A Biobased Radical Curable Composition for Forming Solid Objects A composition for forming a solid object comprising: • from 10 wt% to 70 wt% of one or more compounds A, each compound A comprising a poly(trimethylene ether) moiety and one or two (meth)acrylate groups; wherein the poly(trimethylene ether) moiety is incorporated into compound A by reaction of a poly(trimethylene ether) glycol having a number average molecular weight Mn of from 500 to 5000 Dalton, and a polydispersity Đ of at least 1.5, • from 30 wt% to 90 wt% of one or more (meth)acrylate compounds B different from compound A, wherein each compound B comprises a single (meth)acrylate moiety and wherein the one or more (meth)acrylate compounds B, if polymerized together, have a Tg of more than 30°C; and • from 0 wt% to 25 wt% of other compounds C, different from compounds A and B, wherein the viscosity of the composition is less than 5 Pa.s.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 18/67 - Unsaturated compounds having active hydrogen
A radical curable coating composition comprising: • from 10 wt% to 70 wt% of one or more compounds A, each compound A comprising a poly(trimethylene ether) moiety and one or two (meth)acrylate groups; wherein the poly(trimethylene ether) moiety is incorporated into compound A by a condensation reaction of a poly(trimethylene ether) glycol with an (meth)acrylate compound selected from the group consisting of (meth)acrylic acid, (meth)acryloyl chloride, and alkylesters thereof, the poly(trimethylene ether) glycol having a number average molecular weight Mn, measured by GPC with polystyrene as the standard, of from 900 to 5000 Dalton, • from 30 wt% to 90 wt% of one or more (meth)acrylate compounds B, wherein each compound B comprises two or more (meth)acrylate groups, wherein the one or more (meth)acrylate compounds B, combined, have a viscosity of at most 10000 mPa.s at 25°C; and • from 0 wt% to 25 wt% of one or more other compounds C.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
Present invention relates to an actinic radiation curable coating composition comprising from 10 wt% to 90 wt%, based on the total weight of the coating composition, of a poly(trimethylene ether) (meth)acrylate compound A having at most two (meth)acrylate groups obtainable by a condensation reaction of biobased 1,3 poly(trimethylene ether) glycol and a (meth)acrylate compound selected from the group consisting of (meth)acrylic acid, (meth)acryloyl chloride, and /or alkylesters thereof; wherein the biobased 1,3 poly(trimethylene ether) glycol has a number average molecular weight Mn of from 350 to 600 g/mol, more preferably from 400 to 550g/mol; and from 10 wt% and 89.99 wt%, based on the total weight of the coating composition, of an ethylenically unsaturated oligomer compound B different from compound A, wherein compound B has a viscosity at 25°C of more than 5 Pa s.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
Polymeric amino (meth)acrylate suitable for use in radiation curable compositions, wherein said polymeric amino (meth)acrylate is the reaction product of a secondary amine-terminated copolymer (A) and a multifunctional (meth)acrylate (B); wherein said secondary amine-terminated copolymer is the reaction product of a difunctional (meth)acrylate (Ai) and a bireactive amine (Aii); and wherein the multifunctional (meth) acrylate (B) is different from the difunctional (meth)acrylate (Ai) and which multifunctional (meth) acrylate comprises two or more (meth)acrylate groups.
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
An aqueous radiation curable composition obtained by: a) mixing at least one ethylenically unsaturated compound (A) with at least one reactive ionic external emulsifier (B), wherein the reactive ionic external emulsifier (B) is represented by the general formula (I): D-O-(R1nn-X (I) wherein: D is a moiety comprising an ethylenically unsaturated group (E); R1 is a linear or branched C2-C6 alkylene group; X is an ionic moiety; and n is in a range from 4 to 50, thereby obtaining a premix; and b) adding water to the premix until a phase inversion occurs.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
An aqueous radiation curable composition comprising: a) from 45 to 80 wt.% of at least one (polymerizable) (water-insoluble) ethylenically unsaturated compound (A); and b) from 20 to 55 wt.% of at least one (polymerizable) ethylenically unsaturated polyurethane polymer (B) obtained from the reaction of: i. at least one polyisocyanate compound (i); ii. at least one polymeric polyol (ii); iii. at least one (non-polymerizable) hydrophilic compound (iii) comprising at least one reactive group capable of reacting with isocyanate groups and at least one group which is capable of rendering the polyurethane polymer (B) dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt; iv. at least one compound (iv) comprising at least one (essentially one) reactive group capable of reacting with isocyanate groups and further comprising at least one ethylenically unsaturated group; and v. optionally, at least one (non-polymerizable) compound (v) comprising at least one (essentially one) reactive group capable of reacting with isocyanate groups; and wherein compounds (A), (i), (ii), (iii), (iv) and (v) are all different from each other, and wherein the wt.% are based on the total dry content weight of the radiation curable composition.
A composite comprising a filler and a free-radical curable composition that is cleavable after being cured, comprising at least one crosslinker molecule component a. of general formula E1-O-C(R2)(R3)-X-E2(1), wherein each of E1and E2comprises an ethylenically unsaturated free-radical polymerizable moiety, X is either oxygen (O) or sulphur (S), and optionally, at least one ethylenically unsaturated free-radical polymerizable molecule component b, not comprising the moiety -O-C(R2)(R3gg of more than 50°C as measured by dynamic mechanical thermal analysis (DMTA).
An actinic radiation and/or thermally curable composition (I) for composite material comprising: (A) at least 20 wt% of compound A comprising at least 2 ethylenically unsaturated moieties and a structural moiety; (B) at least 20 wt% of compound B comprising at least 2 ethylenically unsaturated moieties and a cycloaliphatic structure or heterocyclic aliphatic structure; (C) from 1 to 40 wt% of a compound C different from compound A and B containing essentially one ethylenically unsaturated moiety and having a viscosity of less than 100 mPa.s measured at 25°C, preferably below 50 mPa.s, even more preferably below 25 mPa.s; and (D) from 0 to 20wt% of a compound D, comprising at least one ethylenically unsaturated moiety, and which is different from compound A, B and C; whereby the total of compound B and A have a content of from 60 to 99 wt% in view of the total content of compounds A, B, C and optionally D.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C08G 63/199 - Acids or hydroxy compounds containing cycloaliphatic rings
C08G 63/21 - Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups in the presence of unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
C08G 63/676 - Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
C08F 290/04 - Polymers provided for in subclasses or
An aqueous bio-based energy-curable polyurethane composition having at least one ethylenically unsaturated polyurethane pre-polymer (A) obtained from the reaction of at least one aliphatic, cycloaliphatic or aromatic polyisocyanate compound (Ai), at least one hydrophilic compound (Aii) containing at least one reactive group capable to react with an isocyanate and which is capable to render the polyurethane pre-polymer dispersible in an aqueous medium either directly or after the reaction with an organic or inorganic neutralizing agent to provide a salt therefrom, at least one ethylenically unsaturated compound (Aiii), containing essentially one reactive group capable to react with an isocyanate, at least one ethylenically unsaturated compound (Aiv), containing at least two reactive groups capable to react with an isocyanate.
Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes, adhesives, for the making of gel coats, composites, molding compositions or 3D articles. Materials of the invention are in particular suitable as surface cure boosterin UV and UV LED applications.
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09D 135/02 - Homopolymers or copolymers of esters
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C07C 229/30 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and unsaturated
The invention provides a radiation curable gel coat composition for fibers reinforced substrates, comprising a gel coat resin and at least one diluent monomer (B), wherein the gel coat resin comprises urethane (meth)acrylate reaction products (A) of a reaction mixture comprising: (a) a hydroxy-terminated polyol having a weight average molecular weight of about 200 to about 4000, this polyol being a polycaprolactone polyol or a [(poly)carbonate-(poly)caprolactone]polyol; (b) a diisocyanate; and (c) a hydroxyalkyl (meth)acrylate, and wherein both the diluent monomer (B) and the reaction product (A) contain polymerizable ethylenic unsaturated groups, preferably (meth)acrylate groups. Such gel coat composition provides adequate surface appearance and maintain color and high gloss when exposed to outdoor circumstances.
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/67 - Unsaturated compounds having active hydrogen
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 18/28 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08J 5/04 - Reinforcing macromolecular compounds with loose or coherent fibrous material
A radiation curable and at least partially biobased urethane (meth)acrylate for use in a one-component coating composition for cladding an outdoor surface of a building, obtained from the reaction of at least the following compounds: a. A polyisocyanate compound having a biobased carbon content of at least 20%, preferably at least 50%, as determined by method A of the standard ASTM D6866-12: 2008, and b. A (meth)acrylate compound, different from compound a, and containing a reactive group capable to react with isocyanate groups.
The invention is related to an aqueous bio-based energy-curable polyurethane composition comprising at least one ethylenically unsaturated polyurethane pre- polymer (A) obtained from the reaction of at least one aliphatic, cycloaliphatic or aromatic polyisocyanate compound (Ai), at least one hydrophilic compound (Aii) containing at least one reactive group capable to react with an isocyanate and which is capable to render the polyurethane pre-polymer dispersible in an aqueous medium either directly or after the reaction with an organic or inorganic neutralizing agent to provide a salt therefrom, at least one ethylenically unsaturated compound (Aiii), containing essentially one reactive group capable to react with an isocyanate, at least one ethylenically unsaturated compound (Aiv), containing at least two reactive groups capable to react with an isocyanate.
The invention is related to an aqueous bio-based energy-curable polyurethane composition comprising at least one ethylenically unsaturated polyurethane pre- polymer (A) obtained from the reaction of at least one aliphatic, cycloaliphatic or aromatic polyisocyanate compound (Ai), at least one hydrophilic compound (Aii) containing at least one reactive group capable to react with an isocyanate and which is capable to render the polyurethane pre-polymer dispersible in an aqueous medium either directly or after the reaction with an organic or inorganic neutralizing agent to provide a salt therefrom, at least one ethylenically unsaturated compound (Aiii), containing essentially one reactive group capable to react with an isocyanate, at least one ethylenically unsaturated compound (Aiv), containing at least two reactive groups capable to react with an isocyanate.
The present invention generally relates to the field of curable resin compositions for cold flexible applications which are prepared from at least one monofunctional monomer and at least one urethane (meth)acrylate and which exhibit high performing coating properties over a broad range of service temperatures including temperatures in very cold conditions, methods for making these curable compositions and their uses.
C08F 220/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
C08F 220/20 - Esters of polyhydric alcohols or phenols
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/73 - Polyisocyanates or polyisothiocyanates acyclic
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 18/76 - Polyisocyanates or polyisothiocyanates cyclic aromatic
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
The present invention relates to radiation curable coating composition (I) consisting essentially of: —from 20 to 95 wt % of one or more (meth)acrylated compounds (a), —from 5 to 80 wt % of one or more metal salts of a C10 to C22 fatty acid (b), and —optionally, from 0 to 10 wt % of one or more additives (c), wherein the wt % of compounds (a) to (c) add up to at least 95%, preferably add up to 100%. Compositions of the invention are compatible with a whole range of radiation curable materials and with the standard additives like the standard matting agents. Compositions of the invention permit to obtain a dead matt effect using lower amounts of matting agents like silica and/or waxes. Dead matt effects can be obtained over a wide range of coating thicknesses.
C09D 11/08 - Printing inks based on natural resins
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 5/00 - Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C09D 133/10 - Homopolymers or copolymers of methacrylic acid esters
Polymeric amino (meth)acrylate suitable for use in radiation curable compositions, wherein said polymeric amino (meth)acrylate is the reaction product of a secondary amine-terminated copolymer (A) and a multifunctional (meth)acrylate (B); wherein said secondary amine-terminated copolymer is the reaction product of a difunctional (meth)acrylate (Ai) and a bireactive amine (Aii); and wherein the multifunctional (meth) acrylate (B) is different from the difunctional (meth)acrylate (Ai) and which multifunctional (meth) acrylate comprises two or more (meth)acrylate groups.
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
C09D 11/037 - Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
Polymeric amino (meth)acrylate suitable for use in radiation curable compositions, wherein said polymeric amino (meth)acrylate is the reaction product of a secondary amine-terminated copolymer (A) and a multifunctional (meth)acrylate (B); wherein said secondary amine-terminated copolymer is the reaction product of a difunctional (meth)acrylate (Ai) and a bireactive amine (Aii); and wherein the multifunctional (meth) acrylate (B) is different from the difunctional (meth)acrylate (Ai) and which multifunctional (meth) acrylate comprises two or more (meth)acrylate groups.
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09D 155/00 - Coating composition based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 11/037 - Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
The present invention in general relates to acrylate end-capped urethane-based polymers, which are in particular characterized by the presence of at least 3 acrylate end-groups, thereby making them particularly suitable for further processing using multiple kinds of technologies such as 2-photon polymerization, stereolithography (SLA printing), electrospinning, film casting, porogen leaching, extrusion based 3D-printing, spray drying, cryogenic treatment, coatings, cross-linkable micelles, spincoating, and electrospraying.
01 - Chemical and biological materials for industrial, scientific and agricultural use
02 - Paints, varnishes, lacquers
Goods & Services
(1) Chemicals for the manufacture of paints, coatings, varnishes, inks, fiber composites, layered composites being laminates and penetration composites; chemicals for the manufacture of preparations for preventing corrosion; chemicals for use in the manufacture of adhesives; unprocessed artificial resins, unprocessed plastics; adhesives for use in the furniture industry; adhesives for use in the consumer packaging industry; contact adhesives for use with laminates; general use adhesives; synthetic resin adhesives for industrial purposes.
(2) Synthetic resin paints; lacquers for coating papers; preservatives against rust and wood deterioration; unprocessed natural resins; metals in foil and powder form for painters, decorators, printers and artists.
01 - Chemical and biological materials for industrial, scientific and agricultural use
02 - Paints, varnishes, lacquers
Goods & Services
Chemicals used in industry, science, photography; unprocessed artificial resins, unprocessed plastics; fire extinguishing compositions; tanning substances, namely, oils for tanning wood; adhesives used in industry Paints, varnishes, lacquers; preservatives against rust and wood deterioration in the nature of a coating
The present invention provides a radiation curable composition comprising a hydroxyl functional urethane (meth)acrylate compound (A) having an hydroxyl value between 10 and 80 mg KOH/g and which is the reaction product of a hydroxyl functional (meth)acrylate compound (A1) obtained from the reaction a or b: a. at least one diepoxy functional compound (A11a) with a (meth)acrylate compound (A11b) comprising at least one (meth)acrylate group and one carboxylic acid functional group or b. a carboxylic acid functional compound (A12a) comprising two carboxylic acid groups with an epoxy (meth)acrylate compound (A12b) comprising one glycidyl group and at least one (meth)acrylate group, with a diisocyanate functional compound (A3), and optionally a compound (A2) different of compound (A1) comprising two hydroxyl groups. Such composition is useful for example for dual curable compositions or for thick pigmented systems.
C08G 18/62 - Polymers of compounds having carbon-to-carbon double bonds
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
The present invention relates to a process for preparing a polyester (meth)acrylate resin (I), said process comprising the steps of: (a) Reacting a thermoplastic polyester with (a1) at least one polyhydric alcohol and, optionally, with (a2) at least one triglyceride, wherein the molar ratio of triglyceride to thermoplastic polyester is between 0 and 0.3, and the molar ratio of polyhydric alcohol to thermoplastic polyester is at most 1.9 to obtain a depolymerization product A that has a hydroxyl number within the range of from 200 to 800 mg KOH/g; (b) Reacting the depolymerization product A with (b1) at least one fatty acid and/or (b2) at least one polybasic carboxylic acid and, optionally, with (b3) at least one polyhydric alcohol to provide a polyester polyol B; (c) Reacting the polyester polyol B with (c) at least one (meth)acrylating compound to provide a (meth)acrylated compound (I), wherein the weight ratio of fatty acid (b1) to the depolymerization product A is between 0 and 0.6, wherein the weight ratio of polybasic carboxylic acid (b2) to the depolymerization product A is less than 0.3, wherein the weight ratio of (meth)acrylating compounds (c) to the depolymerization product A is between 0.1 and 0.8, and wherein the (meth)acrylated compound (I) that is obtained has a number average molecular weight (Mn) of between 500 and 5,000 Dalton. Typically PET is used as starting material. Typically compounds (I) of the invention have a PET content of at least 15 wt %, preferably at least 25 wt %. The present invention also relates to (meth)acrylated compounds (I) thus obtained and to coating compositions and inks based upon these materials. Materials of the invention allow the use of a high amount of PET waste. Inks and coatings prepared from these materials exhibit an excellent pigment wetting and/or ink-water balance.
C08J 11/24 - Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
C08G 63/47 - Polyesters chemically modified by esterification by unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C08G 63/91 - Polymers modified by chemical after-treatment
C07C 67/02 - Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
C07C 67/03 - Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
Radiation curable aqueous compositions (I) with reduced photo-yellowing are provided. Said composition comprises water, at least one ethylenically unsaturated compound and at least one carboxylic acid hydrazide-containing compound (H) in an amount sufficient to reduce photo-yellowing. Materials of the invention have the advantage that they help to reduce photo-yellowing. They may have a beneficial effect on long term yellowing caused by weathering too. Compositions (I) of the invention allow a better quality control of products and materials just after cure. Materials of the invention can be used to make coatings, inks, paints, varnishes and adhesives and they are further suitable for the making of composites, gel coats, 3D-curing and the making of 3D-objects in general.
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/34 - Carboxylic acids; Esters thereof with monohydroxyl compounds
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
The present invention relates to a radiation curable composition comprising: (I) A radiation curable component comprising a compound having at least one ethylenically unsaturated group and (II) A chlorinated polyester component that is prepared from (A) A polyol component which is substantially free of any Bisphenol A derivative compound and which is substantially free of any cyclic ether polyol compound, said polyol component comprising a polyol compound (Ai) which is cyclic and which has at least two hydroxyl groups, and (B) A polycarboxylic acid component comprising a compound (Bi) having at least one chlorine group and at least two carboxyl groups, (C) optionally at least one monoalcohol compound, (D) optionally at least one monocarboxylic acid compound, (III) optionally at least one polycarboxylic acid compound substantially free of chlorine groups.
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09J 167/02 - Polyesters derived from dicarboxylic acids and dihydroxy compounds
The invention provides a radiation curable gel coat composition for fibers reinforced substrates, comprising a gel coat resin and at least one diluent monomer (B), wherein the gel coat resin comprises urethane (meth)acrylate reaction products (A) of a reaction mixture comprising: (a) a hydroxy-terminated polyol having a weight average molecular weight of about 200 to about 4000, this polyol being a polycaprolactone polyol or a [(poly)carbonate- (poly)caprolactone] polyol; (b) a diisocyanate; and (c) a hydroxyalkyl (meth)acrylate, and wherein both the diluent monomer (B) and the reaction product (A) contain polymerizable ethylenic unsaturated groups, preferably (meth)acrylate groups. Such gel coat composition provides adequate surface appearance and maintain color and high gloss when exposed to outdoor circumstances.
A radiation curable and at least partially biobased urethane (meth)acrylate for use in a one-component coating composition for cladding an outdoor surface of a building, obtained from the reaction of at least the following compounds: a. A polyisocyanate compound having a biobased carbon content of at least 20%, preferably at least 50%, as determined by method A of the standard ASTM D6866-12: 2008, and b. A (meth)acrylate compound, different from compound a, and containing a reactive group capable to react with isocyanate groups.
Provided in the invention is an adhesion promoter (AP) that is the reaction product of: (i-1) at least one hydroxyl functional (meth)acrylated compound bearing at least two (meth)acryloyl groups, (i-2) optionally, at least one hydroxyl functional (meth)acrylated compound bearing one (meth)acryloyl group (ii), at least one titanium orthoester (ii-a) and/or at least one zirconium orthoester (ii-b), and, (iii) optionally, at least one other compound (iii) that is capable to react with hydroxyl groups. Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes (including overprint varnishes), adhesives (including laminating adhesives), for the making of composites, molding compositions or 3D articles. Materials of the invention are suitable for use in inks and coating compositions (clear or pigmented).
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C08F 230/04 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal containing a metal
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
C09D 135/02 - Homopolymers or copolymers of esters
C09D 143/00 - Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Coating compositions based on derivatives of such polymers
The present invention generally relates to the field of radiation curable compositions comprising (meth)acrylated acrylic polymers comprising pendant hydroxyl groups, methods for making these radiation curable compositions and their uses.
C08G 18/24 - Catalysts containing metal compounds of tin
C08G 18/62 - Polymers of compounds having carbon-to-carbon double bonds
C08G 18/67 - Unsaturated compounds having active hydrogen
C08G 18/73 - Polyisocyanates or polyisothiocyanates acyclic
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 18/79 - Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
C09D 11/102 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
C09D 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
C09D 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
C09J 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
C09J 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
The present invention generally relates to the field of curable resin compositions for cold flexible applications which are prepared from at least one monofunctional monomer and at least one urethane (meth)acrylate and which exhibit high performing coating properties over a broad range of service temperatures including temperatures in very cold conditions, methods for making these curable compositions and their uses.
The present invention generally relates to the field of curable resin compositions for cold flexible applications which are prepared from at least one monofunctional monomer and at least one urethane (meth)acrylate and which exhibit high performing coating properties over a broad range of service temperatures including temperatures in very cold conditions, methods for making these curable compositions and their uses.
The present invention in general relates to acrylate end-capped urethane-based polymers, which are in particular characterized by the presence of at least 3 acrylate end-groups, thereby making them particularly suitable for further processing using multiple kinds of technologies such as 2-photon polymerization, stereolithography (SLA printing), electrospinning, film casting, porogen leaching, extrusion based 3D-printing, spray drying, cryogenic treatment, coatings, cross-linkable micelles, spincoating, and electrospraying.
The present invention in general relates to acrylate end-capped urethane-based polymers, which are in particular characterized by the presence of at least 3 acrylate end-groups, thereby making them particularly suitable for further processing using multiple kinds of technologies such as 2-photon polymerization, stereolithography (SLA printing), electrospinning, film casting, porogen leaching, extrusion based 3D-printing, spray drying, cryogenic treatment, coatings, cross-linkable micelles, spincoating, and electrospraying.
The present invention relates to stabilizers for thiol-ene compositions and to radiation curable thiol-ene compositions based thereon. Such radiation curable compositions can advantageously be used in inks, overprint varnishes, coatings, adhesives, for the making of 3D objects and for the making of solder resist and gel nails. Provided in particular is an inhibitor system (I) for thiol-ene compositions based on —at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, —at least one acidic compound (ii) having a pKa between 1 and 3, and —at least one compound (iii) selected from the group consisting of phosphites and phosphonites, with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring. Also provided is an inhibitor system (II) for thiol-ene compositions based on that is based on —at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, —at least one compound (iv) selected from the group consisting of spirophosphites, and —optionally, at least one acidic compound (ii) having a pKa between 1 and 3, and with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring.
C07C 271/22 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
The present invention provides a radiation curable composition comprising a hydroxyl functional urethane (meth)acrylate compound (A) having an hydroxyl value between 10 and 80 mg KOH/g and which is the reaction product of a hydroxyl functional (meth)acrylate compound (A1) obtained from the reaction a or b: a.at least one diepoxy functional compound (A11a) with a (meth)acrylate compound (A11b) comprising at least one (meth)acrylate group and one carboxylic acid functional group or b.a carboxylic acid functional compound (A12a) comprising two carboxylic acid groups with an epoxy (meth)acrylate compound (A12b) comprising one glycidyl group and at least one (meth)acrylate group, with a diisocyanate functional compound (A3), and optionally a compound (A2) different of compound (A1) comprising two hydroxyl groups. Such composition is useful for example for dual curable compositions or for thick pigmented systems.
C08G 18/62 - Polymers of compounds having carbon-to-carbon double bonds
C08G 18/73 - Polyisocyanates or polyisothiocyanates acyclic
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 18/79 - Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
C08G 18/10 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/24 - Catalysts containing metal compounds of tin
The present invention relates to a radiation curable composition comprising: (I) A radiation curable component comprising a compound having at least one ethylenically unsaturated group and (II) A chlorinated polyester component that is prepared from (A) A polyol component which is substantially free of any Bisphenol A derivative compound and which is substantially free of any cyclic ether polyol compound, said polyol component comprising a polyol compound (Ai) which is cyclic and which has at least two hydroxyl groups, and (B) A polycarboxylic acid component comprising a compound (Bi) having at least one chlorine group and at least two carboxyl groups, (C) optionally at least one monoalcohol compound, (D) optionally at least one monocarboxylic acid compound, (III) optionally at least one polycarboxylic acid compound substantially free of chlorine groups.
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C08G 63/682 - Polyesters containing atoms other than carbon, hydrogen, and oxygen containing halogens
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09D 11/10 - Printing inks based on artificial resins
C09D 167/00 - Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
C09D 167/02 - Polyesters derived from dicarboxylic acids and dihydroxy compounds
The present invention relates to a radiation curable composition comprising: (I) A radiation curable component comprising a compound having at least one ethylenically unsaturated group and (II) A chlorinated polyester component that is prepared from (A) A polyol component which is substantially free of any Bisphenol A derivative compound and which is substantially free of any cyclic ether polyol compound, said polyol component comprising a polyol compound (Ai) which is cyclic and which has at least two hydroxyl groups, and (B) A polycarboxylic acid component comprising a compound (Bi) having at least one chlorine group and at least two carboxyl groups, (C) optionally at least one monoalcohol compound, (D) optionally at least one monocarboxylic acid compound, (III) optionally at least one polycarboxylic acid compound substantially free of chlorine groups.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09D 11/10 - Printing inks based on artificial resins
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 167/00 - Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
C09D 167/02 - Polyesters derived from dicarboxylic acids and dihydroxy compounds
C08G 63/682 - Polyesters containing atoms other than carbon, hydrogen, and oxygen containing halogens
The present invention relates to an energy curable aqueous composition (X) comprising (a) Water; (b) At least a water-insoluble ethylenically unsaturated compound (A); (c) At least one (meth)acrylic polymer (B1) containing ionic functional groups that are at least partly neutralized by a neutralizing agent (C) and/or at least one (meth)acrylic hybrid (B2) containing ionic functional groups that are at least partly neutralized by a neutralizing agent (C); and (d) At least one nonionic emulsifier (D) comprising alternating polyalkylene oxide segments, said nonionic emulsifier (D) having an HLB value of at least 4.5. Materials of the invention are suitable for the preparation of inks, overprint varnishes or coating compositions.
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C08F 220/06 - Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
C08F 8/44 - Preparation of metal salts or ammonium salts
C09D 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08F 220/64 - Acids; Metal salts or ammonium salts thereof
C08L 33/02 - Homopolymers or copolymers of acids; Metal or ammonium salts thereof
The radiation curable compositions (I) that comprise from 10 to 80 by weight of at least one silicone-modified urethane (meth) acrylate (A), from 0.5 to 60 by weight of at least one (meth) acrylated compound (B) bearing at least 5 (meth) acryloyl groups per molecule, and optionally, from 10 to 60% by weight of at least one compound (C) different from (A) or (B), wherein the weight percentages are on the total weight of the composition (I). These materials can be used for producing coatings, inks and overprint varnishes with excellent anti-stain properties, to their use and preparation. Materials of the invention are compatible with standard radiation curable materials. They allow to obtain excellent anti-stain properties for high gloss coatings as well as for matte coatings (II) with a gloss level at 60° of at most 15, even at most 10.
C08G 18/67 - Unsaturated compounds having active hydrogen
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 11/102 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
C09D 11/54 - Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink
Provided in the invention is an adhesion promoter (AP) that is the reaction product of: (i-1) at least one hydroxyl functional (meth)acrylated compound bearing at least two (meth)acryloyl groups, (i-2) optionally, at least one hydroxyl functional (meth)acrylated compound bearing one (meth)acryloyl group (ii), at least one titanium orthoester (ii-a) and/or at least one zirconium orthoester (ii-b), and, (iii) optionally, at least one other compound (iii) that is capable to react with hydroxyl groups. Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes (including overprint varnishes), adhesives (including laminating adhesives), for the making of composites, molding compositions or 3D articles. Materials of the invention are suitable for use in inks and coating compositions (clear or pigmented).
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 5/00 - Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
The present invention generally relates to the field of radiation curable compositions comprising (meth)acrylated acrylic polymers comprising pendant hydroxyl groups, methods for making these radiation curable compositions and their uses.In particular, the present invention refers to a radiation curable composition (X) comprising at least one (meth)acrylated acrylic polymer (AA) comprising pendant hydroxyl groups which is the reaction product of: a) At least one water-insoluble(meth)acrylic polymer (AP) comprising pendant hydroxyl groups which is the reaction product of: a1) at least one hydroxy functional ethylenically unsaturated monomer (AP1), and a2)at least one ethylenically unsaturated monomer (AP2) which is different from (AP1), and b) At least one isocyanate group-containing monoadduct (MA) comprising at least one (meth)acrylate group and which attaches to the water-insoluble(meth)acrylic polymer (AP) comprising pendant hydroxyl groups by an urethane linkage and which is the reaction product of: b1) at least one polyisocyanate (MA1), and b2) at least one hydroxy functional (meth)acrylate monomer (MA2), wherein the equivalent ratio of NCO groups to OH groups of the radiation curable composition (X) is from 1:0,5 to 1:10 and the glass transition temperature (Tg) of the radiation curable composition (X) after the acrylation is at least 10°C.
C08G 18/62 - Polymers of compounds having carbon-to-carbon double bonds
C08F 220/20 - Esters of polyhydric alcohols or phenols
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C09D 133/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
C09D 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
The present invention relates to a process for preparing a polyester (meth)acrylate resin (I), said process comprising the steps of: (a) Reacting a thermoplastic polyester with (a1) at least one polyhydric alcohol and, optionally, with (a2) at least one triglyceride, wherein the molar ratio of triglyceride to thermoplastic polyester is between 0 and 0.3, and the molar ratio of polyhydric alcohol to thermoplastic polyester is at most 1.9 to obtain a depolymerization product A that has a hydroxyl number within the range of from 200 to 800 mg KOH/g; (b) Reacting the depolymerization product A with (b1) at least one fatty acid and/or (b2) at least one polybasic carboxylic acid and, optionally, with (b3) at least one polyhydric alcohol to provide a polyester polyol B; (c) Reacting the polyester polyol B with (c) at least one (meth)acrylating compound to provide a (meth)acrylated compound (I), wherein the weight ratio of fatty acid (b 1) to the depolymerization product A is between 0 and 0.6, wherein the weight ratio of polybasic carboxylic acid (b2) to the depolymerization product A is less than 0.3, wherein the weight ratio of (meth)acrylating compounds (c) to the depolymerization product A is between 0.1 and 0.8, and wherein the (meth)acrylated compound (I) that is obtained has a number average molecular weight (Mn) of between 500 and 5,000 Dalton. Typically PET is used as starting material. Typically compounds (I) of the invention have a PET content of at least 15 wt %, preferably at least 25 wt %. The present invention also relates to (meth)acrylated compounds (I) thus obtained and to coating compositions and inks based upon these materials. Materials of the invention allow the use of a high amount of PET waste. Inks and coatings prepared from these materials exhibit an excellent pigment wetting and/or ink-water balance.
C08G 63/91 - Polymers modified by chemical after-treatment
C08J 11/24 - Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
C08G 63/47 - Polyesters chemically modified by esterification by unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C07C 67/02 - Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
C07C 67/03 - Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
Radiation curable aqueous compositions (I) with reduced photo-yellowing are provided. Said composition comprises water, at least one ethylenically unsaturated compound and at least one carboxylic acid hydrazide-containing compound (H) in an amount sufficient to reduce photo-yellowing. Materials of the invention have the advantage that they help to reduce photo-yellowing. They may have a beneficial effect on long term yellowing caused by weathering too. Compositions (I) of the invention allow a better quality control of products and materials just after cure. Materials of the invention can be used to make coatings, inks, paints, varnishes and adhesives and they are further suitable for the making of composites, gel coats, 3D-curing and the making of 3D-objects in general.
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes, adhesives, for the making of gel coats, composites, molding compositions or 3D articles. Materials of the invention are in particular suitable as surface cure boosterin UV and UV LED applications.
C07C 229/30 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and unsaturated
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
Materials of the invention are suitable for use in coating compositions, inks, paints, varnishes, adhesives, for the making of gel coats, composites, molding compositions or 3D articles. Materials of the invention are in particular suitable as surface cure boosterin UV and UV LED applications.
C07C 229/30 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and unsaturated
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
The present invention relates to radiation curable coating composition (I) consisting essentially of: —from 20 to 95 wt % of one or more (meth)acrylated compounds (a), from 5 to 80 wt % of one or more metal salts of a C10 to C22 fatty acid (b), and—optionally, from 0 to 10 wt % of one or more additives (c), wherein the wt % of compounds (a) to (c) add up to at least 95%, preferably add up to 100%. Compositions of the invention are compatible with a whole range of radiation curable materials and with the standard additives like the standard matting agents. Compositions of the invention permit to obtain a dead matt effect using lower amounts of matting agents like silica and/or waxes. Dead matt effects can be obtained over a wide range of coating thicknesses.
C09D 11/08 - Printing inks based on natural resins
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 5/00 - Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C09D 133/10 - Homopolymers or copolymers of methacrylic acid esters
The invention pertains to the technical field of urethane based materials, in particular to radiation curable urethane precursors that are cross-linkable in solid form and materials obtainable therefrom. In addition the invention pertains to methods for manufacturing these precursors and materials, and their uses. The invention is advantageous to the fields of i.e. coatings and biomedical applications.
C08G 18/00 - Polymeric products of isocyanates or isothiocyanates
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 18/67 - Unsaturated compounds having active hydrogen
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/10 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
C08J 3/28 - Treatment by wave energy or particle radiation
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
D01D 5/00 - Formation of filaments, threads, or the like
D01F 11/08 - Chemical after-treatment of man-made filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C08J 3/24 - Crosslinking, e.g. vulcanising, of macromolecules
The present invention relates to an energy curable aqueous composition (X) comprising (a) Water; (b) At least a water-insoluble ethylenically unsaturated compound (A); (c) At least one (meth)acrylic polymer (B1 ) containing ionic functional groups that are at least partly neutralized by a neutralizing agent (C) and/or at least one (meth)acrylic hybrid (B2) containing ionic functional groups that are at least partly neutralized by a neutralizing agent (C); and (d) At least one nonionic emulsifier (D) comprising alternating polyalkylene oxide segments, said nonionic emulsifier (D) having an HLB value of at least 4.5. Materials of the invention are suitable for the preparation of inks, overprint varnishes or coating compositions.
C08F 220/06 - Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09D 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C08F 8/44 - Preparation of metal salts or ammonium salts
A radiation curable compositions (I) that comprise from 10 to 80％by weight of at least one silicone-modified urethane (meth)acrylate (A), from 0.5 to 60％by weight of at least one (meth)acrylated compound (B) bearing at least 5 (meth)acryloyl groups per molecule, and optionally, from 10 to 60％by weight of at least one compound (C) different from (A) or (B), wherein the weight percentages are on the total weight of the composition (I). These materials can be used for producing coatings, inks and overprint varnishes.
C08F 299/08 - Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polysiloxanes
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
50.
RADIATION CURABLE COMPOSITIONS WITH ANTI-STAIN PROPERTIES
The radiation curable compositions (I) that comprise from 10 to 80 by weight of at least one silicone-modified urethane (meth) acrylate (A), from 0.5 to 60 by weight of at least one (meth) acrylated compound (B) bearing at least 5 (meth) acryloyl groups per molecule, and optionally, from 10 to 60% by weight of at least one compound (C) different from (A) or (B), wherein the weight percentages are on the total weight of the composition (I). These materials can be used for producing coatings, inks and overprint varnishes with excellent anti-stain properties, to their use and preparation. Materials of the invention are compatible with standard radiation curable materials. They allow to obtain excellent anti-stain properties for high gloss coatings as well as for matte coatings (II) with a gloss level at 60° of at most 15, even at most 10.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
The present invention relates to a process for preparing a polyester (meth)acrylate resin (I), said process comprising the steps of: (a) Reacting a thermoplastic polyester with (a1) at least one polyhydric alcohol and, optionally, with (a2) at least one triglyceride, wherein the molar ratio of triglyceride to thermoplastic polyester is between 0 and 0.3, and the molar ratio of polyhydric alcohol to thermoplastic polyester is at most 1.9 to obtain a depolymerization product A that has a hydroxyl number within the range of from 200 to 800 mg KOH/g; (b) Reacting the depolymerization product A with (b1) at least one fatty acid and/or (b2) at least one polybasic carboxylic acid and, optionally, with (b3) at least one polyhydric alcohol to provide a polyester polyol B; (c) Reacting the polyester polyol B with (c) at least one (meth)acrylating compound to provide a (meth)acrylated compound (I), wherein the weight ratio of fatty acid (b1) to the depolymerization product A is between 0 and 0.6, wherein the weight ratio of polybasic carboxylic acid (b2) to the depolymerization product A is less than 0.3, wherein the weight ratio of (meth)acrylating compounds (c) to the depolymerization product A is between 0.1 and 0.8, and wherein the (meth)acrylated compound (I) that is obtained has a number average molecular weight (Mn) of between 500 and 5,000 Dalton. Typically PET is used as starting material. Typically compounds (I) of the invention have a PET content of at least 15 wt%, preferably at least 25 wt%. The present invention also relates to (meth)acrylated compounds (I) thus obtained and to coating compositions and inks based upon these materials. Materials of the invention allow the use of a high amount of PET waste. Inks and coatings prepared from these materials exhibit an excellent pigment wetting and/or ink-water balance.
C08G 63/47 - Polyesters chemically modified by esterification by unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C08J 11/24 - Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
C08G 63/91 - Polymers modified by chemical after-treatment
C09D 167/07 - Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
30 and provide polymer materials with a good flow and mirror effect. In general, these materials are less sensitive to dust pick-up and fingerprints. Further provided is a one-vessel solvent free process for preparing such materials.
There is described a powder coating composition suitable for food contact use comprising a mix of: (A) a first polyester that is amorphous and COOH functional being obtained from IPA and/or TPA and no more than 10 mole % neopentyl glycol (NPG); (B) a second optional COOH functional polyester obtained from analiphatic diacid and analiphatic diol, and (C) a curing agent that comprises functional groups reactable with the COOH of the polyester(s). The powders are suitable for coating the interior of metal cans especially those holding alcoholic beverages.
The present invention relates to radiation curable coating composition (I) consisting essentially of: - from 20 to 95 wt% of one or more (meth)acrylated compounds (a), - from 5 to 80 wt% of one or more metal salts of a C10 to C22 fatty acid (b), and - optionally, from 0 to 10 wt% of one or more additives (c), wherein the wt% of compounds (a) to (c) add up to at least 95%, preferably add up to 100%. Compositions of the invention are compatible with a whole range of radiation curable materials and with the standard additives like the standard matting agents. Compositions of the invention permit to obtain a dead matt effect using lower amounts of matting agents like silica and/or waxes. Dead matt effects can be obtained over a wide range of coating thicknesses.
The present invention relates to radiation curable coating composition (I) consisting essentially of: - from 20 to 95 wt% of one or more (meth)acrylated compounds (a), - from 5 to 80 wt% of one or more metal salts of a C10 to C22 fatty acid (b), and - optionally, from 0 to 10 wt% of one or more additives (c), wherein the wt% of compounds (a) to (c) add up to at least 95%, preferably add up to 100%. Compositions of the invention are compatible with a whole range of radiation curable materials and with the standard additives like the standard matting agents. Compositions of the invention permit to obtain a dead matt effect using lower amounts of matting agents like silica and/or waxes. Dead matt effects can be obtained over a wide range of coating thicknesses.
The present patent application relates to a method for gluing two adjacent substrates together by using a radiation curable adhesive composition and a use of a radiation curable adhesive composition for gluing. In particular, the method for gluing involves the use of a radiation curable adhesive composition which comprises from 0.1 wt.% to 30 wt.% of fibers compared to the total weight of the radiation curable adhesive composition, wherein the fibers have a length comprised from 100 microns to 50 mm.
The present invention relates to stabilizers for thiol-ene compositions and to radiation curable thiol-ene compositions based thereon. Such radiation curable compositions can advantageously be used in inks, overprint varnishes, coatings, adhesives, for the making of 3D objects and for the making of solder resist and gel nails. Provided in particular is an inhibitor system (I) for thiol-ene compositions based on —at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, —at least one acidic compound (ii) having a pKa between 1 and 3, and —at least one compound (iii) selected from the group consisting of phosphites and phosphonites, with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring. Also provided is an inhibitor system (II) for thiol-ene compositions based on that is based on —at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, —at least one compound (iv) selected from the group consisting of spirophosphites, and —optionally, at least one acidic compound (ii) having a pKa between 1 and 3, and with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring.
C09K 15/32 - Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing boron, silicon, phosphorus, selenium, tellurium or a metal
C07C 271/22 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
The invention pertains to the technical field of urethane based materials, in particular to radiation curable urethane precursors that are cross-linkable in solid form and materials obtainable therefrom. In addition the invention pertains to methods for manufacturing these precursors and materials, and their uses. The invention is advantageous to the fields of i.e. coatings and biomedical applications.
The present invention relates to waterborne curing compositions for electrodeposition and radiation curing and processes to obtain such compositions. The compositions are characterized in that an ethylenically unsaturated compound (b), is dispersed in an aqueous solution by an at least partially neutralized (meth)acrylic modified amine epoxy adduct. The compositions of the invention are particularly suitable for coating metallic materials and temperature sensitive materials such as electrically conductive plastic materials.
C08G 18/62 - Polymers of compounds having carbon-to-carbon double bonds
C08G 18/64 - Macromolecular compounds not provided for by groups
C09D 5/44 - Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
C08F 283/10 - Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass on to polymers containing more than one epoxy radical per molecule
C09D 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C25D 13/18 - Electrophoretic coating characterised by the process using modulated, pulsed or reversing current
C09D 163/00 - Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
C08G 18/67 - Unsaturated compounds having active hydrogen
C08G 18/79 - Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
C08G 59/17 - Polycondensates modified by chemical after-treatment by monocarboxylic acids or by anhydrides, halides or low-molecular-weight esters thereof by acrylic or methacrylic acid
C08G 59/14 - Polycondensates modified by chemical after-treatment
C08G 59/18 - Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
C09D 163/10 - Epoxy resins modified by unsaturated compounds
The present invention relates to radiation curable compositions (A) comprising—(a) at least one photoinitiator compound of formula (I) wherein Q is the residue of a hydroxy compound having 1 to 6 hydroxyl groups, and wherein x is a number that is at least 1 but no greater than the number of hydroxyl groups originally present in said hydroxy compound;—(b) at least one ethylenically unsaturated compound selected from monomers (b1) and/or from oligomers (b2); and—(c) optionally, at least one co-synergist which preferably is an amino co-synergist. The present invention further relates to photoinitiator compounds(a) and their preparation.
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C08K 5/103 - Esters; Ether-esters of monocarboxylic acids with polyalcohols
C08G 65/332 - Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides or esters thereof
An aqueous radiation curable composition comprising an ethylenically unsaturated polyurethane (A) (obtained from a polyisocyanate compound (Ai); an ethylenically unsaturated compound (Aii); a hydrophilic compound (Aiii); optionally, a polyol (Aiv); a further compound (Av) different from the polyol (Aiv); and/or a reactive electrophilic compound (Avi)); an ethylenically unsaturated polyurethane (B), different from (A) (obtained from a polyisocyanate compound (Bi); an ethylenically unsaturated compound (Bii); optionally, a polyol (Biv); a further compound (Bv) different from the polyol (Biv); and/or a reactive electrophilic compound (Bvi)); and optionally, an ethylenically unsaturated compound (C) different from (A) and (B). The equivalent ratio of isocyanate-reactive groups (compounds (Aii) to (Ai)) is above 50%. The composition has at least 2.5 wt% of compounds (B), and in dry form shows a steady- state creep viscosity 113o, above 1.103 Pa.s. A preparation process and an article or substrate coated with the composition.
Provided in the invention is an aqueous radiation curable composition (I) comprising : - at least one ethylenically unsaturated polyurethane (A) obtained from the reaction of at least one polyisocyanate compound (Ai); at least one ethylenically unsaturated compound (Aii) containing at least one reactive group capable to react with isocyanate groups; at least one hydrophilic compound (Aiii) containing at least one reactive group capable to react with isocyanate groups and at least one other group which is capable to render the polyurethane polymer dispersible in aqueous medium as such or after the formation of a salt; optionally, at least one polyol (Aiv); optionally, at least one further compound (Av) different from the polyol (Aiv) and comprising at least one reactive group capable to react with isocyanate groups; and optionally, at least one reactive electrophilic compound (Avi); said ethylenically unsaturated polyurethane (A) preferably being characterized by a molecular weight that is above 1,000 Daltons; - at least one ethylenically unsaturated polyurethane (B), different from the polyurethane (A), obtained from the reaction of at least one polyisocyanate compound (Bi); at least one ethylenically unsaturated compound (Bii) containing at least one reactive group capable to react with isocyanate groups; optionally, at least one polyol (Biv); optionally, at least one further compound (Bv) different from the polyol (Biv) and comprising at least one reactive group capable to react with isocyanate groups; and optionally, at least one reactive electrophilic compound (Bvi); said ethylenically unsaturated polyurethane (B) preferably being characterized by a molecular weight that is below 10,000 Daltons; and optionally, at least one ethylenically unsaturated compound (C) different from (A) and (B); wherein the radiation curable composition (I) in dry form has a steady-state creep viscosity η30, expressed as the apparent viscosity after a deformation time of 30 minutes with a load σ0 = 50 Pa at 23°C, that is above 1.103 Pa.s, more preferably above 1.104 Pa.s. Compositions (I) of the invention are characterized by a n improved creep viscosity r|3oand provide polymer materials with a good flow and mirror effect. In general these materials are less sensitive to dust pick-up and fingerprints. Further provided in the invention is a one-vessel solvent free process for preparing such materials.
The present invention relates to an aqueous resin composition (I) comprising at least one polymerizable ethylenically unsaturated polyurethane polymer (A), optionally, at least one polymerizable ethylenically unsaturated compound (B) different from (A), and optionally, at least one neutralizing agent (C); wherein the polyurethane polymer (A) has a weight average molecular weight of less than 15.000 Daltons and is obtained from the reaction of: at least one polyisocyanate (i); at least one hydrophilic compound (ii) containing at least one reactive group capable to react with isocyanate groups and at least one group which is capable to render the polyurethane polymer dispersible or soluble in aqueous medium either directly or after reaction with a neutralizing agent (C) to provide a salt; at least one compound (iii) containing essentially one reactive group capable to react with isocyanate groups and at least one copolymerizable ethylenically unsaturated group; at least one compound (iv) containing at least two reactive groups capable to react with isocyanate groups; and, optionally, at least one chain extender (v) containing at least two reactive groups capable to react with isocyanate groups, which chain extender is different from compounds (iv); and wherein the non-volatile components of the resin composition (I) after drying are re-dispersible or re-soluble in water at 25° C. The present invention further relates to radiation curable compositions comprising a resin composition of the invention for use in coating applications or graphic art applications.
C08G 18/67 - Unsaturated compounds having active hydrogen
C08G 18/73 - Polyisocyanates or polyisothiocyanates acyclic
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
The present invention relates to a process for the preparation of dispersions of colloidal polymerized particles and to the colloidal polymerized particles obtained and/or obtainable by the process as well as to their use.
B01J 13/00 - Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
C08F 283/00 - Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass
C08J 3/28 - Treatment by wave energy or particle radiation
C08F 2/50 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
C04B 24/28 - Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C04B 24/26 - Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
C04B 24/32 - Polyethers, e.g. alkylphenol polyglycolether
C08F 2/48 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
The invention relates to radiation-curable aqueous composition comprising an (meth)acrylated polyurethane pre-polymer obtained from the reaction of a polyisocyanate, optionally a polyol, at least one hydrophilic compound containing at least one reactive group capable to react with isocyanate groups and which is capable to render the polyurethane pre-polymer dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, an (meth)acrylated compound containing at least two reactive groups capable to react with isocyanate groups and an (meth)acrylated compound containing essentially one reactive group capable to react with isocyanate groups, said composition comprising an amount of (meth)acrylated and polymerizable ethylenically unsaturated groups of at least 3 meq per g.
C08G 18/34 - Carboxylic acids; Esters thereof with monohydroxyl compounds
C07C 229/02 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
C09D 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C08J 3/28 - Treatment by wave energy or particle radiation
B29C 64/124 - Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
C08L 75/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
B29K 23/00 - Use of polyalkenes as moulding material
B29K 69/00 - Use of polycarbonates as moulding material
B29K 75/00 - Use of polyureas or polyurethanes as moulding material
The present invention provides for a radiation curable composition comprising at least one ethylenically unsaturated compound (A),and at least one inert copolymer (B) that is obtained by an addition reaction of: (b) from 3 to 50% by weight of at least one monofunctional glycidyl ether (b1) and/or at least one monofunctional glycidyl ester (b2) of aliphatic saturated monocarboxylic acids during the free radical polymerization of: (b') from 50 to 97% by weight of at least two ethylenically unsaturated copolymerizable monomers of which at least one contains at least one -COOH group (b'1), wherein the quantity of -COOH groups in component (b'1) is at least equimolar to the quantity of epoxy groups in component (b), and wherein the amount of solvents in the radiation curable composition of the invention is below 10% by weight. The present invention further relates to their making and their use in coating compositions, adhesives, inks and varnishes.
The present invention relates to stabilizers for thiol-ene compositions and to radiation curable thiol-ene compositions based thereon. Such radiation curable compositions can advantageously be used in inks, overprint varnishes, coatings, adhesives, for the making of 3D objects and for the making of solder resist and gel nails. Provided in particular is an inhibitor system (I) for thiol-ene compositions based on - at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, - at least one acidic compound (ii) having a pKa between 1 and 3, and - at least one compound (iii) selected from the group consisting of phosphites and phosphonites, with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring. Also provided is an inhibitor system (II) for thiol-ene compositions based on that is based on - at least one inhibitor compound (i) having a % DPPH radical scavenging activity of at least 90%, the inhibitor compound (i) being selected from substituted benzene compounds or substituted naphthalene compounds containing at least two substituents selected from the group consisting of hydroxyl groups and C1-C3 alkoxy groups bonded directly to the benzene or the naphthalene ring, - at least one compound (iv) selected from the group consisting of spirophosphites, and - optionally, at least one acidic compound (ii) having a pKa between 1 and 3, and with the proviso that if the inhibitor compound (i) is a substituted benzene that it contains at least two hydroxyl groups bonded directly to the benzene ring.
The present invention relates to waterborne curing compositions for electrodeposition and radiation curing and processes to obtain such compositions. The compositions are characterized in that an ethylenically unsaturated compound (b), is dispersed in an aqueous solution by an at least partially neutralized (meth)acrylic modified amine epoxy adduct. The compositions of the invention are particularly suitable for coating metallic materials and temperature sensitive materials such as electrically conductive plastic materials.
C08G 18/62 - Polymers of compounds having carbon-to-carbon double bonds
C08G 18/64 - Macromolecular compounds not provided for by groups
C09D 5/44 - Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
C08F 283/10 - Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass on to polymers containing more than one epoxy radical per molecule
C09D 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C25D 13/18 - Electrophoretic coating characterised by the process using modulated, pulsed or reversing current
C09D 163/00 - Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
The present invention relates to radiation curable compositions (A) comprising -(a) at least one photoinitiator compound of formula (I) wherein Q is the residue of a hydroxy compound having 1 to 6 hydroxyl groups, and wherein x is a number that is at least 1 but no greater than the number of hydroxyl groups originally present in said hydroxy compound; -(b) at least one ethylenically unsaturated compound selected from monomers (b1) and/or from oligomers (b2); and -(c) optionally,at least one co-synergist which preferably is an amino co-synergist. The present invention further relates to photoinitiator compounds(a) and their preparation.
C08F 220/00 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
C08K 5/103 - Esters; Ether-esters of monocarboxylic acids with polyalcohols
The present invention relates to a transparent composite composition (a) comprising: a. a resin composition, comprising i. at least one (meth)acrylated oligomer (ia) and/or monomer (ib), ii. at least one polythiol (ii), and iii. optionally, one or more photo-and/or thermal initiators (iii), and b. at least one transparent filler material (b). The present invention further relates to its preparation and uses.
B24D 11/00 - Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
B32B 1/00 - Layered products essentially having a general shape other than plane
C07C 327/22 - Esters of monothiocarboxylic acids having carbon atoms of esterified thiocarboxyl groups bound to hydrogen atoms or to acyclic carbon atoms
C08F 299/02 - Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
C09J 4/00 - Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C08L 61/24 - Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
C08L 61/28 - Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
C08L 81/00 - Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
The present invention relates to (meth)acrylated compounds (A) prepared from (a) at least one cyclic ether polyol, (b) at least one linking compound (b1) and/or (b2), wherein the linking compound (b1) is selected from cyclic compounds (b11) containing at least one (I) group in the cycle where X=O or NH, from hydroxy acids (b12) and/or from alkylene oxides (b13) containing from 2 to 4 carbon atoms and the linking compound (b2) is selected from epihalohydrins or polyisocyanates, (c) a (meth)acrylating compound; and to their use in radiation curable compositions for the coatings, inks, overprint varnishes, adhesives and composites.
C07D 303/40 - Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
C08F 2/46 - Polymerisation initiated by wave energy or particle radiation
C08G 61/04 - Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
C09D 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
The present invention relates to an aqueous radiation curable composition comprising: (I) at least one ethylenically unsaturated compound (A), and (II) at least one emulsifier (B) comprising alternating polyalkylene oxide segments, wherein said emulsifier optionally bears one or more groups selected from alkyl groups, aryl groups hydroxyl groups and/or ethylenically unsaturated groups, and wherein said emulsifier (B) has an HLB value of at least 4.5, preferably at least 7. The compositions of the invention are particularly suited for the manufacture of sprayable eco-friendly hardcoats, but they are also suitable for the making of inks, overprint varnishes and adhesives, alone or in combination with e.g. a water-borne polymer dispersion.
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09J 4/06 - Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C09D 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
B05D 3/00 - Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
B05D 3/06 - Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
The present invention relates to a (meth)acrylated compound (A) prepared from: (i) a polyol constituent, (ii) a polyacid constituent and (iii) one or more (meth)acrylating compounds, wherein the polyol constituent comprises at least 30% by weight of one or more cyclic ether polyols, relative to the total weight of the polyol constituent, and wherein the compound (A) optionally further contains one or more moieties selected from the group consisting of (poly)caprolactone-containing moieties (ai), (poly)lactide- and/or (poly)glycolide-containing moieties (aii), moieties providing epoxide groups (aiii) and moieties providing alkylene oxide groups containing from 2 to 4 carbon atoms (aiv). The compounds of the invention are in particular suited for the making of radiation curable coating compositions and inks less prone to migration.
C08G 63/47 - Polyesters chemically modified by esterification by unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
C09D 167/07 - Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
C07C 69/604 - Polycarboxylic acid esters, the acid moiety containing more than two carboxyl groups
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C07C 271/24 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a ring other than a six-membered aromatic ring
C09D 11/107 - Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
C09D 133/08 - Homopolymers or copolymers of acrylic acid esters
75.
COMPOSITE COMPOSITION CONTAINING A POLYCYCLIC ETHER POLYPOL
The present invention relates to a composite composition comprising: I. a resin composition (I), comprising A. at least one (meth)acrylated compound (A) prepared from: (a) at least one polycyclic ether polyol (a), (b) optionally, at least one linking compound (b1 ) and/or (b2), (c) at least one (meth)acrylating compound (c), B. optionally, one or more radiation curable oligomer (B), C. optionally, one or more radiation curable monomer (C), D. optionally, one or more photo- and/or thermal initiators (D), and at least 1wt% of a fibrous reinforcement material (II) relative to the total weight of the resin composition (I) and the fibrous reinforcement material (II). The present invention further relates to its preparation and uses.
7 with a compound of the following general formula (IX):
M is a group comprising a number z of (meth)acrylate groups equal to at least one, as well as inks, coating compositions and adhesives comprising the same.
C07C 229/38 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino groups bound to acyclic carbon atoms and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
C07C 229/12 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of acyclic carbon skeletons
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
C07C 227/16 - Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof by reactions not involving the amino or carboxyl groups
C07C 69/76 - Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a six-membered aromatic ring
C07C 229/38 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino groups bound to acyclic carbon atoms and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
C07C 229/12 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of acyclic carbon skeletons
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
C07C 227/16 - Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof by reactions not involving the amino or carboxyl groups
The present invention relates to an aqueous resin composition (I) comprising at least one polymerizable ethylenically unsaturated polyurethane polymer (A), optionally, at least one polymerizable ethylenically unsaturated compound (B) different from (A), and optionally, at least one neutralizing agent (C); wherein the polyurethane polymer (A) has a weight average molecular weight of less than 15.000 Daltons and is obtained from the reaction of: at least one polyisocyanate (i); at least one hydrophilic compound (ii) containing at least one reactive group capable to react with isocyanate groups and at least one group which is capable to render the polyurethane polymer dispersible or soluble in aqueous medium either directly or after reaction with a neutralizing agent (C) to provide a salt; at least one compound (iii) containing essentially one reactive group capable to react with isocyanate groups and at least one copolymerizable ethylenically unsaturated group; at least one compound (iv) containing at least two reactive groups capable to react with isocyanate groups; and, optionally, at least one chain extender (v) containing at least two reactive groups capable to react with isocyanate groups, which chain extender is different from compounds (iv); and wherein the non-volatile components of the resin composition (I) after drying are re-dispersible or re-soluble in water at 25°C. The present invention further relates to radiation curable compositions comprising a resin composition of the invention for use in coating applications or graphic art applications.
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
The present invention relates to a process for the preparation of dispersions of colloidal polymerized particles and to the colloidal polymerized particles obtained and/or obtainable by the process as well as to their use.
C04B 20/00 - Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
C08F 2/32 - Polymerisation in water-in-oil emulsions
C08F 2/48 - Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
The present invention relates to an aqueous radiation curable coating composition comprising at least one radiation curable polymer (A) and at least one organic matting polymer (B) providing uniform matt coatings.
An aqueous dispersion comprising a mixture of a first dispersion and a second dispersion, wherein the first dispersion comprises at least one (meth)acrylated pre-polymer (A), and the second dispersion comprises at least one thiol-functional compound (B). The aqueous dispersion optionally comprises at least one ethylenically unsaturated compound (C).
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
C08L 33/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
The present invention relates to a radiation curable composition comprising at least one (meth)acrylated compound compound (A); and at least one inert polyester (B) that is prepared from a (i) polyol component comprising at least one cyclic ether polyol and (ii) from a polyacid component. The present invention further relates to their preparation and uses.
B01F 17/00 - Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
C08F 20/00 - Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nit
C09D 167/00 - Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
The invention relates to a flame retardant composition comprising at least one radiation curable oligomer and at least one reactive aliphatic halogenated flame retardant additive and its use to make fire-resistant glass laminates with impact resistance.
B32B 17/10 - Layered products essentially comprising sheet glass, or fibres of glass, slag or the like comprising glass as the main or only constituent of a layer, next to another layer of a specific substance of synthetic resin
C08L 33/16 - Homopolymers or copolymers of esters containing halogen atoms
B32B 17/00 - Layered products essentially comprising sheet glass, or fibres of glass, slag or the like
The invention relates to a flame retardant composition comprising at least one radiation curable oligomer and at least one reactive aliphatic halogenated flame retardant additive and its use to make fire-resistant glass laminates with impact resistance.
B32B 17/10 - Layered products essentially comprising sheet glass, or fibres of glass, slag or the like comprising glass as the main or only constituent of a layer, next to another layer of a specific substance of synthetic resin
C08L 33/16 - Homopolymers or copolymers of esters containing halogen atoms
The invention relates to a graft copolymer latex comprising the which comprises a graft copolymer ABC of at least one olefinically unsaturated monomer C and at least one modified alkyd resin A2B or modified oil A1B which modified alkyd resin A2B or modified oil A1B have chain-pendant olefinically unsaturated groups, to a process for its preparation, and the use thereof a binder in coating compositions.
C08F 290/08 - Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
C09D 151/08 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C08G 18/36 - Hydroxylated esters of higher fatty acids
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
The present invention provides for an ethylenically unsaturated hydroxyl-terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (B2); (iii) optionally, at least one ethylenically unsaturated compound (C) containing essentially one reactive group capable of reacting with isocyanate groups; and with (iv) at least one polyisocyanate (D). The present invention further relates to radiation curable coating compositions comprising same, to their preparation process and their uses.
C08G 18/67 - Unsaturated compounds having active hydrogen
C09D 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
The present invention relates to a (meth)acrylated compound (A) prepared from: (i) a polyol constituent, (ii) a polyacid constituent and (iii) one or more (meth)acrylating compounds, wherein the polyol constituent comprises at least 30 % by weight of one or more cyclic ether polyols, relative to the total weight of the polyol constituent, and wherein the compound (A) optionally further contains one or more moieties selected from the group consisting of (poly)caprolactone-containing moieties (ai), (poly)lactide- and/or (poly)glycolide-containing moieties (aii), moieties providing epoxide groups (aiii) and moieties providing alkylene oxide groups containing from 2 to 4 carbon atoms (aiv). The compounds of the invention are in particular suited for the making of radiation curable coating compositions and inks less prone to migration.
C08G 63/199 - Acids or hydroxy compounds containing cycloaliphatic rings
C08G 63/47 - Polyesters chemically modified by esterification by unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
C08G 63/672 - Dicarboxylic acids and dihydroxy compounds
C09D 167/00 - Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
The present invention relates to (meth)acrylated compounds (A) prepared from (a) at least one cyclic ether polyol, (b) at least one linking compound (b1) and/or (b2), wherein the linking compound (b1) is selected from cyclic compounds (b11) containing at least one (I) group in the cycle where X = O or NH, from hydroxy acids (b12) and/or from alkylene oxides (b13) containing from 2 to 4 carbon atoms and the linking compound (b2) is selected from epihalohydrins or polyisocyanates, (c) a (meth)acrylating compound; and to their use in radiation curable compositions for the coatings, inks, overprint varnishes, adhesives and composites.
The present invention relates to an aqueous radiation curable composition comprising: (I) at least one ethylenically unsaturated compound (A), and (II) at least one emulsifier (B) comprising alternating polyalkylene oxide segments, wherein said emulsifier optionally bears one or more groups selected from alkyl groups, aryl groups hydroxyl groups and/or ethylenically unsaturated groups, and wherein said emulsifier (B) has an HLB value of at least 4.5, preferably at least 7. The compositions of the invention are particularly suited for the manufacture of sprayable eco-friendly hardcoats, but they are also suitable for the making of inks, overprint varnishes and adhesives, alone or in combination with e.g. a water-borne polymer dispersion.
A compound obtained by reaction of one or more amines of the general formula NHR6R7 with a compound of the following general formula (IX), wherein - PI is a photoinitiator derivative, - G is linker comprising a number p' of unreacted hydroxyl groups, - M is a group comprising a number z of (meth)acrylate groups equal to at least one, as well as inks, coating compositions and adhesives comprising the same.
C07C 229/12 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of acyclic carbon skeletons
C07C 69/76 - Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a six-membered aromatic ring
C09D 133/04 - Homopolymers or copolymers of esters
C09D 11/10 - Printing inks based on artificial resins
A compound obtained by reaction of one or more amines of general formula NHR6R7 with a benzophenone derivative of the following general formula (IX) wherein M is a group comprising a number z of (meth)acrylate groups equal to at least L is a linker, G is linker comprising a number p' of unreacted hydroxyl groups, and R, R' ' and R' ' ' are optional substituents as well as inks, coating compositions and adhesives comprising the same.
C09D 133/04 - Homopolymers or copolymers of esters
C09D 11/10 - Printing inks based on artificial resins
C07C 69/76 - Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a six-membered aromatic ring
C07C 229/12 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of acyclic carbon skeletons
The present invention relates to a radiation curable aqueous composition comprising at least one ethylenically unsaturated polymer (1) which is the reaction product of—a water-dispersible (meth)acrylic polymer A containing pendant hydroxyl or isocyanate groups, and containing pendant groups capable to render the polymer dispersible in aqueous medium either directly or after reaction with a neutralizing agent; —at least one ethylenically unsaturated compound B which can be radically polymerized under irradiation and which attaches to the (meth)acrylic polymer A by an urethane linkage; —and, optionally, at least one neutralizing agent C. The present invention further relates to the making and use of such radiation curable aqueous compositions.
C08L 33/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
C08G 18/62 - Polymers of compounds having carbon-to-carbon double bonds
C08G 18/67 - Unsaturated compounds having active hydrogen
C08G 18/70 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
C08G 18/73 - Polyisocyanates or polyisothiocyanates acyclic
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
The present invention relates to an active energy ray curable compound (A) comprising: at least one (poly)lactone-containing moiety (a1), at least one fluorine-containing moiety (a3), and at least one further moiety (a2) present between moieties (a1 ) and (a3). The invention further relates to ways of making such compounds and to their use in providing water-oil repellency properties to a coating composition.
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/50 - Polyethers having hetero atoms other than oxygen
C08G 18/67 - Unsaturated compounds having active hydrogen
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
C08G 18/28 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
The present invention relates to an active energy ray curable compound (A) comprising: at least one active energy ray curable group, at least one fluorine-containing moiety (a1) and at least one moiety (a2) comprising at least one portion represented by Formula (1): -[C(=O)-CH(R)-O-C(=O)-CH(R)-O]n- wherein n is an integer from 1 to 10, and wherein R is selected from -H or -CH3. The invention further relates to ways of making such compounds and to their use in providing water-oil repellency properties to a coating composition.
The present invention relates toan aqueous radiation curable coating composition comprising at least one radiation curable polymer (A) and at least one organic matting polymer (B) providing uniform matt coatings.
The invention relates to mixtures of at least one acrylic resin dispersion A and a second dispersion B which is at least one of a polyurethane dispersion B1 which comprises, in its polymer, moieties derived from grafted fatty acids, and a mixture B2 of a polyurethane dispersion B21 and an aqueously dispersed alkyd resin B22, and to a method of use thereof for coating of porous substrates.
C08G 18/36 - Hydroxylated esters of higher fatty acids
C08L 33/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
C08L 75/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
The invention relates to mixtures of at least one acrylic resin dispersion A and a second dispersion B which is at least one of a polyurethane dispersion B1 which comprises, in its polymer, moieties derived from grafted fatty acids, and a mixture B2 of a polyurethane dispersion B21 and an aqueously dispersed alkyd resin B22, and to a method of use thereof for coating of porous substrates.
C09D 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C08L 75/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C08L 33/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
The present invention relates to a process for the preparation of a radiation curable composition comprising at least one (meth)acrylic copolymer A and at least one radiation curable compound B, said process comprising a first copolymerization step, and a subsequent ring opening step.
C08F 265/06 - Polymerisation of acrylate or methacrylate esters on to polymers thereof
C09J 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
C09J 151/00 - Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
An aqueous dispersion comprising a mixture of a first dispersion and a second dispersion, said first dispersion comprising at least one (meth)acrylated pre-polymer (A), and said second dispersion comprising at least one thiol-functional compound (B), said aqueous dispersion optionally comprising at least one ethylenically unsaturated compound (C).
This invention relates to a radiation curable aqueous coating composition comprising: —from 1 to 99% by weight, relative to the total weight of (1) and (2), of at least one radiation curable aqueously dispersed polyester resin composition (1) comprising an emulsifier D and the reaction product AC of a hydroxy functional polyester resin A and an olefinically unsaturated compound C which can be radically polymerized and which is attached to the polyester resin backbone by an ester linkage or a urethane linkage, and—from 1 to 99% by weight, relative to the total weight of (1) and (2), of at least one other olefinically unsaturated compound (2) selected from the group of: water-dispersible compounds (21); water-soluble compounds (22); and/or water-compatible compounds (23) that have a weight average molecular weight of at least 450 Dalton and are different from the reaction product AC.
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C08G 18/81 - Unsaturated isocyanates or isothiocyanates
C08G 63/47 - Polyesters chemically modified by esterification by unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
C09D 133/14 - Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
C09D 135/00 - Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at lea; Coating compositions based on derivatives of such polymers
C09D 167/07 - Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
C09D 175/14 - Polyurethanes having carbon-to-carbon unsaturated bonds
C09J 167/07 - Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
