The instant disclosure relates to textile materials having an acid reactive functionalized polymer layer and a non-acid reactive functionalized layer coupled thereto. The acid reactive functionalized polymer layer may include: a polyamide polymer that captures and neutralizes acidic molecules; a hydrophilic polyether block amide copolymer; a maleic anhydride-grafted ethylene copolymer; and a non-halogenated flame retardant. The acid reactive functionalized polymer layer is fire resistant, acid neutralizing, and allows water vapor to transfer therethrough. The non-acid reactive functionalized layer and acid reactive functionalized polymer layer are free of per- and polyfluoroalkyl substances. The polyamide may include Nylon 12, Nylon 6, or Nylon 6,6 functionalized with an amine (e.g., a pyridine derivative and/or a halogenated-dimethylalkylamine) having a nitrogen that captures and neutralizes acidic molecules. The halogenated-dimethylalkylamine may include a general chemical formula of (CH3)2N—R—X, where R is an alkyl containing 1-12 carbon atoms, and X is chlorine or bromine.
B32B 27/08 - Layered products essentially comprising synthetic resin as the main or only constituent of a layer next to another layer of a specific substance of synthetic resin of a different kind
B29B 9/10 - Making granules by moulding the material, i.e. treating it in the molten state
B29C 48/08 - Flat, e.g. panels flexible, e.g. films
B29K 77/00 - Use of polyamides, e.g. polyesteramides, as moulding material
B32B 37/18 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
A modified acid neutralizing polymer material includes a substrate having a surface including an acid neutralizing polymer material and a modified layer formed on the acid neutralizing polymer material surface. The modified layer includes a reaction product between a basic salt solution and the acid neutralizing polymer material surface. A method for preparing the modified acid neutralizing polymer material includes receiving a substrate comprising an acid neutralizing polymer material, applying a basic salt solution to the substrate to create a modified substrate through a reaction product between the basic salt solution and the acid neutralizing polymer material to form the modified acid neutralizing polymer material, allowing the basic salt solution to evaporate from the modified substrate, and optionally, removing unreacted basic salt material from the modified acid neutralizing polymer material.
C08L 79/00 - Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups
A modified acid neutralizing polymer material includes a substrate having a surface including an acid neutralizing polymer material and a modified layer formed on the acid neutralizing polymer material surface. The modified layer includes a reaction product between a basic salt solution and the acid neutralizing polymer material surface. A method for preparing the modified acid neutralizing polymer material includes receiving a substrate comprising an acid neutralizing polymer material, applying a basic salt solution to the substrate to create a modified substrate through a reaction product between the basic salt solution and the acid neutralizing polymer material to form the modified acid neutralizing polymer material, allowing the basic salt solution to evaporate from the modified substrate, and optionally, removing unreacted basic salt material from the modified acid neutralizing polymer material.
C09D 177/00 - Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chainCoating compositions based on derivatives of such polymers
C08G 69/48 - Polymers modified by chemical after-treatment
D06M 13/207 - Substituted carboxylic acids, e.g. by hydroxy or keto groupsAnhydrides, halides or salts thereof
A method of making an acid neutralizing polymer material includes preparing a first reaction mixture including a buffering agent and an amine salt of either a halogenated tertiary amine or a haloalkyl heterocyclic aromatic amine. The first reaction mixture is added to a first compounding machine and reacted for a time and at a temperature sufficient to produce a neutralized amine. A second reaction mixture including a polyamide material and a strong base is prepared, added to the first reaction product and reacted for a time and at a temperature sufficient to produce the acid neutralizing polymer material. Alternatively, the buffering agent, amine salt of either a halogenated tertiary amine or a haloalkyl heterocyclic aromatic amine, and the polyamide material may be added and reacted for a time and at a temperature sufficient to produce the acid neutralizing polymer material.
B29B 9/06 - Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
B29B 13/10 - Conditioning or physical treatment of the material to be shaped by grinding, e.g. by trituratingConditioning or physical treatment of the material to be shaped by sievingConditioning or physical treatment of the material to be shaped by filtering
B29C 48/00 - Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired formApparatus therefor
B29C 48/40 - Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws, e.g. twin screw extruders
B29K 77/00 - Use of polyamides, e.g. polyesteramides, as moulding material
5.
METHOD OF MAKING AN ACID NEUTRALIZING POLYMER THROUGH REACTIVE COMPOUNDING
A method of making an acid neutralizing polymer material includes preparing a first reaction mixture including a buffering agent and an amine salt of either a halogenated tertiary amine or a haloalkyl heterocyclic aromatic amine. The first reaction mixture is added to a first compounding machine and reacted for a time and at a temperature sufficient to produce a neutralized amine. A second reaction mixture including a polyamide material and a strong base is prepared, added to the first reaction product and reacted for a time and at a temperature sufficient to produce the acid neutralizing polymer material. Alternatively, the buffering agent, amine salt of either a halogenated tertiary amine or a haloalkyl heterocyclic aromatic amine, and the polyamide material may be added and reacted for a time and at a temperature sufficient to produce the acid neutralizing polymer material.
A method of making an acid neutralizing polymer includes: a) preparing a first reaction mixture by blending of a polyamide material, a solid strongly basic material, and a halogenated-dimethylalkylamine; b) adding the first reaction mixture to a first compounding machine; c) reacting the first reaction mixture for a time and at a temperature sufficient to produce a first reaction product; d) preparing a second reaction mixture including the polyamide material; e) adding the second reaction mixture to a second compounding machine; f) reacting the second reaction mixture for a time and at a temperature sufficient to produce a second reaction product; g) preparing a third reaction mixture by blending the first reaction mixture and the second reaction mixture; h) adding the third reaction mixture to a third compounding machine; and i) reacting the third reaction mixture for a time and at a temperature sufficient to produce the acid neutralizing polymer.
A method of making an acid neutralizing polymer includes: a) preparing a first reaction mixture by blending of a polyamide material, a solid strongly basic material, and a halogenated-dimethylalkylamine; b) adding the first reaction mixture to a first compounding machine; c) reacting the first reaction mixture for a time and at a temperature sufficient to produce a first reaction product; d) preparing a second reaction mixture including the polyamide material; e) adding the second reaction mixture to a second compounding machine; f) reacting the second reaction mixture for a time and at a temperature sufficient to produce a second reaction product; g) preparing a third reaction mixture by blending the first reaction mixture and the second reaction mixture; h) adding the third reaction mixture to a third compounding machine; and i) reacting the third reaction mixture for a time and at a temperature sufficient to produce the acid neutralizing polymer.
A method of preparing an acid neutralizing polymer powder (ANPP) includes preparing a first reaction product by contacting and reacting virgin polyamide powder material with tert-butoxide in a first aliquot of a polar aprotic solvent and preparing a mixture of an halogenated dialkylalkylamine to a second aliquot of the polar aprotic solvent. ANPP is prepared by mixing the first reaction product and the mixture for a period of time and at a temperature sufficient to produce the ANPP.
C08G 69/26 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
9.
Acid neutralizing polymer materal and method of making same
A method of preparing an acid reactive functionalized polyamide includes preparing a first reaction product by contacting and reacting virgin polyamide fabric material with tert-butoxide in a first aliquot of a polar aprotic solvent and preparing a second reaction product by adding an amine to a second aliquot of the polar aprotic solvent. A third reaction product is prepared by mixing the first reaction product and the second reaction product where the third reaction product is the acid reactive functionalized polyamide. The preparation of each respective reaction product is for a period of time and at a temperature sufficient to produce the respective reaction product.
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