Provided is a method by which a sodium compound that has a NASICON structure and has a single phase as observed by x-ray diffraction can be produced in an industrially advantageous manner. The present invention is a production method for a sodium compound that has a NASICON structure and contains at least sodium, zirconium, silicon, and phosphorus. The production method is characterized by firing a reaction precursor that contains sodium, zirconium, silicon, and phosphorus and has an infrared absorption spectrum that has at least an absorption peak that has a maximum value at 950–1050 cm-1and an absorption peak that has a maximum value at 1060–1150 cm-1 at 800°C–1100°C.
C03B 32/02 - Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
C04B 35/447 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on phosphates
2.
METHOD FOR PRODUCING TITANIUM CHELATING AGENT AND TITANIUM CHELATING AGENT
Provided is a production method for producing, using an industrially advantageous method, a titanium chelating agent that has a flash point of room temperature or higher and can be handled as a non-hazardous material. This method for producing a titanium chelating agent includes: a moisture adjustment step for adding pure water to a liquid mixture of an organic solvent and a titanium chelating compound to adjust the moisture so that the moisture content is 20 mass% to 70 mass%; and a reduced-pressure distillation step for distilling off the organic solvent from the aqueous liquid mixture obtained in the moisture adjustment step under the conditions of a vacuum level of −30 kPa to −100 kPa and a temperature of 30°C to 80°C.
227xypztt (In the formula, M represents one or more metal elements selected from among Mg, Zn, Cu, Fe, Cr, Mn, Ni, V, Li, Al, B, Na, K, F, Cl, Br, I, Sr, Ba, Ti, Zr, Hf, Nb, Ta, Y, Yb, Si, S, W, Mo, Co, Bi, Te, Pb, Ag, Cd, In, Sn, Sb, Te, Ga, Ge, La, Ce, Nd, Sm, Eu, Tb, Dy, and Ho; 0
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
C04B 35/447 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on phosphates
4.
METHOD FOR PRODUCING WATER-SOLUBLE QUANTUM DOT, AND WATER-SOLUBLE QUANTUM DOT
Provided are: a method for producing a water-soluble quantum dot which has an excellent quantum yield in an aqueous solvent such as water and has a narrow FWHM emission spectrum; and a water-soluble quantum dot obtained by the production method. The method for producing a water-soluble quantum dot comprises: a ligand exchange step for adding a hydrophilic ligand to a hydrophobic quantum dot dispersion and exchanging a ligand bonded to the surface of the quantum dot with a hydrophilic ligand to obtain a hydrophilic quantum dot; a dispersion step for dispersing the hydrophilic quantum dot in an aqueous solvent to obtain an aqueous solvent dispersion of the hydrophilic quantum dot; a surface treatment step for adding a surface treatment agent to the aqueous solvent dispersion to perform surface treatment of the hydrophilic quantum dot in an aqueous solvent, thereby obtaining an aqueous solvent dispersion of the surface-treated hydrophilic quantum dot; and a shell formation step for adding a shell-forming agent to the aqueous solvent dispersion of the surface-treated hydrophilic quantum dot to form a shell on the surface of the surface-treated hydrophilic quantum dot, thereby obtaining an aqueous solvent dispersion of the water-soluble quantum dot.
Provided is a method for producing lithium cobalt-based composite oxide particles that make possible the reduction of the weight and thickness of a positive electrode material when used as a positive electrode active material of a nonaqueous lithium secondary battery or an all-solid-state battery. This method for producing lithium cobalt-based composite oxide particles is characterized by comprising: a thermal decomposition step in which a cobalt compound starting material having an average particle size of 0.05-1.00 μm by SEM observation is thermally decomposed to obtain a cobalt oxide, the cobalt starting material being cobalt hydroxide or a cobalt salt; a mixture preparation step in which a mixture containing at least a lithium compound and the cobalt oxide obtained by the thermal decomposition step is prepared; and a firing step in which the mixture prepared in the mixture preparation step is fired at 500-850°C.
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
6.
METHOD FOR PRODUCING ARYLDIADAMANTYLPHOSPHINE DERIVATIVES AND METHOD FOR PRODUCING ARYLDIADAMANTYLPHOSPHONIUM SALT DERIVATIVES
22) is introduced into a compound having an aryl skeleton. This method for producing aryldiadamantylphosphine derivatives has: a first step for obtaining a lithiated substance by reacting a bromo compound with an alkyllithium; and a second step for then reacting the obtained lithiated substance with a diadamantylchlorophosphine.
A method for producing a quantum dot having excellent in full width at half maximum (FWHM) and symmetry of the emission spectrum, the quantum dot having a core-shell structure, with a core composed of an InP-based quantum dot obtained by a reaction of at least a phosphorus source and an indium source, and a shell composed of a coating compound other than InP-based one, includes performing a reaction to coat the core with the coating compound in a solvent containing a plurality of amine derivatives. The coating compound is obtained preferably from a reaction with at least a zinc source.
Provided are lithium cobalt-based composite oxide particles that are useful as a positive electrode active material for a non-aqueous lithium secondary battery, an all-solid battery, and the like, and comprise a water-soluble lithium compound and lithium cobalt composite oxide fine particles having an average particle diameter of 0.10 to 2.00 μm observed by SEM, the lithium cobalt-based composite oxide particles being characterized in that the water-soluble lithium compound is attached to at least a part of the particle surface of the lithium cobalt composite oxide fine particles.
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
9.
METHOD FOR PRODUCING LITHIUM SILICOPHOSPHATE POWDER COMPOSITION
The present invention provides method for producing a lithium silicophosphate powder composition that makes it possible to obtain, with an industrially advantageous method that does not require excessive pulverization, a lithium silicophosphate powder composition which has excellent sintering properties that enable sintering at low temperatures. Provided is a method for producing a lithium silicophosphate powder composition, said method being characterized by comprising: a first step for mixing lithium hydroxide and fumed silica into an aqueous solvent to prepare a liquid mixture containing the elements Li and Si; a second step for adding, to the liquid mixture, an aqueous solution containing phosphoric acid to obtain a slurry that contains the elements Li, Si, and P as solid content; a third step for subjecting the slurry to a spray drying process to obtain a reaction precursor; a fourth step for sintering the reaction precursor to obtain a LISICON-type lithium silicophosphate; and a fifth step for subjecting the LISICON-type lithium silicophosphate and a lithium compound to a mixing process to obtain a lithium silicophosphate powder composition.
H01B 1/06 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of other non-metallic substances
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
11.
CONDUCTIVE PARTICLES, METHOD FOR MANUFACTURING SAME, CONDUCTIVE MATERIAL, AND CONNECTION STRUCTURE USING SAME
The present invention relates to conductive particles each having a conductive layer on the surface of a core particle, and having a compressibility of 90-98% when the compressive load is 10 mN. It is preferable that the conductive particles have a compressibility of 50% or less when the compressive load is less than 9 mN, and have a recovery rate of 1-10% when the compressibility is 90% or more. The conductive particles can be manufactured by a manufacturing method comprising a step of forming the conductive layer after the core particle is cooled under a specific condition.
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
12.
CARBON DIOXIDE ABSORBENT AND METHOD FOR SEPARATING AND RECOVERING CARBON DIOXIDE
The present invention provides a carbon dioxide absorbent which uses an ionic liquid that has a high carbon dioxide absorption and easily desorbs carbon dioxide during regeneration of the absorbent. This carbon dioxide absorbent is characterized by being composed of at least a porous carrier and an ionic liquid that is supported by the porous carrier, and is also characterized in that the ionic liquid is a phosphonium-based ionic liquid that is represented by general formula (1). (In the formula, each of R1, R2and R3independently represents a linear alkyl group having 1 to 10 carbon atoms, a branched alkyl group or a cyclic alkyl group; m represents an integer of 1 to 10; n represents an integer of 1 to 3; and A1n- represents an anion.)
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
B01J 20/22 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising organic material
Provided are: a foamed resin insulation material that can reduce the difference in coefficient of linear expansion between a metal and a foamed resin insulation material, reduce thermal stress generated in the foamed resin insulation material as much as possible, and prevent the occurrence of cracks; and a method for manufacturing the same. The foamed resin insulation material comprises a foamed resin molded body molded by foaming an unfoamed resin material in which a negative thermal expansion material that contracts in volume as the temperature rises and expands as the temperature falls is mixed. A fiber sheet composed of intersecting warp threads and weft threads is integrated with the inner and outer surfaces of the foamed resin molded body.
C08J 9/02 - Working-up of macromolecular substances to porous or cellular articles or materialsAfter-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
B29C 44/00 - Shaping by internal pressure generated in the material, e.g. swelling or foaming
B29C 44/12 - Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
B32B 5/20 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer containing foamed or specifically porous material foamed in situ
B32B 5/24 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by the presence of two or more layers which comprise fibres, filaments, granules, or powder, or are foamed or specifically porous one layer being a fibrous or filamentary layer
F16L 59/04 - Arrangements using dry fillers, e.g. using slag wool
14.
CARBON DIOXIDE ABSORBENT AND METHOD FOR SEPARATING AND RECOVERING CARBON DIOXIDE
Provided is a carbon dioxide absorbent that uses an ionic liquid which absorbs large amounts of carbon dioxide and easily releases carbon dioxide during absorbent regeneration. This carbon dioxide absorbent is characterized by comprising: a phosphonium ionic liquid having at least one type of cation having therein amino groups; and an ionic liquid other than a phosphonium ionic liquid having at least one type of cation having therein amino groups.
B01D 53/14 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by absorption
The present invention provides conductive particles which have a small connection resistance value and have excellent insulation performance, and with which short circuit is inhibited, and thus exhibit excellent connection reliability. The conductive particles each have a core material particle, and a conductive layer having a plurality of projection parts on the surface of the core material particle. The height variation of the projection parts is 0.01-0.25.
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 1/00 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
16.
LITHIUM-COBALT-BASED COMPOSITE OXIDE PARTICLES AND METHOD FOR PRODUCING SAME, AND LITHIUM-COBALT-BASED COMPOSITE OXIDE PARTICLE COMPOSITION AND METHOD FOR PRODUCING SAME.
Provided are lithium-cobalt-based composite oxide particles obtained by a solid phase process, and a method for producing same, wherein when the lithium-cobalt-based composite oxide particles are used as a positive electrode active material of a non-aqueous lithium secondary battery or all-solid-state battery, the weight and thickness of a positive electrode material can be reduced; and the lithium-cobalt-based composite oxide particles are characterized in that the average particle diameter of primary particles of the lithium-cobalt-based composite oxide is 0.50 μm or less, and the weight decrease ratio in heating at 850°C is 1.5% by mass or less.
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY (Japan)
Inventor
Sawatsugawa, Yuki
Tamura, Ken
Ito, Hajime
Kubota, Koji
Abstract
The purpose of the present invention is to provide a method for producing an aromatic compound, wherein a cross-coupling reaction by means of a mechanochemical process is carried out in a state where a solvent is not substantially contained, the method being able to be applied to a wide range of base materials. A method for producing an aromatic compound according to the present invention performs a cross-coupling reaction of an aromatic compound (A) that has a leaving group and a compound (B) that can be cross-coupled in the presence of a palladium catalyst (C) and a base (D) in a state where a solvent is not substantially contained. This method for producing an aromatic compound comprises: a step in which a solution of the palladium catalyst (C) is prepared; and a step in which a cross-coupling reaction is carried out by adding and mixing the solution of the palladium catalyst (C) to and with a mixture that contains the aromatic compound (A) that has a leaving group, the compound (B) that can be cross-coupled, and the base (D).
C07C 17/269 - Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions of only halogenated hydrocarbons
C07C 22/08 - Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings containing six-membered aromatic rings containing fluorine
C07C 41/30 - Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
C07C 43/20 - Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
C07C 43/205 - Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring the aromatic ring being a non-condensed ring
C07C 253/30 - Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
C07C 255/50 - Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
C07D 295/096 - Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
18.
COMPOUND AND ANTISTATIC AGENT CONTAINING SAME AS ACTIVE INGREDIENT
Provided is a compound that is stably immobilized on the surface of a resin while having excellent compatibility to the resin, and that is suitable as an antistatic agent that can express high antistatic performance even with a small quantity. The present invention provides a compound represented by general formula (1). (In the formula, R1, R2, and R3each independently represent a linear or branched alkyl group having 1-20 carbon atoms, R4 represents a linear or branched fluoroalkyl group having 1-20 carbon atoms, and A represents an anion having a fluorine atom.)
C07C 381/06 - Compounds containing sulfur atoms only bound to two nitrogen atoms
C08L 27/12 - Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogenCompositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
C08L 101/00 - Compositions of unspecified macromolecular compounds
xyztp1+x1+x (1) (in the formula, M represents one or more metal elements selected from among Al, Zr, Cu, Fe, Sr, Ca, V, Mo, Bi, Nb, Si, Zn, Ga, Ge, Sn, Ba, W, Na, and K. x represents 0.98≤x≤1.20, y represents 0.30≤y<1.00, z represents 0
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
20.
NEGATIVE THERMAL EXPANSION MATERIAL, METHOD FOR MANUFACTURING SAME, AND COMPOSITE MATERIAL
xyztt (wherein: M represents a metal element having an atomic number of 11 or higher other than Cu, V, and Al; x satisfies 1.60 ≤ x ≤ 2.40, y satisfies 0.00 ≤ y ≤ 0.40, z satisfies 1.70 ≤ z ≤ 2.30, and t satisfies 6.00 ≤ t ≤ 9.00, provided that 1.00 ≤ x + y ≤ 3.00; and when an element M is contained, the number of moles in terms of Al atoms is greater than the number of moles in terms of M atoms).
C08L 101/00 - Compositions of unspecified macromolecular compounds
C04B 35/495 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates
To provide a method for producing quantum dots having exceptional photostability by using an industrially advantageous method. Provided is a method for producing quantum dots, the method including a washing step for washing quantum dots using an organic solvent capable of dissolving impurities contained in the dispersion containing the quantum dots, and a surface protection step for adding a ligand that is a specific phosphine compound to the dispersion of washed quantum dots to protect the surface of the quantum dots using the ligand. The organic solvent in the washing step is preferably at least one selected from the group consisting of methanol, ethanol, acetone, 2-propanol, and acetonitrile.
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
C04B 35/495 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates
23.
NEGATIVE THERMAL EXPANSION MATERIAL, METHOD FOR MANUFACTURING SAME, AND COMPOSITE MATERIAL
xyabtt [wherein: M represents a metallic element having an atomic number of 11 or more, other than Cu and V; 1.60≤x≤2.40; 0.00≤y≤0.40; 1.60≤a≤2.40; 0.00≤b≤0.40; and 5.00≤t≤9.00, provided that 1.60≤x+y≤2.40 and 1.60≤a+b≤2.40] in which Li atoms are present as a solid solution.
C04B 35/447 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on phosphates
C04B 35/45 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on copper oxide or solid solutions thereof with other oxides
C04B 35/495 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates
24.
NEGATIVE THERMAL EXPANSION MATERIAL, METHOD FOR PRODUCING SAME, AND PASTE
The purpose of the present invention is to provide a negative thermal expansion material comprising zirconium phosphotungstate, from which a paste having a suitable viscosity can be produced when propylene carbonate is used as a solvent. The present invention is a negative thermal expansion material characterized by comprising at least surface-modified zirconium phosphotungstate particles which comprise zirconium phosphotungstate particles and hydrogen peroxide present on the surfaces of the zirconium phosphotungstate particles.
A method for producing quantum dots each having a core-shell structure that comprises an InP-based quantum dot as the core, the InP-based quantum dot being obtained by a reaction of at least a phosphorus source and an indium source, and a cover compound other than an InP-based compound as the shell, the quantum dots having excellent symmetry and excellent full width at half maximum (FWHM) of the emission spectrum. With respect to this method for producing quantum dots, it is preferable that the reaction for covering the core with the cover compound is carried out in a solvent that contains a plurality of kinds of amine derivatives, and it is also preferable that the cover compound is obtained by a reaction with at least a zinc source.
Conductive particles are provided which, while having excellent connection reliability, enable reducing connection resistance between electrodes by improving adhesion of a nickel plating film to core particles. In these conductive particles, which comprise a conductive layer formed on the surface of core particles, the withstand current value per single conductive particle when the compression rate is less than 5% is at least 1mA, and the withstand current value per single conductive particle when the compression rate is greater than or equal 5% is at least 10mA. These conductive particles enable film formation on the surface of the core particle at a stage earlier than the late-stage plating treatment.
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
C23C 18/36 - Coating with one of iron, cobalt or nickelCoating with mixtures of phosphorus or boron with one of these metals using reducing agents using hypophosphites
x1-yy44 (1) (wherein x satisfies the requirement represented by the formula 3.00 ≤ x ≤ 4.00; and y satisfies the requirement represented by the formula 0.00 < y ≤ 1.00), and is characterized by having an average primary particle diameter of 0.1 to 1.5 μm when determined by scanning electron microscopic observation (SEM) and having a standard deviation σ of the particle diameters of 1.5 μm or less.
H01B 1/06 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of other non-metallic substances
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
C04B 35/468 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates
H01B 3/12 - Insulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of inorganic substances ceramics
29.
METHOD FOR PRODUCING TRANSITION-METAL-CONTAINING LITHIUM-PHOSPHORUS-BASED COMPOSITE OXIDE, AND METHOD FOR PRODUCING TRANSITION-METAL-CONTAINING LITHIUM-PHOSPHORUS-BASED COMPOSITE OXIDE CARBON COMPLEX
x11-y1y14x21-y2y2277, the method being characterized by comprising a first step for mixing at least lithium metaphosphate and an M source with a water-based solvent to produce a starting material mixture, a second step for subjecting the starting material mixture to a wet-mode pulverization treatment to produce a slurry containing a starting material pulverized product, a third step for spray-drying the slurry containing the starting material pulverized product by a spray dry method to produce a spray-dried powder, and a fourth step for burning the spray-dried powder.
An object of the present invention is to provide a positive electrode active substance for a lithium secondary battery, the positive electrode active substance, when being used as a positive electrode active substance for a lithium secondary battery, being little in deterioration of cycle characteristics and being high in the energy density retention rate, even in repetition of charge and discharge at high voltages, and a lithium secondary battery little in deterioration of cycle characteristics and high in the energy density retention rate, even in repetition of charge and discharge at high voltages. The positive electrode active substance for a lithium secondary battery comprises a lithium cobalt-based composite oxide particle having a Ti-containing compound and an Mg-containing compound adhered on at least part of the particle surface.
This metal-containing colloidal silica has a mixture layer obtained by dispersing a metal M in silica. The mixture layer is positioned between silica particles serving as a core and a silica layer located on the surface of the metal-containing colloidal silica. The metal M is at least one type of element selected from Au, Ag, Cu, Zn, Ti, Pt, Mg, Zr, Fe, Sr, Ca, V, Mo, Bi, Nb, Ga, Ge, Sn, Ba, W, Co, Ni, and Mn. The molar ratio (Si/M) of silicon to the metal M in a coating layer obtained by combining the mixture layer and the silica layer is 10-10,000. The metal M is uniformly and finely dispersed in the mixture layer.
The purpose of the present invention is to provide a method for manufacturing vanadium lithium phosphate, said method enabling the acquisition of a product that is single-phase by X-ray diffraction, has a low specific surface area, i.e., a BET specific surface area of 10 m224422O (wherein x is an integer of 0-2), the primary particles thereof having an average particle size of 2.0 μm or less; step B for heating the carbon source-attached particles in an oxygen-containing atmosphere to give a reaction precursor; and step C for baking the reaction precursor in an inert gas atmosphere or reductive atmosphere at 500-1300°C to give vanadium lithium phosphate.
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
33.
Optically active bisphosphinomethane, method for producing the same, and transition metal complex and asymmetric catalyst
There is provided a novel optically active bisphosphinomethane useful as a ligand for an asymmetric catalyst, excellent in oxidation resistance in air, and easy in handling. There is also provided a transition metal complex using the optically active bisphosphinoraethane having excellent asymmetric catalytic ability as a ligand. The optically active bisphosphinomethane is represented by the general formula (1), and the transition metal complex has the optically active bisphosphinomethane as a ligand.
2 represents a branched alkyl group having 3 or more carbon atoms; and * represents an asymmetric center on a phosphorus atom.)
The present invention relates to a method for producing an InP-based quantum dot precursor from a phosphorus source and an indium source, in which a silylphosphine compound represented by the following Formula (1) with a content of a compound represented by the following Formula (2) of 0.3 mol % or less is used as the phosphorus source. Further, the present invention provides a method for producing an InP-based quantum dot comprising heating an InP quantum dot precursor to a temperature of 200° C. or more and 350° C. or less to obtain an InP quantum dot.
(R is as defined in the specification.)
x, wherein R is a straight chain or branched chain aliphatic group having 0 to 5 carbon atoms, and x is a number more than 0 and less than 3, with a lower carboxylic acid represented by the following Formula (2): R′COOH, wherein R′ is a hydrogen atom or a straight chain or branched chain aliphatic group having 1 to 5 carbon atoms, and the hydrogen atom in the aliphatic group may be replaced with a halogen atom, so as to obtain a product; and then reacting the product with a higher carboxylic acid having 12 or more carbon atoms.
A production method by which a biarylphosphine useful as a Buchwald phosphine ligand can be obtained in high purity is provided through an industrially advantageous process. The production method of a biarylphosphine comprises a step A of reacting a lithiated product obtained through lithiation of a halogenated benzene derivative with a benzene derivative to obtain a biphenyl derivative, and a step B of the reacting the biphenyl derivative with a halogenated phosphine. In the step A, the charge molar ratio of the halogenated benzene derivative to the benzene derivative is preferably 1.0 to 5.0.
A method for producing barium titanyl oxalate, wherein barium titanyl oxalate is produced by mixing and reacting a solution containing oxalic acid (solution A) and a solution containing a titanium source and a barium source (solution B) with each other, said method being characterized by: separately supplying the solution A and the solution B to one end of a reaction liquid channel, mixing the solution A and the solution B with each other within the reaction liquid channel, discharging the reaction liquid from the other end of the reaction liquid channel, and subsequently performing solid-liquid separation of the reaction liquid; setting the residence time of the reaction liquid within the reaction liquid channel to 30 seconds or less; or separately supplying the solution A and the solution B to one end of the reaction liquid channel, mixing the solution A and the solution B with each other at the one end of the reaction liquid channel, moving the reaction liquid to the other end of the reaction liquid channel, while generating a vortex flow in the reaction liquid, discharging the reaction liquid from the other end of the reaction liquid channel, and subsequently performing solid-liquid separation of the reaction liquid.
C04B 35/468 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
39.
Piezoelectric material filler, composite piezoelectric material, composite piezoelectric device, composite piezoelectric material filler, and method for producing alkali niobate compound
Provided is a piezoelectric material filler including alkali niobate compound particles having a ratio (K/(Na+K)) of the number of moles of potassium to the total number of moles of sodium and potassium of 0.460 to 0.495 in terms of atoms and a ratio ((Li+Na+K)/Nb) of the total number of moles of alkali metal elements to the number of moles of niobium of 0.995 to 1.005 in terms of atoms. The present invention can provide a piezoelectric material filler having excellent piezoelectric properties, and a composite piezoelectric material including the piezoelectric material filler and a polymer matrix.
The purpose of the present invention is to provide coated particles that can increase conduction reliability and insulation reliability. The coated particles comprise: conductive particles having a metal film formed on the surface of a core material; and insulating microparticles coating the conductive particles, wherein the insulating microparticles do not have a glass transition temperature, and have a sphericity of 0.90 or greater. The surface layer of the insulating microparticles is preferably a polymer containing a crosslinking monomer component, and is also preferably a polymer containing a monomer component having a functional group with an electric charge.
C08F 257/02 - Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group on to polymers of styrene or alkyl-substituted styrenes
C08F 265/06 - Polymerisation of acrylate or methacrylate esters on to polymers thereof
H01B 1/00 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
H01R 43/00 - Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors
3 (1), and provided is a method comprising a first step of preparing a raw material mixed slurry (1) comprising, at least, titanium dioxide, phosphoric acid and a surfactant, a second step of heat treating the raw material mixed slurry (1) to obtain a raw material heat-treated slurry (2), a third step of mixing the raw material heat-treated slurry (2) with a lithium source to obtain a lithium-containing raw material heat-treated slurry (3), a fourth step of subjecting the lithium-containing raw material heat-treated slurry (3) to a spray drying treatment to obtain a reaction precursor containing, at least, Ti, P and Li, and a fifth step of firing the reaction precursor.
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
B01J 2/06 - Processes or devices for granulating materials, in generalRendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a liquid medium
The present invention provides barium titanyl oxalate which makes it possible to obtain barium titanate that has a small particle size and that is highly crystalline. The present invention also provides a method for producing said barium titanyl oxalate in an industrially advantageous manner. The barium titanyl oxalate is characterized in that, in thermogravimetric analysis, the temperature at which the weight reduction rate reaches 99% of the weight reduction rate at 1000°C is 600-700°C. The method for producing said barium titanyl oxalate is a method for producing said barium titanyl oxalate by mixing and reacting a solution (liquid A) containing oxalic acid with a solution (liquid B) containing a titanium compound and a barium compound, and is characterized in that: first the liquid A is filled into a reactor vessel, and subsequently, while stirring the liquid A in the reactor vessel, the liquid B is mixed with the liquid A; and the time from when mixing of the liquid B into the liquid A starts to when said mixing ends is not more than 10 seconds.
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
1+xx2-x433 (In the formula, 0.0 < x ≤ 1.0 and M represents one or two or more divalent or trivalent metal elements selected from Al, Ga, Sc, Y, La, Fe, Cr, Ni, Mn, In, and Co.), the method for producing lithium germanium phosphate characterized by having a first step for preparing a starting material mixed solution in which an Li source, M source, Ge source, and P source are dissolved or dispersed in a solvent; a second step for preparing a reaction precursor by heat treating the starting material mixed solution to remove at least a portion of the solvent in the starting material mixed solution; and a third step for firing the reaction precursor, wherein the P source is phosphorous acid.
The purpose is to provide a method for producing electrically conductive particles, in which the quality of the electrically conductive particles is less affected and the cost for the production of the electrically conductive particles is reduced. The method for producing electrically conductive particles comprises a step for heating electrically conductive particles each comprising a core material particle and an electrically conductive layer formed on the surface of the core material particle at a temperature of 200 to 600°C under vacuum of 1000 Pa or less. The time of heating is preferably 0.1 to 10 hours. The core material particle is preferably formed from a material comprising an inorganic substance, an organic substance or both of an inorganic substance and an organic substance, and the electrically conductive layer preferably comprises at least one component selected from nickel, gold, a nickel alloy and a gold alloy.
B22F 1/00 - Metallic powderTreatment of metallic powder, e.g. to facilitate working or to improve properties
B22F 1/02 - Special treatment of metallic powder, e.g. to facilitate working, to improve properties; Metallic powders per se, e.g. mixtures of particles of different composition comprising coating of the powder
C23C 18/16 - Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coatingContact plating by reduction or substitution, i.e. electroless plating
C23C 18/36 - Coating with one of iron, cobalt or nickelCoating with mixtures of phosphorus or boron with one of these metals using reducing agents using hypophosphites
H01B 1/00 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
48.
ELECTRICALLY CONDUCTIVE PARTICLE, AND ELECTRICALLY CONDUCTIVE MATERIAL AND CONNECTION STRUCTURE OBTAINED USING SAME
The present invention provides an electrically conductive particle which exhibits excellent storage stability, excellent corrosion resistance and low connection resistance, and in which a nickel plating layer is formed as an electrically conductive layer on the surface of a core particle. The molar ratio of the amount of carbon relative to the total amount of nickel and phosphorus (C/(Ni+P)) or the molar ratio of the amount of carbon relative to nickel and boron (C/(Ni+B)) is 0.0002-1.65, the molar ratio of the amount of oxygen relative to the total amount of nickel and phosphorus (O/(Ni+P)) or the molar ratio of the amount of oxygen relative to the total amount of nickel and boron (O/(Ni+B)) is 0.0001-1.8, and the molar ratio of phosphorus relative to nickel (P/Ni) or the molar ratio of boron relative to nickel (B/Ni) is 0.003-0.7 in a region within 5 nm in the depth direction from a surface of the electrically conductive layer, as measured using a scanning Auger electron spectroscope.
C23C 18/36 - Coating with one of iron, cobalt or nickelCoating with mixtures of phosphorus or boron with one of these metals using reducing agents using hypophosphites
B22F 1/02 - Special treatment of metallic powder, e.g. to facilitate working, to improve properties; Metallic powders per se, e.g. mixtures of particles of different composition comprising coating of the powder
C23C 18/16 - Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coatingContact plating by reduction or substitution, i.e. electroless plating
C23C 18/34 - Coating with one of iron, cobalt or nickelCoating with mixtures of phosphorus or boron with one of these metals using reducing agents
C23C 18/52 - Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coatingContact plating by reduction or substitution, i.e. electroless plating using reducing agents for coating with metallic material not provided for in a single one of groups
G01N 27/62 - Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosolsInvestigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electric discharges, e.g. emission of cathode
H01B 1/00 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
49.
ELECTROCONDUCTIVE PARTICLES, AND ELECTROCONDUCTIVE MATERIAL AND CONNECTION STRUCTURE USING SAME
Provided are electroconductive particles having a small connection resistance and excellent connection reliability, the electroconductive particles each having an electroconductive layer on the surface of a core particle, wherein: the maximum compressive hardness of the electroconductive particles is 22,000 N/mm2or greater, and the compressive hardness reaches the maximum value thereof with a compression rate of less than 5%; the average compressive hardness when the compression rate is 20%-50% is 5,000-18,000 N/mm2, and the ratio of the maximum compressive hardness to the average compressive hardness when the compression rate is 20%-50% is 2.0-10.0; and when the electroconductive particles are compressed at a load application rate of 0.33 mN/sec, the load at which the electroconductive layer breaks is 3.0 mN or greater.
B22F 1/02 - Special treatment of metallic powder, e.g. to facilitate working, to improve properties; Metallic powders per se, e.g. mixtures of particles of different composition comprising coating of the powder
C23C 18/16 - Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coatingContact plating by reduction or substitution, i.e. electroless plating
C23C 18/36 - Coating with one of iron, cobalt or nickelCoating with mixtures of phosphorus or boron with one of these metals using reducing agents using hypophosphites
H01B 1/00 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
H01R 43/00 - Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors
50.
Positive electrode active substance for lithium secondary battery, method for producing the same and lithium secondary battery
The positive electrode active substance for a lithium secondary battery includes a mixture of a lithium cobalt composite oxide particle and an inorganic fluoride particle. The method for producing a positive electrode active substance for a lithium secondary battery includes a first step of subjecting a lithium cobalt composite oxide particle and an inorganic fluoride particle to a mixing treatment to thereby obtain a mixture of the lithium cobalt composite oxide particle and the inorganic fluoride particle. The lithium secondary battery uses, as a positive electrode active substance, the positive electrode active substance for a lithium secondary battery of the present invention.
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
The positive electrode active substance for a lithium secondary battery includes a mixture of a titanium-containing lithium cobalt composite oxide particle and an inorganic fluoride particle. The method for producing a positive electrode active substance for a lithium secondary battery includes a first step of subjecting a titanium-containing lithium cobalt composite oxide particle and an inorganic fluoride particle to a mixing treatment to thereby obtain a mixture of the titanium-containing lithium cobalt composite oxide particle and the inorganic fluoride particle. The lithium secondary battery uses, as a positive electrode active substance, the positive electrode active substance for a lithium secondary battery of the present invention.
H01M 10/05 - Accumulators with non-aqueous electrolyte
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M 10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodesLithium-ion batteries
H01M 4/02 - Electrodes composed of, or comprising, active material
52.
Method for producing lithium cobalt phosphate and method for producing lithium cobalt phosphate-carbon composite
4 (1), wherein 0.8≤x≤1.2 and 0≤y≤0.5, and M represents one or two or more metal elements selected from the group consisting of Mg, Zn, Cu, Fe, Cr, Mn, Ni, Al, B, Na, K, F, Cl, Br, I, Ca, Sr, Ba, Ti, Zr, Hf, Nb, Ta, Y, Yb, Si, S, Mo, W, V, Bi, Te, Pb, Ag, Cd, In, Sn, Sb, Ga, Ge, La, Ce, Nd, Sm, Eu, Tb, Dy, and Ho; the method comprising: a first step of adding an organic acid and cobalt hydroxide to a water solvent, and then adding phosphoric acid and lithium hydroxide thereto to prepare an aqueous raw material slurry (1); a second step of wet-pulverizing the aqueous raw material slurry (1) with a media mill to obtain a slurry (2) containing a pulverized product of raw materials; a third step of spray-drying the slurry (2) containing the pulverized product of raw materials to obtain a reaction precursor; and a fourth step of firing the reaction precursor. According to the present invention, a single-phase lithium cobalt phosphate in X-ray diffraction analysis can be obtained by an industrially advantageous method.
The phosphine transition metal complex of the present invention is represented by formula (1).
10 are identical groups, and n and y are identical numbers. The phosphine transition metal complex is suitably obtained by reacting a phosphine derivative represented by formula (2) and a phosphine derivative represented by formula (3) with a salt of a transition metal of gold, copper or silver.
See the description for the meanings of the symbols in each formula.
−6/K. According to the present invention, a negative thermal expansion material made of zirconium phosphate tungstate having various thermal expansion coefficients, and an industrially advantageous manufacturing method thereof can be provided.
C04B 35/447 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on phosphates
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
Provided are: an electrically conductive adhesive which exhibits excellent adhesive properties and storage stability and which is obtained using an ultraviolet radiation-curable resin; and a joined structure and electronic component obtained using the electrically conductive adhesive. This electrically conductive adhesive contains a (meth)acrylate (A), a photopolymerization initiator (B), a phosphoric acid group-containing monomer (C), a polyester resin (D) that is soluble in an organic solvent, and electrically conductive particles (E). The phosphoric acid group-containing monomer (C) is preferably a phosphoric acid group-containing (meth)acrylate. The polyester resin (D) is preferably an amorphous polyester resin.
C09J 167/00 - Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chainAdhesives based on derivatives of such polymers
H01B 1/00 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors
H01B 1/20 - Conductive material dispersed in non-conductive organic material
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
The present invention provides covered particles wherein insulating layers cover the surfaces of electroconductive particles, and the covered particles are excellent in the adhesion between the surfaces of the electroconductive particles and the insulating layers. The covered particles includes: electroconductive particles in which metal films are formed on the surfaces of core materials, and a triazole-based compound is disposed on the outer surfaces on the sides opposite to the core materials in the metal films; and insulating layers covering the electroconductive particles, and the insulating layers comprise a compound having phosphonium groups.
B22F 1/18 - Non-metallic particles coated with metal
C08L 25/14 - Copolymers of styrene with unsaturated esters
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
The silyl phosphine compound is represented by the following general formula (1). A content of a compound represented by the following general formula (2) is not more than 0.3 mol %. In the general formula (1), each R is independently an alkyl group having not less than 1 and not more than 5 carbon atoms or an aryl group having not less than 6 and not more than 10 carbon atoms. In the general formula (2), R is the same as in the general formula (1).
C07F 9/06 - Phosphorus compounds without P—C bonds
58.
METHOD FOR PRODUCING PHOSPHINOBENZENE BORANE DERIVATIVE, METHOD FOR PRODUCING 1,2-BIS(DIALKYLPHOSPHINO)BENZENE DERIVATIVE, AND TRANSITION METAL COMPLEX
A method for producing a phosphinobenzene borane derivative comprises a reaction step (A) of obtaining liquid A containing a 1,2-dihalogenobenzene represented by the following general formula (1):
A method for producing a phosphinobenzene borane derivative comprises a reaction step (A) of obtaining liquid A containing a 1,2-dihalogenobenzene represented by the following general formula (1):
A method for producing a phosphinobenzene borane derivative comprises a reaction step (A) of obtaining liquid A containing a 1,2-dihalogenobenzene represented by the following general formula (1):
obtaining liquid B containing a phosphine borane compound obtained by deprotonating a hydrogen-phosphine borane compound represented by the following general formula (2):
A method for producing a phosphinobenzene borane derivative comprises a reaction step (A) of obtaining liquid A containing a 1,2-dihalogenobenzene represented by the following general formula (1):
obtaining liquid B containing a phosphine borane compound obtained by deprotonating a hydrogen-phosphine borane compound represented by the following general formula (2):
A method for producing a phosphinobenzene borane derivative comprises a reaction step (A) of obtaining liquid A containing a 1,2-dihalogenobenzene represented by the following general formula (1):
obtaining liquid B containing a phosphine borane compound obtained by deprotonating a hydrogen-phosphine borane compound represented by the following general formula (2):
and then adding the liquid B to the liquid A to be allowed to react to thereby obtain the phosphinobenzene borane derivative represented by the following general formula (3):
A method for producing a phosphinobenzene borane derivative comprises a reaction step (A) of obtaining liquid A containing a 1,2-dihalogenobenzene represented by the following general formula (1):
obtaining liquid B containing a phosphine borane compound obtained by deprotonating a hydrogen-phosphine borane compound represented by the following general formula (2):
and then adding the liquid B to the liquid A to be allowed to react to thereby obtain the phosphinobenzene borane derivative represented by the following general formula (3):
A method for producing a phosphinobenzene borane derivative comprises a reaction step (A) of obtaining liquid A containing a 1,2-dihalogenobenzene represented by the following general formula (1):
obtaining liquid B containing a phosphine borane compound obtained by deprotonating a hydrogen-phosphine borane compound represented by the following general formula (2):
and then adding the liquid B to the liquid A to be allowed to react to thereby obtain the phosphinobenzene borane derivative represented by the following general formula (3):
According to the present invention, there can be provided the industrially advantageous method for producing the phosphinobenzene borane derivative.
Provided are conductive particles each obtained by forming a conductive layer on the surface of a core particle, wherein the highest value of compressive hardness of the conductive particles is 24000 N/mm2or more, the compressive hardness shows the highest value at a compression rate of less than 5%, the mean value of compressive hardness at compression rates of 20-50% is 5000-18000 N/mm2, and the ratio of the highest value of compressive hardness to the mean value of compressive hardness at compression rates of 20-50% is 1.5-10.
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
C23C 18/34 - Coating with one of iron, cobalt or nickelCoating with mixtures of phosphorus or boron with one of these metals using reducing agents
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
60.
ELECTRICALLY CONDUCTIVE PARTICLES, PRODUCTION METHOD FOR SAME, AND ELECTRICALLY CONDUCTIVE MATERIAL INCLUDING SAME
Electrically conductive particles according to the present invention are obtained by forming electrically conductive layers on the surfaces of core material particles. The electrically conductive particles exhibit a highest value of compressive hardness of not less than 14700 N/mm2and exhibit a highest value of compressive hardness at a compression rate of less than 5%. An average value of compressive hardness at a compression rate of 20-50% is not less than 1300 N/mm2but less than 5000 N/mm2. The ratio of the highest value of compressive hardness with respect to the average value of compressive hardness at a compression rate of 20-50% is 1.5-50.
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
C23C 18/34 - Coating with one of iron, cobalt or nickelCoating with mixtures of phosphorus or boron with one of these metals using reducing agents
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
61.
PHOTOSINTERING COMPOSITION AND METHOD OF FORMING CONDUCTIVE FILM USING THE SAME
Provided is a photosintering composition including: a cuprous oxide particle comprising at least one additive element selected from the group consisting of tin, manganese, vanadium, cerium, iron and silver; a metal particle having a volume resistivity at 20° C. of 1.0×10−3 ω·cm or less; and a solvent.
A coated particle according to the present invention is a coated particle containing a conductive metal-coated particle having a metal film formed on a surface of a core material, the conductive metal-coated particle coated with an insulation layer containing a polymer, wherein the insulation layer has a phosphonium group. The insulation layer preferably contains an insulating fine particle and the fine particle has a phosphonium group on a surface thereof, or the insulation layer is preferably a film having a phosphonium group. In addition, the metal is preferably at least one selected from nickel, gold, nickel alloys, and gold alloys. The polymer constituting the insulation layer is preferably at least one polymerized product selected from styrenes, esters, and nitriles.
B22F 1/102 - Metallic powder coated with organic material
C08F 230/02 - Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
C08J 3/09 - Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
B22F 1/16 - Metallic particles coated with a non-metal
63.
CONDUCTIVE ADHESIVE, AND ADHESIVE STRUCTURE AND ELECTRONIC COMPONENT USING SAME
The purpose of the present invention is to provide a conductive adhesive using an ultraviolet curing resin, said conductive adhesive having excellent adhesiveness and high storage stability, and an adhesive structure and an electronic component in which the conductive adhesive is used. A conductive adhesive comprising: a (meth)acrylate (A); a photopolymerization initiator (B); a phosphate group-containing monomer (C); a phosphate ion inactivator (D); and conductive particles (E). As the phosphate ion inactivator (D), a compound which adsorbs phosphate ions and thus inactivates the same and/or a compound which reacts with phosphate ions and thus inactivates the same can be preferably used.
H01B 1/00 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
64.
METHOD FOR PRODUCING MODIFIED LITHIUM-COBALT-BASED COMPOSITE OXIDE PARTICLES
Provided is a method for producing modified lithium-cobalt-based composite oxide particles which, when used as a positive electrode active material for a lithium secondary battery, can improve cycle properties and an energy density retention rate under a high voltage. A method for producing a modified lithium-cobalt-based composite oxide, characterized by comprising step (A1) of bringing lithium-cobalt-based composite oxide particles into contact with a surface treatment solution containing a titanium chelate compound and then subjecting the resultant product to a heat treatment, thereby producing modified lithium-cobalt-based composite oxide particles (a1).
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
65.
POSITIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERIES, AND LITHIUM SECONDARY BATTERY
The purpose of the present invention is to provide: a positive electrode active material for lithium secondary batteries, said positive electrode active material being suppressed in cycle deterioration even if charging and discharging at a high voltage are repeated, while having high energy density retention rate if used as a positive electrode active material of a lithium secondary battery; and a lithium secondary battery which is suppressed in cycle deterioration even if charging and discharging at a high voltage are repeated, while having high energy density retention rate. A positive electrode active material for lithium secondary batteries, said positive electrode active material being characterized by being composed of lithium-cobalt composite oxide particles wherein a Ti-containing compound and an Mg-containing compound adhere to at least a part of the surface of each particle.
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
66.
2,3-bisphosphinopyrazine derivative, method for producing same, transition metal complex, asymmetric catalyst, and method for producing organic boron compound
Me ELEMENT-SUBSTITUTED ORGANIC ACID TITANYL BARIUM, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING TITANIUM-BASED PEROVSKITE-TYPE CERAMIC RAW MATERIAL POWDER
An Me element-substituted organic acid titanyl barium powder that is Me element-substituted organic acid titanyl barium in which some of the Ba sites are substituted by an Me element (Me represents at least one selected from Ca, Sr, and Mg), characterized in that the molar ratio ((Ba + Me)/Ti) of the total of Ba and Me element to Ti is 0.980 to less than 0.999 and the molar ratio (Me/Ba) of Me element to Ba is 0.001 to 0.250.
C07F 19/00 - Metal compounds according to more than one of main groups
C04B 35/468 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates
68.
Silyl phosphine compound, process for producing silyl phosphine compound and process for producing InP quantum dots
The silyl phosphine compound of the present invention is represented by the formula (1) and has an arsenic content of not more than 1 ppm. The process for producing a silyl phosphine compound of the present invention is a process comprising mixing a basic compound, a silylating agent and phosphine to obtain a solution containing a silyl phosphine compound, removing a solvent from the solution to obtain a concentrated solution of a silyl phosphine compound, and distilling the concentrated solution, wherein an arsenic content in the phosphine is adjusted to not more than 1 ppm by volume in terms of arsine. The process for producing InP quantum dots of the present invention uses, as a phosphorus source, a silyl phosphine compound represented by the formula (1) and having an arsenic content of not more than 1 ppm by mass.
(For definition of R, see the specification.)
Provided is a novel optically active bisphosphine methane that is useful as a ligand for an asymmetric catalyst, has excellent oxidation resistance in the air, and is easy to handle. Also, provided is a transition metal complex using, as a ligand, an optically active bisphosphine methane having an excellent asymmetric catalytic ability. This optically active bisphosphino methane is represented by general formula (1), and this transition metal catalyst contains the optically active bisphosphino methane as a ligand. (In the formula, R1represents an adamantyl group, R2 represents a branched alkyl group having three or more carbon atoms, and * represents an asymmetric center on the phosphorus atom.)
C07C 231/12 - Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
C07C 233/05 - Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
C07C 233/47 - Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
C07F 15/00 - Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
C07C 67/303 - Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
Provided is a modified zirconium phosphate tungstate in which elution of zirconium ions, tungsten ions and phosphorus ions in a zirconium phosphate tungstate is suppressed, and which can be advantageously used as a filler that has negative thermal expansion and that is incorporated in a polymer compound. In this modified zirconium phosphate tungstate, zirconium phosphate tungstate particle surfaces are coated with a titanate-based coupling agent. The BET specific surface area of the particles is preferably 0.1-50 m2/g. The average particle diameter of the particles is preferably 0.02-50 μm.
NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY (Japan)
Inventor
Ito, Hajime
Iwamoto, Hiroaki
Imamoto, Tsuneo
Tamura, Ken
Abstract
An optically active 2,3-bisphosphinopyrazine derivative represented by the following general formula (1):
3 represents a monovalent substituent; n represents an integer of 0 to 4; and * represents an asymmetric center on a phosphorus atom.
C07D 241/44 - Benzopyrazines with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
3-xxx (in the formula, R is a linear or branched aliphatic group having 0-5 carbon atoms, and x is a number greater than 0 and less than 3) with a lower carboxylic acid represented by formula (2): R'COOH (in the formula, R1 is a hydrogen atom or a linear or branched aliphatic group having 1-5 carbon atoms, and the hydrogen atom in the aliphatic group may be substituted with a halogen atom), and then the product is reacted with a higher carboxylic acid having at least 12 carbon atoms.
The present invention pertains to a method for producing InP quantum dot precursors from a phosphorus source and an indium source, wherein a silylphosphine compound represented by general formula (1), which contains a compound represented by general formula (2) in an amount of 0.3 mol% or less, is used as the phosphorus source. Further, the present invention provides a method for producing InP quantum dots, said method comprising heating the InP quantum dot precursors at a temperature of 200-350°C inclusive to thereby give InP quantum dots. (R is as defined in the description.)
Provided is a method by which a biarylphosphine useful as a Buchwald phosphine ligand can be obtained with high purity in an industrially advantageous manner. The method for producing a biarylphosphine comprises: a step A of lithiating a halogenated benzene derivative and reacting the resulting lithiated product with a benzene derivative to obtain a biphenyl derivative; and a step B of reacting the biphenyl derivative with a halogenated phosphine. In the step A, it is preferable that the charge molar ratio of the halogenated benzene derivative to the benzene derivative be 1.0-5.0.
C07C 41/22 - Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of halogenPreparation of ethers by reactions not forming ether-oxygen bonds by substitution of halogen atoms by other halogen atoms
C07C 43/225 - Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
A modified zirconium phosphate tungstate is provided which effectively suppresses the elution of phosphorus ions even when in contact with water, enables excellent performance as a negative thermal expansion filler, can be dispersed in a resin or other polymer compound, and enables successfully producing a low thermal expansion material that contains a negative thermal expansion filler. In this modified zirconium phosphate tungstate, the surface of zirconium phosphate tungstate particles is covered by an inorganic compound containing one or more elements (M) selected from Zn, Si, Al, Ba, Ca, Mg, Ti, V, Sn, Co, Fe and Zr. Preferably, the BET specific surface area of the zirconium phosphate tungstate particles is 0.1 m2/g-50 m2g.
There is provided a method for producing a 2,3-bisphosphinopyrazine derivative, the method comprising a first step of adding a base to a liquid comprising: 2,3-dihalogenopyrazine represented by the following general formula (1); a hydrogen-phosphine borane compound represented by the following general formula (2); and a deboranating agent, and allowing the resultant to react to thereby obtain the 2,3-bisphosphinopyrazine derivative represented by the following general formula (3). According to the present invention, a method for producing the industrially advantageous 2,3-bisphosphinopyrazine derivative can be provided.
C07D 241/44 - Benzopyrazines with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
1+xx1-yy2-x433, is characterized by including: a first step for preparing a raw material mixture slurry (1) containing at least titanium dioxide, phosphoric acid, a surfactant and a solvent; a second step for heat treating the raw material mixture slurry (1) so as to obtain a heat treated raw material slurry (2); a third step for mixing a lithium source with the heat treated raw material slurry (2) so as to obtain a lithium-containing heat treated raw material slurry (3); a fourth step for spray drying the lithium-containing heat treated raw material slurry (3) so as to obtain a reaction precursor containing at least Ti, P and Li; and a fifth step for firing the reaction precursor.
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
C04B 35/447 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on phosphates
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
78.
POSITIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY, METHOD FOR PRODUCING SAME, AND LITHIUM SECONDARY BATTERY
H01M 4/36 - Selection of substances as active materials, active masses, active liquids
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
79.
PHOSPHINE FOR FUMIGATION, METHOD FOR PRODUCING SAME, AND FUMIGATION METHOD
The present invention addresses the problem of providing: a phosphine for fumigation, which effectively suppresses blockage of pipes in a fumigation gas feeding device caused by impurities, and which is unlikely to undergo spontaneous combustion; and a safe phosphine fumigation method for reducing the possibilities of spontaneous combustion and blockage of pipes in a fumigation gas feeding device. This phosphine for fumigation has a P4 content equal to or less than 10 mass ppm and a water content equal to or less than 10 mass ppm. This fumigation method is for fumigating an object to be fumigated, by using a phosphine having a P4 content equal to or less 10 mass ppm and a water content equal to or less than 10 mass ppm.
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
A01N 25/20 - Combustible or heat-generating compositions
A01N 61/00 - Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
A01N 61/00 - Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
A01N 25/00 - Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of applicationSubstances for reducing the noxious effect of the active ingredients to organisms other than pests
A01N 25/20 - Combustible or heat-generating compositions
C07F 9/06 - Phosphorus compounds without P—C bonds
81.
COATED PARTICLE, ELECTRICALLY CONDUCTIVE MATERIAL COMPRISING SAME, AND METHOD OF MANUFACTURING COATED PARTICLE
The purpose of the present invention is to provide a coated particle in which an insulating layer coats the surface of an electrically conductive particle, wherein the surface of the electrically conductive particle and the insulating layer has excellent adhesion. This coated particle comprises: an electrically conductive particle which has a metal film formed on the surface of a core and has a titanium compound having a hydrophobic group arranged on the surface of the metal film opposite the core; and an insulating layer that coats the electrically conductive particle, wherein the insulating layer comprises a compound containing a charged functional group. It is preferable that the insulating layer has a plurality of fine particles arranged in layers or is a continuous film. It is also preferable that the hydrophobic group is an aliphatic hydrocarbon group having 2 to 30 carbon atoms.
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
C23C 28/00 - Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of main groups , or by combinations of methods provided for in subclasses and
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
The purpose of the present invention is to provide a modified zirconium phosphate tungstate which is suppressed in dissolution of ions from particles and exhibits excellent performance as a negative thermal expansion material, and which is capable of producing a low thermal expansion material. A modified zirconium phosphate tungstate according to the present invention is obtained by covering the surfaces of zirconium phosphate tungstate particles with a fatty acid or a derivative thereof. It is preferable that the zirconium phosphate tungstate is covered with a silane compound. The present invention also provides a negative thermal expansion filler which is composed of this modified zirconium phosphate tungstate. The present invention also provides a polymer composition which contains this negative thermal expansion filler and a polymer compound.
Silicotitanate molded body, production method thereof, adsorbent for cesium and/or strontium comprising silicotitanate molded body, and decontamination method for radioactive waste solution by using adsorbent
2O wherein A represents one or two alkali metal elements selected from Na and K, and n represents a number of 0 to 2; and an oxide of one or more elements selected from the group consisting of aluminum, zirconium, iron, and cerium.
B01J 20/10 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
B01J 20/06 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group
B01J 20/08 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group comprising aluminium oxide or hydroxideSolid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group comprising bauxite
B01J 20/28 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof characterised by their form or physical properties
B01J 20/30 - Processes for preparing, regenerating or reactivating
G21F 9/16 - Processing by fixation in stable solid media
84.
POSITIVE-ELECTRODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY, MANUFACTURING METHOD FOR SAME, AND LITHIUM SECONDARY BATTERY
Provided is a positive-electrode active material for a lithium secondary battery, said material making it possible to increase cycle characteristics and energy density retention, as well as lower a decrease in average operating voltage. Also provided are an industrially advantageous manufacturing method for the same, and a lithium secondary battery exhibiting excellent cycle characteristics and high energy density retention, as well as a lower decrease in average operating voltage. A positive-electrode active material for a lithium secondary battery, said material characterized by comprising a mixture of lithium-cobalt composite oxide particles and inorganic fluoride particles. A manufacturing method for a positive-electrode active material for a lithium secondary battery, said method characterized by comprising a first step for obtaining a mixture of lithium-cobalt composite oxide particles and inorganic fluoride particles by mixing and treating lithium-cobalt composite oxide particles and inorganic fluoride particles. A lithium secondary battery characterized in that the positive-electrode active material for a lithium secondary battery according to the present invention is used as the positive-electrode active material therein.
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
Provided is a positive-electrode active material for a lithium secondary battery, said material making it possible to lessen reductions in cycle characteristics and average operating voltage, maintain a high average operating voltage, and further increase energy density retention. Also provided are an industrially advantageous manufacturing method for the same, and a lithium secondary battery exhibiting excellent cycle and average operating voltage characteristics, as well as high energy density retention. A positive-electrode active material for a lithium secondary battery, said material characterized by comprising a mixture of titanium-containing lithium-cobalt composite oxide particles and inorganic fluoride particles. A manufacturing method for a positive-electrode active material for a lithium secondary battery, said method characterized by comprising a first step for obtaining a mixture of titanium-containing lithium-cobalt composite oxide particles and inorganic fluoride particles by mixing and treating titanium-containing lithium-cobalt composite oxide particles and inorganic fluoride particles. A lithium secondary battery characterized in that the positive-electrode active material for a lithium secondary battery according to the present invention is used as the positive-electrode active material therein.
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
This phosphine transition metal complex is represented by formula (1). In the formula, it is preferable that: R1and R6represent a same group; R2and R7represent a same group; R3and R8represent a same group; R4and R9represent a same group; R5and R10 represent a same group; and n and y represent a same number. This phosphine transition metal complex is obtained in a suitable manner by reacting a phosphine derivative represented by formula (2) and a phosphine derivative represented by formula (3) with a transition metal salt of gold, copper or silver. (Refer to the description for the meanings of the symbols in the formulae.)
Method for producing optically active 2, 3-bisphosphinopyrazine derivative and method for producing optically active phosphine transition metal complex
In the method for producing an optically active 2,3-bisphosphinopyrazine derivative of the present invention, an optically active 2,3-bisphosphinopyrazine derivative represented by the following formula (3) is produced by the step of: preparing solution A containing 2,3-dihalogenopyrazine represented by the following formula (1)
and a carboxylic acid amide coordinating solvent, lithiating an optically active R- or S-isomer of a hydrogen-phosphine borane compound represented by the following formula (2)
to give a lithiated phosphine borane compound; adding solution B containing the lithiated phosphine borane compound to the solution A to perform an aromatic nucleophilic substitution reaction; and then performing a deboranation reaction.
(For symbols in the formulas, see the description.)
x1-yy277 (wherein 1.7 ≤ x ≤ 2.2, 0 ≤ y ≤ 0.5, and M represents at least one metal element selected from Mg, Zn, Cu, Fe, Cr, Mn, Ni, Al, B, Na, K, F, Cl, Br, I, Ca, Sr, Ba, Ti, Zr, Hf, Nb, Ta, Y, Yb, Si, S, Mo, W, V, Bi, Te, Pb, Ag, Cd, In, Sn, Sb, Ga, Ge, La, Ce, Nd, Sm, Eu, Tb, Dy and Ho), the method being characterized by comprising: a first step of adding an organic acid and cobalt hydroxide to an aqueous solvent, and then adding phosphoric acid and lithium hydroxide to the resultant solution to prepare an aqueous raw material slurry (1); a second step of subjecting the aqueous raw material slurry (1) to a wet-mode pulverization treatment using a media mill to produce a slurry (2) containing a raw material pulverized product; a third step of subjecting the slurry (2) containing the raw material pulverized product to a spray drying treatment to produce a reaction precursor; and a fourth step of burning the reaction precursor at 600°C or higher. According to the present invention, it becomes possible to provide a method for producing lithium cobalt pyrophosphate that has a single phase as determined by X-ray diffraction in an industrially advantageous manner.
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
The method for producing vanadium dioxide includes a raw material mixing step for mixing divanadium pentoxide and a carbon material source and obtaining a raw material mixture, a firing step for firing the raw material mixture at from 340°C to less than 370°C in an inert gas atmosphere to obtain a fired body, and a cooling step for cooling the fired body to room temperature; in the raw material mixing step, the molar ratio (C/V) of carbon atoms in the carbon material source to vanadium atoms in the divanadium pentoxide is 2.2 or higher, and the cooling step includes an oxidation treatment step for switching from an inert gas atmosphere to an oxygen-containing atmosphere during cooling.
C09K 9/00 - Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
The present invention addresses the problem of providing coated particles in which insulating layers coat surfaces of conductive particles, wherein the surfaces of the conductive particles and the insulating layers have excellent adhesion. These coated particles comprise the conductive particles each of which has a metal coating on a surface of a core and a triazole compound deposited on an outer surface of the metal coating opposite the core, and the insulating layers that coat the conductive particles, each insulating layer including a compound that has a phosphonium group. The insulating layer preferably comprises a plurality of minute particles which are arranged in a layer, or is a continuous coating. The triazole compound is preferably a benzotriazole compound. The metal coating is preferably at least one metal coating selected from the group consisting of nickel, gold, nickel alloy, and gold alloy. The insulating layer also preferably comprises at least one polymer selected from the group consisting of styrene, ester, and nitrile.
H01B 5/00 - Non-insulated conductors or conductive bodies characterised by their form
H01B 5/16 - Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
H01R 11/01 - Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between their connecting locations
91.
PRODUCTION METHOD FOR LITHIUM COBALT PHOSPHATE AND PRODUCTION METHOD FOR LITHIUM COBALT PHOSPHATE-CARBON COMPLEX
x1-yy44 (in which 0.8≤x≤1.2, 0≤y≤0.5, and M represents one or more metallic elements selected from among Mg, Zn, Cu, Fe, Cr, Mn, Ni, Al, B, Na, K, F, Cl, Br, I, Ca, Sr, Ba, Ti, Zr, Hf, Nb, Ta, Y, Yb, Si, S, Mo, W, V, Bi, Te, Pb, Ag, Cd, In, Sn, Sb, Ga, Ge, La, Ce, Nd, Sm, Eu, Tb, Dy, and Ho). The production method is characterized by comprising: a first step in which an aqueous raw material slurry (1) is prepared by adding an organic acid and cobalt hydroxide to an aqueous solvent, then subsequently adding phosphoric acid and lithium hydroxide; a second step in which a slurry (2) that includes a raw material milled product is obtained by subjecting the aqueous raw material slurry (1) to wet milling using a media mill; a third step in which a reaction precursor is obtained by subjecting the slurry (2) that includes the raw material milled product to a spray drying treatment; and a fourth step in which the reaction precursor is fired. Thus, the present invention makes it possible to provide a method by which X-ray diffractive single-phase lithium cobalt phosphate can be obtained by an industrially useful method.
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
H01M 4/58 - Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFySelection of substances as active materials, active masses, active liquids of polyanionic structures, e.g. phosphates, silicates or borates
92.
NEGATIVE THERMAL EXPANSION MATERIAL, METHOD FOR MANUFACTURING SAME, AND COMPOSITE MATERIAL
A negative thermal expansion material characterized by comprising zirconium phosphate tungstate containing Al atoms and having a thermal expansion coefficient of -2.0×10-6to -3.3×10-6/K. According to the present invention, it is possible to provide negative thermal expansion materials comprising zirconium phosphate tungstate having various thermal expansion coefficients, and an industrially advantageous method for manufacturing the same.
C01B 25/45 - Phosphates containing plural metal, or metal and ammonium
C04B 35/447 - Shaped ceramic products characterised by their compositionCeramic compositionsProcessing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxides based on phosphates
93.
PHOSPHINOBENZENE BORANE DERIVATIVE PRODUCTION METHOD, 1,2-BIS(DIALKYLPHOSPHINO)BENZENE DERIVATIVE PRODUCTION METHOD AND TRANSITION METAL COMPLEX
The phosphinobenzene borane derivative production method is characterized by including a reaction process (A) comprising: obtaining an solution A containing the 1,2-dihalogenobenzene represented by general formula (1); [Chem. 1] obtaining a solution B containing a phosphine borane compound by deprotonating the hydrogen-phosphine borane compound represented by general formula (2); [Chem. 2] and obtaining the phosphinobenzene borane derivative represented by general formula (3) by adding the solution B to the solution A such that a reaction occurs therebetween. [Chem. 3] According to the present invention, a phosphinobenzene borane derivative production method that is industrially advantageous can be provided.
Provided is a photonic sintering-type composition that is characterized by comprising: cuprous oxide particles which contain at least one additional element selected from the group consisting of tin, manganese, vanadium, cerium, iron, and silver; metal particles which have a volume resistivity at 20°C of 1.0×10-3 Ωcm or less; and a solvent.
B22F 9/00 - Making metallic powder or suspensions thereofApparatus or devices specially adapted therefor
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
95.
SILYL PHOSPHINE COMPOUND, METHOD FOR PRODUCING SILYL PHOSPHINE COMPOUND AND METHOD FOR FORMING InP QUANTUM DOT
The silyl phosphine compound according to the present invention is represented by formula (1) and has an arsenic content of 1 ppm or less. The method according to the present invention for producing a silyl phosphine compound comprises: mixing a basic compound, a silylating agent and phosphine to give a solution containing a silyl phosphine compound; removing the solvent from the solution to give a liquid concentrate containing the silyl phosphine compound; and then distilling the liquid concentrate, wherein the arsenic content of the phosphine is regulated to 1 ppm by volume or less in terms of arsine. In the method according to the present invention for forming an InP quantum dot, a silyl phosphine compound that is represented by formula (1) (wherein R is as defined in the description) and has an arsenic content of 1 ppm by mass or less is used as a phosphorus source.
The silyl phosphine compound according to the present invention is represented by formula (1) and has an arsenic content of 1 ppm or less. The method according to the present invention for producing a silyl phosphine compound comprises: mixing a basic compound, a silylating agent and phosphine to give a solution containing a silyl phosphine compound; removing the solvent from the solution to give a liquid concentrate containing the silyl phosphine compound; and then distilling the liquid concentrate, wherein the arsenic content of the phosphine is regulated to 1 ppm by volume or less in terms of arsine. In the method according to the present invention for forming an InP quantum dot, a silyl phosphine compound that is represented by formula (1) (wherein R is as defined in the description) and has an arsenic content of 1 ppm by mass or less is used as a phosphorus source.
A method for producing InP quantum dots from a phosphorus source and an indium source, wherein a silylphosphine compound represented by general formula (1) is used as the phosphorus source, said silylphosphine compound having a content of a compound represented by general formula (2) of 0.3% by mole or less. It is preferable that a silylphosphine compound represented by general formula (1), which has a content of a compound represented by general formula (3) of 0.1% by mole or less, is used as the phosphorus source. (In general formula (1), each R independently represents an alkyl group having 1-5 carbon atoms (inclusive) or an aryl group having 6-10 carbon atoms (inclusive).) (In general formula (2), R is as defined in general formula (1).) (In general formula (3), R is as defined in general formula (1).)
2,3-BISPHOSPHINOPYRAZINE DERIVATIVE, METHOD FOR PRODUCING SAME, TRANSITION METAL COMPLEX, ASYMMETRIC CATALYST, AND METHOD FOR PRODUCING ORGANIC BORON COMPOUND
NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY (Japan)
Inventor
Ito, Hajime
Iwamoto, Hiroaki
Imamoto, Tsuneo
Tamura, Ken
Sano, Natsuhiro
Abstract
Provided is a 2,3-bisphosphinopyrazine derivative represented by general formula (1). (In the formula: R1, R2, R3and R4represent an optionally-substituted linear or branched alkyl group having 1–10 carbon atoms, an optionally-substituted cycloalkyl group, an optionally-substituted adamantyl group, or an optionally-substituted fenyl group. R5represents an optionally-substituted alkyl group having 1–10 carbon atoms, or an optionally-substituted fenyl group, and each R5 may be the same group or a different group. R6 represents a monovalent substituent. n represents an integer from 0-2.)
C07F 15/00 - Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
99.
Cuprous oxide particle, method of producing the same, photosintering composition, method of forming conductive film using the same and paste of cuprous oxide particles
Provided is a photosintering composition including cuprous oxide particles containing at least one additive element selected from the group consisting of tin, manganese, vanadium, cerium and silver, and a solvent. It is preferable that the cuprous oxide particle contain 1 ppm to 30,000 ppm of tin as the additive element. It is also preferable that the photosintering composition contain 3% by mass to 80% by mass of the cuprous oxide particles and 20% by mass to 97% by mass of the solvent.
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01B 13/00 - Apparatus or processes specially adapted for manufacturing conductors or cables
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
The process for producing a silyl phosphine compound of the present invention comprises a first step of mixing a solvent having a relative dielectric constant of not more than 4, a basic compound, a silylating agent and phosphine to obtain a solution containing a silyl phosphine compound, a second step of removing the solvent from the solution containing a silyl phosphine compound to obtain a concentrated solution of a silyl phosphine compound, and a third step of distilling the concentrated solution of a silyl phosphine compound to obtain the silyl phosphine compound. The silyl phosphine compound of the present invention is a silyl phosphine compound represented by the following general formula (1), wherein a content of a compound represented by the following general formula (2) is not more than 0.5 mol %. (For explanatory notes of the formulas, see the specification.)
