The present invention relates to a porous electrode for use in electrical energy storage or production devices, such as a lithium ion battery. Said porous electrode is a porous layer comprising at least an active electrode material P and an electronic conductive oxide material.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
The present invention relates to a porous electrode for use in electrical energy storage or production devices, such as a lithium ion battery. Said porous electrode is a porous layer comprising at least an active electrode material P and an electronic conductive oxide material.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
Method A method for manufacturing an anode having a porosity of between 25% and 50% by volume, wherein: (a) a substrate and a colloidal suspension or a paste composed of monodispersed primary nanoparticles, in the form of agglomerates or dispersed, is provided of at least one active material of anode A selected from niobium oxides and mixed oxides of niobium with titanium, germanium, cerium, lanthanum, copper or tungsten, with an average primary diameter D50 of between 2 nm and 100 nm; (b) on at least one face of the substrate a layer of said colloidal suspension or paste provided in step (a) is deposited by a method selected from the group including: electrophoresis, extrusion, a printing process and preferably inkjet printing or flexographic printing, a coating method and preferably doctor blade coating, roll coating, curtain coating, dip coating or through a slot die; (c) the layer obtained in step (b) is dried and consolidated by pressing and/or heating to obtain a porous layer.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
4.
HIGH POWER DENSITY AND LOW-COST LITHIUM-ION BATTERY
Lithium-ion battery comprising at least one stack which comprises successively: a first electronic current collector, a first porous electrode made of a material selected from the group formed by Nb2−xM1xO5−δM3δ, Nb18−xM1xW16−yM2yO93−δM3δ, Nb16−xM1xW5−yM2yO55−δM3δ, Nb2O5−δ with 0≤δ≤2, Nb18W16O93−δ with 0≤δ≤2, Nb16W5O55−δ with 0≤δ≤2, Li4Ti5O12 and Li4Ti5−xMxO12 with M=V, Zr, Hf, Nb, Ta and 0≤x≤0.25, a porous separator made of an electronically insulating inorganic material, a second porous electrode made of a phosphate or a lithium oxide, and a second electronic current collector, knowing that the electrolyte of said battery is a liquid charged with lithium ions confined in said porous layers, each of the three porous layers being free of binder and having a porosity comprised between 20% and 70% by volume.
H01M 50/46 - Separators, membranes or diaphragms characterised by their combination with electrodes
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0568 - Liquid materials characterised by the solutes
H01M 10/0569 - Liquid materials characterised by the solvents
H01M 50/11 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure having a structure in the form of a chip
The invention relates to a method for producing a porous electrode, said electrode comprising a layer deposited on a substrate, said layer being binder-free and having a porosity of more than 30 volume %, and preferably less than 50 volume %, and pores having an average diameter of less than 50 nm, said method being characterized in that:
a colloidal suspension is provided, containing aggregates or agglomerates of nanoparticles of at least one material P having an average primary diameter D50 of less than or equal to 80 nm, and preferably less than or equal to 50 nm, said aggregates or agglomerates having an average diameter comprised between 80 nm and 300 nm (preferably between 100 nm and 200 nm),
a substrate is provided,
a porous, preferably mesoporous, electrode layer is deposited on said substrate by electrophoresis, by ink-jet, by doctor blade, by roll coating, by curtain coating or by dip-coating, from said colloidal suspension provided in step (a);
said layer obtained in step (c) is dried, preferably in an air flow,
optionally, consolidation of the porous, preferably mesoporous electrode layer obtained in step (d) by pressing and/or heating.
H01G 11/24 - Electrodes characterised by the structural features of powders or particles used therefor
H01G 11/30 - Electrodes characterised by their material
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
6.
METHOD FOR PRODUCING A POROUS ANODE FOR A LITHIUM-ION SECONDARY BATTERY, RESULTING ANODE, AND BATTERY COMPRISING SAID ANODE
A method for manufacturing an anode having a porosity of between 25% and 50% by volume, wherein: (a) a substrate and a colloidal suspension or a paste composed of monodispersed primary nanoparticles, in the form of agglomerates or dispersed, is provided of at least one active material of anode A selected from niobium oxides and mixed oxides of niobium with titanium, germanium, cerium, lanthanum, copper or tungsten, with an average primary diameter D50 of between 2 nm and 100 nm; (b) on at least one face of said substrate a layer of the colloidal suspension or paste provided in step (a) is deposited by a method selected from the group including: electrophoresis, a printing process and preferably inkjet printing or flexographic printing, a coating method and preferably doctor blade coating, roll coating, curtain coating, dip coating or through a slot die; (c) the layer obtained in step (b) is dried and consolidated by pressing and/or heating to obtain a porous layer.
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
7.
METHOD FOR MANUFACTURING AN ASSEMBLY COMPRISING A SEPARATOR AND POROUS ELECTRODE, AN ASSEMBLY COMPRISING A SEPARATOR AND POROUS ELECTRODE, AND ELECTROCHEMICAL DEVICE CONTAINING SUCH AN ASSEMBLY
A method for manufacturing an electrochemical device that may be selected from the group consisting of: lithium ion batteries with a capacity greater than 1 mAh, capacitors, supercapacitors, resistors, inductors, transistors, photovoltaic cells, fuel cells, implementing a method for manufacturing an assembly comprising a porous electrode and a porous separator comprising a porous layer deposited on a substrate having a porosity comprised between 20% and 60% by volume, and pores with an average diameter of less than 50 nm.
An anodic member, an electrochemical device having an anodic member, and a method for manufacturing an anodic member for a lithium-ion battery. The method uses nanoparticles of an electrically insulating material that conducts lithium ions, is stable in contact with metallic lithium, does not insert lithium at potentials of between 0 V and 4.3 V with respect to the potential of the lithium, and has a relatively low melting point.
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
9.
HIGH ENERGY AND POWER DENSITY ANODE FOR BATTERIES AND METHOD FOR THE PRODUCTION THEREOF
An anodic member, an electrochemical device having an anodic member, and a method for manufacturing an anodic member for a lithium-ion battery. The method uses nanoparticles of an electrically insulating material that conducts lithium ions, is stable in contact with metallic lithium, does not insert lithium at potentials of between 0 V and 4.3 V with respect to the potential of the lithium, and has a relatively low melting point.
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
A method for manufacturing an electrode having a porosity of between 20% and 60% by volume and pores with an average diameter of less than 50 nm. In the method, provision is made of a substrate and a colloidal suspension of aggregates or agglomerates of monodisperse primary nanoparticles of an active electrode material, having an average primary diameter D50 of between 2 and 100 nm, the aggregates or agglomerates having an average diameter D50 of between 50 nm and 300 nm. A layer is deposited from said colloidal suspension on the substrate. The deposited layer is then dried and consolidated to obtain a mesoporous layer. A coating of an electronically conductive material is then deposited on and inside the pores of the porous layer. Such a porous electrode can be used in lithium-ion microbatteries.
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition (CVD) processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
11.
METHOD FOR PRODUCING A POROUS ELECTRODE, AND BATTERY CONTAINING SUCH AN ELECTRODE
The present invention relates to a porous electrode that can be used in electrochemical devices such as a lithium-ion battery. This porous electrode comprises a porous layer of at least one electrode active material P deposited on a substrate, and a coating made of an oxide electronic conductor material present on and inside the pores of said porous layer of at least one electrode active material P.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1315 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/13915 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 4/02 - Electrodes composed of, or comprising, active material
12.
METHOD FOR PRODUCING A POROUS ELECTRODE, AND BATTERY CONTAINING SUCH AN ELECTRODE
The present invention relates to a porous electrode that can be used in electrochemical devices such as a lithium-ion battery. This porous electrode comprises a porous layer of at least one electrode active material P deposited on a substrate, and a coating made of an oxide electronic conductor material present on and inside the pores of said porous layer of at least one electrode active material P.
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/1315 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/13915 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/02 - Electrodes composed of, or comprising, active material
13.
METHOD FOR MANUFACTURING AN ASSEMBLY COMPRISING A SEPARATOR AND POROUS ELECTRODE, AN ASSEMBLY COMPRISING A SEPARATOR AND POROUS ELECTRODE, AND MICROBATTERY CONTAINING SUCH AN ASSEMBLY
A method for manufacturing a lithium-ion microbattery having a capacity not exceeding 1 mAh, implementing a method for manufacturing an assembly comprising a porous electrode and a porous separator comprising a porous layer deposited on a substrate having a porosity comprised between 20% and 60% by volume, and pores with an average diameter of less than 50 nm. The separator comprises a porous inorganic layer deposited on the electrode, the porous inorganic layer having a porosity comprised between 20% and 60% by volume, and pores with an average diameter of less than 50 nm.
A battery, and a method for manufacturing at least one battery. The method includes forming a stack formed by an alternating succession of cathode strata and anode strata, each cathode stratum forming cathode entities and each anode stratum forming anode entities. The method further includes conducting a heat treatment and/or a mechanical compression of the formed stack to form a consolidated stack, and then making a pair of main cuts between two adjacent empty zones, in a top view, so as to expose an anode connection zone and an cathode connection zone, and to separate a given battery, formed from a given row (Rn), from at least one other adjacent battery, formed from at least one adjacent row (Rn+1).
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
15.
METHOD FOR MANUFACTURING DENSE LAYERS THAT CAN BE USED AS ELECTRODES AND/OR ELECTROLYTES FOR LITHIUM ION BATTERIES, AND LITHIUM ION MICROBATTERIES OBTAINED IN THIS WAY
A method for manufacturing a dense layer that includes: supplying a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate using the suspension; drying the layer thus obtained; and densifying the dried layer by mechanical compression and/or heat treatment. The method is characterised in that the suspension of non-agglomerated nanoparticles of material P includes nanoparticles of material P having a size distribution having a value of D50. The distribution includes nanoparticles of material P of a first size D1 between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by the value D50 being at least five times less than that of D1, or the distribution has a mean size of nanoparticles of material P less than 50 nm, and a standard deviation to mean size ratio greater than 0.6.
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
C25D 13/02 - Electrophoretic coating characterised by the process with inorganic material
A method for manufacturing a lithium ion battery with a capacitance greater than 1 mA h, including the deposition of at least one dense layer, which can be an anode and/or a cathode and/or an electrolyte, by a method of depositing a dense layer. The method includes: supplying a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate using the suspension; drying the layer thus obtained; densifying the dried layer by mechanical compression and/or heat treatment. The method of depositing being characterised in that the suspension of non-agglomerated nanoparticles of material P includes nanoparticles of material P having a size distribution, said size being characterised by the value of D50 thereof, such that: the distribution includes nanoparticles of material P of a first size D1 between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by a value D50 at least five times less than that of D1, or the distribution has a mean size of nanoparticles of material P less than 50 nm, and a standard deviation to mean size ratio greater than 0.6.
Battery including at least one unit cell formed by an anode, an electrolyte, and a cathode, defining a stack. The stack of the battery has a plurality of faces that includes two end faces opposite one another, two lateral faces opposite one another, and two longitudinal faces opposite one another. The first longitudinal face includes at least one anode connection zone and a second longitudinal face of the battery includes at least one cathode connection zone that is laterally opposite to the at least one anode connection zone. In a first longitudinal direction of the battery, each anode current-collecting substrate protrudes from each anode layer, from each layer of electrolyte material or layer of a separator impregnated with an electrolyte, from each cathode layer and from each cathode current-collecting substrate layer. In a second longitudinal direction of the battery that is opposite to the first longitudinal direction, each cathode current-collecting substrate protrudes from each anode layer, from each layer of electrolyte material, or layer of a separator impregnated with an electrolyte, from each cathode layer and from each anode current-collecting substrate layer.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/131 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by physical properties, e.g. gas-permeability or size
18.
METHOD FOR MANUFACTURING A POROUS ELECTRODE, AND BATTERY CONTAINING SUCH AN ELECTRODE
A method for manufacturing an electrochemical device, implementing a process for manufacturing a porous electrode having a porous layer deposited on a substrate, the porous layer having a porosity of between 20% and 60% by volume and pores with an average diameter of less than 50 nm. The method includes providing a substrate and a colloidal suspension including aggregates or agglomerates of monodisperse primary nanoparticles of an active electrode material, having an average primary diameter of between 2 and 60 nm, the aggregates or agglomerates having an average diameter of between 50 nm and 300 nm, then depositing a layer from the colloidal suspension on the substrate, then drying and consolidating the layer to obtain a mesoporous layer, and then depositing a coating of an electronically conductive material on and inside the pores of the layer.
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/54 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of silver
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/56 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead
H01M 10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M 12/08 - Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
H01M 4/86 - Inert electrodes with catalytic activity, e.g. for fuel cells
19.
METHOD FOR PRODUCING LITHIUM-ION BATTERIES, IN PARTICULAR HIGH-POWER BATTERIES, AND BATTERY OBTAINED BY THIS METHOD
A battery-type of electrochemical device including a unit stack formed by at least one unit cell, an electrical connection support, made at least in part of a conductive material, provided near a first frontal face of the unit stack, electrical insulation means enabling two distant regions of the electrical connection support to be insulated from one another, anode contact means enabling a first lateral face of the unit stack to be electrically connected to the electrical connection support, cathode contact means enabling a second lateral face of the unit stack to be electrically connected to the electrical connection support, an encapsulation system covering the other frontal face of the unit stack, the anode contact means, the cathode contact means, and at least in part the face of the electrical connection support that is facing the unit stack, and a mechanical stiffening system covering the encapsulation system opposite the electrical connection support.
H01M 50/186 - Sealing members characterised by the disposition of the sealing members
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
21.
BATTERY HAVING AN ENCAPSULATION SYSTEM THAT IS REINFORCED AT THE CONTACT MEMBERS
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/586 - Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries inside the batteries, e.g. incorrect connections of electrodes
H01M 50/59 - Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries characterised by the protection means
22.
BATTERY, IN PARTICULAR A THIN-FILM BATTERY, HAVING A NOVEL ENCAPSULATION SYSTEM
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
H01M 10/04 - Construction or manufacture in general
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/176 - Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for prismatic or rectangular cells
A battery including a stack alternating between at least one anode and at least one cathode, a primary encapsulation system covering some of the faces of the stack, at least one anode contact member operable to make electrical contact between the stack and an external conductive element, and at least one cathode contact member operable to make an electrical contact between the stack and an external conductive element. An additional encapsulation system includes two frontal regions respectively covering a respective frontal region of the primary encapsulation system and two lateral regions which cover a respective lateral region devoid of any contact member of the primary encapsulation system. Each of the two frontal regions of the additional encapsulation system further cover the frontal ends respectively of the anode contact members and the cathode contact members. The frontal regions of the additional encapsulation system form a surface continuity with the lateral regions of the additional encapsulation system.
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
H01M 50/103 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure prismatic or rectangular
Systems, methods, and apparatus for encapsulating objects like that of microelectronic components and batteries. The system includes three successive layers that include a first covering layer composed of an electrically insulating material deposited by atomic layer deposition, which at least partly covers the object, a second covering layer that includes parylene and/or polyimide, and which is disposed on the first covering layer, and a third covering layer deposited on the second covering layer in such a way as to protect the second encapsulation layer, namely, with respect to oxygen, and thereby increase the service life of the object.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition (CVD) processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 50/10 - Primary casings, jackets or wrappings of a single cell or a single battery
H01M 50/116 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
25.
HIGH POWER DENSITY AND LOW-COST LITHIUM-ION BATTERY
A lithium-ion battery comprising at least one stack which successively comprises: a first electronic current collector, a first porous electrode made of a material selected from the group comprising ?b2-x?1O5-d?3d, Nb18- xM1 xW16-yM2 y?93-d M3 d, Nb16-xM1 xW5-yM2yO55-dM3 d, Nb2O5-d with 0 = d = 2, Nb18W16O93-d with 0 = d = 2, Nb16W5O55-d with 0 = d = 2, Li4Ti5O12 and Li4Ti5-xMxO12 with M = V, Zr, Hf, Nb, Ta and 0 = x = 0.25, a porous separator made of an electronically insulating inorganic material, a second porous electrode made of a phosphate or a lithium oxide, and a second electronic current collector, wherein the electrolyte of the battery is a liquid charged with lithium ions sealed in the porous layers, each of the three porous layers being binder-free and having a porosity of between 20% and 70% by volume.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
2-x2-xΜ1O5-δΜ318xxM1x16-y16-yM2y93-δ93-δ M3δ16-x16-xM1x5-y5-yM255-δ55-δM3δ25-δ181693-δ16555-δ451245-xx1212 with M = V, Zr, Hf, Nb, Ta and 0 ≤ x ≤ 0.25, a porous separator made of an electronically insulating inorganic material, a second porous electrode made of a phosphate or a lithium oxide, and a second electronic current collector, wherein the electrolyte of the battery is a liquid charged with lithium ions sealed in the porous layers, each of the three porous layers being binder-free and having a porosity of between 20% and 70% by volume.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
A battery (1000) comprising an elementary cell (100) that comprises, in succession, a planar anode current collector substrate (10), an anode layer (20), a layer of an electrolyte material (30) or of a separator impregnated with an electrolyte (31), a cathode layer (50), and a planar cathode current collector substrate (40), said battery (1000) also comprising longitudinal edges (1011, 1012), a first lateral edge (1001) comprising an anode connection area (1002) and a second lateral edge (1005) comprising a cathode connection area (1006). Each elementary cell (100) comprises a primary body (111), a secondary body (112) and a tertiary body (113), said secondary body and said tertiary body being arranged on either side of said primary body, it being understood that each of the primary (111), secondary (112) and tertiary (113) bodies comprises, in succession, a planar anode current collector substrate (10), an anode layer (20), a layer of an electrolyte material (30) or of a separator impregnated with an electrolyte (31), a cathode layer (50), and a planar cathode current collector substrate (40). Said secondary body (112) is separated from the primary body (111) by a notch (120) free from any anode, electrolyte, cathode and anode current collector substrate material. Said notch extends from a longitudinal edge (1011) to the opposite longitudinal edge of the battery (1012) in a direction perpendicular to the main plane of the battery. Said tertiary body (113) is separated from the primary body (111) by a recess (130) free from any anode, electrolyte, cathode and cathode current collector substrate material. Said recess (130) extends from a longitudinal edge (1011) to the opposite longitudinal edge of the battery (1012) in a direction perpendicular to the main plane of the battery.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
A method for producing an anode having a porosity of between 25% and 50% by volume, comprising: (a) supplying a substrate and a colloidal suspension or paste consisting of monodispersed primary nanoparticles, in agglomerate or dispersed form, of at least one active anode material A selected from niobium oxides and mixed oxides of niobium and titanium, germanium, cerium, lanthanum, copper, or tungsten, having an average primary diameter D50 of between 2 nm and 100 nm; (b) depositing, on at least one face of the substrate, a layer from said colloidal suspension or paste supplied in step (a) using a method selected from the group made up of electrophoresis, extrusion, a printing method, preferably inkjet printing or flexographic printing, and a coating method, preferably by means of knife coating, roller coating, curtain coating, dip coating, or slot-die coating; and (c) drying the layer obtained in step (b), and solidifying same, by pressing and/or heating, to obtain a porous layer.
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
29.
METHOD FOR PRODUCING A POROUS ANODE FOR A LITHIUM-ION SECONDARY BATTERY, RESULTING ANODE, AND BATTERY COMPRISING SAID ANODE
A method for producing an anode having a porosity of between 25% and 50% by volume, comprising: (a) supplying a substrate and a colloidal suspension or paste consisting of monodispersed primary nanoparticles, in agglomerate or dispersed form, of at least one active anode material A selected from niobium oxides and mixed oxides of niobium and titanium, germanium, cerium, lanthanum, copper, or tungsten, having an average primary diameter D50 of between 2 nm and 100 nm; (b) depositing, on at least one face of the substrate, a layer from said colloidal suspension or paste supplied in step (a) using a method selected from the group made up of electrophoresis, a printing method, preferably inkjet printing or flexographic printing, and a coating method, preferably by means of knife coating, roller coating, curtain coating, dip coating, or slot-die coating; and (c) drying the layer obtained in step (b), and solidifying same, by pressing and/or heating, to obtain a porous layer.
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/02 - Electrodes composed of, or comprising, active material
5050 of between 2 nm and 100 nm; (b) depositing, on at least one face of the substrate, a layer from said colloidal suspension or paste supplied in step (a) using a method selected from the group made up of electrophoresis, extrusion, a printing method, preferably inkjet printing or flexographic printing, and a coating method, preferably by means of knife coating, roller coating, curtain coating, dip coating, or slot-die coating; and (c) drying the layer obtained in step (b), and solidifying same, by pressing and/or heating, to obtain a porous layer.
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 4/02 - Electrodes composed of, or comprising, active material
31.
METHOD FOR MANUFACTURING BATTERIES AND BATTERY OBTAINED BY SAID METHOD
Battery comprising at least one anode and at least one cathode, arranged on top of one another in an alternating manner, the battery comprising lateral edges and longitudinal edges, in which the anode comprises a current collector substrate, —at least one anode layer, and—optionally, a layer of an electrolyte material, and the cathode comprises: —a current collector substrate, at least one cathode layer, and—optionally a layer of an electrolyte material such that the battery comprises successively at least one anode layer, at least one layer of an electrolyte material and at least one cathode layer, characterized in that each anode and each cathode comprises a respective main body, separated from a respective secondary body by a space that is free of any electrode, electrolyte and/or current collector substrate material, the free space joining or extending between the opposite longitudinal edges of the battery.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/54 - Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
32.
CONTACT UNIT FOR AN ELECTRONIC OR ELECTROCHEMICAL DEVICE
Contact unit for an electronic or electrochemical device such as a battery, intended to create electrical contact with an external conductor element, said electronic or electrochemical device comprising a contact surface defining an electrical connection area, characterized in that the contact unit comprises a first layer, arranged on at least the electrical connection area, this first layer comprising a material filled with electrically conductive particles, preferably a polymer resin and/or a material obtained using a sol-gel process and filled with electrically conductive particles, and even more preferably a polymer resin filled with graphite.
This invention relates to a method for manufacturing an anodic member for a lithium ion secondary battery with a capacity greater than 1 mAh. The anodic member is manufactured from a colloidal suspension having aggregates or agglomerates of monodisperse nanoparticles of a lithium ion conducting material with a mean primary diameter of between 5 nm and 100 nm having a mesoporosity of between 35% and 70% by volume. This anodic member may be used in a lithium ion battery. When first charged, metallic lithium precipitates into the mesopores of the anodic member and forms the anode.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/04 - Construction or manufacture in general
H01M 50/128 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers with two or more layers of only inorganic material
H01M 50/129 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers with two or more layers of only organic material
34.
HIGH ENERGY AND POWER DENSITY ANODE FOR BATTERIES AND METHOD FOR THE PRODUCTION THEREOF
This invention relates to a method for producing an anodic member for a lithium-ion secondary battery. The anodic member is produced from a colloidal suspension having aggregates or agglomerates of monodisperse nanoparticles of a conductive material of lithium ions having an average primary diameter of between 5 nm and 100 nm, and has a mesoporosity between 35% and 70% by volume. This anodic member may be used in lithium-ion microbatteries. During its first charging, the metallic lithium precipitates in the mesopores of the anodic member and forms the anode.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/128 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers with two or more layers of only inorganic material
H01M 50/129 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers with two or more layers of only organic material
H01M 4/02 - Electrodes composed of, or comprising, active material
35.
HIGH ENERGY AND POWER DENSITY ANODE FOR BATTERIES AND METHOD FOR THE PRODUCTION THEREOF
This invention relates to a method for producing an anodic member for a lithium-ion secondary battery. The anodic member is produced from a colloidal suspension having aggregates or agglomerates of monodisperse nanoparticles of a conductive material of lithium ions having an average primary diameter of between 5 nm and 100 nm, and has a mesoporosity between 35% and 70% by volume. This anodic member may be used in lithium-ion microbatteries. During its first charging, the metallic lithium precipitates in the mesopores of the anodic member and forms the anode.
01 - Chemical and biological materials for industrial, scientific and agricultural use
09 - Scientific and electric apparatus and instruments
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemical products intended for industry and science; mineral
powders for industrial use; carbon and ceramic powders for
electrochemical devices; mineral powders for industrial
use, namely carbon and ceramic powders for secondary battery
cells comprising components used for deposition of
insulating layers, electrodes and electrolyte layers in
electric and electronic batteries; nanometric powders for
industrial use, namely carbon and ceramic powders for
secondary battery cells comprising components used for
introducing insulating layers, electrodes and electrolyte
layers in electronic and electric batteries; mixtures of
mineral powders for industrial use, namely mixtures of
ceramic and carbon powders for secondary battery cells
comprising components used for introducing insulating
layers, electrodes and electrolyte layers in electronic and
electric batteries; mixtures of nanometric powders used in
industry, namely ceramic and carbon powders for secondary
battery cells comprising components used for introducing
insulating layers, electrodes and electrolyte layers in
electronic and electric batteries; suspension of mineral
powders for industrial use, namely ceramic and carbon powder
for secondary battery cells comprising components used for
introducing insulating layers, electrodes and electrolyte
layers in electronic and electric batteries; suspension of
nanometric powders, namely suspension of ceramic and carbon
powder for secondary battery cells comprising components
used for introducing insulating layers, electrodes and
electrolyte layers in electronic and electric batteries. Electric batteries; electric cells, namely batteries;
plates for batteries; electric accumulators; charging
apparatus for batteries; vehicle batteries;
semi-conductors, namely integrated circuits; blank memory
cards; black integrated circuit cards, namely blank smart
cards; printed circuits; microprocessors; passive
components, namely electric capacitors and inductors;
photovoltaic cells; solar batteries; apparatus and
instruments for conducting, switching, transforming,
accumulating, regulating or controlling electricity, namely
power management integrated circuits (PMIC); electric
resistances; magnetic identity cards. Scientific and technological services, together with
research services, namely research and development of new
products for others; research and development of new
products and processes in the fields of chemistry and
electrochemistry for others; product development, namely
the development of chemicals for others and work on chemical
syntheses, namely mineral powder syntheses; synthesis of
mineral powders, namely development and evaluation of
mineral powder syntheses.
According to this method: a stack (I) is produced comprising, viewed from above, x rows and y lines, in order to form a number (x*y) of batteries, this stack being formed by an alternating succession of layers (SA, SC) that are respectively cathodic (SC) and anodic (SA), each layer (SA, SC) comprising a plurality of primary blanks that are respectively anodic (111') and cathodic (141'), a plurality of secondary blanks that are respectively anodic (112') and cathodic (142'), these blanks forming the primary and secondary bodies of the batteries, as well as so-called "empty" zones (80", 70") between these primary and secondary bodies; a pair of main cuts (DYn, DY'n) is made between two adjacent empty zones (80", 70"), viewed from above, so as to expose the anodic connection zone (1002) and the cathodic connection zone (1006 of each battery), and to separate a given battery, formed from a given row, from at least one other adjacent battery, formed from at least one adjacent row.
H01M 10/04 - Construction or manufacture in general
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/131 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by physical properties, e.g. gas-permeability or size
38.
METHOD FOR MANUFACTURING ANODES FOR LITHIUM-ION BATTERIES
Anode for a lithium-ion battery, including at least one anode material and being binder-free, said anode being precharged with lithium ions, characterized in that said anode material, deposited on an electronic conductor substrate capable of serving as anode current collector, is coated with a protective coating in contact with said anode material, said protective coating being capable of protecting said anode material from the atmosphere of the environment.
Anode for a lithium-ion battery, including at least one anode material and being binder-free, said anode being precharged with lithium ions, characterized in that said anode material, deposited on an electronic conductor substrate capable of serving as anode current collector, is coated with a protective coating in contact with said anode material, said protective coating being capable of protecting said anode material from the atmosphere of the environment.
The anode can be deposited from a vapor phase or by electrophoresis, and the protective coating by ALD or chemically in solution.
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/587 - Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
According to this method: a stack (I) is produced comprising, viewed from above, x rows and y lines, in order to form a number (x*y) of batteries, this stack being formed by an alternating succession of layers (SA, SC) that are respectively cathodic (SC) and anodic (SA), each layer (SA, SC) comprising a plurality of primary blanks that are respectively anodic (111') and cathodic (141'), a plurality of secondary blanks that are respectively anodic (112') and cathodic (142'), these blanks forming the primary and secondary bodies of the batteries, as well as so-called "empty" zones (80", 70") between these primary and secondary bodies; a pair of main cuts (DYn, DY'n) is made between two adjacent empty zones (80", 70"), viewed from above, so as to expose the anodic connection zone (1002) and the cathodic connection zone (1006 of each battery), and to separate a given battery, formed from a given row, from at least one other adjacent battery, formed from at least one adjacent row.
H01M 10/04 - Construction or manufacture in general
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/131 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by physical properties, e.g. gas-permeability or size
40.
METHOD FOR MANUFACTURING A POROUS ELECTRODE, AND BATTERY CONTAINING SUCH AN ELECTRODE
A method for manufacturing an electrochemical device selected from the group formed by: lithium-ion batteries having a capacity higher than 1 mAh, capacitors, supercapacitors, resistors, inductors, transistors, photovoltaic cells, and fuel cells, using a method for manufacturing a porous electrode comprising a porous layer deposited on a substrate, said layer having a porosity of between 20% and 60% by volume and pores with an average diameter smaller than 50 nm, said method for manufacturing said porous electrode being characterized in that it comprises: (a) providing a substrate and a colloidal suspension comprising aggregates or agglomerates of monodisperse primary nanoparticles of an electrode active material, having an average primary diameter Dso of between 2 and 60 nm, said aggregates or agglomerates having an average diameter Dso of between 50 nm and 300 nm, (b) depositing, on said substrate, a layer originating from said colloidal suspension, using a technique selected from the group formed by: electrophoresis, printing processes, and a coating technique; (c) drying said layer and consolidating it, by pressing and/or heating, to obtain a mesoporous layer, (d) depositing, on and inside the pores of said layer, a coating of an electron-conducting material, or using a porous electrode capable of being obtained using said method for manufacturing a porous electrode.
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/39 - Accumulators not provided for in groups working at high temperature
H01M 12/06 - Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1315 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/13915 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
41.
METHOD FOR MANUFACTURING A POROUS ELECTRODE, AND MICROBATTERY CONTAINING SUCH AN ELECTRODE
soso of between 2 and 100 nm, said aggregates or agglomerates having an average diameter Dso of between 50 nm and 300 nm, (b) depositing, on said substrate, a layer originating from said colloidal suspension, using a technique selected from the group formed by: electrophoresis, a printing technique, and a coating technique; (c) drying said layer obtained in step (b) and consolidating it, by pressing and/or heating, to obtain a mesoporous layer, (d) depositing, on and inside the pores of said layer, a coating of an electron-conducting material. This porous electrode may be used in lithium-ion microbatteries.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/1315 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/13915 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
42.
METHOD FOR MANUFACTURING A POROUS ELECTRODE, AND MICROBATTERY CONTAINING SUCH AN ELECTRODE
A method for manufacturing an electrode having a porosity of between 20% and 60% by volume and pores with an average diameter smaller than 50 nm, which method comprises: (a) providing a substrate and a colloidal suspension comprising aggregates or agglomerates of monodisperse primary nanoparticles of an electrode active material, having an average primary diameter Dso of between 2 and 100 nm, said aggregates or agglomerates having an average diameter Dso of between 50 nm and 300 nm, (b) depositing, on said substrate, a layer originating from said colloidal suspension, using a technique selected from the group formed by: electrophoresis, a printing technique, and a coating technique; (c) drying said layer obtained in step (b) and consolidating it, by pressing and/or heating, to obtain a mesoporous layer, (d) depositing, on and inside the pores of said layer, a coating of an electron-conducting material. This porous electrode may be used in lithium-ion microbatteries.
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1315 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/13915 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
43.
METHOD FOR MANUFACTURING AN ASSEMBLY CONSISTING OF A SEPARATOR AND POROUS ELECTRODE, AN ASSEMBLY CONSISTING OF A SEPARATOR AND POROUS ELECTRODE, AND MICROBATTERY CONTAINING SUCH AN ASSEMBL
The invention relates to a method for manufacturing a lithium-ion microbattery with a capacity not exceeding 1 mAh, using a method for manufacturing an assembly consisting of a porous electrode and a porous separator comprising a porous layer deposited on a substrate having a porosity of between 20% and 60% by volume, and pores having an average diameter smaller than 50 nm, and in which said separator comprises a porous inorganic layer deposited on said electrode, and said inorganic layer has a porosity of between 20% and 60% by volume, and pores with an average diameter smaller than 50 nm.
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1315 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/13915 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
44.
METHOD FOR MANUFACTURING AN ASSEMBLY CONSISTING OF A SEPARATOR AND POROUS ELECTRODE, AN ASSEMBLY CONSISTING OF A SEPARATOR AND POROUS ELECTRODE, AND ELECTROCHEMICAL DEVICE CONTAINING SUCH AN ASSEMBL
The invention relates to a method for manufacturing an electrochemical device selected from the group formed by batteries with a capacity higher than 1 mAh, capacitors, supercapacitors, resistors, inductors, transistors, photovoltaic cells, and fuel cells, using a method for manufacturing an assembly consisting of a porous electrode and of a porous separator comprising a porous layer deposited on a substrate having a porosity of between 20% and 60% by volume, and pores having an average diameter smaller than 50 nm.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1315 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/13915 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M 8/023 - Porous and characterised by the material
H01L 31/18 - Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
H01M 4/48 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/86 - Inert electrodes with catalytic activity, e.g. for fuel cells
H01M 12/06 - Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
45.
METHOD FOR MANUFACTURING AN ASSEMBLY CONSISTING OF A SEPARATOR AND POROUS ELECTRODE, AN ASSEMBLY CONSISTING OF A SEPARATOR AND POROUS ELECTRODE, AND MICROBATTERY CONTAINING SUCH AN ASSEMBLY
The invention relates to a method for manufacturing a lithium-ion microbattery with a capacity not exceeding 1 mAh, using a method for manufacturing an assembly consisting of a porous electrode and a porous separator comprising a porous layer deposited on a substrate having a porosity of between 20% and 60% by volume, and pores having an average diameter smaller than 50 nm, and in which said separator comprises a porous inorganic layer deposited on said electrode, and said inorganic layer has a porosity of between 20% and 60% by volume, and pores with an average diameter smaller than 50 nm.
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/1315 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/13915 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
46.
LITHIUM-ION BATTERY AND METHOD FOR THE MANUFACTURE THEREOF
A battery (1000) comprising at least one elementary cell (100) formed by an anode (20), an electrolyte (30) and a cathode (50), defining a stack (I), said stack (I) and said battery having six faces, specifically - two mutually opposing front faces (F1, F2), - two mutually opposing side faces (F3, F5), - and two mutually opposing longitudinal faces (F4, F6), it being understood that the first longitudinal face (F6) of the battery comprises at least one anode connection region (1002) and that a second longitudinal face (F4) of the battery comprises at least one cathode connection region (1006), said anode connection region (1002) and cathode connection region (1006) being laterally opposed, characterized in that - in a first longitudinal direction (XX') of the battery, each anode current collector substrate (10) projects simultaneously from each anode layer (20), from each electrolyte material layer (30) or separator layer impregnated with an electrolyte (31), from each cathode layer (50) and from each cathode current collector substrate layer (40) and - in a second longitudinal direction (XX'') of the battery, opposite said first longitudinal direction (XX'), each cathode current collector substrate (40) projects simultaneously from each anode layer (20), from each electrolyte material layer (30) or separator layer impregnated with an electrolyte (31), from each cathode layer (50) and from each anode current collector substrate layer (10).
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/54 - Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
Method for manufacturing a lithium-ion battery with a capacity greater than 1 mAh, comprising the depositing of at least one dense layer, which can be an anode and/or a cathode and/or an electrolyte, using a dense layer depositing method comprising the following steps: procuring a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer, on the substrate, from the suspension; drying the layer produced in this manner; compacting the dried layer using mechanical compression and/or heat treatment; the depositing method being characterised in that the suspension of non-agglomerated nanoparticles of material P comprises nanoparticles of material P having a size distribution, the size being characterised by its value D50, such that: - the distribution comprises nanoparticles of material P of a first size D1 between 20 nm and 50 nm, and nanoparticles of material P of a second size D2, characterised by a value D50 at least five times less than that of D1; or - the distribution has an average size of nanoparticles of material P that is less than 50 nm and a ratio of standard deviation from the average size greater than 0.6.
A battery (1000) comprising at least one elementary cell (100) formed by an anode (20), an electrolyte (30) and a cathode (50), defining a stack (I), said stack (I) and said battery having six faces, specifically - two mutually opposing front faces (F1, F2), - two mutually opposing side faces (F3, F5), - and two mutually opposing longitudinal faces (F4, F6), it being understood that the first longitudinal face (F6) of the battery comprises at least one anode connection region (1002) and that a second longitudinal face (F4) of the battery comprises at least one cathode connection region (1006), said anode connection region (1002) and cathode connection region (1006) being laterally opposed, characterized in that - in a first longitudinal direction (XX') of the battery, each anode current collector substrate (10) projects simultaneously from each anode layer (20), from each electrolyte material layer (30) or separator layer impregnated with an electrolyte (31), from each cathode layer (50) and from each cathode current collector substrate layer (40) and - in a second longitudinal direction (XX'') of the battery, opposite said first longitudinal direction (XX'), each cathode current collector substrate (40) projects simultaneously from each anode layer (20), from each electrolyte material layer (30) or separator layer impregnated with an electrolyte (31), from each cathode layer (50) and from each anode current collector substrate layer (10).
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/54 - Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
METHOD FOR MANUFACTURING DENSE LAYERS THAT CAN BE USED AS ELECTRODES AND/OR ELECTROLYTES FOR LITHIUM ION BATTERIES, AND LITHIUM ION MICROBATTERIES OBTAINED IN THIS WAY
Disclosed is a method for manufacturing a dense layer, comprising the following steps: providing a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate from the suspension; drying the layer obtained in this way; densifying the dried layer by mechanical compression and/or heat treatment; the method being characterised in that the suspension of non-agglomerated nanoparticles of material P comprises nanoparticles of material P having a size distribution, the size being characterised by its D50 value, such that: - the distribution comprises nanoparticles of material P of a first size D1 of between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by a D50 value at least five times less than that of D1; or - the distribution has an average size of nanoparticles of material P of less than 50 nm, and a standard deviation to average size ratio greater than 0.6.
B82Y 30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites
B82Y 40/00 - Manufacture or treatment of nanostructures
B01J 35/00 - Catalysts, in general, characterised by their form or physical properties
B01J 37/02 - Impregnation, coating or precipitation
C23C 18/12 - Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
C25D 13/02 - Electrophoretic coating characterised by the process with inorganic material
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
50.
METHOD FOR MANUFACTURING DENSE LAYERS THAT CAN BE USED AS ELECTRODES AND/OR ELECTROLYTES FOR LITHIUM ION BATTERIES, AND LITHIUM ION MICROBATTERIES OBTAINED IN THIS WAY
Disclosed is a method for manufacturing a dense layer, comprising the following steps: providing a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate from the suspension; drying the layer obtained in this way; densifying the dried layer by mechanical compression and/or heat treatment; the method being characterised in that the suspension of non-agglomerated nanoparticles of material P comprises nanoparticles of material P having a size distribution, the size being characterised by its D50 value, such that: - the distribution comprises nanoparticles of material P of a first size D1 of between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by a D50 value at least five times less than that of D1; or - the distribution has an average size of nanoparticles of material P of less than 50 nm, and a standard deviation to average size ratio greater than 0.6.
B01J 35/00 - Catalysts, in general, characterised by their form or physical properties
B01J 37/02 - Impregnation, coating or precipitation
B22F 1/02 - Special treatment of metallic powder, e.g. to facilitate working, to improve properties; Metallic powders per se, e.g. mixtures of particles of different composition comprising coating of the powder
B82Y 30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites
C23C 18/12 - Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
C25D 13/02 - Electrophoretic coating characterised by the process with inorganic material
C25D 15/00 - Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
B82Y 40/00 - Manufacture or treatment of nanostructures
C04B 35/00 - Shaped ceramic products characterised by their composition; Ceramic compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
01 - Chemical and biological materials for industrial, scientific and agricultural use
09 - Scientific and electric apparatus and instruments
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemicals for use in industry and science; mineral powders for industrial use, namely, carbon powders and ceramic powders used in industrial manufacturing; carbon and ceramic powders for use in manufacturing electrochemical devices; mineral powders for industrial use, namely, carbon and ceramic powders for use in manufacturing secondary battery cells comprising components used for deposition of insulating layers, electrodes and electrolyte layers in electric and electronic batteries; nanometric powders for industrial use, namely, carbon and ceramic powders for use in manufacturing secondary battery cells comprising components used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; mixtures of mineral powders for industrial use, namely, mixtures of ceramic and carbon powders for use in manufacturing secondary battery cells comprising components used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; mixtures of nanometric powders used in industry, namely, ceramic and carbon powders for use in manufacturing secondary battery cells comprising components used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; suspension agents comprised of mineral powders for industrial use, namely, ceramic and carbon powder for use in manufacturing secondary battery cells comprising components used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; suspension agents comprised of nanometric powders, namely, suspension of ceramic and carbon powder for use in manufacturing secondary battery cells comprising components used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries Vehicle batteries; semi-conductors, namely, integrated circuits; blank flash memory cards; blank integrated circuit cards, namely, blank smart cards; printed circuits; microprocessors; magnetic identity cards Scientific and technological services, together with research services, namely, research and development of new products for others; research and development of new products and processes in the fields of chemistry and electrochemistry for others; product development, namely, the development of chemicals for others and work on chemical syntheses, namely, mineral powder syntheses; engineering services in the field of synthesis of mineral powders, namely, development and evaluation of mineral powder syntheses
52.
Hot-pressing tool, method of operating it, and corresponding installation and method of manufacture
A hot-pressing tool mounted on a press and operable under a controlled atmosphere, a method for implementing such a hot-pressing tool, and a facility for manufacturing objects that includes such a hot-pressing tool. The tool includes a first tool portion having a first fastening device to fasten onto a first platen, a second tool portion having a second fastening device to fasten onto a second platen. The first fastening device and the second fastening device are mobile with respect to one another to define a pressing chamber having an inner volume which is heated via a heating device. The first fastening device and the second fastening device each respectively have a pressing member to exert a pressing force on opposite faces of an object to be pressed in the pressing chamber. The heating device is to heat via optical radiation that is concentrated on the object via a concentration device.
Thin-layer electrolyte in an electrochemical device such as a lithium-ion battery, said electrolyte comprising a porous inorganic layer impregnated with a phase carrying lithium ions,
Thin-layer electrolyte in an electrochemical device such as a lithium-ion battery, said electrolyte comprising a porous inorganic layer impregnated with a phase carrying lithium ions,
characterized in that said porous inorganic layer has an interconnected network of open pores.
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
H01M 50/176 - Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for prismatic or rectangular cells
H01M 50/204 - Racks, modules or packs for multiple batteries or multiple cells
H01M 50/526 - Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing characterised by the material having a layered structure
55.
BATTERY-TYPE ELECTROCHEMICAL DEVICE COMPRISING IMPROVED SEALING MEANS AND METHOD FOR MANUFACTURING SAME
This battery-type electrochemical device comprises a so-called elementary stack (2) formed by at least one elementary cell, an electrical connection support (5) which is at least partially produced from a conductive material and provided in the vicinity of a first front face (12) of the elementary stack, electrical insulation means (53, 54) for mutual insulation of two remote regions (56, 57) of the electrical connection support (5), anode contact means (30) which allow a first lateral face (23) of the elementary stack to be electrically connected to the electrical connection support (5), cathode contact means (40) which allow a second lateral face (24) of the elementary stack opposite the first lateral face to be electrically connected to the electrical connection support (5), an encapsulation system (7) covering the other front face (11) of the elementary stack, the anode contact means, the cathode contact means and at least partially the face (51) of the electrical connection support (5), which face is directed towards the elementary stack, and a mechanical stiffening system (8) which covers the encapsulation system opposite the electrical connection support (5).
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
H01M 50/176 - Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for prismatic or rectangular cells
H01M 50/204 - Racks, modules or packs for multiple batteries or multiple cells
H01M 50/526 - Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing characterised by the material having a layered structure
56.
ELECTROCHEMICAL BATTERY DEVICE WITH IMPROVED LIFETIME, COMPRISING IMPROVED SEALING AND ELECTRICAL CONDUCTION MEANS, AND MANUFACTURING METHOD THEREOF
Said battery comprises a stack (I) alternating between at least one anode (20) and at least one cathode (50), an encapsulating system which is referred to as the primary encapsulating system (1020) and covers four of the six faces of the stack (I), at least one anode contact member (1040) capable of ensuring electrical contact between the stack and an external conductive element, and at least one cathode contact member (1050) capable of ensuring electrical contact between the stack and an external conductive element. According to the invention, the battery also comprises an encapsulating system referred to as the additional encapsulating system (1030), said additional encapsulating system comprising two front regions (1031, 1032), each of which covers a respective front region (1021, 1022) of the primary encapsulating system, and two side regions (1033, 1035), each of which covers a respective side region (1023, 1025), which is free of any contact member, of the primary encapsulating system, each of the two front regions (1031, 1032) of the additional encapsulating system (1030) also covering the front ends (1041, 1042, 1051, 1052) of the anode contact members and the cathode contact members, respectively, and each of the front regions (1031, 1032) of the additional encapsulating system forming a continuous surface with the side regions (1033, 1035) of the additional encapsulating system.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/103 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure prismatic or rectangular
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
H01M 10/04 - Construction or manufacture in general
57.
METHOD FOR PRODUCING LITHIUM-ION BATTERIES, IN PARTICULAR HIGH POWER LITHIUM-ION BATTERIES, AND BATTERY OBTAINED BY THIS METHOD
A battery and its manufacturing process, the battery includes an anode comprising a current collecting substrate, an anode layer, and a cathode comprising a current collecting substrate, at least one cathode layer, successively forming an elementary stack of an anode layer, an electrolyte material or an electrolyte-impregnated separator, and a cathode layer, lateral edges of the battery comprising an anode and cathode connection zone, laterally opposite each anode and cathode comprises a main body, separated from a secondary body by a free space of electrode, electrolyte and current collecting substrate material, and through holes extending into the main and secondary body, forming a first through hole receiving a cathode conductor for collecting current to the cathode area, and a second through hole receiving an anode conductor for collecting current to the anode connection area.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
This battery-type electrochemical device comprises a so-called elementary stack (2) formed by at least one elementary cell, an electrical connection support (5) which is at least partially produced from a conductive material and provided in the vicinity of a first front face (12) of the elementary stack, electrical insulation means (53, 54) for mutual insulation of two remote regions (56, 57) of the electrical connection support (5), anode contact means (30) which allow a first lateral face (23) of the elementary stack to be electrically connected to the electrical connection support (5), cathode contact means (40) which allow a second lateral face (24) of the elementary stack opposite the first lateral face to be electrically connected to the electrical connection support (5), an encapsulation system (7) covering the other front face (11) of the elementary stack, the anode contact means, the cathode contact means and at least partially the face (51) of the electrical connection support (5), which face is directed towards the elementary stack, and a mechanical stiffening system (8) which covers the encapsulation system opposite the electrical connection support (5).
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/04 - Construction or manufacture in general
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
H01M 50/176 - Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for prismatic or rectangular cells
H01M 50/204 - Racks, modules or packs for multiple batteries or multiple cells
H01M 50/526 - Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing characterised by the material having a layered structure
59.
BATTERY HAVING AN ENCAPSULATION SYSTEM THAT IS REINFORCED AT THE CONTACT MEMBERS
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 6/18 - Cells with non-aqueous electrolyte with solid electrolyte
H01M 50/103 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure prismatic or rectangular
H01M 50/116 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
The invention relates to a novel high-power battery architecture comprising singular anode and cathode-conducting means that give it an improved service life.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/103 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure prismatic or rectangular
H01M 50/116 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
Said battery comprises a stack (I) alternating between at least one anode (20) and at least one cathode (50), an encapsulating system which is referred to as the primary encapsulating system (1020) and covers four of the six faces of the stack (I), at least one anode contact member (1040) capable of ensuring electrical contact between the stack and an external conductive element, and at least one cathode contact member (1050) capable of ensuring electrical contact between the stack and an external conductive element. According to the invention, the battery also comprises an encapsulating system referred to as the additional encapsulating system (1030), said additional encapsulating system comprising two front regions (1031, 1032), each of which covers a respective front region (1021, 1022) of the primary encapsulating system, and two side regions (1033, 1035), each of which covers a respective side region (1023, 1025), which is free of any contact member, of the primary encapsulating system, each of the two front regions (1031, 1032) of the additional encapsulating system (1030) also covering the front ends (1041, 1042, 1051, 1052) of the anode contact members and the cathode contact members, respectively, and each of the front regions (1031, 1032) of the additional encapsulating system forming a continuous surface with the side regions (1033, 1035) of the additional encapsulating system.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
H01M 50/103 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure prismatic or rectangular
H01M 50/116 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
63.
BATTERY, IN PARTICULAR THIN-FILM BATTERY, HAVING A NOVEL ENCAPSULATION SYSTEM
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/04 - Construction or manufacture in general
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/126 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
H01M 50/176 - Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for prismatic or rectangular cells
H01M 50/204 - Racks, modules or packs for multiple batteries or multiple cells
H01M 50/526 - Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing characterised by the material having a layered structure
Method for manufacturing a solid electrolyte for lithium-ion battery or supercapacitor, deposited on an electrode, comprising the steps of:
a. providing a conductive substrate, covered beforehand with a layer of material that can be used as an electrode (“electrode layer”),
b. deposition on said electrode layer of an electrolyte layer, preferably by electrophoresis or by dip-coating, from a suspension of core-shell particles comprising, as a core, a particle of a material that can be used as an electrolyte or electric insulator, on which a shell comprising PEO is grafted;
c. drying the electrolyte layer thus obtained, preferably in an airflow;
d. optionally, densifying said electrolyte layer by mechanical compression and/or heat treatment.
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01G 11/84 - Processes for the manufacture of hybrid or EDL capacitors, or components thereof
H01G 11/56 - Solid electrolytes, e.g. gels; Additives therein
H01G 11/24 - Electrodes characterised by the structural features of powders or particles used therefor
H01G 11/30 - Electrodes characterised by their material
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
66.
LITHIUM-ION BATTERY AND METHOD FOR THE MANUFACTURE THEREOF
A battery (1000) comprising an elementary cell (100) that comprises, in succession, a planar anode current collector substrate (10), an anode layer (20), a layer of an electrolyte material (30) or of a separator impregnated with an electrolyte (31), a cathode layer (50), and a planar cathode current collector substrate (40), said battery (1000) also comprising longitudinal edges (1011, 1012), a first lateral edge (1001) comprising an anode connection area (1002) and a second lateral edge (1005) comprising a cathode connection area (1006). Each elementary cell (100) comprises a primary body (111), a secondary body (112) and a tertiary body (113), said secondary body and said tertiary body being arranged on either side of said primary body, it being understood that each of the primary (111), secondary (112) and tertiary (113) bodies comprises, in succession, a planar anode current collector substrate (10), an anode layer (20), a layer of an electrolyte material (30) or of a separator impregnated with an electrolyte (31), a cathode layer (50), and a planar cathode current collector substrate (40). Said secondary body (112) is separated from the primary body (111) by a notch (120) free from any anode, electrolyte, cathode and anode current collector substrate material. Said notch extends from a longitudinal edge (1011) to the opposite longitudinal edge of the battery (1012) in a direction perpendicular to the main plane of the battery. Said tertiary body (113) is separated from the primary body (111) by a recess (130) free from any anode, electrolyte, cathode and cathode current collector substrate material. Said recess (130) extends from a longitudinal edge (1011) to the opposite longitudinal edge of the battery (1012) in a direction perpendicular to the main plane of the battery.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
A battery (1000) comprising an elementary cell (100) that comprises, in succession, a planar anode current collector substrate (10), an anode layer (20), a layer of an electrolyte material (30) or of a separator impregnated with an electrolyte (31), a cathode layer (50), and a planar cathode current collector substrate (40), said battery (1000) also comprising longitudinal edges (1011, 1012), a first lateral edge (1001) comprising an anode connection area (1002) and a second lateral edge (1005) comprising a cathode connection area (1006). Each elementary cell (100) comprises a primary body (111), a secondary body (112) and a tertiary body (113), said secondary body and said tertiary body being arranged on either side of said primary body, it being understood that each of the primary (111), secondary (112) and tertiary (113) bodies comprises, in succession, a planar anode current collector substrate (10), an anode layer (20), a layer of an electrolyte material (30) or of a separator impregnated with an electrolyte (31), a cathode layer (50), and a planar cathode current collector substrate (40). Said secondary body (112) is separated from the primary body (111) by a notch (120) free from any anode, electrolyte, cathode and anode current collector substrate material. Said notch extends from a longitudinal edge (1011) to the opposite longitudinal edge of the battery (1012) in a direction perpendicular to the main plane of the battery. Said tertiary body (113) is separated from the primary body (111) by a recess (130) free from any anode, electrolyte, cathode and cathode current collector substrate material. Said recess (130) extends from a longitudinal edge (1011) to the opposite longitudinal edge of the battery (1012) in a direction perpendicular to the main plane of the battery.
H01M 2/10 - Mountings; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/42 - Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
A method for producing an all-solid multilayer battery, and an all-solid multilayer battery. The all-solid multilayer battery may be produced by depositing, by electrophoresis without any binder, at least one anode layer, at least one electrolyte layer, and at least one cathode layer. The at least one electrolyte layer, and the at least one cathode layer are obtained from a colloidal suspension containing nanoparticles that are not agglomerated with each other to create clusters and remain isolated from each other. A layer of Ms bonding material is then deposited on a surface of the at least one electrolyte layer. Next, two layers from the at least one dense anode layer, the at least one dense electrolyte layer, and the at least one dense cathode layer, are stacked face-to-face to obtain the all-solid multilayer battery having an assembly of a plurality of elementary cells connected with one another in parallel.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
Battery comprising at least one anode and at least one cathode, arranged on top of one another in an alternating manner, the battery comprising lateral edges comprising an anode connection area and a cathode connection area, preferably laterally opposite the anode connection area, and longitudinal edges, in which the anode comprises a current collector substrate, - at least one anode layer, and - optionally, a layer of an electrolyte material, and the cathode comprises: - a current collector substrate, at least one cathode layer, and - optionally a layer of an electrolyte material such that the battery comprises successively at least one anode layer, at least one layer of an electrolyte material and at least one cathode layer, characterized in that each anode and each cathode comprises a respective main body, separated from a respective secondary body by a space that is free of any electrode, electrolyte and/or current collector substrate material, the free space joining or extending between the opposite longitudinal edges of the battery.
H01M 50/503 - Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing characterised by the shape of the interconnectors
H01M 50/231 - Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by the material of the casings or racks having a layered structure
H01M 50/46 - Separators, membranes or diaphragms characterised by their combination with electrodes
H01M 50/562 - Terminals characterised by the material
70.
METHOD FOR MANUFACTURING BATTERIES AND BATTERY OBTAINED BY SAID METHOD
Battery comprising at least one anode and at least one cathode, arranged on top of one another in an alternating manner, the battery comprising lateral edges comprising an anode connection area and a cathode connection area, preferably laterally opposite the anode connection area, and longitudinal edges, in which the anode comprises a current collector substrate, - at least one anode layer, and - optionally, a layer of an electrolyte material, and the cathode comprises: - a current collector substrate, at least one cathode layer, and - optionally a layer of an electrolyte material such that the battery comprises successively at least one anode layer, at least one layer of an electrolyte material and at least one cathode layer, characterized in that each anode and each cathode comprises a respective main body, separated from a respective secondary body by a space that is free of any electrode, electrolyte and/or current collector substrate material, the free space joining or extending between the opposite longitudinal edges of the battery.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
71.
CONTACT UNIT FOR AN ELECTRONIC OR ELECTROCHEMICAL DEVICE
Contact unit (40) for an electronic or electrochemical device such as a battery (1), intended to create electrical contact with an external conductor element, said electronic or electrochemical device comprising a contact surface (51) defining an electrical connection area (50), characterized in that the contact unit (40) comprises a first layer (41), arranged on at least the electrical connection area (50), this first layer (41) comprising a material filled with electrically conductive particles, preferably a polymer resin and/or a material obtained using a sol-gel process and filled with electrically conductive particles, and even more preferably a polymer resin filled with graphite.
Contact unit (40) for an electronic or electrochemical device such as a battery (1), intended to create electrical contact with an external conductor element, said electronic or electrochemical device comprising a contact surface (51) defining an electrical connection area (50), characterized in that the contact unit (40) comprises a first layer (41), arranged on at least the electrical connection area (50), this first layer (41) comprising a material filled with electrically conductive particles, preferably a polymer resin and/or a material obtained using a sol-gel process and filled with electrically conductive particles, and even more preferably a polymer resin filled with graphite.
Systems, methods, and apparatus for encapsulating objects like that of microelectronic components and batteries. The system includes three successive layers that include a first covering layer composed of an electrically insulating material deposited by atomic layer deposition, which at least partly covers the object, a second covering layer that includes parylene and/or polyimide, and which is disposed on the first covering layer, and a third covering layer deposited on the second covering layer in such a way as to protect the second encapsulation layer, namely, with respect to oxygen, and thereby increase the service life of the object.
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition (CVD) processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 50/124 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
H01M 50/10 - Primary casings, jackets or wrappings of a single cell or a single battery
H01M 50/116 - Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
H01M 50/141 - Primary casings, jackets or wrappings of a single cell or a single battery for protecting against damage caused by external factors for protecting against humidity
The invention relates to a method for producing a porous electrode, said electrode comprising a layer deposited on a substrate, said layer being binder-free and having a porosity of more than 30 volume %, and preferably less than 50 volume %, and pores having an average diameter of less than 50 nm, said method being characterised in that: (a) a colloidal suspension is provided, containing aggregates or agglomerates of nanoparticles of at least one material P having an average primary diameter D50 of less than or equal to 80 nm, and preferably less than or equal to 50 nm, said aggregates or agglomerates having an average diameter of between 80 nm and 300 nm (preferably between 100 nm and 200 nm), (b) a substrate is provided, (c) a porous, preferably mesoporous, electrode layer is deposited on said substrate by electrophoresis, by means of an ink-jet printing method, by scraping, by roller coating, by curtain coating or by dip coating, on the basis of said colloidal suspension provided in step (a), (d) said layer produced in step (c) is dried, preferably beneath an air flow, and (e) optionally, the porous, preferably mesoporous, electrode layer produced in step (d) is consolidated by pressing and/or by heating.
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01G 11/28 - Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
A method for manufacturing a solid electrolyte for a lithium-ion battery or a supercapacitor, deposited onto an electrode, comprising the following steps: a. providing a conductive substrate, previously covered with a layer of a material that can be used as an electrode ("electrode layer"); b. depositing an electrolyte layer onto said electrode layer, preferably by electrophoresis or by dip-coating, from a suspension of core-shell particles comprising, as a core, a particle of a material that can be used as an electrolyte or an electric isolator, on which a shell comprising PEO is grafted; c. drying the electrolyte layer that is thus obtained, preferably in an airflow; d. optionally densifying said electrolyte layer by mechanical compression and/or heat treatment.
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01G 11/56 - Solid electrolytes, e.g. gels; Additives therein
76.
POROUS CERAMIC FOR ELECTROLYTES USED IN THIN-FILM ELECTROCHEMICAL DEVICES
The invention relates to a thin-film electrolyte in an electrochemical device such as a lithium-ion battery, said electrolyte comprising a porous inorganic layer impregnated with a phase carrying lithium ions, characterized in that said porous inorganic layer has an interconnected network of open pores.
5050 of less than or equal to 80 nm, and preferably less than or equal to 50 nm, said aggregates or agglomerates having an average diameter of between 80 nm and 300 nm (preferably between 100 nm and 200 nm), (b) a substrate is provided, (c) a porous, preferably mesoporous, electrode layer is deposited on said substrate by electrophoresis, by means of an ink-jet printing method, by scraping, by roller coating, by curtain coating or by dip coating, on the basis of said colloidal suspension provided in step (a), (d) said layer produced in step (c) is dried, preferably beneath an air flow, and (e) optionally, the porous, preferably mesoporous, electrode layer produced in step (d) is consolidated by pressing and/or by heating.
H01G 11/28 - Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 10/04 - Construction or manufacture in general
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
The invention relates to an anode for a lithium-ion battery, including at least one anode material and being binder-free, said anode being precharged with lithium ions, characterised in that said anode material, deposited on an electronic conductor substrate capable of serving as anode current collector, is coated with a protective coating in contact with said anode material, said protective coating being capable of protecting said anode material from the atmosphere of the environment. The anode can be deposited from a vapour phase or by electrophoresis, and the protective coating by ALD or chemically in solution.
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/48 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
The invention relates to an anode for a lithium-ion battery, including at least one anode material and being binder-free, said anode being precharged with lithium ions, characterised in that said anode material, deposited on an electronic conductor substrate capable of serving as anode current collector, is coated with a protective coating in contact with said anode material, said protective coating being capable of protecting said anode material from the atmosphere of the environment. The anode can be deposited from a vapour phase or by electrophoresis, and the protective coating by ALD or chemically in solution.
H01M 2/16 - Separators; Membranes; Diaphragms; Spacing elements characterised by the material
H01M 4/48 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
A method for manufacturing a solid electrolyte for a lithium-ion battery or a supercapacitor, deposited onto an electrode, comprising the following steps: a. providing a conductive substrate, previously covered with a layer of a material that can be used as an electrode ("electrode layer"); b. depositing an electrolyte layer onto said electrode layer, preferably by electrophoresis or by dip-coating, from a suspension of core-shell particles comprising, as a core, a particle of a material that can be used as an electrolyte or an electric isolator, on which a shell comprising PEO is grafted; c. drying the electrolyte layer that is thus obtained, preferably in an airflow; d. optionally densifying said electrolyte layer by mechanical compression and/or heat treatment.
H01G 11/56 - Solid electrolytes, e.g. gels; Additives therein
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
81.
POROUS CERAMIC FOR ELECTROLYTES USED IN THIN-FILM ELECTROCHEMICAL DEVICES
The invention relates to a thin-film electrolyte in an electrochemical device such as a lithium-ion battery, said electrolyte comprising a porous inorganic layer impregnated with a phase carrying lithium ions, characterized in that said porous inorganic layer has an interconnected network of open pores.
A process for fabrication of a battery that includes providing a colloidal suspension of particles conducting lithium ions and providing two conducting substrates as battery current collectors, at least one surface of the conducting substrates being at least partially coated with one of a cathode film and an anode film, and depositing an electrolyte film by electrophoresis, from a suspension of electrolyte material particles, on at least one of said anode film, said cathode film and said conducting substrates.
H01M 10/0564 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
and in which said process also comprises at least one step in which said sheets or bands are stacked so as to form at least one battery with a “collector/anode/electrolyte/cathode/collector” type of stacked structure.
C25D 15/00 - Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
C25D 13/12 - Electrophoretic coating characterised by the process characterised by the article coated
H01M 4/1397 - Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
C25D 5/50 - After-treatment of electroplated surfaces by heat-treatment
84.
ENCAPSULATION SYSTEM FOR ELECTRONIC COMPONENTS AND BATTERIES
The invention relates to a system (30) for encapsulating an object (1000), such as an electronic or electrochemical component such a a battery. The system is characterised in that it is formed by three successive layers comprising: (i) a first cover layer (31, 31') consisting of an electrically insulating material deposited by means of atomic layer deposition, which at least partially covers the object; (ii) a second cover layer (32, 32') comprising parylene and/or polyimide, disposed on the first cover layer; (iii) a third cover layer (33, 33') deposited on the second cover layer such as to protect the second encapsulation layer, in particular against oxygen and to increase the service life of the object.
H01M 50/197 - Sealing members characterised by the material having a layered structure
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 6/18 - Cells with non-aqueous electrolyte with solid electrolyte
85.
ENCAPSULATION SYSTEM FOR ELECTRONIC COMPONENTS AND BATTERIES
The invention relates to a system (30) for encapsulating an object (1000), such as an electronic or electrochemical component such a a battery. The system is characterised in that it is formed by three successive layers comprising: (i) a first cover layer (31, 31') consisting of an electrically insulating material deposited by means of atomic layer deposition, which at least partially covers the object; (ii) a second cover layer (32, 32') comprising parylene and/or polyimide, disposed on the first cover layer; (iii) a third cover layer (33, 33') deposited on the second cover layer such as to protect the second encapsulation layer, in particular against oxygen and to increase the service life of the object.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
01 - Chemical and biological materials for industrial, scientific and agricultural use
09 - Scientific and electric apparatus and instruments
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemicals intended for industry and science; mineral powders
for industrial use, namely carbon powders and ceramic
powders for secondary battery cells comprising components
used for introducing insulating layers, electrodes and
electrolyte layers in electronic and electric batteries;
nanometric powders for industrial use, namely carbon and
ceramic powders for secondary battery cells comprising
components used for introducing insulating layers,
electrodes and electrolyte layers in electronic and electric
batteries; mixtures of mineral powders for industrial use,
namely mixtures of ceramic and carbon powders for secondary
battery cells comprising components used for introducing
insulating layers, electrodes and electrolyte layers in
electronic and electric batteries; mixtures of nanometric
powders used in industry, namely ceramic and carbon powders
for secondary battery cells comprising components used for
introducing insulating layers, electrodes and electrolyte
layers in electronic and electric batteries; suspension of
mineral powders for industrial use, namely ceramic and
carbon powder for secondary battery cells comprising
components used for introducing insulating layers,
electrodes and electrolyte layers in electronic and electric
batteries; suspension of nanometric powders, namely
suspension of ceramic and carbon powder for secondary
battery cells comprising components used for introducing
insulating layers, electrodes and electrolyte layers in
electronic and electric batteries. Electric batteries; electric cells, namely batteries;
plates for batteries; electric accumulators; charging
apparatus for batteries; vehicle batteries;
semi-conductors, namely integrated circuits; blank memory
cards; black integrated circuit cards, namely blank smart
cards; printed circuits; microprocessors; passive
components, namely electric capacitors and inductors;
photovoltaic cells; solar batteries; apparatus and
instruments for conducting, switching, transforming,
accumulating, regulating or controlling electricity, namely
power management integrated circuits (PMIC); electric
resistances; magnetic identity cards. Scientific and technological services, together with
research services, namely research and development of new
products for others; research and development of new
products and processes in the fields of chemistry and
electrochemistry for others; product development, namely
the development of chemicals for others and work on chemical
syntheses, namely mineral powder syntheses; synthesis of
mineral powders, namely development and evaluation of
mineral powder syntheses.
01 - Chemical and biological materials for industrial, scientific and agricultural use
09 - Scientific and electric apparatus and instruments
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemicals intended for industry and science; mineral powders for industrial use, namely, carbon powders and ceramic powders used in manufacturing for secondary battery cells used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; nanometric powders for industrial use, namely, carbon and ceramic powders used in manufacturing for secondary battery cells used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; mixtures of mineral powders for industrial use, namely, mixtures of ceramic and carbon powders used in manufacturing for secondary battery cells used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; mixtures of nanometric powders used in industry, namely, ceramic and carbon powders used in manufacturing for secondary battery cells used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; suspension of mineral powders for industrial use, namely, ceramic and carbon powder used in manufacturing for secondary battery cells used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries; suspension of nanometric powders, namely, suspension of ceramic and carbon powder used in manufacturing for secondary battery cells used for introducing insulating layers, electrodes and electrolyte layers in electronic and electric batteries Electric batteries; electric cells, namely, batteries; plates for batteries; electric accumulators; charging apparatus for batteries; vehicle batteries; semi-conductors, namely, integrated circuits; blank memory cards being computer hardware; blank integrated circuit cards, namely, blank smart cards; printed circuits; microprocessors; passive components, namely, electric capacitors and inductors; photovoltaic cells; solar batteries; apparatus and instruments for conducting, switching, transforming, accumulating, regulating or controlling electricity, namely, power management integrated circuits (PMIC); electric resistances; magnetically encoded identity cards Scientific and technological services, and research services thereto, namely, research and development of new products for others; research and development of processes in the fields of chemistry and electrochemistry for others; new product development for others, namely, the development of chemicals for others; development and testing of chemical production methods in the nature of work on chemical syntheses, namely, mineral powder syntheses; synthesis of mineral powders, namely, development and evaluation of chemical production methods in the nature of mineral powder syntheses
88.
HOT-PRESSING PRESS TOOL, METHOD OF OPERATING IT, AND CORRESPONDING INSTALLATION AND METHOD OF MANUFACTURE
This hot-pressing press tool, intended to be mounted on a press, comprises: – a first tool part (2) equipped with first means (29; 60) of attachment to a first press platen (12), – a second tool part (3) equipped with second means (13, 14; 60) of attachment to a second press platen (10), these two tool parts being mobile relative to one another between a distant position and a close-together position, in which they delimit a pressing chamber (300), – means (5) of heating the interior volume of the pressing chamber, – the first and second tool parts also being respectively equipped with a first and a second pressing member (28, 38), which members are able to apply a pressing force to opposite faces of an object that is to be pressed, received in the pressing chamber. According to the invention, the heating means are means of heating by optical radiation (5) and the tool further comprises concentration means (26, 28, 46) able to concentrate the energy of the radiation towards the said object. In that way, the optical radiation is directed at the entirety of the object that is to be pressed but, by contrast, no substantial proportion of this radiation passes outside the lateral edges of this object. A preferred, although not exclusive, use of this tool is the creation of solid-state lithium-ion batteries.
The invention relates to a method for manufacturing an all-solid-state battery made up of thin layers, including the following consecutive steps: a) depositing a layer including at least one anode material on the conductive substrate thereof; b) depositing a layer including at least one cathode material on the conductive substrate thereof; c) depositing a layer including at least one solid electrolyte material on at least one layer obtained in step a) and/or b); d) depositing a layer of an ion-conducting material with a thickness of less than 10 µm, preferably less than 5 µm, and more preferably less than 2 µm, either on the layer of anode material coated with a layer of solid electrolyte material and/or on the layer of cathode material optionally coated with a layer of solid electrolyte material, or on the layer of cathode material coated with a layer of solid electrolyte material and/or on the layer of anode material optionally coated with a layer of solid electrolyte material; e) drying said layer of said solution of the ion-conducting material obtained in step d) in order to obtain a layer of an ion-conducting material; f) consecutively stacking a layer of anode material obtained in step a), c) or e), face-to-face, with a layer of cathode material obtained in step b), c) or e), with the proviso that the stack includes at least one layer of solid electrolyte material obtained in step c) and at least one layer of an ion-conducting material obtained in step e); and g) thermally treating and/or mechanically compressing the stack obtained in step e) to obtain an all-solid-state battery made up of thin layers.
An all-solid battery including a solid electrolyte made of a cross-linked polymer material, and which has good mechanical resistance and superior ionic conductivity.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
A process for producing all-solid, thin-layer batteries that do not lead to the appearance of phases at the interface between electrolyte layers to be assembled. Such a process for producing a battery may occur at low temperature without causing inter-diffusion phenomena at the interfaces with the electrodes.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 4/02 - Electrodes composed of, or comprising, active material
01 - Chemical and biological materials for industrial, scientific and agricultural use
09 - Scientific and electric apparatus and instruments
42 - Scientific, technological and industrial services, research and design
Goods & Services
Chemical products for use in industry and science; mineral
powders; ceramic powders; nanometric powders; mineral
powder mixtures; nanometric powder mixtures; mineral powder
suspension; nanometric powder suspension. Electric batteries; electric cells (batteries); plates for
batteries; electric accumulators; apparatus for charging
electric accumulators; vehicle batteries; semi-conductors:
chips (integrated circuits); memory cards; integrated
circuit cards (smart cards); printed circuits;
microprocessors; passive components; photovoltaic cells;
solar batteries; apparatus and instruments for conducting,
switching, transforming, accumulating, regulating or
controlling electricity; electric resistances; magnetic
cards; magnetic identity cards. Scientific and technological services as well as research
services, namely research and development of new products;
research and development of new products and processes in
the fields of chemistry and electrochemistry; development of
chemical products and syntheses of mineral powders;
synthesis of mineral powders.
93.
Process for manufacturing a monolithic all-solid-state battery
An all-inorganic, all-solid-state monolithic Li-ion battery, the monolithic body having a plurality of elementary cells, and which is produced by producing dense electrode deposits directly on the two faces of a substrate acting as a battery current collector, and by depositing an all-solid-state dense electrolyte layer on at least one of the dense electrode deposits obtained.
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
The invention relates to a method for manufacturing an all-solid thin-film battery including the following consecutive steps: a) depositing a layer including at least one anode material on the conductive substrate thereof; b) depositing a layer including at least one cathode material on the conductive substrate thereof; c) depositing on the layer obtained in step a) and/or b) a layer including at least one solid electrolyte material selected among: Li3(Sc2-xMx)(P04)3 wherein M = Al or Y and 0 ≤ x ≤ 1; or Li1+xMx(Sc)2-x(P04)3 wherein M = Al, Y, Ga or a mixture of the three compounds and 0 ≤ x ≤ 0.8; or Li1+xMx(Ga1-yScy)2-x(P04)3 wherein 0 ≤ x ≤ 0.8; 0 ≤ y ≤ 1 and M = Al or Y; or a mixture of the two compounds; or Li1+xMx(Ga)2-x(P04)3 wherein M = Al, Y or a mixture of the two compounds and 0 ≤ x ≤ 0.8; or Li3+y(Sc2-xMxQyP3-yO12, wherein M = Al and/or Y and Q = Si and/or Se, 0 ≤ x ≤ 0.8 and 0 ≤ y ≤ 1; or Li1+x+yMxSc2-xQyP3-yO12, wherein M = Al, Y, Ga or a mixture of the three compounds and Q = Si and/or Se, 0 ≤ x ≤ 0.8 and 0 ≤ y ≤ 1; or Li1+x+y+zMx(Gai-yScy)2-xQzP3-zOi2 wherein 0 ≤ x ≤ 0.8; 0 < y < 1; 0 ≤ z ≤ 0.6 wherein M = Al or Y or a mixture of the two compounds and Q= Si and/or Se; Li1+xNxM2-xP3012, wherein 0 ≤ x ≤ 1 and N = Cr and/or V, M = Se, Sn, Zr, Hf, Se or Si, or a mixture of these compounds; d) consecutively stacking, face-to-face: either a layer of anode material coated with a layer of electrolyte material obtained in step c) with a layer of cathode material optionally coated with a layer of solid electrolyte material obtained in step c), or a layer of cathode material coated with a layer of electrolyte material obtained in step c) with a layer of anode material optionally coated with a layer of solid electrolyte material obtained in step c); and e) thermally treating and/or a mechanically compressing the stack obtained in step d) in order to obtain an all-solid thin-film battery.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
The invention relates to a method for manufacturing an all-solid thin-film battery including the following consecutive steps: a) depositing a layer including at least one anode material on the conductive substrate thereof; b) depositing a layer including at least one cathode material on the conductive substrate thereof; c) depositing a layer including at least one solid electrolyte material on at least one layer obtained in step a) and/or b); d) depositing a layer of a cross-linked polymer material comprising ion groupings with a thickness of less than 10 µm, preferably less than 5 µm, and more preferably less than 2 µm: either on the layer of anode material coated with a layer of solid electrolyte material and/or on the layer of cathode material optionally coated with a layer of solid electrolyte material, or on the layer of cathode material coated with a layer of solid electrolyte material and/or on the layer of anode material optionally coated with a layer of solid electrolyte material; e) consecutively stacking, face-to-face, a layer of anode material obtained in steps a), c) or d) with a layer of cathode material obtained in steps b), c) or d), with the understanding that the stack includes at least one layer of solid electrolyte material obtained in step c) and at least one layer of cross-linked polymer material obtained in step d); f) thermally treating and/or a mechanically compressing of the stack obtained in step e) in order to obtain an all-solid thin-film battery.
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/056 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
96.
SOLID-STATE BATTERY INCLUDING AN ELECTROLYTE MADE OF A CROSS-LINKED SOLID POLYMER MATERIAL
The invention relates to a method for manufacturing a thin-layer solid-state battery including the following consecutive steps: a) depositing a layer including at least one anode material on the conductive substrate thereof; b) depositing a layer including at least one cathode material on the conductive substrate thereof; c) depositing on at least one layer obtained in step a) and/or b) a layer including at least one solid electrolyte material having a thickness smaller than 10 µm, preferably smaller than 5 µm, and even more preferably smaller 2 µm, the solid electrolyte material including a cross-linked solid polymer material comprising ion groupings; d) consecutively stacking the following face-to-face: either a layer of anode material coated with a layer of solid electrolyte material obtained in step c) with a layer of cathode material optionally coated with a layer of solid electrolyte material obtained in step c), or a layer of cathode material coated with a layer of solid electrolyte material obtained in step c) with a layer of anode material optionally coated with a layer of solid electrolyte material obtained in step c); and e) performing a thermal treatment and/or a mechanical compression of the stack obtained in step d) in order to obtain a thin-layer solid-state battery.
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
97.
Method for the production of electrodes for fully solid batteries
R that preferably does not exceed 0.7 times the melting temperature (expressed in ° C.), even more preferably does not exceed 0.5 times the melting temperature (expressed in ° C.), and much more preferably does not exceed 0.3 times the melting temperature (expressed in ° C.) of the electrode material that melts at the lowest temperature.
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/13 - Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
98.
Method for producing dense thin films by electrophoresis
C25D 13/00 - Electrophoretic coating characterised by the process
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/1391 - Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
H01F 41/26 - Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates from liquids using electric currents
C25D 5/50 - After-treatment of electroplated surfaces by heat-treatment
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
A process for fabrication of all-solid-state thin film batteries, may include batteries including a film of anode materials, a film of solid electrolyte materials and a film of cathode materials. Each of these three films may be deposited using an electrophoresis process. The anode film and the cathode film may each be deposited on a conducting substrate, preferably a thin metal sheet or band, or a metalized insulating sheet or band or film. The conducting substrates or their conducting elements may be useable as battery current collectors, the electrolyte film may be deposited on the anode and/or cathode film. The process may also include stacking the sheets or bands so as to form at least one battery with a “collector/anode/electrolyte/cathode/collector” type of stacked structure.
H01M 10/0585 - Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
C25D 5/10 - Electroplating with more than one layer of the same or of different metals
C25D 15/00 - Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
H01M 4/485 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M 10/0564 - Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only