aqueous electrolyte
54.
SILICON WITH CARBON-BASED COATING FOR LITHIUM-ION BATTERY ELECTRODES
Systems and methods are provided for silicon with a carbon-based coating for lithium-ion battery electrodes. An example electrode, for use in an electrochemical cell, includes an active material that includes a plurality of silicon particles, with each silicon particle having a coating covering a surface of the particle. The coating may include a carbon based coating. A least a portion of the silicon (e.g., at least 70%) in the silicon particles is elemental silicon.
Systems and methods are provided for control of thermal transfer during electrode pyrolysis based processing. An apparatus for processing battery electrodes may include a core configured for use in forming an electrode roll and a thermal rod. The core is configured to engage a sheet including electrode material applied on a current collector, specifically by rolling the sheet on the core to create concentric alternating layers of electrode material and current collector around an internal space formed by the core. The thermal rod is configured for engaging the electrode roll via the internal space of the core such that, once engaged, at least a portion of the thermal rod is disposed within the concentric alternating layers of electrode material and current collector. The thermal rod is configured to provide thermal transfer into the electrode roll via the core during processing of the electrode roll, with the processing including applying pyrolysis.
Systems and methods are provided for carbon additives for direct coating of silicon-dominant anodes. An example composition for use in directly coated anodes may include a silicon-dominated anode active material, a carbon-based binder, and a carbon-based additive, with the composition being configured for low-temperature pyrolysis. The low-temperature pyrolysis may be conducted at <600° C. An anode may be formed using a direct coating process of the composition on a current collector. The anode active material yields silicon constituting between 86% and 97% of weight of the formed anode after pyrolysis. The carbon-based additive yields carbon constituting between 2% and 6% of weight of the formed anode after pyrolysis.
Systems and methods for an ultra-high voltage cobalt-free cathode for alkali ion batteries may include an anode, a cathode, and a separator, with the cathode comprising an active material ANi(1-x)MnxSbOy, where x is a number between 0.0 and 1.0, y is an integer, and A comprises one or more of lithium, sodium, and potassium. The anode may include one or more of an alkali metal, silicon, and carbon. In one example, x is a value in the range between 0.05 and 0.9 and y is a value in the range between 1 and 8 where a specific capacity of the active material is greater than 50 milliamp-hours per gram. In another example, x is a value in the range between 0.4 and 0.6 and y is a value in the range between 1 and 8, where a specific capacity of the active material is greater than 70 milliamp-hours per gram.
Systems and methods are provided for state-of-charge balancing in battery management systems for Si/Li batteries. At least one state-of-charge (SOC) model may be configured, particularly to account for one or more unique characteristics associated with a cell type of one or more cells of the plurality of lithium-ion cells, and a state-of-charge (SOC) of a plurality of lithium-ion cells may be assessed. Based on the assessing of the state-of-charge (SOC), the plurality of lithium-ion cells may be controlled. The assessing may include calculating or estimating the state-of-charge (SOC) using the at least one state-of-charge (SOC) model. The controlling may be configured to equilibrate the state-of-charge (SOC) of the plurality of lithium-ion cells, or to modify a state-of-charge (SOC) of an individual lithium-ion cell or a group of lithium-ion cells, so that the plurality of lithium-ion cells as a whole has a balanced state-of-charge (SOC).
H01M 10/48 - Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
59.
Method And System For Silicon-Dominant Lithium-Ion Cells With Controlled Utilization of Silicon
Systems and methods for silicon-dominant lithium-ion cells with controlled utilization of silicon may include a cathode, an electrolyte, and an anode, where the anode has an active material comprising more than 50% silicon. The battery may be charged by lithiating silicon while not lithiating carbon. The active material may comprise more than 70% silicon. A voltage of the anode during discharge of the battery may remain above a minimum voltage at which silicon can be lithiated. The anode may have a specific capacity of greater than 3000 mAh/g. The battery may have a specific capacity of greater than 1000 mAh/g. The anode may have a greater than 90% initial Coulombic efficiency and may be polymer binder free. The battery may be charged at a 10 C rate or higher. The battery may be charged at temperatures below freezing without lithium plating. The electrolyte may comprise a liquid, solid, or gel.
An energy storage device comprising a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode comprises a self-supporting composite material film, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator, wherein the electrolyte comprises at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. The composite material film having greater than 0% and less than about 90% by weight of silicon particles, and greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases can be a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.
In some embodiments, an electrode can include a current collector, a composite material in electrical communication with the current collector, and at least one phase configured to adhere the composite material to the current collector. The current collector can include one or more layers of metal, and the composite material can include electrochemically active material. The at least one phase can include a compound of the metal and the electrochemically active material. In some embodiments, a composite material can include electrochemically active material. The composite material can also include at least one phase configured to bind electrochemically active particles of the electrochemically active material together. The at least one phase can include a compound of metal and the electrochemically active material.
C04B 35/52 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxides based on carbon, e.g. graphite
C04B 35/524 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxides based on carbon, e.g. graphite obtained from polymer precursors, e.g. glass-like carbon material
H01G 11/30 - Electrodes characterised by their material
H01G 11/64 - Liquid electrolytes characterised by additives
H01M 4/13 - Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulatorsProcesses of manufacture thereof
H01M 4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M 4/134 - Electrodes based on metals, Si or alloys
H01M 4/1393 - Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M 4/1395 - Processes of manufacture of electrodes based on metals, Si or alloys
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/587 - Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
Systems and methods are provided for silicon with a carbon-based coating for lithium-ion battery electrodes. An example electrode, for use in an electrochemical cell, includes an active material that includes a plurality of silicon particles, with each silicon particle having a coating covering a surface of the particle. The coating may include a carbon based coating. A least a portion of the silicon (e.g., at least 70%) in the silicon particles is elemental silicon.
Systems and methods are provided for aqueous based electrodes (e.g., anodes) with mechanical enhancement additives. An electrode for use in an electrochemical cell has an active material that includes silicon and a mechanical enhancement additive, with the mechanical enhancement additive selected to offset or counter silicon volume changes, and with the mechanical enhancement additive selected based on one or more selection thresholds relating to one or both of Young's modulus and aspect ratio.
Systems and methods are provided for advanced fusion of physics-based and machine learning based state-of-charge and state-of-health models in battery management systems.
G01R 31/36 - Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
G01R 31/367 - Software therefor, e.g. for battery testing using modelling or look-up tables
G01R 31/387 - Determining ampere-hour charge capacity or SoC
G01R 31/392 - Determining battery ageing or deterioration, e.g. state of health
G01R 31/396 - Acquisition or processing of data for testing or for monitoring individual cells or groups of cells within a battery
65.
AQUEOUS BASED ANODE WITH MECHANICAL ENHANCEMENT ADDITIVES
Systems and methods are provided for aqueous based electrodes (e.g., anodes) with mechanical enhancement additives. An electrode for use in an electrochemical cell has an active material that includes silicon and a mechanical enhancement additive, with the mechanical enhancement additive selected to offset or counter silicon volume changes, and with the mechanical enhancement additive selected based on one or more selection thresholds relating to one or both of Young's modulus and aspect ratio.
Electrolyte formulations for energy storage devices are disclosed. The energy storage device comprises a first electrode and a second electrode, where one or both of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte composition. Electrolyte formulations as described herein are electrolyte compositions comprising two or more components such as solvents, co-solvents, salts and/or additives. In some embodiments, three or more, four or more, five or more, six or more, seven or more, or eight or more components are included in the electrolyte composition.
Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.
Systems and methods for thermal curing of water soluble polymers for silicon dominant anodes to improve the mechanical properties of the anode and electrochemical performance of a battery are provided.
In certain embodiments, an electrode includes a body of material formed in substantial part of carbon, the body having an exterior surface and an interior located within the exterior surface, and a plurality cavities located in the interior of the body. Each of the cavities is in communication with the exterior of the body and has an interior surface. The cavities can each be sized to accommodate a battery separator located therein and substantially covering the interior surface of the cavity.
Silicon particles for use in an electrode in an electrochemical cell are provided. The silicon particles may have outer regions extending about 20 nm deep from the surfaces, the outer regions comprising an amount of aluminum such that a bulk measurement of the aluminum comprises at least about 0.01% by weight of the silicon particles. The bulk measurement of the aluminum may provide the amount of aluminum present at least in the outer regions.
Methods of recycling silicon from lithium-ion batteries having silicon-based electrodes are disclosed. Batteries and methods of manufacturing batteries from the recycled silicon are also disclosed. A method of recycling may include discharging each of one or more batteries to below a threshold voltage and disassembling each of the one or more batteries to collect source material from silicon-based electrodes of the one or more batteries. The source material may include silicon from the silicon-based electrodes. The method may further include rinsing the source material in alcohol to obtain a solution and extracting recycled silicon from the solution by heating the silicon for a first period of time and leaching the silicon in an acid for a second period of time. In some methods, the heating occurs before the leaching. In other embodiments, the leaching occurs before the heating.
Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight silicon particles, the silicon particles having an average particle size between about 10 nm and about 40 μm, wherein the silicon particles have surface coatings comprising silicon carbide or a mixture of carbon and silicon carbide, and greater than 0% and less than about 90% by weight of one or more types of carbon phases, wherein at least one of the one or more types of carbon phases is a substantially continuous phase.
H01M 4/134 - Electrodes based on metals, Si or alloys
H01M 4/1395 - Processes of manufacture of electrodes based on metals, Si or alloys
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 4/587 - Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01B 1/04 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of carbon-silicon compounds, carbon, or silicon
H01M 4/48 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
H01M 4/583 - Carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01B 1/24 - Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon, or silicon
73.
SILICON-DOMINANT ELECTRODES FOR ENERGY STORAGE USING WET OXIDIZED SILICON BY ACID
Systems and methods are provided for silicon-dominant electrodes for energy storage using wet oxidized silicon by acid. Silicon may be treated by wet oxidization treatment using acid. The acid may be a nitric acid. Treated silicon may include silicon particles, with each silicon particle including an oxide surface layer formed as a result of the wet oxidization treatment. The wet oxidization treatment may include immersing untreated silicon powder in an acid, dispersing the silicon power continuously, and after an immersion period of pre-determined duration, filtering the silicon powder from the acid.
Systems and methods are provided for Si-based anodes with cross-linked carbon nanotubes. A slurry for use in anodes may be mixed, with the slurry including an anode active material and a carbon-based additive, where the slurry may be used in forming an anode. The anode active material may yield a silicon-dominant anode when the slurry is used in forming the anode, and the carbon-based additive forms a mesh-like structure in the silicon-dominant anode. The carbon-based additive includes cross-linked carbon nanotubes (CNT).
Systems and methods for pulverization mitigation additives for silicon dominant anodes may include an electrode including a metal current collector and an active material layer on the current collector. The active material layer may include islands of material separated by cracks, with the islands including, at least, silicon and conductive additives. At least a portion of the additives may extend from within the islands and bridge the cracks of the active material layer. The conductive additives may form a structure providing electrical conductivity between a first island and a second island, or between at least one island and the metal current collector. The additives may include between 1% and 40% of the active material layer. The active material layer may include between 20% to 95% silicon. The conductive additives may include carbon nanotubes and/or graphene sheets.
Systems and methods are provided for Si-based anodes with cross-linked carbon nanotubes. A slurry for use in anodes may be mixed, with the slurry including an anode active material and a carbon-based additive, where the slurry may be used in forming an anode. The anode active material may yield a silicon-dominant anode when the slurry is used in forming the anode, and the carbon-based additive forms a mesh-like structure in the silicon-dominant anode. The carbon-based additive includes cross-linked carbon nanotubes (CNT).
Systems and methods are provided for state-of-charge balancing in battery management systems for Si/Li batteries. State-of-charge (SOC) of one or more lithium-ion cells may be assessed, and based on the assessing of the SOC, the one or more lithium-ion cells may be controlled. The controlling may include setting or modifying one or more operating parameters of at least one lithium-ion cell, and the controlling may be configured to equilibrate the SOC of the one or more lithium-ion cells or to modify an SOC of at least one lithium-ion cell so that the one or more lithium-ion cells have a balanced SOC.
Systems and methods utilizing aqueous-based polymer binders for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a water soluble polymer and may comprise one or more of the following materials: pH modifiers, viscosity modifiers, strengthening additives, surfactants and anti-foaming agents. The electrode coating layer may include more than 70% silicon and the anode may be in a lithium ion battery.
Aspects of the present disclosure relate to energy generation and storage. More specifically, certain embodiments of the disclosure relate to using aqueous based polymers to fabricate silicon-based anode materials.
A system and/or method for replacing solvents/additives such as fluoroethylene carbonate (FEC) to create new electrolyte compositions for lithium-ion energy storage devices with silicon-based electrode materials and reduce undesirable gassing. The electrolyte compositions may be used in an energy storage device comprising a first electrode and a second electrode, where at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and the electrolyte composition.
H01M 10/0569 - Liquid materials characterised by the solvents
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 10/0568 - Liquid materials characterised by the solutes
81.
IMPROVEMENT OF CYCLE LIFE IN SI/LI BATTERIES USING HIGH TEMPERATURE DEEP DISCHARGE CYCLING
Systems and methods are provided for improvement of cycle life in Si/Li batteries using high temperature deep discharge cycling. One or more deep discharge cycles may be applied to a cell that includes a cathode, a separator, and a silicon-dominant anode, with each of the one or more deep discharge cycles including at least charging and discharging the cell, and with each of the one or more deep discharge cycles being performed at a higher temperature that is above normal operating temperature range. The higher temperature may be 40 °C or higher, 45 °C or higher, or around 45 °C.
Systems and methods are provided for improvement of cycle life in Si/Li batteries using high temperature deep discharge cycling. One or more deep discharge cycles may be applied to a cell that includes a cathode, a separator, and a silicon-dominant anode, with each of the one or more deep discharge cycles including at least charging and discharging the cell, and with each of the one or more deep discharge cycles being performed at a higher temperature that is above normal operating temperature range. The higher temperature may be 40° C. or higher, 45° C. or higher, or around 45° C.
Systems and methods are provided for state-of-charge balancing in battery management systems for Si/Li batteries. State-of-charge (SOC) of one or more lithium-ion cells may be assessed, and based on the assessing of the SOC, the one or more lithium-ion cells may be controlled. The controlling may include setting or modifying one or more operating parameters of at least one lithium-ion cell, and the controlling may be configured to equilibrate the SOC of the one or more lithium-ion cells or to modify an SOC of at least one lithium-ion cell so that the one or more lithium-ion cells have a balanced SOC.
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
H01M 10/48 - Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 4/02 - Electrodes composed of, or comprising, active material
84.
Direct coating of electrodes in silicon-dominant anode cells
Systems and methods are provided for high volume roll-to-roll direct coating of electrodes for silicon-dominant anode cells. A slurry that includes silicon particles and a binder material may be applied to a current collector film, and the slurry may be processed to form a precursor composite film coated on the current collector film. The current collector film with the coated precursor composite film may be rolled into a precursor composite roll. A heat treatment may be applied to the current collector film with the coated precursor composite film in an environment including nitrogen gas, to convert the coated precursor composite film to a pyrolyzed composite film coated on the current collector film. The heat treatment may include applying the heat treatment to the precursor composite roll in whole and/or applying the heat treatment to the current collector film with the coated precursor composite film as it is continuously fed.
The present disclosure relates to prelithiated Si electrodes, methods of prelithiating Si electrodes, and use of prelithiated electrodes in electrochemical devices are described. There are several characteristics of electrode prelithiation that enable the superior battery performance. First, a prelithiated silicon anode is already in its expanded state during SEI formation, and therefore less of the SEI layer breaks down and reforms during cycling. Second, the prelithiated anode has a lower anode potential, which may also help the cycle performance of an electrochemical device. A silicon-based electrode, for use in energy storage devices, may have prelithiated silicon active material with a prelithiation level of above 0% to about 30%, with a lithium source within the energy storage devices providing excess lithium for contributing at least a portion of the prelithiation of the silicon active material.
Silicon particles for use in an electrode in an electrochemical cell are provided. The silicon particles may have outer regions extending about 20 nm deep from the surfaces, the outer regions comprising an amount of aluminum such that a bulk measurement of the aluminum comprises at least about 0.01% by weight of the silicon particles. The bulk measurement of the aluminum may provide the amount of aluminum present at least in the outer regions.
Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.
Systems and methods are provided for algorithm-optimized voltage and/or current windows for lithium-silicon batteries. A lithium-ion cell may be managed, with the managing including controlling voltage and/or current of the lithium-ion cell using an enhanced algorithm. The controlling includes adjusting voltage and/or current limits applied during one or both of charging and discharging of the lithium-ion cell, and the enhanced algorithm is configured to control a voltage range and/or a current range of the lithium-ion cell to maximize a combination of one or more variable associated with the lithium-ion cell including one or more of cycle life, energy density, cumulative capacity before end of life, and cumulative energy before end of life. The lithium-ion cell may be a silicon-dominant cell having a silicon-dominant anode with silicon >50% of active material of the anode, and the enhanced algorithm may be configured based on characteristic(s) unique to silicon-dominant cells.
H01M 10/48 - Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
G01R 31/3835 - Arrangements for monitoring battery or accumulator variables, e.g. SoC involving only voltage measurements
Systems and methods are provided for state-of-health balanced battery management system. State-of-health (SOH) of one or more lithium-ion cells may be assessed, and based on the assessing of state-of-health (SOH), the one or more lithium-ion cells may be controlled. The controlling may include setting or modifying one or more operating parameters of at least one lithium-ion cell, and the controlling may be configured to equilibrate the state-of-health (SOH) of the one or more lithium-ion cells or to modify a state-of-health (SOH) of at least one lithium-ion cell so that the one or more lithium-ion cells have a uniform state-of-health (SOH).
Systems and methods are provided for carbon additives for direct coating of silicon-dominant anodes. An example composition for use in directly coated anodes may include a silicon-dominated anode active material, a carbon-based binder, and a carbon-based additive, with the composition being configured for low-temperature pyrolysis. The low-temperature pyrolysis may be conducted at <600° C. An anode may be formed using a direct coating process of the composition on a current collector. The anode active material yields silicon constituting between 86% and 97% of weight of the formed anode after pyrolysis. The carbon-based additive yields carbon constituting between 2% and 6% of weight of the formed anode after pyrolysis.
Systems and methods are provided for state-of-health models for lithium-silicon batteries. State-of-health (SOH) of a lithium-ion cell may be assessed, with the assessing including calculating the state-of-health (SOH) using an enhanced state-of-health (SOH) model, with the enhanced state-of-health (SOH) model using input data other than data provided directly by the lithium-ion cell. The input data includes at least data acquired during operation of the lithium-ion cell and/or data acquired during manufacturing and initialization of the lithium-ion cell or electrodes of the lithium-ion cell. The lithium-ion cell may be a silicon-dominant cell including a silicon-dominant anode with silicon >50% of active material of the anode, and the enhanced state-of-health (SOH) model may be configured based on one or more characteristics unique to silicon-dominant cells.
Electrolytes and electrolyte additives for energy storage devices comprising sulfonate or carboxylate salt based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a sulfonate or carboxylate salt based compound.
Silicon-dominate battery electrodes, battery cells utilizing the silicon-dominate battery electrodes, and methods of manufacturing are disclosed. Such a battery cell includes a cathode, a separator, an electrolyte, and an anode. The anode comprises a current collector and active material on the current collector. The active material layer includes at least 50% silicon. A ratio of the electrolyte to Ah is over 2 g/Ah.
A method for formation of cylindrical and prismatic can cells may include providing a battery, where the battery includes one or more cells, with each cell including at least one silicon-dominant anode, a cathode, and a separator. The battery also includes a metal can that contains the one or more cells such that during formation a pressure between 50 kPa and 1 MPa is applied to the one or more cells. The battery may include strain absorbing materials arranged between the one or more cells and interior walls of the can. The strain absorbing materials may include foam. The strain absorbing materials may include a solid electrolyte layer. The strain absorbing materials may include PMMA, PVDF, or a combination thereof. The pressure during a formation process may be due to a thickness of the strain absorbing materials being thicker than an expansion of the one or more cells.
H01M 10/04 - Construction or manufacture in general
H01M 50/231 - MountingsSecondary casings or framesRacks, modules or packsSuspension devicesShock absorbersTransport or carrying devicesHolders characterised by the material of the casings or racks having a layered structure
H01M 4/134 - Electrodes based on metals, Si or alloys
95.
Single lithium-ion conductive polymer electrolytes for Si anode-based lithium-ion batteries
Single Li-ion conducting solid-state polymer electrolytes for use in energy storage devices are disclosed. The energy storage device comprises a first electrode and a second electrode, where at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte. Electrolytes may include all-solid-state polymer electrolytes, quasi-solid polymer electrolytes and/or polymer gel electrolytes. The single Li-ion conducting solid-state polymer electrolytes can improve the electrochemical performances and safety of Si anode-based Li-ion batteries.
A clamping device for a multilayered battery comprising one or more electrochemical cells is provided. The clamping device can include one or more plates, guided elastic members, and/or one or more layers of an interfacial material, such as foam pads or papers, to provide distributed pressure across one or more surfaces of the multilayered battery during cell formation and/or cycling. A compression plate is employed to provide a compressive force to compress the elastic members to a predetermined length, at which the position of the elastic members can be fixed.
H01M 10/04 - Construction or manufacture in general
H01M 50/204 - Racks, modules or packs for multiple batteries or multiple cells
H01M 4/134 - Electrodes based on metals, Si or alloys
H01M 10/48 - Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
H01M 4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M 4/38 - Selection of substances as active materials, active masses, active liquids of elements or alloys
H01M 4/587 - Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
A clamping device for an electrochemical cell stack is provided. The clamping device can include a first plate and a second plate. The second plate can be positionable relative to the first plate such that a space between the first plate and the second plate can be sized to receive an electrochemical cell stack. The device also can include a coupling member coupling the first plate to the second plate. At least one of the first and second plates can be movable away from the other plate. The coupling member can have a first end portion and a second end portion. The device further can include an elastic member disposed between the first end portion and the second end portion.
Additives for energy storage devices comprising phosphorus-containing compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, where at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte composition. Phosphorus-containing compounds may serve as additives to the first electrode, the second electrode and/or the electrolyte, as well as the separator.
C07F 9/6561 - Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing systems of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring or ring system, with or without other non-condensed hetero rings
H01M 4/02 - Electrodes composed of, or comprising, active material
100.
Silicon-based energy storage devices with electrolyte containing a benzoyl peroxide based compound
Electrolytes and electrolyte additives for energy storage devices comprising benzoyl peroxide based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a benzoyl peroxide based compound.
