Methods for producing or regenerating an iodinated resin are presented. The methods include converting iodide residues on a surface of and in pores of an iodide loaded anion exchange resin to iodine and iodine intermediates using a source of active halogen to form an iodinated resin having iodine and iodine intermediate residues on the surface of and in the pores of the iodinated resin. The iodinated resins show reduced and stable levels of iodine elution compared to conventional iodinated anion exchange resins and may utilizes less iodine raw materials during the manufacturing process. The iodinated resin can also act as an end-of life indicator in a water purification system that incorporates the iodinated resin to reduce microbial, including bacterial and viral, contamination in drinking water sources. Methods and systems for purifying water are also presented.
Methods for producing or regenerating an iodinated anion exchange resin are presented. The methods include treating an iodide loaded anionic resin with an aqueous solution comprising an in situ formed I2 to produce the iodinated resin. The iodinated resins show reduced and stable levels of iodine elution compared to resins produced by conventional methods. Methods and systems for purifying water are also presented.
Methods for preparing a chitosan-based material for use in a halogen water treatment system are described. Treating chitosan or chitin with a compound selected from the group consisting of an acid, a base, a mild halogenating solution and combinations thereof provides a chitosan-based material that displays reduced leakage of halide ion. Water treatment systems and methods for treating water comprising at least one contaminant are also described.
C23F 11/00 - Inhibition de la corrosion de matériaux métalliques par application d'inhibiteurs sur la surface menacée par la corrosion ou par addition d'inhibiteurs à l'agent corrosif
The water treatment systems may generally comprise multiple halogens and chitosan or derivatives thereof as well as methods of making and using the same. A water treatment system to provide potable water may generally comprise an inlet in fluid communication with an outlet, a halogen release system intermediate the inlet and the outlet, and a halogenated chitosan intermediate the halogen release system and the outlet. The system may comprise a scavenger barrier intermediate the halogenated chitosan and the outlet. The halogen release system may comprise a first halogen having a first oxidizing potential. The halogenated chitosan may comprise a second halogen having a second oxidizing potential. The second oxidizing potential is greater than the first oxidizing potential.
B01D 15/04 - Procédés de séparation comportant le traitement de liquides par des adsorbants ou des absorbants solidesAppareillages pour ces procédés par des substances échangeuses d'ions comme adsorbants
C02F 1/42 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par échange d'ions
5.
FILTER COMPRISING A HALOGEN RELEASE SYSTEM AND CHITOSAN
A filter to provide potable water may generally comprise an inlet in fluid communication with an outlet, a halogen release system intermediate the inlet and the outlet, a filter material comprising chitosan or a derivative thereof intermediate the halogen release system and the outlet, and a scavenger barrier intermediate the filter material and the outlet. The filter material may comprise a chitosan-halogen complex. The filter material is capable of regeneration during periods of stagnation. The filter may have a Log reduction value for viruses of at least 4 and a Log reduction value for bacteria of at least 6.
B01D 35/00 - Dispositifs filtrants ayant des particularités non couvertes spécifiquement par les groupes , applications non couvertes spécifiquement par les groupes Dispositifs auxiliaires pour la filtrationStructure du carter de filtre
6.
Filter comprising a halogen release system and chitosan
A filter to provide potable water may generally comprise an inlet in fluid communication with an outlet, a halogen release system intermediate the inlet and the outlet, a filter material comprising chitosan or a derivative thereof intermediate the halogen release system and the outlet, and a scavenger barrier intermediate the filter material and the outlet. The filter material may comprise a chitosan-halogen complex. The filter material is capable of regeneration during periods of stagnation. The filter may have a Log reduction value for viruses of at least 4 and a Log reduction value for bacteria of at least 6.
C02F 1/28 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par absorption ou adsorption
C02F 1/68 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par addition de substances spécifiées, pour améliorer l'eau potable, p. ex. par addition d'oligo-éléments
C02F 1/76 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout par oxydation au moyen d'halogènes ou de composés halogénés
C02F 1/00 - Traitement de l'eau, des eaux résiduaires ou des eaux d'égout
7.
WATER TREATMENT SYSTEMS WITH DUAL PURPOSE ION EXCHANGE RESIN
A low pressure point-of-use water treatment system may generally comprise at least one inlet port (20) in fluid communication with at least one outlet port (30) to define a fluid pathway therethrough (40); an iodinated resin (50) intermediate the at least one inlet port (20) and the at least one outlet port (30), wherein the iodinated resin (50) transfers iodine into the fluid pathway (40) for a volume of water corresponding to an effective life of the iodinated resin (50); and an ion exchange resin (60) intermediate the iodinated resin (50) and the at least one outlet port, wherein the ion exchange resin removes at least a portion of the iodine transferred by the iodinated resin into the fluid pathway for a volume of water corresponding to a breakthrough point as measured by iodide leakage; and wherein the ion exchange resin inactivates contaminants in the fluid pathway as the iodinated resin nears the end of its effective life.
A filter (10) having a flow path for a filtrate may generally comprise an iodinated resin (20), wherein the iodinated resin releases iodine into the filtrate, and an ion exchange column downstream from the iodinated resin (30), the ion exchange column comprising at least one ion exchange resin (40), wherein the at least one ion exchange resin progressively changes color as iodine is absorbed from the filtrate, and an indicator (50) to indicate when the amount of iodine in the iodinated resin reaches a predetermined lower threshold. Other embodiments include methods of using embodiments of the filter described herein.
A water treatment system may generally comprise a generally cylindrical halogenated resin bed comprising an empty bed contact time greater than 1 second, an aspect ratio less than 0.8, and a fluid velocity less than 0.5 cm/s, wherein the aspect ratio is the ratio of the length of the halogenated resin bed to the diameter of the halogenated resin bed; and wherein the fluid velocity is the quotient of the volumetric flow rate of the water treatment system and the cross-sectional area of the halogenated resin bed; and wherein the halogenated resin bed improves the removal of contaminates relative to a corresponding water treatment system having an aspect ratio greater than 0.8.
B01D 15/04 - Procédés de séparation comportant le traitement de liquides par des adsorbants ou des absorbants solidesAppareillages pour ces procédés par des substances échangeuses d'ions comme adsorbants
B01D 15/00 - Procédés de séparation comportant le traitement de liquides par des adsorbants ou des absorbants solidesAppareillages pour ces procédés
B01D 29/00 - Filtres à éléments filtrants stationnaires pendant la filtration, p. ex. filtres à aspiration ou à pression, non couverts par les groupes Leurs éléments filtrants
B01D 35/00 - Dispositifs filtrants ayant des particularités non couvertes spécifiquement par les groupes , applications non couvertes spécifiquement par les groupes Dispositifs auxiliaires pour la filtrationStructure du carter de filtre
A water treatment system comprises a generally cylindrical halogenated resin bed comprising an empty bed contact time greater than 1 second, an aspect ratio less than 0.8, and a fluid velocity less than 0.5 cm/s, wherein the aspect ratio is the ratio of the length of the halogenated resin bed to the diameter of the halogenated resin bed; and wherein the fluid velocity is the quotient of the volumetric flow rate of the water treatment system and the cross-sectional area of the halogenated resin bed; and wherein the halogenated resin bed improves the removal of the contaminates relative to a corresponding water treatment system having an aspect ratio greater than 0.8.
A multi-barrier filter comprising a halogenated resin capable of removing contaminants from a fluid, and at least one contaminant sorbent medium downstream of the halogenated resin capable of adsorbing or absorbing contaminants. The at least one contaminant sorbent medium is preferably 'halogen-neutral' to maximize the antimicrobial effectiveness of the halogen in the fluid. The filter may comprise at least one 'halogen- scavenger' barrier downstream of the halogen-neutral barrier. Because of the efficiency of the filter, a low-residual halogenated resin, such as, for example, low residual iodinated resin, may be used.
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