1,4-CINEOLE DERIVATIVE AND INTERMEDIATE THEREOF, HERBICIDE CONTAINING SAID DERIVATIVE AS ACTIVE INGREDIENT, METHOD FOR USING HERBICIDE, AND METHOD FOR PREPARING AGROCHEMICAL COMPOSITION
The present invention provides: a 1,4-cineole derivative which is represented by general formula (1), (1'), (2), (2'), (3), or (3') and exhibits excellent herbicidal activity; an intermediate thereof; and a herbicide and the like, which is characterized by containing the derivative as an active ingredient. In general formulae (1), (1'), (2), (2'), (3), and (3'), R1to R3, X, and W each represent a predetermineed substituent set forth in the description.
A01N 43/90 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
BICYCLIC PYRIDINE DERIVATIVE AND SALT THEREOF, AND HARMFUL ORGANISM CONTROL AGENT CHARACTERIZED BY CONTAINING SAID DERIVATIVE OR SALT THEREOF AS ACTIVE INGREDIENT
The present invention provides: a bicyclic pyridine derivative represented by general formula (1) or a salt thereof; and an agricultural/horticultural chemical agent, a pesticide, and others each containing the bicyclic pyridine derivative or a salt thereof as an active ingredient. In the general formula (1), R1, R2, Z and A1to A3 each independently represent a specific substituent; and n represents 0 or 1.
A01N 43/90 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
1,4-CINEOLE DERIVATIVE AND INTERMEDIATE THEREOF, HERBICIDE CONTAINING SAME AS ACTIVE INGREDIENT, METHOD FOR USING HERBICIDE, AND METHOD FOR PREPARING AGROCHEMICAL COMPOSITION
The present invention provides a 1,4-cineole derivative represented by general formula (1), (1'), (2) or (2') that exhibits excellent herbicidal activity, an intermediate thereof, a herbicide characterized by containing the derivative as an active ingredient, etc. In general formulae (1), (1'), (2) and (2'), R1to R3 and X each represent a specific substituent.
A01N 43/90 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
A01N 47/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
A01N 47/06 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groupsThio-analogues thereof
A01N 47/34 - Ureas or thioureas containing the groups N—CO—N or N—CS—N containing the groups , e.g. biuretThio-analogues thereofUrea-aldehyde condensation products
The present invention provides: a 6-(fluoroalkyl)-3,4-dihydro-2H-pyran-5-carboxylic acid ester derivative represented by a specific formula (3); a method for producing the same; a method for producing a 2-(fluoroalkyl) nicotinic acid derivative which is represented by a specific formula (5), and is characterized in that the 6-(fluoroalkyl)-3,4-dihydro-2H-pyran-5-carboxylic acid ester derivative is reacted with an ammonium compound or ammonia, or is reacted with a base, an ammonium compound or ammonia, or after treating with acid or Lewis acid, is reacted with an ammonium compound or ammonia; and a method for producing an intermediate of the 2-(fluoroalkyl)nicotinic acid derivative.
1-(n,n-disubstituted carbamoyl) 4-(substituted sulfonyl)triazolin-5-one derivative, 4-(n,n-disubstituted carbamoyl) 1-(substituted sulfonyl)triazolin-5-one derivative, and herbicide containing said derivative as active ingredient
The present invention provides a 1-(N,N-disubstituted carbamoyl)4-(substituted sulfonyl)triazolin-5-one derivative represented by the following formula (1), a 4-(N,N-disubstituted carbamoyl)1-(substituted sulfonyl)triazolin-5-one derivative represented by the following formula (11), each of which exhibits an excellent herbicidal activity, and a herbicide characterized by containing the derivative as an active ingredient:
14 represent predetermined substituents.
An isoxazolin-5-one derivative represented by the following (1):
4 and X each represents a certain substituent or the like; and n represents an integer of 1 to 4, wherein X's may be different from each other when n represents an integer of 2 to 4, and an herbicide containing the isoxazolin-5-one derivative as an active ingredient are provided.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
The present invention addresses the problem of providing: a thermosetting resin-based composition having good curability; and a thermosetting resin-based cured product having good adhesion and heat resistance. To solve the problem, an onium salt represented by general formula (2'-2) and comprising an onium cation and an anion residue of at least one phenol derivative selected from the group consisting of phenol derivatives; a curing accelerator containing the onium salt; a thermosetting resin-based composition containing the onium salt; and a thermosetting resin-based cured product are provided.
C07C 39/15 - Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings
C08G 59/68 - Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups characterised by the catalysts used
The present invention addresses the problem of providing a water surface-floating agrochemical preparation which exhibits good floating properties and diffusion properties in a flooding treatment under shallow water conditions, and with which this performance is maintained even after long term storage. This problem is solved by providing a water surface-floating agrochemical preparation which is characterized: by containing (a) an agrochemical active ingredient, (b) a floating carrier, and (c) at least one type selected from sodium alkylnaphthalene sulfonates and sodium dialkylsuccinate sulfonates; in that (d) the long axis/short axis ratio of the bottom surface of a particle is 1.1-1.4; (e) 80 wt% or more of particles have particle sizes within the range 2.80-1.70 mm; and (f) the number of particles per 1g is 50-150.
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
A01N 25/08 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
A01N 25/30 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
A01N 43/12 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atom with one hetero atom five-membered rings condensed with a carbocyclic ring
A01N 43/16 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atom with one hetero atom six-membered rings with oxygen as the ring hetero atom
A01N 43/38 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
A01N 43/70 - Diamino-1,3,5-triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
A01N 43/707 - 1,2,3- or 1,2,4-TriazinesHydrogenated 1,2,3- or 1,2,4-triazines
Provided are: an isoxazolin-5-one derivative represented by general formula (1); and a herbicide containing the isoxazolin-5-one derivative as an active ingredient. In the formula, R1represents a C1-C6 haloalkyl group; Q represents a C3-C8 cycloalkyl group substituted by a C1-C6 alkoxy group; R2, R3 and X independently represent a specific substituent or the like; n represents an integer of 1 to 4; and X's may be different from each other when n is an integer of 2 to 4.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The present invention provides a 1,2,3-triazole derivative and an insecticide or acaricide containing the 1,2,3-triazole derivative as an active ingredient.
C07D 249/06 - 1,2,3-TriazolesHydrogenated 1,2,3-triazoles with aryl radicals directly attached to ring atoms
A01N 43/82 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with three hetero atoms
A61K 31/4439 - Non-condensed pyridinesHydrogenated derivatives thereof containing further heterocyclic ring systems containing a five-membered ring with nitrogen as a ring hetero atom, e.g. omeprazole
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 401/14 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
C07D 403/10 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 413/10 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
11.
IMIDE DERIVATIVE AND BACTERICIDE CONTAINING SAME AS ACTIVE INGREDIENT
The present invention provides: an imide derivative which is represented by general formula (1) wherein R1 is substituted by a substituent such as an isothiazolyl group, Q is substituted by a substituent such as a thiophenyl group, or A is substituted by a substituent such as a pyrazolyl group; and a bactericide for agricultural and horticultural use, which is characterized by containing this imide derivative as an active ingredient, and which exhibits excellent bactericidal effects in agricultural and horticultural fields.
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Organic magnesium phosphide and manufacturing method thereof, organic magnesium phosphide complex and manufacturing method thereof, and manufacturing method of organic phosphorus compound using said phosphide
An organic magnesium phosphide expressed by Formula (1) below and an organic magnesium phosphide complex expressed by Formula (9) below are provided, and a manufacturing method of organic phosphorus compound is characterized in that the above compounds used as a reagent is reacted with an electrophile:
2 are each independently an aliphatic group, heteroaliphatic group, alicyclic group, or heterocyclic group, and X is chlorine, bromine, or iodine,
4 are each independently an aliphatic group, heteroaliphatic group, aromatic group, alicyclic group, or heterocyclic group, and X and Y are each independently chlorine, bromine, or iodine.
Provided are a water-soluble triarylphosphine for a palladium catalyst, which has high selectivity in a telomerization reaction and is easily recovered with efficiency, an ammonium salt thereof, and a method for efficiently producing the same. Specifically, provided are bis(6-methyl-3-sulphophenyl)(2-methylphenyl)phosphine; a bis(6-methyl-3-sulphonatophenyl)(2-methylphenyl)phosphine diammonium salt obtained by reacting the phosphine with a tertiary amine having a total of 3 to 27 carbon atoms in groups bonded to one nitrogen atom; and a method for producing the same.
C07C 29/36 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy groups, e.g. O-metal
C07C 211/07 - Monoamines containing one, two or three alkyl groups, each having the same number of carbon atoms in excess of three
C07C 211/08 - Monoamines containing alkyl groups having a different number of carbon atoms
B01J 31/02 - Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
14.
1-(N,N-DISUBSTITUTED CARBAMOYL) 4-(SUBSTITUTED SULFONYL)TRIAZOLIN-5-ONE DERIVATIVES, 4-(N,N-DISUBSTITUTED CARBAMOYL) 1-(SUBSTITUTED SULFONYL)TRIAZOLIN-5-ONE DERIVATIVES, AND HERBICIDE CONTAINING SAME AS ACTIVE INGREDIENT
The present invention provides 1-(N,N-disubstituted carbamoyl) 4-(substituted sulfonyl)triazolin-5-one derivatives represented by general formula 1 and 4-(N,N-disubstituted carbamoyl) 1-(substituted sulfonyl)triazolin-5-one derivatives represented by general formula (11) which show excellent herbicidal activity, and herbicides characterized by containing the derivatives as an active ingredient. In general formula (1), R1-R4represent predetermined substituents. In general formula (11), R11-R14 represent predetermined substituents.
A01N 47/38 - Ureas or thioureas containing the groups N—CO—N or N—CS—N containing the group N—CO—N where at least one nitrogen atom is part of a heterocyclic ringThio-analogues thereof
C07D 401/06 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
15.
ISOXAZOLIN-5-ONE DERIVATIVE AND HERBICIDE CONTAINING SAME AS ACTIVE INGREDIENT
Provided are: an isoxazolin-5-one derivative represented by general formula (1); and a herbicide which contains the isoxazolin-5-one derivative as an active ingredient. In general formula (1), R1 represents a C1-C6 haloalkyl group; R2-R4 and X represent specific substituents or the like, respectively; n represents an integer of 1-4; and in cases where n represents an integer of 2-4, the X moieties may be different from each other.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
C07D 413/06 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
16.
Bis(6-methyl-3-sulphophenyl)phenylphosphine, ammonium salt thereof, and method for producing same
Provided are a water-soluble triarylphosphine for a palladium catalyst, which has high selectivity in a telomerization reaction and can be recovered with efficiency, an ammonium salt thereof, and a method for efficiently producing the same. Specifically, provided are bis(6-methyl-3-sulphophenyl)phenylphosphine; a bis(6-methyl-3-sulphonatopheyl)phenylphosphine diammonium salt obtained by reacting the phosphine with a tertiary amine having a total of 3 to 27 carbon atoms in groups bonded to one nitrogen atom; and a method for producing the same.
C07C 29/36 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy groups, e.g. O-metal
A heat-curable resin composition characterized by comprising (A) a heat-curable resin, (B) a curing agent and (C) a curing accelerator that is a phosphonium salt composed of two molecules of a phosphonium cation represented by general formula (1) and one molecule of a bivalent anion residue of pyromellitic acid represented by formula (2). The heat-curable resin composition potentially has a property such that the curing accelerator has a poor catalytic activity at a lower temperature and therefore cannot cure the heat-curable resin composition at the lower temperature but exhibits a high catalytic activity at an intended curing temperature and therefore can cure the heat-curable resin composition within a short time at the intended curing temperature. The heat-curable resin composition has excellent storage stability in the form of a one-part preparation, and is colorless and transparent when the curing agent is an acid anhydride.
C08G 59/68 - Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups characterised by the catalysts used
C08J 3/22 - Compounding polymers with additives, e.g. colouring using masterbatch techniques
18.
ORGANIC MAGNESIUM PHOSPHIDE AND MANUFACTURING METHOD THEREOF, ORGANIC MAGNESIUM PHOSPHIDE COMPLEX AND MANUFACTURING METHOD THEREOF, AND MANUFACTURING METHOD OF ORGANIC PHOSPHORUS COMPOUND USING SAID PHOSPHIDE
Organic phosphorus compounds are used in wide-ranging applications such as ligands in transition metal catalysts and hardening accelerators for epoxy resins. An object of the invention is to provide a new organic magnesium phosphide characterized by a phosphorus-magnesium bond expressed by Formula (1), an organic magnesium phosphide complex, and methods for their production. The organic magnesium phosphide complex according to the invention can be prepared much more efficiently, and a reaction liquid with the magnesium phosphide complex can be manipulated easily.
ORGANIC MAGNESIUM PHOSPHIDE AND METHOD FOR PRODUCING SAME, ORGANIC MAGNESIUM PHOSPHIDE COMPLEX AND METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING ORGANIC PHOSPHORUS-CONTAINING COMPOUND USING SAID PHOSPHIDE
The present invention addresses the problem of providing: a novel organic magnesium phosphide characterized by having a phosphorus-magnesium bond and a method for producing the organic magnesium phosphide; and a novel organic magnesium phosphide complex and a method for producing the organic magnesium phosphide complex. The present invention also addresses the problem of providing a novel method for producing an organic phosphorus-containing compound using the organic magnesium phosphide or the organic magnesium phosphide complex. As a solution, an organic magnesium phosphide represented by formula (1) and an organic magnesium phosphide complex represented by formula (9) are provided. Also provided is a method for producing an organic phosphorus-containing compound, characterized by reacting any one of the reagents with an electrophile. (In the formula, R1 and R2 independently represent an aliphatic group, a heteroaliphatic group, an alicyclic group or a heterocyclic group; and X represents a chlorine atom, a bromine atom or a iodine atom.) (In the formula, R3 and R4 independently represent an aliphatic group, a heteroaliphatic group, an aromatic group, an alicyclic group or a heterocyclic group; and X and Y independently represent a chlorine atom, a bromine atom or a iodine atom.)
The present invention provides a 1,2,3-triazole derivative represented by general formula (1) and an insecticide/acaricide having a 1,2,3-triazole derivative as an active ingredient. In general formula (1), R represents a C1-C6 alkyl group or a C1-C6 haloalkyl group, n represents an integer of 0-2, Ｗ１ and Ｗ２ each independently represent CH or a nitrogen atom, X, Q, and Z each represent a predetermined substituent or the like, m represents an integer of 1-4, and when m is an integer of 2 or higher, each X may be the same or different.
A61K 31/4439 - Non-condensed pyridinesHydrogenated derivatives thereof containing further heterocyclic ring systems containing a five-membered ring with nitrogen as a ring hetero atom, e.g. omeprazole
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
21.
Reaction catalyst for cross-coupling and method for manufacturing aromatic compound
The object of the present invention is to provide a new organic phosphorus ligand that can efficiently promote cross-coupling reaction to obtain the target substance at high yield, as well as a method of manufacturing such ligand whose steric characteristics and electronic characteristics can be fine-tuned and which can be used to cause cross-coupling reaction at high yield. As a means for achieving the aforementioned object, a phosphine compound expressed by General Formula (1) below is provided.
4 are not both hydrogen at the same time).
C07C 209/10 - Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
C07D 295/02 - Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
C07C 1/32 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero atoms other than, or in addition to, oxygen or halogen
C07C 41/30 - Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
C07C 253/30 - Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
C07D 295/033 - Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring with the ring nitrogen atoms directly attached to carbocyclic rings
22.
SUBSTITUTED PHENYL ETHER COMPOUND AND PEST CONTROL AGENT
The purpose of the present invention is to provide: a novel substituted phenyl ether compound which has a control effect against pests; and a pest control agent which contains this substituted phenyl ether compound as an active ingredient. A substituted phenyl ether compound represented by formula (1) is provided as a solution.
C07C 317/22 - SulfonesSulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
A01N 31/08 - Oxygen or sulfur directly attached to an aromatic ring system
C07C 215/68 - Compounds containing amino and hydroxy groups bound to the same carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings and hydroxy groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton
C07C 229/42 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino groups bound to carbon atoms of at least one six-membered aromatic ring and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton with carboxyl groups linked to the six-membered aromatic ring, or to the condensed ring system containing that ring, by saturated carbon chains
C07C 271/28 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
C07C 309/65 - Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
C07C 309/73 - Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
C07C 323/20 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton with singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
23.
BIS(6-METHYL-3-SULPHOPHENYL)(2-METHYLPHENYL)PHOSPHINE, AMMONIUM SALT THEREOF, AND METHOD FOR PRODUCING SAME
Provided are: a water-soluble triaryl phosphine for a palladium catalyst that can be easily recovered in an efficient manner and that has high selectivity in telomerization reactions; an ammonium salt thereof; and a method for efficiently producing same. Specifically, provided are: bis(6-methyl-3-sulphophenyl)(2-methylphenyl)phosphine; diammonium bis(6-methyl-3-sulphophenyl)(2-methylphenyl)phosphinate obtained by reacting the phosphine with a ternary amine having 3-27 carbon atoms in a group bonded to one nitrogen atom; and a method for producing same.
C07C 209/68 - Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
Provided are: a water-soluble triaryl phosphine for a palladium catalyst that can be efficiently and easily recovered and that has high selectivity in a telomerization reaction; an ammonium salt thereof; and a method for efficiently producing same. Specifically, provided are: bis(6-methyl-3-sulphophenyl)phenylphosphine; diammonium bis(6-methyl-3-sulphophenyl)phenylphosphinate obtained by reacting the phosphine with a ternary amine having 3-27 carbon atoms in a group bonded to one nitrogen atom; and a method for producing same.
C07C 209/68 - Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
Provided are: a water-soluble triaryl phosphine for a palladium catalyst that can be easily recovered in an efficient manner and that has high selectivity in telomerization reactions; an ammonium salt thereof; and a method for efficiently producing same. Specifically, provided are: bis(6-methyl-3-sulphophenyl)(2-methylphenyl)phosphine; diammonium bis(6-methyl-3-sulphophenyl)(2-methylphenyl)phosphinate obtained by reacting the phosphine with a ternary amine having 3-27 carbon atoms in a group bonded to one nitrogen atom; and a method for producing same.
C07C 209/68 - Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
Provided are: a water-soluble triaryl phosphine for a palladium catalyst that can be efficiently and easily recovered and that has high selectivity in a telomerization reaction; an ammonium salt thereof; and a method for efficiently producing same. Specifically, provided are: bis(6-methyl-3-sulphophenyl)phenylphosphine; diammonium bis(6-methyl-3-sulphophenyl)phenylphosphinate obtained by reacting the phosphine with a ternary amine having 3-27 carbon atoms in a group bonded to one nitrogen atom; and a method for producing same.
C07C 209/68 - Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
The purpose of the present invention is to provide new organic phosphorus-based ligands that can efficiently perform a cross coupling reaction to obtain a target substance with high yield; and also to provide a manufacturing method that can finely adjust the steric properties and electrical properties, and can perform a cross coupling reaction with high-efficiency using these ligands. A phosphine compound expressed by general formula (1) is provided as resolution means. (In the formula, R1 and R2 each independently represent a secondary alkyl group, tertiary alkyl group, or cycloalkyl group; and R3 and R4 each independently represent a hydrogen, aliphatic group, heteroaliphatic group, aromatic group, alicyclic group, or heterocyclic group. Note that R3 and R4 do not contain a phosphorus atom, and R3 and R4 are not both simultaneously hydrogen.)
C07C 1/32 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero atoms other than, or in addition to, oxygen or halogen
C07C 15/14 - Polycyclic non-condensed hydrocarbons all phenyl groups being directly linked
C07C 209/10 - Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
C07C 211/54 - Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
C07C 211/56 - Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
C07D 295/02 - Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
The purpose of the present invention is to provide new organic phosphorus-based ligands that can efficiently perform a cross coupling reaction to obtain a target substance with high yield; and also to provide a manufacturing method that can finely adjust the steric properties and electrical properties, and can perform a cross coupling reaction with high-efficiency using these ligands. A phosphine compound expressed by general formula (1) is provided as resolution means. (In the formula, R1 and R2 each independently represent a secondary alkyl group, tertiary alkyl group, or cycloalkyl group; and R3 and R4 each independently represent a hydrogen, aliphatic group, heteroaliphatic group, aromatic group, alicyclic group, or heterocyclic group. Note that R3 and R4 do not contain a phosphorus atom, and R3 and R4 are not both simultaneously hydrogen.)
C07C 1/32 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero atoms other than, or in addition to, oxygen or halogen
C07C 15/14 - Polycyclic non-condensed hydrocarbons all phenyl groups being directly linked
C07C 209/10 - Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
C07C 211/54 - Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
C07C 211/56 - Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
C07D 295/02 - Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
A vaccine composition for prophylaxis and/or therapy of Alzheimer's disease, which comprises a fusion protein prepared by inserting a single or tandemly repeated multiple copies of amyloid β antigenic peptide having 5 to 15 continuous amino acid residues derived from the N-terminus of amyloid β peptide into a wild type seed storage protein.
C12N 15/62 - DNA sequences coding for fusion proteins
C12N 15/82 - Vectors or expression systems specially adapted for eukaryotic hosts for plant cells
A61P 25/28 - Drugs for disorders of the nervous system for treating neurodegenerative disorders of the central nervous system, e.g. nootropic agents, cognition enhancers, drugs for treating Alzheimer's disease or other forms of dementia
C12N 15/29 - Genes encoding plant proteins, e.g. thaumatin
A61K 39/00 - Medicinal preparations containing antigens or antibodies
C07K 14/415 - Peptides having more than 20 amino acidsGastrinsSomatostatinsMelanotropinsDerivatives thereof from plants
C07K 14/47 - Peptides having more than 20 amino acidsGastrinsSomatostatinsMelanotropinsDerivatives thereof from animalsPeptides having more than 20 amino acidsGastrinsSomatostatinsMelanotropinsDerivatives thereof from humans from vertebrates from mammals
30.
Transformed soybean plant which accumulates vaccine, and use thereof
A transformed soybean plant having a gene encoding a modified seed storage protein introduced therein, obtained by inserting a gene encoding an Alzheimer's disease vaccine to a variable region(s) of a gene encoding a wild-type seed storage protein, is produced, and said vaccine is produced and accumulated in the seeds thereof.
A61P 25/28 - Drugs for disorders of the nervous system for treating neurodegenerative disorders of the central nervous system, e.g. nootropic agents, cognition enhancers, drugs for treating Alzheimer's disease or other forms of dementia
C12N 15/82 - Vectors or expression systems specially adapted for eukaryotic hosts for plant cells
National Institute of Advanced Industrial Science and Technology (Japan)
Inventor
Terakawa, Teruhiko
Yamamura, Tomomichi
Sugiyama, Masao
Takagi, Masaru
Mitsuda, Nobutaka
Abstract
A process for producing a multi-petaled cyclamen plant having an increased number of petals, comprising at least a step of inhibiting the function of a transcriptional factor involved in the formation of flower organs in a cyclamen plant.
A palladium-containing perovskite-type composite oxide represented by general formula (1) is used as a synthesis reaction catalyst in a Suzuki coupling reaction: Ln2MyCu1-x-yPdxO4±δ (1) wherein Ln represents elements comprising at least one essential element selected from La, Pr, Nd, Sm, Eu, and Gd and at least one optional element selected from Y, Ce, Yb, Ca, Sr, and Ba; M represents at least one element selected from Cr, Mn, Fe, Co, Ni, and Al; x, indicating atomic proportion, is 0.001≤x≤0.4; y, indicating atomic proportion, is 0≤y≤0.5; and δ indicates an oxygen excess or oxygen deficiency.
C07C 41/30 - Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
B01J 23/89 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with noble metals
C07C 43/205 - Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring the aromatic ring being a non-condensed ring
01 - Chemical and biological materials for industrial, scientific and agricultural use
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Chemical products used in industry, science, agriculture, horticulture, forestry. Antibiotics, Fungicides, Herbicides, Insecticides, Acaricides, Miticides for agricultural and horticultural use, preparations for killing weeds and destroying vermin and microorganisms.
35.
TRANSFORMED SOYBEAN PLANT WHICH STORES VACCINE, AND USE THEREOF
A transformed soybean plant, in which is introduced a gene which codes for a modified seed storage protein—for which a gene which codes for an Alzheimer's disease vaccine is inserted into a variable region of a gene which codes for a wild-type seed storage protein—is manufactured, and said vaccine is produced and stored in the seeds thereof.
C12N 15/00 - Mutation or genetic engineeringDNA or RNA concerning genetic engineering, vectors, e.g. plasmids, or their isolation, preparation or purificationUse of hosts therefor
A01H 5/00 - Angiosperms, i.e. flowering plants, characterised by their plant partsAngiosperms characterised otherwise than by their botanic taxonomy
A61K 39/00 - Medicinal preparations containing antigens or antibodies
A61P 25/28 - Drugs for disorders of the nervous system for treating neurodegenerative disorders of the central nervous system, e.g. nootropic agents, cognition enhancers, drugs for treating Alzheimer's disease or other forms of dementia
C12N 5/10 - Cells modified by introduction of foreign genetic material, e.g. virus-transformed cells
A transformed soybean plant having a gene encoding a modified seed storage protein introduced therein, obtained by inserting a gene encoding an Alzheimer's disease vaccine to a variable region(s) of a gene encoding a wild-type seed storage protein, is produced, and said vaccine is produced and accumulated in the seeds thereof.
A61K 39/00 - Medicinal preparations containing antigens or antibodies
A61P 25/28 - Drugs for disorders of the nervous system for treating neurodegenerative disorders of the central nervous system, e.g. nootropic agents, cognition enhancers, drugs for treating Alzheimer's disease or other forms of dementia
C12N 5/10 - Cells modified by introduction of foreign genetic material, e.g. virus-transformed cells
C12N 15/00 - Mutation or genetic engineeringDNA or RNA concerning genetic engineering, vectors, e.g. plasmids, or their isolation, preparation or purificationUse of hosts therefor
01 - Chemical and biological materials for industrial, scientific and agricultural use
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
(1) Pharmaceutical preparations for use in agriculture, namely agrochemicals and antibiotics for agricultural use; insecticides, fungicides, herbicides.
(2) Pharmaceutical preparations for use in agriculture, namely agrochemicals for agricultural use; fungicides.
38.
PROCESS FOR PRODUCTION OF PHOSPHINE DERIVATIVE FROM PHOSPHINE OXIDE DERIVATIVE
National University Corporation Okayama University (Japan)
Asahi Kasei Chemicals Corporation (Japan)
HOKKO CHEMICAL INDUSTRY CO., LTD. (Japan)
Inventor
Tanaka, Hideo
Kuroboshi, Manabu
Yano, Tomotake
Hoshino, Masakatsu
Kawakubo, Hiromu
Abstract
Disclosed is a process for producing a phosphine derivative from a phosphine oxide derivative, which comprises the following steps: (I) mixing a phosphine oxide derivative represented by formula (1) with a chlorinating agent in a polar organic solvent to cause the reaction between these components; and (II-1) adding a salt of a metal having an ionization tendency equal to or lower than that of aluminum to the reaction mixture and carrying out the reductive reaction in the presence of aluminum or (II-2) subjecting the reaction mixture to electrolytic reduction, thereby producing a phosphine derivative represented by formula (2). ArnR3-nP=O (1) ArnR3-nP (2) In formulae (1) and (2), Ar represents an aryl group such as a phenyl group, a phenyl group having a substituent, a heteroaromatic ring group, and a heteroaromatic ring group having a substituent; R represents an aliphatic hydrocarbon group or an aliphatic hydrocarbon group having a substituent; and n represents an integer of 0 to 3.
Disclosed is a novel phenyltriazolinone production process which enables to produce a highly pure phenyltriazolinone in high yield in an simpler and safer manner and at a lower cost by using a more inexpensive raw material. Specifically disclosed is a process for producing a phenyltriazolinone, which comprises the steps of: reacting an aniline with a nitrite salt to produce a diazonium salt; reducing the diazonium salt with a sulfite salt or a bisulfite salt; hydrolyzing the reduced product to produce a phenylhydrazine; reacting the phenylhydrazine with formaldehyde in the presence of a catalyst at pH 5-10 to produce a formaldehyde-phenylhydrazone; reacting the formaldehyde-phenylhydrazone (3) with cyanic acid to produce a phenyltriazolidinone; and reacting the phenyltriazolidinone (4) with an oxidizing agent selected from a hypohalous acid salt and oxygen in the absence of any catalyst or in the presence of an oxidation catalyst.
NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY (Japan)
HOKKO CHEMICAL INDUSTRY CO., LTD. (Japan)
Inventor
Ono, Michiyuki
Terakawa, Teruhiko
Takagi, Masaru
Abstract
A plant with modified flower morphology is produced by suppressing the function of a transcription factor related to the polarity determination of the plant. More particularly, a plant with modified flower morphology is produced through the steps of: obtaining a transformed cell by introducing into a plant cell a chimeric DNA obtained by fusing a DNA encoding a transcription factor related to the polarity determination to a DNA encoding a functional peptide for converting a transcription factor into a transcription suppressor; and regenerating a transgenic plant from the transformed cell.
Disclosed is a method for producing (1,3,5/2,4,6)-1-fluoro-2,3,4,5,6-cyclohexanepentol, which comprises a step (A) for producing a compound represented by the general formula (II) below by reacting a compound represented by the general formula (I) below with a reagent containing an F ion and a step (B) for removing a protecting group from the compound of the general formula (II). (In the formula (I), R1 represents a protecting group of a hydroxy group, and R2 represents a leaving group.) (In the formula (II), R1 represents a protecting group.)
C07C 29/10 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
C07C 29/62 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by introduction of halogenPreparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by substitution of halogen atoms by other halogen atoms
C07C 29/76 - SeparationPurificationStabilisationUse of additives by physical treatment
Disclosed is a process for producing an industrially useful alkylthio-substituted benzene derivative by using an aqueous solution of an alkali metal salt of a lower alkanethiol which is available at a low cost. Specifically disclosed is a process for producing an alkylthio-substituted benzene derivative represented by the general formula (6) by reacting a halogenated benzene derivative represented by the general formula (1) with an alkanethiol alkali metal salt represented by the general formula (2). The process comprises: a first reaction step for conducting the reaction by adding an aqueous solution of the alkali metal salt of the lower alkanethiol to a mixed solution of the halogenated benzene derivative, a reaction solvent and an azeotropic solvent (a solvent which can be removed together with water from a reaction system by distillation) which may be the same as the halogenated benzene derivative represented by the formula (1), while distilling a mixture of water and the azeotropic solvent to remove water present in the reaction system continuously so that the water content of the reaction mixture becomes 10 mass% or less; and, optionally, a second reaction step for adding an alkyl halide represented by the general formula (3), an alkyl sulfate ester represented by the general formula (4) or an alkyl carbonate ester represented by the general formula (5) to the reaction system.
C07C 319/14 - Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
C07C 323/09 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton having sulfur atoms of thio groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
C07C 323/20 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton with singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
The invention aims at providing novel 4'-substituted avermectin monoglycoside derivatives which have excellent miticidal, insecticidal or antiparasitic activity and exert excellent control activity against mites or excellent effects against various disease damages caused by animal parasites. The invention provides avermectin monoglycoside derivatives represented by the general formula (I) or salts thereof; and miticides, insecticides or antiparasitics containing the same as the active ingredient: [wherein R1 is isopropyl or sec-butyl; and A is a five- or six-membered or fused ring containing one or more atoms which are selected from the group consisting of oxygen, nitrogen and sulfur and may be the same or different with the provisos that the ring may be unsubstituted or substituted with one or two substituents and that when A is a nitrogen-containing ring, N-oxide may be formed.]
C07H 17/08 - Hetero rings containing eight or more ring members, e.g. erythromycins
A01N 43/90 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
NATIONAL INSTITUTE OF AGROBIOLOGICAL SCIENCES (Japan)
HOKKO CHEMICAL INDUSTRY CO., LTD. (Japan)
TOKYO METROPOLITAN UNIVERSITY (Japan)
Inventor
Koshiba, Tomokazu
Terakawa, Teruhiko
Hasegawa, Hisakazu
Komatsu, Setsuko
Okamoto, Takashi
Furukawa, Toshiko
Shimaya, Kentaroh
Abstract
A plant whose heat tolerance is improved and/or growth is promoted is produced by a step of obtaining a transformed plant cell by introducing a DNA selected from the group consisting of (a) a DNA encoding a protein comprising an amino acid sequence represented by SEQ ID NO: 2, (b) a DNA containing a coding region of a nucleotide sequence represented by SEQ ID NO: 1, (c) a DNA encoding a protein having an amino acid sequence in which one or more amino acids have been substituted, deleted, inserted and/or added in the amino acid sequence represented by SEQ ID NO: 2 and involved in a growth-promoting effect and heat tolerance, (d) a DNA encoding a protein hybridized to a DNA comprising the nucleotide sequence represented by SEQ ID NO: 1 under stringent conditions and involved in a growth-promoting effect and heat tolerance, and (e) a DNA encoding a protein with an amino acid sequence identity of 90% or more to the amino acid sequence represented by SEQ ID NO: 2 and involved in a growth-promoting effect, heat tolerance, dry tolerance and salt tolerance into a plant cell, and a step of regenerating a transgenic plant from the transformed plant cell.
N-Acetyl-D-glucosamine can be produced by cultivating a mold capable of producing N-acetyl-D-glucosamine, such as Trichoderma hamatum strain AB10282 (FERM BP-10623) or Trichoderma harzianum strain AB10283 (FERM BP-10624), in a culture medium supplemented with a carbon source other than chitin and chitin oligosaccharide and a nitrogen source to produce and accumulate N-acetyl-D-glucosamine in the culture medium and then collecting N-acetyl-D-glucosamine from the culture medium.
It is intended to provide a novel NAD+-independent myo-inositol 2-dehydrogenase which converts myo-inositol into scyllo-inosose in the absence of NAD+; a novel enzyme scyllo-inositol dehydrogenase which stereospecifically reduces scyllo-inosose into scyllo-inositol in the presence of NADH or NADPH; and a novel microorganism which belongs to the genus Acetobacter or Burkholderia and can convert myo-inositol into scyllo-inositol. Specifically described is a method for producing a purified scyllo-inositol. The method comprises a first step of forming a scyllo-inositol/boric acid complex by adding boric acid and a metal salt into a liquid mixture containing scyllo-inositol and neutral sugar other than scyllo- inositol in an amount two times or more larger than that of scyllo-inositol dissolved in the liquid mixture, and by adjusting the pH of the liquid mixture to 8.0 to 11.0; a second step of separating the complex from the liquid mixture; a third step of dissolving the separated complex into acid to cleave into scyllo-inositol and boric acid; and a fourth step of isolating and purifying the scyllo-inositol from the acidic solution or acidic suspension obtained from the third step.
It is intended to provide a novel NAD+-independent myo-inositol 2-dehydrogenase which converts myo-inositol into scyllo-inosose in the absence of NAD+; a novel enzyme scyllo-inositol dehydrogenase which stereospecifically reduces scyllo-inosose into scyllo-inositol in the presence of NADH or NADPH; and a novel microorganism which belongs to the genus Acetobacteror Burkholderia and can convert myo-inositol into scyllo-inositol. By using these enzymes or the microorganism, scyllo-inositol is produced. Further, scyllo-inositol is purified by adding boric acid and a metal salt to a liquid mixture containing scyllo-inositol and a neutral saccharide other than scyllo-inositol to form a scyllo-inositol/boric acid complex, separating the complex from the liquid mixture, dissolving the thus separated complex in an acid to give an acidic solution or an acidic suspension and then purifying scyllo-inositol from the acidic solution or the acidic suspension.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
(1) Chemicals, pharmaceuticals, medical treatment accessories, namely: organic compounds used as polymerization promoters and regulators; catalysts; mineral estractants; flame retardants; reagents; polymer additives; raw materials for organic synthesis; raw materials for fine ceramics; intermediates for stabilizers for applications in food and medicine packaging; and pharmaceutical intermediates.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
CHEMICAL PRODUCTS, namely, [ DI-N-OCTYLTIN OXIDE (DOTO) AS AN INTERMEDIATE FOR NON-TOXIC ORGANO-TIN STABILIZERS FOR POLYVINYL CHLORIDE (PVC) OF FOOD CONTACT AND HUMAN CONTACT APPLICATIONS; DIMETHYL BENZYL CARBINOL (DMBC) FOR FRAGRANCES USED IN THE MANUFACTURE OF PERFUMES; TRI-N-BUTYL PHOSPHINE (TBP) AND ] TRIPHENYL PHOSPHINE (TPP) FOR METALLIC COMPLEX CATALYSTS OR IN SYNTHESIS OF NATURAL SUBSTANCES; TRI-N-OCTYLPHOSPHINE OXIDE (TOPO) USED AS AN EXTRACTANT AGENT FOR RARE METALS; PARA-CHOLOROSTYRENE (PCST) USED AS A HIGH PURITY MONOMER FOR FUNCTIONAL POLYMERS; [AND HYDROCHLORIDE OF [5-AMINO-Z-METHY 1-6- (2,3,4,5,6 - PENTAHYDROXY CYCLOHEXYLOXY) TETRA-HYDROPYRAN - 3-Y 1] AMINO-ALPHA-IMINOACETIC ACID TO BE USED AS AN AGRICULTURAL AND ANTI-BACTERIAL MEASURE]
