44 - Medical, veterinary, hygienic and cosmetic services; agriculture, horticulture and forestry services
Goods & Services
Medical apparatus; medical apparatus for chronic condition
treatment; medical respiratory-assistance apparatus; medical
apparatus for oxygen therapy, for airway ventilation, for
sleep disorder diagnosis and care; medical
oxygen-concentration apparatus for delivering oxygen for
medical use; medical furniture and bedding; medical devices
for home care and assistance. Home health care services; oxygen therapy, aerosol therapy,
respiratory failure care, ventilation, treatment of sleep
disorders and other chronic illnesses (medical services);
patient monitoring services (medical services); rental of
medical apparatus; information and advisory services in the
medical field.
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Ouakrim, Wassim
Abstract
A method for filling a cryogenic liquid receiving tank, the method using a movable source tank and a towing vehicle, the method being carried out in a distribution site comprising a first zone for parking the source tanks and the towing vehicle, and a second zone, distinct from the first zone, for filling the receiving tank, the first zone comprising a depressurization zone and a waiting zone distinct from the depressurization zone, the method comprising the steps of moving the source tank, transferring a quantity of cryogenic liquid from the source tank to the receiving tank and, preferably, simultaneously transferring a quantity of boil-off gas present in the receiving tank to the source tank, moving the source tank to the first zone, verifying at least one parking condition of the source tank.
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Durst, Oliver
Weigand, Peter
Muller-Hagedorn, Matthias
Ritter, Sven
Kress, Michael
Abstract
The invention relates to a reactor, in particular an entrained flow gasifier, for producing synthesis gas by partial oxidation of a carbonaceous feedstock. The reactor comprises a reaction space, a cooling space and a gas duct fluidically connecting the reaction space and the cooling space. The gas duct has a gas inlet region adjacent to the reaction space and a gas outlet region adjacent to the cooling space. The feeding of cooling medium is effected via the gas duct. According to the invention it is provided that in the flow direction of the synthesis gas to be cooled the gas duct has a first region and a second region connected thereto, wherein the first region has a constant diameter and the second region has a diverging diameter in the flow direction of the synthesis gas to be cooled.
L'AIP LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
AMERICAN AIR LIQUIDE, INC (USA)
Inventor
Turney, Michael, A.
Guillard, Alain
Abstract
A process for producing liquid nitrogen utilizes a distillation system comprising higher- pressure and lower-pressure columns, a first condenser in the lower-pressure column bottom, and a second condenser disposed on top of the lower-pressure column. Feed air is compressed in a main air compressor above 15 bar(a) and cooled in a main heat exchanger. A first cooled air portion is expanded in a cold turbine before separation in the higher-pressure column. A second cooled air portion is liquefied before entering the higher-pressure column. Liquid nitrogen streams condensed by both the first and second condensers are combined to yield the final product. Another feature involves warming and expanding a lost air stream (e.g., from the cold turbine outlet and/or higher-pressure column) to below 2 bar(a) in a warm turbine.
F25J 3/04 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Ouakrim, Wassim
Light, Joshua
Abstract
Method for filling a plurality of cryogenic liquid receiving tanks, using a plurality of mobile source tanks, the method comprising the following steps: transferring a first quantity of cryogenic liquid from a first source tank to a first receiving tank, and simultaneous transfer of a first quantity of vaporization gas present in the first receiving tank to the first source tank; checking at least the distribution condition that the pressure in the first source tank is lower than a predetermined pressure threshold; and if the distribution condition is met, transfer of a second quantity of cryogenic liquid from the first source tank to a second receiving tank, and simultaneous transfer of a second quantity of vaporization gas present in the second receiving tank to the first source tank.
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude (France)
Inventor
Briglia, Alain
Day, Eric
Wakim, Michael
Abstract
A device for preparing high-purity hydrogen and/or high-purity oxygen by electrolysis of water, wherein the hydrogen and/or oxygen produced has an argon content of less than 5 ppb by weight. Including, in sequence, a desalination water treatment system, a desalination water storage tank, a degasser feed water pump, a desalinated and degassed water heat exchanger, a degasser for degassing desalinated water, an electrolyzer feed water pump, and an electrolyzer. The degasser is configured to produce water that has an argon content of less than 10 ppb by weight after being degassed. The electrolyzer is an alkaline electrolyzer, and includes an electrolytic cell, and anode lye separator, a cathode lye separator, and a lye cooler. The electrolyzer also includes a lye heat exchanger and a hot lye recirculation stream. Also involved is a method of preparing high-purity hydrogen and/or oxygen by using the device.
L'Air Liquide, Societe Anonyme pour I'Etude et I'Exploitation des Procedes Georges Claude (France)
Inventor
Choudar, Yann
Nesselberger, Markus
Tadiello, Jean-Philippe
Abstract
A device for separating a gas flow and a liquid electrolyte flow from a biphasic flow including a separator vessel oriented along a horizontal axis, a hold-up plate, and multiple separator plates. Wherein the separator vessel includes a biphasic flow inlet and a product gas outlet and a liquid electrolyte outlet, wherein the hold-up plate and the multiple separator plates are arranged in the separator vessel, and wherein the hold-up plate is arranged downstream of the multiple separator plates. Wherein the hold-up plate is arranged in a hold-up plane, and the multiple separator plates are arranged in respective separator planes, wherein the multiple separator planes are distanced axially from each other along the horizontal axis.
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Turney, Michael A.
Guillard, Alain
Abstract
A process for producing liquid nitrogen utilizes a distillation system comprising higher-pressure and lower-pressure columns, a first condenser in the lower-pressure column bottom, and a second condenser disposed on top of the lower-pressure column. Feed air is compressed in a main air compressor above 15 bar(a) and cooled in a main heat exchanger. A first cooled air portion is expanded in a cold turbine before separation in the higher-pressure column. A second cooled air portion is liquefied before entering the higher-pressure column. Liquid nitrogen streams condensed by both the first and second condensers are combined to yield the final product. Another feature involves warming and expanding a lost air stream (e.g., from the cold turbine outlet and/or higher-pressure column) to below 2 bar(a) in a warm turbine.
F25J 3/04 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Andrich, Marine
Redon, Emilien
Granados, Ludovic
Abstract
The invention relates to a refrigeration installation and method comprising a cycle-fluid refrigerator (3) comprising a cycle circuit (13) comprising a compression device (23), an expansion device (33), the installation (1) comprising a buffer store (5) for the cycle fluid and a transfer circuit arrangement (6, 7) connecting the cycle circuit (13) to the buffer store (5), the transfer circuit arrangement (6, 7) being configured to allow at least part of the cycle fluid to be purged from the cycle circuit (13) into the buffer store (5) and to allow cycle fluid in the buffer store (5) to return to the cycle circuit (13), the installation (1) further comprising a pressurization line (8) configured to allow a pressurized gas to be injected into the buffer store (5) in order to cause the cycle fluid to move into the cycle circuit (13), the pressurization line (8) being connected to the cycle circuit (13) in order to use the cycle fluid of the cycle circuit (13) as pressurized gas to be injected into the cycle fluid buffer store.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Ulber, Dieter
Shrivastava, Swatantra Kumar
Kuzniar, Jakub
Abstract
The invention relates to a process (100) for producing a hydrogen product (81) from an endothermic cracking reaction of an ammonia feed (4), comprising the following steps: - in said cracking unit, performing (S20) the endothermic cracking reaction of the ammonia feed, thereby producing a cracked gas (80) containing hydrogen (81), nitrogen (82) and unconverted ammonia (83), - in said cracking unit, combusting the separated unconverted ammonia in a combustion step (S40) to provide heat to the endothermic cracking reaction, - reducing (S50) a cracking temperature (Tc) of the endothermic cracking reaction, thus increasing the amount of unconverted ammonia in the cracked gas and to be combusted to provide heat to the endothermic cracking reaction, - controlling (S60) the flow of the ammonia feed directed to the cracking unit to produce a desired amount of hydrogen product (Psp).
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Murino, Michele
Granados, Ludovic
Bonifacio, Abigail
Abstract
The invention relates to a method for the low-temperature separation of a gas containing CO2 in order to produce a CO2-rich fluid, in which method a gas containing CO2 and at least one component lighter than CO2 is compressed in a compressor comprising at least two stages, the gas being cooled downstream of at least one of the stages in a cooler and by exchanging heat with air and then being cooled in a first heat exchanger, the gas cooled in the first heat exchanger is separated at low temperature by partial condensation and/or distillation in order to produce a fluid rich in CO2 and depleted in the component lighter than CO2 and a gas depleted in CO2 and enriched in the component lighter than CO2. The gas depleted in CO2 is first heated in the first heat exchanger and then in the cooler before being expanded in a turbine.
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
12.
METHOD AND APPARATUS FOR LOW-TEMPERATURE SEPARATION OF A GAS CONTAINING CO2 TO PRODUCE A CO2-RICH FLUID
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Murino, Michele
Granados, Ludovic
Bonifacio, Abigail
Abstract
The invention relates to a method for the low-temperature separation of a feed gas containing CO2, at least one component lighter than CO2 and at least one component heavier than CO2, wherein, in order to produce a CO2-rich fluid, the feed gas is compressed, the compressed gas being cooled in a first heat exchanger, the gas cooled in the first heat exchanger is separated at low temperature in a first distillation column to produce a liquid that is enriched in CO2 and depleted in the at least one component lighter than CO2 and a gas that is depleted in CO2 and enriched in the at least one component lighter than CO2, the gas depleted in CO2 is heated in the first heat exchanger, a first part of the liquid enriched in CO2 is expanded and sent to a second distillation column in liquid form, a second part of the liquid enriched in CO2 is vaporized in the first heat exchanger then sent in gas form into the tank of the second distillation column, a liquid depleted in CO2 and enriched in the at least one heavier component is withdrawn from the second column, and a gas enriched in CO2 and depleted in the at least one heavier component is withdrawn at the top of the second column as product.
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
13.
METHOD AND APPARATUS FOR SEPARATING A MIXTURE CONTAINING CO2, AT LEAST ONE COMPONENT LIGHTER THAN CO2 AND MERCURY
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Leclerc, Mathieu
Granados, Ludovic
Abstract
In a method for separating a mixture containing CO2, at least one component lighter than CO2 and mercury, the mixture (11) is cooled in a heat exchanger (43) and is partially condensed forming a first two-phase fluid, the first two-phase fluid exits the heat exchanger at a first temperature between -25°C and -38°C and is separated in a first phase separator (12) forming a gas (14) that is enriched in the at least one lighter component relative to the mixture and a liquid bath that is enriched in CO2 and in mercury relative to the mixture, a first liquid (16) is drawn off by means of a pipe that is in communication with the upper portion of the liquid bath and a flow of a second liquid (18) corresponding to less than 1% of the liquid generated by the partial condensation of the mixture is drawn off at most once per year.
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
F25J 3/08 - Separating gaseous impurities from gases or gaseous mixtures
F25J 5/00 - Arrangements of cold-exchangers or cold-accumulators in separation or liquefaction plants
F25J 1/02 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen
L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude (France)
Inventor
Valentin, Solène
Barraud, Francois
Gary, Daniel
Abstract
The invention relates to a plant and method for producing deoxygenated biomethane (10) having an oxygen concentration below a determined threshold, in particular below 100 ppm, from biogas (1), the plant comprising:—a membrane-permeation treatment unit (5) which is able to produce biomethane (9) and is configured to produce biomethane having a molar concentration below a first determined threshold, for example less than 5% CO2 and less than 1% O2, in particular less than 3% CO2 and less than 0.7% O2, from a stream of biogas having a CO2 concentration above a second threshold, for example from 15 to 60% carbon dioxide,—a compressor (2) configured to compress the biogas (1), and—at least one catalytic reaction unit (3) comprising at least one bed of at least one oxidation catalyst configured to deoxygenate the biogas (1) and/or the biomethane (9) and/or the partially purified biogas (7).
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Hernandez, Antoine
Bali, Naila
Abstract
In a process for the production of an ammonia synthesis gas, a gas mixture containing hydrogen, argon, carbon monoxide, carbon dioxide and methane originates from a reformer in combination with a combustion unit, the mixture being treated to remove the carbon dioxide which it contains before being cooled and separated in a cryogenic separation unit in a thermally insulated chamber, the mixture being separated to provide a liquid which is vaporized and sent as fuel to the combustion unit having been purified of carbon monoxide and/or methane.
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
16.
METHOD FOR LIQUEFYING A FEED FLUID AT A CRYOGENIC TEMPERATURE
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Gaertner, Axelle
Abstract
The invention relates to a plant for liquefying a feed fluid at a cryogenic temperature, comprising: a feed circuit (2); a set of heat exchanger(s) (3, 4) exchanging heat with the feed circuit; a device (6) for cooling the set of heat exchanger(s) and comprising a refrigerator which employs cycle gas comprising hydrogen and/or helium and at least one additional constituent having a molar mass greater than 15 g/mol, the cycle circuit (60) comprising at least one unit (7) for purifying the cycle gas by adsorption arranged downstream of a compressor of the compression system (16) and upstream of an expansion unit of the expansion system (26), the plant (1) comprising at least one regeneration pipe (8) for the cycle-gas purifying unit (7), the regeneration pipe being configured to inject a stream of regeneration gas into the cycle-gas purifying unit (7) during a regeneration phase, the at least one regeneration pipe (8) having an upstream end connected to the feed circuit (2) and/or to the cycle circuit (60) and a downstream end connected to an inlet of the cycle-gas purifying unit (7).
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Lecourt, Apolline
Rigon, Etienne
Monereau, Christian
Abstract
A method for separating a feedstock gas by pressure swing adsorption which produces a first gaseous fraction enriched in a first component and a second gaseous fraction enriched in a second component, the separation unit comprising a plurality of adsorbers, the pressure cycle comprising a plurality of steps including at least one adsorption step and at least one rinsing step in which a rinsing fluid enriched in a first component flows through at least one adsorber so as to flush at least some of the second component out of the adsorber, the pressure cycle having a phase time corresponding to the duration of the pressure cycle divided by the number of adsorbers.
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Marty, Pascal
Monereau, Christian
Toulemonde, Louis
Abstract
A method for purifying a TSA unit operating according to a cycle comprising an elution-cooling step, said elution-cooling step comprising at least the following two sub-steps: - a first elution-cooling sub-step (C) with, at the adsorber outlet, extraction of a purge gas from the TSA unit as long as the impurity content in said purge gas remains above a predetermined threshold, - a second elution-cooling sub-step (D) using purified product gas, with recycling of the purge gas at the adsorber outlet to at least one other adsorber in adsorption step, the impurity content in said recycled gas then being below the predetermined threshold.
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Pontisso, Hugo
Turmel, Vanessa
Grandjean, Sosthene
Koenig, Sebastian
Abstract
The invention relates to a plant and a method for producing liquefied hydrogen comprising a hydrogen gas generator, a liquefier, a feed line connecting an outlet of the hydrogen gas generator to an inlet of the liquefier, the liquefier comprising a refrigerator having a cycle circuit to cool the hydrogen gas from the feed line, the plant comprising a buffer store configured to store the compressed hydrogen gas between the hydrogen gas generator and the liquefier, the liquefier being configured to supply a cooling power and/or the liquefaction capacity that can be modified between at least two levels, the plant comprising a means for determining the fill level of the buffer store, the plant being configured to modify the cooling power and/or liquefaction capacity of the liquefier as a function of the fill level of the buffer store determined by the determining means.
F25J 1/02 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude (France)
Inventor
Oelmann, Tobias
Bartels, Katja
Mueller, Brigitte
Gronemann, Veronika
Strozyk, Michael
Abstract
A device (1.1, 1.2) with a reactor vessel (2), a tube bundle (3) of multiple tubes (4), and at least one support plate (5), wherein the tube bundle (3) is disposed in the reactor vessel (2), wherein the support plate (5) is disposed in the reactor vessel (2) transversely to a longitudinal axis (6) of the reactor vessel (2), wherein each tube (4) of the tube bundle (3) is routed through a respective tube opening (7) of the support plate (5), wherein the support plate (5) supports the tubes (4) of the tube bundle (3) in the tube openings (7) transversely to the longitudinal direction of the tubes (4), wherein the support plate (5) has fluid-exchange cutouts (8) between the tube openings (7).
G21C 13/02 - Pressure vesselsContainment vesselsContainment in general Details
C07C 29/152 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
21.
PROCESS FOR REMOTE LOX/LIN PRODUCTION BY HPAIR TURBO EXPANSION
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Turney, Michael A.
Guillard, Alain
Abstract
A process for cryogenic air separation and liquefaction, including purifying and compressing an inlet air stream, thereby producing a compressed inlet air stream, dividing the compressed inlet air stream into an ASU portion and a liquefaction portion, introducing the ASU portion into an air separation unit, thereby producing a gaseous oxygen steam and a gaseous nitrogen stream, and introducing the liquefaction portion, the gaseous oxygen steam and the gaseous nitrogen stream into a liquefaction unit, thereby producing a liquid nitrogen stream and a liquid oxygen stream. Wherein, the air separation unit is located more than 200 meters from the liquefaction unit, and there is no compression driven by external energy within 200 meters of the liquefaction unit.
F25J 3/04 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Petitpas, Guillaume
Mazeau, Alexandre
Abstract
The invention relates to a double-walled storage tank for liquefied gas, in particular cryogenic fluid, having an inner wall and an outer wall which is arranged around the inner wall with a thermally insulated gap, wherein the inner wall is suspended in the outer wall at at least one of its ends via a tensioned-cable(s) suspension system between the inner wall and the outer wall, the suspension system having the one same cable passing back and forth more than once between the inner wall and the outer wall via respective guide passages, the cable forming a plurality of connections between the inner wall and the outer wall in different directions, one end of the cable being secured to one of the walls and configured to place the cable under tension.
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude (France)
Inventor
Oelmann, Tobias
Strozyk, Michael
Personne, David
Tercan, Abdullah Enes
Gronemann, Veronika
Abstract
A device (1.1; 1.2) with a reactor vessel (2), a tube bundle (3) of multiple tubes (4), a first support plate (5) and a second support plate (6), wherein the tube bundle (3) is located in the reactor vessel (2), wherein the tube bundle (3) comprises multiple first tube groups (7) and multiple second tube groups (8), wherein the first support plate (5) and the second support plate (6) are disposed in the reactor vessel (2) transversely to a longitudinal axis (9) of the reactor vessel (2), wherein the first support plate (5) is offset from the second support plate (6) along the longitudinal axis (9) of the reactor vessel (2).
L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude (France)
Inventor
Oelmann, Tobias
Strozyk, Michael
Bartels, Katja
Tercan, Abdullah Enes
Gronemann, Veronika
Abstract
A device (1.1;1.2) with a reactor vessel (2), a tube bundle (3) of multiple tubes (4), a first support plate (5) and a second support plate (6), wherein the tube bundle (3) is disposed in the reactor vessel (2), wherein the tube bundle (3) comprises a first tube group (7), a second tube group (8) and a third tube group (9), wherein the first support plate (5) and the second support plate (6) are disposed in the reactor vessel (2) transversely to a longitudinal axis (10) of the reactor vessel (2), wherein each of the tubes (4) is made to pass through the first support plate (5) and the second support plate (6).
C07C 1/12 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of carbon from carbon dioxide with hydrogen
F28D 1/04 - Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with the heat-exchange conduits immersed in the body of fluid with tubular conduits
F28F 9/013 - Auxiliary supports for elements for tubes or tube-assemblies
25.
STABILIZED PLATINUM FUEL CELL CATALYST AND PREPARATION METHOD THEREOF
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
AMERICAN AIR LIQUIDE, INC. (USA)
Inventor
Teramoto, Takashi
Huang, Qi-An
Dussarrat, Christian
Blasco, Nicolas
Abstract
The disclosure describes a method of stabilizing a carbon supported noble metal catalyst by selective metal oxide deposition on the carbon support of the catalyst by a vapor deposition process. The method includes the flowing steps: a) Providing a carbon supported noble metal catalyst, b) Forming a blocking layer over an exposed surface of the noble metal on the catalyst, c) Exposing the catalyst to a gas containing metal organic compounds to absorb the compounds selectively to the carbon support, d) Exposing the catalyst to an oxidant to form a metal oxide on the catalyst carbon support, e) Repeating steps c) and d) sequentially for one to ten of cycles, preferably one to five cycles, f) Removing the blocking layer from the catalyst to re-expose the noble metal catalyst surface.
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Sonnendrucker, Antoine
Serpry, Adrien
Leclerc, Mathieu
Morel, Thomas
Ricci, Laura
Abstract
In a method for separating a mixture of CO2, NOx and at least one component that is lighter than CO2 by partial condensation, the mixture is cooled and sent into the bottom of a first washing column (K1) fed at the top with a liquid (43, 45) containing at least 90 mol% of CO2, a gas (5) depleted in NOx and enriched in CO2 exits the top of the first washing column and a liquid (3) enriched in NO2 and depleted in CO2 exits at the bottom of the first washing column, the NOx-depleted gas is separated by partial condensation and optionally by distillation forming at least one CO2-enriched liquid (33, 38) and at least one CO2-depleted gas (37), at least one portion (39) of one of the at least one CO2-enriched liquid is vaporized, compressed, cooled and sent in the form of gas into the bottom of a second washing column (K3) fed at the top with a liquid (51) containing at least 90 mol% of CO2, a gas (41) depleted in NOx and enriched in CO2 exits the top of the second washing column and a liquid (43) enriched in NO2 and depleted in CO2 exits at the bottom of the second washing column.
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
F25J 3/00 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification
B01D 3/00 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
F23J 15/04 - Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
F23J 15/00 - Arrangements of devices for treating smoke or fumes
L'Air Liquide, Société Anonyme Pour I'Etude et I'Exploitation des Procédés Georges Claude (France)
Inventor
Widuch, Dennis
Tadiello, Jean-Philippe
Nesselberger, Markus
Abstract
An electrolysis system (1) having:
a first electrolysis cells unit (2) and a second electrolysis cells unit (3), each respectively having a first end plate (4), a second end plate (5) and a plurality of electrolysis cells (6) arranged adjacent to each other between the first end plate (4) and the second end plate (5), wherein each of the electrolysis cells (6) respectively has an anode space (13) with an anode (14), a cathode space (15) with a cathode (16) and a diaphragm (17) that separates the anode space (13) from the cathode space (15), and
a first separator (18) that is connected fluidly to the first outlets (9) of both electrolysis cells units (2,3) and to the second outlets (10) of both electrolysis cells units (2,3), and that has a separator gas outlet (21) and a separator liquid outlet (22).
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude (France)
Inventor
Ulber, Dieter
Bruder, Frank
Abstract
Assembly comprising a reactor, a waste heat boiler, an actuator, a shaft, a shaft sealing element, an axial bearing and a temperature control means, wherein the waste heat boiler is connected to the reactor, wherein the shaft, the shaft sealing element and the axial bearing are arranged on a common axis, wherein the waste heat boiler has an opening through which the shaft is passed and which is sealed by the shaft sealing element, wherein the actuator is arranged outside the waste heat boiler, wherein the temperature control means is arranged inside the waste heat boiler, wherein the actuator is coupled to the shaft at a first end and wherein the actuator is designed to effect rotational drive of the shaft, wherein the temperature control means is coupled to the shaft at a second end and is designed to be adjusted by rotational motion of the shaft, wherein the axial bearing is designed to counteract a motion of the shaft in the direction of the first end of the shaft.
F22B 33/18 - Combinations of steam boilers with other apparatus
F22B 1/18 - Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Keuchel, Florian
Meyer, Quentin
Chaubet, Lucie
Schmid Mcguinness, Teja
Raulli, Elena
Abstract
The invention relates to a process for separating carbon dioxide from a flue gas stream by gas scrubbing with a liquid scrubbing agent containing at least one absorbent compound which is selective for carbon dioxide absorption. According to the invention, a carbon dioxide enriched scrubbing agent stream discharged from an absorption column is introduced into a partial regeneration column, and is contacted by means of a gaseous nonpolar stripping agent in countercurrent flow, to generate a partially regenerated scrubbing agent stream which is returned to the absorption column.
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
30.
APPARATUS FOR PERFORMING AN ENDOTHERMIC REACTION OF A GAS FEED
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Shrivastava, Swatantra Kumar
Rossi, Umberto
Ulber, Dieter
Abstract
Apparatus for the endothermic reaction of a gas feed, the apparatus comprising: a pre-heater arranged for pre-heating the gas feed, —at least one reactor tube, —a furnace arranged for the radiation and/or convection heating of said at least one reactor tube, said at least one reactor tube being at least partially filled with a catalyst material configured for promoting the endothermic reaction, said at least one reactor tube comprising a tube inlet for said pre-heated gas feed, —a main reaction tube portion extending within said furnace and a pre-reaction tube portion extending outside of the furnace, said pre-reaction tube portion being arranged between the tube inlet and the main reaction tube portion, wherein part of the catalyst material is extending within the pre-reaction tube portion.
B01J 8/06 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds in tube reactorsChemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the solid particles being arranged in tubes
C01B 3/04 - Production of hydrogen or of gaseous mixtures containing hydrogen by decomposition of inorganic compounds, e.g. ammonia
C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Gaertner, Axelle
Portier, Marie
Abstract
The invention relates to a method and an installation for liquefying hydrogen, wherein a first gaseous hydrogen flow (1) is pre-cooled to a first temperature and then sent to a cooling chamber (8) where it is cooled to a second temperature lower than 40K, the cold for cooling the first hydrogen flow from the first temperature to the second temperature being produced exclusively by the expansion of a second hydrogen flow (2) by at least one expansion member (10) in the cooling chamber (8), the second gaseous hydrogen flow (2) at the first pressure being drawn from a pipe network (11, 3) for distributing hydrogen to at least one user (13) having at least one hydrogen pipe (3) at a pressure of between 50 and 200 bar, after its expansion in the at least one expansion member (10), the expanded second hydrogen flow (2) is at a second pressure level lower than the first pressure, at least a first fraction (122) of this second hydrogen flow (2) at the second pressure level being at least partially supplied to a pipe (3) of the network (11, 3) of pipes for distributing hydrogen to the at least one user (13) which is at a pressure level corresponding to the second pressure level.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Vicari, Lorenzo
Kuzniar, Jakub
Shrivastava, Swatantra Kumar
Williams, Bryce
Lutz, Michael
Hyla, Kaja
Ulber, Dieter
Abstract
The invention relates to an apparatus (2) for producing hydrogen, from a feedstock stream (3) comprising ammonia, traces of water and oil contaminants, said apparatus (2) comprising: - a vaporizer (4) comprising a vaporization chamber (6) configured to receive the feedstock stream (3) and produce a vaporized purified ammonia stream (7), said vaporization chamber (6) comprising a blowdown outlet (8) configured to discharge a blowdown stream (10) comprising the traces of water and oil contaminants from said vaporization chamber (6); - an ammonia cracking reactor (12) for performing an endothermic reaction of said vaporized purified ammonia stream (7), thereby producing said hydrogen; and - a fired equipment (14); wherein said blowdown outlet (8) is connected to the fired equipment (14) for providing the blowdown stream (10) as an ammonia fuel stream to the fired equipment (14).
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Andrich, Marine
Aires, Matilde
Cardon, Guillaume
Abstract
The invention relates to a cryogenic fluid production facility, comprising: a circuit of gas to be cooled, an assembly of heat exchangers exchanging heat with the circuit of gas to be cooled, a cooling device arranged to cool the circuit of gas to be cooled by means of heat exchange with a heat exchanger, a bypass pipe for the gas to be cooled, arranged to divert the gas to be cooled from the circuit of gas to be cooled to a compression member which is arranged to compress the diverted gas to be cooled, a pipe for reinjecting the gas treated in this way, the reinjection pipe being arranged to reinject the gas treated in this way into the circuit of gas to be cooled, the facility being arranged so that at least 50% of the flow of gas to be cooled is diverted to the bypass pipe during a starting phase of the facility.
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
F25J 1/02 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Beurey, Claire
Gaertner, Axelle
Granados, Ludovic
Abstract
The invention relates to a facility for producing a cryogenic fluid, the facility comprising: a circuit for gas to be cooled, having an upstream end intended to be connected to a source of gas to be cooled and a downstream end intended to be connected to a receiving system; a set of heat exchangers in thermal exchange with the circuit for gas to be cooled; a cooling circuit with a cooling gas cycle, arranged so as to cool the gas to be cooled via thermal exchange with one of the heat exchangers, wherein the cooling circuit comprises at least one cryogenic purifier arranged so as to purify at least the cooling gas; a pipe for conveying a vaporised gas mixed with impurities to the cooling circuit, wherein the cryogenic purifier comprises a purification vessel, and wherein a regeneration circuit is arranged so as to regenerate the purification tank.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Bignaud, Charles
Leclerc, Mathieu
Rodrigues, Guillaume
Abstract
The invention relates to a method for capturing CO2 from a mixture (1, 3) containing at least carbon dioxide, at least 1 mol%, or even at least 3 mol%, oxygen, and at least one hydrocarbon, in which method hydrocarbons are removed from the mixture by catalytic oxidation (CAT), upstream of the low-temperature separation, using the oxygen already present in the mixture.
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
37.
FLUORINATION OF ANCILLARY LIGANDS OF GROUP (III) PRECURSORS AND THEIR APPLICATIONS IN VAPOR DEPOSITIONS
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Mckeown, Bradley
Diemoz, Kayla
Abstract
A method for forming a Group (III)-containing film on a substrate comprises exposing the substrate to a vapor of a Group (III)-containing film-forming composition that contains a Group (III)-containing precursor and depositing at least part of the Group (III)-containing precursor onto the substrate to form the Group (III)-containing film on the substrate through a vapor deposition process. The Group (III)-containing precursor contains at least one fluorocarbon group on at least one of ancillary ligands. The Group (III)-containing precursor is tris(2-(dimethylamino)methyl-1,1,1,3,3,3-hexafluoropropan-2-ol)indium, represented as (F-dmamp)3In.
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Sirac, Denis
Andre, Johan
Abstract
The invention relates to a fuel cell assembly (26) comprising a first fuel cell plate (1) intended to come into contact with a membrane electrode assembly, the first plate (1) comprising a reactive face (11) that comprises a reactive zone (2), a clamping band (9), a thinned portion (3) and a peripheral sealing zone (12), wherein the reactive zone (2) comprises flow channels for a reactant, wherein the clamping band (9) is configured to at least partially surround the reactive zone (2) by being designed to clamp the membrane electrode assembly, wherein the peripheral sealing zone (12) is configured to surround the clamping band (9) by being designed to form, together with the membrane electrode assembly, a seal for the cell against the reactant, and wherein the thinned portion (3) is arranged between the peripheral sealing zone (12) and the clamping band (9).
L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude (France)
Institut National de Recherche pour I'Agriculture, I'Alimentation et I'Environnement (France)
Inventor
Bertrandias, Aude
Bremond, Ulysse
Steyer, Jean-Philippe
Carrere, Helene
Abstract
Process for producing biogas from a digestate obtained from a digester, said process comprising a step of recovering the digestate at the outlet of a digester, a post-digester or a storage tank; a step of separating the digestate into a solid digestate and a liquid digestate; a step of introducing the solid digestate into at least one closed tank; a step of anaerobic digestion in the tank with neither heating nor mixing; and a step of recovering the biogas at the tank outlet.
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude (France)
Air Liquide France Industrie (France)
Inventor
Cousin, Franck
Alban, Bruno
Ibarra, Dominique
Abstract
Device for mixing a gas into a liquid, implementing a screw structure in a pipe in which the liquid is able to circulate, and also means for injecting the gas at one or more points into the pipe, characterized in that:
the first zone encountered by the liquid has a screw portion within which the shaft is a pipe pierced with orifices, the liquid to be treated passing through the space inside the pipe surrounding the shaft, while the gas is distributed inside the shaft and discharges via the orifices into the liquid;
the second zone encountered by the liquid situated downstream of the first zone is constituted by a screw portion of which the shaft is devoid of orifices.
B01F 23/233 - Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
B01F 27/1143 - Helically shaped stirrers, i.e. stirrers comprising a helically shaped band or helically shaped band sections screw-shaped, e.g. worms
41.
DEVICE FOR STORING AND SUPPLYING CRYOGENIC FLUID, IN PARTICULAR LIQUEFIED HYDROGEN
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Fayer, Thomas
Abstract
A device for storing and supplying cryogenic fluid, in particular liquefied hydrogen, comprising a tank delimiting a fluid-storage volume, the tank comprising a set of plates intended to limit or guide the movement of fluid in the tank, the set of plates comprising a plurality of first plates spaced vertically and extending in a horizontal direction when the tank is in a use position, characterized in that the set of plates further comprises one or more second plates extending in a vertical direction when the tank is in a use position, and connected to the first plates, the device further comprising a withdrawal circuit comprising a liquid-withdrawal pipe having a first end connected to a lower portion of the tank and a second end intended to be connected to a member for receiving the fluid, the liquid-withdrawal pipe comprising a pump, the device further comprising a system for pressurizing the tank that comprises a fluid-pressurizing pipe connecting the lower and upper parts of the tank and provided with a fluid-heating member configured to tap off some liquid, beat it and reinject it into the tank.
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude (France)
Inventor
Kim, Sanghoon
Prost, Laurent
Briand, Francis
Abstract
To provide: a range of gas mixture compositions that make it possible to hinder Li/Ni cation mixing and transition metal peroxidation; and a method for producing a nickel-rich cathode active material, comprising a firing process using the gas mixtures. The method for producing a nickel-rich cathode active material comprises a firing step, in which a cathode precursor containing at least a predetermined amount of nickel, and a metal oxide solid raw material containing lithium raw material, are fired in a reactor having an atmosphere comprising a gas mixture containing oxygen in the range of 94% by volume to 98% by volume. The oxygen content of the gas mixture is preferably 95% by volume to 97% by volume.
C01G 53/506 - Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5 with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.8, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.8
43.
PROCESS AND FACILITY FOR REGULATION THE AMOUNT OF OXYGEN SUPPLIED TO ANIMAL DRINKING WATER
L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude (France)
Inventor
Ibarra, Dominique
Cousin, Franck
Le Dru, Pauline
Abstract
The invention relates to a facility for farming animals, and in particular poultry and pigs, comprising means for supplying water to the animals for their drinking, said supply means comprising: —an injector (7, 8) making it possible to inject a gas into the water; —a water inlet line (20) and a gas inlet line (3, 4, 5, 6), reaching into the injector; and—a source (1) of oxygen or of a gaseous mixture comprising oxygen, for example an oxygen store, which is able to dispense oxygen into the gas line; —a water tank (17) at atmospheric pressure, the injector being supplied with water from the water located in this tank, which tank can additionally be supplied with fresh water (20); —a coil (10) able to receive water loaded with dissolved oxygen originating from the injector, which water reaches the coil by virtue of a pump (9), which coil makes it possible to create a water/oxygen contact time; —the water leaving the coil passing through a discharge spout (12) in order to be entirely directed towards the drinking water or else partially towards the drinking water and partially into the tank (17). The invention is characterised in that two simultaneous injections of oxygen or of a mixture comprising oxygen in the water are carried out: one (3, 5, 7) upstream of the pump and the other (4, 6, 8) downstream of the pump (9), the flow rate of the injection carried out upstream being lower than the flow rate of the injection carried out downstream of the pump.
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude (France)
Air Liquide France Industrie (France)
Inventor
Cousin, Fanck
Ibarra, Dominique
Le Dru, Pauline
Abstract
Facility for oxygen-doping of water used to irrigate crops or to water animals (40) comprises an injector (7, 8), a water inlet line (20), at least one gas inlet line (3, 4, 5, 6), at least one source (1, 60) of oxygen or of a gas mixture including oxygen, a tank (17) of water at atmospheric pressure, a pump (9), a coil (10), a water pressure sensor (90), and a water flow sensor (80).
B01F 23/237 - Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
C02F 1/68 - Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
C02F 103/02 - Non-contaminated water, e.g. for industrial water supply
45.
PROCESS TO PURIFY HELIUM FROM METHANE WITH INTEGRATED NITROGEN REJECTION USING MEMBRANE TECHNOLOGY
A process to purify helium from a feed gas stream containing a mixture of at least nitrogen, methane and helium including introducing the feed gas stream into a first helium membrane separation unit, thereby producing a first helium membrane permeate and a first helium membrane residue; introducing at least part of the first residue into a first nitrogen membrane separation unit thereby producing a first nitrogen membrane permeate stream; introducing a stream derived from the first helium membrane permeate into a hydrogen PSA unit thereby producing a helium rich product stream. Wherein a stream derived from the first nitrogen membrane permeate stream exits the system as a fuel gas product stream. Wherein the feed gas stream has a higher heating value, and wherein the first nitrogen membrane permeate stream has a higher heating value at least 5% higher than the higher heating value of the feed gas.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
C01B 3/56 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solidsRegeneration of used solids
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Abdo, Youssef
Ouakrim, Wassim
Abstract
The invention relates to an apparatus (1) for compressing cryogenic fluid, comprising a sealed chamber (13) intended to contain a bath (6) of liquid cryogenic fluid, a compression chamber (3), a movable piston (5) for compressing the fluid in the compression chamber (3), and a set of one or more valves (2) configured to control the inlet and/or outlet of fluid relative to the compression chamber (3), the set of one or more valves (2) comprising at least one disc-shaped or annular valve that is movable relative to a seat (4), the valve (2) being of the composite type comprising, across its thickness, a first portion (12) and a second portion (22) that are separate and stacked, an upper face of the first portion (12) being in communication with an internal volume of the apparatus (1), a lower face of the second portion (22) being intended to engage in sealed contact with the seat (4) of the valve, the second portion (22) consisting of a material that is more flexible than the material that constitutes the first portion (12).
F04B 15/08 - Pumps adapted to handle specific fluids, e.g. by selection of specific materials for pumps or pump parts for liquids near their boiling point, e.g. under subnormal pressure the liquids having low boiling points
F04B 23/02 - Pumping installations or systems having reservoirs
F04B 37/18 - Pumps specially adapted for elastic fluids and having pertinent characteristics not provided for in, or of interest apart from, groups for special use for specific elastic fluids
F04B 39/10 - Adaptation or arrangement of distribution members
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Granados, Ludovic
Aires, Matilde
Abstract
The invention relates to a facility for storing and/or producing cryogenic hydrogen, comprising at least one catalysis section (6) comprising a catalyst, for example based on ferrous oxide, the catalysis section (6) being configured to promote ortho-para conversion of hydrogen, the facility (1) comprising a device for activating and/or regenerating the catalyst of the catalysis section (6), the activation and/or regeneration device comprising a pipe for injecting a flow of flushing gas having a temperature of greater than 20°C, the injection pipe being configured to allow a gas flush of the catalyst of the catalysis section (6).
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
F25J 1/02 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen
B01J 23/00 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group
48.
PROCESSING METHOD, PROCESSING DEVICE, PROGRAM, AND HIGH-PURITY RAW MATERIAL COMPOSITION
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Yamaguchi Daigo
Akae Naonori
Terui Yusuke
Ueno Ryota
Nesterov Vitaly
Willing Guillemin
Abstract
The present invention has: (a) a step for preparing a substrate having a recessed portion on the surface thereof; and (b) a step for forming a film on the surface of the substrate and within the recessed portion by supplying, to the substrate, a raw material that contains a halogeno group and an alkyl group and contains a silicon-silicon bond, and a reactant that contains oxygen and hydrogen, under conditions in which, if the raw material is present alone, the physical adsorption of the raw material occurs dominantly among the thermal decomposition of the raw material, the chemical adsorption of the raw material, and the physical adsorption of the raw material.
H01L 21/31 - Treatment of semiconductor bodies using processes or apparatus not provided for in groups to form insulating layers thereon, e.g. for masking or by using photolithographic techniquesAfter-treatment of these layersSelection of materials for these layers
49.
METHOD AND APPARATUS FOR SEPARATING A MIXTURE CONTAINING CO2 BY PARTIAL CONDENSATION
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Leclerc, Mathieu
Abstract
In a method for separating a CO2-containing mixture by partial condensation, said mixture (G) containing at least one impurity lighter than CO2 as well as at least one impurity in the form of SO2 or SO3, the mixture is washed in a washing column (Q), dried in a drying unit (A) and separated by partial condensation (15), a portion (25B) of the regeneration gas (25) of the drying unit being sent directly to the washing column (Q) in gaseous form.
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
50.
NEW METHOD FOR PRODUCING A COMPOSITE TANK AND NEW COMPOSITE TANK PRODUCED BY THIS METHOD
L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'EXPLOITATION DES PROCÉDÉS GEORGES CLAUDE (France)
COVESS NV (Belgium)
Inventor
Papin, Philippe
Dirix, Bert
Vanswijgenhoven, Tony
Abstract
A method for producing a fibre composite tank, includes assembling a removable moulding mandrel; applying an end fitting to the moulding mandrel, the end fitting being a metal ring having an opening; forming a first fibre composite shell layer on the moulding mandrel and on the end fitting; disassembling and removing the moulding mandrel through the opening; shrinking a metal boss by cooling; inserting the metal boss in the opening of the end fitting; expanding the metal boss by warming.
F17C 1/06 - Protecting sheatings built-up from wound-on bands or filamentary material, e.g. wires
B23P 11/02 - Connecting or disconnecting metal parts or objects by metal-working techniques, not otherwise provided for by first expanding and then shrinking or vice versa, e.g. by using pressure fluidsConnecting or disconnecting metal parts or objects by metal-working techniques, not otherwise provided for by making force fits
B29C 53/60 - Winding and joining, e.g. winding spirally helically using internal forming surfaces, e.g. mandrels
B29K 105/10 - Condition, form or state of moulded material containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns oriented
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Hirose, Kenji
Abstract
An air separation unit including: a main heat exchanger, a medium-pressure rectification column, a low-pressure rectification column, a crude argon column, a nitrogen condenser, a crude argon condenser, an oxygen turbine, a nitrogen compressor, and a nitrogen turbine. The nitrogen turbine expands nitrogen gas supplied from the nitrogen compressor. The air separation unit includes an inlet temperature of the oxygen turbine is lower than an inlet temperature of the nitrogen turbine.
F25J 3/04 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Trunk, Sebastian
Pontzen, Florian
Schack, Dominik
Vicari, Lorenzo
Ulber, Dieter
Bertail, Caroline
Schmidt, Robin
Abstract
Method for producing a hydrogen product from ammonia, comprising the steps of: - Providing an ammonia feed stream; - Passing the ammonia feed stream to at least one ammonia pre-cracking reactor for producing a partly converted ammonia feed stream comprising ammonia, hydrogen and nitrogen by a pre-cracking reaction, said pre-cracking reactor comprising a pre-cracking catalyst bed comprising from 20 wt% to 60 wt% of nickel, preferably from 25 wt% to 50 wt% of nickel as a pre-cracking catalytically active material, - Passing the partly converted ammonia feed stream to an ammonia cracking reactor for producing an effluent gas stream comprising hydrogen and nitrogen and optionally also unconverted ammonia by a cracking reaction, said cracking reactor comprising a cracking catalyst bed comprising from 10 wt% to 20 wt% of nickel as a cracking catalytically active material.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Harbal, Achraf
Leclerc, Mathieu
Tran, Michael
Demolliens, Bertrand
Abstract
The invention relates to a method for separating a gaseous mixture containing CO2 and at least one component, wherein the gaseous mixture is separated by adsorption, producing a fluid (1) enriched in CO2 and depleted in the at least one component relative to the gaseous mixture, and a gas enriched in the at least one component and depleted in CO2 relative to the gaseous mixture at a pressure higher than 6 bara, wherein the CO2-enriched fluid is separated in a separation unit, and wherein a portion of the CO2-depleted fluid is used as barrier gas in a compressor (C1, C2, C3, C4, C5, C6, C7) of the separation unit.
B01D 53/02 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
54.
SYSTEM AND METHOD OF GENERATING SINGLET OXYGEN FOR WATER PURIFICATION
L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'EXPLOITATION DES PROCÉDÉS GEORGES CLAUDE (France)
SINGLETO2 THERAPEUTICS LLC (USA)
Inventor
Mahmudov, Rovshan
Ihalagedara, Hasanuwan B.
Lyons, Alan Michael
Greer, Alexander
Xu, Qianfeng
Abstract
A system for generating singlet oxygen comprises a photosensitizer device comprising a substrate on the surface of which a photosensitizer material is coated, at least one light source configured to illuminate light at a wavelength to the photosensitizer device, a water stream containing dissolved oxygen by injecting oxygen gas into the water, a water inlet configured to feed the water stream to a flow chamber that contains the photosensitizer device, wherein the singlet oxygen is generated by contact of the water stream with the photosensitizer material under light illumination, simultaneously, the generated singlet oxygen purifies the water stream by oxidizing impurities and inactivates biological contaminants in the water stream, and a water outlet, configured to discharge a purified water.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Leclerc, Mathieu
Harbal, Achraf
Chaix, Jean-Baptiste
Abstract
The invention relates to a method for capturing CO2, wherein a stream (1) containing CO2 and at least one other component is separated by pressure swing adsorption (PSA), producing a fluid (5) enriched in CO2 at a first pressure and a fluid (3) depleted in CO2 at a second pressure, higher than the first pressure, wherein the CO2-enriched fluid is compressed in a compressor (C1), which generates compression heat and produces a compressed fluid at a pressure between 15 and 40 bar abs, wherein the compressed fluid is sent to a unit for separation via partial condensation, which produces a CO2-enriched flow, wherein the CO2-depleted fluid is expanded in two turbines (T1, T2) to produce an expanded fluid, and wherein the compression heat is used to heat the fluid upstream of each turbine.
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Yao, Huaqin
Hirose, Kenji
Tomita, Shinji
Abstract
An air separation unit may include: a main heat exchanger 1, a first rectification column 2, a nitrogen condenser 3, a second rectification column 4, a third rectification column 5, a crude argon condenser 6, a high-purity oxygen rectification column 8, and a high-purity oxygen reboiler 9. The air separation unit uses a portion of the feed air that has passed through the main heat exchanger 1 as a heat source in the high-purity oxygen reboiler 9.
F25J 3/04 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
57.
PROCESS AND APPARATUS FOR THE SEPARATION OF A GASEOUS MIXTURE INCLUDING CARBON DIOXIDE AND AT LEAST ONE COMPONENT LIGHTER THAN CARBON DIOXIDE BY PARTIAL CONDENSATION
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Leclerc, Mathieu
Ricci, Laura
Pontisso, Hugo
Raventos, Martin
Lu, Vincent
Abstract
Process for the separation of a gaseous mixture including carbon dioxide and at least one component lighter than carbon dioxide by partial condensation including the steps of: partially condensing the gaseous mixture (1), expanding the gaseous phase in a first turbine (T1) and separating the expanded gaseous phase by permeation (M).
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Hirose, Kenji
Nagata, Daisuke
Tomita, Shinji
Abstract
An oxygen liquefaction apparatus may include a heat exchanger that allows oxygen gas to be cooled and condensed with liquid nitrogen. The oxygen liquefaction apparatus may include: a differential pressure gauge that measures the difference in pressure between the hot and cold ends of an oxygen flow path; and an oxygen control unit that calculates the level of oxygen inside the heat exchanger based on the differential pressure gauge reading, that controls an oxygen control valve to adjust the level, and that controls the heat transfer area to control the condensation of the oxygen.
F25J 1/02 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
59.
METHOD AND SYSTEM FOR HEATING A REFORMER WITH AN AMMONIA-FIRED BURNER PRODUCING A STABLE FLAME
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
AMERICAN AIR LIQUIDE, INC. (USA)
Inventor
Dhungel, Bhupesh
Tsiava, Remi
Abstract
A method for heating a furnace with an ammonia-fired burner producing a stable flame including heating a first stream of ammonia through heat exchange with a stream of flue gas, thereby producing a heated first stream of ammonia. Feeding the heated first stream of ammonia to an ammonia cracker to produce a stream of cracked ammonia. Heating a stream of air through heat exchange with the stream of flue gas at a second heat exchanger to produce a heated stream of air. Feeding the heated stream of air to a burner. Feeding a second stream of ammonia to the burner. And feeding the stream of cracked ammonia to the burner for injection into the combustion space to produce a pilot flame through combustion of the injected stream of cracked ammonia and amounts of the injected heated stream of air.
C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
C01B 3/04 - Production of hydrogen or of gaseous mixtures containing hydrogen by decomposition of inorganic compounds, e.g. ammonia
C01B 3/56 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solidsRegeneration of used solids
60.
INSTALLATION AND METHOD FOR STORING AND DISTRIBUTING CRYOGENIC FLUID
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Ouakrim, Wassim
Benistand-Hector, Cyril
Try, Rasmey
Abstract
The invention relates to an installation for storing and distributing cryogenic fluid, for example liquid hydrogen, comprising a cryogenic reservoir which is buried below the ground, a liquid withdrawal circuit connected to the reservoir with a downstream end located above the ground and designed to be connected to a consumer, the withdrawal circuit comprising a cryogenic pump arranged above the ground, the installation comprising a pipe for the recovery of vaporization gas generated inside the cryogenic pump, having a downstream end connected to the reservoir, the pipe for the recovery of the vaporization gases comprising at least one device for controlling the pressure and/or flow rate of the vaporization gas returned to the reservoir and the device for controlling the pressure and/or flow rate being configured to control the pressure inside the reservoir at a pressure level which is greater than the pressure at the inlet of the cryogenic pump.
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Le Bot, Patrick
Andrich, Marine
Kofman, Nicolas
Abstract
Facility and method for hydrogen refrigeration, comprising a hydrogen circuit to be cooled, comprising: —a first and a second set of heat exchanger(s) arranged in series for exchanging heat with the hydrogen circuit to be cooled; —a first cooling device for exchanging heat with the first set of heat exchanger(s) comprising a refrigerator that operates a refrigeration cycle of a first cycle gas; —a second cooling device for exchanging heat with the second set of heat exchanger(s) comprising a refrigerator that operates a refrigeration cycle of a second cycle gas having a molar mass of less than 3 g/mol, the refrigerator of the second cooling device comprising, arranged in series in a cycle circuit: at least one centrifugal compressor, a cooling member, an expansion member and a member for reheating the second expanded cycle gas; —a system for mixing at least one additional component having a molar mass greater than 50 g/mol with the second cycle gas before it enters the at least one centrifugal compressor and a member for purifying the mixture at the outlet of the at least one compressor configured to remove the at least one additional component up to a determined residual content and located upstream of the first set of heat exchanger(s).
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
F25J 1/02 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen
62.
INTEGRATION OF SOLID OXIDE ELECTROLYSIS CELLS (SOEC) AND OXYGEN PURIFICATOR TO ENHANCE HIGH TEMPERATURE PROCESSES
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
AIR LIQUIDE JAPAN G.K. (Japan)
Inventor
Wiff Verdugo, Juan Paulo
Haridas, Sujith
Kimura, Chikashi
Iatrides, Jean-Yves
Abstract
The present disclosure relates to a method for producing a purified oxygen-containing stream, the method comprising: heating a Solid Oxide Electrolyzer Cells (SOEC) unit to a SOEC operating temperature; providing a water source or a steam source at a water source or steam source temperature; heating the water source or the steam source to produce a steam stream at a steam stream temperature; providing a sweep gas at a sweep gas temperature; feeding the steam stream and the sweep gas to the SOEC unit to produce an oxygen-containing stream and a hydrogen-containing stream; cooling the oxygen-containing stream to a temperature in the range of about 20°C to about 100°C, preferably about 40°C to about 60°C, more preferably about 44°C to about 55°C, and even more preferably about 50°C; and, after the cooling step, purifying the oxygen-containing stream to produce the purified oxygen-containing stream The present disclosure also relates a system for producing a purified oxygen-containing stream.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Hoerner, Stéphane
Aires, Mathilde
Carafa, Antony
Granados, Ludovic
Prasad, Bhadri
Abstract
The invention relates to a facility and a method for liquefying a cryogenic fluid comprising a set of heat exchangers (4, 5) in heat exchange with a supply circuit (3) and a cooling system in heat exchange with the set of heat exchangers (4, 5) comprising a cycle gas cryogenic refrigerator (10), wherein the supply circuit (3) comprises an expansion member (6) and a phase separator (7), a liquid outlet of which supplies the downstream end (23) with liquefied supply gas and a gas outlet of which is connected to a gas phase recovery member, wherein the facility (1) comprises an injection duct (8) having an upstream end (80) connected to a pressurised gas reserve of the facility, wherein the reserve supplies a gas having the same nature as the supply gas and/or a gas having the same nature as the cycle gas or a component of the cycle gas, and a downstream end (81) configured to allow the pressurised gas to be injected into the phase separator (7).
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Simanullang, Marolop
Nakadai, Yasuhiro
Nadolski, Dawid
Abstract
The present invention discloses a quenching apparatus having: a quenching chamber for air blast cooling a material using hydrogen gas; a heat exchanger for cooling the hydrogen gas; a first pipe for supplying the heat exchanger with hydrogen gas discharged from the quenching chamber; and a second pipe for supplying the quenching chamber with hydrogen gas cooled by means of the heat exchanger.
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Allidieres, Laurent
Abstract
The invention relates to a method and a device for transferring liquefied cryogenic fluid, for example liquid hydrogen, from a cryogenic tank containing liquefied cryogenic fluid having a gas phase in equilibrium with the liquid phase, the transfer of fluid to a receiver being realized at least in part by way of a pressure difference between the cryogenic tank and the fluid receiver, the method comprising a step of pressurizing the fluid contained in the cryogenic tank, a step of withdrawing liquid from the pressurized cryogenic tank, a step of measuring the volume flow rate of withdrawn fluid, a step of determining the mass of withdrawn liquid from the measured volume flow rate of withdrawn fluid and the density of the withdrawn fluid, the density of the withdrawn fluid being determined from the pressure of the fluid in the cryogenic tank measured before the pressurization step.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
AIR LIQUIDE JAPAN G.K. (Japan)
Inventor
Wiff Verdugo, Juan Paulo
Haridas, Sujith
Prost, Laurent
Kimura, Chikashi
Paubel, Xavier
Iatrides, Jean-Yves
Abstract
The present disclosure relates to a method of using flue gas heat resulting from a combustion reaction, comprising: a) providing a fuel and an oxidant; b) preheating the fuel and the oxidant to produce a preheated fuel and a preheated oxidant; c) feeding the preheated fuel and preheated oxidant to a combustion chamber; d) heating raw materials via the combustion reaction of the preheated fuel with the preheated oxidant in the combustion chamber and generating flue gas; e) transferring at least part of the heat of the flue gas exiting the combustion chamber to an intermediate fluid, thereby producing a heated intermediate fluid; f) heating a Solid Oxide Electrolyzer Cells (SOEC) unit to a SOEC operating temperature, g) exchanging heat using at least part of the heat of the heated intermediate fluid, h) providing a steam stream at a steam stream temperature and an oxygen-containing carrier gas at an oxygen-containing carrier gas temperature, and feeding the steam stream and the oxygen-containing carrier gas to the SOEC unit to produce an oxygen-containing stream and a hydrogen-containing stream; wherein exchanging heat comprises 1. preheating the fuel to produce the preheated fuel to be fed to the combustion chamber and/or 2. preheating the oxidant to produce the preheated oxidant to be fed to the combustion chamber. The present disclosure also relates to a system of using flue gas heat from a combustion reaction.
F23D 14/32 - Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid using a mixture of gaseous fuel and pure oxygen or oxygen-enriched air
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Hoerner, Stéphane
Aires, Mathilde
Carafa, Antony
Granados, Ludovic
Prasad, Bhadri
Abstract
The invention relates to a facility and a method for liquefying a cryogenic fluid comprising a set of heat exchangers (4, 5) in heat exchange with a supply circuit (3) and a cooling system in heat exchange with the set of heat exchangers (4, 5) comprising a cycle gas cryogenic refrigerator (10), wherein the supply circuit (3) comprises an expansion member (6) and a phase separator (7), a liquid outlet of which supplies the downstream end (23) with liquefied supply gas and a gas outlet of which is connected to a gas phase recovery member, wherein the facility (1) comprises an injection duct (8) having an upstream end (80) connected to a pressurised gas reserve of the facility, wherein the reserve supplies a gas having the same nature as the supply gas and/or a gas having the same nature as the cycle gas or a component of the cycle gas, and a downstream end (81) configured to allow the pressurised gas to be injected into the phase separator (7).
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Abdo, Youssef
Coleiro, Gaetan
Abstract
The invention relates to a fluid compression apparatus (1) comprising a sealed enclosure (13) intended to contain a bath (16) of cryogenic fluid, a first (3) and a second (4) compression chambers, an intake system (2) for admission into the first chamber (3), a system (6) for transfer from the first (3) to the second (4) chamber, the apparatus (1) further comprising a communicating discharge orifice (7) for compressed fluid to leave the second chamber, the apparatus (1) further comprising a discharge orifice provided with a valve (9) for discharge from the first compression chamber (3) to the bath (16) so as to let surplus liquid leave during compression of fluid in the first chamber (3), the discharge orifice communicating with the enclosure (13) via at least one flow retarder (10) configured to attenuate the speed and/or intensity of the discharged liquid flow by limiting its pressure drop.
F04B 37/08 - Pumps specially adapted for elastic fluids and having pertinent characteristics not provided for in, or of interest apart from, groups for evacuating by thermal means by condensing or freezing, e.g. cryogenic pumps
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Abdo, Youssef
Coleiro, Gaetan
Benistand-Hector, Cyril
Abstract
The invention relates to a fluid compression apparatus and method comprising first and second compression chambers, an intake system into the first chamber, a transfer system from the first chamber to the second chamber, a piston for ensuring the compression of the fluid in the first and second chambers, and an orifice for discharging the compressed fluid, the intake system comprising one or more valves, the apparatus further comprising a discharge orifice allowing communication between the first compression chamber and the bath to allow surplus liquid trapped in the first compression chamber to leave during a compression movement of the piston in the first compression chamber, the apparatus comprising a discharge valve configured to control the discharge of liquid via the discharge orifice and to prevent fluid from entering the compression chamber via the discharge orifice.
F04B 3/00 - Machines or pumps with pistons coacting within one cylinder, e.g. multi-stage
F04B 15/08 - Pumps adapted to handle specific fluids, e.g. by selection of specific materials for pumps or pump parts for liquids near their boiling point, e.g. under subnormal pressure the liquids having low boiling points
F04B 53/12 - ValvesArrangement of valves arranged in or on pistons
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Davidian, Benoit
Abstract
In a method for compressing a gas, the gas is compressed in a compressor having an intermediate stage and a final stage, an intermediate cooler for cooling the gas downstream of the intermediate stage and a final cooler for cooling the gas downstream of the final compression stage, a refrigerant coming from a source is divided into a first flow and a second flow, the first flow is sent to cool the intermediate cooler and the second flow is sent to cool the final cooler, the first and second heated flows being at different temperatures, the first heated flow is sent to provide heat to an element, producing a first cooled flow, and the second heated flow is mixed with the first cooled flow and the mixture is sent to the source.
F25J 3/04 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Bignaud, Charles
Lu, Vincent
Guerif, Pierre-Philippe
Leclerc, Mathieu
Abstract
Apparatus for separation of a gaseous mixture containing CO2, hydrogen and water includes a compressor for compressing the gaseous mixture to a first pressure between 20 to 60 bara, a temperature swing adsorption unit for drying the compressed gas mixture comprising at least two adsorbent beds, a separation unit for separation of the dry and compressed gaseous mixture in by at least one of the following techniques: partial condensation, distillation, washing and solidification to produce at least two streams, being a rich CO2 liquid enriched in CO2 and depleted in at least one of methane and hydrogen and carbon monoxide as compared with the gaseous mixture and a first residual gas depleted in CO2 and enriched in at least one of methane and hydrogen and carbon monoxide as compared with the gaseous mixture, a pressure swing adsorption unit for separation of the first residual gas depleted in CO2 by at least one pressure swing adsorption unit in order to produce at least one gas richer in CO2 than the first residual gas and at least one gas depleted in CO2 and enriched in at least one of methane and hydrogen and carbon monoxide as compared to the first residual gas, a conduit for sending to one of said adsorbent beds a regeneration gas which is at least a part of at least one gas depleted in CO2 as compared to the first residual gas.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Tran, Michael
Redon, Emilien
Granados, Ludovic
Abstract
The invention relates to a method for separating a first gaseous mixture (05) containing carbon dioxide and at least one impurity that is lighter than carbon dioxide, the first gaseous mixture originating from a storage (70) of liquid carbon dioxide, in which method the first gaseous mixture is sent to the sump of the column if its CO2 content is above a CO2 purity threshold and is sent to at least two theoretical trays above the sump of the column if its CO2 content is below the CO2 purity threshold.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
AMERICAN AIR LIQUIDE, INC. (USA)
Inventor
Kim, Daehyeon
Lee, Jooho
Noh, Wontae
Abstract
A method of forming Group 2 metal containing films on a substrate comprises a) exposing the substrate to a vapor of a Group 2 metal containing film forming composition that contains an alkaline earth metal precursor having the formula:wherein M is Be, Mg, Ca, Sr, or Ba; R1- R611010 alkyl group, a fluoro group, an alkylsilyl group, a germyl group, an alkylamide or an alkylsilylamide, b) depositing at least part of the alkaline earth metal precursor onto the substrate to form a Group 2 metal-containing film through a vapor deposition process; and c) repeating a) and b) until a desired thickness of the Group 2 metal containing film is formed.
C23C 16/18 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metallo-organic compounds
75.
APPARATUS AND METHOD FOR PROMOTING RECOVERY OF EFFECTIVE GAS IN SYNTHESIS GAS PURIFICATION PROCESS
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Ulber, Dieter
Kuzniar, Jakub
Sulkowska, Urszula
Vicari, Lorenzo
Bogucka, Kaja
Abstract
The invention relates to a safety guard process (2) for a combustion process comprising the combustion of a fuel (4), in particular an ammonia fuel (4), with a stabilizing fuel (6), said safety guard process (2) comprises the following steps of: - providing flow rate data of the fuel (4), and flow rate data of the stabilizing fuel (6) (S10); - determining safeguard data (8) based on said flow rate data (NH3, SF) of said fuels (S20); - providing threshold data (SP) indicating a stability limit of the safeguard data (S30); - comparing the safeguard data (8) with the threshold data (SP) (S40); and - carrying out a security action (12), based on the result of said comparison of the safeguard data (8) with the threshold data (SP) (S50).
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Ladous, Robin
Boye, Guillaume
Abstract
A container (1) for storing a cryogenic fluid, comprising an inner tank (2) delimiting a housing (3) intended to contain the cryogenic fluid, and an outer tank (4) arranged around the inner tank (2), the inner tank (2) and the outer tank (3) delimiting between them a thermally insulated space (5), preferably under vacuum, the container (1) being delimited in a main direction (X) by a first side (6) and a second side (7), at least one of the two sides (6, 7) comprising a connection system (8, 9) fixing the inner tank (2) inside the outer tank (4), the connection system (8, 9) comprising, in the main direction (X), a neck (81, 91) secured to the inner tank (2) and a pin (82, 92) secured to the outer tank (4), characterized in that the neck (81, 91) and the pin (82, 92) are fitted one inside the other.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Petitpas, Guillaume
Bouin, Marius
Ouakrim, Wassim
Abstract
The invention relates to a device for storing and supplying fluid, in particular hydrogen, and a vehicle comprising a cryogenic tank (2) for storing liquefied fluid, a withdrawal circuit comprising a withdrawal line (3) having a first upstream end (13) located in the tank (2) and a second downstream end (23) intended to be connected to a user member, the device (1) further comprising a system for pressurizing the tank (2) comprising a pressurization line having two ends connected to the inside of the tank (2), a vaporization heat exchanger (4) and a set of valves (6, 16, 26, 36) configured to allow the withdrawal of liquid from the tank (2), the heating of the withdrawn liquid in the vaporization heat exchanger (4) and its reintroduction into the tank (2), the device (1) further comprising a filling circuit comprising an upstream end (5) intended to be connected to a source and a downstream end (7) opening into the tank, characterized in that the filling circuit comprises a line portion coinciding or concentric with a portion of the pressurization line located in the tank (2).
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Bignaud, Charles
Leclerc, Mathieu
Abstract
The invention relates to an apparatus for separating a gas mixture containing CO2 and at least one component that is lighter than CO2, which comprises a separation unit (CC) for separation by partial condensation and/or distillation at a temperature lower than 0°C of the gas mixture (MG), generating a CO2-enriched fluid (P) and a first waste gas (PGR) depleted in CO2 which is substantially at the same pressure as the gas mixture and an apparatus for separation by pressure swing adsorption (CO2 PSA) of the first waste gas, producing a first CO2-enriched gas (GE) at a first pressure and a second waste gas (DGR) depleted in CO2 at a second pressure higher than the first pressure, a turbine (T1) and a pipe for sending the first waste gas (PGR) to expand in the turbine (T1) downstream of the separation unit (CC) and upstream of the apparatus for separation by pressure swing adsorption (CO2 PSA).
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
C01B 3/56 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solidsRegeneration of used solids
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
80.
SPIN-COATABLE METAL DOPED SILICON-CONTAINING FILM-FORMING COMPOSITIONS AND PROCESSES OF USING THEM FOR DEPOSITION
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Husson, Guillaume
Qin, Fan
Abstract
A metal doped silicon-containing film-forming composition for forming a metal doped silicon-containing film comprises: 1) at least one silicon-containing precursor, 2) a metal precursor, and 3) a solvent, wherein the metal precursor is selected from an alkyl metal, alkyl metalloxane or polymetalloxane, wherein the metal doped silicon-containing film-forming composition is capable of forming the metal doped silicon-containing film.
C23C 18/12 - Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coatingContact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
C23C 18/04 - Pretreatment of the material to be coated
81.
GROUP 2 METAL CONTAINING FILM FORMING COMPOSITIONS AND VAPOR DEPOSITION OF THE FILMS USING THE SAME
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Kim, Daehyeon
Lee, Jooho
Noh, Wontae
Abstract
A method of forming Group 2 metal containing films on a substrate comprises a) exposing the substrate to a vapor of a Group 2 metal containing film forming composition that contains an alkaline earth metal precursor having the formula:
A method of forming Group 2 metal containing films on a substrate comprises a) exposing the substrate to a vapor of a Group 2 metal containing film forming composition that contains an alkaline earth metal precursor having the formula:
A method of forming Group 2 metal containing films on a substrate comprises a) exposing the substrate to a vapor of a Group 2 metal containing film forming composition that contains an alkaline earth metal precursor having the formula:
wherein M is Be, Mg, Ca, Sr, or Ba; R1-R6 each independently are a C1-C10 alkyl group, a fluoro group, an alkylsilyl group, a germyl group, an alkylamide or an alkylsilylamide, b) depositing at least part of the alkaline earth metal precursor onto the substrate to form a Group 2 metal-containing film through a vapor deposition process; and c) repeating a) and b) until a desired thickness of the Group 2 metal-containing film is formed.
C23C 16/455 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into the reaction chamber or for modifying gas flows in the reaction chamber
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Bouin, Marius
Petitpas, Guillaume
Bravais, Patrick
Cohard, Pierrick
Abstract
The invention relates to a tank for storing cryogenic fluid, for example hydrogen or liquefied helium, having a storage shell with a cylindrical overall shape extending in a longitudinal direction that is horizontal when the tank is in the use configuration, the storage shell having, within it, a homogenization device for homogenizing the temperature of the fluid vertically in the tank, the homogenization device having at least one heat-transfer wall having a material with a coefficient of thermal conductivity of greater than 30 W·m−1·K−1, the transfer wall being arranged parallel to the longitudinal direction of the tank and extending vertically over 20 to 100% of the height of the storage shell and extending longitudinally over at least 50% of the length of the storage shell.
F17C 1/14 - Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge constructed of aluminiumPressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge constructed of non-magnetic steel
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Ayrault, Laura
Roig, Mathieu
Abstract
Process and device for producing nitrogen-purified liquid methane from a feed gas stream containing at least 98 mol % of methane and between 0.1 and 2 mol % of nitrogen, in which the feed gas stream is cooled to a temperature of between 110 K and 200 K in a first heat exchanger in countercurrent with a stream of nitrogen vapour to produce a cooled stream, a bath of liquid nitrogen is in heat exchange with the cooled stream via a second heat exchanger through which the cooled stream passes, the liquid nitrogen bath producing nitrogen vapour supplied to the first heat exchanger to produce the cooled stream, the cooled stream leaving the second heat exchanger is introduced into a distillation column with a view to its distillation, and a liquid containing at least 99.5 mol % of methane is withdrawn from the bottom of the distillation column as the final product.
C07C 7/04 - Purification, separation or stabilisation of hydrocarbonsUse of additives by distillation
B01D 5/00 - Condensation of vapoursRecovering volatile solvents by condensation
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
84.
INJECTOR FOR A GAS RESERVOIR, AND RESERVOIR EQUIPPED WITH SUCH AN INJECTOR
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Augusto, Angelo
Gonin, Remi
Abstract
An injector for a gas reservoir, the injector having a duct designed to fluidically connect a filling station and the reservoir to be filled, the duct extending along a main axis and having an inlet orifice designed to receive a pressurized gas flow coming from the filling station and an outlet orifice designed to convey said flow towards the reservoir to be filled, also including a mobile member disposed inside the duct and designed to move relative to the outlet orifice, between a first extreme position in which the mobile member provides the outlet orifice with a minimum passage section, and a second extreme position in which the mobile member provides the outlet orifice with a maximum passage section.
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Schmidt, Sophia
Linicus, Matthias
Raventos, Martin
Abstract
A process for producing hydrogen from a synthesis gas stream, in which carbon dioxide is removed from the synthesis gas stream by absorption. After the carbon dioxide has been desorbed from the absorption medium, absorption medium present in the resulting carbon dioxide stream is removed by adsorption on a solid adsorbent, for example owing to a molecular sieve effect. A portion of the carbon dioxide stream thus obtained, now free of absorption medium, is heated and used for regeneration of the laden solid adsorbent. The invention further provides a plant for performing the process according to the invention.
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
C01B 3/52 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquidsRegeneration of used liquids
L'Air Liquide, Société Anonyme pour I'Etude et l'Exploitation des Procédés Georges Claude (France)
Inventor
Shi, Chunqiong
Lu, Jian
Zhu, Hao
Peng, Huoxiang
Pathier, Didier
Cheng, Xu
Wu, Dianhui
Cai, Guolin
Abstract
The present application discloses a malt production method and a method for improving the antioxidant activity of malt, wherein grains are subjected to at least one steeping step, in which the grains are immersed in hydrogen water with a dissolved hydrogen concentration of 0.3 to 1.6 ppm. By using hydrogen rich water in malt production, it is possible to take into account simultaneous improvements to multiple quality indicators at the same time. The positive biological effects of hydrogen rich water are especially significant. The increased content of α-amino nitrogen in the malt brings greater economic benefit to malt producers. Moreover, the colour intensity and turbidity of the malt are significantly reduced, effectively solving the problem of wort often being turbid. The endogenous antioxidant activity of malt, wort and even fermented beverages is increased, as desired by malt producers and the brewing industry. No additional additives are introduced during malt production.
L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGE CLAUDE (France)
ÉCOLE NATIONALE D'INGÉNIEURS DE BREST (ENIB) (France)
Inventor
Gardelein, Arnaud
Franco, Maeva
Sharaiha, Ammar
Morel, Pascal
Abstract
Interruption system 10 configured to control transmission of an optical signal, the system comprising a solid state optical amplifier (AMP, AMP1, AMP2) configured to receive:
an input optical signal (SOE, SOE1, SOE2), and
a control signal (SC, SC1, SC2) configured to control the semiconductor optical amplifier (AMP, AMP1, AMP2),
characterised in that the interruption system further comprises a cooling device (12, 12-1, 12-2) configured to cool the semiconductor optical amplifier (AMP, AMP1, AMP2) to a temperature greater than or equal to 10 K, preferably greater than or equal to 40 K, and to cool the optical modulator to a temperature less than or equal to 90 K, preferably less than or equal to 80 K.
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Lefebvre, Philippe
Mandou, Quentin
Abstract
A device for the additive manufacturing of at least one part having a manufacturing chamber which includes, in its internal space, a manufacturing region, an irradiating means configured to irradiate at least one portion of the manufacturing region corresponding to a cross-section of the part, a gas supply system connected to the internal space of the manufacturing chamber and configured to produce a gas flow for protecting the manufacturing region when the manufacturing chamber is supplied with gas, an adjustable robot configured to utilize at least one portion of the protective gas flow, the adjustable robot comprising a measurement arm, a first frame carrying the measurement arm, a first movement arm associated with the first frame and extending parallel to a first direction, first drive means for driving the first frame, capable of causing the first frame to move in translation along the first movement arm, a second frame.
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Van Kampen, Peter
Shi, Chunqiong
Abstract
Gas-liquid injection apparatus, having a body, a liquid passage, a bypass passage, a gas inlet, a gas-liquid mixing cavity and a gas-liquid mixing passage, wherein the body includes an inlet end face and an outlet end face, and the liquid passage includes a liquid inlet that opens onto the inlet end face and a passage outlet that is arranged on the outlet end face, and includes a converging section and a throat section that are arranged in sequence downstream of the liquid inlet; one end of the bypass passage opens to the converging section, and the other end is connected to the gas-liquid mixing cavity, and the bypass passage allows liquid flowing in the liquid passage to bypass to the gas-liquid mixing cavity; the gas-liquid mixing cavity is located at the periphery of the liquid passage; the gas inlet opens onto the inlet end face.
B01F 25/312 - Injector mixers in conduits or tubes through which the main component flows with Venturi elementsDetails thereof
B01F 23/2326 - Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles adding the flowing main component by suction means, e.g. using an ejector
B01F 35/00 - Accessories for mixersAuxiliary operations or auxiliary devicesParts or details of general application
B01F 101/00 - Mixing characterised by the nature of the mixed materials or by the application field
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Shrivastava, Swatantra Kumar
Kot, Krzysztof
Abstract
A process for producing a cracked gas product comprising hydrogen from an endothermic cracking reaction of an ammonia feedstock stream, said process comprising the following steps: - Recovering heat from said cracked gas product flowing in a cracked gas conduit (23) in a heat recovery step, - Redirecting the recovered heat to at least one secondary reactor in a heat redirection step, the secondary reactor comprising a gas reaction section in which a secondary catalytic endothermic conversion of the ammonia feedstock stream into the partially converted ammonia stream is performed, - Transferring the redirected heat to the secondary catalytic endothermic conversion through a thermal conductive layer at least partly delimiting the gas reaction section, in a heat transfer step the process comprising : - Performing a heat exchanges step by performing heat exchanges between the cracked gas product and the main catalytic endothermic conversion.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Valentin, Solène
Barraud, François
Makhlouche, Rachid
Mangeant, Baptiste
Zick, Golo
Fraysse, Philippe
Abstract
In a plant and method for producing gaseous biomethane (24) and liquid carbon dioxide (11) from biogas (2), the plant comprises a first compressor (3), a first membrane separation unit (5a), a second membrane separation unit (5b), a third membrane separation unit (5c) and a conduit (23) for recycling the second permeate to upstream of the first compressor, an apparatus (9) for separating and liquefying the first permeate, a device (7) for regulating the pressure of the first permeate, and a conduit (17) for recycling non-condensable gases, which extends from the top of the distillation column downstream of the first compressor.
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
F25J 1/02 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Pages, Baptiste
Turmel, Vanessa
Abstract
The invention relates to a method for cooling hydrogen, in which method liquefied natural gas is heated by indirect heat exchange in a first heat exchanger with an intermediate fluid flow, the intermediate fluid flow is cooled, a hydrogen gas flow is cooled in a second heat exchanger without being condensed, and a gas flow derived from the cooled intermediate fluid is heated in a second heat exchanger to a temperature of between −150° C. and −90° C., which gas flow is withdrawn from the second heat exchanger at said temperature and compressed in a compressor with an inlet temperature of between −150° C. and −90° C.
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
F25J 1/02 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen
95.
PROCESS FOR THE PRODUCTION OF HYDROGEN FROM AMMONIA
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Ulber, Dieter
Jarolin, Kolja
Abstract
The invention relates to a process (1) for the production of hydrogen from ammonia comprising the following steps: in a first zone of the reactor, non- catalytically partially oxidizing the ammonia feed stream with the oxidant stream (4), thus generating heat and producing a partially oxidized stream containing ammonia, nitrogen, water, amounts of nitrogen oxides, and potentially a residual portion of oxygen. in a second zone of the reactor, homogenizing the temperature and concentration of the partially oxidized stream (5), thus producing an homogenized stream containing ammonia, nitrogen, and water, in a third zone of the reactor, catalytically cracking ammonia contained in the homogenized stream in an endothermic reaction using the generated heat (6), thus creating a cracked gas product containing nitrogen and hydrogen.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
Inventor
Plays, Thibault
Haik, Natacha
Demolliens, Bertrand
Abstract
The invention relates to an apparatus (200) for measuring the ortho-para composition of hydrogen, comprising an analyser (20) configured to measure the relative proportions of ortho and para hydrogen, the analyser being of the type that can be calibrated and/or verified by at least one reference measurement of hydrogen having a proportion of ortho and para hydrogen, the apparatus comprising a calibration and/or verification device comprising a device (100) for converting ortho hydrogen into para hydrogen, comprising a collection line (15) having an upstream end configured to be connected to a cold hydrogen source at a given temperature less than or equal to 80 K, the collection line comprising at least one catalysis section (17) for catalysing the hydrogen collected by the collection line, the catalysis section having an amount of catalyst configured to ensure the conversion of ortho hydrogen to para hydrogen until the ortho-para equilibrium composition corresponding to the given temperature is obtained.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
AMERICAN AIR LIQUIDE, INC. (USA)
Inventor
Shrivastava, Swatantra
Lutz, Michael
Ulber, Dieter
Abstract
A method for producing hydrogen using a feed stream comprising ammonia is provided. The method can include the steps of: cracking a gaseous ammonia feed in an ammonia cracker to produce a cracked gas stream comprising hydrogen, nitrogen, and unreacted ammonia; cooling the cracked gas stream to a first temperature that is sufficient for condensing at least a portion of the unreacted ammonia to form a dual phase fluid; separating the dual phase fluid in an ammonia separator to produce a liquid ammonia stream and a top gas stream comprised predominately of hydrogen and nitrogen; removing additional ammonia from the top gas stream using a front-end purification system to form a purified top gas stream; further cooling the purified top gas stream to a second temperature that is sufficient for condensing at least a portion of the nitrogen within the top gas stream to form a dual-phase stream, wherein the second temperature is colder than the first temperature; introducing the dual-phase stream to a cryogenic hydrogen separator under conditions effective for separating hydrogen and nitrogen, thereby creating a liquid nitrogen stream and a hydrogen top gas; warming and vaporizing the liquid nitrogen stream to produce a gaseous nitrogen stream; warming the hydrogen top gas to produce a gaseous hydrogen product stream: and recycling the liquid ammonia stream produced by the ammonia separator to a point upstream the ammonia cracker.
C01B 3/04 - Production of hydrogen or of gaseous mixtures containing hydrogen by decomposition of inorganic compounds, e.g. ammonia
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
F25J 1/00 - Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
C01B 3/56 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solidsRegeneration of used solids
L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude (France)
Inventor
Sirac, Denis
Andre, Johan
Abstract
The invention relates to a proton-exchange membrane fuel cell comprising a stack of a plurality of cells, the stack being sandwiched between a first clamping plate and a second clamping plate in order to apply a predetermined clamping pressure to the stack, one of the clamping plates comprising at least one tapered seat leading into a through-hole, the stack comprising at least one clamping device that comprises a tie rod and a tapered washer received by the tapered seat in such a way that the tapered portions are facing one another, the tie rod being held in position by a first of its ends by the tapered washer so as to apply a clamping pressure to the stack.
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE (France)
AMERICAN AIR LIQUIDE, INC. (USA)
Inventor
Tranier, Jean-Pierre
Fuentes, Francois
Abstract
A method for producing hydrogen using a feed stream comprising ammonia is provided. The method may include the steps of: cracking a gaseous ammonia feed comprising ammonia and at least 0.15% water vapor in an ammonia cracker to produce a cracked gas stream comprising hydrogen, nitrogen, unreacted ammonia, and water vapor; cooling the cracked gas stream to a separation temperature that is sufficient for condensing at least a portion of the unreacted ammonia and the water vapor to form a dual phase fluid; separating the dual phase fluid in a separator that is configured to produce an aqueous ammonia stream and a vapor stream, the vapor stream comprising predominantly of hydrogen and nitrogen; wherein the separation temperature is below 0°C.
C01B 3/04 - Production of hydrogen or of gaseous mixtures containing hydrogen by decomposition of inorganic compounds, e.g. ammonia
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
C01B 3/56 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solidsRegeneration of used solids
100.
METHOD FOR REMOVING LIQUID DROPLETS FROM A GAS AND PRESSURIZING THE RESULTING LIQUID
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude (France)
Inventor
Miller, Gary D.
Light, Joshua
Abstract
A method for removing entrained liquid droplets from a gas is provided. This method includes introducing a gas with entrained liquid droplets into a cyclone separator, thereby producing a gaseous portion and a liquid portion, wherein the gaseous portion exits the cyclone separator, and wherein the liquid portion is restricted by a liquid control valve and collected in a reservoir volume in the cyclone separator. The method also includes opening the liquid control valve upon receiving a signal from a liquid level sensor located in the reservoir volume, the liquid portion exits the cyclone separator and is introduced into a lock hopper. The method also provides a pressurized vapor stream to the lock hopper, thereby pressurizing the lock hopper, and then withdrawing a pressurized liquid stream from the lock hopper.