A system for synthesizing carbon nanotubes (CNT) on a fiber material includes a surface treatment system adapted to modify the surface of the fiber material to receive a barrier coating upon which carbon nanotubes are to be grown, a barrier coating application system downstream of the surface treatment system adapted to apply the barrier coating to the treated fiber material surface, and a barrier coating curing system downstream of the barrier coating application systems for partially curing the applied barrier coating to enhance reception of CNT growth catalyst nanoparticles.
B01J 35/00 - Catalysts, in general, characterised by their form or physical properties
B01J 37/02 - Impregnation, coating or precipitation
B82Y 30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites
B82Y 40/00 - Manufacture or treatment of nanostructures
D06B 1/02 - Applying liquids, gases or vapours on to textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
D06B 3/10 - Passing of textile materials through liquids, gases, or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
D06B 19/00 - Treatment of textile materials by liquids, gases, or vapours, not provided for in groups
D06M 11/74 - Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphiteTreating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbidesTreating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with graphitic acids or their salts
C01B 32/162 - Preparation characterised by catalysts
2.
Composite materials formed by shear mixing of carbon nanostructures and related methods
Carbon nanostructures free of an adhered growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Under applied shear, crosslinks between the carbon nanotubes in carbon nanostructures can break to form fractured carbon nanotubes that are branched and share common walls. Methods for making polymer composites from carbon nanostructures can include combining a polymer matrix and a plurality of carbon nanostructures that are free of an adhered growth substrate, and dispersing the carbon nanostructures in the polymer matrix under applied shear. The applied shear breaks crosslinks between the carbon nanotubes to form a plurality of fractured carbon nanotubes that are dispersed as individuals in the polymer matrix. Polymer composites can include a polymer matrix and a plurality of fractured carbon nanotubes dispersed as individuals in the polymer matrix.
Described herein are multi-functional composite materials containing energy storage assemblies that can be significantly resistant to tension/compression stress. The energy storage assemblies can contain at least one energy storage layer that contains an insulating layer having a plurality of openings arranged in a spaced apart manner, and a plurality of energy storage devices, each energy storage device being contained within one of the openings. The energy storage devices can be electrically connected to one another. The energy storage layer can contain a support material upon which electrical connections are formed. One or more energy storage layers can be disposed between two or more stress carrying layers to form an energy storage assembly that can have significant resistance to tension/compression stress. Energy storage devices suitable for use in the energy storage assemblies can include, for example, batteries, capacitors and/or supercapacitors. Methods for producing the energy storage assemblies are also described.
H01G 9/26 - Structural combinations of electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices with each other
H01G 11/84 - Processes for the manufacture of hybrid or EDL capacitors, or components thereof
H05K 3/32 - Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
4.
CNT-infused carbon fiber materials and process therefor
A composition includes a carbon nanotube (CNT)-infused carbon fiber material that includes a carbon fiber material of spoolable dimensions and carbon nanotubes (CNTs) infused to the carbon fiber material. The infused CNTs are uniform in length and uniform in distribution. The CNT infused carbon fiber material also includes a barrier coating conformally disposed about the carbon fiber material, while the CNTs are substantially free of the barrier coating. A continuous CNT infusion process includes: (a) functionalizing a carbon fiber material; (b) disposing a barrier coating on the functionalized carbon fiber material (c) disposing a carbon nanotube (CNT)-forming catalyst on the functionalized carbon fiber material; and (d) synthesizing carbon nanotubes, thereby forming a carbon nanotube-infused carbon fiber material.
D06M 11/74 - Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphiteTreating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbidesTreating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with graphitic acids or their salts
D02G 3/16 - Yarns or threads made from mineral substances
D03D 15/00 - Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
D04H 1/76 - Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres otherwise than in a plane, e.g. in a tubular way
Objects produced by conventional three-dimensional printing methods are often incompletely consolidated and are not easily repaired. Printing compositions to address this issue can include a solidifiable matrix and a microwave absorber dispersed in the solidifiable matrix. The microwave absorber can be a plurality of carbon nanostructures containing a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Methods for processing a three-dimensional printed object can include: providing a three-dimensional printed object formed from a printing composition containing a solidifiable matrix and a microwave absorber dispersed in the solidifiable matrix, and applying a focused input of microwave radiation to the printed object at one or more locations. Applying the microwave radiation heats the microwave absorber at the one or more locations and promotes consolidation of the printing composition within the printed object.
Objects produced by conventional three-dimensional printing methods often have limited structural quality. Printing compositions to address this issue can include a solidifiable matrix and a plurality of carbon nanostructures dispersed in the solidifiable matrix. The carbon nanostructures include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Three-dimensional printing methods utilizing such printing compositions can include: depositing the printing composition in a layer-by-layer deposition process, and while depositing the printing composition, applying a focused input of microwave radiation in proximity to a location where the printing composition is being deposited. The focused input of microwave radiation heats the carbon nanostructures at the location and promotes consolidation of the printing composition within an object being produced by the layer-by-layer deposition process.
Objects produced by conventional three-dimensional printing methods often have limited structural quality. Printing compositions to address this issue can include a solidifiable matrix and a plurality of carbon nanostructures dispersed in the solidifiable matrix. The carbon nanostructures include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Three-dimensional printing methods utilizing such printing compositions can include: depositing the printing composition in a layer-by-layer deposition process, and while depositing the printing composition, applying a focused input of microwave radiation in proximity to a location where the printing composition is being deposited. The focused input of microwave radiation heats the carbon nanostructures at the location and promotes consolidation of the printing composition within an object being produced by the layer-by-layer deposition process.
B33Y 70/00 - Materials specially adapted for additive manufacturing
B29C 64/153 - Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
B29C 70/12 - Fibrous reinforcements only characterised by the structure of fibrous reinforcements using fibres of short length, e.g. in the form of a mat
B82Y 30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites
Objects produced by conventional three-dimensional printing methods are often incompletely consolidated and are not easily repaired. Printing compositions to address this issue can include a solidifiable matrix and a microwave absorber dispersed in the solidifiable matrix. The microwave absorber can be a plurality of carbon nanostructures containing a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Methods for processing a three-dimensional printed object can include: providing a three-dimensional printed object formed from a printing composition containing a solidifiable matrix and a microwave absorber dispersed in the solidifiable matrix, and applying a focused input of microwave radiation to the printed object at one or more locations. Applying the microwave radiation heats the microwave absorber at the one or more locations and promotes consolidation of the printing composition within the printed object.
Carbon nanostructures can convey enhanced electrical conductivity to various substrates, while maintaining a high surface area and low density per unit area. Such substrates can provide good shielding against electromagnetic radiation over a wide range of frequencies. Electrically conductive structures can include a support layer containing a plurality of fibers having apertures defined between the fibers, and a plurality of carbon nanostructures at least partially conformally coating the fibers and bridging across the apertures defined between adjacent fibers to form a continuous carbon nanostructure layer. Each carbon nanostructure can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another.
B05D 5/12 - Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
10.
Carbon nanostructure-coated fibers of low areal weight and methods for producing the same
Carbon nanostructures can convey enhanced electrical conductivity to various substrates, while maintaining a high surface area and low density per unit area. Such substrates can provide good shielding against electromagnetic radiation over a wide range of frequencies. Electrically conductive structures can include a support layer containing a plurality of fibers having apertures defined between the fibers, and a plurality of carbon nanostructures at least partially conformally coating the fibers and bridging across the apertures defined between adjacent fibers to form a continuous carbon nanostructure layer. Each carbon nanostructure can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another.
Carbon nanostructures can be formed into polymer composites that are electrically conductive and highly reflective of microwave radiation, thereby facilitating transmission of the microwave radiation. Microwave transmission assemblies containing carbon nanostructures can include an elongate structure containing elongate opposing surfaces that extend the length of the elongate structure and that are spaced apart from one another with a channel region defined in between. The elongate opposing surfaces include a polymer composite containing a polymer matrix and a plurality of carbon nanostructures. Each carbon nanostructure can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another.
A carbon nanostructure that is free of a growth substrate adhered to the carbon nanostructure can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Carbon nanostructures can be agglomerated with one another and densified to form a carbon nanostructure layer in which at least a portion of the carbon nanotubes in each carbon nanostructure are aligned substantially parallel to one another. Methods for forming a carbon nanostructure layer can include providing a plurality of carbon nanostructures that are free of a growth substrate adhered to each carbon nanostructure, and forming a carbon nanostructure layer by depositing the carbon nanostructures on a surface.
C08G 63/48 - Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acidsPolyesters chemically modified by esterification by resin acids
B82Y 30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites
B82Y 40/00 - Manufacture or treatment of nanostructures
B82B 3/00 - Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
B82B 1/00 - Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
A carbon nanostructure that is free of a growth substrate adhered to the carbon nanostructure can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Carbon nanostructures can be agglomerated with one another and densified to form a carbon nanostructure layer in which at least a portion of the carbon nanotubes in each carbon nanostructure are aligned substantially parallel to one another. Methods for forming a carbon nanostructure layer can include providing a plurality of carbon nanostructures that are free of a growth substrate adhered to each carbon nanostructure, and forming a carbon nanostructure layer by depositing the carbon nanostructures on a surface.
Carbon nanostructures can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another, thereby defining a porous space having a tortuous path within the carbon nanostructures. The porous space can be used for sequestering a range of particulate sizes from various types of substances. Separation membranes can include a separation body having an effective pore size of about 1 micron or less and providing a tortuous path for passage of a substance therethrough. The separation body can include carbon nanostructures.
Carbon nanostructures can be formed into polymer composites that are electrically conductive and highly reflective of microwave radiation, thereby facilitating transmission of the microwave radiation. Microwave transmission assemblies containing carbon nanostructures can include an elongate structure containing elongate opposing surfaces that extend the length of the elongate structure and that are spaced apart from one another with a channel region defined in between. The elongate opposing surfaces include a polymer composite containing a polymer matrix and a plurality of carbon nanostructures. Each carbon nanostructure can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another.
Carbon nanostructures free of an adhered growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Under applied shear, crosslinks between the carbon nanotubes in carbon nanostructures can break to form fractured carbon nanotubes that are branched and share common walls. Methods for making polymer composites from carbon nanostructures can include combining a polymer matrix and a plurality of carbon nanostructures that are free of an adhered growth substrate, and dispersing the carbon nanostructures in the polymer matrix under applied shear. The applied shear breaks crosslinks between the carbon nanotubes to form a plurality of fractured carbon nanotubes that are dispersed as individuals in the polymer matrix. Polymer composites can include a polymer matrix and a plurality of fractured carbon nanotubes dispersed as individuals in the polymer matrix.
A carbon nanostructure that is free of a growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. The carbon nanostructure can be released from a growth substrate in the form of a flake material. Optionally, the carbon nanotubes of the carbon nanostructure can be coated, such as with a polymer, or a filler material can be present within the porosity of the carbon nanostructure. Methods for forming a carbon nanostructure that is free of a growth substrate can include providing a carbon nanostructure adhered to a growth substrate, and removing the carbon nanostructure from the growth substrate to form a carbon nanostructure that is free of the growth substrate. Various techniques can be used to affect removal of the carbon nanostructure from the growth substrate. Isolation of the carbon nanostructure can further employ various wet and/or dry separation techniques.
B01J 2/30 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic using agents to prevent the granules sticking togetherRendering particulate materials free flowing in general, e.g. making them hydrophobic
B82Y 30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites
A carbon nanostructure that is free of a growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. The carbon nanostructure can be released from a growth substrate in the form of a flake material. Optionally, the carbon nanotubes of the carbon nanostructure can be coated, such as with a polymer, or a filler material can be present within the porosity of the carbon nanostructure. Methods for forming a carbon nanostructure that is free of a growth substrate can include providing a carbon nanostructure adhered to a growth substrate, and removing the carbon nanostructure from the growth substrate to form a carbon nanostructure that is free of the growth substrate. Various techniques can be used to affect removal of the carbon nanostructure from the growth substrate. Isolation of the carbon nanostructure can further employ various wet and/or dry separation techniques.
Carbon nanostructures free of an adhered growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Under applied shear, crosslinks between the carbon nanotubes in carbon nanostructures can break to form fractured carbon nanotubes that are branched and share common walls. Methods for making polymer composites from carbon nanostructures can include combining a polymer matrix and a plurality of carbon nanostructures that are free of an adhered growth substrate, and dispersing the carbon nanostructures in the polymer matrix under applied shear. The applied shear breaks crosslinks between the carbon nanotubes to form a plurality of fractured carbon nanotubes that are dispersed as individuals in the polymer matrix. Polymer composites can include a polymer matrix and a plurality of fractured carbon nanotubes dispersed as individuals in the polymer matrix.
B32B 3/26 - Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layerLayered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a layer with cavities or internal voids
B32B 3/06 - Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions for securing layers togetherLayered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions for attaching the product to another member, e.g. to a support
20.
Composite materials formed by shear mixing of carbon nanostructures and related methods
Carbon nanostructures free of an adhered growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. Under applied shear, crosslinks between the carbon nanotubes in carbon nanostructures can break to form fractured carbon nanotubes that are branched and share common walls. Methods for making polymer composites from carbon nanostructures can include combining a polymer matrix and a plurality of carbon nanostructures that are free of an adhered growth substrate, and dispersing the carbon nanostructures in the polymer matrix under applied shear. The applied shear breaks crosslinks between the carbon nanotubes to form a plurality of fractured carbon nanotubes that are dispersed as individuals in the polymer matrix. Polymer composites can include a polymer matrix and a plurality of fractured carbon nanotubes dispersed as individuals in the polymer matrix.
Carbon nanostructure growth on a substrate can be evaluated by visual imaging techniques. Methods for imaging carbon nanostructures on a substrate can include providing a plurality of carbon nanostructures infused to a substrate; acquiring an image of the plurality of carbon nanostructures while they are infused to the substrate; converting the image of the plurality of carbon nanostructures into a binary image, the binary image comprising a carbon nanostructure/substrate portion and an extraneous portion; and correlating the carbon nanostructure/substrate portion of the binary image with an amount of carbon nanostructures infused to the substrate. An illustrative substrate can be one or more fibers onto which carbon nanostructures are infused.
A composition includes a carbon nanotube (CNT) yarn or sheet and a plurality of carbon nanostructures (CNSs) infused to a surface of the CNT yarn or sheet, wherein the CNSs are disposed substantially radially from the surface of the CNT yarn or outwardly from the sheet. Such compositions can be used in various combinations in composite articles.
A shielded wire includes a carbon nanostructure (CNS)-shielding layer including a CNS material in a matrix material, the CNS-shielding layer being monolithic and disposed about a dielectric layer and a conducting wire, wherein the dielectric layer is disposed between the CNS-shielding layer and the conducting wire. An extruded thermoplastic jacket includes a CNS material, the extruded thermoplastic jacket being configured to protect at least one wire. A thermoplastic article includes a CNS-infused fiber material and a flexible thermoplastic.
A quality control system for the manufacture of carbon nanostructure-laden substrates includes a resistance measurement module for continuously measuring resistance of the carbon nanostructure (CNS)-laden substrate.
An energy storage device can include at least one electrode that comprise a plurality carbon nanostructure (CNS)-infused fibers in contact with an active material and an electrolyte.
A system includes a reusable substrate upon which a carbon nanostructure is formed as a carbon nanostructure-laden reusable substrate, a first conveyor system adapted to continuously convey the reusuable substrate through a carbon nanotube catalyst application station and carbon nanostructure growth station, and a second conveyor system adapted to create an interface between a second substrate and the carbon nanostructure-laden reusuable substrate, the interface facilitating transfer of a carbon nanostructure from the carbon nanostructure-laden reusuable substrate to the second substrate. A method includes growing a carbon nanostructure on a reusable substrate, the carbon nanostructure includes a carbon nanotube polymer having a structural morphology comprising interdigitation, branching, crosslinking, and shared walls and transferring the carbon nanostructure to a second substrate to provide a carbon nanostructure-laden second substrate. The method is adapted for continuous carbon nanostructure production on the reusable substrate. A pre-preg includes such a carbon nanostructure.
An electrode includes a substrate having a carbon nanostructure (CNS) disposed thereon and a coating including an active material conformally disposed about the carbon nanostructure and the substrate. The electrode is used in a hybrid capacitor-battery having a bifunctional electrolyte capable of energy storage.
An apparatus for growing carbon nanostructures (CNSs) on a substrate can include at least two CNS growth zones with at least one intermediate zone disposed therebetween and a substrate inlet before the CNS growth zones sized to allow a spoolable length substrate to pass therethrough.
Toolings containing a composite having a coefficient of thermal expansion of less than about 5 ppm/°C are described. The composites contain a matrix material and a carbon nanotube material and are operable for forming a part thereon. Methods for forming such toolings and use of such toolings to form parts thereon are also described. The carbon nanotube material can be a carbon nanotube-infused fiber material. Use of the carbon nanotube material in the tooling allows decreased curing and consolidation process times of the part to be realized.
B29C 47/00 - Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor (extrusion blow-moulding B29C 49/04)
A shielded wire includes a carbon nanostructure (CNS)-shielding layer including a CNS material in a matrix material, the CNS-shielding layer being monolithic and disposed about a dielectric layer and a conducting wire, wherein the dielectric layer is disposed between the CNS-shielding layer and the conducting wire. An extruded thermoplastic jacket includes a CNS material, the extruded thermoplastic jacket being configured to protect at least one wire. A thermoplastic article includes a CNS-infused fiber material and a flexible thermoplastic.
H01B 7/00 - Insulated conductors or cables characterised by their form
H01B 3/00 - Insulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties
H01B 1/24 - Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon, or silicon
H05K 9/00 - Screening of apparatus or components against electric or magnetic fields
31.
IONICALLY CONDUCTIVE POLYMERS, METHODS FOR PRODUCTION THEREOF AND ELECTRICAL DEVICES MADE THEREFROM
The electrical conductivity of ionically conductive polymers can be increased by polymerizing a mixture of a polymer precursor and an electrolyte in the presence of an electric field. Methods for making ionically conductive polymers can include providing a mixture containing an electrolyte and a polymer precursor, and polymerizing the polymer precursor while applying an electric field to the mixture. Ionically conductive polymers so prepared can be used in electrical devices. Methods for making electrical devices containing the ionically conductive polymers are also described.
Methods for depositing a coating on a metal surface can include heating a metal surface to a temperature not greater than its melting point; while heating the metal surface, applying a vacuum thereto; and while heating the metal surface, releasing the vacuum and backfilling with a first purge gas, where the first purge gas is reactive with the heated metal surface so as to deposit at least one layer of a coating thereon. The present methods can be used to deposit a coating in situ during the fabrication of solar receivers, in which the solar receivers contain an annulus defined by a metal tube as the inner surface and a material that is at least partially transparent to solar radiation as the outer surface.
C23C 14/56 - Apparatus specially adapted for continuous coatingArrangements for maintaining the vacuum, e.g. vacuum locks
C23C 8/06 - Solid state diffusion of only non-metal elements into metallic material surfacesChemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
33.
CARBON FIBER SUBSTRATES HAVING CARBON NANOTUBES GROWN THEREON AND PROCESSES FOR PRODUCTION THEREOF
Processes for growing carbon nanotubes on carbon fiber substrates are described herein. The processes can include depositing a catalyst precursor on a carbon fiber substrate, optionally depositing a non-catalytic material on the carbon fiber substrate, and after depositing the catalyst precursor and the optional non-catalytic material, exposing the carbon fiber substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The carbon nanotube growth conditions can convert the catalyst precursor into a catalyst that is operable for growing carbon nanotubes. The carbon fiber substrate can remain stationary or be transported while the carbon nanotubes are being grown. Optionally, the carbon fiber substrates can include a barrier coating and/or be free of a sizing agent. Carbon fiber substrates having carbon nanotubes grown thereon are also described.
A wire includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes. An electromagnetic shield for a wire includes a plurality of carbon nanotube infused fibers, in which the infused carbon nanotubes are aligned radially about the fiber axes. The plurality of carbon nanotube infused fibers are arranged circumferentially about the wire with the fiber axes parallel to the wire. A self-shielded wire includes 1) a wire that includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes; and 2) an electromagnetic shield that includes a plurality of carbon nanotube infused fibers in which the carbon nanotubes are aligned radially about the fiber axes. The axes of the carbon nanotube infused fibers of the wire and the carbon nanotube infused fibers of the electromagnetic shield share are parallel.
Processes for growing carbon nanotubes on carbon fiber substrates are described herein. The processes can include depositing a catalyst precursor on a carbon fiber substrate, optionally depositing a non-catalytic material on the carbon fiber substrate, and after depositing the catalyst precursor and the optional non-catalytic material, exposing the carbon fiber substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The carbon nanotube growth conditions can convert the catalyst precursor into a catalyst that is operable for growing carbon nanotubes. The carbon fiber substrate can remain stationary or be transported while the carbon nanotubes are being grown. Optionally, the carbon fiber substrates can include a barrier coating and/or be free of a sizing agent. Carbon fiber substrates having carbon nanotubes grown thereon are also described.
C23C 16/00 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
B82Y 30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites
C23C 16/54 - Apparatus specially adapted for continuous coating
C23C 16/458 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for supporting substrates in the reaction chamber
Methods for growing carbon nanotubes on glass substrates, particularly glass fiber substrates, are described herein. The methods can include depositing a catalytic material or a catalyst precursor on a glass substrate; depositing a non-catalytic material on the glass substrate prior to, after, or concurrently with the catalytic material or catalyst precurosr; and exposing the glass substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The glass substrate, particularly a glass fiber substrate, can be transported while the carbon nanotubes are being grown thereon. Catalyst precursors can be converted into a catalyst when exposed to carbon nanotube growth conditions. The catalytic material or catalyst precursor and the non-catalytic material can be deposited from a solution containing water as a solvent. Illustrative deposition techniques include, for example, spray coating and dip coating.
B05D 5/06 - Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
B05D 5/12 - Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
37.
Glass substrates having carbon nanotubes grown thereon and methods for production thereof
Methods for growing carbon nanotubes on glass substrates, particularly glass fiber substrates, are described herein. The methods can include depositing a catalytic material or a catalyst precursor on a glass substrate; depositing a non-catalytic material on the glass substrate prior to, after, or concurrently with the catalytic material or catalyst precursor; and exposing the glass substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The glass substrate, particularly a glass fiber substrate, can be transported while the carbon nanotubes are being grown thereon. Catalyst precursors can be converted into a catalyst when exposed to carbon nanotube growth conditions. The catalytic material or catalyst precursor and the non-catalytic material can be deposited from a solution containing water as a solvent. Illustrative deposition techniques include, for example, spray coating and dip coating.
C23C 16/00 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
C23C 16/458 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for supporting substrates in the reaction chamber
C23C 16/54 - Apparatus specially adapted for continuous coating
B05D 3/10 - Pretreatment of surfaces to which liquids or other fluent materials are to be appliedAfter-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
38.
METAL SUBSTRATES HAVING CARBON NANOTUBES GROWN THEREON AND METHODS FOR PRODUCTION THEREOF
The present disclosure describes methods for growing carbon nanotubes on metal substrates. The methods include depositing a catalytic material on a metal substrate to form a catalyst-laden metal substrate; optionally depositing a non-catalytic material on the metal substrate prior to, after, or concurrently with the catalytic material; conveying the catalyst-laden metal substrate through a carbon nanotube growth reactor having carbon nanotube growth conditions therein; and growing carbon nanotubes on the catalyst-laden metal substrate. The catalyst-laden metal substrate can optionally remain stationary while the carbon nanotubes are being grown. The catalytic material can be a catalyst or a catalyst precursor. The catalytic material and the optional non-catalytic material can be deposited on the metal substrate from one or more solutions by, for example, spray coating or dip coating techniques.
B05D 5/12 - Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
39.
STRUCTURAL ENERGY STORAGE ASSEMBLIES AND METHODS FOR PRODUCTION THEREOF
Described herein are multi-functional composite materials containing energy storage assemblies that can be significantly resistant to tension/compression stress. The energy storage assemblies can contain at least one energy storage layer that contains an insulating layer having a plurality of openings arranged in a spaced apart manner, and a plurality of energy storage devices, each energy storage device being contained within one of the openings. The energy storage devices can be electrically connected to one another. The energy storage layer can contain a support material upon which electrical connections are formed. One or more energy storage layers can be disposed between two or more stress carrying layers to form an energy storage assembly that can have significant resistance to tension/compression stress. Energy storage devices suitable for use in the energy storage assemblies can include, for example, batteries, capacitors and/or supercapacitors. Methods for producing the energy storage assemblies are also described.
Processes for growing carbon nanotubes on metal substrates are described herein. The processes include depositing a catalyst precursor on a metal substrate, optionally depositing a non-catalytic material on the metal substrate, and after depositing the catalyst precursor and the optional non-catalytic material, exposing the metal substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The carbon nanotube growth conditions convert the catalyst precursor into a catalyst that is operable for growing carbon nanotubes. The metal substrate can remain stationary or be transported while the carbon nanotubes are being grown. Metal substrates having carbon nanotubes grown thereon are also described.
B05D 5/12 - Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
41.
Structural energy storage assemblies and methods for production thereof
Described herein are multi-functional composite materials containing energy storage assemblies that can be significantly resistant to tension/compression stress. The energy storage assemblies can contain at least one energy storage layer that contains an insulating layer having a plurality of openings arranged in a spaced apart manner, and a plurality of energy storage devices, each energy storage device being contained within one of the openings. The energy storage devices can be electrically connected to one another. The energy storage layer can contain a support material upon which electrical connections are formed. One or more energy storage layers can be disposed between two or more stress carrying layers to form an energy storage assembly that can have significant resistance to tension/compression stress. Energy storage devices suitable for use in the energy storage assemblies can include, for example, batteries, capacitors and/or supercapacitors. Methods for producing the energy storage assemblies are also described.
Electrical devices having a plurality of stacked electrode layers are described. At least one of the electrode layers contains continuous fibers that are infused with carbon nanotubes. The continuous fibers can be disposed upon an electrically conductive base plate. The electrical devices can further contain an electrolyte contacting each electrode layer and a layer of separator material disposed between each electrode layer, in which case the electrical devices can form a supercapacitor. Such supercapacitors can have a capacitance of at least about 1 Farad/gram of continuous fibers. The capacitance can be increased by coating at least a portion of the infused carbon nanotubes with a material such as, for example, a conducting polymer, a main group metal compound, and/or a transition metal compound. Methods for producing the electrical devices are also described.
Electrical devices having a plurality of stacked electrode layers are described. At least one of the electrode layers contains continuous fibers that are infused with carbon nanotubes. The continuous fibers can be disposed upon an electrically conductive base plate. The electrical devices can further contain an electrolyte contacting each electrode layer and a layer of separator material disposed between each electrode layer, in which case the electrical devices can form a supercapacitor. Such supercapacitors can have a capacitance of at least about 1 Farad/gram of continuous fibers. The capacitance can be increased by coating at least a portion of the infused carbon nanotubes with a material such as, for example, a conducting polymer, a main group metal compound, and/or a transition metal compound. Methods for producing the electrical devices are also described.
Carbon nanotube-infused fiber materials containing substantially parallel-aligned, infused carbon nanotubes are described herein. The carbon nanotube-infused fiber materials contain a fiber material and a layer of carbon nanotubes infused to the fiber material, where the infused carbon nanotubes are aligned substantially parallel to the longitudinal axis of the fiber material and at least a portion of the substantially parallel-aligned, infused carbon nanotubes are crosslinked to each other, to the fiber material, or both. Crosslinking can occur through covalent bonding or pi-stacking interactions, for example. The carbon nanotube-infused fiber materials can further contain additional carbon nanotubes that are grown on the layer of substantially parallel-aligned, infused carbon nanotubes. Composite materials containing the carbon nanotube-infused fiber materials and methods for production of the carbon nanotube-infused fiber materials are also described herein.
Flame-resistant composite materials containing carbon nanotubes are described herein. The flame-resistant composite materials contain an outer layer and at least one inner layer, containing a first polymer matrix and a second polymer matrix, respectively. The outer layer has an exterior surface and a first carbon nanotube-infused fiber material that contains a first fiber material and a first plurality of carbon nanotubes greater than about 50 μηι in length. In some embodiments, the at least one inner layer also contains a second fiber material and/or a second carbon nanotube-infused fiber material containing a second fiber material and a second plurality of carbon nanotubes. When present, the second plurality of carbon nanotubes are generally shorter in length than the first plurality of carbon nanotubes. Alignment of the carbon nanotubes in the outer layer can transfer heat away from the composite material's inner layer(s). Flame-resistant articles containing carbon nanotube- infused fiber materials are also described.
B32B 1/00 - Layered products having a non-planar shape
B32B 15/02 - Layered products essentially comprising metal in a form other than a sheet, e.g. wire, particles
B05D 7/14 - Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
An apparatus having a composite land-based structure with a first carbon nanotube infused material and a second carbon nanotube infused material. The first and second carbon nanotube infused materials each having a range of carbon nanotube loading selected to provide different functionalities.
An apparatus having a composite air-based structure with a first carbon nanotube infused material and a second carbon nanotube infused material. The first and second carbon nanotube infused materials each having a range of carbon nanotube loading selected to provide different functionalities.
D02G 3/02 - Yarns or threads characterised by the material or by the materials from which they are made
C23C 16/44 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
D03D 15/00 - Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
An apparatus having a composite sea-based structure with a first carbon nanotube infused material and a second carbon nanotube infused material. The first and second carbon nanotube infused materials each having a range of carbon nanotube loading selected to provide different functionalities.
D02G 3/02 - Yarns or threads characterised by the material or by the materials from which they are made
C23C 16/44 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
D03D 15/00 - Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
49.
Spiral wound electrical devices containing carbon nanotube-infused electrode materials and methods and apparatuses for production thereof
Electrical devices having electrodes containing carbon nanotubes infused to a substrate are described herein. The electrical devices contain at least a first electrode material containing a first plurality of carbon nanotubes infused to a first substrate and a second electrode material containing a second plurality of carbon nanotubes infused to a second substrate. The first electrode material and the second electrode material are wound in a spiral configuration about a central axis. The electrical devices can be supercapacitors, which also contain at least an electrolyte in contact with the first electrode material and the second electrode material, and a first separator material disposed between the first electrode material and the second electrode material. Methods and apparatuses for making the electrical devices are also disclosed herein.
Electrical devices containing continuous fibers that are infused with carbon nanotubes are described herein. The electrical devices contain at least a first electrode layer and a second electrode layer, where the first and second electrode layers each contain a plurality of continuous fibers that are infused with carbon nanotubes. In some embodiments, the electrical devices can be supercapacitors, further containing at least a base plate, a layer of separator material disposed between the first and second electrode layers, and an electrolyte in contact with the first and second electrode layers. The first and second electrode layers can be formed by conformal winding of the continuous fibers. The electrical devices can contain any number of additional electrode layers, each being separated from one another by a layer of separator material. Methods for producing the electrical devices are also described herein.
Electrical devices having electrodes containing carbon nanotubes infused to a substrate are described herein. The electrical devices contain at least a first electrode material containing a first plurality of carbon nanotubes infused to a first substrate and a second electrode material containing a second plurality of carbon nanotubes infused to a second substrate. The first electrode material and the second electrode material are wound in a spiral configuration about a central axis. The electrical devices can be supercapacitors, which also contain at least an electrolyte in contact with the first electrode material and the second electrode material, and a first separator material disposed between the first electrode material and the second electrode material. Methods and apparatuses for making the electrical devices are also disclosed herein.
Electrical devices containing continuous fibers that are infused with carbon nanotubes are described herein. The electrical devices contain at least a first electrode layer and a second electrode layer, where the first and second electrode layers each contain a plurality of continuous fibers that are infused with carbon nanotubes. In some embodiments, the electrical devices can be supercapacitors, further containing at least a base plate, a layer of separator material disposed between the first and second electrode layers, and an electrolyte in contact with the first and second electrode layers. The first and second electrode layers can be formed by conformal winding of the continuous fibers. The electrical devices can contain any number of additional electrode layers, each being separated from one another by a layer of separator material. Methods for producing the electrical devices are also described herein.
Carbon nanotube-infused fiber materials containing substantially parallel-aligned, infused carbon nanotubes are described herein. The carbon nanotube-infused fiber materials contain a fiber material and a layer of carbon nanotubes infused to the fiber material, where the infused carbon nanotubes are aligned substantially parallel to the longitudinal axis of the fiber material and at least a portion of the substantially parallel-aligned, infused carbon nanotubes are crosslinked to each other, to the fiber material, or both. Crosslinking can occur through covalent bonding or pi-stacking interactions, for example. The carbon nanotube-infused fiber materials can further contain additional carbon nanotubes that are grown on the layer of substantially parallel-aligned, infused carbon nanotubes. Composite materials containing the carbon nanotube-infused fiber materials and methods for production of the carbon nanotube-infused fiber materials are also described herein.
Filtration systems containing a filtration medium and methods related thereto are described herein. The filtration system includes a plurality of fibers of spoolable length, where the fibers are a carbon nanotube-infused fiber material. The filtration systems can be operated with reel-to-reel processing or in a continuous manner in order to sorb hydrophobic materials from a liquid medium. The filtration systems also include various means to remove the hydrophobic materials from the filtration medium, including press rollers and chemical extraction baths. Illustrative liquid media that can be treated with the filtration systems include, for example, hydrophobic materials admixed in an aqueous phase, bilayers (e.g., oil-water bilayers), oil in a subterranean formation, water sources containing trace organic pollutants or trace organic compounds, and fermentation broths.
B05D 7/00 - Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
55.
APPARATUS AND METHOD FOR THE PRODUCTION OF CARBON NANOTUBES ON A CONTINUOUSLY MOVING SUBSTRATE
An apparatus having at least one carbon nanotube growth zone having a substrate inlet sized to allow a spoolable length substrate to pass therethrough. The apparatus also has at least one heater in thermal communication with the carbon nanotube growth zone. The apparatus has at least one feed gas inlet in fluid communication with the carbon nanotube growth zone. The apparatus is open to an atmospheric environment during operation.
A wire includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes. An electromagnetic shield for a wire includes a plurality of carbon nanotube infused fibers, in which the infused carbon nanotubes are aligned radially about the fiber axes. The plurality of carbon nanotube infused fibers are arranged circumferentially about the wire with the fiber axes parallel to the wire. A self-shielded wire includes 1) a wire that includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes; and 2) an electromagnetic shield that includes a plurality of carbon nanotube infused fibers in which the carbon nanotubes are aligned radially about the fiber axes. The axes of the carbon nanotube infused fibers of the wire and the carbon nanotube infused fibers of the electromagnetic shield share are parallel.
Composite materials containing a metal matrix having at least one metal and a carbon nanotube-infused fiber material are described herein. Metal matrices include aluminum, magnesium, copper, cobalt, nickel, zirconium, silver, gold, titanium and various mixtures thereof. The fiber materials include glass fibers, carbon fibers, metal fibers, ceramic fibers, organic fibers, silicon carbide fibers, boron carbide fibers, silicon nitride fibers and aluminum oxide fibers. The composite materials can further include a passivation layer overcoating at least the carbon nanotube-infused fiber material and, optionally, the plurality of carbon nanotubes. The metal matrix can include at least one additive that increases compatibility of the metal matrix with the carbon nanotube-infused fiber material. The fiber material can be distributed uniformly, non-uniformly or in a gradient manner in the metal matrix. Non-uniform distributions may be used to form impart different mechanical, electrical or thermal properties to different regions of the metal matrix.
Flame-resistant composite materials containing carbon nanotubes are described herein. The flame-resistant composite materials contain an outer layer and at least one inner layer, containing a first polymer matrix and a second polymer matrix, respectively. The outer layer has an exterior surface and a first carbon nanotube-infused fiber material that contains a first fiber material and a first plurality of carbon nanotubes greater than about 50 μm in length. In some embodiments, the at least one inner layer also contains a second fiber material and/or a second carbon nanotube-infused fiber material containing a second fiber material and a second plurality of carbon nanotubes. When present, the second plurality of carbon nanotubes are generally shorter in length than the first plurality of carbon nanotubes. Alignment of the carbon nanotubes in the outer layer can transfer heat away from the composite material's inner layer(s). Flame-resistant articles containing carbon nanotube-infused fiber materials are also described.
B32B 5/12 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by structural features of a layer comprising fibres or filaments characterised by the relative arrangement of fibres or filaments of adjacent layers
B32B 5/16 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer formed of particles, e.g. chips, chopped fibres, powder
A composite includes a thermoplastic matrix material and a carbon nanotube (CNT)-infused fiber material dispersed through at least a portion of the thermoplastic matrix material.
An apparatus having a composite air-based structure with a first carbon nanotube infused material and a second carbon nanotube infused material. The first and second carbon nanotube infused materials each having a range of carbon nanotube loading selected to provide different functionalities.
An apparatus having a composite sea-based structure with a first carbon nanotube infused material and a second carbon nanotube infused material. The first and second carbon nanotube infused materials each having a range of carbon nanotube loading selected to provide different functionalities.
A carbon/carbon (C/C) composite includes a carbon matrix and a non- woven, carbon nanotube (CNT)-infused carbon fiber material. Where woven materials are employed, CNTs are infused on a parent carbon fiber material in a non- woven state. A C/C composite includes a barrier coating on the CNT-infused fiber material. An article is constructed from these (C/C) composites. A method of making a C/C composite includes winding a continuous CNT-infused carbon fiber about a template structure and forming a carbon matrix to provide an initial C/C composite or by dispersing chopped CNT-infused carbon fibers in a carbon matrix precursor to provide a mixture, placing the mixture in a mold, and forming a carbon matrix to provide an initial C/C composite.
An apparatus having a composite space-based structure with a first carbon nanotube infused material and a second carbon nanotube infused material. The first and second carbon nanotube infused materials each having a range of carbon nanotube loading selected to provide different functionalities.
C23C 16/00 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
64.
CERAMIC COMPOSITE MATERIALS CONTAINING CARBON NANOTUBE-INFUSED FIBER MATERIALS AND METHODS FOR PRODUCTION THEREOF
In various embodiments, composite materials containing a ceramic matrix and a carbon nanotube-infused fiber material are described herein. Illustrative ceramic matrices include, for example, binary, ternary and quaternary metal or non-metal borides, oxides, nitrides and carbides. The ceramic matrix can also be a cement. The fiber materials can be continuous or chopped fibers and include, for example, glass fibers, carbon fibers, metal fibers, ceramic fibers, organic fibers, silicon carbide fibers, boron carbide fibers, silicon nitride fibers and aluminum oxide fibers. The composite materials can further include a passivation layer overcoating at least the carbon nanotube-infused fiber material and, optionally, the plurality of carbon nanotubes. The fiber material can be distributed uniformly, non-uniformly or in a gradient manner in the ceramic matrix. Non-uniform distributions may be used to form impart different mechanical, electrical or thermal properties to different regions of the ceramic matrix.
A structural support includes a cylindrical core, an inner layer within the core and an outer layer. The inner and outer layers include CNT-infused fiber materials in a thermoset matrix. A composite includes a thermoset matrix and a CNT-infused fiber material having CNTs with lengths between about 20 to about 500 microns or about 0.1 to about 15 microns. For the latter range, CNTs are present between about 0.1 to about 5 percent by weight of the composite. A method of making a structural support includes wet winding a first CNT-infused fiber about a cylindrical mandrel in a direction substantially parallel to the mandrel axis, wet winding a baseline layer about the first CNT-infused fiber at an angle substantially non-parallel to the mandrel axis, and wet winding a second CNT- infused fiber about the baseline layer in a direction substantially parallel to the mandrel axis.
B32B 5/16 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer formed of particles, e.g. chips, chopped fibres, powder
B32B 9/00 - Layered products essentially comprising a particular substance not covered by groups
B32B 3/00 - Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form
66.
CNT-INFUSED CERAMIC FIBER MATERIALS AND PROCESS THEREFOR
A composition includes a carbon nanotube (CNT)-infused ceramic fiber material, wherein the CNT-infused ceramic fiber material includes: a ceramic fiber material of spoolable dimensions; and carbon nanotubes (CNTs) bonded to the ceramic fiber material. The CNTs are uniform in length and uniform in distribution. A continuous CNT infusion process includes (a) disposing a carbon-nanotube forming catalyst on a surface of a ceramic fiber material of spoolable dimensions; and (b) synthesizing carbon nanotubes on the ceramic fiber material, thereby forming a carbon nanotube-infused ceramic fiber material.
A composition includes a carbon nanotube (CNT)-infused carbon fiber material that includes a carbon fiber material of spoolable dimensions and carbon nanotubes (CNTs) infused to the carbon fiber material. The infused CNTs are uniform in length and uniform in distribution. The CNT infused carbon fiber material also includes a barrier coating conformally disposed about the carbon fiber material, while the CNTs are substantially free of the barrier coating. A continuous CNT infusion process includes: (a) functionalizing a carbon fiber material; (b) disposing a barrier coating on the functionalized carbon fiber material (c) disposing a carbon nanotube (CNT)-forming catalyst on the functionalized carbon fiber material; and (d) synthesizing carbon nanotubes, thereby forming a carbon nanotube-infused carbon fiber material.
B05D 3/10 - Pretreatment of surfaces to which liquids or other fluent materials are to be appliedAfter-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
B82B 1/00 - Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
68.
CNT-INFUSED METAL FIBER MATERIALS AND PROCESS THEREFOR
A composition includes a carbon nanotube (CNT)-infused metal fiber material which includes a metal fiber material of spoolable dimensions, a barrier coating conformally disposed about the metal fiber material, and carbon nanotubes (CNTs) infused to the metal fiber material. A continuous CNT infusion process includes: (a) disposing a barrier coating and a carbon nanotube (CNT)-forming catalyst on a surface of a metal fiber material of spoolable dimensions; and (b) synthesizing carbon nanotubes on the metal fiber material, thereby forming a carbon nanotube- infused metal fiber material.
A composition includes a carbon nanotube (CNT)-infused aramid fiber material that includes an aramid fiber material of spoolable dimensions, a barrier coating conformally disposed about the aramid fiber material, and carbon nanotubes (CNTs) infused to the aramid fiber material. The infused CNTs are uniform in length and uniform in density. A continuous CNT infusion process includes:(a) disposing a barrier coating and a carbon nanotube (CNT)-forming catalyst on a surface of an aramid fiber material of spoolable dimensions; and (b) synthesizing carbon nanotubes on the aramid fiber material, thereby forming a carbon nanotube-infused aramid fiber material.
A composite includes a matrix material and a unidirectional array of carbon nanotube- infused fibers disposed in a portion of the matrix material. An article includes this composite and a network of electrodes disposed about the periphery of the composite. The electrodes send and receive an electrical charge. Such an article is included in a system, along with sensing circuitry and a source for supplying current to the network of electrodes. Such a system is used in a method that includes subjecting the article to a load that causes a condition in the composite including strain, fatigue, damage, or cracks, and monitoring the location of the condition.
A method includes a providing a molten glass fiber core and disposing a plurality of nanoparticles that include a transition metal oxide on the molten glass fiber core at or above the softening temperature of the glass fiber core, thereby forming a nanoparticle-laden glass fiber. The plurality of nanoparticles are embedded at the surface of said glass fiber core. A method includes providing a mixture of molten glass and a plurality of nanoparticles. The plurality of nanoparticles include a transition metal. The method further includes forming nanoparticle-laden glass fibers, in which the plurality of nanoparticles are embedded throughout the glass fibers.
A composite structure includes a matrix material and a carbon nanotube (CNT)-infused fiber material that includes a plurality of carbon nanotubes (CNTs) infused to a fiber material. The CNT-infused fiber material is disposed throughout a portion of the matrix material. The composite structure is adapted for application of a current through the CNT-infused fiber material to provide heating of the composite structure. A heating element includes a CNT-infused fiber material includes a plurality of CNTs infused to a fiber material. The CNT-infused fiber material is of sufficient proportions to provide heating to a structure in need thereof.
A composite composition includes a plurality of carbon nanotube (CNT)-infused fibers dispersed in a matrix material. The amount of carbon nanotubes in the composition is in a range between about 0.1% percent by weight to about 60 percent by weight of the composite.
H01B 1/18 - Conductive material dispersed in non-conductive inorganic material the conductive material comprising carbon-silicon compounds, carbon, or silicon
H01B 1/24 - Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon, or silicon
74.
Incorporation of nanoparticles in composite fibers
A method includes a providing a molten glass fiber core and disposing a plurality of nanoparticles that include a transition metal oxide on the molten glass fiber core at or above the softening temperature of the glass fiber core, thereby forming a nanoparticle-laden glass fiber. The plurality of nanoparticles are embedded at the surface of said glass fiber core. A method includes providing a mixture of molten glass and a plurality of nanoparticles. The plurality of nanoparticles include a transition metal. The method further includes forming nanoparticle-laden glass fibers, in which the plurality of nanoparticles are embedded throughout the glass fibers.
B29C 39/14 - Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressureApparatus therefor for making articles of indefinite length
B29C 41/24 - Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped articleApparatus therefor for making articles of indefinite length
C03C 14/00 - Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
A composite composition includes a plurality of carbon nanotube (CNT)-infused fibers dispersed in a matrix material. The amount of carbon nanotubes in the composition is in a range between about 0.1% percent by weight to about 60 percent by weight of the composite.
A radar absorbing composite includes a (CNT)-infused fiber material disposed in at least a portion of a matrix material. The composite absorbs radar in a frequency range from about 0.10 Megahertz to about 60 Gigahertz. The CNT-infused fiber material forms a first layer that reduces radar reflectance and a second layer that dissipates the energy of the radar. A method of manufacturing this composite includes disposing a CNT-infused fiber material in a portion of a matrix material with a controlled orientation of the CNT-infused fiber material within the matrix material, and curing the matrix material. The composite can be formed into a panel which is adaptable as a structural component of a transport vessel or missile for use in stealth applications.
B32B 5/26 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by the presence of two or more layers which comprise fibres, filaments, granules, or powder, or are foamed or specifically porous one layer being a fibrous or filamentary layer another layer also being fibrous or filamentary
B32B 9/00 - Layered products essentially comprising a particular substance not covered by groups
B29C 51/14 - Shaping by thermoforming, e.g. shaping sheets in matched moulds or by deep-drawingApparatus therefor using multilayered preforms or sheets
77.
LOW TEMPERATURE CNT GROWTH USING GAS-PREHEAT METHOD
A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.
A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.
C23C 16/00 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
D01F 9/12 - Carbon filamentsApparatus specially adapted for the manufacture thereof
79.
CNT-BASED RESISTIVE HEATING FOR DEICING COMPOSITE STRUCTURES
A composite structure includes a matrix material and a carbon nanotube (CNT)- infused fiber material that includes a plurality of carbon nanotubes (CNTs) infused to a fiber material. The CNT-infused fiber material is disposed throughout a portion of the matrix material. The composite structure is adapted for application of a current through the CNT- infused fiber material to provide heating of the composite structure. A heating element includes a CNT-infused fiber material includes a plurality of CNTs infused to a fiber material. The CNT-infused fiber material is of sufficient proportions to provide heating to a structure in need thereof.
G06F 19/00 - Digital computing or data processing equipment or methods, specially adapted for specific applications (specially adapted for specific functions G06F 17/00;data processing systems or methods specially adapted for administrative, commercial, financial, managerial, supervisory or forecasting purposes G06Q;healthcare informatics G16H)
80.
METHOD AND SYSTEM FOR CLOSE PROXIMITY CATALYSIS FOR CARBON NANOTUBE SYNTHESIS
A method for carbon nanotube synthesis can include providing in a growth chamber, a substrate in close proximity with a surface of a first plate having a catalyst. The method can also include heating the growth chamber to a temperature sufficient to cause transfer of catalytic particles from the first plate to the substrate. The method can also include growing carbon nanotubes on the substrate by directing feed gas to the substrate.
A carbon nanotube-infused fiber and a method for its production are disclosed. Nanotubes are synthesized directly on a parent fiber by first applying a catalyst to the fiber. The properties of the carbon nanotube-infused fiber will be a combination of those of the parent fiber as well as those of the infused carbon nanotubes.
C23C 16/00 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
A composite for use in electromagnetic interference (EMI) shielding applications includes a carbon nanotube(CNT)-infused fiber material disposed in at least a portion of a matrix material. The composite is capable of absorbing or reflecting EM radiation, or combinations thereof in a frequency range from between about 0.01 MHz to about 18 GHz. The electromagnetic interference (EMI) shielding effectiveness (SE), is in a range from between about 40 decibels (dB) to about 130 dB. A method of manufacturing the composite includes disposing a CNT-infused fiber material in a portion of a matrix material with a controlled orientation of the CNT-infused fiber material within the matrix material, and curing the matrix material. A panel includes the composite and is adaptable to interface with a device for use in EMI shielding applications. The panel is further equipped with an electrical ground.
H05K 9/00 - Screening of apparatus or components against electric or magnetic fields
G02B 6/12 - Light guidesStructural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
A composite for use in electromagnetic interference (EMI) shielding applications includes a carbon nanotube (CNT)-infused fiber material disposed in at least a portion of a matrix material. The composite is capable of absorbing or reflecting EM radiation, or combinations thereof in a frequency range from between about 0.01 MHz to about 18 GHz. The electromagnetic interference (EMI) shielding effectiveness (SE), is in a range from between about 40 decibels (dB) to about 130 dB. A method of manufacturing the composite includes disposing a CNT-infused fiber material in a portion of a matrix material with a controlled orientation of the CNT-infused fiber material within the matrix material, and curing the matrix material. A panel includes the composite and is adaptable to interface with a device for use in EMI shielding applications. The panel is further equipped with an electrical ground.
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H05K 9/00 - Screening of apparatus or components against electric or magnetic fields
H01B 1/18 - Conductive material dispersed in non-conductive inorganic material the conductive material comprising carbon-silicon compounds, carbon, or silicon
H01B 1/24 - Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon, or silicon
H01Q 17/00 - Devices for absorbing waves radiated from an antenna Combinations of such devices with active antenna elements or systems
A radar absorbing composite includes a (CNT)-infused fiber material disposed in at least a portion of a matrix material. The composite absorbs radar in a frequency range from about 0.10 Megahertz to about 60 Gigahertz. The CNT-infused fiber material forms a first layer that reduces radar reflectance and a second layer that dissipates the energy of the radar. A method of manufacturing this composite includes disposing a CNT-infused fiber material in a portion of a matrix material with a controlled orientation of the CNT-infused fiber material within the matrix material, and curing the matrix material. The composite can be formed into a panel which is adaptable as a structural component of a transport vessel or missile for use in stealth applications.
Systems and methods for sensing an external measurand are disclosed. A sensor includes an optical fiber having at least one fiber Bragg grating (FBG) section and a plurality of carbon nanotubes (CNTs) surrounding at least a portion of the FBG section. Light is provided into the sensor while the CNTs are exposed to one or more measurands. A change in a spectrum of one of a transmitted portion and a reflected portion of the light is determined. A measurand that has caused the change is identified.
G01P 15/093 - Measuring accelerationMeasuring decelerationMeasuring shock, i.e. sudden change of acceleration by making use of inertia forces with conversion into electric or magnetic values by photoelectric pick-up
A fiber sizing formulation includes (1) a nanoparticle (NP)solution that includes a dispersion of transition metal nanoparticles (NPs) in a solvent and (2) a first fiber sizing agent. The NPs disperse throughout the first fiber sizing agent after application of the fiber sizing formulation to a fiber and removal of the solvent. The NPs serve a function selected from a secondary sizing agent, a catalyst for further nanostructure growth on the fiber, and combinations thereof. A fiber includes a sizing disposed about the fiber. The sizing includes transition metal nanoparticles dispersed throughout the sizing. A method includes applying the sizing formulation to a fiber during manufacture of the fiber, and removing the solvent from the applied formulation. A method includes adding a solution of transition metal NPs to a sizing-coated fiber and baking, whereby the sizing solution of NPs is added before baking the sizing.
B82B 1/00 - Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
B82B 3/00 - Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
87.
SOLAR RECEIVER UTILIZING CARBON NANOTUBE INFUSED COATINGS
A solar receiver includes a heat absorbing element having an outer surface and an inner surface opposite the outer surface and a first coating including a carbon nanotube-infused fiber material in surface engagement with and at least partially covering the outer surface of the heat absorbing element. Solar radiation incident onto the first coating is received, absorbed, and converted to heat energy, and the heat energy is transferred from the first coating to the heat absorbing element. A multilayer coating for a solar receiver device includes a first coating that includes a CNT-infused fiber material and an environmental coating disposed on the first coating.
A method for forming a CNT infused substrate comprises exposing a catalyst nanoparticle, a carbon feedstock gas, and a carrier gas to a CNT synthesis temperature, allowing a CNT to form on the catalyst nanoparticle, cooling the CNT, and exposing the cooled CNT to a surface of a substrate to form a CNT infused substrate.
An apparatus having at least one carbon nanotube growth zone having a substrate inlet sized to allow a spoolable length substrate to pass therethrough. The apparatus also has at least one heater in thermal communication with the carbon nanotube growth zone. The apparatus has at least one feed gas inlet in fluid communication with the carbon nanotube growth zone. The apparatus is open to the atmosphere during operation.
A system for synthesizing carbon nanotubes (CNT) on a fiber material includes a surface treatment system adapted to modify the surface of the fiber material to receive a barrier coating upon which carbon nanotubes are to be grown, a barrier coating application system downstream of the surface treatment system adapted to apply the barrier coating to the treated fiber material surface, and a barrier coating curing system downstream of the barrier coating application system for partially curing the applied barrier coating to enhance reception of CNT growth catalyst nanoparticles.
A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.
C23C 16/00 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
D01F 9/12 - Carbon filamentsApparatus specially adapted for the manufacture thereof
D01C 5/00 - Carbonising rags to recover animal fibres
92.
CNT-INFUSED GLASS FIBER MATERIALS AND PROCESS THEREFOR
A composition includes a carbon nanotube (CNT)-infused glass fiber material, which includes a glass fiber material of spoolable dimensions and carbon nanotubes (CNTs) bonded to it. The CNTs are uniform in length and distribution. A continuous CNT infusion process includes: (a) disposing a carbon-nanotube forming catalyst on a surface of a glass fiber material of spoolable dimensions; and (b) synthesizing carbon nanotubes on the glass fiber material, thereby forming a carbon nanotube-infused glass fiber material. The continuous CNT infusion process optionally includes extruding a glass fiber material from a glass melt or removing sizing material from a pre-fabricated glass fiber material.
A composition includes a carbon nanotube (CNT)-infused carbon fiber material that includes a carbon fiber material of spoolable dimensions and carbon nanotubes (CNTs) infused to the carbon fiber material. The infused CNTs are uniform in length and uniform in distribution. The CNT infused carbon fiber material also includes a barrier coating conformally disposed about the carbon fiber material, while the CNTs are substantially free of the barrier coating. A continuous CNT infusion process includes: (a) functionalizing a carbon fiber material; (b) disposing a barrier coating on the functionalized carbon fiber material (c) disposing a carbon nanotube (CNT)-forming catalyst on the functionalized carbon fiber material; and (d) synthesizing carbon nanotubes, thereby forming a carbon nanotube-infused carbon fiber material.
B32B 9/00 - Layered products essentially comprising a particular substance not covered by groups
D02G 3/00 - Yarns or threads, e.g. fancy yarnsProcesses or apparatus for the production thereof, not otherwise provided for
D02G 3/16 - Yarns or threads made from mineral substances
D03D 15/00 - Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
D04H 1/76 - Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres otherwise than in a plane, e.g. in a tubular way
D06M 11/74 - Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphiteTreating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbidesTreating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereofSuch treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with graphitic acids or their salts
A composition includes a carbon nanotube (CNT)-infused metal fiber material which includes a metal fiber material of spoolable dimensions, a barrier coating conformally disposed about the metal fiber material, and carbon nanotubes (CNTs) infused to the metal fiber material. A continuous CNT infusion process includes: (a) disposing a barrier coating and a carbon nanotube (CNT)-forming catalyst on a surface of a metal fiber material of spoolable dimensions; and (b) synthesizing carbon nanotubes on the metal fiber material, thereby forming a carbon nanotube-infused metal fiber material.
B32B 9/00 - Layered products essentially comprising a particular substance not covered by groups
D02G 3/00 - Yarns or threads, e.g. fancy yarnsProcesses or apparatus for the production thereof, not otherwise provided for
C22C 47/04 - Pretreatment of the fibres or filaments by coating, e.g. with a protective or activated covering
B22F 3/00 - Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sinteringApparatus specially adapted therefor
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