[Problem] To provide an excellent agricultural and horticultural plant disease control agent. [Solution] Provided is a nicotinamide derivative, or its salt, represented by general formula [I] [In the formula, Q denotes -NRaRbor the like, W denotes an oxygen atom or the like, Y denotes an oxygen atom or the like, A1denotes an oxygen atom or the like, A2denotes -CH- or a nitrogen atom, R1denotes a hydrogen atom or the like, R2and R316166 alkoxy group, or the like, L denotes L-1, L-2 or L-3, R5166 alkyl group or the like, R6denotes a hydrogen atom or the like, R7denotes a hydrogen atom or the like, R8166 alkoxy group, or the like, R9denotes a hydrogen atom or the like, Rxand Ryeach independently denote a hydrogen atom, a halogen atom, or the like, Rzdenotes a hydrogen atom or the like, and Raand Rb166 alkyl group, or the like], or a salt thereof. Also provided is an agricultural and horticultural plant disease control agent that contains this nicotinamide derivative, or its salt, as an active ingredient.
A01N 43/40 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
A01N 43/42 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
A01N 43/713 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
A01N 43/84 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
A01N 43/90 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
A01N 47/12 - Carbamic acid derivatives, i.e. containing the group —O—CO—NThio-analogues thereof containing a —O—CO—N group, or a thio-analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
A01N 55/08 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing boron
A61K 31/455 - Nicotinic acid, i.e. niacinDerivatives thereof, e.g. esters, amides
A61K 31/4709 - Non-condensed quinolines containing further heterocyclic rings
A61K 31/501 - PyridazinesHydrogenated pyridazines not condensed and containing further heterocyclic rings
A61K 31/506 - PyrimidinesHydrogenated pyrimidines, e.g. trimethoprim not condensed and containing further heterocyclic rings
A61K 31/5377 - 1,4-Oxazines, e.g. morpholine not condensed and containing further heterocyclic rings, e.g. timolol
A61K 31/539 - Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with at least one nitrogen and at least one oxygen as the ring hetero atoms, e.g. 1,2-oxazines having two or more oxygen atoms in the same ring, e.g dioxazines
A61P 31/00 - Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
C07D 401/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 405/12 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 405/14 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
C07D 409/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 413/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 417/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
The present invention provides an industrially preferable method for producing a sulfone derivative that is useful as a herbicide, and an intermediate thereof.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
3.
AQUEOUS SUSPENSION AGROCHEMICAL COMPOSITION, METHOD FOR PREVENTING CROP DAMAGE, AND USEFUL PLANT SEEDS
To provide an aqueous suspension agrochemical composition containing an agrochemical active ingredient, an oil which is a vegetable oil or a vegetable oil derivative, and water, a method for preventing crop damage in which the aqueous suspension agrochemical composition is applied to surfaces of seeds of a useful plant, and a seed of a useful plant treated with the aqueous suspension agrochemical composition.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The present invention provides heterocyclic compounds or salts thereof having excellent pest control effects, pest control agents containing the same as active ingredients, and production intermediates thereof.
The present invention provides heterocyclic compounds or salts thereof having excellent pest control effects, pest control agents containing the same as active ingredients, and production intermediates thereof.
The present invention provides heterocyclic compounds represented by the general formula [I]
The present invention provides heterocyclic compounds or salts thereof having excellent pest control effects, pest control agents containing the same as active ingredients, and production intermediates thereof.
The present invention provides heterocyclic compounds represented by the general formula [I]
The present invention provides heterocyclic compounds or salts thereof having excellent pest control effects, pest control agents containing the same as active ingredients, and production intermediates thereof.
The present invention provides heterocyclic compounds represented by the general formula [I]
(wherein, R1 represents a hydrogen atom, cyano group, or C1-C7 acyl group which is unsubstituted or substituted with a halogen atom, R2 represents a C1-C6 alkyl group, etc., each of A1 and A2 independently represents a nitrogen atom, CH or bond, either W1 or W2 represents a nitrogen atom, and the other represents a carbon atom, each of A3, A4, A5, A6, A7, A8, and A9 independently represents a nitrogen atom or a carbon atom substituted with R3, R4, R5, R6, R7, R8, and R9, respectively, each of R3, R4, R5, R6, R7, R8, and R9 represents hydrogen atoms, C1-C6 haloalkyl groups, etc., R10 represents a hydrogen atom, C1-C12 alkyl group, C1-C6 alkoxy C1-C6 alkyl group, C1-C12 haloalkyl group, etc., and R11 represents a halogen atom, azido group, cyano group, etc.) or pesticide-acceptable salts thereof, and pest control agents characterized by containing the same as active ingredients.
The present invention provides a compound of formula (2), and use thereof. The compound of formula (2) is useful as a pest control agent. The compound of formula (2) is also useful as a herbicide, particularly as a production intermediate of pyroxasulfone.
The present invention provides a compound of formula (2), and use thereof. The compound of formula (2) is useful as a pest control agent. The compound of formula (2) is also useful as a herbicide, particularly as a production intermediate of pyroxasulfone.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 403/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
6.
AGRICULTURAL AND HORTICULTURAL INSECT PEST CONTROL AGENT AND INSECT PEST CONTROL METHOD USING SAME
Provided is an agricultural and horticultural insect pest control agent exhibiting excellent controlling effect on agricultural insect pests including sap-sucking pests, e.g., Hemiptera pests typified by whiteflies and aphids and Thrips pests, and Lepidoptera pests. Also provided is an insect pest control method for useful plants using the agricultural and horticultural insect pest control agent. The agricultural and horticultural insect pest control agent contains, as an active ingredient, a compound having plant disease resistance-inducing activity, such as probenazole, isotianil, dichlobentiazox, tiadinil or acibenzolar-S-methyl. The insect pest control method is for controlling insect pests of useful plants, particularly for controlling agricultural insect pests such as sap-sucking pests and Lepidoptera pests, using the agricultural and horticultural insect pest control agent.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The purpose of the present invention is to provide an excellent agricultural or horticultural plant disease control agent. Provided are: a formamide derivative represented by general formula [I] and the like (in the formula, X1, X2, X3, and X4 each independently represents a carbon atom and the like, Y represents an oxygen atom or a sulfur atom, R1 represents a halogen atom, and R2 represents a hydrogen atom, a C1-C6 alkyl group, and the like) or an agriculturally acceptable salt thereof; and an agricultural or horticultural plant disease control agent containing the same as an active ingredient.
The purpose of the present invention is to provide an excellent agricultural or horticultural plant disease control agent. Provided are: a formamide derivative represented by general formula [I] and the like (in the formula, X1, X2, X3, and X4 each independently represents a carbon atom and the like, Y represents an oxygen atom or a sulfur atom, R1 represents a halogen atom, and R2 represents a hydrogen atom, a C1-C6 alkyl group, and the like) or an agriculturally acceptable salt thereof; and an agricultural or horticultural plant disease control agent containing the same as an active ingredient.
A01N 43/82 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with three hetero atoms
A01N 37/52 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
C07C 259/18 - Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups with replacement of the other oxygen atom of the carboxyl group by nitrogen atoms, e.g. N-hydroxyamidines having carbon atoms of hydroxyamidine groups bound to carbon atoms of six-membered aromatic rings
The present invention provides an industrially preferred method for producing a sulfone derivative that is useful as an herbicide. This process is for producing a compound of the formula (2). In the method, a compound of the formula (1) is reacted with an oxidizer in the presence of a metal catalyst and the presence of a carboxylic acid to produce the compound of the formula (2).
The present invention provides an industrially preferred method for producing a sulfone derivative that is useful as an herbicide. This process is for producing a compound of the formula (2). In the method, a compound of the formula (1) is reacted with an oxidizer in the presence of a metal catalyst and the presence of a carboxylic acid to produce the compound of the formula (2).
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Preparations for destroying vermin, fungicides, herbicides; herbicides for agricultural purposes; fungicides for agricultural purposes; insecticides for agricultural purposes; antiseptics for agricultural purposes; rat poison for agricultural purposes; fumigants for agricultural purposes
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
(1) Pharmaceutical preparations and other preparations for destroying vermin, fungicides, herbicides; herbicides for agricultural purposes; fungicides for agricultural purposes; insecticides for agricultural purposes; antiseptics for agricultural purposes; rat poison for agricultural purposes; fumigants for agricultural purposes; preparations for destroying vermin.
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
(1) Pharmaceutical preparations and other preparations for destroying vermin, fungicides, herbicides; herbicides for agricultural purposes; fungicides for agricultural purposes; insecticides for agricultural purposes; antiseptics for agricultural purposes; rat poison for agricultural purposes; fumigants for agricultural purposes; preparations for destroying vermin.
12.
PYRAZOLE-4-CARBOXAMIDE COMPOUND AND AGRICULTURAL OR HORTICULTURAL PLANT DISEASE CONTROL AGENT USING SAME
[Problem] To provide an excellent agricultural or horticultural plant disease control agent. [Solution] Provided are: a pyrazole-4-carboxamide compound represented by general formula [I] [in the formula, T represents an oxygen atom or a sulfur atom, R1166 alkyl group or the like, R2166 alkyl group or the like, R51661212 aryl group or the like], or a salt thereof; and an agricultural or horticultural plant disease control agent containing the same as an active ingredient.
C07D 231/14 - Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 47/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
A01N 47/30 - Derivatives containing the group N—CO—N—aryl or N—CS—N—aryl
A01N 55/10 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing silicon
A01P 1/00 - DisinfectantsAntimicrobial compounds or mixtures thereof
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 401/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 403/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 405/04 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 405/12 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 409/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 413/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
13.
Pyrazole derivative and harmful organism-controlling agent
Embodiments provide a pest control agent that is excellent in safety, controlling effect, residual activity, and so on. According to an embodiment, there is provided a pyrazole derivative represented by general formula [II] or an agriculturally acceptable salt thereof:
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
A01N 25/30 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
The present invention provides a plant disease control composition capable of exhibiting an excellent control effect on plant diseases, and a method for controlling a disease of a useful plant using the composition. Provided are: a plant disease control composition containing, as active ingredients, ingredient (A) selected from the group consisting of a formamide derivative represented by general formula [I] and an agriculturally acceptable salt thereof, and ingredient (B) selected from disease-control active ingredients; and a method for controlling a disease of a useful plant using the composition.
A01N 37/24 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N, e.g. carboxylic acid amides or imidesThio-analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
A01N 37/32 - Cyclic imides of polybasic carboxylic acids or thio-analogues thereof
A01N 37/50 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio-analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio-analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
A01N 43/32 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atom with two or more hetero atoms six-membered rings
A01N 43/40 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
A01N 43/84 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
A01N 43/88 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with three ring hetero atoms
A01N 43/90 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
A01N 47/00 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
A01N 47/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
A01N 47/04 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing N—S—C≡Hal3 groups
A01N 47/06 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groupsThio-analogues thereof
A01N 47/12 - Carbamic acid derivatives, i.e. containing the group —O—CO—NThio-analogues thereof containing a —O—CO—N group, or a thio-analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
A01N 47/24 - Carbamic acid derivatives, i.e. containing the group —O—CO—NThio-analogues thereof containing the groups , or Thio-analogues thereof
A01N 47/28 - Ureas or thioureas containing the groups N—CO—N or N—CS—N
A01N 47/30 - Derivatives containing the group N—CO—N—aryl or N—CS—N—aryl
A01N 47/38 - Ureas or thioureas containing the groups N—CO—N or N—CS—N containing the group N—CO—N where at least one nitrogen atom is part of a heterocyclic ringThio-analogues thereof
A01N 55/08 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing boron
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
15.
LYSINIBACILLUS BACTERIAL STRAIN THAT PROMOTES PLANT GROWTH, AND USE THEREOF
NATIONAL UNIVERSITY CORPORATION TOKAI NATIONAL HIGHER EDUCATION AND RESEARCH SYSTEM (Japan)
Kumiai Chemical Industry Co., Ltd. (Japan)
Inventor
Shimizu, Masafumi
Furuse, Katsumi
Abstract
A naturally derived, safe-to-use microbial material that can contribute to increasing agricultural production by promoting crop growth and increasing yield, while controlling plant disease at the same time. Viable bacteria of a novel bacterial strain of genus Lysinibacillus, or a culture containing the viable bacteria, are used as an active component. The novel bacterial strain may be Lysinibacilus xylanilyticus GIC41 (NITE BP-03464). A plant growth regulator contains the bacterial strain and promotes crop growth and increases yield. A plant disease control agent that contains the bacterial strain is capable of controlling a disease, such as by damping-off.
A more effective weed control method is provided for a case where soil treatment with pyroxasulfone is carried out. The present invention provides a weed control method in which treatment with columnar crystals of pyroxasulfone is carried out for soil with a composition having a clay content of less than 15% and a sand content of not less than 65%.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The present invention provides an industrially desirable production method for a sulfone derivative that is useful as a herbicide, and an intermediate thereof.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
A more effective weed control method is provided for a case where soil treatment with pyroxasulfone is carried out. The present invention provides a weed control method in which treatment with needle crystals of pyroxasulfone is carried out for soil with a composition having a clay content of not less than 15% or a sand content of less than 65%.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The present invention provides an industrially preferable method for producing a sulfone derivative that is useful as a herbicide, and an intermediate thereof.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
20.
PLANT GROWTH REGULATING AGENT CONTAINING VIABLE CELLS OR CULTURE OF BACILLUS-GENUS STRAIN AS ACTIVE INGREDIENT, AND USAGE METHOD THEREFOR
[Problem] The purpose of the present invention is to provide a microbial material that is naturally derived, can be safely used, and can contribute to the improvement of agricultural production quantity by increasing yield through regulating the growth of crops and imparting resistance to environmental stress, while simultaneously preventing plant disease. [Solution] The present invention makes it possible to provide: a plant growth regulating agent that, by comprising viable cells of a specific strain belonging to the Bacillus genus, or a culture including the viable cells, as an active ingredient, increases yield by regulating the growth of crops and imparting resistance to environmental stress; and/or a plant disease prevention agent and the like. Selected drawing: none
A01N 63/00 - Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Pharmaceutical preparations and other preparations for destroying vermin, fungicides, herbicides; herbicides for agricultural purposes; fungicides for agricultural purposes; insecticides for agricultural purposes; antiseptics for agricultural purposes; rat poison for agricultural purposes; fumigants for agricultural purposes; preparations for destroying vermin
01 - Chemical and biological materials for industrial, scientific and agricultural use
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Agricultural chemicals, except fungicides, herbicides,
insecticides and parasiticides; chemical intermediates for
use in the manufacture of agricultural chemicals; active
chemical ingredients for use in the manufacture of
acaricides, insecticides, fungicides and herbicides. Acaricides; insecticides; fungicides; herbicides.
01 - Chemical and biological materials for industrial, scientific and agricultural use
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Agricultural chemicals, except fungicides, herbicides,
insecticides and parasiticides; chemical intermediates for
use in the manufacture of agricultural chemicals; active
chemical ingredients for use in the manufacture of
acaricides, insecticides, fungicides and herbicides. Acaricides; insecticides; fungicides; herbicides.
24.
NUCLEIC ACID THAT INTERACTS WITH A RECEPTOR FOR ENDOCRINE DISRUPTING CHEMICALS AND USE THEREOF
This invention provides a nucleic acid that enables evaluation of various endocrine disrupting actions of a very small amount of endocrine disrupting chemicals with high sensitivity. Such nucleic acid comprises a total of 20 to 60 nucleotides comprising the nucleotide sequence shown in SEQ ID NO: 1 and shows excellent responsiveness to various endocrine disrupting chemicals.
C12N 15/113 - Non-coding nucleic acids modulating the expression of genes, e.g. antisense oligonucleotides
C07K 14/435 - Peptides having more than 20 amino acidsGastrinsSomatostatinsMelanotropinsDerivatives thereof from animalsPeptides having more than 20 amino acidsGastrinsSomatostatinsMelanotropinsDerivatives thereof from humans
C07K 14/72 - ReceptorsCell surface antigensCell surface determinants for hormones
C12N 15/81 - Vectors or expression systems specially adapted for eukaryotic hosts for fungi for yeasts
Metabolic activity is exhibited against a larger number of compounds having different acting properties. A cytochrome P450 gene encodes a protein having an amino acid sequence of any of SEQ ID NOS: 2, 4, 6, and 8.
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
raw materials in the manufacture of artificial resins, namely, amine compounds, including diamines, as curing agents for producing synthetic resins and artificial isocyanate compounds including polyisocyanate compounds, for producing synthetic resins
01 - Chemical and biological materials for industrial, scientific and agricultural use
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Agricultural chemicals, except fungicides, herbicides, insecticides and parasiticides; chemical intermediates for use in the manufacture of agricultural chemicals; active chemical ingredients for use in the manufacture of acaricides, insecticides, fungicides and herbicides Acaricides; insecticides; fungicides; herbicides
01 - Chemical and biological materials for industrial, scientific and agricultural use
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Agricultural chemicals, except fungicides, herbicides, insecticides and parasiticides; chemical intermediates for use in the manufacture of agricultural chemicals; active chemical ingredients for use in the manufacture of acaricides, insecticides, fungicides and herbicides Acaricides; insecticides; fungicides; herbicides
29.
BACTERIAL STRAIN BELONGING TO BACILLUS GENUS, AND MICROBIOLOGICAL CONTROL AGENT USING SAID BACTERIAL STRAIN
NATIONAL UNIVERSITY CORPORATION TOKAI NATIONAL HIGHER EDUCATION AND RESEARCH SYSTEM (Japan)
Kumiai Chemical Industry Co., Ltd. (Japan)
Inventor
Shimizu, Masafumi
Kaneko, Isao
Ohtaka, Nobuaki
Maruyama, Nozomu
Abstract
A soil-borne plant disease control agent that can be safely used as a biopesticide. The active component of the control agent includes viable bacteria of novel strains of Bacillus and Fictibacillus, or a culture of these bacteria. The soil-borne plant disease control agent is a vegetable wilt control agent. The plant disease control agent can be applied (sprayed) to stems and leaves to control a bacterial wilt disease caused by soil bacteria Ralstonia solanacearum species complex, and/or bacterial soft rots. A plant disease control method.
The present invention provides a novel fused heterocyclic derivative or an agriculturally acceptable salt thereof, and an herbicide containing the same as an active ingredient. Provided are a fused heterocyclic derivative represented by general formula [I] (in general formula [I], Q represents Q-1, Q-2 or Q-3, R6166 haloalkyl group or a cyano group, etc., A1represents N or C-R7, and R7 represents a hydrogen atom, a halogen atom or a cyano group) or a salt thereof, and an herbicide characterized by containing the same as an active ingredient.
C07D 401/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 401/14 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
C07D 403/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 403/14 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
C07D 413/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 413/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 417/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
A01N 43/84 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
A01N 43/86 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
A01N 25/30 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
A01N 47/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
01 - Chemical and biological materials for industrial, scientific and agricultural use
Goods & Services
raw materials in the manufacture of artificial resins, namely, amine compounds, including diamines, as curing agents for producing synthetic resins and artificial isocyanate compounds including polyisocyanate compounds, for producing synthetic resins; chemical intermediates and active chemical ingredients for use in the manufacturing of pharmaceuticals and agricultural chemicals
32.
Methane-production inhibitor composition and method for inhibiting methane production
Provided are a methane-production inhibitor capable of inhibiting methane production for a long period of time, and a method for inhibiting methane production using the composition. A methane-production inhibitor composition contains one or more compounds selected from compounds represented by formula [I] as an effective ingredient, and a method for inhibiting methane production uses the composition.
3 represents a chloromethyl group or a hydroxymethyl group.)
C07C 317/22 - SulfonesSulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
C07C 309/65 - Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
C07C 309/68 - Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a carbon skeleton substituted by singly-bound oxygen atoms
A23K 50/10 - Feeding-stuffs specially adapted for particular animals for ruminants
An aqueous agrochemical suspension composition containing: an agrochemical active ingredient, a plant oil or an oil that is a plant oil derivative, and water, a method for preventing crop damage by treating the surface of a seed of a useful plant with the aqueous agrochemical suspension composition, and a seed of a useful plant treated with the aqueous agrochemical suspension composition.
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A compound of formula (2) and use thereof. The compound of formula (2) is useful as a pest control agent. The compound of formula (2) is also useful as a herbicide, especially as a production intermediate of pyroxasulfone.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
35.
AQUEOUS SUSPENSION AGROCHEMICAL COMPOSITION, METHOD FOR PREVENTING CROP DAMAGE, AND USEFUL PLANT SEEDS
An aqueous agrochemical suspension composition containing: an agrochemical active ingredient, a plant oil or an oil that is a plant oil derivative, and water, a method for preventing crop damage by treating the surface of a seed of a useful plant with the aqueous agrochemical suspension composition, and a seed of a useful plant treated with the aqueous agrochemical suspension composition.
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
An aqueous agrochemical suspension composition containing: dichlobentiazox, a plant oil or an oil that is a plant oil derivative, and water, a method for controlling plant disease by treating the surface of a seed of a useful plant with the aqueous agrochemical suspension composition, and a seed of a useful plant treated with the aqueous agrochemical suspension composition.
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
An aqueous agrochemical suspension composition containing: dichlobentiazox, a plant oil or an oil that is a plant oil derivative, and water, a method for controlling plant disease by treating the surface of a seed of a useful plant with the aqueous agrochemical suspension composition, and a seed of a useful plant treated with the aqueous agrochemical suspension composition.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
C07C 319/20 - Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
The present invention provides: a 3-alkoxybenzamide derivative having an excellent pest control effect, or a salt thereof; and a pest control agent and a production intermediate which contain the same as an active ingredient.
The present invention provides: a 3-alkoxybenzamide derivative having an excellent pest control effect, or a salt thereof; and a pest control agent and a production intermediate which contain the same as an active ingredient.
Provided are: a 3-alkoxybenzamide derivative represented by general formula [I]
The present invention provides: a 3-alkoxybenzamide derivative having an excellent pest control effect, or a salt thereof; and a pest control agent and a production intermediate which contain the same as an active ingredient.
Provided are: a 3-alkoxybenzamide derivative represented by general formula [I]
The present invention provides: a 3-alkoxybenzamide derivative having an excellent pest control effect, or a salt thereof; and a pest control agent and a production intermediate which contain the same as an active ingredient.
Provided are: a 3-alkoxybenzamide derivative represented by general formula [I]
[In the formula, A represents an oxygen atom or a sulfur atom, G represents a hydrogen atom, a halogen atom, or a C1-C6 alkyl group, le represents a C1-C6 alkyl group, a C3-C6 cycloalkyl group, etc., R2 represents a hydrogen atom, etc., R3 represents a halogen atom, C1-C6 alkyl group, etc., R4 represents a halogen atom, C1-C6 alkyl group, etc., and R5 represents a C1-C12 alkyl group, etc.], or a salt thereof; and a pest control agent characterized by containing said derivative or salt thereof as an active ingredient.
A01N 37/18 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N, e.g. carboxylic acid amides or imidesThio-analogues thereof
A01N 25/30 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
The present invention addresses the problem of providing an industrially preferable method for producing an aldehyde represented by formula (3) or (4): (3) (4). The present invention produces a compound of formula (3) or compound of formula (4) by causing a corresponding compound of formula (1) or compound of formula (2) to undergo, in the presence of a metal catalyst, nitric acid, oxygen, and a nitroxyl radical compound, reaction represented by the following reaction formulae. The present invention further addresses the problem of providing an industrially preferable method for producing a dihydroisoxazole represented by formula (7): (7). The obtained compound of formula (3) or compound of formula (4) is subjected to an oximation step and a cyclization step to produce the compound of formula (7).
C07C 45/29 - Preparation of compounds having C=O groups bound only to carbon or hydrogen atomsPreparation of chelates of such compounds by oxidation of hydroxy groups
C07C 47/198 - Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing ether groups, groups, groups, or groups
C07D 261/04 - Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
A method for producing a compound of a formula (3), including reacting a compound of a formula (1) with a compound of a formula (2) by using a tertiary alcohol and a base:
9 are each independently a hydrogen atom, a halogen atom, a (C1-C4)alkyl, or a (C1-C4)alkoxy, the amount of the base used is 2.0-4.0 equivalents per 1 equivalent of the compound of formula (2), the amount of the tertiary alcohol used is 0.3-2.5 equivalents per 1 equivalent of the compound of formula (2), the base is a plurality of compounds comprising a lithium-containing base as a first compound, and a second compound selected from the group consisting of alkali metal hydrides, alkali metal amides, alkoxides, alkyl metals, alkali metals, and organic bases, and the reaction is performed in the presence of an aromatic hydrocarbon solvent.
C07D 241/44 - Benzopyrazines with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
C07C 213/08 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions not involving the formation of amino groups, hydroxy groups or etherified or esterified hydroxy groups
46.
FORMAMIDE DERIVATIVE AND AGRICULTURAL OR HORTICULTURAL PLANT DISEASE CONTROL AGENT
The purpose of the present invention is to provide an excellent agricultural or horticultural plant disease control agent. Provided are: a formamide derivative represented by general formula [I] and the like (in the formula, X1, X2, X3, and X4each independently represents a carbon atom and the like, Y represents an oxygen atom or a sulfur atom, R1represents a halogen atom, and R2166 alkyl group, and the like) or an agriculturally acceptable salt thereof; and an agricultural or horticultural plant disease control agent containing the same as an active ingredient.
C07C 259/18 - Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups with replacement of the other oxygen atom of the carboxyl group by nitrogen atoms, e.g. N-hydroxyamidines having carbon atoms of hydroxyamidine groups bound to carbon atoms of six-membered aromatic rings
C07D 413/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
47.
PROCESS FOR PRODUCING HERBICIDE AND INTERMEDIATE THEREOF
The present invention provides industrially preferable processes for producing a sulfone derivative useful as a herbicide and an intermediate thereof. Provided are a process for producing a compound of the formula (4), comprising the following step ii:
(step ii) a step of reacting a compound of the formula (2) with a compound of the formula (3) in the presence of a base to produce the compound of the formula (4), and
The present invention provides industrially preferable processes for producing a sulfone derivative useful as a herbicide and an intermediate thereof. Provided are a process for producing a compound of the formula (4), comprising the following step ii:
(step ii) a step of reacting a compound of the formula (2) with a compound of the formula (3) in the presence of a base to produce the compound of the formula (4), and
a process for producing a compound of the formula (5), comprising the following step iii:
(step iii) a step of reacting the compound of the formula (4) with hydrogen peroxide in the presence of a metal catalyst to produce the compound of the formula (5).
The present invention provides industrially preferable processes for producing a sulfone derivative useful as a herbicide and an intermediate thereof. Provided are a process for producing a compound of the formula (4), comprising the following step ii:
(step ii) a step of reacting a compound of the formula (2) with a compound of the formula (3) in the presence of a base to produce the compound of the formula (4), and
a process for producing a compound of the formula (5), comprising the following step iii:
(step iii) a step of reacting the compound of the formula (4) with hydrogen peroxide in the presence of a metal catalyst to produce the compound of the formula (5).
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
48.
WEED CONTROL METHOD AND MIXED AGROCHEMICAL COMPOSITION FOR SOIL TREATMENT
The present invention is aimed at providing a weed control method and a mixed agrochemical composition for soil treatment, which, in a soil treatment of farmland with pyroxasulfone, not only can inhibit or reduce crop injury caused by absorption into cultivated crops, without being influenced by heavy rainfall, soil type, seeding depth and the like, but also are effective against a wide range of weed species. The weed control method includes a soil treatment step of performing a soil treatment on farmland with an agrochemical composition for soil treatment, which contains pyroxasulfone, and with a protoporphyrinogen oxidase inhibitor, simultaneously or sequentially, the method being characterized in that the agrochemical composition for soil treatment further contains a masking substance that masks the pyroxasulfone, and the pyroxasulfone is microencapsulated in or coated with the masking substance. The mixed agrochemical composition for soil treatment is characterized by containing the agrochemical composition for soil treatment and a protoporphyrinogen oxidase inhibitor.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 43/84 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
NATIONAL UNIVERSITY CORPORATION TOKAI NATIONAL HIGHER EDUCATION AND RESEARCH SYSTEM (Japan)
Inventor
Shimizu, Masafumi
Furuse, Katsumi
Abstract
[Problem] To provide a microbial material that can promote crop growth to increase the yield and, at the same time, control plant diseases to thereby contribute to improvement in agricultural production, and that is naturally derived and can be used safely. [Solution] By using, as an active ingredient, viable cells of a novel strain belonging to the genus Lysinibacillus or a culture containing the viable cells, a plant growth regulating agent, which can promote crop growth to increase the yield, and/or a plant disease control agent, which can control diseases such as damping-off, etc., can be provided.
A01M 17/00 - Apparatus for the destruction of vermin in soil or in foodstuffs
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
NATIONAL UNIVERSITY CORPORATION TOKAI NATIONAL HIGHER EDUCATION AND RESEARCH SYSTEM (Japan)
KUMIAI CHEMICAL INDUSTRY CO., LTD. (Japan)
Inventor
Shimizu, Masafumi
Furuse, Katsumi
Abstract
[Problem] To provide a microbial material that can promote crop growth to increase the yield and, at the same time, control plant diseases to thereby contribute to improvement in agricultural production, and that is naturally derived and can be used safely. [Solution] By using, as an active ingredient, viable cells of a novel strain belonging to the genus Lysinibacillus or a culture containing the viable cells, a plant growth regulating agent, which can promote crop growth to increase the yield, and/or a plant disease control agent, which can control diseases such as damping-off, etc., can be provided.
A01M 17/00 - Apparatus for the destruction of vermin in soil or in foodstuffs
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
The present invention is aimed at providing: an agrochemical composition for soil treatment which, in a soil treatment of farmland with pyroxasulfone, not only can inhibit or reduce crop injury caused by absorption into cultivated crops, without being influenced by heavy rainfall, soil type, seeding depth and the like, but also is highly safe and has a broad herbicidal spectrum; and a pest control method using the agrochemical composition. The agrochemical composition for soil treatment contains pyroxasulfone and a masking substance that masks the pyroxasulfone, in which the pyroxasulfone is microencapsulated in or coated with the masking substance.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
01 - Chemical and biological materials for industrial, scientific and agricultural use
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Agricultural chemicals, except fungicides, herbicides, insecticides and parasiticides; Chemicals for use in the manufacture of agricultural chemicals; Chemicals used as active ingredients of acaricides, insecticides, fungicides and herbicides. Acaricides, insecticides, fungicides, herbicides.
01 - Chemical and biological materials for industrial, scientific and agricultural use
05 - Pharmaceutical, veterinary and sanitary products
Goods & Services
Agricultural chemicals, except fungicides, herbicides, insecticides and parasiticides; Chemicals for use in the manufacture of agricultural chemicals; Active ingredient chemicals for use in the manufacture of acaricides, insecticides, fungicides and herbicides Acaricides, insecticides, fungicides, herbicides
The present invention provides: a heterocyclic compound or salt thereof having an excellent pest controlling effect; and a pest control agent and a production intermediate that contain the heterocyclic compound as an active ingredient. Provided are: a heterocyclic compound represented by general formula [I] [In the formula, R1177 acyl group that is unsubstituted or substituted with a halogen atom, R2166 alkyl group or the like, A1and A2each independently denote a nitrogen atom, CH or a bond, one of W1and W2denotes a hydrogen atom, with the other being a carbon atom, A3, A4, A5, A6, A7, A8and A9each independently denote a nitrogen atom or a carbon atom substituted with R3, R4, R5, R6, R7, R8and R9respectively, R3, R4, R5, R6, R7, R8and R9166 haloalkyl group, or the like, and R10112161611212 haloalkyl group, or the like], or an agrochemically acceptable salt thereof; and a pest control agent characterized by containing the same as an active ingredient.
A01N 43/90 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
A01N 47/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
55.
METHOD FOR PRODUCING SULFONE DERIVATIVE AS HERBICIDE
The present invention provides an industrially preferred method for producing a sulfone derivative that is useful as an herbicide. This method is for producing a compound of formula (2). In the method, a compound of formula (1) is reacted with an oxidizer in the presence of a metal catalyst and the presence of a carboxylic acid to produce the compound of formula (2).
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
56.
METHOD FOR PRODUCING SULFONE DERIVATIVE AS HERBICIDE
The present invention provides an industrially preferred method for producing a sulfone derivative that is useful as an herbicide. This method is for producing a compound of formula (2). In the method, a compound of formula (1) is reacted with an oxidizer in the presence of a metal catalyst and the presence of a carboxylic acid to produce the compound of formula (2).
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
Gene involved in synthesis of cyclic peptide compound, method for producing cyclic peptide compound using the same, and transformant comprising the same
A more effective weed control method is provided for a case where soil treatment with pyroxasulfone is carried out. The present invention provides a weed control method in which treatment with columnar crystals of pyroxasulfone is carried out for soil with a composition having a clay content of less than 15% and a sand content of not less than 65%.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A more effective weed control method is provided for a case where soil treatment with pyroxasulfone is carried out. The present invention provides a weed control method in which treatment with needle crystals of pyroxasulfone is carried out for soil with a composition having a clay content of not less than 15% or a sand content of less than 65%.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Provided is a method for more effectively controlling weeds in the case in which soil is treated by using pyroxasulfone. The present invention provides a method for controlling weeds, the method employing pyroxasulfone in an acicular crystal form to treat soil having a composition in which the clay content is at least 15% or the sand content is less than 65%.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Provided is a method for controlling weeds more effectively when applying pyroxasulfone in a soil treatment. The present invention is, inter alia, a method for controlling weeds by applying columnar-crystal pyroxasulfone to soil having a composition comprising less than 15% clay and 65% or more sand.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The present invention provides an industrially desirable production method for a sulfone derivative that is useful as a herbicide, and an intermediate thereof.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
The present invention provides an industrially desirable production method for a sulfone derivative that is useful as a herbicide, and an intermediate thereof.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
The present invention provides an industrially desirable production method for a sulfone derivative that is useful as a herbicide, and an intermediate thereof.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
65.
AZETIDINONE DERIVATIVE AND HERBICIDE CONTAINING SAME AS ACTIVE INGREDIENT
The present invention provides: a novel azetidinone derivative having excellent herbicidal activity, or a salt thereof; an herbicide containing the same as an active ingredient; and a production intermediate. Provided are: an azetidinone derivative represented by general formula [I] [in the formula, Q1366 cycloalkyl group which is unsubstituted, or mono- or poly-substituted with a substituent selected from a substituent group α, a phenyl group which is unsubstituted, or mono- or poly-substituted with a substituent selected from the substituent group α, or the like, Q21616366 cycloalkyl group, or the like, Y1and Y2each independently represent an oxygen atom or a sulfur atom, R116166 haloalkyl group, or the like, R2and R4166 alkyl group, R316366 cycloalkyl group, or the like, the substituent group α represents a halogen atom, a nitro group, a cyano group, or the like, and a substituent group β represents a halogen atom, a nitro group, a cyano group, or the like] or a salt thereof; and an herbicide characterized by containing the same as an active ingredient.
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 401/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 401/14 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 403/10 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 403/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 403/14 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
C07D 405/04 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 405/10 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 405/12 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 405/14 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
C07D 409/04 - Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 409/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 411/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 205/06 - Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
C07D 205/08 - Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with one oxygen atom directly attached in position 2, e.g. beta-lactams
A01N 43/40 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
A01N 43/44 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom three- or four-membered rings
A01N 43/713 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 47/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
A01N 47/04 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing N—S—C≡Hal3 groups
66.
Aqueous agrochemical suspension composition and method for spraying same
An object of the present invention is to provide: an aqueous suspension agrochemical composition having a good storage stability, with which an increase in the viscosity of a formulation can be inhibited even when the composition contains a high concentration of pyroxasulfone; and a process of spraying the same. The present invention provides: an aqueous suspension agrochemical composition containing: pyroxasulfone; an acrylic graft copolymer; an alcohol alkoxylate; and a lignin sulfonate, in which composition the alcohol alkoxylate contains a polyoxyethylene alkyl ether; and a process of spraying an aqueous suspension agrochemical composition, the process including spraying the above-described aqueous suspension agrochemical composition to a field where agricultural/horticultural plants grow.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 25/30 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
The present invention provides a novel fused heterocycle derivative or an agriculturally acceptable salt thereof and an herbicide containing the same as an active ingredient. Provided are a fused heterocycle derivative represented by general formula [I] (in general formula [I], Q represents Q-1, Q-2, Q-3, Q-4, Q-5, Q-6, Q-7, or Q-8, R7166 haloalkyl group, a cyano group, etc., Z represents an oxygen atom or a sulfur atom, A represents N or C-R13, R13 represents a hydrogen atom, a halogen atom, or a cyano group) or a salt thereof and an herbicide characterized by containing the same as an active ingredient.
C07D 401/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 403/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 403/14 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 413/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 417/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 47/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.
C12N 15/70 - Vectors or expression systems specially adapted for E. coli
C12N 15/75 - Vectors or expression systems specially adapted for prokaryotic hosts other than E. coli, e.g. Lactobacillus, Micromonospora for Bacillus
C12N 15/77 - Vectors or expression systems specially adapted for prokaryotic hosts other than E. coli, e.g. Lactobacillus, Micromonospora for CorynebacteriumVectors or expression systems specially adapted for prokaryotic hosts other than E. coli, e.g. Lactobacillus, Micromonospora for Brevibacterium
C12N 15/78 - Vectors or expression systems specially adapted for prokaryotic hosts other than E. coli, e.g. Lactobacillus, Micromonospora for Pseudomonas
C12N 15/81 - Vectors or expression systems specially adapted for eukaryotic hosts for fungi for yeasts
C12P 21/02 - Preparation of peptides or proteins having a known sequence of two or more amino acids, e.g. glutathione
The present invention provides: a method having a high effect on the efficiently controlling diseases in small grain cereals, in particular, powdery mildew, leaf rust, leaf blotch, and eyespot disease; a method for suppressing lodging damage in small grain cereals; and seed of small grain cereals. A method for controlling diseases in small grain cereals, a method for suppressing lodging damage in small grain cereals, and seed of small grain cereals, in which seed of small grain cereals is treated with one or more types selected from a dichloroisothiazole compound or a salt thereof, are provided.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 25/32 - Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
The present invention exhibits metabolic activity against many compounds having different actions. A cytochrome P450 gene encoding a protein having an amino acid sequence of SEQ ID NO: 2, 4, 6, or 8.
The present invention exhibits metabolic activity against many compounds having different actions. A cytochrome P450 gene encoding a protein having an amino acid sequence of SEQ ID NO: 2, 4, 6, or 8.
The present invention aims to provide a microcapsule composition that enables reduction or prevention of injury of useful plants caused by pyroxasulfone, a production method therefor, an agrochemical formulation containing the same, and a weed control method. A microcapsule composition including pyroxasulfone and a polyester block copolymer encapsulated therein, an agrochemical formulation containing the same, and a weed control method are provided. A method of producing the microcapsule composition, the method including: an emulsifying dispersion step of performing high-speed stirring of pyroxasulfone crystal particles, a polyester block copolymer, isocyanate, oily phase, and aqueous phase at a peripheral speed of 10,000 to 50,000 mm/s to allow emulsifying dispersion of the oily phase in the aqueous phase, to form emulsion particles of the oily phase; and a membrane formation step of forming a membrane on at least the surface of the emulsion particles of the oily phase formed by the emulsifying dispersion step; is also provided.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The invention is intended to identify glutathione-S-transferase that exhibits the activities to metabolize and detoxify an isoxazoline derivative, such as pyroxasulfone. The invention provides a method for cultivating a transgenic plant into Which a nucleic acid encoding a protein (a or b) below has been introduced in the presence of isoxazoline derivatives:
(a) a protein comprising the amino acid sequence as shown in SEQ ID NO: 2; or
(b) a protein comprising an amino acid sequence having 80% or higher identity to the amino acid sequence as shown in SEQ ID NO: 2 and having the activity of glutathione-S-transferase.
C07K 14/415 - Peptides having more than 20 amino acidsGastrinsSomatostatinsMelanotropinsDerivatives thereof from plants
C12N 15/82 - Vectors or expression systems specially adapted for eukaryotic hosts for plant cells
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
75.
MICROCAPSULE COMPOSITION, METHOD FOR MANUFACTURING SAME, AGROCHEMICAL FORMULATION COMPRISING SAME AND WEED CONTROL METHOD
The present invention aims to provide a microcapsule composition that enables reduction or prevention of injury of useful plants caused by pyroxasulfone, a production method therefor, an agrochemical formulation containing the same, and a weed control method. A method of producing a microcapsule composition containing pyroxasulfone encapsulated therein, the method including: an emulsifying dispersion step of performing high-speed stirring of pyroxasulfone crystal particles, isocyanate, oily phase, and aqueous phase at a peripheral speed of 6.000 to 30,000 mm/s to allow emulsifying dispersion of the oily phase in the aqueous phase, to form emulsion particles of the oily phase; and a film formation step of forming a film on at least the surface of the emulsion particles of the oily phase formed by the emulsifying dispersion step; and the like are provided.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
NATIONAL UNIVERSITY CORPORATION TOKAI NATIONAL HIGHER EDUCATION AND RESEARCH SYSTEM (Japan)
Inventor
Shimizu, Masafumi
Kaneko, Isao
Ohtaka, Nobuaki
Maruyama, Nozomu
Abstract
Abstract:?Problem: To provide a soil-transmissible plant disease control agent or similar that can safely be used as a biological control agent.?Solution: A soil-transmissible plant disease control agent or similar, such as a vegetable bacterial wilt control agent, can be provided by using, as an active ingredient, live bacterial cells of a novel strain of a bacterium of the Bacillus or Fictibacillus genus with a heretofore unknown soil-transmissible plant disease controlling action, or a cultured product including said live bacterial cells. This control agent is characterized by being able, through a foliage application treatment, to control bacterial wilt and/or bacterial soft rot caused by the Ralstonia solanacearum species complex, which are soil-borne bacteria.?Selected drawing: none
NATIONAL UNIVERSITY CORPORATION TOKAI NATIONAL HIGHER EDUCATION AND RESEARCH SYSTEM (Japan)
KUMIAI CHEMICAL INDUSTRY CO., LTD. (Japan)
Inventor
Shimizu, Masafumi
Kaneko, Isao
Ohtaka, Nobuaki
Maruyama, Nozomu
Abstract
Abstract: Problem: To provide a soil-transmissible plant disease control agent or similar that can safely be used as a biological control agent. Solution: A soil-transmissible plant disease control agent or similar, such as a vegetable bacterial wilt control agent, can be provided by using, as an active ingredient, live bacterial cells of a novel strain of a bacterium of the Bacillus or Fictibacillus genus with a heretofore unknown soil-transmissible plant disease controlling action, or a cultured product including said live bacterial cells. This control agent is characterized by being able, through a foliage application treatment, to control bacterial wilt and/or bacterial soft rot caused by the Ralstonia solanacearum species complex, which are soil-borne bacteria. Selected drawing: none
C07C 319/20 - Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
C07C 323/12 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
C07C 319/20 - Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
C07C 323/12 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
C07C 317/14 - SulfonesSulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
C07C 317/22 - SulfonesSulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
C09K 17/14 - Soil-conditioning materials or soil-stabilising materials containing organic compounds only
The present invention evaluate various endocrine disrupting activities with high sensitivity even at low doses. Provided is a nucleic acid which comprises the nucleotide sequence represented by SEQ ID NO: 1, has a full length of 20 to 60 base pairs, and can exhibit excellent responsiveness to various endocrine disruptors.
Embodiments provide a pest control agent that is excellent in safety, controlling effect, residual activity, and so on. According to an embodiment, there is provided a pyrazole derivative represented by general formula [I], or an agriculturally acceptable salt thereof, and a pest control agent containing the same as an active ingredient:
6 alkyl group, or the like.
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
A01N 25/30 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
A method for producing a nitroso compound of the following formula (3), comprising reacting a compound of the following formula (1) with a compound of the following formula (2) by using a tertiary alcohol and a base.
9 are each independently a hydrogen atom, a halogen atom, a (C1-C4) alkyl, or a (C1-C4) alkoxy.
C07D 241/44 - Benzopyrazines with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
C07C 213/08 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions not involving the formation of amino groups, hydroxy groups or etherified or esterified hydroxy groups
84.
3-ALKOXY BENZOIC ACID AMIDE DERIVATIVE, AND PEST CONTROL AGENT
166 alkyl group, R116366 cycloalkyl group, etc., R2represents a hydrogen atom, etc., R3166 alkyl group, etc., R4166 alkyl group, etc., and R511212 alkyl group, etc.], or a salt thereof; and a pest control agent characterized by containing said derivative or salt thereof as an active ingredient.
C07C 235/46 - Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
C07C 271/16 - Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
C07C 311/09 - Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
C07C 317/18 - SulfonesSulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
C07C 323/12 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
C07C 323/17 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a ring other than a six-membered aromatic ring of the carbon skeleton
C07C 327/48 - Amides of thiocarboxylic acids having carbon atoms of thiocarboxamide groups bound to carbon atoms of six-membered aromatic rings
C07C 333/04 - Monothiocarbamic acidsDerivatives thereof having nitrogen atoms of thiocarbamic groups bound to hydrogen atoms or to acyclic carbon atoms
A01N 37/18 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N, e.g. carboxylic acid amides or imidesThio-analogues thereof
The objective of the present invention is to provide a production method for a 4,5-dihydroisoxazole represented by formula (3), which is safe, industrially desirable, economical, and environmentally friendly.
The present invention causes the compound of formula (1) to react with hydroxylamine in the presence of an acid catalyst to produce the compound of formula (3) through the reaction represented by the reaction equation.
C07D 261/04 - Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
B01J 31/02 - Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
Rhizobium bacteria by liquid culture using a medium containing a disaccharide (for example, maltose, trehalose, lactose, sucrose) accounting for at least 25 mass % of the carbon source in the medium while maintaining a pH of 5.0 to 7.0 in the culture solution throughout the course of the culture, namely from the beginning of the culturing to the end of the culturing of said bacteria.
Rhizobium bacteria and more than 10 mass % moisture is lyophilized to bring the moisture content to 10 mass %, and the drying is ended before the moisture content becomes less than 5 mass % so that the composition after the lyophilization contains the viable bacteria and 5 to 10 mass % of moisture.
C12N 1/00 - Microorganisms, e.g. protozoaCompositions thereofProcesses of propagating, maintaining or preserving microorganisms or compositions thereofProcesses of preparing or isolating a composition containing a microorganismCulture media therefor
C12N 1/04 - Preserving or maintaining viable microorganisms
A01N 63/20 - BacteriaSubstances produced thereby or obtained therefrom
The present disclosure relates generally to a weed control method and a mixed agrochemical composition for soil treatment, which, in a soil treatment of farmland with pyroxasulfone, not only can inhibit or reduce crop injury caused by absorption into cultivated crops, without being influenced by heavy rainfall, soil type, seeding depth and the like, but also are effective against a wide range of weed species. The weed control method includes a soil treatment step of performing a soil treatment on farmland with pyroxasulfone and a protoporphyrinogen oxidase inhibitor, simultaneously or sequentially, the method being characterized in that the agrochemical composition for soil treatment further contains a masking substance that masks the pyroxasulfone, and the pyroxasulfone is microencapsulated in or coated with the masking substance. The mixed agrochemical composition for soil treatment is characterized by containing the agrochemical composition for soil treatment and a protoporphyrinogen oxidase inhibitor.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 43/84 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
Provided are: an agrochemical composition for soil treatment which, when soil treatment with pyroxasulfone is performed on a field, is able to prevent or reduce chemical injury on crops caused by absorption without being affected by heavy rain, soil type, depth of seeding, and the like, and has high safety and a wide herbicidal spectrum; and a pest control method using the same. The agrochemical composition for soil treatment contains pyroxasulfone and a masking substance for masking the pyroxasulfone and is characterized in that the pyroxasulfone is microcapsulated in or coated with the masking substance.
A01M 21/04 - Apparatus for destruction by steam, chemicals, burning, or electricity
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The present invention addresses the problem of providing an excellent pesticide. The prevent invention provides an azole derivative or an agrochemically acceptable salt thereof and a pesticide characterized by comprising the same as an active ingredient, the azole derivative being represented by general formula [I] (In the formula: R1177 acyl group which is unsubstituted or substituted with a halogen atom; R2166 alkyl group or the like; A3, A4, A5, A6, A7, A8, and A9are each independently a nitrogen atom, or a carbon atom substituted respectively with R3, R4, R5, R6, R7, R8, and R9; R3, R4, R5, R6, R7, R8, and R9are each independently a hydrogen atom, a halogen atom, or the like; R10112161611212 haloalkyl group, or the like; and R11 is a halogen atom, an azido group, a cyano group, or the like).
C07D 233/74 - Two oxygen atoms, e.g. hydantoin with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to other ring members
C07D 401/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 401/10 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 401/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 401/14 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
C07D 403/04 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 403/10 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 403/12 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 403/14 - Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
C07D 405/04 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring- member bond
C07D 405/10 - Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 409/10 - Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 413/10 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 413/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
C07D 417/10 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a carbon chain containing aromatic rings
C07D 417/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
C07D 417/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
C07D 491/056 - Ortho-condensed systems with two or more oxygen atoms as ring hetero atoms in the oxygen-containing ring
A01N 47/02 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
A01N 47/18 - Carbamic acid derivatives, i.e. containing the group —O—CO—NThio-analogues thereof containing a —O—CO—N group, or a thio-analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
A01N 47/30 - Derivatives containing the group N—CO—N—aryl or N—CS—N—aryl
A01N 47/34 - Ureas or thioureas containing the groups N—CO—N or N—CS—N containing the groups , e.g. biuretThio-analogues thereofUrea-aldehyde condensation products
C07F 7/08 - Compounds having one or more C—Si linkages
C07D 249/06 - 1,2,3-TriazolesHydrogenated 1,2,3-triazoles with aryl radicals directly attached to ring atoms
A01N 55/10 - Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing silicon
A01N 43/66 - 1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
A01N 43/707 - 1,2,3- or 1,2,4-TriazinesHydrogenated 1,2,3- or 1,2,4-triazines
A01N 43/713 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The present invention is for providing a technique of imparting to the seeds the function of controlling weeds, pests, or plant diseases. This agrichemical composition for treating seeds is characterized by containing: crystal particles of an active agrichemical component having a volume median diameter of less than 1 μm; and a water-soluble polymer. The present invention also pertains to: a plant seed characterized by being obtained by providing a coating of the agrichemical composition on the outer shell of a plant seed to be cultivated; and a plant cultivation method characterized by involving disseminating and cultivating the seed on agricultural land or non-agricultural land.
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
METHOD OF INHIBITING AND/OR REDUCING CROP INJURY CAUSED BY ABSORPTION INTO CULTIVATED CROPS, WITH PYROXASULFONE THAT IS MICROENCAPSULATED OR COATED WITH A MASKING SUBSTANCE
The present invention is aimed at providing: an agrochemical composition for soil treatment which, in a soil treatment of farmland with pyroxasulfone, not only can inhibit or reduce crop injury caused by absorption into cultivated crops, without being influenced by heavy rainfall, soil type, seeding depth and the like, but also is highly safe and has a broad herbicidal spectrum; and a pest control method using the agrochemical composition. The agrochemical composition for soil treatment contains pyroxasulfone and a masking substance that masks the pyroxasulfone, in which the pyroxasulfone is microencapsulated in or coated with the masking substance.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The purpose of the present invention is to provide a weed control method and a mixed agrochemical composition for soil treatment which are capable of preventing or reducing absorption phytotoxicity to cultivated crops regardless of heavy rainfall, soil species, sowing depth, etc., when an upland field is subjected to a soil treatment with pyroxasulfone, and which are effective against a wide range of weed species. A weed control method is characterized by including a soil treatment step for soil treating an upland field with a protoporphyrinogen oxidase inhibitor and a pyroxasulfone-containing agrochemical composition for soil treatment at the same time or before or after, wherein the agrochemical composition for soil treatment further contains a concealing substance that conceals the pyroxasulfone, and the concealing substance microencapsulates or coats the pyroxasulfone. A mixed agrochemical composition for soil treatment is characterized by containing said agrochemical composition for soil treatment and a protoporphyrinogen oxidase inhibitor.
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
A01N 43/84 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
To provide a technique for promoting elution of an agrochemical active ingredient using a water-soluble polymer, the present invention provides: an agrochemical composition characterized by containing a water-soluble polymer, and agrochemical active ingredient crystal particles having a volume median diameter of less than 1 μｍ; and a method for producing the same.
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
The present invention addresses the problem of providing an industrially preferable, economical, and environmentally friendly method for producing the 4,5-dihydroisoxazole represented by a formula (3).
The present invention enables the compound of a formula (3) to be produced by reacting the compound of a formula (2) according to the reaction represented by a reaction formula in the presence of an acid catalyst.
C07D 261/04 - Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
B01J 31/04 - Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
B01J 31/02 - Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
96.
PROCESS FOR PRODUCING HERBICIDE AND INTERMEDIATE THEREOF
The present invention provides industrially preferable processes for producing a sulfone derivative useful as a herbicide and an intermediate thereof.Provided are a process for producing a compound of the formula (4), comprising the following step ii:(step ii) a step of reacting a compound of the formula (2) with a compound of the formula (3) in the presence of a base to produce the compound of the formula (4), anda process for producing a compound of the formula (5), comprising the following step iii:(step iii) a step of reacting the compound of the formula (4) with hydrogen peroxide in the presence of a metal catalyst to produce the compound of the formula (5).INipC.R5R2 S Step iii 2R), N c ______________________________________________ vb., 0 - R3 Het a l cat a I ystHydrogen pe rox i de NN 'NFt' i;?1(4) (5)CA 03156419 2022-4-27
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
97.
HERBICIDE AND PRODUCTION METHOD FOR INTERMEDIATE THEREOF
The present invention provides a sulfone derivative that is useful as a herbicide, and an industrially preferable production method for an intermediate of said derivative. Provided is a production method for a compound of formula (4), the method including step ii, wherein step ii is a step for producing a compound of formula (4) by reacting a compound of formula (2) with a compound of formula (3) in the presence of a base. Also provided is a production method for a compound of formula (5), the method including step iii, wherein step iii is a step for producing a compound of formula (5) by reacting a compound of formula (4) with hydrogen peroxide in the presence of a metal catalyst.
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
The present invention provides industrially preferable processes for producing a sulfone derivative useful as a herbicide and an intermediate thereof.Provided are a process for producing a compound of the formula (4), comprising the following step ii:(step ii) a step of reacting a compound of the formula (2) with a compound of the formula (3) in the presence of a base to produce the compound of the formula (4), anda process for producing a compound of the formula (5), comprising the following step iii:(step iii) a step of reacting the compound of the formula (4) with hydrogen peroxide in the presence of a metal catalyst to produce the compound of the formula (5).
A01N 43/80 - Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms, as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
C07D 413/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
The present invention addresses the problem of providing a production method for a 4,5-dihydroisoxazole represented by formula (5), said production method being industrially desirable, economical, and environmentally friendly. The present invention produces a compound of formula (5) by causing a compound of formula (2) to react with an oximation agent through the reaction represented by reaction formula AA.
C07D 261/04 - Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
100.
Method for producing thiocarboxamidine salt compound
The present disclosure provides an industrially preferable, economical, and environmentally friendly method for producing a compound [C1] of formula (5), namely, a (4,5-dihydroisoxazol-3-yl)thiocarboxamidine salt compound. The present disclosure relates to a method wherein: a reaction expressed by reaction formula [C2] is caused so as to produce a compound of formula (4) by reacting a compound of formula (3) with a halogenation agent in the presence of a nitrile solvent, and the compound of formula (4) is subsequently reacted with an isothiouronium-forming agent, thereby producing a compound of formula (5).
C07D 261/04 - Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
