An apparatus includes a reactor vessel containing a carbonaceous bed and having means for establishing an elevated temperature within the carbonaceous bed; and the reactor vessel also having one or more feed material inlets above the carbonaceous bed for depositing process material from outside the vessel onto the carbonaceous bed, one or more gas exhaust ports above the bed for exit of gaseous products from the vessel, and one or more slag ports at the bottom of the carbonaceous bed for exit of molten and vitreous material from the vessel; wherein the carbonaceous bed comprises bricks that contain carbon and are of varied size and shape of which at least 25% of the total carbon content of the bed comprises spent pot liner material from aluminum processing, and wherein the bricks further comprise at least one of: Portland cement, potassium silicate cement, or aluminum silicate cement.
C10B 53/08 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form in the form of briquettes, lumps or the like
A process for gasification of solid feed material to produce a syngas includes: providing a plasma heated carbonaceous bed in a bottom section of a reactor vessel; forming a bed of deposited feed material on top of the carbonaceous bed; reacting the feed material with hot gases rising from the bottom section; forming, in a middle section of the reactor vessel, a syngas mixture containing a varying quantity of unreacted particles of the feed material; allowing the syngas mixture to rise into a top section of the reactor vessel; and at least partially quenching, by injecting a quench fluid including water, steam, or a mixture thereof, in a second, upper part of the top section, at least some of the unreacted particles sufficiently to reduce the number of unreacted particles exiting the reactor vessel that are likely to be deposited on walls of external ductwork.
A method for treatment of ash from incineration plants includes: collecting ash from an incinerator; feeding the collected ash to a vitrification reactor; vitrifying the ash in the vitrification reactor, to form a slag of molten material; allowing the slag to flow from the vitrification reactor and solidify outside the vitrification reactor; gasifying volatile components in the ash and the additional feed material; and routing flue gas generated in the vitrification reactor to a heat exchanger, wherein the heat exchanger is connected to a heat recovery steam generator that receives exhaust from the incinerator.
A62D 3/40 - Processes for making harmful chemical substances harmless, or less harmful, by effecting a chemical change in the substances by heating to effect chemical change, e.g. by pyrolysis
B09B 3/00 - Destroying solid waste or transforming solid waste into something useful or harmless
C03B 5/00 - Melting in furnacesFurnaces so far as specially adapted for glass manufacture
F23J 1/00 - Removing ash, clinker, or slag from combustion chambers
F23G 5/027 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels including pretreatment pyrolising or gasifying
A62D 101/08 - Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
4.
Process and apparatus for treatment of incinerator bottom ash and fly ash
A method for treatment of ash from incineration plants includes: collecting ash from an incinerator; feeding the collected ash and additional feed material to a gasification/vitrification reactor; vitrifying the ash and additional feed material in the gasification/vitrification reactor, to form a slag of molten material; allowing the slag to flow from the gasification/vitrification reactor and solidify outside the gasification/vitrification reactor; gasifying volatile components in the ash and the additional feed material; combusting syngas generated in the gasification/vitrification reactor in a secondary combustion zone in the gasification/vitrification reactor; and supplying products of the syngas combustion to the incinerator to augment the thermal environments of the incinerator. An apparatus used to practice the method is also provided.
B09B 3/00 - Destroying solid waste or transforming solid waste into something useful or harmless
A62D 3/40 - Processes for making harmful chemical substances harmless, or less harmful, by effecting a chemical change in the substances by heating to effect chemical change, e.g. by pyrolysis
C03B 5/00 - Melting in furnacesFurnaces so far as specially adapted for glass manufacture
F23J 1/00 - Removing ash, clinker, or slag from combustion chambers
F23G 5/027 - Methods or apparatus, e.g. incinerators, specially adapted for combustion of waste or low-grade fuels including pretreatment pyrolising or gasifying
A62D 101/08 - Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
An apparatus includes a tuyere, a plasma torch positioned to inject hot gas into the tuyere, and a plurality of nozzles configured to inject a combustible material into the tuyere for combustion of the combustible material within the tuyere. The apparatus can be used to practice a method including: injecting a combustible material into a plurality of tuyeres in a wall of a reactor vessel, using a plasma torch to inject hot gas into the tuyeres to ignite the combustible material, and directing heat from combustion of the combustible material into the reactor vessel to preheat the reactor vessel.
F23D 14/22 - Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other
A process for forming and maintaining a carbonaceous bed with coke replacement units suitable for use in pyrolytic processes includes the steps of: forming a plurality of non-coke units that are either or both irregularly shaped natural wood blocks and bricks including carbon-containing fines and one or more binders; forming an initial carbonaceous bed by a quantity of particles of coke in which at least about 25% of the carbon content of the initial bed is provided by said quantity of non-coke units and up to about 75% of the carbon content of the initial bed is provided by said quantity of particles of coke; and performing a pyrolytic process with the carbonaceous bed including reacting carbon in the bed with other added process material at an elevated temperature in the bed and supplementing carbon material during the pyrolytic process by adding additional carbon material of which at least 25% of the additional carbon material is not coke.
C10B 53/08 - Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form in the form of briquettes, lumps or the like
A system and process for upgrading hydrocarbons such as heavy oils includes a high temperature plasma reactor apparatus, in one or more vessels, into which the oils are introduced along with water, such as steam, to produce lighter hydrocarbon fractions, along with carbon monoxide and hydrogen, that flows to an additional stage where more hydrocarbons and water are introduced for further fractionating reactions facilitated by reaction of carbon monoxide and water to produce carbon dioxide and nascent, or prompt, free radicals of hydrogen. Heavy hydrocarbons upgraded can include heavy oils in the form of tar sands, oil shale, and oil residuals. The vessel or vessels can each contain a carbonaceous bed facilitating the described reactions and example embodiments include one vessel with the reactions performed in a single bed and, also, two vessels with the reactions performed in a carbonaceous bed portion in each vessel.
B01J 8/04 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
A plasma gasification reactor vessel having a top section with a conical wall extending up from a bottom section, containing a carbonaceous bed into which plasma is injected by plasma torches, to a roof of the vessel is arranged in ways that can contribute to characteristics of gas flow and solids residence time that are favorable for thoroughness of reactions and yield of useful reactions products. In some cases, such a conical wall is combined in arrangements with other features such as one or more feed ports arranged to give more uniform distribution including examples with a feed port that has a distributive feed mechanism. The roof of the vessel, in some examples, has vertical outlet ports that include intrusions into the interior volume of the reactor proximate the conical wall of the top section. The configurations of outlet ports with intrusions and the configurations of feed ports for more uniform distribution of feed material are also applicable to reactor vessels with other geometries.
A system and process for upgrading hydrocarbons such as heavy oils includes high temperature plasma reactor apparatus, in one or more vessels, into which the oils are introduced along with water, such as steam, to produce lighter hydrocarbon fractions, along with carbon monoxide and hydrogen, that flows to an additional stage where more hydrocarbons and water are introduced for further fractionating reactions facilitated by reaction of carbon monoxide and water to produce carbon dioxide and nascent, or prompt, free radicals of hydrogen. Heavy hydrocarbons upgraded can include heavy oils in the form of tar sands, oil shale, and oil residuals. The vessel or vessels can each contain a carbonaceous bed facilitating the described reactions and example embodiments include one vessel with the reactions performed in a single bed and, also, two vessels with the reactions performed in a carbonaceous bed portion in each vessel.
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