2222 and the hydrocarbon in the feedgas mixture into a product mixture comprising the primary reaction products; thereby forming a gaseous post-plasma outflow stream comprising the primary reaction products and the thermal energy.
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
2.
SYSTEMS AND METHODS FOR PRODUCING SYNGAS AND DERIVATIVES
222 into a plasma reactor: a source of microwave energy; and an outflow tract at the distal end of the reaction chamber and in fluid communication therewith, wherein the chemical products and the thermal energy exit the reaction zone as a gaseous outflow stream that enters the outflow tract to be removed from the plasma reactor.
B01J 12/00 - Chemical processes in general for reacting gaseous media with gaseous mediaApparatus specially adapted therefor
B01J 19/08 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor
C01B 3/32 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
C10J 3/10 - Continuous processes using external heating
H05H 1/46 - Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of this gas processing system.
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01J 19/08 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor
B01J 19/24 - Stationary reactors without moving elements inside
C07C 2/76 - Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
C07C 2/80 - Processes with the aid of electrical means
The invention includes a systems and methods for producing a gaseous outflow stream comprising chemical products and thermal energy, where the method includes providing a first reactant stream comprising CO2 and a second reactant stream comprising a hydrocarbon reactant, providing a plasma reactor equipped with a source of microwave energy for forming a non-thermal plasma; mixing the first reactant stream and the second reactant stream to form a feedgas mixture; directing the feedgas mixture to encounter microwave energy in the plasma reactor, wherein the microwave energy energizes the feedgas mixture to form the non-thermal plasma, thereby producing thermal energy and transforming the feedgas mixture in the non-thermal plasma into a product mixture comprising the chemical products; and directing the product mixture and the thermal energy to exit the plasma reactor, thereby forming the gaseous outflow stream comprising the chemical products and the thermal energy.
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
5.
SYSTEMS AND METHODS FOR PRODUCING SYNGAS AND DERIVATIVES
The invention includes a systems and methods for producing a gaseous outflow stream comprising chemical products and thermal energy, where the method includes providing a first reactant stream comprising CO2 and a second reactant stream comprising a hydrocarbon reactant, providing a plasma reactor equipped with a source of microwave energy for forming a non-thermal plasma; mixing the first reactant stream and the second reactant stream to form a feedgas mixture; directing the feedgas mixture to encounter microwave energy in the plasma reactor, wherein the microwave energy energizes the feedgas mixture to form the non-thermal plasma, thereby producing thermal energy and transforming the feedgas mixture in the non-thermal plasma into a product mixture comprising the chemical products; and directing the product mixture and the thermal energy to exit the plasma reactor, thereby forming the gaseous outflow stream comprising the chemical products and the thermal energy.
B01J 12/00 - Chemical processes in general for reacting gaseous media with gaseous mediaApparatus specially adapted therefor
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
C10L 3/10 - Working-up natural gas or synthetic natural gas
B01J 12/00 - Chemical processes in general for reacting gaseous media with gaseous mediaApparatus specially adapted therefor
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of the gas processing system.
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01J 4/00 - Feed devicesFeed or outlet control devices
B01J 19/08 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
B01J 19/24 - Stationary reactors without moving elements inside
C01B 3/52 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquidsRegeneration of used liquids
C10G 32/04 - Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by particle radiation
C10G 53/08 - Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one sorption step
The invention includes a system for producing a carbon dioxide conversion product, where the system includes a carbon dioxide gas source providing carbon dioxide; a delivery system for the carbon dioxide in fluid communication with the carbon dioxide gas source, wherein the delivery system delivers the carbon dioxide gas into a plasma reactor, and wherein the plasma reactor energizes the carbon dioxide gas as a plasma to produce activated carbon dioxide species.
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
The invention includes a system for producing a carbon dioxide conversion product, where the system includes a carbon dioxide gas source providing carbon dioxide; a delivery system for the carbon dioxide in fluid communication with the carbon dioxide gas source, wherein the delivery system delivers the carbon dioxide gas into a plasma reactor, and wherein the plasma reactor energizes the carbon dioxide gas as a plasma to produce activated carbon dioxide species.
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
The invention includes a system for producing a carbon dioxide conversion product, where the system includes a carbon dioxide gas source providing carbon dioxide; a delivery system for the carbon dioxide in fluid communication with the carbon dioxide gas source, wherein the delivery system delivers the carbon dioxide gas into a plasma reactor, and wherein the plasma reactor energizes the carbon dioxide gas as a plasma to produce activated carbon dioxide species; a secondary reactant source providing a secondary reactant in a secondary reactant stream that is separated from the carbon dioxide gas, wherein the secondary reactant stream is directed to contact the activated carbon dioxide species in a reaction zone, and wherein the contact between the activated carbon dioxide species and the secondary reactant in the reaction zone produces a reaction that yields the carbon dioxide conversion product. The invention also includes methods of the use of such a system for producing a carbon dioxide conversion product.
The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of this gas processing system.
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
C07C 2/76 - Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
C07C 2/80 - Processes with the aid of electrical means
The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of the gas processing system.
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
C01B 3/52 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquidsRegeneration of used liquids
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01J 4/00 - Feed devicesFeed or outlet control devices
B01J 19/08 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor
B01J 19/24 - Stationary reactors without moving elements inside
C10G 32/04 - Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by particle radiation
C10G 53/08 - Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one sorption step
The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of this gas processing system.
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
C07C 17/08 - Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated hydrocarbons
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
H05H 1/46 - Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy
C07C 2/76 - Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
C07C 2/80 - Processes with the aid of electrical means
The invention includes methods for removing higher acetylenes from a gaseous stream that includes a hydrogen fraction and a non-hydrogen fraction, wherein the gaseous stream includes less than about 4% in total of diacetylene and vinylacetylene, where the method includes the following steps: (i) an adsorption that passes the gaseous stream at a preselected superficial linear gas velocity across an adsorption bed supported within an enclosure, the adsorption bed containing a crystalline porous ceramic adsorbent to adsorb the higher acetylenes onto the adsorbent, thereby producing a saturated adsorption bed and a purified gaseous stream including less than about 25 ppm of diacetylene that regenerates the saturated adsorbent bed by passing a regeneration gas across the saturated adsorption bed to desorb the higher acetylenes retained thereupon, thereby producing a regenerated adsorbent bed and a contaminated gas stream bearing the higher acetylenes; and (iii) a purging step that removes the contaminated gas stream from the enclosure. The invention also includes systems for removing diacetylene and vinylacetylene from a hydrogen-dominant acetylene-hydrogen gaseous stream.
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
C07C 7/13 - Purification, separation or stabilisation of hydrocarbonsUse of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
B01J 20/28 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof characterised by their form or physical properties
The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of the gas processing system.
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
C01B 3/52 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquidsRegeneration of used liquids
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01J 4/00 - Feed devicesFeed or outlet control devices
B01J 19/08 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor
B01J 19/24 - Stationary reactors without moving elements inside
C10G 32/04 - Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by particle radiation
C10G 53/08 - Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one sorption step
The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of the gas processing system.
C01B 3/34 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
B01J 19/12 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor employing electromagnetic waves
C01B 3/52 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquidsRegeneration of used liquids
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01J 4/00 - Feed devicesFeed or outlet control devices
B01J 19/08 - Processes employing the direct application of electric or wave energy, or particle radiationApparatus therefor
B01J 19/24 - Stationary reactors without moving elements inside
C10G 32/04 - Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by particle radiation
C10G 53/08 - Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one sorption step
patents
