2, and formaldehyde. The overhead vapor stream can be cooled using an absorption refrigeration cycle to form a cooled overhead vapor stream. Olefin monomers can be separated from diluents in the cooled overhead vapor stream.
A process for dehydration of an ethanol feedstock into ethylene, comprising the vaporization of said ethanol feedstock in a mixture with at least a portion of the recycled purified water stream from heat exchange with the effluent that is obtained from the last reactor.
C07C 1/24 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes par élimination d'eau
C07C 7/04 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par distillation
The present invention relates to a device comprising at least one conductive or semiconductive layer, and at least one additional layer, said additional layer having a composition comprising polylactic acid (PLA) and at least one coated metal oxide particle.
H01L 31/04 - Dispositifs à semi-conducteurs sensibles aux rayons infrarouges, à la lumière, au rayonnement électromagnétique d'ondes plus courtes, ou au rayonnement corpusculaire, et spécialement adaptés, soit comme convertisseurs de l'énergie dudit rayonnement e; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de ces dispositifs ou de leurs parties constitutives; Leurs détails adaptés comme dispositifs de conversion photovoltaïque [PV]
H01L 51/44 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés, soit comme convertisseurs de l'énergie dudit rayonnement en énergie électrique, soit comme dispositifs de commande de l'énergie électrique par ledit rayonnement - Détails des dispositifs
H01L 33/44 - DISPOSITIFS À SEMI-CONDUCTEURS NON COUVERTS PAR LA CLASSE - Détails caractérisés par les revêtements, p.ex. couche de passivation ou revêtement antireflet
The present invention relates to a device comprising at least one conductive or semiconductive layer, and at least one additional layer, said additional layer having a composition comprising polyethylene terephthalate (PET) and at least one coated metal oxide particle.
H01L 31/04 - Dispositifs à semi-conducteurs sensibles aux rayons infrarouges, à la lumière, au rayonnement électromagnétique d'ondes plus courtes, ou au rayonnement corpusculaire, et spécialement adaptés, soit comme convertisseurs de l'énergie dudit rayonnement e; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de ces dispositifs ou de leurs parties constitutives; Leurs détails adaptés comme dispositifs de conversion photovoltaïque [PV]
H01L 51/44 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés, soit comme convertisseurs de l'énergie dudit rayonnement en énergie électrique, soit comme dispositifs de commande de l'énergie électrique par ledit rayonnement - Détails des dispositifs
H01L 33/44 - DISPOSITIFS À SEMI-CONDUCTEURS NON COUVERTS PAR LA CLASSE - Détails caractérisés par les revêtements, p.ex. couche de passivation ou revêtement antireflet
The present invention relates to a device comprising at least one conductive or semiconductive layer, and at least one additional layer, said additional layer having a composition comprising polystyrene (PS) and at least one, optionally coated, metal oxide particle.
H01L 31/04 - Dispositifs à semi-conducteurs sensibles aux rayons infrarouges, à la lumière, au rayonnement électromagnétique d'ondes plus courtes, ou au rayonnement corpusculaire, et spécialement adaptés, soit comme convertisseurs de l'énergie dudit rayonnement e; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de ces dispositifs ou de leurs parties constitutives; Leurs détails adaptés comme dispositifs de conversion photovoltaïque [PV]
H01L 51/44 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés, soit comme convertisseurs de l'énergie dudit rayonnement en énergie électrique, soit comme dispositifs de commande de l'énergie électrique par ledit rayonnement - Détails des dispositifs
H01L 33/44 - DISPOSITIFS À SEMI-CONDUCTEURS NON COUVERTS PAR LA CLASSE - Détails caractérisés par les revêtements, p.ex. couche de passivation ou revêtement antireflet
The present invention relates to a device comprising at least one conductive or semiconductive layer, and at least one additional layer, said additional layer having a composition comprising at least one polyolefin and at least one coated metal oxide particle.
H01L 31/04 - Dispositifs à semi-conducteurs sensibles aux rayons infrarouges, à la lumière, au rayonnement électromagnétique d'ondes plus courtes, ou au rayonnement corpusculaire, et spécialement adaptés, soit comme convertisseurs de l'énergie dudit rayonnement e; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de ces dispositifs ou de leurs parties constitutives; Leurs détails adaptés comme dispositifs de conversion photovoltaïque [PV]
H01L 51/44 - Dispositifs à l'état solide qui utilisent des matériaux organiques comme partie active, ou qui utilisent comme partie active une combinaison de matériaux organiques et d'autres matériaux; Procédés ou appareils spécialement adaptés à la fabrication ou au traitement de tels dispositifs ou de leurs parties constitutives spécialement adaptés, soit comme convertisseurs de l'énergie dudit rayonnement en énergie électrique, soit comme dispositifs de commande de l'énergie électrique par ledit rayonnement - Détails des dispositifs
H01L 33/44 - DISPOSITIFS À SEMI-CONDUCTEURS NON COUVERTS PAR LA CLASSE - Détails caractérisés par les revêtements, p.ex. couche de passivation ou revêtement antireflet
7.
Polymerization process with improved polymer homogeneity
The present invention relates to a process for the polymerization of an olefin monomer. In particular, the present invention relates to a process for the polymerization of an olefin monomer and one or more optional comonomers in presence of a polymerization catalyst and hydrogen, said process being characterized by an improved control of the hydrogen concentration in the polymerization reactor. In addition, the present invention provides for an improved hydrogen feeding system to a polymerization reactor. Furthermore, the present invention provides for a polymerization reactor comprising such an improved hydrogen feeding system.
C08F 210/00 - Copolymères d'hydrocarbures aliphatiques non saturés contenant une seule liaison double carbone-carbone
F01N 3/20 - Silencieux ou dispositifs d'échappement comportant des moyens pour purifier, rendre inoffensifs ou traiter les gaz d'échappement pour rendre les gaz d'échappement inoffensifs par conversion thermique ou catalytique des composants nocifs des gaz d'échappement caractérisés par les méthodes d'opérationCommande spécialement adaptés à la conversion catalytique
8.
Process for producing steam using heat recovered from a polymerization reaction
The present invention relates to a process for producing steam using heat recovered from a polymerization reaction. In particular, the present invention relates to a process for producing steam using heat recovered from a polymerization reaction for producing polyolefin, comprising the steps of: thermally contacting said polymerization reaction with a cooling fluid such that the cooling fluid removes heat from said reaction, thermally contacting at least part of said cooling fluid with at least one absorption cycle thereby transferring heat from the cooling fluid to said absorption cycle, using said absorption cycle to produce steam from a condensate, wherein the cooling fluid is used as a hot source for heating at least one evaporator and at least one generator comprised in said at least one absorption cycle. The present invention also relates to a process for cooling a polymerization reaction using a process as described herein. Said invention also relates to a polyolefin producing unit.
3+ alpha olefin comonomer and a diluent carrier liquid into a reactor system comprising at least one loop reactor; supplying at least one polymerization catalyst system to said reactor system; circulating said diluent liquid, ethylene monomer, and alpha olefin copolymer through said loop reactor while copolymerizing said ethylene and said alpha olefin monomer in the presence of said catalyst system to produce a slurry of polymer fluff particles in said diluent carrier liquid; diverting the flow of said slurry through said loop reactor into at least one settling leg connected to the loop reactor and sequentially discharging the settled polymer slurry from said at least one settling leg to withdraw said polymer slurry from said reactor system; and introducing an ethylene monomer co-feed into said loop reactor at least two spaced locations downstream of the point of introduction of ethylene comonomer and diluent in subparagraph a), said ethylene co-feed being introduced in an amount effective to reduce the variation in the ratio of ethylene monomer and comonomer within said loop reactor.
Centre National de la Recherche Scientifique (France)
Inventeur(s)
Helou, Marion
Guillaume, Sophie
Carpentier, Jean-François
Miserque, Olivier
Abrégé
This invention relates to the polymerisation of five-, six- or seven-membered cyclic carbonates by ring-opening polymerisation in the presence of a system comprising a metal salt such as triflate, triflimidate, acetylacetonate or carboxylate and an alcohol.
The present invention (in a first embodiment) relates to a process for the dehydration of an alcohol having at least 2 carbon atoms to make the corresponding olefin, comprising: introducing in a reactor a stream (A) comprising at least an alcohol, optionally water, optionally an inert component, contacting said stream with a catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, recovering from said reactor an olefin containing stream (B), wherein, the catalyst is a crystalline silicate of the group FER, MWW, EUO, MFS, ZSM- 48, MTT or TON having Si/Al under 100, or a dealuminated crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT or TON having Si/Al under 100, or a phosphorus modified crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT or TON having Si/Al under 100, the WHSV of the alcohol is at least 4 h-1 and/or the temperature ranges from 320°C to 600°C.
C07C 1/24 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes par élimination d'eau
The present invention concerns a heterophasic propylene copolymer of high melt flow for injection molding, which comprise a propylene polymer matrix and a rubber. The heterophasic propylene copolymers of the present invention are characterized by a high viscosity of the rubber phase and a well-defined ratio of the intrinsic viscosities of the rubber phase and the propylene polymer matrix, thus resulting in improved mechanical properties. The present invention further relates to a process for the production of such heterophasic propylene copolymers, their use and articles produced with them.
A resin composition comprising at least 0.1% by weight of poly(hydroxy carboxylic acid) and at least 50% by weight of polyethylene prepared with a single-site catalyst, preferably a metallocene.
The present invention is a process for removing oxygenated contaminants and water from an hydrocarbon stream comprising : introducing the contaminated hydrocarbon stream in a gaseous phase in an absorption zone, contacting said hydrocarbon stream in said absorption zone at a pressure of at least 5 bars, advantageously in the range 5 to 40 bars with an alcohol capable to absorb water and oxygenated contaminants at conditions effective to produce an overhead hydrocarbon stream having a reduced oxygenated contaminants and water content and an absorbent bottoms stream comprising the alcohol, hydrocarbons and having an enhanced oxygenated contaminants and water content, sending the overhead of the absorption zone to a wash column (referred to as the high pressure water wash column) at a pressure of at least 5 bars, advantageously in the range 5 to 40 bars, essentially washed with water at conditions effective to produce an overhead hydrocarbon stream having a reduced oxygenated contaminants and an aqueous bottoms stream having an enhanced oxygenated contaminants content. Advantageously the process is further comprising : sending the bottoms stream from the absorption zone to a distillation column (referred to as the alcohol distillation column) operating at a pressure of less than 3 bars absolute and advantageously at a pressure in the range 1 -3 bars absolute at conditions effective to produce a n overh ead com pri si n g essenti a l ly oxygen ated conta m i n a nts a n d hydrocarbons, optionally treated to recover the hydrocarbons, an alcohol bottoms stream comprising water and essentially free of hydrocarbons and oxygenated contaminants, sending said alcohol bottoms to the process which has produced the hydrocarbon stream comprising oxygenated contaminants and water to be purified
C07C 7/00 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs
C07C 7/11 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par absorption, c.-à-d. purification ou séparation d'hydrocarbures gazeux à l'aide de liquides
The present invention is a process for removing oxygenated contaminants and water from an hydrocarbon stream comprising : introducing the contaminated hydrocarbon stream in a gaseous phase in an absorption zone, contacting said hydrocarbon stream in said absorption zone with an absorbent capable to absorb water and oxygenated contaminants at conditions effective to produce, - an overhead hydrocarbon stream having a reduced oxygenated contaminants and water content and - an absorbent bottoms stream comprising the absorbent, hydrocarbons and having an enhanced oxygenated contaminants and water content, introducing the above absorbent bottoms stream in a stripping zone at conditions effective to produce, - an absorbent bottoms stream essentially free of hydrocarbons, oxygenated contaminants and water and - an overhead stream comprising essentially hydrocarbons, water and the oxygenated contaminants, recycling the absorbent bottoms stream of the stripping zone to the absorption zone, optionally fractionating the overhead stream from the stripping zone to recover the hydrocarbons, optionally sending the overhead of the absorption zone to a caustic wash to remove the acidic components and recovering an hydrocarbon stream essentially free of water and oxygenated contaminants.
C07C 7/00 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs
C07C 7/11 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par absorption, c.-à-d. purification ou séparation d'hydrocarbures gazeux à l'aide de liquides
The present invention is a process for removing oxygenated contaminants and water from an hydrocarbon stream comprising : introducing the contaminated hydrocarbon stream in a gaseous phase in an absorption zone, contacting said hydrocarbon stream in said absorption zone at a pressure of at least 5 bars, advantageously in the range 5 to 40 bars with an alcohol capable to absorb water and oxygenated contaminants at conditions effective to produce - an overhead hydrocarbon stream having a reduced oxygenated contaminants and water content and - an absorbent bottoms stream comprising the alcohol, hydrocarbons and having an enhanced oxygenated contaminants and water content, sending the overhead of the absorption zone to a wash column (referred to as the high pressure water wash column) at a pressure of at least 5 bars, advantageously in the range 5 to 40 bars, essentially washed with water at conditions effective to produce - an overhead hydrocarbon stream having a reduced oxygenated contaminants and - an aqueous bottoms stream having an enhanced oxygenated contaminants content. Advantageously the process is further comprising : sending the bottoms stream from the absorption zone to a distillation column (referred to as the alcohol distillation column) operating at a pressure of less than 3 bars absolute and advantageously at a pressure in the range 1-3 bars absolute at conditions effective to produce an overhead comprising essentially oxygenated contaminants and hydrocarbons, optionally treated to recover the hydrocarbons, an alcohol bottoms stream comprising water and essentially free of hydrocarbons and oxygenated contaminants, sending said alcohol bottoms to the process which has produced the hydrocarbon stream comprising oxygenated contaminants and water to be purified.
C07C 7/00 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs
C07C 7/11 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par absorption, c.-à-d. purification ou séparation d'hydrocarbures gazeux à l'aide de liquides
The present invention is a process for removing oxygenated contaminants and water from an hydrocarbon stream comprising: introducing the contaminated hydrocarbon stream in a gaseous phase in an absorption zone, contacting said hydrocarbon stream in said absorption zone with an absorbent capable to absorb water and oxygenated contaminants at conditions effective to produce, •an overhead hydrocarbon stream having a reduced oxygenated contaminants and water content and • an absorbent bottoms stream comprising the absorbent, hydrocarbons and having an enhanced oxygenated contaminants and water content, introducing the above absorbent bottoms stream in a stripping zone at conditions effective to produce, • an absorbent bottoms stream essentially free of hydrocarbons, oxygenated contaminants and water and • an overhead stream comprising essentially hydrocarbons, water and the oxygenated contaminants, recycling the absorbent bottoms stream of the stripping zone to the absorption zone, optionally fractionating the overhead stream from the stripping zone to recover the hydrocarbons, optionally sending the overhead of the absorption zone to a caustic wash to remove the acid ic components and recovering an hydrocarbon stream essentially free of water and oxygenated contaminants.
C07C 7/00 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs
C07C 7/11 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par absorption, c.-à-d. purification ou séparation d'hydrocarbures gazeux à l'aide de liquides
The present invention relates to a process for preparing a bimodal polyethylene product in a single loop reactor, comprising polymerizing ethylene monomer and optionally one or more olefin co-monomers in the presence of a single heterogeneous polymerization catalyst consisting of a metallocene-alumoxane catalyst immobilized on a porous support wherein said metallocene comprises only one transition metal. Said polymerization catalyst consists of two physically different fractions of support particles onto which said metallocene-alumoxane catalyst is immobilized.
The present invention relates to a method for monitoring the level of an ethylene polymerization catalyst slurry in a mud pot (2), whereby said catalyst slurry is prepared by introducing a solid catalyst and a liquid diluent in said mud pot (2), and whereby through sedimentation an interface (35) is formed between said diluent and the obtained catalyst slurry, characterized in that said interface (35) is monitored with Time Domain Reflectometry.
B01J 8/22 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées l'agent fluidisant étant un liquide du gaz étant introduit dans le liquide
The present invention relates to a method for optimizing the sequential use of at least two ethylene polymerization catalysts to an ethylene polymerization loop reactor, comprising: transferring to a mixing vessel a first ethylene polymerization catalyst and a first diluent, thereby providing a first catalyst slurry, transferring said first catalyst slurry from said mixing vessel to an ethylene polymerization loop reactor at a concentration suitable for polymerizing ethylene, increasing the ratio of said diluent to said first ethylene polymerization catalyst in said first catalyst slurry, stopping the supply of said first catalyst slurry to said mixing vessel, stopping the supply of said first catalyst slurry to said ethylene polymerization loop reactor, stopping the supply of ethylene to said ethylene polymerization loop reactor, removing said first catalyst slurry from said ethylene polymerization loop reactor, emptying said mixing vessel, optionally rinsing said mixing vessel with fresh diluent, transferring to said mixing vessel a second ethylene polymerization catalyst and a second diluent, thereby providing a second catalyst slurry, decreasing the ratio of said second diluent to said second ethylene polymerization catalyst in said mixing vessel to obtain a concentration of said second ethylene polymerization catalyst in said second diluent suitable for polymerizing ethylene, transferring said second ethylene polymerization catalyst slurry from said mixing vessel to said ethylene polymerization reactor, restoring the supply of ethylene to said ethylene polymerization loop reactor, restarting ethylene polymerization in said ethylene polymerization loop reactor.
The present invention relates to a method for initiating an ethylene polymerization reaction in an ethylene polymerization loop reactor. More particularly, the invention relates to the timing upon which hydrogen is introduced into the ethylene polymerization loop reactor. The catalysts used in the ethylene polymerization reaction according to present invention are preferably metallocene catalysts.
The present invention relates to a process for cleaning a catalyst slurry preparation system and/or a catalyst preparation system. More particularly, the invention relates to a cleaning process for a catalyst preparation system and/or for a catalyst slurry preparation system, wherein an aqueous catalyst inactivation agent is used to rinse the systems, or any parts thereof. The catalysts used in the present invention may be chromium, Ziegler-Natta or metallocene catalysts.
The present invention is a method for debottlenecking an existing steam cracker unit of which the operation is modified from high severity to low severity operation, having a cracking zone and a fractionation zone, said fractionation zone comprising a gasoline stripper, a de-methaniser (I), a de-ethaniser (I), a de-propaniser (I) and a de-butaniser (I), said de-propaniser (I) receiving product from the bottom of the de-ethaniser (I) and optionally product from the bottom of the gasoline stripper (I), wherein said debottlenecking method comprises the steps of : a) adding a selective hydrogenation unit (II), b) adding a cracking reactor (II) comprising a catalyst selective towards light olefins in the outlet, c) adding a re-run column and a de-propaniser (II), d) sending a part or all of the bottoms stream of the gasoline stripper (I) to the selective hydrogenation unit (II) and subsequently to the cracking reactor (II) at conditions effective to produce an outlet with an olefin content of lower molecular weight than that of the inlet, e) sending a part of the bottoms stream of the de-ethaniser (I) to the de-propaniser (II), such as, not to overload the de-propaniser (I), f) optionally sending a part or all of the overhead raw C4 fraction of the de-butaniser (I) to the selective hydrogenation unit (II), g) sending the cracking reactor (II) outlet to the re-run column to produce a C6+ bottom stream and a C1-C5 overhead, sending said overhead to the de-propaniser (II) to produce a C1-C3 overhead and a C4+ bottom stream recycled in whole or in part to the selective hydrogenation unit (II), optionally withdrawing a part of said C4+ bottom stream.
C10G 9/00 - Craquage thermique non catalytique, en l'absence d'hydrogène, des huiles d'hydrocarbures
C10G 51/04 - Traitement des huiles d'hydrocarbures, en l'absence d'hydrogène, uniquement par plusieurs procédés de craquage uniquement par plusieurs étapes en série ne comprenant que des étapes de craquage thermique et catalytique
C10G 69/06 - Traitement des huiles d'hydrocarbures par au moins un procédé d'hydrotraitement et au moins un autre procédé de conversion uniquement par plusieurs étapes en série comprenant au moins une étape de craquage thermique en l'absence d'hydrogène
24.
PROCESS FOR THE PREPARATION OF A PARTICULATE BIMODAL POLYETHYLENE PRODUCT
The invention relates to a process for the preparation of a particulate bimodal polyethylene product having a median particle diameter of less than 300 μm in a serially connected double loop reactor, wherein said polymerization catalyst applied in the polymerization process comprises a particulate metallocene-alumoxane catalyst immobilized on a porous silica support, wherein said polymerization catalyst has a median particle diameter of less than 50 μm; and whereby the ratio of the median particle diameter of the obtained bimodal polyethylene product to the median particle diameter of the applied polymerization catalyst is less than 30.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
25.
METHOD FOR REPLACING COMPATIBLE ETHYLENE POLYMERIZATION CATALYSTS
The present invention relates to a method for optimizing the sequential feeding of at least two ethylene polymerization catalysts to an ethylene polymerization reactor, comprising: transferring to a mixing vessel a first ethylene polymerization catalyst and a first diluent, decreasing the concentration of said first ethylene polymerization catalyst in said mixing vessel, - transferring to said mixing vessel a second ethylene polymerization catalyst and a second diluent, progressively replacing said first ethylene polymerization catalyst by said second ethylene polymerization catalyst and said first diluent by said second diluent, increasing the concentration of said second ethylene polymerization catalyst in said mixing vessel, sequentially transferring said first ethylene polymerization catalyst and said second ethylene polymerization catalyst from said mixing vessel to an ethylene polymerization reactor.
The invention relates to a process for the preparation of a particulate polyethylene product in a loop reactor, wherein the polymerization catalyst applied in the polymerization process comprises a particulate metallocene-alumoxane catalyst immobilized on a porous silica support; and whereby said metallocene-alumoxane catalyst is heterogeneously distributed on said porous silica support.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
The present invention relates to a method for producing a catalyst slurry blend suitable for polymerizing ethylene in an ethylene polymerization loop reactor for obtaining an at least trimodal polyethylene product, comprising the steps of: - transferring a first ethylene polymerization catalyst at a first mass flow rate to a mixing vessel, - simultaneously transferring a second ethylene polymerization catalyst at a second mass flow rate to said mixing vessel, thereby in situ providing a catalyst slurry blend, wherein said second ethylene polymerization catalyst is different from the first ethylene polymerization catalyst, - adjusting and monitoring said first and second mass flow rates, thereby obtaining said catalyst slurry blend at a concentration suitable for polymerizing ethylene, and - feeding said catalyst slurry blend to an ethylene polymerization double loop reactor producing said at least trimodal polyethylene product.
A polyethylene resin having a multimodal molecular weight distribution comprising at least two polyethylene fractions A and B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a Ziegler-Natta catalyst system, the polyethylene resin having a density of from 0.950 to 0.965 g/cm3 and a melt index MI2 of from 0.5 to 5 g/10min.
PPH. The invention further concerns the process to produce such heterophasic propylene copolymers. The heterophasic propylene copolymers of the present invention are particularly suited for corrugated sheet and cast film applications.
The present invention concerns a propylene polymer comprising at least two propylene polymer fractions of different melt flow index and a minor amount of at least one comonomer, said propylene polymer being further characterized by specific ranges for melt flow index, xylene solubles content and recovery compliance. Said propylene polymer is particularly suited for thermoforming. The present invention further concerns a process for producing said propylene polymer as well as its use in thermoforming.
The present invention relates to a process for recycling product streams that have been separated from a hydrocarbon-containing feed stream comprising olefin monomer, olefin co-monomer, hydrocarbon diluent and components such as H2, N2, O2, CO, CO2, and formaldehyde. In accordance with the present process a hydrocarbon-containing feed stream is separated into a) a first side stream comprising hydrocarbon diluent and olefin monomer; b) a second side stream which is substantially hydrogen-free and comprises hydrocarbon diluent and olefin monomer, c) a bottom stream comprising substantially olefin-free hydrocarbon diluent, and d) an overhead vapor stream comprising olefin monomer, hydrocarbon diluent and components such as formaldehyde, H2, N2, O2, CO and CO2. The present process further includes recycling said first and said second side streams in a polymerization process for preparing bimodal polyolefin.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Helou, Marion
Guillaume, Sophie
Carpentier, Jean-François
Brusson, Jean-Michel
Abrégé
The present invention discloses a method for polymerising cyclic carbonates by immortal ring-opening polymerisation in the presence of organocatalysts and alcohol, said alcohol acting as initiator and as transfer agent.
Use of fatty acids produced from a complex mixture of natural occurring oils & fats and/or of triglycerides deriving from said complex mixture as the feedstock of a steamcracker, by mixing the fatty acids with steam in a steam/feedstock ratio of at least 0.2 kg per kg, a coil outlet temperature of at least 700 °C and a coil outlet pressure of at least 1.2 bara in order to obtain cracking products including bio-ethylene, bio-propylene, bio-butadiene,bio-isoprene, bio-cyclopentadiene and bio-piperylenes, bio-benzene, bio-toluene, bio-xylene and bio-gasoline.
A process for making a bio-naphtha and optionally bio-propane from a complex mixture of natural occurring fats & oils, wherein -said complex mixture is subjected to a refining treatment for removing the major part of non- triglyceride and non-fatty acid components, thereby obtaining refined fats & oils; -said refined fats & oils are transformed into linear or substantially linear paraffin's as the bio-naphtha by an hydrodeoxygenation -or from said refined fats & oils are obtained fatty acids that are transformed into linear or substantially linear paraffin's as the bio-naphtha by hydrodeoxygenation or decarboxylation of the free fatty acids -or from said refined fats & oils are obtained fatty acids soaps that are transformed into linear or substantially linear paraffin's as the bio-naphtha by decarboxylation of the soaps.
C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p. ex. huiles, acides gras
C11C 3/12 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse par hydrogénation
C11C 3/00 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse
C11C 3/02 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse par estérification des acides gras avec la glycérine
36.
A PROCESS FOR THE PRODUCTION OF BIO-NAPHTHA FROM COMPLEX MIXTURES OF NATURAL OCCURRING FATS & OILS
Process for making a bio-diesel and a bio-naphtha and optionally bio-propane from a complex mixture of natural occurring fats & oils, wherein — said complex mixture is subjected to a refining treatment for removing the major part of the non- triglyceride and non-fatty acid components, thereby obtaining refined oils; - said refined oils are subjected to a fractionation step for obtaining: o an unsaturated or substantially unsaturated, liquid or substantially liquid triglyceride part (phase L); and o a saturated or substantially saturated, solid or substantially solid triglyceride part (phase S); and - said phase L is transformed into alkyl-esters as bio- diesel by a transesterification; - said phase S is transformed into linear or substantially linear paraffin's as the bio-naphtha : • by an hydrodeoxygenation • or from said phase S are obtained fatty acids that are transformed into linear or substantially linear paraffin's as the bio-naphtha by hydrodeoxygenation or decarboxylation of the free fatty acids or from said phase S are obtained fatty acids soaps that are transformed into linear or substantially linear paraffin's as the bio-naphtha by decarboxylation of the soaps.
C11C 3/12 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse par hydrogénation
C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p. ex. huiles, acides gras
37.
Process for preparing multilayer rotomoulded articles
This invention relates to the field of multilayer articles prepared by rotational molding with a robotized rotomolding machine wherein the mold is under direct heating.
This invention discloses caps and closures produced by injection moulding with a bimodal high density polyethylene (HDPE) resin comprising a low molecular weight, high density polyethylene fraction substantially free of comonomer and a high molecular weight, low density polyethylene fraction, having a molecular weight distribution of at least 3.5, preferably greater than 4,0, prepared in two reactors connected in series in the presence of a metallocene-containing catalyst system, wherein the metallocene comprises a bisindenyl or a bis-tetrahydrogenated-indenyl component.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
The present invention relates to a process for producing steam using heat recovered from a polymerization reaction. In particular, the present invention relates to a process for producing steam using heat recovered from a polymerization reaction for producing polyolefin, comprising the steps of: thermally contacting said polymerization reaction with a cooling fluid such that the cooling fluid removes heat from said reaction, thermally contacting at least part of said cooling fluid with at least one absorption cycle thereby transferring heat from the cooling fluid to said absorption cycle, using said absorption cycle to produce steam from a condensate, wherein the cooling fluid is used as a hot source for heating at least one evaporator and at least one generator comprised in said at least one absorption cycle. The present invention also relates to a process for cooling a polymerization reaction using a process as described herein. Said invention also relates to a polyolefin producing unit.
B01J 19/18 - Réacteurs fixes avec éléments internes mobiles
C08F 10/00 - Homopolymères ou copolymères d'hydrocarbures aliphatiques non saturés contenant une seule liaison double carbone-carbone
F22B 1/16 - Méthodes de production de vapeur caractérisées par le genre de chauffage par exploitation de l'énergie thermique contenue dans une source chaude la source chaude étant un liquide chaud ou une vapeur chaude, p. ex. un liquide résiduel, une vapeur résiduelle
F22B 1/18 - Méthodes de production de vapeur caractérisées par le genre de chauffage par exploitation de l'énergie thermique contenue dans une source chaude la source chaude étant un gaz chaud, p. ex. des gaz d'évacuation tels que les gaz d'échappement de moteurs à combustion interne
40.
EXPANDABLE VINYL AROMATIC POLYMERS AND PROCESS FOR THE PREPARATION THEREOF
The present invention is an expandable vinyl aromatic polymer which comprises: a ) a matrix of a branched aromatic ionomer, b ) 1 -10% by weight calculated with respect to the polymer (a), of an expanding agent englobed in the polymeric matrix, c ) 0-20% by weight, calculated with respect to the polymer (a), of a filler homogeneously distributed in the polymeric matrix, in which, the branched aromatic ionomer comprises the product of co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer comprising an ionic moiety and at least two unsaturated moieties, wherein the ionic moiety has at least two ionizable groups, a cationic group that ionizes to form cations and an anionic group that ionizes to form anions, and wherein the cationic group is polyvalent and one capable of forming bridges to other molecules. The present invention also relates to the use of the expandable vinyl aromatic polymer to make expanded articles, in particular insulation boards.
The present invention relates to a process for the polymerization of an olefin monomer. In particular, the present invention relates to a process for the polymerization of an olefin monomer and one or more optional comonomers in presence of a polymerization catalyst and hydrogen, said process being characterized by an improved control of the hydrogen concentration in the polymerization reactor. In addition, the present invention provides for an improved hydrogen feeding system to a polymerization reactor. Furthermore, the present invention provides for a polymerization reactor comprising such an improved hydrogen feeding system.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Pannier, Gaëlle
Boisson, Christophe
Spitz, Roger
Abrégé
The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerisation of olefins comprising the steps of: I) providing a support consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalising the support with a solution containing a metallic salt; IV) heating the functionalised support of step c) under an inert gas or hydrogen; V) oxidising the support of step IV by treatment under N2O and then under oxygen; Vl) retrieving an active support having a controlled number of OH groups. That activating support is used to activate a metallocene catalyst component for the polymerisation of olefins.
wherein the working fluid is phase converted thereby providing energy in the form of heat and/or electricity and/or mechanical power back to the polyolefin production process.
Said invention also relates to a polymerization process for producing olefin polymers in a reactor, and also relates to a process for energy optimization of energy consumption in a polymerization process and to a polymerization unit.
B01J 19/18 - Réacteurs fixes avec éléments internes mobiles
F25B 27/02 - Machines, installations ou systèmes utilisant des sources d'énergie particulières utilisant la chaleur perdue, p. ex. chaleur dégagée par des moteurs à combustion interne
44.
CATALYTIC SYSTEMS FOR IMMORTAL RING-OPENING POLYMERISATION OF CYCLIC ESTERS AND CYCLIC CARBONATES.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Carpentier, Jean-François
Sarazin, Yann
Poirier, Valentin
Helou, Marion
Abrégé
The present invention discloses new catalyst systems based on complexes of divalent metals supported by chelating phenoxy ligands for immortal ring-opening polymerisation of cyciic esters and cyclic carbonates.
The present invention is a process to upgrade light naphthas comprising branched paraffins and their use as a feedstock in a steam cracking unit, said light naphthas consisting essentially of 90 to 100% by weight of hydrocarbons having at least 5 and up to 8 carbon atoms, said process comprising, a)optionally providing an isomerization zone recovered from the gasoline unit of an oil refinery, b)optionally providing a separation zone capable to treat an hydrocarbon stream comprising branched paraffins and normal paraffins to produce a first hydrocarbon stream having a reduced branched paraffins content and an enhanced normal paraffins content and a second hydrocarbon stream having an enhanced branched paraffins content and a reduced normal paraffins content, c)optionally providing a depentanizer, such that at least two of a), b) and c) are present, wherein, the light naphtha is sent to one of a), b) and c), streams are circulating between the various zones a), b) or c), a stream rich in normal paraffins is sent to the steam cracking unit.
C10G 9/00 - Craquage thermique non catalytique, en l'absence d'hydrogène, des huiles d'hydrocarbures
C10G 45/58 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour changer la structure du squelette de certains hydrocarbures sans craquer les autres hydrocarbures présents, p. ex. pour abaisser le point d'écoulementHydrocraquage sélectif des paraffines normales
C10G 45/62 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour changer la structure du squelette de certains hydrocarbures sans craquer les autres hydrocarbures présents, p. ex. pour abaisser le point d'écoulementHydrocraquage sélectif des paraffines normales caractérisé par le catalyseur utilisé contenant des métaux du groupe du platine ou leur composés
C10G 45/64 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour changer la structure du squelette de certains hydrocarbures sans craquer les autres hydrocarbures présents, p. ex. pour abaisser le point d'écoulementHydrocraquage sélectif des paraffines normales caractérisé par le catalyseur utilisé contenant des alumino-silicates cristallins, p. ex. des tamis moléculaires
C10G 69/06 - Traitement des huiles d'hydrocarbures par au moins un procédé d'hydrotraitement et au moins un autre procédé de conversion uniquement par plusieurs étapes en série comprenant au moins une étape de craquage thermique en l'absence d'hydrogène
C10G 69/14 - Traitement des huiles d'hydrocarbures par au moins un procédé d'hydrotraitement et au moins un autre procédé de conversion uniquement par plusieurs étapes en parallèle
46.
Process for the separation of a hydrocarbon-containing feed stream
The present invention relates to a process for the separation by distillation of a hydrocarbon-containing feed stream containing olefin monomer, co-monomer and hydrocarbon diluent. The present invention also relates to a distillation system including a distillation column for carrying out the process according to the invention.
The present invention relates to a method for preparing and extruding a bimodal polyethylene product, which comprises a first polyethylene fraction and a second polyethylene fraction having a different molecular weight than the first polyethylene fraction. More specifically, the present invention relates to a method for controlling the specific energy applied on said bimodal polyethylene product by regulating the amount of the polyethylene fraction having the higher molecular weight in said bimodal polyethylene product. According to the present invention regulation of the amount of said polyethylene fraction having the higher molecular weight in said bimodal polyethylene product is obtained by regulating the polymerization conditions for preparing the bimodal polyethylene product, and in particular by adjusting ethylene monomer feed during the polymerization process.
The present invention is a composition stabil ized aga inst prematu re polymerization comprising : a) one or more olefinic monomers, b) one or more oxygenated components capable to be converted to peroxides, c) an efficient amount of one or more additives capable to inhibit the polymerization of the olefinic monomers of a), d) optionally an efficient amount of one or more additives capable to inhibit the production of peroxides. In an embodiment to make the stabilized composition, the additives c) and d) are introduced separately into the mixture of a) and b). The oxygenated components capable to be converted to peroxides can be selected among alcohols, aldehydes, cetones, ethers and organic acids. The additive capable to inhibit the polymerization of the olefinic monomers can be a stable free radical or hydroxylamines substituted with at least one alkyl, aryl, alkylaryl, hydroxyalkyl or hydroxylaryl group. The stable free radical is advantageously a stable nitroxide. The additive capable to inhibit the production of peroxides can be selected among the unhindered phenols, the hindered phenols, the aminophenols and the phenylenediamines.
The present invention relates to a process for quenching the effluent gas of a furnace comprising : a)providing a furnace comprising a radiant zone enclosure means having a plurality of tubes disposed therein, an inlet means for introducing the process fluid into the tubes, means for exposing the external surface of the tubes to radiant heat for heating said process fluid and thereby produce an effluent gas, b)providing a quench zone having a plurality of quench tubes in which the effluent gas is passed and such as the inlet of one quench tube is connected to the outlet of one or more tubes of the radiant zone, c)recovering the effluent gas after it has been cooled in the quench tubes, wherein, at least a part of the quench tubes and advantageously all the quench tubes are tubes having means inside of it, on all the length or a part of the length, to promote turbulent flow by breaking the boundary film on the internal surface of the tube. The present invention also relates to a quench exchanger to carry out the above process.
B01J 8/06 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés avec des particules immobiles, p. ex. dans des lits fixes dans des réacteurs tubulairesProcédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés avec des particules immobiles, p. ex. dans des lits fixes les particules solides étant disposées dans des tubes
F28F 13/12 - Dispositions pour modifier le transfert de chaleur, p. ex. accroissement, diminution en affectant le mode d'écoulement des sources de potentiel calorifique en créant une turbulence, p. ex. par brassage, par augmentation de la force de circulation
The present invention relates to a polypropylene composition comprising a first component being a propylene polymer produced in presence of a metallocene-based catalyst system, and a second component being a random copolymer of propylene and one or more comonomers, said random copolymer being produced in presence of a Ziegler-Natta polymerization catalyst. The polypropylene composition of the present invention is particularly suited for blown film and is characterized by excellent optical properties. Further, the present invention relates to a multilayer film or a laminate comprising such a blown film. Additionally, the present invention relates to a process for producing such a blown film, multilayer film or laminate.
The present invention is a refrigerator interior liner made of a rubber modified monovinylaromatic polymer composition comprising: a) a monovinylaromatic polymer matrix having an average molecular weight in weight Mw above 150,000 g/mol, b) rubber particles dispersed therein, said particles having: a volume median particle size (RPS volume) of about 8.5 μm, a monomodal distribution with essentially no shoulder, a low-to-moderate crosslinking of the rubber expressed as a swell index (SI) above 13.8, a rubber phase volume fraction (RPVF) of at least 39%, c) a moderate amount of low-Mw plasticizers, defined as the weight fraction of solubles in methanol, and such that the weight ratio c/(a+b+c) ranges from 0 to 5%. The present invention is also a process for preparing the above composition comprising: a) forming a polymerizable mixture comprising at least one monovinylaromatic monomer and optionally one or more comonomers, b) dissolving at least a viscous rubber of essentially linear structure in said polymerizable mixture to form a rubber containing polymerizable solution, c) contacting a free radical initiator and a chain transfer agent with the polymerizable mixture at conditions whereby phase inversion subsequently occurs, wherein the chain transfer agent is capable to produce an increase of the rubber to PS phase viscosity ratio within the inversion reactor, d) continuing the polymerization of the solution obtained at step c), optionally in the presence of a free radical initiator, until a monovinylaromatic polymer matrix having rubber particles dispersed therein is obtained.
C08L 51/04 - Compositions contenant des polymères greffés dans lesquels le composant greffé est obtenu par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carboneCompositions contenant des dérivés de tels polymères greffés sur des caoutchoucs
C08F 279/02 - Composés macromoléculaires obtenus par polymérisation de monomères sur des polymères de monomères contenant plusieurs liaisons doubles carbone-carbone tels que définis dans le groupe sur des polymères de diènes conjugués
C08F 2/38 - Polymérisation utilisant des régulateurs, p. ex. des agents d'arrêt de chaîne
52.
PROCESS TO MAKE OLEFINS FROM ORGANICS AND PARAFFINS
The present invention relates to a process to make light olefins, in a XTO process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, c) contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) fractionating said heavy hydrocarbon fraction to remove the essential part of the aromatics and recovering a heavy hydrocarbon fraction having a reduced aromatics content; f) recycling at least a part of said heavy hydrocarbon fraction having a reduced aromatics content at the inlet of the XTO reaction zone; wherein, to adjust the proportion of C4+ paraffins recycled at the inlet of the XTO reaction zone, a fraction of the stream recycled at step f) is purged.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
C07C 1/26 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'halogènes en tant qu'hétéro-atomes
C07C 1/32 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés renfermant des hétéro-atomes autres que l'oxygène ou les halogènes, ou en addition à ceux-ci
The present invention is a burner tip to be used in a furnace for the combustion of fuel gas in the combustion zone of said furnace, comprising a burner tube having a longitudinal axis and having a downstream end and an upstream end for receiving the fuel gas, wherein, the furnace comprises means to introduce an effective amount of air into the combustion zone to cause the combustion of the fuel gas, the burner tube extends through an opening in the wall or floor into the combustion zone, the burner tube comprises a plurality of primary ports to deliver the primary fuel gas in the combustion zone, said primary ports are located in the combustion zone in order to create the fuel-lean combustion zone, a bluff body is attached to the tube, located close to the primary ports which deliver the primary fuel gas and between said ports and the upstream end of the burner tube, the bluff body is designed to produce, in the vicinity of the ports which deliver the primary fuel gas, an air speed as low as possible, advantageously lower than the flame speed, such as the said primary fuel gas is given sufficient residence time to ignite, the burner tube comprises a plurality of secondary ports to deliver the secondary fuel gas in the combustion zone, said secondary ports are located in the flue gas zone (or outside the combustion zone) in order to create a fuel-rich zone, said secondary ports are located between the primary ports and the downstream end, optionally other ports are located after the secondary ports having regards to the fuel gas flow from the upstream end to the downstream end. The flame stabilization is ensured by the bluff body, for example fins or a perforated plate, which has been welded to the tip just below the primary fuel ports. The flame stabilizer creates a recirculation zone for the air in which the primary fuel is given sufficient residence time to ignite.
The present invention relates to the use of a resin composition comprising from 5% to 100% by weight of a polyethylene having a density of from 0.947 to 0.970 g/c3 when measured according to ASTM D 1505 and a molecular weight distribution of less than 4 produced with a metallocene catalyst, and from 0% to 95% by weight of a polyolefin selected from the group consisting of very low density polyethylene, low density polyethylene, linear low density polyethylene, medium density polyethylene, Ziegler-Natta catalysed high density polyethylene, chromium catalysed high density polyethylene, ethylene vinyl acetate copolymers and mixtures thereof to produce films having improved impact resistance.
GOSUDARSTVENNOE UCHEBNO-NAUCHNOE UCHREZHDENIE KHIMICHESKY FAKULTET MOSKOVSKOGO GOSUDARSTVENNOGO UNIVERSITETA IM. M.V.LOMONOSOVA (Russie)
Inventeur(s)
Voskoboynikov, Alexander, Z.
Izmer, Vyatcheslav, V.
Kononovich, Dmitry, S.
Razavi, Abbas
Abrégé
This invention relates to the synthesis of substituted tetrahydroindenyls and the use of the synthesised complexes in the homo- and co-polymerisation of ethylene and alpha-olefins.
A multilayer film comprising a first layer comprising a poly(hydroxy carboxylic acid) and a second layer adjacent to the first layer comprising more than 50 % by weight of polyethylene prepared with a single-site catalyst, preferably a metallocene catalyst.
B32B 27/32 - Produits stratifiés composés essentiellement de résine synthétique comprenant des polyoléfines
B32B 27/36 - Produits stratifiés composés essentiellement de résine synthétique comprenant des polyesters
B32B 27/08 - Produits stratifiés composés essentiellement de résine synthétique comme seul composant ou composant principal d'une couche adjacente à une autre couche d'une substance spécifique d'une résine synthétique d'une sorte différente
B65D 65/46 - Emploi de matériaux désintégrables, solubles ou comestibles
57.
METHOD TO PURIFY OLEFIN-CONTAINING HYDROCARBON FEEDSTOCKS
A process for purifying an olefin-containing hydrocarbon feedstock comprising the steps of: (a)passing the said hydrocarbon feedstock in the presence of hydrogen over a first catalyst bed material comprising nickel deposited on a support material wherein said nickel is present as both nickel oxide and metallic nickel (b)recovering the feedstock having a substantially reduced acetylenics (in particular methylacetylene) and allenes (in particular propadiene) content.
C07C 7/163 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par traitement provoquant une modification chimique d'au moins un composé par hydrogénation
C07C 7/167 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par traitement provoquant une modification chimique d'au moins un composé par hydrogénation pour éliminer les composés comportant une triple liaison carbone-carbone
Selective hydrogenation process comprising: • contacting in the presence of hydrogen an hydrocarbon feedstock comprising at least one unsaturated compound selected from the group consisting of al kynes and dienes and mixtures thereof with a first hydrogenation catalyst in a first reaction zone to produce a first product stream having a reduced proportion of alkynes and/or dienes; and • contacting the first product stream in a second reaction zone having an inlet and an outlet, in the presence of optional additional hydrogen, with a second hydrogenation catalyst to produce a second product stream, wherein, the first hydrogenation catalyst comprises: • a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and optionally a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11-14 of the Periodic Table of Elements, and said first constituent and optional second constituent are on a carrier made essentially of SiC or of an alkaline earth metal silicate. Hydrogenation catalyst comprising : • a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11 -14 of the Periodic Table of Elements, and • said first constituent and second constituent are on a carrier made essentially of an alkaline earth metal silicate or of SiC, • the second constituent is optional if the carrier is made essentially of SiC.
Hydrogenation process comprising: contacting in the presence of hydrogen an hydrocarbon feedstock comprising at least one unsaturated compound selected from the group consisting of alkynes and dienes and mixtures thereof with an hydrogenation catalyst in a reaction zone to produce a product stream having a reduced proportion of alkynes and/or dienes, wherein, the hydrogenation catalyst comprises : • a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11-14 of the Periodic Table of Elements, • said first constituent and second constituent are on a carrier made essentially of SiC or of an alkaline earth metal silicate and • the second constituent is optional if the carrier is made essentially of SiC. Hydrogenation catalyst comprising : • a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11-14 of the Periodic Table of Elements, and • said first constituent and second constituent are on a carrier made essentially of an alkaline earth metal silicate or of SiC, • the second constituent is optional if the carrier is made essentially of SiC.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Carpentier, Jean-François
Helou, Marion
Guillaume, Sophie
Razavi, Abbas
Abrégé
The present invention discloses a process for preparing di-, tri, or multi-block polyester/polycarbonate (co)polymers by ring-opening polymerisation in the presence of a non-toxic catalyst system in combination with either a linear monohydroxy HO-PC-OR, or a linear telechelic dihydroxy HO-PC-OH, or a star polyhydroxy R-(PC-OH)n end-capped polyester/polycarbonate.
The present invention relates to a process to make alpha olefins comprising: dehydrating ethanol to recover an ethylene stream, introducing said ethylene stream into an oligomerization zone containing an oligomerization catalyst and into contact with said oligomerization catalyst, operating said oligomerization zone at conditions effective to produce an effluent consisting essentially of 1-butene, 1-hexene, optionally heavier alpha olefins and unconverted ethylene if any, introducing the above effluent into a fractionation zone to recover a stream consisting essentially of 1-butene, a stream consisting essentially of 1-hexene, optionally a stream consisting essentially of heavier alpha olefins and an optional ethylene stream. In an advantageous embodiment the 1-hexene or at least one heavier alpha olefins, if any, are isomerized to an internal olefin and subsequently transformed by metathesis with the aid of additional ethylene into different alpha-olefins with even or odd number of carbons. By way of example 1-hexene is isomerized into 2-hexene and by methathesis with ethylene converted to 1-pentene and propylene. In another embodiment the oligomerization zone is only a dimerization zone and butene is produced. 1-butene is isomerized to 2-butene and sent to a methathesis zone in the presence of ethylene to be converted to propylene. In said embodiment the dehydration catalyst is selected in the group consisting of a crystalline silicate having a ratio Si/AI of at least about 100, a dealuminated crystalline silicate, and a phosphorus modified zeolite.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Carpentier, Jean-François
Kirillov, Evgueni
Marquet, Nicolas
Razavi, Abbas
Abrégé
The present invention discloses a method for preparing long-chain-branched isotactic polypropylene by first oligomerising propylene with a suitable oligomerisation catalyst system and then copolymerising propylene and the oligomer obtained in situ with a mono-aryl-substituted methylene bridged catalyst system.
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
63.
PURIFICATION OF ALCOHOLS PRIOR TO THEIR USE IN THE PRESENCE OF AN ACID CATALYST
Process for the purification of an alcohol in the course of a process comprising : (1) providing a reaction zone (C) comprising an acid type catalyst; (2) providing a reaction zone (B) comprising an acid adsorbent material; (3) providing an alcohol stream comprising impurities; (4) introducing the alcohol stream of (3) into the reaction zone (B) and bringing said stream into contact with the acid adsorbent material at conditions effective to reduce the amount of impurities having an adverse effect on the acid type catalyst of the reaction zone (C); (5) recovering from step (4) an alcohol stream and introducing it into the reaction zone (C); (6) optionally introducing one or more reactants (R) into the reaction zone (C); (7) operating said reaction zone (C) at conditions effective to recover a valuable effluent.
The present invention relates to a method for optimizing the supply of a catalyst slurry during a polymerization process for preparing a polyolefin in a polymerization reactor (1), whereby said slurry consists of solid catalyst particles suspended in a hydrocarbon diluent and is characterised by a ratio of solid catalyst particles/diluent, whereby the catalyst slurry is fed to the reactor through at least two parallel catalyst feeding conduits (4, 104) which are intermittently operative in the polymerisation process, said method comprising the steps of : - determining an effective initial ratio solid catalyst particles/diluent for the polymerization process; - determining the actual ratio solid catalyst particles/diluent in a first operative feeding conduit (4); - calculating the difference between actual and initial ratio and in the event that said difference is more than a specified threshold, shutting down the first catalyst feeding conduit (4) and activating a second catalyst feeding conduit (104). The catalyst slurry is periodically supplied to the reactor. The invention also relates to polyolefin production processes and polyolefin producing units.
A multi-component article with controllable degradation and/or disintegration, comprising: - a first part (A) which comprises at least one polyolefin combined with at least one prodegradation/prodisintegration agent; and; - a second part (B) which comprises at least one polyolefin combined with at least one pr odegr adat i on /prodi s integration agent, provided that said first and said second parts differ at least by either one of type of polyolefin, type of prodegradation/prodisintegration agent and level of pr odegr adat ion /prodi s integration agent, the types of polyolefin and of prodegradation/prodisintegration agent and the levels of prodegradation/prodisintegration agent being selected so as said part (B) degrades more slowly than said part (A), and said part (B) at least partially covers said part (A).
C08L 23/00 - Compositions contenant des homopolymères ou des copolymères d'hydrocarbures aliphatiques non saturés ne possédant qu'une seule liaison double carbone-carboneCompositions contenant des dérivés de tels polymères
66.
ROTOMOULDED STRUCTURAL PARTS HAVING ASYMMETRICAL LAYERING
B29C 41/06 - Coulée par rotation ou par centrifugation, c.-à-d. revêtement de la surface interne d'un moule par rotation du moule autour d'au moins deux axes
B29C 41/22 - Fabrication d'objets multicouches ou polychromes
A process is described for obtaining a chemical blend of a polyolefin with a poly(hydroxy carboxylic acid) by mixing poly(hydroxy carboxylic acid) with at least one polyolefin in the presence of a compatibilising compound having at least one polymerisable double bond and at least one electrophilic functional group. The invention also relates to the chemical blend obtainable according to this process, as well as the use of the compatibilising compound to obtain chemical blends of polyolefin with poly(hydroxy carboxylic acid).
C08F 255/02 - Composés macromoléculaires obtenus par polymérisation de monomères sur des polymères d'hydrocarbures tels que définis dans le groupe sur des polymères d'oléfines contenant deux ou trois atomes de carbone
C08G 81/02 - Composés macromoléculaires obtenus par l'interréaction de polymères en l'absence de monomères, p. ex. polymères séquencés au moins un des polymères étant obtenu par des réactions ne faisant intervenir que des liaisons non saturées carbone-carbone
C08J 3/22 - Formation de mélanges de polymères avec des additifs, p. ex. coloration en utilisant les techniques des charges mères
68.
ACTIVATING SUPPORTS BASED ON PERFLUORINATED BORONIC ACIDS
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Pannier, Gaëlle
Boisson, Christophe
Spitz, Roger
Slawinski, Martine
Abrégé
The present invention discloses activating supports based on perfluorinated boronic acids and aluminium alkyls and their use in the activation of metallocene and post- metallocene complexes for the polymerisation of ethylene and alpha-olefins.
C08F 210/16 - Copolymères de l'éthylène avec des alpha-alcènes, p. ex. caoutchoucs EP
C08F 4/6592 - Composant couvert par le groupe contenant une liaison métal de transition-carbone contenant au moins un cycle cyclopentadiényle, condensé ou non, p. ex. un cycle indényle ou fluorényle
C08F 4/70 - Métaux du groupe du fer, métaux du groupe du platine ou leurs composés
69.
METHOD FOR ADDITIVATING POLYMERS IN ROTOMOULDING APPLICATIONS
This invention relates to a method for additivating polymer resins with antioxidants and anti UV stabilsers. It is particularly suitable for resins used rotomoulding applications.
B29C 41/00 - Façonnage par revêtement d'un moule, noyau ou autre support, c.-à-d. par dépôt de la matière à mouler et démoulage de l'objet forméAppareils à cet effet
C08J 3/20 - Formation de mélanges de polymères avec des additifs, p. ex. coloration
C08F 6/26 - Traitement des polymères préparés en masse
B29C 41/04 - Coulée par rotation ou par centrifugation, c.-à-d. revêtement de la surface interne d'un moule par rotation du moule
A process for obtaining a metalloaluminophosphate (MeAPO) molecular sieve comprising the following steps in the order given: a), providing an aqueous solution containing sources of at least 2 of the following: Metals (Me), Al and P; b). co-precipitating an amorphous precursor of the molecular sieve from the solution by changing the solution's pH, followed by separating the amorphous precursor from the water, optionally including formulation; c). optionally washing and drying at a temperature below 45O°C of the amorphous precursor; d). contacting the amorphous precursor with a template-containing aqueous solution and with a source of Al, P or Me, which is not already present in step (a) and optionally additional sources of Al and/or P and/or Me; and e). partially crystallising the molecular sieve under autogeneous conditions so that 5 to 90% by weight of the amorphous precursor crystallises.
C01B 39/00 - Composés ayant des propriétés de tamis moléculaires et d'échangeurs de base, p. ex. zéolites cristallinesLeur préparationPost-traitement, p. ex. échange d'ions ou extraction de l'aluminium
C01B 39/54 - Phosphates, p. ex. composés APO ou SAPO
C01B 37/06 - Aluminophosphates contenant d'autres éléments, p. ex. métaux, bore
The invention relates to a process for obtaining a metalloaluminophosphate (MeAPO) molecular sieve comprising the following steps in the order given: a) providing a homogeneous solution containing sources of at least 2 of the following: -aluminium (Al), -phosphorous (P), -metal (Me); b) adding a first MeAPO molecular sieve to the solution and modifying the pH before and/or after the addition of the first MeAPO molecular sieve to obtain an amorphous precursor; c) separating the amorphous precursor from the water; d) optionally washing and drying at a temperature below 450°C of the amorphous precursor; e) contacting the amorphous precursor with an organic template-containing aqueous solution and with a source of Al, P or Me, which is not already present in step (a), optionally additional sources of Al and/or P and/or Me and optionally in the presence of aliphatic alcohols; f) performing a crystallization of the amorphous precursor under autogeneous conditions so as to increase the concentration of the crystalline molecular sieve in respect to the initial precursor and so as to obtain a second MeAPO molecular sieve.
C01B 39/00 - Composés ayant des propriétés de tamis moléculaires et d'échangeurs de base, p. ex. zéolites cristallinesLeur préparationPost-traitement, p. ex. échange d'ions ou extraction de l'aluminium
B01J 29/04 - Catalyseurs contenant des tamis moléculaires ayant des propriétés d'échangeurs de base, p. ex. zéolites cristallines, argiles pontées
B01J 49/00 - Régénération ou réactivation des échangeurs d'ionsAppareillage à cet effet
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Helou, Marion
Guillaume, Sophie
Carpentier, Jean-François
Miserque, Olivier
Abrégé
This invention relates to the polymerisation of five-, six- or seven-membered cyclic carbonates by ring-opening polymerisation in the presence of a system comprising a metal salt such as triflate, triflimidate, acetylacetonate or carboxylate and an alcohol.
The present invention is a process for making an olefin product from an oxygen-containing organic feedstock comprising: providing a mixture of said oxygen-containing feedstock, an hydrocarbon and optionally an inert diluent, contacting said mixture in a reaction zone having an inner surface (the MTO reactor) with a zeolitic catalyst at conditions effective to convert at least a part of the oxygen-containing organic feedstock to olefin products (the MTO reactor effluent), recovering a reactor effluent comprising light olefins, a heavy hydrocarbon fraction and undesired by-products, wherein :at least a part of the inner surface is passivated such that the undesired by-products are reduced by comparison with a non passivated inner surface and /or one or more sulphur compound is co-injected with the said oxygen-containing feedstock and the hydrocarbon and said sulphur compound is capable to reduce the undesired by-products by comparison with a non injection of sulphur compound.The present invention is of high interest for the catalyst of the ZSM type such as ZSM-5 optionally containing phosphorus and regenerated in the MTO reactor.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
74.
BICOMPONENT FIBERS WITH AN EXTERIOR COMPONENT COMPRISING POLYPROPYLENE
The present invention relates to bicomponent fibers with improved bonding properties. In particular, the present invention relates to bicomponent fibers comprising an exterior component, which in turn comprises a polypropylene that has been degraded from a first melt flow index MFI1 (measured according to ISO 1133, condition L, 230°C, 2.16 kg) to a second melt flow index MFI2 (measured according to ISO 1133, condition L, 230°C, 2.16 kg), such that the degradation ratio MFI1/MFI2 is within a well-defined range and such that the second melt flow index MFI2 is in the range from 50 dg/min to 300 dg/min. Further, the present invention relates to nonwovens, composites and laminates comprising said bicomponent fibers. The present invention also relates to a process for making such bicomponent fibers, nonwovens, composites and laminates.
D01F 8/06 - Filaments, ou similaires, faits par l’homme, conjugués, c.-à-d. à plusieurs composantsLeur fabrication à partir de polymères synthétiques avec au moins une polyoléfine comme constituant
D01D 5/30 - Filaments conjuguésEnsembles de filage à cet effet
75.
FIBERS AND NONWOVENS WITH INCREASED SURFACE ROUGHNESS
The present invention relates to fibers having an increased surface roughness. Further, the present invention relates to nonwovens, laminates and composites comprising such fibers. Additionally, the present invention relates to a process for producing such fibers, nonwovens, laminates and composites.
D01F 8/06 - Filaments, ou similaires, faits par l’homme, conjugués, c.-à-d. à plusieurs composantsLeur fabrication à partir de polymères synthétiques avec au moins une polyoléfine comme constituant
76.
METHOD TO MITIGATE THE CONSEQUENCES OF AN UNCONFINED OR PARTIALLY CONFINED VAPOR CLOUD EXPLOSION
The present invention concerns a method to mitigate the consequences of an unconfined or partially confined vapor cloud explosion due to the accidental release of a flammable gas in an open area, wherein: • means capable to release a flame acceleration suppression product are dispersed in said area, • a signal is generated by a detector of said flammable gas release, or by an operator, or by an approaching flame or by the explosion itself, or by any combination thereof, • said signal activates the release of the flame acceleration suppression product in said area and in a sufficient amount to transform the flammable cloud into a mixture of flammable product, air and said flame acceleration suppression product to prevent flame accelerations in an unconfined vapor cloud explosion but to let the flammable product burn in case of ignition. In a specific embodiment the release of the flame acceleration suppression product is made by a signal generated by a detector of said flammable gas release or by an operator and before ignition or beginning of an explosion.
The present invention is a process to make a composition comprising at least a monovinylaromatic polymer and at least a dispersed phase of one or more polymers made from renewable resources comprising: a) forming a polymerizable mixture comprising: at least a monomer or a dimer (a1) selected among an hydroxy carboxylic acid, a precursor of said hydroxy carboxylic acid, a cyclic component polymerizable by ring-opening polymerization (ROP) and a mixture of an epoxide and carbon dioxide, dispersed in at least (a2) one monovinylaromatic monomer, optionally a rubber dissolved in (a2) the monovinylaromatic monomer, b) contacting an appropriate catalyst with the polymerizable solution at conditions effective to produce a polymer A1 comprising the repeating units (a1) dispersed in the (a2) monovinylaromatic monomer, c) polymerizing through a radical pathway the solution obtained at step b) optionally in the presence of a free radical initiator, optionally in the presence of chain transfer agents, to obtain a monovinylaromatic polymer A2 comprising a dispersed phase of the polymer A1, d) degassing the product of step c) to separate the optional unpolymerized monomers and comonomers and recovering a composition comprising at least a (A2) monovinylaromatic polymer and at least (A1) wherein, the weight proportion A1/(A2+A1) is up to 50%. In a second embodiment steps b) and c) are made in one step. The polymerizable mixture is contacted with an appropriate catalyst at conditions effective to essentially simultaneously produce a polymer A1 and a monovinylaromatic polymer. (a1) is advantageously a lactide. The monovinylaromatic monomer is advantageously styrene.
C08F 2/44 - Polymérisation en présence d'additifs, p. ex. plastifiants, matières colorantes, charges
C08L 25/00 - Compositions contenant des homopolymères ou des copolymères de composés possédant un ou plusieurs radicaux aliphatiques non saturés, chacun ne contenant qu'une seule liaison double carbone-carbone et l'un au moins étant terminé par un cycle carbocyclique aromatiqueCompositions des dérivés de tels polymères
C08L 67/00 - Compositions contenant des polyesters obtenus par des réactions créant une liaison ester carboxylique dans la chaîne principaleCompositions contenant des dérivés de tels polymères
C08F 283/02 - Composés macromoléculaires obtenus par polymérisation de monomères sur des polymères prévus par la sous-classe sur des polycarbonates ou des polyesters saturés
C08L 51/08 - Compositions contenant des polymères greffés dans lesquels le composant greffé est obtenu par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carboneCompositions contenant des dérivés de tels polymères greffés sur des composés macromoléculaires obtenus autrement que par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone
C08F 295/00 - Composés macromoléculaires obtenus par une polymérisation utilisant successivement des catalyseurs de types différents sans désactivation du polymère intermédiaire
B32B 27/32 - Produits stratifiés composés essentiellement de résine synthétique comprenant des polyoléfines
B29C 41/04 - Coulée par rotation ou par centrifugation, c.-à-d. revêtement de la surface interne d'un moule par rotation du moule
B29C 41/00 - Façonnage par revêtement d'un moule, noyau ou autre support, c.-à-d. par dépôt de la matière à mouler et démoulage de l'objet forméAppareils à cet effet
B29C 41/22 - Fabrication d'objets multicouches ou polychromes
B29C 41/32 - Fabrication d'objets multicouches ou polychromes
The present invention discloses a transfer system between the first and second reactors in a double loop reactor that is equipped to reduce clogging in the transfer lines by providing a regulation mechanism arranged to insure equivalent flushing in each transfer line.
The present invention concerns a heterophasic propylene copolymer of high melt flow for injection molding, which comprise a propylene polymer matrix and a rubber. The heterophasic propylene copolymers of the present invention are characterized by a high viscosity of the rubber phase and a well-defined ratio of the intrinsic viscosities of the rubber phase and the propylene polymer matrix, thus resulting in improved mechanical properties. The present invention further relates to a process for the production of such heterophasic propylene copolymers, their use and articles produced with them.
The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur- containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone;c) contacting the first portion of said oxygen-containing, halogenide- containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
The present invention relates to a process to make light olefins and aromatics, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide- containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins and aromatics.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, optionally at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide- containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
B01J 27/16 - PhosphoreSes composés contenant de l'oxygène
B01J 29/40 - Zéolites aluminosilicates cristallinesLeurs composés isomorphes du type pentasil, p. ex. types ZSM-5, ZSM-8 ou ZSM-11
The invention discloses a metallocene catalysed slurry polymerisation process of ethylene in the presence of a low concentration of scavenger. This allows improving the anti-sheeting of the reactor during the polymerisation process.
C08F 4/52 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides choisis parmi le bore, l'aluminium, le gallium, l'indium, le thallium ou les terres rares
The present invention relates to a process for making a crystalline metallosilicate composition and comprising crystallites having an inner part (the core) and an outer part (the outer layer or shell) such that : the ratio Si/Metal is higher in the outer part than in the inner part, the crystallites have a continuous distribution of metal and silicon over the crystalline cross-section, said process comprising : a) providing an aqueous medium comprising OH- anions and a metal source, b) providing an aqueous medium comprising an inorganic source of silicon and optionally a templating agent, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to partly crystallize the desired metallosilicate, e) cooling down the reaction mixture a)+b)+c) to about room temperature, f) decreasing the pH of the reaction mixture by at least 0.1 preferably by 0.3 to 4, more preferably by 0.5 to 3, g) subjecting the resulting mixture of step f) at conditions effective to continue the crystallization of the desired metallosilicate, h) recovering the desired metallosilicate, wherein at step d) in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is < 0.3, advantageously < 0.2 and preferably 0, the molar ratio OH-/SiO2 is at least 0.3, advantageously from 0.3 to 0.62, preferably from 0.31 to 0.61, more preferably from 0.32 to 0.61, very preferably from 0.33 to 0.6.
The present invention provides a method for preparing a metallosilicate of MFI type, wherein organic templates, seeding techniques, using low aliphatic alcohols miscible with water or homogeneous starting solutions are not required. The present invention relates to a process for making a crystalline metallosilicate with high Si/Metal ratio comprising: a) providing an aqueous medium comprising OH− anions and a metal source, b) providing an aqueous medium comprising an inorganic water insoluble source of silicon, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallize the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is < 0.3, advantageously < 0.2 and preferably 0, the molar ratio OH−/SiO2 is at least 0.3, advantageously from 0.3 to 0.62, preferably from 0.31 to 0.61, more preferably from 0.32 to 0.61, very preferably from 0.33 to 0.6 and there is essentially no template. In another embodiment steps e), f) and g) are inserted before recovering the desired metallosilicate : e) cooling down the reaction mixture a)+b)+c) to about room temperature, f) decreasing the pH of the reaction mixture by at least 0.1 preferably by 0.3 to 4, more preferably by 0.5 to 3, g) subjecting the resulting mixture of step f) at conditions effective to continue the crystallization of the desired metallosilicate.
The present invention relates to a process for making a crystalline metallosilicate composition comprising crystallites having an inner part (the core) and an outer part (the outer layer or shell) such that : the ratio Si/metal is higher in the outer part than in the inner part, the crystallites have a continuous distribution of metal and silicon over the crystalline cross-section, said process comprising : a) providing an aqueous medium comprising OH- anions and a metal source, b) providing an aqueous medium comprising an inorganic source of silicon and optionally a templating agent, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallyze the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is < 0.3, advantageously < 0.2 and preferably 0, the molar ratio OH-/SiO2 is at least 0.3, advantageously from 0.3 to 0.62, preferably from 0.31 to 0.61, more preferably from 0.32 to 0.61, very preferably from 0.33 to 0.6 and the pH of the mixture a)+b)+c), before crystallization, is higher than 13, preferably higher than 13.1, more preferably higher than 13.2, still more preferably higher than 13.3 and most preferred higher than 13.4.
B05D 7/22 - Procédés, autres que le flocage, spécialement adaptés pour appliquer des liquides ou d'autres matériaux fluides, à des surfaces particulières, ou pour appliquer des liquides ou d'autres matériaux fluides particuliers à des surfaces internes, p. ex. à l'intérieur de tubes
B05D 7/16 - Procédés, autres que le flocage, spécialement adaptés pour appliquer des liquides ou d'autres matériaux fluides, à des surfaces particulières, ou pour appliquer des liquides ou d'autres matériaux fluides particuliers à du métal, p. ex. à des carrosseries de voiture en utilisant des laques ou vernis synthétiques
B05D 1/00 - Procédés pour appliquer des liquides ou d'autres matériaux fluides aux surfaces
90.
PROCESS FOR THE THERMAL AND/OR CATALYTIC CONVERSION OF REACTIVE FLUIDS PASSING THROUGH VARIOUS LONGITUDINAL REACTION VOLUMES OF A ROTATING FLUIDIZED BED
The present invention relates to processes for the thermal and/or catalytic conversion of at least two different reactive fluids passing through a rotating fluidized bed comprising solid particles that may be or may contain catalysts and that rotate inside an annular reaction chamber, into which said reactive fluids (A, C) are injected separately and pass through said rotating fluidized bed each in at least one longitudinal reaction volume (VA, VC), which reaction volumes are optionally separated from one another by at least two longitudinal separation volumes (VB1, VB2) where a separation fluid (B) is injected. The present invention also relates to a rotating fluidized bed device that enables a thermal and/or catalytic conversion of at least two different reactive fluids passing through the rotating fluidized bed, and to the use of such a device in cracking processes, dehydrogenation processes or processes for other thermal and/or catalytic conversions of fluids.
B01J 8/36 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" le déplacement des particules dans le lit fluidisé étant essentiellement horizontal
B01J 8/38 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" le lit fluidisé comportant un dispositif rotatif ou étant soumis à une rotation
91.
STERICALLY EMCUMBERED BIDENTATE AND TRIDENTATE NAPHTHOXY-IMINE METALLIC COMPLEXES
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Carpentier, Jean-François
Kirillov, Evgueni
Razavi, Abbas
Abrégé
The present invention discloses post-metallocene complexes based on sterically encumbered bi- and tri-dentate naphthoxy-imine ligands. It also relates to the use of such post-metallocene complexes in the oligomerisation of ethylene to selectively prepare vinyl-end capped linear alpha-olefins.
This invention relates to the field of multilayer articles having reinforced structural properies prepared by rotational moulding wherein the external and internal skin layers are prepared from polyethylene resin and the intermediate layer is prepared from foamed polyethylene.
The present invention relates to a process for the production of a high melt flow propylene homopolymer or random copolymer with low odor and low volatiles content, which is suitable for thin-walled injection molding applications, said process comprising the step of polymerizing propylene and one or more optional comonomers in presence of a Ziegler-Natta catalyst comprising a titanium compound having at least one titanium-halogen bond, and a diether compound as internal electron donor, both supported on a magnesium halide in active form, an organoaluminium compound and an optional external donor.
C08F 4/44 - MétauxHydrures métalliquesComposés organiques de métalLeur utilisation comme précurseurs de catalyseurs choisis parmi les métaux légers, le zinc, le cadmium, le mercure, le cuivre, l'argent, l'or, le bore, le gallium, l'indium, le thallium, les terres rares ou les actinides
94.
BLENDS OF POLAR LOW DENSITY ETHYLENE COPOLYMERS AND POLY(HYDROXY CARBOXYLIC ACID)S
A resin composition comprising at least 0.1% by weight of poly(hydroxy carboxylic acid) and at least 50% by weight of polar low density polyethylene, the pLDPE comprising from 0.5 to 25% by weight of a polar vinyl-containing comonomer.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Carpentier, Jean-François
Kirillov, Evgueni
Razavi, Abbas
Abrégé
The present invention relates to the field of group 4 post-metallocene complexes based on sterically encumbered bis(naphtoxy)pyridine and bis(naphtoxy)thiophene ligands. It also relates to the use of such post-metallocene complexes in the polymerisation of ethylene and alpha-olefins.
C08F 10/00 - Homopolymères ou copolymères d'hydrocarbures aliphatiques non saturés contenant une seule liaison double carbone-carbone
96.
GROUP 3 POST-METALLOCENE COMPLEXES BASED ON BIS(NAPHTHOXY)PYRIDINE AND BIS(NAPHTHOXY)THIOPHENE LIGANDS FOR THE RING-OPENING POLYMERISATION OF POLAR CYCLIC MONOMERS
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Carpentier, Jean-François
Kirillov, Evgueni
Razavi, Abbas
Abrégé
The present invention relates to the use of group 3 post-metallocene complexes based on sterically encumbered bis(naphthoxy)pyridine and bis(naphthoxy)thiophene ligands in the ring-opening polymerisation of polar monomers such as, for examples, lactones, lactides, cyclic carbonates.
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) (France)
Inventeur(s)
Carpentier, Jean-François
Guillaume, Sophie
Helou, Marion
Sarazin, Yann
Miserque, Olivier
Abrégé
This invention relates to the synthesis of polycarbonates prepared from carbonate monomers derived from the biomass in the presence of a system comprising an organometallic transfer agent and alcohol. It also relates to the polymers resulting from these cyclic compounds.
The present invention relates to fibers, particularly to as-spun fibers, having improved properties, in particular improved mechanical properties. In particular, the present invention relates to fibers comprising a metallocene polypropylene having a broader molecular weight distribution. The present invention further relates to nonwovens comprising such fibers and to a process for producing such fibers and nonwovens. The fibers and the nonwoven of the present invention are characterized by improved properties, in particular improved mechanical properties, when compared to the prior art fibers and nonwovens.
D01F 6/06 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir d'homopolymères obtenus par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone à partir des polyoléfines à partir de polypropylène
D01F 6/30 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir de copolymères obtenus par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone comportant des oléfines comme constituant majeur
D01F 8/06 - Filaments, ou similaires, faits par l’homme, conjugués, c.-à-d. à plusieurs composantsLeur fabrication à partir de polymères synthétiques avec au moins une polyoléfine comme constituant
B32B 5/02 - Produits stratifiés caractérisés par l'hétérogénéité ou la structure physique d'une des couches caractérisés par les caractéristiques de structure d'une couche comprenant des fibres ou des filaments
B32B 27/32 - Produits stratifiés composés essentiellement de résine synthétique comprenant des polyoléfines
D04H 3/16 - Non-tissés formés uniquement ou principalement de fils ou de matériaux filamenteux similaires de bonne longueur caractérisés par la méthode de renforcement ou de consolidation avec liages produits par soudage entre fils thermoplastiques ou filaments avec liages entre filaments thermoplastiques produits en relation avec la formation des filaments, p. ex. suivant immédiatement l'extrusion
99.
FIBERS AND NONWOVENS WITH IMPROVED MECHANICAL AND BONDING PROPERTIES
The present invention relates to fibers, particularly to as-spun fibers, having improved properties, in particular improved bonding performance and mechanical properties. In particular, the present invention relates to fibers comprising a metallocene random copolymer of propylene and one or more comonomers, said metallocene random copolymer having a broader molecular weight distribution. The present invention further relates to nonwovens comprising such fibers and to a process for producing such fibers and nonwovens. The fibers and the nonwovens of the present invention are characterized by improved properties, in particular improved bonding performance and mechanical properties, when compared to the prior art fibers and nonwovens.
D01F 6/06 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir d'homopolymères obtenus par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone à partir des polyoléfines à partir de polypropylène
D01F 6/30 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir de copolymères obtenus par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone comportant des oléfines comme constituant majeur
D01F 8/06 - Filaments, ou similaires, faits par l’homme, conjugués, c.-à-d. à plusieurs composantsLeur fabrication à partir de polymères synthétiques avec au moins une polyoléfine comme constituant
B32B 5/02 - Produits stratifiés caractérisés par l'hétérogénéité ou la structure physique d'une des couches caractérisés par les caractéristiques de structure d'une couche comprenant des fibres ou des filaments
B32B 27/32 - Produits stratifiés composés essentiellement de résine synthétique comprenant des polyoléfines
D04H 3/16 - Non-tissés formés uniquement ou principalement de fils ou de matériaux filamenteux similaires de bonne longueur caractérisés par la méthode de renforcement ou de consolidation avec liages produits par soudage entre fils thermoplastiques ou filaments avec liages entre filaments thermoplastiques produits en relation avec la formation des filaments, p. ex. suivant immédiatement l'extrusion
100.
FIBRES AND NONWOVEN PREPARED FROM POLYPROPYLENE HAVING A LARGE DISPERSITY INDEX
The present invention relates to a process for the production of fibres and filaments with polypropylene having a broad polydispersity index. The present invention also relates to high elongation nonwoven prepared from such fibres and filaments. It further relates to films and laminates prepared from high elongation nonwoven.
D01F 6/06 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir d'homopolymères obtenus par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone à partir des polyoléfines à partir de polypropylène
D01F 8/06 - Filaments, ou similaires, faits par l’homme, conjugués, c.-à-d. à plusieurs composantsLeur fabrication à partir de polymères synthétiques avec au moins une polyoléfine comme constituant
D01F 6/30 - Filaments, ou similaires, faits par l’homme, à un seul composant, formés de polymères synthétiquesLeur fabrication à partir de copolymères obtenus par des réactions faisant intervenir uniquement des liaisons non saturées carbone-carbone comportant des oléfines comme constituant majeur
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