Ensyn Renewables, Inc.

United States of America

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2021 1
2020 2
Before 2020 70
IPC Class
C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids 28
C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material 24
C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique 23
C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal 19
C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons 19
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NICE Class
04 - Industrial oils and greases; lubricants; fuels 2
37 - Construction and mining; installation and repair services 1
39 - Transport, packaging, storage and travel services 1
40 - Treatment of materials; recycling, air and water treatment, 1
42 - Scientific, technological and industrial services, research and design 1
Status
Pending 4
Registered / In Force 69

1.

Systems and methods for preparing and co-processing biocrude oil

      
Application Number 16319123
Grant Number 11427765
Status In Force
Filing Date 2017-07-19
First Publication Date 2021-11-11
Grant Date 2022-08-30
Owner Ensyn Renewables, Inc. (USA)
Inventor Freel, Barry A.

Abstract

The present application generally relates to catalytically preparing liquid fuel products with an improved product mix by co-processing a plurality of reactants in in refinery or field-upgrading operations. The reactants may include, for example, petroleum fraction and a biocrude oil having an alcohol additive.

IPC Classes  ?

  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids

2.

Systems and methods for renewable fuel

      
Application Number 16575997
Grant Number 11441081
Status In Force
Filing Date 2019-09-19
First Publication Date 2020-08-13
Grant Date 2022-09-13
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 4/00 - Feed devicesFeed or outlet control devices
  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
  • B01J 8/26 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
  • C10G 65/04 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
  • C10L 1/06 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition

3.

Demetallization of liquid biomass

      
Application Number 16517245
Grant Number 10982152
Status In Force
Filing Date 2019-07-19
First Publication Date 2020-01-09
Grant Date 2021-04-20
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Normand, Josh
  • Brandvold, Timothy A.
  • Frey, Stanley J.
  • Clarke, Doug

Abstract

Methods, processes, systems, or apparatus are provided to remove contaminants such as metals and chlorine present in a pyrolysis stream to form reduced-contaminant liquid biomass. In certain embodiments, for example, a metal chelating agent is dissolved into a metal-containing pyrolysis stream condensate to form metal chelate complex, followed by filtering to obtain the reduced-contaminant liquid biomass.

IPC Classes  ?

  • C10C 5/00 - Production of pyroligneous acid
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C12P 7/46 - Dicarboxylic acids having four or less carbon atoms, e.g. fumaric acid, maleic acid
  • C07C 7/09 - Purification, separation or stabilisation of hydrocarbonsUse of additives by fractional condensation
  • C10G 7/00 - Distillation of hydrocarbon oils

4.

Apparatuses for controlling heat for rapid thermal processing of carbonaceous material and methods for the same

      
Application Number 16026367
Grant Number 10794588
Status In Force
Filing Date 2018-07-03
First Publication Date 2019-06-06
Grant Date 2020-10-06
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Myers, Daniel N.
  • Palmas, Paolo

Abstract

Embodiments of apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material are provided herein. The apparatus comprises a reactor, a reheater for forming a fluidized bubbling bed comprising an oxygen-containing gas, inorganic heat carrier particles, and char and for burning the char into ash to form heated inorganic particles. An inorganic particle cooler is in fluid communication with the reheater. The inorganic particle cooler comprises a shell portion and a tube portion. The inorganic particle cooler is configured such that the shell portion receives a portion of the heated inorganic particles and the tube portion receives a cooling medium for indirect heat exchange with the portion of the heated inorganic particles to form partially-cooled heated inorganic particles.

IPC Classes  ?

  • F23C 10/18 - Apparatus in which combustion takes place in a fluidised bed of fuel or other particles DetailsAccessories
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • F27D 9/00 - Cooling of furnaces or of charges therein

5.

Liquid biomass heating system

      
Application Number 16263949
Grant Number 10948179
Status In Force
Filing Date 2019-01-31
First Publication Date 2019-05-30
Grant Date 2021-03-16
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Hopkins, Geoffrey D.
  • Stiles, Cameron A. F.
  • Torrens, R. Lee
  • Muller, Stefan

Abstract

The present disclosure generally relates to the introduction of a liquid biomass in heating systems such as commercial boilers in order to reduce dependence on petroleum-based heating fuel oils as a source of combustion fuel. More specifically, the present disclosure is directed to systems, methods, and apparatuses utilizing a liquid thermally produced from biomass into commercial and industrial boiler or thermal systems such as boilers, furnaces, and kilns, and methods for generating renewable identification numbers (RINs), alternative energy credits (AECs) and renewable energy credits (RECs).

IPC Classes  ?

  • F23C 1/00 - Combustion apparatus specially adapted for combustion of two or more kinds of fuel simultaneously or alternately, at least one kind of fuel being either a fluid fuel or a solid fuel suspended in air
  • F23M 20/00 - Details of combustion chambers, not otherwise provided for
  • F23D 11/24 - Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space by pressurisation of the fuel before a nozzle through which it is sprayed by a substantial pressure reduction into a space
  • F23D 11/44 - Preheating devicesVaporising devices

6.

Systems and methods for renewable fuel

      
Application Number 15949807
Grant Number 10570340
Status In Force
Filing Date 2018-04-10
First Publication Date 2019-03-14
Grant Date 2020-02-25
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • C10L 1/18 - Organic compounds containing oxygen
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • G06Q 50/06 - Energy or water supply
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10L 1/16 - Hydrocarbons
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 65/04 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
  • C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10L 1/06 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition

7.

Demetallization of liquid biomass

      
Application Number 15851080
Grant Number 10400176
Status In Force
Filing Date 2017-12-21
First Publication Date 2018-11-22
Grant Date 2019-09-03
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Normand, Josh
  • Brandvold, Timothy A.
  • Frey, Stanley J.
  • Clarke, Doug

Abstract

Methods, processes, systems, or apparatus are provided to remove contaminants such as metals and chlorine present in a pyrolysis stream to form reduced-contaminant liquid biomass. In certain embodiments, for example, a metal chelating agent is dissolved into a metal-containing pyrolysis stream condensate to form metal chelate complex, followed by filtering to obtain the reduced-contaminant liquid biomass.

IPC Classes  ?

  • C07C 7/152 - Purification, separation or stabilisation of hydrocarbonsUse of additives by treatment giving rise to a chemical modification of at least one compound by forming adducts or complexes
  • C10G 7/10 - Inhibiting corrosion during distillation
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C07C 7/09 - Purification, separation or stabilisation of hydrocarbonsUse of additives by fractional condensation
  • C10G 7/00 - Distillation of hydrocarbon oils
  • C12P 7/46 - Dicarboxylic acids having four or less carbon atoms, e.g. fumaric acid, maleic acid

8.

Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas

      
Application Number 15918374
Grant Number 10563127
Status In Force
Filing Date 2018-03-12
First Publication Date 2018-07-19
Grant Date 2020-02-18
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Sechrist, Paul A.
  • Bozzano, Andrea G.

Abstract

Processes for controlling afterburn in a reheater and loss of entrained solid particles in reheater flue gas are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium comprising combustible solid particles. The spent heat transfer medium is introduced into a fluidizing dense bed. The combustible solid particles of the spent heat transfer medium are combusted forming combustion product flue gas in a dilute phase above the fluidizing dense bed. The combustion product flue gas comprises flue gas and solid particles entrained therein. The solid particles are separated from the combustion product flue gas to form separated solid particles. At least a portion of the separated solid particles are returned to the fludizing dense bed.

IPC Classes  ?

  • C10B 21/12 - Burners
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • B01D 45/16 - Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by the winding course of the gas stream
  • B04C 3/00 - Apparatus in which the axial direction of the vortex remains unchanged
  • B04C 9/00 - Combinations with other devices, e.g. fans
  • C10B 45/00 - Other details
  • C10B 47/24 - Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10B 57/12 - Applying additives during coking

9.

DEMETALLIZATION OF LIQUID BIOMASS

      
Application Number US2017067932
Publication Number 2018/125753
Status In Force
Filing Date 2017-12-21
Publication Date 2018-07-05
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry, A.
  • Normand, Josh
  • Brandvold, Timothy, A.
  • Frey, Stanley, J.
  • Clarke, Doug

Abstract

Methods, processes, systems, or apparatus are provided to remove contaminants such as metals and chlorine present in a pyrolysis stream to form reduced-contaminant liquid biomass. In certain embodiments, for example, a metal chelating agent is dissolved into a metal-containing pyrolysis stream condensate to form metal chelate complex, followed by filtering to obtain the reduced-contaminant liquid biomass.

IPC Classes  ?

  • B01J 29/90 - Regeneration or reactivation
  • B01J 38/40 - Treating with free oxygen-containing gas and forming useful by-products
  • B01J 38/60 - Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
  • C10G 1/04 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10G 31/10 - Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for with the aid of centrifugal force
  • C10G 17/06 - Liquid-liquid treatment forming two immiscible phases using acids derived from sulfur or acid sludge thereof
  • C10G 32/02 - Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by electric or magnetic means
  • C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
  • C12P 7/46 - Dicarboxylic acids having four or less carbon atoms, e.g. fumaric acid, maleic acid

10.

DEMETALLIZATION OF LIQUID BIOMASS

      
Document Number 03048681
Status Pending
Filing Date 2017-12-21
Open to Public Date 2018-07-05
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry A.
  • Normand, Josh
  • Brandvold, Timothy A.
  • Frey, Stanley J.
  • Clarke, Doug

Abstract

Methods, processes, systems, or apparatus are provided to remove contaminants such as metals and chlorine present in a pyrolysis stream to form reduced-contaminant liquid biomass. In certain embodiments, for example, a metal chelating agent is dissolved into a metal-containing pyrolysis stream condensate to form metal chelate complex, followed by filtering to obtain the reduced-contaminant liquid biomass.

IPC Classes  ?

11.

Rapid thermal conversion of biomass

      
Application Number 15461062
Grant Number 10544368
Status In Force
Filing Date 2017-03-16
First Publication Date 2018-02-01
Grant Date 2020-01-28
Owner Ensyn Renewables, Inc. (USA)
Inventor Freel, Barry A.

Abstract

The present invent provides improved rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. In an embodiment, biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. In one embodiment, the liquid product itself is used as the quench media.

IPC Classes  ?

  • C10B 57/00 - Other carbonising or coking processesFeatures of destructive distillation processes in general
  • C10B 27/00 - Arrangements for withdrawal of the distillation gases
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10G 9/28 - Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material
  • C10K 1/04 - Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
  • F28C 3/08 - Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour with change of state, e.g. absorption, evaporation, condensation
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation

12.

SYSTEMS AND METHODS FOR PREPARING AND CO-PROCESSING BIOCRUDE OIL

      
Document Number 03030625
Status Pending
Filing Date 2017-07-19
Open to Public Date 2018-01-25
Owner ENSYN RENEWABLES, INC. (USA)
Inventor Freel, Barry A.

Abstract

The present application generally relates to catalytically preparing liquid fuel products with an improved product mix by co-processing a plurality of reactants in in refinery or field- upgrading operations. The reactants may include, for example, petroleum fraction and a biocrude oil having an alcohol additive.

IPC Classes  ?

  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons

13.

SYSTEMS AND METHODS FOR PREPARING AND CO-PROCESSING BIOCRUDE OIL

      
Application Number US2017042782
Publication Number 2018/017664
Status In Force
Filing Date 2017-07-19
Publication Date 2018-01-25
Owner ENSYN RENEWABLES, INC. (USA)
Inventor Freel, Barry, A.

Abstract

The present application generally relates to catalytically preparing liquid fuel products with an improved product mix by co-processing a plurality of reactants in in refinery or field- upgrading operations. The reactants may include, for example, petroleum fraction and a biocrude oil having an alcohol additive.

IPC Classes  ?

  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons

14.

INTEGRATED PROCESS FOR THE PRE-TREATMENT OF BIOMASS AND PRODUCTION OF BIO-OIL

      
Document Number 03026306
Status In Force
Filing Date 2017-05-26
Open to Public Date 2017-11-30
Grant Date 2024-04-09
Owner
  • ENSYN RENEWABLES, INC. (USA)
  • SUZANO S.A. (Brazil)
Inventor
  • Ribeiro De Lima, Danilo
  • Antunes Guimaraes, Matheus
  • Freel, Barry
  • D. Hopkins, Geoffrey

Abstract

The present invention is aimed at providing an integrated process for the pre-treatment of biomass and to the use of biomass as the raw material in a process for producing biochemicals and bio-fuels, the present integrated method preferably allowing the production of high-quality bio-oil from biomass such as wood, forestry waste, waste from the sugar and alcohol industries, and energy cane.

IPC Classes  ?

  • C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
  • C11B 1/02 - Pretreatment
  • C11B 1/04 - Pretreatment of vegetable raw material

15.

INTEGRATED PROCESS FOR THE PRE-TREATMENT OF BIOMASS AND PRODUCTION OF BIO-OIL

      
Application Number BR2017050133
Publication Number 2017/201598
Status In Force
Filing Date 2017-05-26
Publication Date 2017-11-30
Owner
  • FIBRIA CELULOSE S.A. (Brazil)
  • ENSYN RENEWABLES, INC. (USA)
Inventor
  • Ribeiro De Lima, Danilo
  • Antunes Guimaraes, Matheus
  • Freel, Barry
  • D. Hopkins, Geoffrey

Abstract

The present invention is aimed at providing an integrated process for the pre-treatment of biomass and to the use of biomass as the raw material in a process for producing biochemicals and bio-fuels, the present integrated method preferably allowing the production of high-quality bio-oil from biomass such as wood, forestry waste, waste from the sugar and alcohol industries, and energy cane.

IPC Classes  ?

  • C10G 1/04 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
  • C10L 5/44 - Solid fuels essentially based on materials of non-mineral origin on vegetable substances
  • C10B 57/08 - Non-mechanical pretreatment of the charge
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C11B 1/04 - Pretreatment of vegetable raw material

16.

Systems and methods for renewable fuel

      
Application Number 15498063
Grant Number 10640719
Status In Force
Filing Date 2017-04-26
First Publication Date 2017-09-28
Grant Date 2020-05-05
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids

17.

LIQUID BIOMASS HEATING SYSTEM

      
Document Number 02995845
Status Pending
Filing Date 2016-08-19
Open to Public Date 2017-03-02
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Torrens, R. Lee
  • Freel, Barry A.
  • Hopkins, Geoffrey D.
  • Muller, Stefan
  • Stiles, Cameron A.F.

Abstract

The present disclosure generally relates to the introduction of a liquid biomass in heating systems such as commercial boilers in order to reduce dependence on petroleum-based heating fuel oils as a source of combustion fuel. More specifically, the present disclosure is directed to systems, methods, and apparatuses utilizing a liquid thermally produced from biomass into commercial and industrial boiler or thermal systems such as boilers, furnaces, and kilns, and methods for generating renewable identification numbers (RINs), alternative energy credits (AECs) and renewable energy credits (RECs).

IPC Classes  ?

  • F23C 1/00 - Combustion apparatus specially adapted for combustion of two or more kinds of fuel simultaneously or alternately, at least one kind of fuel being either a fluid fuel or a solid fuel suspended in air
  • F23G 5/027 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels including pretreatment pyrolising or gasifying
  • F23G 7/00 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of specific waste or low grade fuels, e.g. chemicals

18.

LIQUID BIOMASS HEATING SYSTEM

      
Application Number US2016047777
Publication Number 2017/034981
Status In Force
Filing Date 2016-08-19
Publication Date 2017-03-02
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry, A.
  • Hopkins, Geoffrey, D.
  • Stiles, Cameron, A.F.
  • Torrens, R., Lee
  • Muller, Stefan

Abstract

The present disclosure generally relates to the introduction of a liquid biomass in heating systems such as commercial boilers in order to reduce dependence on petroleum-based heating fuel oils as a source of combustion fuel. More specifically, the present disclosure is directed to systems, methods, and apparatuses utilizing a liquid thermally produced from biomass into commercial and industrial boiler or thermal systems such as boilers, furnaces, and kilns, and methods for generating renewable identification numbers (RINs), alternative energy credits (AECs) and renewable energy credits (RECs).

IPC Classes  ?

  • F02B 43/08 - Plants characterised by the engines using gaseous fuel generated in the plant from solid fuel, e.g. wood

19.

Liquid biomass heating system

      
Application Number 15241875
Grant Number 10337726
Status In Force
Filing Date 2016-08-19
First Publication Date 2017-02-23
Grant Date 2019-07-02
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Hopkins, Geoffrey D.
  • Stiles, Cameron A. F.
  • Torrens, R. Lee
  • Muller, Stefan

Abstract

The present disclosure generally relates to the introduction of a liquid biomass in heating systems such as commercial boilers in order to reduce dependence on petroleum-based heating fuel oils as a source of combustion fuel. More specifically, the present disclosure is directed to systems, methods, and apparatuses utilizing a liquid thermally produced from biomass into commercial and industrial boiler or thermal systems such as boilers, furnaces, and kilns, and methods for generating renewable identification numbers (RINs), alternative energy credits (AECs) and renewable energy credits (RECs).

IPC Classes  ?

  • C10L 1/12 - Inorganic compounds
  • F23C 1/00 - Combustion apparatus specially adapted for combustion of two or more kinds of fuel simultaneously or alternately, at least one kind of fuel being either a fluid fuel or a solid fuel suspended in air
  • F23M 20/00 - Details of combustion chambers, not otherwise provided for

20.

Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas

      
Application Number 15052334
Grant Number 09951278
Status In Force
Filing Date 2016-02-24
First Publication Date 2017-01-19
Grant Date 2018-04-24
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Sechrist, Paul A.
  • Bozzano, Andrea G.

Abstract

Processes for controlling afterburn in a reheater and loss of entrained solid particles in reheater flue gas are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium comprising combustible solid particles. The spent heat transfer medium is introduced into a fluidizing dense bed. The combustible solid particles of the spent heat transfer medium are combusted forming combustion product flue gas in a dilute phase above the fluidizing dense bed. The combustion product flue gas comprises flue gas and solid particles entrained therein. The solid particles are separated from the combustion product flue gas to form separated solid particles. At least a portion of the separated solid particles are returned to the fluidizing dense bed.

IPC Classes  ?

  • C10B 21/12 - Burners
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • B01D 45/16 - Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by the winding course of the gas stream
  • B04C 3/00 - Apparatus in which the axial direction of the vortex remains unchanged
  • B04C 9/00 - Combinations with other devices, e.g. fans
  • C10B 45/00 - Other details
  • C10B 47/24 - Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10B 57/12 - Applying additives during coking

21.

Systems and methods for renewable fuel

      
Application Number 15239581
Grant Number 09969942
Status In Force
Filing Date 2016-08-17
First Publication Date 2016-12-08
Grant Date 2018-05-15
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • C10L 1/06 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
  • C10G 65/04 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps

22.

Heat removal and recovery in biomass pyrolysis

      
Application Number 15233560
Grant Number 11028325
Status In Force
Filing Date 2016-08-10
First Publication Date 2016-12-01
Grant Date 2021-06-08
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Palmas, Paolo
  • Myers, Daniel N.

Abstract

Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.

IPC Classes  ?

  • C10B 49/10 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10B 39/06 - Wet quenching in the oven
  • F27D 17/00 - Arrangements for using waste heatArrangements for using, or disposing of, waste gases
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • F23G 5/027 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels including pretreatment pyrolising or gasifying
  • F23G 5/30 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels with combustion in a fluidised bed
  • F23G 7/10 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of specific waste or low grade fuels, e.g. chemicals of field or garden waste
  • F27B 15/02 - Details, accessories or equipment specially adapted for furnaces of these types

23.

Systems and methods for renewable fuel

      
Application Number 14801283
Grant Number 10975315
Status In Force
Filing Date 2015-07-16
First Publication Date 2016-02-11
Grant Date 2021-04-13
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 65/04 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 4/00 - Feed devicesFeed or outlet control devices
  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • B01J 8/26 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10L 1/18 - Organic compounds containing oxygen
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10L 1/06 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
  • C10L 1/16 - Hydrocarbons
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

24.

Thermal extraction method and product

      
Application Number 14812711
Grant Number 09809564
Status In Force
Filing Date 2015-07-29
First Publication Date 2016-01-28
Grant Date 2017-11-07
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Boulard, David
  • Graham, Robert G.
  • Freel, Barry A.

Abstract

The present invention is related to a thermal extract of a plant material and methods of extraction thereof. The method of producing a thermal extract from a plant starting material by means of a thermal extraction of the starting material wherein the improvement consists in requiring smaller amounts of costly and/or toxic organic solvents for the extraction and partitioning steps.

IPC Classes  ?

  • C07D 305/14 - Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms condensed with carbocyclic rings or ring systems
  • A61K 36/00 - Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
  • A61K 36/13 - Coniferophyta (gymnosperms)
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10C 5/00 - Production of pyroligneous acid
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material

25.

Rapid thermal conversion of biomass

      
Application Number 14593831
Grant Number 09631145
Status In Force
Filing Date 2015-01-09
First Publication Date 2015-07-09
Grant Date 2017-04-25
Owner Ensyn Renewables, Inc. (USA)
Inventor Freel, Barry A.

Abstract

Processes are provided including quenching a hot vapor stream to improve rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production.

IPC Classes  ?

  • C10B 57/12 - Applying additives during coking
  • C10B 57/00 - Other carbonising or coking processesFeatures of destructive distillation processes in general
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 9/28 - Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material
  • C10K 1/04 - Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
  • C10B 27/00 - Arrangements for withdrawal of the distillation gases
  • F28C 3/08 - Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour with change of state, e.g. absorption, evaporation, condensation

26.

Systems and methods for renewable fuel

      
Application Number 14480211
Grant Number 09127223
Status In Force
Filing Date 2014-09-08
First Publication Date 2015-03-12
Grant Date 2015-09-08
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

27.

Fluidized catalytic cracker riser quench system

      
Application Number 14485000
Grant Number 09102889
Status In Force
Filing Date 2014-09-12
First Publication Date 2015-03-05
Grant Date 2015-08-11
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to a riser quench system comprising a quench line and one or more quench injecting ports for injecting a renewable fuel oil into the riser of a fluidized catalytic cracker co-processing a renewable fuel oil and a petroleum fraction as reactants.

IPC Classes  ?

  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

28.

Method of trading cellulosic-renewable identification numbers

      
Application Number 14490116
Grant Number 09422485
Status In Force
Filing Date 2014-09-18
First Publication Date 2015-03-05
Grant Date 2016-08-23
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to a method of trading cellulosic-renewable identification numbers by co-processing a renewable fuel oil with a petroleum fraction to form a renewable identification number-compliant fuel, obtaining one or more renewable identification numbers, and transferring the rights of renewable identification numbers.

IPC Classes  ?

  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply
  • C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 65/04 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps

29.

Methods for renewable fuels with reduced waste streams

      
Application Number 14484874
Grant Number 09102888
Status In Force
Filing Date 2014-09-12
First Publication Date 2015-03-05
Grant Date 2015-08-11
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a reduced volatility renewable fuel oil as a feedstock and processing it with a petroleum stream in the presence of a catalyst to reduce the generation of waste streams in refinery systems or field upgrading equipment.

IPC Classes  ?

  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

30.

External steam reduction method in a fluidized catalytic cracker

      
Application Number 14484953
Grant Number 09127224
Status In Force
Filing Date 2014-09-12
First Publication Date 2015-03-05
Grant Date 2015-09-08
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present disclosure generally relates to methods to reduce the external steam supplied to a fluidized catalytic cracker by injecting a stream comprising a water-containing renewable fuel oil into a riser of a fluidized catalytic cracker.

IPC Classes  ?

  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

31.

Methods to increase gasoline yield

      
Application Number 14487442
Grant Number 09120988
Status In Force
Filing Date 2014-09-16
First Publication Date 2015-01-01
Grant Date 2015-09-01
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to methods to increase the gasoline and/or light cycle oil yield of a fluidized catalytic cracker processing a petroleum fraction by injecting a stream comprising a renewable fuel oil into a riser of a fluidized catalytic cracker, and the resulting fuels therefrom.

IPC Classes  ?

  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

32.

Generating cellulosic-renewable identification numbers in a refinery

      
Application Number 14487575
Grant Number 09120989
Status In Force
Filing Date 2014-09-16
First Publication Date 2015-01-01
Grant Date 2015-09-01
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to methods of generating cellulosic-renewable identification numbers by thermally processing a cellulosic biomass to form a renewable fuel oil, and then co-processing the renewable fuel oil with a petroleum fraction in a refinery to form a cellulosic-renewable identification number-compliant fuel.

IPC Classes  ?

  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

33.

Systems and methods for renewable fuel

      
Application Number 14314785
Grant Number 10633606
Status In Force
Filing Date 2014-06-25
First Publication Date 2015-01-01
Grant Date 2020-04-28
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids

34.

Preparing a fuel from liquid biomass

      
Application Number 14487522
Grant Number 09410091
Status In Force
Filing Date 2014-09-16
First Publication Date 2015-01-01
Grant Date 2016-08-09
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to methods to prepare a fuel from a liquid biomass by first producing the liquid biomass from a solid biomass by a thermal process, and then processing the liquid biomass with a petroleum fraction in the presence of a catalyst.

IPC Classes  ?

  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10G 45/02 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing
  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 65/04 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps

35.

Systems for fuels from biomass

      
Application Number 14490150
Grant Number 09120990
Status In Force
Filing Date 2014-09-18
First Publication Date 2015-01-01
Grant Date 2015-09-01
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to a system to prepare a fuel from a biomass and a petroleum fraction wherein a renewable fuel oil is obtained via pyrolysis, delivered to the injection point of a refinery system, and then co-processed with a petroleum fraction in the presence of a catalyst.

IPC Classes  ?

  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

36.

Fluidized catalytic cracking apparatus

      
Application Number 14490181
Grant Number 09102890
Status In Force
Filing Date 2014-09-18
First Publication Date 2015-01-01
Grant Date 2015-08-11
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to a fluidized catalytic cracking apparatus having one or more ports for injecting a renewable fuel oil for co-processing the renewable fuel oil and a petroleum fraction.

IPC Classes  ?

  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

37.

SYSTEMS AND METHODS FOR RENEWABLE FUEL

      
Application Number US2014044088
Publication Number 2014/210150
Status In Force
Filing Date 2014-06-25
Publication Date 2014-12-31
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry, A.
  • Graham, Robert, G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • C10L 1/16 - Hydrocarbons
  • C12P 5/00 - Preparation of hydrocarbons

38.

Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material

      
Application Number 14346517
Grant Number 10400175
Status In Force
Filing Date 2012-09-14
First Publication Date 2014-12-11
Grant Date 2019-09-03
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Palmas, Paolo

Abstract

Embodiments of apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material are provided herein. The apparatus comprises a reheater for containing a fluidized bubbling bed comprising an oxygen-containing gas, inorganic heat carrier particles, and char and for burning the char into ash to form heated inorganic particles. An inorganic particle cooler is in fluid communication with the reheater to receive a first portion of the heated inorganic particles. The inorganic particle cooler is configured to receive a cooling medium for indirect heat exchange with the first portion of the heated inorganic particles to form first partially-cooled heated inorganic particles that are fluidly communicated to the reheater and combined with a second portion of the heated inorganic particles to form second partially-cooled heated inorganic particles. A reactor is in fluid communication with the reheater to receive the second partially-cooled heated inorganic particles.

IPC Classes  ?

  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
  • B01J 8/26 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
  • B01J 8/32 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with introduction into the fluidised bed of more than one kind of moving particles
  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • F28D 7/16 - Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
  • F28F 1/14 - Tubular elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending longitudinally
  • F23C 10/04 - Apparatus in which combustion takes place in a fluidised bed of fuel or other particles with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
  • C10C 5/00 - Production of pyroligneous acid

39.

DEVOLATILIZATION OF THERMALLY PRODUCED LIQUIDS

      
Application Number US2013056400
Publication Number 2014/031965
Status In Force
Filing Date 2013-08-23
Publication Date 2014-02-27
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Hopkins, Geoffrey
  • Freel, Barry, A.
  • Clarke, Doug

Abstract

Methods and systems for the devolatilization of thermally produced liquids to raise the flash point are disclosed. Various methods and apparatus can be used to effectively reduce the volatile components, such as wiped film evaporator, falling film evaporator, flash column, packed column, devolatilization vessel or tank.

IPC Classes  ?

40.

SYSTEMS AND METHODS FOR THE DEVOLATILIZATION OF THERMALLY PRODUCED LIQUIDS

      
Document Number 02882993
Status In Force
Filing Date 2013-08-23
Open to Public Date 2014-02-27
Grant Date 2020-07-21
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Hopkins, Geoffrey
  • Freel, Barry A.
  • Clarke, Doug

Abstract

A method of processing a petroleum fraction feedstock and a devolatilized liquid product in a refinery system, wherein the petroleum fraction feedstock and the devolatilized liquid product are co-injected into the refinery system. The method comprises: i) supplying a starting liquid formed by pyrolysis of a biomass and having a flash point as measured by the ASTM D-93 test in a Pensky-Martens closed cup flash point tester below a first threshold of 55-62 .degree.C to a first component; ii) heating the first component to a temperature of 20 .degree.C to 200 .degree.C; iii) obtaining a processed liquid product, wherein the processed liquid has an increased flash point above the first threshold and a reduced concentration of volatile components as compared to the starting liquid; iv) obtaining a volatile components product; and v) processing the processed liquid with the petroleum fraction feedstock in the refinery system.

IPC Classes  ?

  • B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10G 11/02 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
  • C10G 31/06 - Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment

41.

Methods and apparatuses for thermally converting biomass

      
Application Number 13536538
Grant Number 09670413
Status In Force
Filing Date 2012-06-28
First Publication Date 2014-01-02
Grant Date 2017-06-06
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Baird, Lance Awender
  • Freel, Barry
  • Clarke, Doug
  • Morin, Gregory Joseph

Abstract

Methods and apparatuses for thermally converting or pyrolyzing biomass are provided. In one embodiment, a method of thermally converting biomass includes introducing the biomass to a reactor feed chamber. The method provides for flowing a low oxygen gas into the reactor feed chamber to purge the reactor feed chamber and biomass of oxygen. The method also includes delivering the purged biomass to a thermal conversion reactor and thermally converting the biomass in the thermal conversion reactor.

IPC Classes  ?

  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10B 49/00 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
  • C10B 49/16 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
  • C10B 49/20 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
  • C10B 49/10 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form according to the "fluidised bed" technique

42.

Char-handling processes in a pyrolysis system

      
Application Number 13810405
Grant Number 09422478
Status In Force
Filing Date 2011-07-08
First Publication Date 2013-12-12
Grant Date 2016-08-23
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Palmas, Paolo
  • Sechrist, Paul A.
  • Kulprathipanja, Sid
  • Frey, Stanley J.
  • Freel, Barry
  • Myers, Daniel N.

Abstract

Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.

IPC Classes  ?

  • F23B 90/00 - Combustion methods not related to a particular type of apparatus
  • C10B 23/00 - Other methods of heating coke ovens
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10C 5/00 - Production of pyroligneous acid
  • C10K 1/02 - Dust removal
  • F23G 5/027 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels including pretreatment pyrolising or gasifying
  • F23G 5/30 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels with combustion in a fluidised bed
  • F23G 5/46 - Recuperation of heat
  • F23G 5/50 - Control or safety arrangements
  • F23G 7/10 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of specific waste or low grade fuels, e.g. chemicals of field or garden waste

43.

SYSTEMS AND METHODS FOR RENEWABLE FUEL

      
Application Number US2012068876
Publication Number 2013/090229
Status In Force
Filing Date 2012-12-11
Publication Date 2013-06-20
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry, A.
  • Graham, Robert, G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10G 9/00 - Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils

44.

SYSTEMS AND METHODS FOR RENEWABLE FUEL

      
Document Number 03027224
Status In Force
Filing Date 2012-12-11
Open to Public Date 2013-06-20
Grant Date 2020-06-16
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only

45.

SYSTEMS AND METHODS FOR RENEWABLE FUEL

      
Document Number 03077789
Status In Force
Filing Date 2012-12-11
Open to Public Date 2013-06-20
Grant Date 2022-09-20
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the pro<:lucts, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • F27B 1/00 - Shaft or like vertical or substantially vertical furnaces

46.

SYSTEMS AND METHODS FOR RENEWABLE FUEL

      
Document Number 03167505
Status Pending
Filing Date 2012-12-11
Open to Public Date 2013-06-20
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Graham, Robert G
  • Freel, Barry A.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
  • F27B 1/00 - Shaft or like vertical or substantially vertical furnaces

47.

SYSTEMS AND METHODS FOR RENEWABLE FUEL

      
Document Number 02858968
Status In Force
Filing Date 2012-12-11
Open to Public Date 2013-06-20
Grant Date 2019-01-29
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/18 - Organic compounds containing oxygen

48.

Systems and methods for renewable fuel

      
Application Number 13709822
Grant Number 09109177
Status In Force
Filing Date 2012-12-10
First Publication Date 2013-06-13
Grant Date 2015-08-18
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry A.
  • Graham, Robert G.

Abstract

The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.

IPC Classes  ?

  • C10L 1/18 - Organic compounds containing oxygen
  • C10L 1/16 - Hydrocarbons
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10G 11/18 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised bed" technique
  • B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
  • C10L 1/04 - Liquid carbonaceous fuels essentially based on blends of hydrocarbons
  • C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • G06Q 40/04 - Trading Exchange, e.g. stocks, commodities, derivatives or currency exchange
  • G06Q 50/06 - Energy or water supply

49.

APPARATUSES AND METHODS FOR CONTROLLING HEAT FOR RAPID THERMAL PROCESSING OF CARBONACEOUS MATERIAL

      
Document Number 02849646
Status In Force
Filing Date 2012-09-14
Open to Public Date 2013-03-28
Grant Date 2020-07-14
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Palmas, Paolo

Abstract

Embodiments of apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material are provided herein. The apparatus comprises a reheater for containing a fluidized bubbling bed comprising an oxygen-containing gas, inorganic heat carrier particles, and char and for burning the char into ash to form heated inorganic particles. An inorganic particle cooler is in fluid communication with the reheater to receive a first portion of the heated inorganic particles. The inorganic particle cooler is configured to receive a cooling medium for indirect heat exchange with the first portion of the heated inorganic particles to form first partially-cooled heated inorganic particles that are fluidly communicated to the reheater and combined with a second portion of the heated inorganic particles to form second partially-cooled heated inorganic particles. A reactor is in fluid communication with the reheater to receive the second partially-cooled heated inorganic particles.

IPC Classes  ?

  • C10B 49/18 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form according to the "moving bed" technique
  • C10G 9/30 - Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material according to the "moving bed" technique
  • C10G 55/04 - Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one thermal cracking step

50.

Apparatuses for controlling heat for rapid thermal processing of carbonaceous material and methods for the same

      
Application Number 13240513
Grant Number 10041667
Status In Force
Filing Date 2011-09-22
First Publication Date 2013-03-28
Grant Date 2018-08-07
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Myers, Daniel N.
  • Palmas, Paolo

Abstract

A rapid thermal processing system includes an inorganic heat carrier particles reheater coupled to an inorganic particle cooler. For example. inorganic heat carrier particles may be cooled in a shell and tube inorganic particle cooler by indirect heat exchange with a cooling medium. The cooled inorganic heat carrier particles may then be supplied to a reactor to transfer heat to carbonaceous material.

IPC Classes  ?

  • F23C 10/18 - Apparatus in which combustion takes place in a fluidised bed of fuel or other particles DetailsAccessories
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • F23C 10/26 - Devices for removal of material from the bed combined with devices for partial reintroduction of material into the bed, e.g. after separation of agglomerated parts

51.

Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material

      
Application Number 13240570
Grant Number 09044727
Status In Force
Filing Date 2011-09-22
First Publication Date 2013-03-28
Grant Date 2015-06-02
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Palmas, Paolo

Abstract

Embodiments of apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material are provided herein. The apparatus comprises a reheater for containing a fluidized bubbling bed comprising an oxygen-containing gas, inorganic heat carrier particles, and char and for burning the char into ash to form heated inorganic particles. An inorganic particle cooler is in fluid communication with the reheater to receive a first portion of the heated inorganic particles. The inorganic particle cooler is configured to receive a cooling medium for indirect heat exchange with the first portion of the heated inorganic particles to form first partially-cooled heated inorganic particles that are fluidly communicated to the reheater and combined with a second portion of the heated inorganic particles to form second partially-cooled heated inorganic particles. A reactor is in fluid communication with the reheater to receive the second partially-cooled heated inorganic particles.

IPC Classes  ?

  • C10B 51/00 - Destructive distillation of solid carbonaceous materials by combined direct and indirect heating
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • F28F 7/00 - Elements not covered by group , , or
  • B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
  • B01J 8/26 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
  • B01J 8/32 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with introduction into the fluidised bed of more than one kind of moving particles
  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • F28D 7/16 - Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
  • F28F 1/14 - Tubular elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending longitudinally
  • C10C 5/00 - Production of pyroligneous acid

52.

APPARATUSES AND METHODS FOR CONTROLLING HEAT FOR RAPID THERMAL PROCESSING

      
Application Number US2012055384
Publication Number 2013/043485
Status In Force
Filing Date 2012-09-14
Publication Date 2013-03-28
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Palmas, Paolo

Abstract

Embodiments of apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material are provided herein. The apparatus comprises a reheater for containing a fluidized bubbling bed comprising an oxygen-containing gas, inorganic heat carrier particles, and char and for burning the char into ash to form heated inorganic particles. An inorganic particle cooler is in fluid communication with the reheater to receive a first portion of the heated inorganic particles. The inorganic particle cooler is configured to receive a cooling medium for indirect heat exchange with the first portion of the heated inorganic particles to form first partially-cooled heated inorganic particles that are fluidly communicated to the reheater and combined with a second portion of the heated inorganic particles to form second partially-cooled heated inorganic particles. A reactor is in fluid communication with the reheater to receive the second partially-cooled heated inorganic particles.

IPC Classes  ?

  • C10B 49/18 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form according to the "moving bed" technique
  • C10G 9/30 - Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material according to the "moving bed" technique
  • C10G 55/04 - Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one thermal cracking step

53.

Methods and apparatuses for rapid thermal processing of carbonaceous material

      
Application Number 13231625
Grant Number 09347005
Status In Force
Filing Date 2011-09-13
First Publication Date 2013-03-14
Grant Date 2016-05-24
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Palmas, Paolo

Abstract

Embodiments of methods and apparatuses for rapid thermal processing of carbonaceous material are provided herein. The method comprises the step of contacting a carbonaceous feedstock with heated inorganic heat carrier particles at reaction conditions effective to rapidly pyrolyze the carbonaceous feedstock to form a product stream comprising pygas, pyrolysis oil, and solids. The solids comprise char and cooled inorganic heat carrier particles. The reaction conditions include a reactor pressure of about 70 kPa gauge or greater.

IPC Classes  ?

  • C10B 49/20 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material

54.

HEAT REMOVAL AND RECOVERY IN BIOMASS PYROLYSIS

      
Document Number 02828037
Status In Force
Filing Date 2012-02-01
Open to Public Date 2012-08-30
Grant Date 2019-03-12
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Palmas, Paolo
  • Myers, Daniel N. (deceased)

Abstract

Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.

IPC Classes  ?

  • C10B 53/00 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • F23G 5/027 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels including pretreatment pyrolising or gasifying

55.

HEAT REMOVAL AND RECOVERY IN BIOMASS PYROLYSIS

      
Application Number US2012023460
Publication Number 2012/115754
Status In Force
Filing Date 2012-02-01
Publication Date 2012-08-30
Owner ENSYN RENEWABLES, INC. (USA)
Inventor Myers, Daniel, N.

Abstract

Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.

IPC Classes  ?

  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10B 53/00 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
  • B09B 3/00 - Destroying solid waste or transforming solid waste into something useful or harmless
  • F23G 5/027 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels including pretreatment pyrolising or gasifying

56.

Heat removal and recovery in biomass pyrolysis

      
Application Number 13031701
Grant Number 09441887
Status In Force
Filing Date 2011-02-22
First Publication Date 2012-08-23
Grant Date 2016-09-13
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Kulprathipanja, Sathit
  • Palmas, Paolo
  • Myers, Daniel N

Abstract

Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.

IPC Classes  ?

  • F27D 3/00 - ChargingDischargingManipulation of charge
  • F23B 70/00 - Combustion apparatus characterised by means for returning solid combustion residues to the combustion chamber
  • F27B 15/02 - Details, accessories or equipment specially adapted for furnaces of these types
  • F27D 17/00 - Arrangements for using waste heatArrangements for using, or disposing of, waste gases
  • F23G 5/027 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels including pretreatment pyrolising or gasifying
  • F23G 5/30 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels with combustion in a fluidised bed
  • F23G 7/10 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of specific waste or low grade fuels, e.g. chemicals of field or garden waste
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids

57.

Low water biomass-derived pyrolysis oils and processes for producing the same

      
Application Number 12842394
Grant Number 08519205
Status In Force
Filing Date 2010-07-23
First Publication Date 2012-01-26
Grant Date 2013-08-27
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Frey, Stanley J.
  • Clarke, Douglas A.

Abstract

Low water-containing biomass-derived pyrolysis oils and processes for producing them are provided. The process includes condensing pyrolysis gases including condensable pyrolysis gases and non-condensable gases to separate the condensable pyrolysis gases from the non-condensable gases, the non-condensable gases having a water content, drying the non-condensable pyrolysis gases to reduce the water content of the-non-condensable gases to form reduced-water non-condensable pyrolysis gases, and providing the reduced-water non-condensable pyrolysis gases to a pyrolysis reactor for forming the biomass-derived pyrolysis oil.

IPC Classes  ?

  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal

58.

LOW WATER BIOMASS-DERIVED PYROLYSIS OILS AND PROCESSES FOR PRODUCING THE SAME

      
Document Number 02806181
Status In Force
Filing Date 2011-07-14
Open to Public Date 2012-01-26
Grant Date 2018-03-20
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Frey, Stanley J.
  • Clarke, Douglas A.

Abstract

Low water-containing biomass-derived pyrolysis oils and processes for producing them are provided. The process (200) includes condensing (204) pyrolysis gases including condensable pyrolysis gases and non-condensable gases to separate the condensable pyrolysis gases from the non-condensable gases, the non-condensable gases having a water content, drying (206) the non-condensable pyrolysis gases to reduce the water content of the-non-condensable gases to form reduced-water non-condensable pyrolysis gases, and providing (208) the reduced-water non-condensable pyrolysis gases to a pyrolysis reactor for forming the biomass-derived pyrolysis oil.

IPC Classes  ?

  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only

59.

LOW WATER BIOMASS-DERIVED PYROLYSIS OILS AND PROCESSES FOR PRODUCING THE SAME

      
Application Number US2011044011
Publication Number 2012/012260
Status In Force
Filing Date 2011-07-14
Publication Date 2012-01-26
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Frey, Stanley J.
  • Clarke, Douglas A.

Abstract

Low water-containing biomass-derived pyrolysis oils and processes for producing them are provided. The process (200) includes condensing (204) pyrolysis gases including condensable pyrolysis gases and non-condensable gases to separate the condensable pyrolysis gases from the non-condensable gases, the non-condensable gases having a water content, drying (206) the non-condensable pyrolysis gases to reduce the water content of the-non-condensable gases to form reduced-water non-condensable pyrolysis gases, and providing (208) the reduced-water non-condensable pyrolysis gases to a pyrolysis reactor for forming the biomass-derived pyrolysis oil.

IPC Classes  ?

  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only

60.

CHAR-HANDLING PROCESSES IN A PYROLYSIS SYSTEM

      
Document Number 02805386
Status In Force
Filing Date 2011-07-08
Open to Public Date 2012-01-19
Grant Date 2017-08-01
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Palmas, Paolo
  • Sechrist, Paul A.
  • Kulprathipanja, Sid
  • Frey, Stanley J.
  • Freel, Barry
  • Myers, Daniel N. (deceased)

Abstract

Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.

IPC Classes  ?

  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10J 3/72 - Other features
  • C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
  • F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures

61.

CHAR-HANDLING PROCESSES IN A PYROLYSIS SYSTEM

      
Application Number US2011043295
Publication Number 2012/009207
Status In Force
Filing Date 2011-07-08
Publication Date 2012-01-19
Owner
  • ENSYN RENEWABLES, INC. (USA)
  • MYERS, Vincenza (USA)
Inventor Myers, Daniel, N.

Abstract

Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.

IPC Classes  ?

  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10G 3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
  • C10J 3/72 - Other features
  • C10L 1/02 - Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
  • F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures

62.

Char-handling processes in a pyrolysis system

      
Application Number 12837376
Grant Number 08499702
Status In Force
Filing Date 2010-07-15
First Publication Date 2012-01-19
Grant Date 2013-08-06
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Palmas, Paolo
  • Sechrist, Paul Alvin
  • Myers, Daniel N.
  • Kulprathipanja, Sid
  • Frey, Stanley Joseph
  • Freel, Barry

Abstract

Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.

IPC Classes  ?

  • F23B 90/00 - Combustion methods not related to a particular type of apparatus

63.

RFO

      
Serial Number 85515302
Status Registered
Filing Date 2012-01-12
Registration Date 2019-09-24
Owner Ensyn Renewables, Inc. ()
NICE Classes  ? 04 - Industrial oils and greases; lubricants; fuels

Goods & Services

Liquid fuel derived from cellulosic biomass

64.

RFO

      
Application Number 153596600
Status Registered
Filing Date 2011-07-15
Registration Date 2016-01-15
Owner Ensyn Renewables, Inc. (USA)
NICE Classes  ?
  • 04 - Industrial oils and greases; lubricants; fuels
  • 37 - Construction and mining; installation and repair services
  • 39 - Transport, packaging, storage and travel services
  • 40 - Treatment of materials; recycling, air and water treatment,
  • 42 - Scientific, technological and industrial services, research and design

Goods & Services

(1) Liquid fuel derived from cellulosic biomass namely for heating and electricity, biobased refinery feedstocks and transportation fuels. (1) Production of liquid fuel by the conversion of cellulosic biomass; transportation and delivery of liquid fuel; transportation and delivery of liquid fuel for thermal and power applications; design, manufacture and installation of rapid thermal processing equipment and process equipment for the production of liquid fuel.

65.

Rapid thermal conversion of biomass

      
Application Number 13021508
Grant Number 08961743
Status In Force
Filing Date 2011-02-04
First Publication Date 2011-05-26
Grant Date 2015-02-24
Owner Ensyn Renewables, Inc. (USA)
Inventor Freel, Barry

Abstract

An improved rapid thermal conversion process for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production, is disclosed. In the process, biomass material, e.g., wood, is fed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product.

IPC Classes  ?

  • C10B 21/20 - Methods of heating ovens of the chamber oven type
  • B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
  • C10G 9/28 - Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
  • C10K 1/04 - Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials

66.

Mitigation of deposits and secondary reactions in thermal conversion processes

      
Application Number 12791145
Grant Number 08726443
Status In Force
Filing Date 2010-06-01
First Publication Date 2010-09-23
Grant Date 2014-05-20
Owner Ensyn Renewables, Inc. (USA)
Inventor
  • Freel, Barry
  • Hopkins, Geoffrey

Abstract

Described herein are systems and methods for reducing cumulative deposition and unwanted secondary thermal reactions in pyrolysis and other thermal conversion processes. In an embodiment, a system comprises a device, referred to as a reamer, for removing product deposits between thermal conversion and condensation operations of a pyrolysis process. The reamer may comprise, but is not limited to, a mechanical reciprocating rod or ram, a mechanical auger, a drill bit, a high-temperature wiper, brush, or punch to remove deposits and prevent secondary reactions. Alternatively or in addition, the reamer may use a high-velocity curtain or jet (i.e., a hydraulic or pneumatic stream) of vapor, product gas, recycle gas, other gas jet or non-condensing liquid to remove deposits. Preferably, the reamer removes deposits during the pyrolysis process allowing for continuous operation of the pyrolysis process.

IPC Classes  ?

  • B08B 1/00 - Cleaning by methods involving the use of tools
  • B08B 9/04 - Cleaning the internal surfacesRemoval of blockages using cleaning devices introduced into and moved along the pipes

67.

Thermal extraction method and product

      
Application Number 12295916
Grant Number 09127208
Status In Force
Filing Date 2007-04-02
First Publication Date 2009-12-03
Grant Date 2015-09-08
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Boulard, David
  • Graham, Robert G.
  • Freel, Barry

Abstract

The present invention is related to a thermal extract of a plant material and methods of extraction thereof. The method of producing a thermal extract from a plant starting material by means of a thermal extraction of the starting material wherein the improvement consists in requiring smaller amounts of costly and/or toxic organic solvents for the extraction and partitioning steps.

IPC Classes  ?

  • C07D 305/00 - Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • A61K 36/00 - Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
  • A61K 36/13 - Coniferophyta (gymnosperms)
  • C10B 49/22 - Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
  • C10C 5/00 - Production of pyroligneous acid
  • C07D 305/14 - Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms condensed with carbocyclic rings or ring systems

68.

MITIGATION OF DEPOSITS AND SECONDARY REACTIONS IN THERMAL CONVERSION PROCESSES

      
Document Number 02719698
Status In Force
Filing Date 2009-03-06
Open to Public Date 2009-10-29
Grant Date 2016-08-30
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry
  • Hopkins, Geoffrey

Abstract

Described herein are systems and methods for reducing cumulative deposition and unwanted secondary thermal reactions in pyrolysis and other thermal conversion processes. In an embodiment, a system comprises a device, referred to as a reamer, for removing product deposits between thermal conversion and condensation operations of a pyrolysis process. The reamer may comprise, but is not limited to, a mechanical reciprocating rod or ram, a mechanical auger, a drill bit, a high-temperature wiper, brush, or punch to remove deposits and prevent secondary reactions. Alternatively or in addition, the reamer may use a high-velocity curtain or jet (i.e., a hydraulic or pneumatic stream) of vapor, product gas, recycle gas, other gas jet or non-condensing liquid to remove deposits. Preferably, the reamer removes deposits during the pyrolysis process allowing for continuous operation of the pyrolysis process.

IPC Classes  ?

  • B08B 9/032 - Cleaning the internal surfacesRemoval of blockages by the mechanical action of a moving fluid, e.g. by flushing
  • B08B 9/045 - Cleaning the internal surfacesRemoval of blockages using cleaning devices introduced into and moved along the pipes moved by externally powered mechanical linkage, e.g. pushed or drawn through the pipes the cleaning devices being rotated while moved
  • C10G 75/00 - Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
  • C10J 3/72 - Other features

69.

Mitigation of deposits and secondary reactions in thermal conversion processes

      
Application Number 12110197
Grant Number 08097090
Status In Force
Filing Date 2008-04-25
First Publication Date 2009-10-29
Grant Date 2012-01-17
Owner Ensyn Renewables Inc. (USA)
Inventor
  • Freel, Barry
  • Hopkins, Geoffrey

Abstract

Described herein are systems and methods for reducing cumulative deposition and unwanted secondary thermal reactions in pyrolysis and other thermal conversion processes. In an embodiment, a system comprises a device, referred to as a reamer, for removing product deposits between thermal conversion and condensation operations of a pyrolysis process. The reamer may comprise, but is not limited to, a mechanical reciprocating rod or ram, a mechanical auger, a drill bit, a high-temperature wiper, brush, or punch to remove deposits and prevent secondary reactions. Alternatively or in addition, the reamer may use a high-velocity curtain or jet (i.e., a hydraulic or pneumatic stream) of vapor, product gas, recycle gas, other gas jet or non-condensing liquid to remove deposits. Preferably, the reamer removes deposits during the pyrolysis process allowing for continuous operation of the pyrolysis process.

IPC Classes  ?

  • B08B 9/04 - Cleaning the internal surfacesRemoval of blockages using cleaning devices introduced into and moved along the pipes

70.

MITIGATION OF DEPOSITS AND SECONDARY REACTIONS IN THERMAL CONVERSION PROCESSES

      
Application Number US2009036289
Publication Number 2009/131757
Status In Force
Filing Date 2009-03-06
Publication Date 2009-10-29
Owner ENSYN RENEWABLES, INC. (USA)
Inventor
  • Freel, Barry
  • Hopkins, Geoffrey

Abstract

Described herein are systems and methods for reducing cumulative deposition and unwanted secondary thermal reactions in pyrolysis and other thermal conversion processes. In an embodiment, a system comprises a device, referred to as a reamer, for removing product deposits between thermal conversion and condensation operations of a pyrolysis process. The reamer may comprise, but is not limited to, a mechanical reciprocating rod or ram, a mechanical auger, a drill bit, a high-temperature wiper, brush, or punch to remove deposits and prevent secondary reactions. Alternatively or in addition, the reamer may use a high-velocity curtain or jet (i.e., a hydraulic or pneumatic stream) of vapor, product gas, recycle gas, other gas jet or non-condensing liquid to remove deposits. Preferably, the reamer removes deposits during the pyrolysis process allowing for continuous operation of the pyrolysis process.

IPC Classes  ?

  • C10G 9/36 - Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours

71.

Rapid thermal conversion of biomass

      
Application Number 11943329
Grant Number 07905990
Status In Force
Filing Date 2007-11-20
First Publication Date 2009-06-04
Grant Date 2011-03-15
Owner Ensyn Renewables, Inc. (USA)
Inventor Freel, Barry

Abstract

A rapid thermal conversion process for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. Biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. The liquid product may itself be used as the quench media.

IPC Classes  ?

  • C10B 47/00 - Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
  • C10G 1/00 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal

72.

RAPID THERMAL CONVERSION OF BIOMASS

      
Document Number 02705775
Status In Force
Filing Date 2008-11-10
Open to Public Date 2009-05-28
Grant Date 2014-01-14
Owner ENSYN RENEWABLES, INC. (USA)
Inventor Freel, Barry A.

Abstract

A rapid thermal conversion process for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. Biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. The liquid product may itself be used as the quench media.

IPC Classes  ?

  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10G 1/02 - Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation

73.

RAPID THERMAL CONVERSION OF BIOMASS

      
Application Number US2008083040
Publication Number 2009/067350
Status In Force
Filing Date 2008-11-10
Publication Date 2009-05-28
Owner ENSYN RENEWABLES, INC. (USA)
Inventor Freel, Barry A.

Abstract

The present invent provides improved rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. In an embodiment, biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. In one embodiment, the liquid product itself is used as the quench media.

IPC Classes  ?

  • C10B 53/02 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
  • C10B 9/00 - Beehive ovens