A low-power process for combining a first, lower pressure gas stream with a second, higher pressure gas stream employs a membrane device. The first and second gas streams are permeated in the device's permeation membrane, which facilitates net permeation flow from the first gas stream to the second gas stream. A low pressure stream and a separate high pressure stream are discharged from the membrane device after permeating. The low pressure stream has a flow rate less than that of the first stream and the high pressure stream has a flow rate greater than that of the second stream. Because of the membrane permeation, the low pressure stream can be combined with the high pressure stream using less compression power than would be required for direct compression of the first gas stream into the second.
B01F 25/314 - Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit
01 - Chemical and biological materials for industrial, scientific and agricultural use
40 - Treatment of materials; recycling, air and water treatment,
Goods & Services
Polymeric membranes in chemical form for the separation of gas Greenhouse gas reduction services utilizing a chemical process that operates on effluent gas streams from power plants and other sources that generate carbon dioxide
01 - Chemical and biological materials for industrial, scientific and agricultural use
40 - Treatment of materials; recycling, air and water treatment,
Goods & Services
Polymeric membranes in chemical form for the separation of gas Greenhouse gas reduction services utilizing a chemical process that operates on effluent gas streams from power plants and other sources that generate carbon dioxide
A low-power process for combining a first, lower pressure gas stream with a second, higher pressure gas stream employs a membrane device. The first and second gas streams are permeated in the device's permeation membrane, which facilitates net permeation flow from the first gas stream to the second gas stream. A low pressure stream and a separate high pressure stream are discharged from the membrane device after permeating. The low pressure stream has a flow rate less than that of the first stream and the high pressure stream has a flow rate greater than that of the second stream. Because of the membrane permeation, the low pressure stream can be combined with the high pressure stream using less compression power than would be required for direct compression of the first gas stream into the second.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 61/00 - Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltrationApparatus, accessories or auxiliary operations specially adapted therefor
B01D 63/00 - Apparatus in general for separation processes using semi-permeable membranes
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
The present invention relates to a counterflow membrane module configured to separate a feed fluid into a permeate fluid and a residue fluid across one or more membrane sheet(s). The counterflow module comprises a second end offset from a first end along the first direction where an inlet is provided at the first end and an outlet is provided at the second end. The one or more membrane sheet(s) each have a first portion, a second portion and a permeate section. A conduit is adjacent to the permeate section of the membrane and is configured to receive and output the permeate fluid separated from the feed fluid.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
The present invention relates to a crossflow membrane module configured to separate a feed fluid into a permeate fluid and a residue fluid across one or more membrane sheet(s). The crossflow module comprises a second end offset from a first end along the first direction where an inlet is provided at the first end and an outlet is provided at the second end. The one or more membrane sheet(s) each have a first portion and a second portion. A conduit is adjacent to the first side of each membrane sheet and is configured to receive and output the permeate fluid separated from the feed fluid. The second portion of the membrane sheet has a greater permeance for a major component than the first portion such that the second part of the permeate fluid, which is generated by separation across the second portion of the membrane sheet, has a higher concentration of the major component than the first part of the permeate fluid, which is generated by separation across the first portion. The second portion is spaced apart from the first side of the membrane sheet along the second direction thereby causing the second part of the permeate gas to flow towards the first side of the membrane sheet such that the second part of the permeate gas mixes with the first part of the permeate gas thereby reducing the concentration of the minor component in the first part of the permeate gas.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01D 53/10 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents with dispersed adsorbents
The present invention relates to a counterflow membrane module configured to separate a feed fluid into a permeate fluid and a residue fluid across one or more membrane sheet(s). The counterflow module comprises a second end offset from a first end along the first direction where an inlet is provided at the first end and an outlet is provided at the second end. The one or more membrane sheet(s) each have a first portion, a second portion and a permeate section. A conduit is adjacent to the permeate section of the membrane and is configured to receive and output the permeate fluid separated from the feed fluid.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
The present invention relates to a crossflow membrane module configured to separate a feed fluid into a permeate fluid and a residue fluid across one or more membrane sheet(s). The crossflow module comprises a second end offset from a first end along the first direction where an inlet is provided at the first end and an outlet is provided at the second end. The one or more membrane sheet(s) each have a first portion and a second portion. A conduit is adjacent to the first side of each membrane sheet and is configured to receive and output the permeate fluid separated from the feed fluid. The second portion of the membrane sheet has a greater permeance for a major component than the first portion such that the second part of the permeate fluid, which is generated by separation across the second portion of the membrane sheet, has a higher concentration of the major component than the first part of the permeate fluid, which is generated by separation across the first portion. The second portion is spaced apart from the first side of the membrane sheet along the second direction thereby causing the second part of the permeate gas to flow towards the first side of the membrane sheet such that the second part of the permeate gas mixes with the first part of the permeate gas thereby reducing the concentration of the minor component in the first part of the permeate gas.
A61M 1/34 - Filtering material out of the blood by passing it through a membrane, i.e. hemofiltration, diafiltration
B01D 24/42 - Feed or discharge devices for discharging filtrate
B01D 29/01 - Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups Filtering elements therefor with flat filtering elements
12.
PROCESS OF IMPROVED SULFUR CAPTURE FROM A SYNGAS MIXTURE INVOLVING ABSORPTION AND MEMBRANE DIFFUSION STEPS
A process for sweetening a syngas stream, the process comprising the steps of: providing a syngas stream to a nonselective amine absorption unit, the sour syngas stream comprising syngas, carbon dioxide, and hydrogen sulfide; separating the syngas stream in the nonselective amine absorption unit to obtain an overhead syngas stream and an acid gas stream; introducing the acid gas stream to a membrane separation unit, the acid gas stream comprising hydrogen sulfide and carbon dioxide; separating the acid gas stream in the membrane separation unit to produce a retentate stream and a permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/24 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by centrifugal force
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
13.
HYDROGEN SULFIDE-CARBON DIOXIDE MEMBRANE SEPARATION PROCESS USING PERFLUORINATED MEMBRANES
A process for recovering sulfur from a sour gas is provided. The process includes the steps of: providing the sour gas to a membrane separation unit having a carbon dioxide-selective membrane that comprises a perfluoropolymer, wherein the sour gas comprises carbon dioxide and at least 1 mol % hydrogen sulfide; separating the sour gas using the carbon dioxide-selective membrane in the membrane separation stage to obtain hydrogen sulfide-enriched gas and hydrogen sulfide-stripped gas, wherein the hydrogen sulfide-enriched gas has a hydrogen sulfide concentration of at least 20 mol %, and wherein the hydrogen sulfide-stripped gas comprises carbon dioxide; and processing the hydrogen sulfide-enriched gas in a sulfur recovery unit to obtain sulfur.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
14.
Improving Sulfur Recovery Operation with Improved Carbon Dioxide Recovery
A process for recovering sulfur and carbon dioxide from a sour gas stream, the process comprising the steps of: providing a sour gas stream to a membrane separation unit, the sour gas stream comprising hydrogen sulfide and carbon dioxide; separating the hydrogen sulfide from the carbon dioxide in the membrane separation unit to obtain a retentate stream and a first permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur; introducing the permeate stream to an amine absorption unit; and processing the permeate stream in the amine absorption unit to produce an enriched carbon dioxide stream.
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
C01B 17/04 - Preparation of sulfurPurification from gaseous sulfur compounds including gaseous sulfides
C10L 3/10 - Working-up natural gas or synthetic natural gas
15.
Process of improved sulfur capture from a syngas mixture
A process for sweetening a syngas stream, the process comprising the steps of: providing a syngas stream to a nonselective amine absorption unit, the sour syngas stream comprising syngas, carbon dioxide, and hydrogen sulfide; separating the syngas stream in the nonselective amine absorption unit to obtain an overhead syngas stream and an acid gas stream; introducing the acid gas stream to a membrane separation unit, the acid gas stream comprising hydrogen sulfide and carbon dioxide; separating the acid gas stream in the membrane separation unit to produce a retentate stream and a permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
A process for recovering sulfur from a sour gas is provided. The process includes the steps of: providing the sour gas to a membrane separation unit having a carbon dioxide-selective membrane that comprises a perfluoropolymer, wherein the sour gas comprises carbon dioxide and at least 1 mol % hydrogen sulfide; separating the sour gas using the carbon dioxide-selective membrane in the membrane separation stage to obtain hydrogen sulfide-enriched gas and hydrogen sulfide-stripped gas, wherein the hydrogen sulfide-enriched gas has a hydrogen sulfide concentration of at least 20 mol %, and wherein the hydrogen sulfide-stripped gas comprises carbon dioxide; and processing the hydrogen sulfide-enriched gas in a sulfur recovery unit to obtain sulfur.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
C08F 34/02 - Homopolymers or copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring in a ring containing oxygen
C09K 8/58 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
17.
Sulfur recovery operation with improved carbon dioxide recovery
A process for recovering sulfur and carbon dioxide from a sour gas stream, the process comprising the steps of: providing a sour gas stream to a membrane separation unit, the sour gas stream comprising hydrogen sulfide and carbon dioxide; separating the hydrogen sulfide from the carbon dioxide in the membrane separation unit to obtain a retentate stream and a first permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur; introducing the permeate stream to an amine absorption unit; and processing the permeate stream in the amine absorption unit to produce an enriched carbon dioxide stream.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
The disclosure relates to improved composite membranes for use in separating components in a fluid mixture. The composite membrane comprises an isoporous support layer which provides support to a nonporous selective layer of the composite membrane and which maintains high membrane permeance and selectivity.
B01D 69/02 - Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or propertiesManufacturing processes specially adapted therefor characterised by their properties
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 63/00 - Apparatus in general for separation processes using semi-permeable membranes
B01D 3/00 - Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
C10L 3/10 - Working-up natural gas or synthetic natural gas
C10G 70/04 - Working-up undefined normally gaseous mixtures obtained by processes covered by groups , , , , by physical processes
C10G 5/06 - Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C07C 7/04 - Purification, separation or stabilisation of hydrocarbonsUse of additives by distillation
C07C 7/12 - Purification, separation or stabilisation of hydrocarbonsUse of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
C07C 7/144 - Purification, separation or stabilisation of hydrocarbonsUse of additives using membranes, e.g. selective permeation
C07C 7/20 - Use of additives, e.g. for stabilisation
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
21.
INTEGRATED CO2 CAPTURE PROCESSES IN GAS SEPARATION TURBINES
Sweep-based gas separation processes are used for reducing carbon dioxide emissions from gas power plants. The invention involves at least two compression steps, a combustion step, a carbon dioxide capture step, a power generation step and a sweep-based membrane separation step. One of the compression steps is used for producing a low-pressure and low-temperature compressed stream treated in the carbon dioxide capture step, thus dispensing with the need to spend large amounts of energy to cool a compressed stream from a typical compressor which produces a high-pressure stream, generally of 20-30 bar or more.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
The present invention relates to a process for concurrently removing CO2 and SO2 from flue gas produced by a combustion process, comprising: (a) performing a combustion process by combusting a fuel and air in a combustion apparatus, thereby creating an exhaust stream comprising CO2 and SO2; (b) compressing the exhaust stream in a first compression step, thereby producing a first compressed gas stream; (c) providing a first membrane having a feed side and a permeate side, and being selectively permeable to CO2 and SO2 over nitrogen and to CO2 and SO2 over oxygen; (d) passing at least a portion of the first compressed gas stream across the feed side; (e) withdrawing from the feed side a CO2-and SO2-depleted residue stream; (f) withdrawing from the permeate side at a lower pressure than the first compressed gas stream, a first permeate stream enriched in CO2 and SO2; (g) passing the first permeate stream to a separation process that produces a stream enriched in CO2 and a stream enriched in SO2.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
Plate-and-frame membrane modules, assemblies and processes for separating components of a fluid mixture. The assemblies comprise of a pressure vessel filled with, and able to hold, pressurized fluid being processed. Lightweight membrane plate-and-frame modules are contained inside the vessel. Fluid directing conduits direct the fluid streams being processed into and out of the vessel and across the surface of the separating membrane. Because the modules are surrounded by high pressure fluid, the forces acting on the module are small. This means the modules can be made of lightweight, inexpensive materials, such as plastic. The design of the assemblies is such that it allows for modules to be easily replaced as needed. The assemblies are also designed for pressurized feed fluid separations and separation using a sweep fluid on the permeate side of the membrane. The pressure vessel can contain one or several membrane modules.
A gas separation process for treating exhaust gases from multiple combustion sources (203, 210), wherein an exhaust gas stream (204) is directed from a first combustion step (203) to a carbon capture step (205). An off-gas stream (207) depleted in carbon dioxide from the carbon capture step is mixed with a second exhaust stream (211) from a second combustion step (210) to form a mixed gas stream (212). The mixed gas stream is passed as a feed stream across the feed side of a membrane (213) that is selectively permeable to carbon dioxide over nitrogen and carbon dioxide over oxygen. A sweep gas stream (216), usually air, flows across the permeate side, and picks up the preferentially permeating carbon dioxide. The permeate stream withdrawn from the permeate side of the membrane is then recycled back to the combustor (203).
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
F23G 5/00 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels
F23L 7/00 - Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
F23J 15/00 - Arrangements of devices for treating smoke or fumes
F23J 15/02 - Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
F23C 6/02 - Combustion apparatus characterised by the combination of two or more combustion chambers in parallel arrangement
A separation membrane module and assembly for housing ceramic tubular membranes. The module includes a plurality of tubes containing the ceramic tubular membranes. The tubes are arranged parallel to one another and are supported by tube sheet plates at each end. Fluid-tight seals surround each membrane, preventing a permeate fluid within the inner lumen of the membrane from mixing with a feed or residue fluid in the tube interior. The module also contains a distribution pipe for introducing feed fluid into, and withdrawing residue fluid out of, the module. This configuration allows for ceramic tubular membranes to be modularized for use in an assembly that carries out many types of fluid separations.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A gas separation module and assembly for housing ceramic tubular membranes. The module includes a plurality of tubes containing the ceramic tubular membranes. The tubes are arranged parallel to one another and are supported by tube sheet plates at each end. Gas-tight seals surround each membrane, preventing a feed gas and a residue gas within the inner lumen of the membrane from mixing with a permeate gas in the tube interior. The module also contains a gas distribution pipe for withdrawing the permeate gas out of, or introducing a sweep gas into, the module. This configuration allows for ceramic tubular membranes to be modularized for use in an assembly that carries out many types of gas separations.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A process for separating components or a fluid mixture using membranes comprising a selective layer made from copolymers of an amorphous per fluorinated dioxolane and a fluorovinyl monomer. The resulting membranes have superior selectivity performance for certain fluid components of interest while maintaining fast permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A gas separation process for treating exhaust gases from combustion processes. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
F01N 3/08 - Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
F01N 3/02 - Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
29.
GAS SEPARATION MEMBRANES BASED ON FLUORINATED AND PERFLUORINATED POLYMERS
A process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of partially fluorinated or perfluorinated dioxolane monomers and a second monomer, such as dioxane or a partially fluorinated dioxolane. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A gas separation module and assembly for housing ceramic tubular membranes. The module includes a plurality of tubes containing the ceramic tubular membranes. The tubes are arranged parallel to one another and are supported by tube sheet plates at each end. Gas-tight seals surround each membrane, preventing a permeate gas within the inner lumen of the membrane from mixing with a feed or residue gas in the tube interior. The module also contains a gas distribution pipe for introducing feed gas into, and withdrawing residue out of, the module. This configuration allows for ceramic tubular membranes to be modularized for use in an assembly that carries out many types of gas separations.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A process for treating an effluent gas stream arising from a manufacturing operation that produces an olefin or an olefin derivative to recover unreacted olefin. The process involves compressing the effluent gas stream, which comprises an olefin, a paraffin, and a third gas, to produce a first compressed stream, then directing the first compressed stream to a membrane separation pretreatment step. The permeate stream withdrawn from this step is enriched in olefin and is sent to a second compressor, which produces a second compressed stream that is then cooled and condensed. The condensation step produces a liquid condensate and an uncondensed gas stream. The uncondensed gas stream undergoes a second membrane separation step to produce another olefin-enriched permeate stream, which is recirculated within the process prior to the second compression step, and an olefin-depleted residue stream, which may be purged from the process.
C07C 7/09 - Purification, separation or stabilisation of hydrocarbonsUse of additives by fractional condensation
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C07C 7/144 - Purification, separation or stabilisation of hydrocarbonsUse of additives using membranes, e.g. selective permeation
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
32.
Sweep-based membrane separation process for removing carbon dioxide from exhaust gases generated by multiple combustion sources
A gas separation process for treating exhaust gases from multiple combustion sources. The invention involves directing an exhaust gas stream from one combustion step to a carbon capture step. An off-gas stream depleted in carbon dioxide from the carbon capture step is mixed with a second exhaust stream from a second combustion step to form a mixed gas stream. The mixed gas stream is passed as a feed stream across the feed side of a membrane that is selectively permeable to carbon dioxide over nitrogen and carbon dioxide over oxygen. A sweep gas stream, usually air, flows across the permeate side, and picks up the preferentially permeating carbon dioxide. The permeate stream withdrawn from the permeate side of the membrane is then recycled back to the combustor.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
F23J 15/02 - Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
F23L 7/00 - Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
33.
Membrane-based gas separation processes to separate dehydrogenation reaction products
Gas separation processes are provided for separating dehydrogenation reaction products from a raw gas stream to recover hydrocarbons, specifically olefins, such as propylene and iso-butene, as well as unreacted feedstock. The processes employ a sequence of partial condensation steps, interspersed with membrane separation steps to raise the hydrocarbon dewpoint of the uncondensed gas, thereby avoiding the use of low-temperature or cryogenic conditions.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C07C 7/144 - Purification, separation or stabilisation of hydrocarbonsUse of additives using membranes, e.g. selective permeation
F25J 3/02 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
34.
PROCESS AND SYSTEM FOR RECOVERING NATURAL GAS LIQUIDS (NGL) FROM FLARE GAS USING JOULE-THOMSON (J-T) COOLING AND MEMBRANE SEPARATION
A process and system for recovering natural gas liquids (NGL) using a combination of J-T cooling and membrane separation. The process involves compressing, separating, and cooling a flare gas stream comprising at least methane and C3+ hydrocarbons prior to being introduced to a J-T valve. The cooled stream exiting the J-T valve is further separated, producing a NGL product stream and an uncondensed gas stream. The uncondensed gas stream is directed to a membrane separation step, which results in a C3+ hydrocarbon enriched stream and a C3+ hydrocarbon depleted stream. The C3+ hydrocarbon enriched stream may be recycled back to the process to recover more NGL.
C10L 3/10 - Working-up natural gas or synthetic natural gas
C10G 70/04 - Working-up undefined normally gaseous mixtures obtained by processes covered by groups , , , , by physical processes
C10G 5/06 - Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas by cooling or compressing
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C07C 7/04 - Purification, separation or stabilisation of hydrocarbonsUse of additives by distillation
C07C 7/12 - Purification, separation or stabilisation of hydrocarbonsUse of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
C07C 7/144 - Purification, separation or stabilisation of hydrocarbonsUse of additives using membranes, e.g. selective permeation
C07C 7/20 - Use of additives, e.g. for stabilisation
F25J 3/06 - Processes or apparatus for separating the constituents of gaseous mixtures involving the use of liquefaction or solidification by partial condensation
36.
GAS SEPARATION MEMBRANES BASED ON FLUORINATED AND PERFLUORINATED POLYMERS
A process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of an amorphous perfluorinated dioxolane and a fluorovinyl monomer. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
Disclosed herein is a process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of perfluorodioxolane monomers. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of an amorphous perfluorinated dioxolane and a fluorovinyl monomer. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers such as Teflon® AF, Hlyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of partially fluorinated or perfluorinated dioxolane monomers and a second monomer, such as dioxane or a partially fluorinated dioxolane. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A process for producing syngas with a high content of carbon monoxide, reflected in a high CO:CO2 ratio. The process involves integrating membrane-based gas separation and steam methane reforming.
C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
41.
GAS SEPARATION MEMBRANES BASED ON PERFLUORINATED POLYMERS
Disclosed herein is a process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of perfluorodioxolane monomers. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
Disclosed herein is a process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of perfluorodioxolane monomers. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
Gas separation processes are provided for separating dehydrogenation reaction products from a raw gas stream to recover hydrocarbons, specifically olefins, such as propylene and iso-butene, as well as unreacted feedstock. The processes employ a sequence of partial condensation steps, interspersed with membrane separation steps to raise the hydrocarbon dewpoint of the uncondensed gas, thereby avoiding the use of low-temperature or cryogenic conditions.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C07C 7/144 - Purification, separation or stabilisation of hydrocarbonsUse of additives using membranes, e.g. selective permeation
B01D 53/00 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols
44.
TWO-STEP MEMBRANE GAS SEPARATION PROCESS WITH MEMBRANES HAVING DIFFERENT SELECTIVITIES
A gas separation process for treating a gas stream containing vapors of condensable components. The process includes two membrane separation steps, the second step using membranes of lower selectivity than the first step. Advantageously, the first membrane separation step may be carried out outside the pressure-ratio-limited region and the second membrane separation step may be carried out within the pressure-ratio-limited region. The second residue stream is a desired product of the process, and the process is particularly useful for applications where the target concentration of component A in this product is low, such as below 1-2 vol%.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A gas-separation membrane module assembly and a gas-separation process using the assembly. The assembly includes sets of manifolds, between which are mounted arrays of membrane modules, the manifolds and membrane modules forming a stack within a pressure vessel or housing. The stacked, manifolded arrangement enables many membrane elements to be fed in parallel with the gas to be treated.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
47.
Gas separation membranes based on perfluorinated polymers
Disclosed herein is a process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of perfluorodioxolane monomers. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
Disclosed herein is a membrane separation process and system for controlling the relative concentrations of carbon dioxide, oxygen, and nitrogen within a shipping or storage container containing respiring produce. The process uses a first membrane that is selective to carbon dioxide over oxygen and nitrogen, and a second membrane that is selective to oxygen over nitrogen.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A23B 7/148 - Preserving or ripening with chemicals not covered by group or in the form of gases, e.g. fumigationCompositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
B65D 88/74 - Large containers having means for heating, cooling, aerating or other conditioning of contents
49.
SWEEP-BASED MEMBRANE GAS SEPARATION INTEGRATED WITH GAS-FIRED POWER PRODUCTION AND CO2 RECOVERY
A process involving membrane-based gas separation and power generation, specifically for controlling carbon dioxide emissions from gas-fired power plants. The process includes a compression step, a combustion step, and an expansion/electricity generation step, as in traditional power plants. The process also includes a sweep-driven membrane separation step and a carbon dioxide removal or capture step. The carbon dioxide removal step is carried out on a portion of gas from the compression step.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
F02C 3/34 - Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
50.
PROCESSES FOR THE PRODUCTION OF METHANOL USING SWEEP-BASED MEMBRANE SEPARATION STEPS
Disclosed herein are methanol production processes that include a sweep-based membrane separation step using a membrane that is selective to carbon dioxide over hydrogen. Using the processes of the invention, the efficiency of methanol production from syngas is increased by reducing the compression requirements of the process and/or improving the methanol product yield. In certain embodiments, a hydrogen-rich stream is generated; this hydrogen-rich stream can be sent for other uses. An additional benefit is that the processes of the invention may debottleneck existing methanol plants if more syngas or carbon dioxide is available, allowing for feed of imported carbon dioxide into the synthesis loop. This is a way of sequestering carbon dioxide.
C07C 29/151 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
C07C 29/76 - SeparationPurificationStabilisationUse of additives by physical treatment
Disclosed herein are methanol production processes that include a sweep-based membrane separation step using a membrane that is selective to carbon dioxide over hydrogen. Using the processes of the invention, the efficiency of methanol production from syngas is increased by reducing the compression requirements of the process and/or improving the methanol product yield. In certain embodiments, a hydrogen-rich stream is generated; this hydrogen-rich stream can be sent for other uses. An additional benefit is that the processes of the invention may debottleneck existing methanol plants if more syngas or carbon dioxide is available, allowing for feed of imported carbon dioxide into the synthesis loop. This is a way of sequestering carbon dioxide.
Processes for removing water from organic compounds, especially polar compounds such as alcohols. The processes include a membrane-based dehydration step, using a membrane that has a dioxole-based polymer selective layer or the like and a hydrophilic selective layer, and can operate even when the stream to be treated has a high water content, such as 10 wt % or more. The processes are particularly useful for dehydrating ethanol.
A gas separation process that utilizes ejector recycle with a membrane separation step in combination with a second separation step. The second separation step may be a second membrane separation, or may involve a different type of separation process. At least a portion of the non-product (i.e. residue) stream withdrawn from the second separation step is directed back to the ejector to form a processing loop. The ejector drives the gas flow in the loop and recycles the non-product stream to the first separation step.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
54.
MEMBRANE-BASED GAS SEPARATION PROCESS USING EJECTOR-DRIVEN GAS RECYCLE
Disclosed herein is a gas separation process that utilizes ejector recycle with a membrane separation step in combination with a second separation step. The second separation step may be a second membrane separation step, or may involve a different type of separation process.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
55.
GAS SEPARATION PROCESS FOR PRODUCTION OF HYDROGEN BY AUTOTHERMAL REFORMING OF NATURAL GAS, WITH CARBON DIOXIDE RECOVERY
Disclosed herein is a gas separation process for the production of hydrogen by autothermal reforming of natural gas, employing a hydrogen separation step and with simultaneous recovery of carbon dioxide using carbon dioxide-selective membrane separation. Residual gas from the hydrogen and carbon dioxide recovery is recycled back to the autothermal reformer.
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
C01B 3/56 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solidsRegeneration of used solids
C01B 3/38 - Production of hydrogen or of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
Disclosed herein is a membrane separation apparatus that includes an integrated filter element. The apparatus is useful in the conditioning of fuel gas to separate methane from C2+ hydrocarbons.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
Disclosed herein is a process for conditioning natural gas containing C2+ hydrocarbons, so that it can be used as combustion fuel to run gas-powered equipment, including gas engines and turbine-driven compressors, in the gas field or the gas processing plant. The claimed process uses preferably glassy polymeric membranes that are preferentially permeable to methane over C2+, hydrocarbons to produce a partially purified methane stream. Conditioned fuel gas has lower heating value, higher methane number, and will result in greatly reduced emissions from the engines.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
C07C 7/144 - Purification, separation or stabilisation of hydrocarbonsUse of additives using membranes, e.g. selective permeation
C10L 3/10 - Working-up natural gas or synthetic natural gas
58.
PROCESS FOR THE PRODUCTION OF METHANOL INCLUDING ONE OR MORE MEMBRANE SEPARATION STEPS
Disclosed herein is a methanol production process (311) that includes a membrane separation step or steps (305,319). Using the process of the invention, the efficiency of methanol production from syngas is increased by reducing the compression requirements of the process and/or improving the methanol product yield. As an additional advantage, the membrane separation step (305) generates a hydrogen - rich stream (307) which can be sent for other uses. An additional benefit is that the process of the invention may debottleneck existing methanol plants if more syngas or carbon dioxide is available, allowing for feed of imported carbon dioxide into the synthesis loop. This is a way of sequestering carbon dioxide.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
C07C 29/151 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
C01B 3/50 - Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
B01J 19/24 - Stationary reactors without moving elements inside
59.
Process for the production of methanol including two membrane separation steps
Disclosed herein is a methanol production process that includes at least two membrane separation steps. Using the process of the invention, the efficiency of methanol production from syngas is increased by reducing the compression requirements of the process and/or improving the methanol product yield. As an additional advantage, the first membrane separation step generates a hydrogen-rich stream which can be sent for other uses. An additional benefit is that the process of the invention may debottleneck existing methanol plants if more syngas or carbon dioxide is available, allowing for feed of imported carbon dioxide into the synthesis loop. This is a way of sequestering carbon dioxide.
Disclosed herein is a power generation process in which a portion of the carbon dioxide generated by gaseous fuel combustion is recycled back to the power generation process, either pre-combustion, post-combustion, or both. The power generation process of the invention may be a combined cycle process or a traditional power generation process. The process utilizes sweep-based membrane separation.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
F02C 3/34 - Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
F23C 9/00 - Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
61.
Gas-separation processes using membranes with permeate sweep to recover reaction feedstocks
A gas separation process for treating off-gas streams from reaction processes, and reaction processes including such gas separation. The invention involves flowing the off-gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, and passing the permeate/sweep gas mixture to the reaction. The process recovers unreacted feedstock that would otherwise be lost in the waste gases in an energy-efficient manner.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
62.
Gas separation process for production of hydrogen by autothermal reforming of natural gas, with carbon dioxide recovery
Disclosed herein is a process for the production of hydrogen by autothermal reforming of natural gas, with simultaneous recovery of carbon dioxide using carbon dioxide-selective membrane separation. Residual gas from the hydrogen and carbon dioxide recovery is recycled back to the autothermal reformer.
C01B 3/24 - Production of hydrogen or of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
C01B 3/26 - Production of hydrogen or of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
The invention is a process involving membrane -based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it (113) in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step (112) and a membrane separation step (111). A portion (107) of the carbon dioxide-enriched gas (106) can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A gas separation process for treating exhaust gases (105) from the combustion (112) of gaseous fuels (102), and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion (107) of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion (108) of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream (101), usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor (112).
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A gas separation process for treating flue gases (117) from combustion processes (112), and combustion processes including such gas separation. The invention involves routing a first portion (106) of the flue gas stream to be treated to an absorption -based carbon dioxide capture step (113), while simultaneously flowing a second portion (103) of the flue gas across the feed side of a membrane (118), flowing a sweep gas stream (101), usually air, across the permeate side, then passing the permeate/sweep gas to the combustor (112).
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.
B01D 61/00 - Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltrationApparatus, accessories or auxiliary operations specially adapted therefor
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/04 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
F23J 15/02 - Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
F23L 7/00 - Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
F23J 15/00 - Arrangements of devices for treating smoke or fumes
Disclosed herein is a power generation process in which a portion of the carbon dioxide generated by gaseous fuel combustion is recycled back to the power generation process, either pre-combustion, post-combustion, or both. The power generation process of the invention may be a combined cycle process or a traditional power generation process. The process utilizes sweep-based membrane separation.
Disclosed herein is a power generation process in which a portion of the carbon dioxide generated by gaseous fuel combustion is recycled back to the power generation process, either pre-combustion, post-combustion, or both. The power generation process of the invention may be a combined cycle process or a traditional power generation process. The process utilizes sweep-based membrane separation.
A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
B01D 53/02 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
70.
Membrane augmented distillation to separate solvents from water
United States Environmental Protection Agency (USA)
Inventor
Huang, Yu
Baker, Richard W.
Daniels, Ramin
Aldajani, Tiem
Ly, Jennifer H.
Alvarez, Franklin R.
Vane, Leland M.
Abstract
Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.
A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves flowing the flue gas stream to be treated across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
72.
DEHYDRATION PROCESSES USING MEMBRANES WITH HYDROPHOBIC COATING
Processes for removing water from organic compounds, especially polar compounds such as alcohols. The processes include a membrane-based dehydration step, using a membrane that has a dioxole-based polymer selective layer or the like and a hydrophilic selective layer, and can operate even when the stream to be treated has a high water content, such as 10wt% or more. The processes are particularly useful for dehydrating ethanol.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.
Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
The invention is a pervaporation process and pervaporation equipment, using a series of membrane modules (102 to 105, 204), and including inter-module reheating of the feed solution under treatment. The inter-module heating is achieved within the tube or vessel (101, 201) in which the modules are housed, thereby avoiding the need to repeatedly extract the feed solution from the membrane module train.
The invention is a pervaporation process and pervaporation equipment, using a series of membrane modules, and including inter-module reheating of the feed solution under treatment. The inter-module heating is achieved within the tube or vessel in which the modules are housed, thereby avoiding the need to repeatedly extract the feed solution from the membrane module train.
A gas-separation membrane assembly, and a gas-separation process using the assembly. The assembly incorporates multiple gas-separation membranes in an array within a single vessel or housing, and is equipped with two permeate ports, enabling permeate gas to be withdrawn from both ends of the membrane module permeate pipes.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A process for removing carbon dioxide or nitrogen from gas, especially natural gas. The process uses three membrane separation stages without compression between the second and third stages.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A gas-separation membrane module assembly and a gas-separation process using the assembly. The assembly includes a set of tubes, each containing gas-separation membranes, arranged within a housing. The housing contains a tube sheet that divides the space within the housing into two gas-tight spaces. A permeate collection system within the housing gathers permeate gas from the tubes for discharge from the housing.
B01D 53/22 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by diffusion
A process for producing and recovering light alcohols, particularly ethanol, alcohol mixtures containing ethanol, and ABE mixtures (alcohol mixtures containing acetone, butanol and ethanol), using a combination of steps including fermentation, first membrane separation, dephlegmation and dehydration by second membrane separation.
environmental control apparatus for separating vapors from gas streams, namely a vapor separation membrane unit comprising a membrane module and a compressing or vacuum unit to produce a pressure differential across the module, for commercial, industrial and/or municipal use
