Air Liquide Large Industries U.S. LP

United States of America

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IPC Class
B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth 11
C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts 8
G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations 8
G01K 7/02 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples 7
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes 6
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Status
Pending 6
Registered / In Force 45
Found results for  patents

1.

METHOD FOR REMOVING LIQUID DROPLETS FROM A GAS AND PRESSURIZING THE RESULTING LIQUID

      
Application Number 18530527
Status Pending
Filing Date 2023-12-06
First Publication Date 2025-06-12
Owner
  • Air Liquide Large Industries U.S. LP (USA)
  • L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude (France)
Inventor
  • Miller, Gary D.
  • Light, Joshua

Abstract

A method for removing entrained liquid droplets from a gas is provided. This method includes introducing a gas with entrained liquid droplets into a cyclone separator, thereby producing a gaseous portion and a liquid portion, wherein the gaseous portion exits the cyclone separator, and wherein the liquid portion is restricted by a liquid control valve and collected in a reservoir volume in the cyclone separator. The method also includes opening the liquid control valve upon receiving a signal from a liquid level sensor located in the reservoir volume, the liquid portion exits the cyclone separator and is introduced into a lock hopper. The method also provides a pressurized vapor stream to the lock hopper, thereby pressurizing the lock hopper, and then withdrawing a pressurized liquid stream from the lock hopper.

IPC Classes  ?

  • F25J 3/08 - Separating gaseous impurities from gases or gaseous mixtures

2.

METHOD FOR REMOVING ENTRAINED LIQUID DROPLETS FROM A CRYOGENIC GAS

      
Application Number 18530512
Status Pending
Filing Date 2023-12-06
First Publication Date 2025-06-12
Owner
  • Air Liquide Large Industries U.S. LP (USA)
  • L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude (France)
Inventor
  • Miller, Gary D.
  • Light, Joshua

Abstract

A method for removing entrained liquid droplets from a gas is provided. The method includes introducing a gas with entrained liquid droplets into a cyclone separator, thereby producing a gaseous portion and a liquid portion. Wherein the gaseous portion exits the cyclone separator, and wherein the liquid portion is restricted by a liquid control valve and collected in a reservoir volume in the cyclone separator. The method also includes opening the liquid control valve upon receiving a signal from a liquid level sensor located in the reservoir volume, the liquid portion thereby exiting the cyclone separator.

IPC Classes  ?

  • B01D 45/16 - Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by the winding course of the gas stream
  • B01D 45/18 - Cleaning-out devices
  • F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation

3.

METHOD FOR PRESSURIZING A LIQUID EXITING A PHASE SEPARATOR

      
Application Number 18530483
Status Pending
Filing Date 2023-12-06
First Publication Date 2025-06-12
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A method for pressurizing a liquid exiting a phase separator includes opening an inlet control valve, thereby providing a two-phase fluid stream to a phase separator and producing a vapor stream and a liquid stream. Wherein a first liquid control valve prevents the liquid stream from leaving the phase separator. Then closing the inlet control valve and opening the first liquid control valve, thereby withdrawing the liquid stream from the phase separator and introducing the liquid stream into a lock hopper. Wherein, a second liquid control valve prevents the liquid stream from leaving the lock hopper. Then closing the first liquid control valve and then opening a pressurized vapor control valve, thereby providing a pressurized vapor stream to the lock hopper, thereby pressurizing the lock hopper. Then closing the pressurized vapor control valve, and opening the second liquid control valve, thereby withdrawing a pressurized liquid stream from the lock hopper.

IPC Classes  ?

  • F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation

4.

METHOD FOR SECURING NUTS IN A HIGH VIBRATING ENVIRONMENT

      
Application Number 18529874
Status Pending
Filing Date 2023-12-05
First Publication Date 2025-06-05
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

An apparatus for securing nuts in a vibrating environment, including a plurality of anti-vibration adaptors, designed to mate with a nut in a vibrating environment, and a plurality of anti-vibration rods. Wherein at least two adjacent anti-vibration adaptors are rigidly linked by an anti-vibration rod, thereby forming an anti-vibration web. A method for securing nuts in a vibrating environment, including attaching an anti-vibration adaptor to each of a plurality of nuts in a vibrating environment, and rigidly linking each anti-vibration adaptor to at least two adjacent anti-vibration adaptors, thereby forming an anti-vibration web. Thus, allowing each anti-vibration adaptor to be associated with a specific nut, and prohibiting any anti-vibration adaptor and the associated nut to turn.

IPC Classes  ?

  • F16B 39/10 - Locking of screws, bolts, or nuts in which the locking takes place after screwing down by a plate or ring immovable with regard to the bolt or object

5.

APPARATUS AND METHOD FOR CONTROLLING CATALYST TEMPERATURE WITHIN A REACTOR TUBE

      
Application Number 18529914
Status Pending
Filing Date 2023-12-05
First Publication Date 2025-06-05
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A method and apparatus for adjusting the temperature inside a reformer tube is provided. This includes utilizing at least one heating element. The heating element is inserted inside the reformer tube and is located approximately at the axial center of the reformer tube. The reformer tube is then filled with catalyst, thereby maintaining the central location of the heating element. The heat input of the heating element may now be adjusted, thereby controlling the temperature of the catalyst.

IPC Classes  ?

  • B01J 8/06 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds in tube reactorsChemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the solid particles being arranged in tubes
  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts

6.

APPARATUS AND METHOD FOR CONTROLLING CATALYST TEMPERATURE WITHIN A REACTOR TUBE

      
Application Number 18529821
Status Pending
Filing Date 2023-12-05
First Publication Date 2025-06-05
Owner Air Liquide Large Industries U.S.LP (USA)
Inventor Miller, Gary D.

Abstract

Method and apparatus for adjusting the temperature inside a reformer tube. Including providing at least one axial quench lance, wherein the at least one axial quench lance configured to receive a temperature control gas, the at least one axial quench lance having multiple delivery holes, and the at least one axial quench lance configured to deliver the temperature control gas through the multiple delivery holes. Inserting the at least one axial quench lance inside the reformer tube, wherein the at least one axial quench lance is located approximately at the axial center of the reformer tube. Filling the reformer tube with catalyst, thereby maintaining the location of the at least one axial quench lance. Introducing the temperature control gas into the at least one axial quench lance, the temperature control gas thereby exiting the multiple delivery holes and entering the catalyst. Adjusting the flow rate of the temperature control gas thereby controlling the temperature of the catalyst.

IPC Classes  ?

  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts

7.

Method for controlling the velocity of a pipeline pig

      
Application Number 17734712
Grant Number 12265402
Status In Force
Filing Date 2022-05-02
First Publication Date 2023-11-02
Grant Date 2025-04-01
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor
  • Hoff, Jr., Robert D.
  • Malone, Matthew J.
  • Gryder, Michael C.

Abstract

A method for controlling the velocity of a pipeline pig, the method including, introducing a pressurized gas into a section of pipeline to be treated and maintaining the velocity of a smart pipeline pig at a predetermined velocity by regulating the pressurized gas to a predetermined volume. A method for controlling the velocity of a pipeline pig, the method including fluidically connecting a first skid to a first end of a section of pipeline to be treated, fluidically connecting a second skid to a second end of the section of pipeline to be treated, introducing a pressurized gas into the section of pipeline to be treated via the first skid, launching a smart pipeline pig into the section of pipeline to be treated, and maintaining the velocity of the smart pipeline pig at a predetermined velocity by regulating the pressurized gas to a predetermined volume.

IPC Classes  ?

  • G05D 13/62 - Control of linear speedControl of angular speedControl of acceleration or deceleration, e.g. of a prime mover characterised by the use of electric means, e.g. use of a tachometric dynamo, use of a transducer converting an electric value into a displacement
  • F16L 55/38 - Constructional aspects of the propulsion means, e.g. towed by cables driven by fluid pressure

8.

Magnetic Ljungstrom filter

      
Application Number 16987663
Grant Number 11633744
Status In Force
Filing Date 2020-08-07
First Publication Date 2022-02-10
Grant Date 2023-04-25
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A heat exchange apparatus for removing magnetic particulates from a gas stream, including a rotating element basket having a regenerative heat exchanger and at least one magnetic element. A method of removing magnetic particulates from a gas stream, including heating the regenerative heat exchanger during a first portion of a cycle as a segment of the rotating element basket passes through a first zone wherein contact is made with a flue gas thereby accumulating any magnetic particulates as they are attached to the magnetic element. Then cleaning a portion of the magnetic element during a second portion of the cycle. And cooling the regenerative heat exchanger and simultaneously heating an inlet air stream during a third portion of the cycle as the segment of the rotating element basket passes through a third zone wherein fluidic contact is made with the air inlet stream.

IPC Classes  ?

  • B03C 1/032 - Matrix cleaning systems
  • F23J 15/02 - Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
  • F23L 15/02 - Arrangements of regenerators
  • B03C 1/033 - Component partsAuxiliary operations characterised by the magnetic circuit
  • B03C 1/12 - Magnetic separation acting directly on the substance being separated with cylindrical material carriers with magnets moving during operationMagnetic separation acting directly on the substance being separated with cylindrical material carriers with movable pole pieces
  • F23L 15/04 - Arrangements of recuperators
  • B03C 1/30 - Combinations with other devices, not otherwise provided for
  • B03C 1/28 - Magnetic plugs and dipsticks

9.

Method and system for selecting and using a salt cavern to store very pure hydrogen

      
Application Number 15428006
Grant Number 11180318
Status In Force
Filing Date 2017-02-08
First Publication Date 2021-11-23
Grant Date 2021-11-23
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Ellerbusch, Susan A.

Abstract

The invention generally relates to a method and system for storing hydrogen product in a salt cavern. The method is directed to substantially confining a high purity hydrogen stored within the salt cavern by maintaining the stored hydrogen at a pressure between a lower limit and an upper limit within the cavern, whereby the salt cavern forms a substantially impermeable barrier to the stored hydrogen therein between the lower limit and the upper limit and wherein the improvement over the predicate art enables the upper limit to exceed about 1 psi per liner foot of cavern depth.

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth
  • E21D 13/00 - Large underground chambersMethods or apparatus for making them
  • E21F 17/16 - Modification of mine passages or chambers for storage purposes, especially for liquids or gases

10.

METHOD FOR OPERATING A RELIQUEFACTION SYSTEM

      
Application Number US2021031392
Publication Number 2021/226525
Status In Force
Filing Date 2021-05-07
Publication Date 2021-11-11
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLC (USA)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor
  • Guerif, Pierre-Philippe
  • Guillard, Alain
  • Flavien, Gilles
  • Follaca, Vincent
  • Kong, Paul

Abstract

A method for increasing the reliability and availability of a cryogenic fluid reliquefaction system is provided. It may comprise at least N sub-coolers comprising a motor and a compressor and at least one variable speed. It may comprise N-1 variable speed systems to be shared between the motors and compressors if N equals 2, or N-2 variable speed systems to be shared between the motors and compressors if N is greater than 2. If may comprise two different liquid cryogenic fluid users are provided liquid cryogenic fluid, utilizing two different main cryogenic tanks, with a common sub-cooler and recirculation loop, wherein the pressure in the two different main cryogenic tanks are controlled with pressure controllers acting on two different subcooled liquid cryogenic fluid valves. And or, it may comprise at least one liquid cryogenic fluid user is provided refrigeration from two or more sub-cooling systems in a lead-lag arrangement.

IPC Classes  ?

  • F17C 7/04 - Discharging liquefied gases with change of state, e.g. vaporisation

11.

Method for storing very high purity hydrogen in a salt cavern

      
Application Number 15427900
Grant Number 11167927
Status In Force
Filing Date 2017-02-08
First Publication Date 2021-11-09
Grant Date 2021-11-09
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Ellerbusch, Susan A.

Abstract

A method for storing very high purity hydrogen in a salt cavern is provided. The method includes introducing a compressed very high purity hydrogen gas into a salt cavern, thereby producing a stored very high purity hydrogen gas; maintaining the stored very high purity hydrogen gas at a pressure greater than about 1.0 psi per linear foot of height within the cavern, and less than about 4.0 psi per linear foot of height within the cavern.

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth
  • E21F 17/16 - Modification of mine passages or chambers for storage purposes, especially for liquids or gases
  • E21D 13/00 - Large underground chambersMethods or apparatus for making them

12.

METHOD FOR INSTALLING A THERMOCOUPLE INSIDE A REACTOR TUBE FILLED WITH CATALYST

      
Application Number US2020057673
Publication Number 2021/086920
Status In Force
Filing Date 2020-10-28
Publication Date 2021-05-06
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A method of installing a temperature measuring device inside a reactor tube while filling the tube with catalyst is provided. The method includes inserting a positioning system, including multiple inflatable bladders connected at a central location to a centering ring, into reactor tube, the reactor tube comprising a distal end and a proximal end. Then inserting a temperature measurement device into the centering ring. Locating the positioning system at a first predetermined distance from the distal end. Then inflating the multiple inflatable bladders, thereby centering the centering ring and the temperature measurement device within the SMR tube, and introducing catalyst into the SMR tube, thereby enclosing the temperature measurement device in catalyst.

IPC Classes  ?

  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • B01J 8/02 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds
  • B01J 4/00 - Feed devicesFeed or outlet control devices
  • C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
  • G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations
  • B01J 8/06 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds in tube reactorsChemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the solid particles being arranged in tubes
  • G01K 7/02 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples

13.

APPARATUS FOR INSTALLING A THERMOCOUPLE INSIDE A REACTOR TUBE FILLED WITH CATALYST

      
Application Number US2020057694
Publication Number 2021/086934
Status In Force
Filing Date 2020-10-28
Publication Date 2021-05-06
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A device for centering a temperature measurement device inside a reactor tube that will be filled with catalyst, including multiple inflatable bladders mechanically and fluidically attached to a centering ring.

IPC Classes  ?

  • G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations
  • B01J 8/02 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds
  • C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
  • G01K 7/02 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples

14.

APPARATUS FOR INSTALLING A THERMOCOUPLE INSIDE A REACTOR TUBE FILLED WITH CATALYST

      
Application Number US2020057705
Publication Number 2021/086942
Status In Force
Filing Date 2020-10-28
Publication Date 2021-05-06
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U. S. LP (USA)
Inventor Miller, Gary, D.

Abstract

A device for centering a temperature measurement device inside a tube reactor that will be filled with catalyst, including a single inflatable bladder mechanically and fluidically attached to a centering ring.

IPC Classes  ?

  • B01J 8/02 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds
  • G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations
  • C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
  • G01K 7/02 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples

15.

METHOD FOR INSTALLING A THERMOCOUPLE INSIDE A REACTOR TUBE FILLED WITH CATALYST

      
Application Number US2020057688
Publication Number 2021/086931
Status In Force
Filing Date 2020-10-28
Publication Date 2021-05-06
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A method of installing a temperature measuring device inside a reactor tube while filling the tube with catalyst is provided. The method includes inserting a positioning system, including a single inflatable bladder connected at a central location to a centering ring, into a reactor tube, the reactor tube comprising a distal end and a proximal end. Then inserting the centering ring around the temperature measurement device. Then locating the positioning system at a first predetermined distance from the distal end, and inflating the single inflatable bladder, thereby centering the centering ring and the temperature measurement device within the SMR tube. Then introducing catalyst into the SMR tube, thereby enclosing the temperature measurement device in catalyst.

IPC Classes  ?

  • G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations
  • G01K 7/04 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples the object to be measured not forming one of the thermoelectric materials
  • C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
  • B01J 8/02 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds

16.

Method for installing a thermocouple inside a reactor tube filled with catalyst

      
Application Number 16665315
Grant Number 11534731
Status In Force
Filing Date 2019-10-28
First Publication Date 2020-08-13
Grant Date 2022-12-27
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A method of installing a temperature measuring device inside a reactor tube while filling the tube with catalyst is provided. The method includes inserting a positioning system, including multiple inflatable bladders connected at a central location to a centering ring, into reactor tube, the reactor tube comprising a distal end and a proximal end. Then inserting a temperature measurement device into the centering ring. Locating the positioning system at a first predetermined distance from the distal end. Then inflating the multiple inflatable bladders, thereby centering the centering ring and the temperature measurement device within the SMR tube, and introducing catalyst into the SMR tube, thereby enclosing the temperature measurement device in catalyst.

IPC Classes  ?

  • B01J 4/00 - Feed devicesFeed or outlet control devices
  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • B01J 8/02 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds
  • B01J 8/06 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds in tube reactorsChemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the solid particles being arranged in tubes
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • B01J 19/24 - Stationary reactors without moving elements inside
  • G01K 1/02 - Means for indicating or recording specially adapted for thermometers
  • G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations
  • G01K 7/02 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples
  • G21C 17/112 - Measuring temperature

17.

Method for installing a thermocouple inside a reactor tube filled with catalyst

      
Application Number 16665330
Grant Number 11541366
Status In Force
Filing Date 2019-10-28
First Publication Date 2020-08-13
Grant Date 2023-01-03
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A method of installing a temperature measuring device inside a reactor tube while filling the tube with catalyst is provided. The method includes inserting a positioning system, including a single inflatable bladder connected at a central location to a centering ring, into a reactor tube, the reactor tube comprising a distal end and a proximal end. Then inserting the centering ring around the temperature measurement device. Then locating the positioning system at a first predetermined distance from the distal end, and inflating the single inflatable bladder, thereby centering the centering ring and the temperature measurement device within the SMR tube. Then introducing catalyst into the SMR tube, thereby enclosing the temperature measurement device in catalyst.

IPC Classes  ?

  • B01J 4/00 - Feed devicesFeed or outlet control devices
  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • B01J 8/06 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds in tube reactorsChemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the solid particles being arranged in tubes
  • B01J 19/00 - Chemical, physical or physico-chemical processes in generalTheir relevant apparatus
  • B01J 19/24 - Stationary reactors without moving elements inside
  • G01K 1/02 - Means for indicating or recording specially adapted for thermometers
  • G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations
  • G21C 17/112 - Measuring temperature
  • G01K 7/02 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples

18.

Apparatus for installing a thermocouple inside a reactor tube filled with catalyst

      
Application Number 16665377
Grant Number 11517867
Status In Force
Filing Date 2019-10-28
First Publication Date 2020-08-13
Grant Date 2022-12-06
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A device for centering a temperature measurement device inside a reactor tube that will be filled with catalyst, including multiple inflatable bladders mechanically and fluidically attached to a centering ring.

IPC Classes  ?

  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • B01J 8/06 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds in tube reactorsChemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the solid particles being arranged in tubes
  • G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations
  • G01K 7/02 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples
  • G01K 1/02 - Means for indicating or recording specially adapted for thermometers
  • G21C 17/112 - Measuring temperature

19.

Apparatus for installing a thermocouple inside a reactor tube filled with catalyst

      
Application Number 16665394
Grant Number 11253830
Status In Force
Filing Date 2019-10-28
First Publication Date 2020-08-13
Grant Date 2022-02-22
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Miller, Gary D.

Abstract

A device for centering a temperature measurement device inside a tube reactor that will be filled with catalyst, including a single inflatable bladder mechanically and fluidically attached to a centering ring.

IPC Classes  ?

  • B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
  • B01J 8/02 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds
  • B01J 4/00 - Feed devicesFeed or outlet control devices
  • C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
  • G01K 1/02 - Means for indicating or recording specially adapted for thermometers
  • G01K 1/14 - SupportsFastening devicesArrangements for mounting thermometers in particular locations
  • B01J 8/06 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds in tube reactorsChemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the solid particles being arranged in tubes
  • G01K 7/02 - Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat using thermoelectric elements, e.g. thermocouples
  • G21C 17/112 - Measuring temperature

20.

Method for forming and maintaining a fundamentally impervious boundary to very high purity hydrogen in a salt cavern

      
Application Number 15427862
Grant Number 10221689
Status In Force
Filing Date 2017-02-08
First Publication Date 2019-03-05
Grant Date 2019-03-05
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Ellerbusch, Susan A.

Abstract

A method for forming and maintaining a fundamentally impervious boundary to very high purity hydrogen stored in a salt cavern is provided. The cavern includes a salt cavern wall. The method includes introducing a compressed very high purity hydrogen gas into a salt cavern, thereby producing a stored very high purity hydrogen gas; forming a fundamentally impervious boundary to the very high purity hydrogen along at least a part of the perimeter of the salt cavern, and maintaining the fundamentally impervious boundary to the stored very high purity hydrogen gas at a pressure greater than 1.0 psi per linear foot of height within the cavern, and less than 4.0 psi per linear foot of height within the cavern and thereby retaining within the salt cavern over 95% of the stored very high purity hydrogen over a period of time of at least 72 hours.

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth
  • E21D 13/00 - Large underground chambersMethods or apparatus for making them
  • E21F 17/16 - Modification of mine passages or chambers for storage purposes, especially for liquids or gases
  • F17C 1/00 - Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge

21.

System for forming and maintaining a fundamentally impervious boundary in a salt cavern for storing very pure hydrogen

      
Application Number 15427945
Grant Number 10215024
Status In Force
Filing Date 2017-02-08
First Publication Date 2019-02-26
Grant Date 2019-02-26
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Ellerbusch, Susan A.

Abstract

A system for forming and/or maintaining a fundamentally impervious boundary within a salt cavern for storing very high purity hydrogen is provided. The system includes a salt cavern comprising a salt cavern wall; a conduit configured to introduce a compressed very high purity hydrogen gas into a salt cavern, thereby producing a stored very high purity hydrogen gas; the conduit also configured to remove the compressed very high purity hydrogen gas from the salt cavern, wherein the stored very high purity hydrogen gas is maintained at a pressure greater than about 1.0 psi per linear foot of height within the cavern, and less than about 4.0 psi per linear foot of height within the cavern.

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth
  • E21D 13/00 - Large underground chambersMethods or apparatus for making them
  • E21F 17/16 - Modification of mine passages or chambers for storage purposes, especially for liquids or gases

22.

Automatic pressure and vacuum clearing skid

      
Application Number 15370453
Grant Number 10253891
Status In Force
Filing Date 2016-12-06
First Publication Date 2018-06-07
Grant Date 2019-04-09
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Harrington, Jeffrey K.

Abstract

A pressurization and evacuation system is provided, including a top 3-way valve including a first port, a second port and a third port, a bottom 3-way valve including an first port, a second outlet port and a third port, and an educator including a pressure inlet, a suction inlet, and a discharge outlet. Wherein: a first conduit fluidically connects the top 3-way valve third port with the educator pressure inlet; a second conduit fluidically connects the top 3-way valve second port with the bottom 3-way valve first port; a third conduit fluidically connects the bottom 3-way valve third port with the educator suction inlet; and a fourth conduit fluidically connects the bottom 3-way valve second port with a customer apparatus.

IPC Classes  ?

  • F16K 11/00 - Multiple-way valves, e.g. mixing valvesPipe fittings incorporating such valvesArrangement of valves and flow lines specially adapted for mixing fluid
  • F16K 11/10 - Multiple-way valves, e.g. mixing valvesPipe fittings incorporating such valvesArrangement of valves and flow lines specially adapted for mixing fluid with two or more closure members not moving as a unit
  • F17C 1/00 - Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
  • F16K 11/087 - Multiple-way valves, e.g. mixing valvesPipe fittings incorporating such valvesArrangement of valves and flow lines specially adapted for mixing fluid with all movable sealing faces moving as one unit comprising only taps or cocks with spherical plug
  • F16K 11/22 - Multiple-way valves, e.g. mixing valvesPipe fittings incorporating such valvesArrangement of valves and flow lines specially adapted for mixing fluid with two or more closure members not moving as a unit operated by separate actuating members with an actuating member for each valve, e.g. interconnected to form multiple-way valves
  • F16K 11/18 - Multiple-way valves, e.g. mixing valvesPipe fittings incorporating such valvesArrangement of valves and flow lines specially adapted for mixing fluid with two or more closure members not moving as a unit operated by one actuating member, e.g. a handle with separate operating movements for separate closure members
  • F16K 11/20 - Multiple-way valves, e.g. mixing valvesPipe fittings incorporating such valvesArrangement of valves and flow lines specially adapted for mixing fluid with two or more closure members not moving as a unit operated by separate actuating members

23.

USE OF MULTIPLE STORAGE CAVERNS FOR PRODUCT INVENTORY CONTROL

      
Application Number US2016062289
Publication Number 2017/087529
Status In Force
Filing Date 2016-11-16
Publication Date 2017-05-26
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

An inventory management method is provided, which includes filling a first salt cavern with a product gas, removing all the working gas from a second salt cavern when the frequency requirement to empty the second salt cavern is reached, while concurrently, removing and replacing the gas product from the first salt cavern as supply and demand dictate, analyzing the frequency requirement for emptying the first salt cavern, calculating the time to fill the second salt cavern, filling the second salt cavern with a product gas, removing all the working gas from the first salt cavern when the frequency requirement to empty the first salt cavern is reached, while concurrently, removing and replacing the gas product from the second salt cavern as supply and demand dictate, analyzing the frequency requirement for emptying the second salt cavern, calculating the time to fill the first salt cavern, and repeating steps b) - j).

IPC Classes  ?

  • G06Q 50/06 - Energy or water supply
  • G06Q 50/28 - Logistics, e.g. warehousing, loading, distribution or shipping
  • G06Q 10/08 - Logistics, e.g. warehousing, loading or distributionInventory or stock management

24.

USE OF MULTIPLE STORAGE CAVERNS FOR PRODUCT IMPURITY CONTROL

      
Application Number US2016062443
Publication Number 2017/087617
Status In Force
Filing Date 2016-11-17
Publication Date 2017-05-26
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

An inventory management method is also provided. This method includes removing and replacing the gas product from a first salt cavern as supply and demand dictate, analyzing the impurities in the gas product that is removed, predicting the duration until a maximum acceptable impurity limit is present, removing all the working gas from the first salt cavern when the maximum acceptable impurity limit is reached, then replacing the working gas in the first salt cavern, while concurrently, removing and replacing the gas product from a second salt cavern as supply and demand dictate, analyzing the impurities in the gas product that is removed, predicting the duration until a maximum acceptable impurity limit is present, removing all the working gas from the second salt cavern when the maximum acceptable impurity limit is reached, then replacing the working gas in the second salt cavern, while concurrently repeating steps a) - g).

IPC Classes  ?

  • F17C 7/00 - Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass

25.

USE OF MULTIPLE STORAGE CAVERNS FOR PRODUCT IMPURITY CONTROL

      
Application Number US2016062450
Publication Number 2017/087622
Status In Force
Filing Date 2016-11-17
Publication Date 2017-05-26
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

An inventory management method is also provided. This method includes removing and replacing the gas product from a first salt cavern as supply and demand dictate, analyzing the impurities in the gas product that is removed, predicting the duration until a maximum acceptable impurity limit is present, removing all the working gas from the first salt cavern when the maximum acceptable impurity limit is reached, then replacing the working gas in the first salt cavern, while concurrently, removing and replacing the gas product from a second salt cavern as supply and demand dictate, analyzing the impurities in the gas product that is removed, predicting the duration until a maximum acceptable impurity limit is present, removing all the working gas from the second salt cavern when the maximum acceptable impurity limit is reached, then replacing the working gas in the second salt cavern, while concurrently repeating steps a) - g).

IPC Classes  ?

  • F17C 7/00 - Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass

26.

CAVERN PRESSURE MANAGEMENT

      
Application Number US2016035646
Publication Number 2016/196882
Status In Force
Filing Date 2016-06-03
Publication Date 2016-12-08
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

A cavern pressure control method includes storing compressible and possibly incompressible fluids in an underground storage volume, removing a portion or introducing additional incompressible fluid into the underground storage volume, possibly removing a portion or introducing additional compressible fluid into the underground storage volume, thereby producing a net pressure increase rate (Pinc) within the underground storage volume, wherein Pinc is maintained at less than a predetermined maximum increase value (PImax).

IPC Classes  ?

  • F17C 1/00 - Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge

27.

Cavern pressure management

      
Application Number 14732124
Grant Number 09573762
Status In Force
Filing Date 2015-06-05
First Publication Date 2016-12-08
Grant Date 2017-02-21
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

max).

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth

28.

GAS DETECTION AND FIRE SUPPRESSION SYSTEM FOR HYDROGEN SALT CAVERN

      
Application Number US2016035644
Publication Number 2016/196881
Status In Force
Filing Date 2016-06-03
Publication Date 2016-12-08
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor James, Phillip

Abstract

A gas detection and fire suppression system is proposed that includes at least one hydrogen gas detector located proximate to a hydrogen salt cavern wellhead, the at least one hydrogen gas detector configured to generate a signal upon detecting a concentration of hydrogen gas above a predetermined threshold. The system also includes at least one automatic self oscillating fire monitor located proximate to the hydrogen salt cavern wellhead, the at least one automatic self oscillating fire monitor configured to activate upon the receive a signal from the at least one hydrogen gas detector. And the system includes an alarm, wherein the alarm is configured to activate upon the receipt of the signal from the at least one hydrogen gas detector.

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth

29.

CAVERN PRESSURE MANAGEMENT

      
Application Number US2016035649
Publication Number 2016/196884
Status In Force
Filing Date 2016-06-03
Publication Date 2016-12-08
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

A cavern pressure control method includes storing compressible and possibly incompressible fluids in an underground storage volume, removing a portion or introducing additional incompressible fluid into the underground storage volume, possibly removing a portion or introducing additional compressible fluid into the underground storage volume, thereby producing a net pressure decrease rate (Pdec) within the underground storage volume, wherein Pdec is maintained at less than a predetermined maximum decrease value (PDmax).

IPC Classes  ?

  • F17C 1/00 - Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge

30.

Use of multiple storage caverns for product impurity control

      
Application Number 14943687
Grant Number 09482654
Status In Force
Filing Date 2015-11-17
First Publication Date 2016-11-01
Grant Date 2016-11-01
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

An inventory management method is also provided. This method includes removing and replacing the gas product from a first salt cavern as supply and demand dictate, analyzing the impurities in the gas product that is removed, predicting the duration until a maximum acceptable impurity limit is present, removing all the working gas from the first salt cavern when the maximum acceptable impurity limit is reached, then replacing the working gas in the first salt cavern, while concurrently, removing and replacing the gas product from a second salt cavern as supply and demand dictate, analyzing the impurities in the gas product that is removed, predicting the duration until a maximum acceptable impurity limit is present, removing all the working gas from the second salt cavern when the maximum acceptable impurity limit is reached, then replacing the working gas in the second salt cavern, while concurrently repeating steps a)-g).

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth
  • G01N 33/00 - Investigating or analysing materials by specific methods not covered by groups

31.

SOLUTION MINING A STABLE ROOF UNDER AN INERT GAS

      
Application Number US2015064184
Publication Number 2016/094267
Status In Force
Filing Date 2015-12-07
Publication Date 2016-06-16
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

This method includes a solution mined underground salt cavern, wherein the salt cavern has a main body with a mean diameter of DN and an upper portion comprising an inert gas pad, a stream of leaching water which is injected below the inert gas pad with a velocity V, thereby leaching an Nth tier adjacent to the upper portion having a height H1 and a mean diameter DN+1 that is smaller than DN by a ratio R raising the inert gas pad by an amount A1, providing a stream of leaching water which is injected below the inert gas pad with a velocity V, thereby leaching an N+1th tier adjacent to the Nth tier having a height H2 and to a mean diameter DN+2 that is smaller than DN+1 by a ratio R, and repeating steps c and d a number of times T, thereby forming a stable roof.

IPC Classes  ?

  • E21B 43/28 - Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent
  • E21C 41/16 - Methods of underground miningLayouts therefor
  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth

32.

Use of multiple storage caverns for product impurity control

      
Application Number 14943851
Grant Number 09365349
Status In Force
Filing Date 2015-11-17
First Publication Date 2016-06-14
Grant Date 2016-06-14
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

An inventory management method is also provided. This method includes removing and replacing the gas product from a first salt cavern as supply and demand dictate, analyzing the impurities in the gas product that is removed, predicting the duration until a maximum acceptable impurity limit is present, removing all the working gas from the first salt cavern when the maximum acceptable impurity limit is reached, then replacing the working gas in the first salt cavern, while concurrently, removing and replacing the gas product from a second salt cavern as supply and demand dictate, analyzing the impurities in the gas product that is removed, predicting the duration until a maximum acceptable impurity limit is present, removing all the working gas from the second salt cavern when the maximum acceptable impurity limit is reached, then replacing the working gas in the second salt cavern, while concurrently repeating steps a)-g).

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth
  • G01N 33/00 - Investigating or analysing materials by specific methods not covered by groups

33.

DETONATION ARRESTOR FOR CAVERN STORAGE

      
Application Number US2015061269
Publication Number 2016/081559
Status In Force
Filing Date 2015-11-18
Publication Date 2016-05-26
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

A hydrogen pipeline detonation arrestor is provided. The detonation arrestor includes a pipeline spool, having a segment length, an inner volume, an outer surface. The detonation arrester also includes a detonation barrier having a plurality of axially aligned quench pipes located within the inner volume. The detonation arrester is located within a hydrogen pipeline upstream or downstream of a hydrogen salt cavern storage facility.

IPC Classes  ?

  • A62C 4/02 - Flame traps allowing passage of gas but not of flame or explosion wave in gas-pipes

34.

MATERIALS OF CONSTRUCTION FOR USE IN HIGH PRESSURE HYDROGEN STORAGE IN A SALT CAVERN

      
Application Number US2015061279
Publication Number 2016/081564
Status In Force
Filing Date 2015-11-18
Publication Date 2016-05-26
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

A carbon steel for use in high pressure hydrogen service is provided. This steel may have greater than 1.20% manganese and greater than 0.035% sulfur.

IPC Classes  ?

  • C22C 38/04 - Ferrous alloys, e.g. steel alloys containing manganese
  • E21B 17/00 - Drilling rods or pipesFlexible drill stringsKelliesDrill collarsSucker rodsCasingsTubings

35.

MATERIALS OF CONSTRUCTION FOR USE IN HIGH PRESSURE HYDROGEN STORAGE IN A SALT CAVERN

      
Application Number US2015061304
Publication Number 2016/081578
Status In Force
Filing Date 2015-11-18
Publication Date 2016-05-26
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

A carbon steel for use in high pressure hydrogen service is provided. This steel may have no more than 0.16% carbon, no more than 1.10% manganese, no more than 0.010% phosphorus, no more than 0.05% sulfur, no more than 0.02% silicon, no more than 0.15% copper, no more than 0.10% nickel, no more than 0.1 % chromium, no more than 0.03% molybdnium, no more than 0.40% aluminum, no more than 0.02% vanadium, no more than 0.0005% boron, no more than 0.003% titanium, and no more than 0.02% niobium.

IPC Classes  ?

  • C22C 38/00 - Ferrous alloys, e.g. steel alloys
  • C22C 38/02 - Ferrous alloys, e.g. steel alloys containing silicon
  • C22C 38/04 - Ferrous alloys, e.g. steel alloys containing manganese
  • C22C 38/06 - Ferrous alloys, e.g. steel alloys containing aluminium
  • C22C 38/08 - Ferrous alloys, e.g. steel alloys containing nickel
  • C22C 38/12 - Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium or niobium
  • C22C 38/14 - Ferrous alloys, e.g. steel alloys containing titanium or zirconium
  • C22C 38/18 - Ferrous alloys, e.g. steel alloys containing chromium
  • C22C 38/32 - Ferrous alloys, e.g. steel alloys containing chromium with boron
  • E21B 17/00 - Drilling rods or pipesFlexible drill stringsKelliesDrill collarsSucker rodsCasingsTubings

36.

DETONATION ARRESTOR FOR CAVERN STORAGE

      
Application Number US2015061289
Publication Number 2016/081569
Status In Force
Filing Date 2015-11-18
Publication Date 2016-05-26
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

A hydrogen pipeline detonation arrestor is provided. The detonation arrestor includes a pipeline spool, having a segment length, an inner volume, an outer surface. The detonation arrester also includes a detonation barrier having a plurality of axially aligned quench pipes located within the inner volume. The detonation arrester is located within a hydrogen pipeline upstream or downstream of a hydrogen salt cavern storage facility.

IPC Classes  ?

  • A62C 4/02 - Flame traps allowing passage of gas but not of flame or explosion wave in gas-pipes

37.

SOLUTION MINING UNDER AN INERT GAS

      
Application Number US2015061461
Publication Number 2016/081678
Status In Force
Filing Date 2015-11-19
Publication Date 2016-05-26
Owner
  • L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
  • AIR LIQUIDE LARGE INDUSTRIES U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

This method includes providing an cased borehole located within a salt bed, injecting an aqueous liquid into the cased borehole at a first pressure, in order to expose the salt bed to the aqueous liquid, thereby dissolving at least a portion of the salt bed and forming a brine solution within an underground storage volume, withdrawing at least a portion of the brine solution from the underground storage volume, and injecting an inert gas into the cased borehole at a second pressure, in order to provide an inert blanket within the underground storage volume, wherein the second pressure that is greater than the first pressure but less than the maximum allowable pressure of the cavern.

IPC Classes  ?

  • E21B 43/28 - Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent
  • E21C 41/20 - Methods of underground miningLayouts therefor for rock salt or potash salt

38.

Materials of construction for use in high pressure hydrogen storage in a salt cavern

      
Application Number 14753845
Grant Number 09399810
Status In Force
Filing Date 2015-06-29
First Publication Date 2016-05-19
Grant Date 2016-07-26
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Strybos, Ronald

Abstract

A carbon steel for use in high pressure hydrogen service is provided. This steel may have greater than 1.20% manganese and greater than 0.035% sulfur. This steel may have no more than 0.16% carbon, no more than 1.10% manganese, no more than 0.010% phosphorus, no more than 0.05% sulfur, no more than 0.02% silicon, no more than 0.15% copper, no more than 0.10% nickel, no more than 0.1% chromium, no more than 0.03% molybdnium, no more than 0.40% aluminum, no more than 0.02% vanadium, no more than 0.0005% boron, no more than 0.003% titanium, and no more than 0.02% niobium.

IPC Classes  ?

  • E21B 17/00 - Drilling rods or pipesFlexible drill stringsKelliesDrill collarsSucker rodsCasingsTubings
  • E21B 33/14 - Methods or devices for cementing, for plugging holes, crevices or the like for cementing casings into boreholes
  • C22C 38/54 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
  • C22C 38/48 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
  • C22C 38/46 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
  • C22C 38/44 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
  • C22C 38/42 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
  • C22C 38/06 - Ferrous alloys, e.g. steel alloys containing aluminium
  • C22C 38/04 - Ferrous alloys, e.g. steel alloys containing manganese
  • C22C 38/02 - Ferrous alloys, e.g. steel alloys containing silicon
  • F16L 9/02 - Rigid pipes of metal
  • C22C 38/50 - Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
  • E21B 33/03 - Well headsSetting-up thereof
  • E21B 33/04 - Casing headsSuspending casings or tubings in well heads
  • E21B 34/02 - Valve arrangements for boreholes or wells in well heads
  • F16L 1/028 - Laying or reclaiming pipes on land, e.g. above the ground in the ground
  • F16L 1/12 - Laying or reclaiming pipes on or under water
  • C22C 38/00 - Ferrous alloys, e.g. steel alloys
  • C22C 38/08 - Ferrous alloys, e.g. steel alloys containing nickel
  • C22C 38/12 - Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium or niobium
  • C22C 38/14 - Ferrous alloys, e.g. steel alloys containing titanium or zirconium
  • C22C 38/18 - Ferrous alloys, e.g. steel alloys containing chromium
  • C22C 38/32 - Ferrous alloys, e.g. steel alloys containing chromium with boron

39.

Hydrogen cavern pad gas management

      
Application Number 14468531
Grant Number 09656807
Status In Force
Filing Date 2014-08-26
First Publication Date 2015-11-12
Grant Date 2017-05-23
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor
  • Strybos, Ronald
  • Dony, Azadeh

Abstract

act, and wherein the transient pressure condition has a duration (D) of less than 7 days, more preferably less than 5 days.

IPC Classes  ?

  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth
  • F17C 1/00 - Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
  • F17C 7/00 - Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass

40.

Method and apparatus for improving the integrity of a pipeline

      
Application Number 14464048
Grant Number 09109418
Status In Force
Filing Date 2014-08-20
First Publication Date 2015-08-18
Grant Date 2015-08-18
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Norris, Dennis

Abstract

A method and apparatus is provided which will improve the integrity of a pipeline by removing moisture and solid particulates that have been entrapped within a gas originating from an underground storage cavern following pressure reduction before introducing the gas into the pipeline.

IPC Classes  ?

  • B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
  • E21B 37/00 - Methods or apparatus for cleaning boreholes or wells
  • B01D 46/00 - Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
  • B01D 53/26 - Drying gases or vapours
  • B65G 5/00 - Storing fluids in natural or artificial cavities or chambers in the earth

41.

Data sampling method for determining salient values in a large data stream

      
Application Number 13796274
Grant Number 09372603
Status In Force
Filing Date 2013-03-12
First Publication Date 2014-09-18
Grant Date 2016-06-21
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor
  • Mukhi, Sultan Q.
  • Momin, Emitaz A.
  • Momin, Mehrab

Abstract

Techniques are disclosed for presenting users with relevant data and statistics related to the operations of an industrial system. Data obtained by a SCADA system may be stored in a real-time status database (which reflects the current process data of the industrial system) and a historian database (which archives the process data from the industrial system as it changes over time). A user may request from the SCADA system process data obtained during a specified period of time. The request may be subdivided into a plurality of time intervals, and process data associated with each time interval may be analyzed to determine one or more salient values that are representative of the interval. The salient values associated with each time interval then may be transmitted to the user in response to the process data request.

IPC Classes  ?

  • G06F 3/0484 - Interaction techniques based on graphical user interfaces [GUI] for the control of specific functions or operations, e.g. selecting or manipulating an object, an image or a displayed text element, setting a parameter value or selecting a range
  • G05B 23/02 - Electric testing or monitoring
  • G05B 19/418 - Total factory control, i.e. centrally controlling a plurality of machines, e.g. direct or distributed numerical control [DNC], flexible manufacturing systems [FMS], integrated manufacturing systems [IMS] or computer integrated manufacturing [CIM]

42.

Green SMR to refuel HRSG duct burners

      
Application Number 13158717
Grant Number 09062876
Status In Force
Filing Date 2011-06-13
First Publication Date 2012-12-13
Grant Date 2015-06-23
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Anderson, Erik

Abstract

An energy generation system including a primer mover producing a power output, and a combustion product outlet stream; and a steam generator wherein a water inlet stream and the combustion product outlet stream exchange heat to produce at least one steam outlet stream is provided. The steam generator further comprises at least one set of supplemental burners situated in the path of the combustion product outlet stream, and a hydrogen fuel inlet stream at least a portion of which is combusted in at least one of the supplemental burners or the prime mover.

IPC Classes  ?

  • F02C 6/18 - Plural gas-turbine plantsCombinations of gas-turbine plants with other apparatusAdaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
  • F22B 1/18 - Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines

43.

Method to extract billing type peak data from an existing electric meter installation

      
Application Number 13333141
Grant Number 08994554
Status In Force
Filing Date 2011-12-21
First Publication Date 2012-07-05
Grant Date 2015-03-31
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor
  • Carpman, Joshua
  • Harper, Charles N.

Abstract

Techniques are disclosed for monitoring the consumption of a plurality of metered resources. The techniques involve receiving a KYZ pulse from a first utility meter, where the first utility meter is coupled to a source of one of the metered resources, and where the first utility meter outputs the KYZ pulse based on a predefined amount of metered resource being passed through the utility meter. A first counter is incremented, where the first counter is associated with the utility meter and stored in a memory.

IPC Classes  ?

  • G08B 21/00 - Alarms responsive to a single specified undesired or abnormal condition and not otherwise provided for
  • G01F 1/60 - Circuits therefor
  • G06Q 50/06 - Energy or water supply
  • G06Q 30/04 - Billing or invoicing

44.

Process for recovering hydrogen and carbon dioxide

      
Application Number 12974183
Grant Number 08535638
Status In Force
Filing Date 2010-12-21
First Publication Date 2012-05-17
Grant Date 2013-09-17
Owner
  • Air Liquide Large Industries U.S. (USA)
  • L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude (France)
Inventor
  • Terrien, Paul
  • Chaubey, Trapti
  • Shanbhag, Purushottam V.
  • Grover, Bhadra S.
  • Vauk, Dennis A.
  • Darde, Arthur

Abstract

The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream of a process unit wherein the process stream contains at least carbon dioxide, hydrogen, and methane.

IPC Classes  ?

  • C01B 3/24 - Production of hydrogen or of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
  • C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts

45.

Combined first and second generation biofuels process

      
Application Number 12840699
Grant Number 08431755
Status In Force
Filing Date 2010-07-21
First Publication Date 2012-01-26
Grant Date 2013-04-30
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Vauk, Dennis A.

Abstract

A process to integrate a first biofuels process and a second generation cellulosic biofuels process is provided. The pyrolysis means which produces the char stream and a bioliquid stream. The low pressure hydrotreating component, a high pressure hydrotreating component, the low pressure hydrotreating component which produces the hydrocarbon stream, the high pressure hydrotreating component which produces the steam stream and bioliquid stream. A distillation means, which produces a green gasoline stream and a green diesel stream from the bioliquid stream. The second biofuels process may be a first generation bio-ethanol process, which produces a bio-ethanol stream. The hydrogen production unit, which produces the hydrogen stream and the steam stream. The hydrogen production unit may be a steam reformer or partial oxidation unit.

IPC Classes  ?

  • C07C 1/00 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
  • C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives

46.

Presenting dynamic SCADA data

      
Application Number 12500446
Grant Number 08255186
Status In Force
Filing Date 2009-07-09
First Publication Date 2011-01-13
Grant Date 2012-08-28
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor
  • Mukhi, Sultan Q.
  • Forman, Jay A.

Abstract

Techniques are disclosed for presenting users with dynamic views of process data related to the operations of an industrial system. Data obtained by a SCADA system may be stored in a real-time status database (which reflects the current process data of the industrial system) and a historian database (which archives the process data from the industrial system as it changes over time). A design canvas allows users to compose a dynamic view of the process data obtained by the SCADA system. For example, a user may compose a dynamic view of selected temperatures, pressures, and flow rates obtained by the SCADA system while monitoring the status of a pipeline.

IPC Classes  ?

  • G06F 11/32 - Monitoring with visual indication of the functioning of the machine
  • G06F 17/40 - Data acquisition and logging
  • G06F 19/00 - Digital computing or data processing equipment or methods, specially adapted for specific applications (specially adapted for specific functions G06F 17/00;data processing systems or methods specially adapted for administrative, commercial, financial, managerial, supervisory or forecasting purposes G06Q;healthcare informatics G16H)

47.

Steam meter

      
Application Number 12207868
Grant Number 07703338
Status In Force
Filing Date 2008-09-10
First Publication Date 2009-03-12
Grant Date 2010-04-27
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Harper, Charles Neely

Abstract

A flowmeter detects a differential pressure of steam as the steam passes through a conduit with a feature shaped to produce changes in velocity and pressure of the steam. Taps used to enable detection of the differential pressure extend from a wall of the conduit upward toward vertical (defined as parallel to the direction of gravitational force) in order to drain liquid water into the conduit from the tap. The differential pressure measured enables calculation of flow rate of the steam.

IPC Classes  ?

48.

Programmable logic controller protocol converter

      
Application Number 12180334
Grant Number 07894460
Status In Force
Filing Date 2008-07-25
First Publication Date 2009-01-29
Grant Date 2011-02-22
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor
  • Carpman, Joshua
  • Cummings, Travis R.
  • Rabat-Torki, Hamid J.

Abstract

A programmable logic controller (PLC) protocol converter is disclosed that allows a supervisory control and data acquisition (SCADA) system to effectively communicate with a PLC device using a desired communications protocol, particularly in cases where the PLC device does not “speak” the desired communications protocol. A first thread may be configured to continually read PLC addresses, one at a time, using a communications protocol understood by the PLC device. The first thread may store the data values in the shared data array within program memory. Thus, the first thread exposes data from the PLC device, as specified in the configuration file. At the same time, a second thread may be configured to serve the data in the shared data array according to a second communications protocol, e.g., to the SCADA system.

IPC Classes  ?

  • H04L 12/56 - Packet switching systems
  • H04J 3/22 - Time-division multiplex systems in which the sources have different rates or codes
  • G06F 15/16 - Combinations of two or more digital computers each having at least an arithmetic unit, a program unit and a register, e.g. for a simultaneous processing of several programs

49.

Synchronizing historical archive data between primary and secondary historian systems

      
Application Number 11771557
Grant Number 07853569
Status In Force
Filing Date 2007-06-29
First Publication Date 2009-01-01
Grant Date 2010-12-14
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor
  • Mukhi, Sultan Q.
  • Momin, Emtiaz A.
  • Vinta, Prabhakara R.

Abstract

Techniques for operating an archival database, referred to as a historian, are disclosed. Embodiments of the invention provide techniques for synchronizing historical archive files and/or archival data between a primary and a secondary historian used to archive data values from a real-time database. The real-time database may be used to monitor the current operational state of a large industrial system, such as a pipeline. In turn, the historian may be used to archive the data stored by the real-time database. In the event that either the primary or the secondary system (or both) goes down and then comes back online at a later time, embodiments of the invention may be used to synchronize data between the primary and secondary historian systems.

IPC Classes  ?

  • G06F 17/30 - Information retrieval; Database structures therefor

50.

High speed data historian

      
Application Number 11681063
Grant Number 07853568
Status In Force
Filing Date 2007-03-01
First Publication Date 2008-09-04
Grant Date 2010-12-14
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor Mukhi, Sulton Q.

Abstract

Techniques for operating an archival database, referred to as a historian, are disclosed. The historian may be used to archive values from a real-time database. Data values to be archived in the historian are first written to a short-term, high-availability repository, such as a memory-mapped database. As data values “fill” the short-term repository, an archival processor application may be configured to “drain” them from the short-term repository and store them in a high-capacity, long-term archive, such as a disk-based database. Thus, the short-term repository may be used to provide fast access to the recent operational history of a monitored system, (e.g., a complex pipeline network), where long-term archive may be used to provide access to a comprehensive operational history of the monitored system.

IPC Classes  ?

  • G06F 7/00 - Methods or arrangements for processing data by operating upon the order or content of the data handled

51.

Pipeline optimizer system

      
Application Number 11279554
Grant Number 07643974
Status In Force
Filing Date 2006-04-12
First Publication Date 2006-10-26
Grant Date 2010-01-05
Owner Air Liquide Large Industries U.S. LP (USA)
Inventor
  • Harper, Charles N.
  • Boczon, Michael T.

Abstract

One embodiment of the invention provides a method for optimizing a variety of aspects of pipeline operations by using a genetic algorithm. Generally, the genetic algorithm is used to evolve a population of feasible solutions over successive generations until a termination condition is satisfied. Each solution specifies a feasible operational state of the pipeline system. Over successive generations existing solutions are modified, and an identified solution in the population is removed at each successive generation. Over repeated generations, the solutions in the population improve. Once an optimized production solution is generated, an optimized pressure solution may be generated using a direct pressure optimization process.

IPC Classes  ?

  • G06F 9/455 - EmulationInterpretationSoftware simulation, e.g. virtualisation or emulation of application or operating system execution engines