DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Fuxiang
Xin, Xueshang
Abrégé
The invention belongs to the technical field of photocatalytic materials. Provided are perovskite tantalum-nitrogen co-doped strontium titanate, and a preparation method therefor and the use thereof. Titanium isopropoxide and tantalum pentachloride are dissolved in methyl alcohol, ethylene glycol, citric acid and strontium carbonate are then added thereto, and after polymerization, organic carbon is removed by means of roasting with air, thereby obtaining tantalum-doped strontium titanate; same is then mixed with a magnesium powder, and the resulting mixture is nitrided in an ammonia gas flow atmosphere; and the resulting reaction product is subjected to acid pickling, water washing and drying, thereby obtaining perovskite tantalum-nitrogen co-doped strontium titanate. Titanium-oxygen bonds are weakened by means of pre-doping with tantalum, and the spatial distribution of a high-content nitrogen dopant in strontium titanate is then achieved by means of a magnesium-powder-assisted nitriding method; therefore, the synthesized catalyst has a wider light absorption range, and has significant photocatalytic activity in both hydrogen production by means of photocatalytic water splitting and oxygen production by means of water splitting.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ye, Mingliang
Li, Kejia
Abrégé
Disclosed in the present invention is a method for detecting a protein having changes in an energy state, and affinity of a ligand to a protein. Specifically, after the energy state of a protein changes, its tolerance to proteolytic cleavage destruction changes. The structure of the protein in a low-energy state is also destroyed under a non-denaturation condition by using a large amount of enzymes, and small peptide fragments, which have molecular weight of less than 5 KDa and can be directly used for bottom-top mass spectrometry analysis, are directly generated. The method has extremely high sensitivity. Quantitative proteomics is used to find enzyme cleavage differential peptide fragments, and proteins to which the differential peptide fragments belong and the positions in the proteins are analyzed, so that a protein having changes in an energy state, and a change region can be determined in the whole proteome range. If the energy state of the protein changes due to addition of a ligand, the method can determine a binding protein and a binding region of the ligand; and the output of a quantitative result on the peptide fragment level further enables the method to determine the local affinity of binding of the ligand to the protein.
G01N 33/68 - Analyse chimique de matériau biologique, p.ex. de sang ou d'urine; Test par des méthodes faisant intervenir la formation de liaisons biospécifiques par ligands; Test immunologique faisant intervenir des protéines, peptides ou amino-acides
3.
METHOD FOR PRODUCING BENZENE, TOLUENE AND P-XYLENE BY COUPLING CONVERSION OF NAPHTHA AND CARBON DIOXIDE
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liu, Zhongmin
Yu, Zhengxi
Yang, Yue
Abrégé
A method for preparing a modified molecular sieve catalyst and a method for producing benzene, toluene and p-xylene by coupling conversion of naphtha and CO2 are provided. Preparing a modified molecular sieve catalyst includes subjecting a molecular sieve to metal modification by using a high temperature hydrothermal method, which includes: (1) preparing a soluble metal salt aqueous solution; (2) placing a zeolite molecular sieve to be metal-modified in the soluble metal salt aqueous solution, and impregnating the same at a temperature of 60-100° C.; and (3) draining the molecular sieve, followed by drying and calcination. Producing benzene, toluene and p-xylene by coupling conversion of naphtha and CO2 includes: (a) preparing a modified molecular sieve catalyst; and (b) enabling a raw material containing naphtha and CO2 to contact with the modified molecular sieve catalyst in a reactor for a reaction to produce benzene, toluene and p-xylene.
C07C 6/08 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant un nombre différent d'atomes de carbone par des réactions de redistribution par conversion d'une liaison carbone-carbone saturée
4.
MOLECULAR SIEVE DNL, PREPARATION METHOD THEREFOR, AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Guo, Peng
Nie, Chenyang
Ma, Chao
Yan, Nana
Liu, Xiaona
Liu, Zhongmin
Abrégé
3423222O, mixing same, and crystallizing at 80-240℃ for 1-60 days, to obtain a molecular sieve DNL; wherein a = 0.1-10.0, b = 0-6.0, c = 0-100.0, q = 0-1.2, m = 0-100, and n = 5-1000; and the organic template agent is selected from 1,5-(N-triethyl) pentane diamine hydroxide, a pyridine compound, or a compound of the structure of formula I. The molecular sieve having a novel framework structure prepared in the present application can be used for synthesizing a SAPO framework structure, is beneficial for subsequent use in the field of catalysis, and can be used in a water adsorption material; and the synthesis process is simple and highly operable.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Guo, Jianping
Guan, Yeqin
Chen, Ping
Abrégé
The present application discloses a method for reversible hydrogen storage in a light-driven metal hydride. The method comprises the following steps: (1) introducing inactive gas into a closed and transparent reactor containing metal hydride powder; (2) applying light to the reactor for dehydrogenation to obtain a dehydrogenation product; and (3) hydrogenating the dehydrogenation product in a hydrogen atmosphere to obtain a metal hydride, wherein the metal hydride is selected from at least one of an alkali metal hydride, an alkaline earth metal hydride, and a rare earth metal hydride, and the valence of the hydrogen element in the metal hydride is -1. In the present application, the metal hydride can be directly driven by light energy and has high reaction activity. Reversible dehydrogenation circulation can be achieved at normal temperature by using specific hydride. The process is simple and suitable for scale production.
C01B 3/00 - Hydrogène; Mélanges gazeux contenant de l'hydrogène; Séparation de l'hydrogène à partir de mélanges en contenant; Purification de l'hydrogène
C01B 6/04 - Hydrures des métaux alcalins, des métaux alcalino-terreux, du béryllium ou du magnésium; Leurs complexes d'addition
C01B 6/02 - Hydrures des éléments de transition; Leurs complexes d'addition
6.
CATALYST FOR PREPARING HIGHER ALIPHATIC ALCOHOL FROM SYNTHESIS GAS, AND PREPARATION METHOD THEREFOR AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Hu, Jingting
Yu, Liang
Abrégé
Disclosed in the present invention are a catalyst for preparing a higher aliphatic alcohol from synthesis gas, and a preparation method therefor and the use thereof, which mainly solve the problems of an existing catalyst system having a low active site concentration and slow diffusion of reactant and product molecules, and achieve both high activity and high selectivity of a higher aliphatic alcohol. In the present invention, by means of a template method, a small-size and multi-scale porous molybdenum sulfide material grows on a proper template; and the material has rich edge sulfur vacancies and is used for preparing a high aliphatic alcohol from synthesis gas after alkali metal modification. The catalyst for preparing a high aliphatic alcohol from synthesis gas provided in the present invention has the characteristics of a high carbon monoxide conversion rate, high selectivity of a higher aliphatic alcohol, good stability, etc., and has very good industrial use prospects and high commercial values.
C07C 29/153 - Préparation de composés comportant des groupes hydroxyle ou O-métal liés à un atome de carbone ne faisant pas partie d'un cycle aromatique à six chaînons par réduction exclusivement des oxydes de carbone avec de l'hydrogène ou des gaz contenant de l'hydrogène caractérisée par le catalyseur utilisé
7.
ALKALINE NEGATIVE ELECTROLYTE AND ALKALINE ZINC-IRON FLOW BATTERY ASSEMBLED BY SAME
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Xianfeng
Xu, Pengcheng
Yuan, Zhizhang
Abrégé
An alkaline negative electrolyte and alkaline zinc-iron flow battery assembled by same are provided. The alkaline negative electrolyte includes zinc ions, a complexing agent, and alkali; the complexing agent is at least one selected from the group consisting of ethylenediaminetetraacetic acid, ethylene glycol diethyl ether diamine tetraacetic acid, cyclohexane tetraacetic acid, and ethylenediamine tetrapropionic acid; a molar ratio of the zinc ions to the complexing agent is 1:1; and a molar ratio of the complexing agent to the alkali is 1:(3-4). The zinc ions in the negative electrolyte are in form of a complex state, which is used as the negative electrolyte to assemble and obtain the alkaline zinc-iron flow battery, solves the problem of electrolyte migration in alkaline zinc-iron flow battery and improves the cycling stability of the battery; moreover, it improves the low-temperature performance of the battery, and broadens the operating temperature range of alkaline zinc-iron flow battery.
H01M 8/04186 - Dispositions pour la commande des paramètres des réactifs, p.ex. de la pression ou de la concentration des réactifs chargés en liquide ou en électrolyte
H01M 8/18 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Éléments à combustible; Leur fabrication Éléments à combustible à régénération, p.ex. batteries à flux REDOX ou éléments à combustible secondaires
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liu, Zhongmin
Yu, Zhengxi
Yang, Yue
Abrégé
A method for preparing p-xylene is provided. Raw materials containing methanol, naphtha and CO2 are introduced into a reactor filled with a catalyst for a reaction to produce p-xylene. By adding the methanol, the product distribution is adjusted, and the selectivity of p-xylene is obviously improved. In addition, components containing benzene and toluene in aromatic hydrocarbon products are returned to a reaction system and co-fed with the raw materials for a reaction to produce p-xylene, so that cyclic utilization of the raw materials is achieved, and the method has extremely high economic benefits. The method has a simple process and high feasibility, can greatly improve the selectivity and yield of p-xylene, has an important application value, and provides a new way for large-scale utilization of CO2.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Zhu, Peixin
Liu, Yanting
Gao, Hehua
Abrégé
Disclosed in the present invention are a system and method for hydrogen production by water electrolysis applicable to a floating offshore wind turbine. The system is installed on the foundation of a floating offshore wind turbine, and the electric energy generated by the floating offshore wind turbine is utilized on-site to perform hydrogen production by seawater electrolysis. The system comprises an alkaline electrolytic cell unit, a hydrogen separation and cooling unit, a hydrogen purification and cooling unit, an oxygen separation and cooling unit, an alkaline solution filtration and circulation unit, an alkaline solution cooling unit, a negative-pressure seawater desalination unit, a raw freshwater storage and supply unit, an expansion tank unit, and a circulating freshwater transportation unit. According to the present invention, closed circulating freshwater is used as a cooling medium for the cooling units in hydrogen production by alkaline water electrolysis, absorbed heat is used as a heat source for the negative-pressure seawater desalination unit to perform seawater desalination, and a closed freshwater circulation is formed to perform heat circulation and transfer, thereby achieving the self-sufficiency of freshwater. The present invention is applicable to a distributed seawater hydrogen production scenario of the floating offshore wind turbine, and a wind-power-hydrogen-freshwater one-stop device system is formed, thus accelerating the development of offshore green hydrogen production technology.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Zhu, Peixin
Liu, Yanting
Gao, Hehua
Abrégé
Disclosed in the present invention is a system and method for coupling water electrolysis for hydrogen production with seawater desalination. Functional modules for coupling water electrolysis for hydrogen production with seawater desalination mainly comprise an alkaline electrolyzer module, an oxygen separation module, a hydrogen separation module, an alkali liquor filtering and circulation module, a negative-pressure seawater desalination module, a fresh water supply module and a hydrogen purification module. The present invention directly uses an alkali liquor needing to be cooled to heat up seawater in a negative pressure environment, thus not only cooling the alkali liquor, but also utilizing the heat dissipated during alkali liquor cooling for low-temperature seawater desalination; and the qualified fresh water is used as a raw material for water electrolysis to be supplemented to the alkaline electrolyzer module. The present invention replaces an alkali liquor cooler and an auxiliary cooling water system with the negative-pressure seawater desalination module, thus not only reducing the energy consumption for water electrolysis for hydrogen production, but also relieving dependence of water electrolysis for hydrogen production on fresh water resources. In addition, the present invention not only expands use scenarios of alkaline water electrolysis for hydrogen production, but also facilitates popularization and application of the offshore green hydrogen preparation technology, thus having large application prospects.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Liu, Yanting
Bo, Xin
Shu, Yunmao
Abrégé
An efficient oxyhydrogen generation device for medical care has a housing, an upper cover and a bottom cover which form a main frame. The housing is composed of a front part and a rear part, the bottom cover being fastened at the bottom of the housing to form a space for accommodating an electrolytic cell, a water supply tank, a water supply tank upper cover and a secondary water tank. The upper cover is fastened on the upper part of the housing and is provided with an atomized gas circulation part, a supply part for supplying water to the water supply tank, and a control panel for controlling the operation of an electrolyzing water hydrogen-oxygen generator. The oxyhydrogen generated by electrolysis sequentially enters the water supply tank and the secondary water tank by means of a gas guide plate and is cleaned. discharged from a gas circulation part.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Guangyuan
Li, Lu
Jiang, Min
Wang, Rui
Abrégé
A preparation method of a polyester is provided. The method includes the following steps: allowing a raw material including a diacid and a diol to contact a monoclinic nano-TiO2 (namely, TiO2(B)) catalyst, and conducting an esterification reaction and a polycondensation reaction sequentially to obtain the polyester. The method can efficiently catalyze the synthesis of the polyester and avoid from yellowing of the polyester. Meanwhile, nano-TiO2(B) is polymerized in situ in the polyester, such that a structure of nano-TiO2(B) can adjust the structure and properties of a polyester matrix and effectively improve the mechanical, thermal, and barrier properties of the polyester.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Huang, Shengjun
Zhang, Dazhi
Ding, Hui
Zou, Mingming
Abrégé
222 consumption of the reaction can be effectively reduced. There is no need to construct two parallel devices of "benzene-cyclohexene-cyclohexanol-adipic acid" and "cyclohexane-KA oil-adipic acid" to realize the use of cyclohexane in the production process of adipic acid. The synthetic route is mild in reaction conditions and suitable for continuous and stable large-scale production.
C07C 35/08 - Composés comportant au moins un groupe hydroxyle ou O-métal lié à un atome de carbone d'un cycle autre qu'un cycle aromatique à six chaînons monocycliques contenant des cycles à six chaînons
C07C 29/149 - Préparation de composés comportant des groupes hydroxyle ou O-métal liés à un atome de carbone ne faisant pas partie d'un cycle aromatique à six chaînons par réduction d'un groupe fonctionnel contenant de l'oxygène de groupes contenant C=O, p.ex. —COOH d'acides carboxyliques ou de leurs dérivés avec de l'hydrogène ou des gaz contenant de l'hydrogène
C07C 29/04 - Préparation de composés comportant des groupes hydroxyle ou O-métal liés à un atome de carbone ne faisant pas partie d'un cycle aromatique à six chaînons par addition de groupes hydroxyle à des liaisons carbone-carbone non saturées, p.ex. à l'aide de H2O2 par hydratation de liaisons doubles carbone-carbone
C07C 51/31 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par oxydation de composés cycliques avec ouverture du cycle
14.
INTEGRAL NICKEL-IRON PHOSPHIDE POROUS ELECTRODE AND PREPARATION METHOD THEREFOR
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Shu, Yunmao
Liu, Yanting
Bo, Xin
Gao, Hehua
Abrégé
The present invention relates to the field of electrochemical electrode preparation, and in particular relates to an integral metal phosphide porous electrode. The integral metal phosphide porous electrode comprises a matrix material and a quantitative phosphating synthesis method, wherein the matrix material is nickel, iron, an intermetallic compound thereof and red phosphorus, and is polycrystalline or multiphase. A high-activity and high-stability integrated nickel-iron phosphide porous electrode is prepared by combining a phosphating reaction between a metal and red phosphorus and a space pore-forming particle method. Compared with a traditional load-type integral electrode, the integral electrode of the present invention has the advantages of a hierarchical porous microstructure, a controllable height of the microscopic pore structure and a controllable target phosphating product, thereby showing better electrocatalytic performance. Specifically, the initial potential of an electrolytic water oxygen evolution reaction is significantly reduced, overpotential under large current conditions is significantly reduced, and stability under a large current is greatly improved.
C25B 11/042 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par le matériau Électrodes à base d’un seul matériau
B22F 3/11 - Fabrication de pièces ou d'objets poreux
C25B 11/031 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par la configuration ou la forme perforées ou foraminées Électrodes poreuses
15.
FUEL CELL ELECTRODE CATALYTIC LAYER AND MEMBRANE ELECTRODE COMPRISING SAME
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Shao, Zhigang
Liu, Xinyi
Song, Wei
Abrégé
The present invention relates to the technical field of fuel cells. Disclosed are a fuel cell electrode catalytic layer and a membrane electrode comprising same. The fuel cell electrode catalytic layer is formed by the mutual bonding and accumulation of resin particles the surfaces of which are coated with catalyst particles, and staggered pore channel structures are arranged between the resin particles, so that the transport capability of a reaction material in the catalytic layer is improved, and a catalyst covering the outer layer of a resin has a relatively high utilization rate. The present invention also relates to a preparation method for the fuel cell electrode catalytic layer, comprising: first, under a heating condition by means of an electrostatic effect, adsorbing and bonding, to the surface of a membrane, powder prepared from the catalyst and the resin, and further curing the powder by means of hot pressing to form a stable catalytic layer.
H01M 4/86 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Électrodes Électrodes inertes ayant une activité catalytique, p.ex. pour piles à combustible
H01M 4/90 - Emploi de matériau catalytique spécifié
H01M 8/1004 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Éléments à combustible; Leur fabrication Éléments à combustible avec électrolytes solides caractérisés par les ensembles membrane-électrodes [MEA]
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Huang, Shengjun
Zhang, Dazhi
Ding, Hui
Jiao, Yutong
Abrégé
222 consumption of the reaction can be effectively reduced. The synthetic route is mild in reaction conditions and suitable for continuous and stable large-scale production.
C07C 69/34 - Esters d'acides acycliques polycarboxyliques saturés dont un groupe carboxyle estérifié est lié à un atome de carbone acyclique
C07C 67/04 - Préparation d'esters d'acides carboxyliques par réaction d'acides carboxyliques ou d'anhydrides symétriques sur des liaisons carbone-carbone non saturées
C07C 69/14 - Esters d'acide acétique de composés monohydroxylés
17.
NAPHTHALENE-TYPE COMPOUND AND PREPARATION METHOD THEREFOR AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Zhangkun
Li, Xianfeng
Zhao, Ziming
Abrégé
Disclosed in the present invention are a naphthalene-type compound, and a preparation method therefor and a use thereof. The naphthalene-type compound has a molecular structure substituted with polyhydroxyl, polybenzylamine, and quaternary ammonium or multiple quaternary ammonium functional groups, and compared with a raw material, the naphthalene-type compound has greatly improved water solubility in an acidic aqueous solution. An electrochemical reaction has low raw material costs and a high reaction yield, is carried out under a normal temperature and pressure condition without adding additional catalysts, and is carried out under air conditions without inert gas protection.
H01M 8/18 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Éléments à combustible; Leur fabrication Éléments à combustible à régénération, p.ex. batteries à flux REDOX ou éléments à combustible secondaires
H01M 4/86 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Électrodes Électrodes inertes ayant une activité catalytique, p.ex. pour piles à combustible
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Huang, Jiahui
Su, Xin
Wang, Huan
Wang, Changyun
Zhao, Chaoyue
Abrégé
A process for producing polyphenylene oxide by using a tubular reactor, relating to the technical field of polymer production and reactor design. The tubular reactor mainly comprises a liquid-phase mixer (5), a reactor main body (1), and a gas-liquid separator (8) that are sequentially connected in series. An outlet of the liquid-phase mixer (5) is connected to the bottom side wall of the reactor main body (1). A gas inlet (6) is connected to the bottom of the reactor main body (1). A gas distributor (7) is disposed between the gas inlet (6) and the reactor main body (1). An inner component (2) is disposed in the reactor main body (1). A top outlet of the reactor main body (1) is connected to the gas-liquid separator (8). Oxidative coupling is performed on 2,6-dimethylphenol by using the tubular reactor to prepare the polyphenylene oxide, and the obtained reaction mixed solution undergoes separation to obtain a polyphenylene oxide product. The problems of a large back mixing degree, wide product molecular weight distribution, difficulty in implementing molecular weight regulation, and the like in batch stirred tank reactors are resolved. Continuous production operations of reaction and a separation process of a catalyst, a solvent, and a product are also implemented, facilitating industrial production.
C08G 65/44 - Composés macromoléculaires obtenus par des réactions créant une liaison éther dans la chaîne principale de la macromolécule à partir de composés hydroxylés ou de leurs dérivés métalliques dérivés des phénols par oxydation des phénols
B01J 19/18 - Réacteurs fixes avec éléments internes mobiles
B01J 19/00 - Procédés chimiques, physiques ou physico-chimiques en général; Appareils appropriés
19.
A SYSTEM AND METHOD FOR REMOVING ACIDIC GAS FROM A POST COMBUSTION PROCESS STREAM
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Khalit, Siti Hajar Bt
Quek, Ven Chian
Rostani, Khairul B
Cao, Yiming
Kang, Guodong
Abrégé
A method for removing acidic gases from a post combustion process stream comprises the steps of: receiving the post combustion process stream (25) into hollow fibres of at least one MBC cell (10), each hollow fibre gas permeable, liquid impermeable; passing a lean solvent in contact with an external surface of the hollow fibres; exchanging the acidic gases into the solvent through the hollow fibres; venting an acidic gas lean stream (45); and exiting an acidic gas rich solvent.
B01D 53/14 - SÉPARATION Épuration chimique ou biologique des gaz résiduaires, p.ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols par absorption
B01D 53/96 - Régénération, réactivation ou recyclage des réactifs
B01D 53/22 - SÉPARATION Épuration chimique ou biologique des gaz résiduaires, p.ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols par diffusion
B01D 53/18 - Unités d'absorption; Distributeurs de liquides
F23J 15/04 - Aménagement des dispositifs de traitement de fumées ou de vapeurs des purificateurs, p.ex. pour enlever les matériaux nocifs utilisant des fluides de lavage
20.
PROCESS FOR PREPARING EPICHLOROHYDRIN BY DIRECTLY OXIDIZING CHLOROPROPENE BY USING LIQUID-SOLID CIRCULATING FLUIDIZED BED REACTOR
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Huang, Jiahui
Liu, Yingchun
Su, Xin
He, Guse
Zhang, Hengyun
He, Peng
Wang, Changyun
Li, Xinju
Jia, Yuhua
Long, Huayun
Abrégé
The present invention belongs to the technical field of epichlorohydrin production, and disclosed is a process for preparing epichlorohydrin by directly oxidizing chloropropene by using a liquid-solid circulating fluidized bed reactor. In the present invention, a liquid-solid circulating fluidized bed reactor is used for preparing epichlorohydrin by directly oxidizing chloropropene with hydrogen peroxide. The liquid-solid circulating fluidized bed reactor mainly comprises a reactor, a liquid-solid separator, a liquid extractor, a spent inclined tube, a regenerator, a catalyst bin, a regeneration inclined tube, etc. In the process, the liquid-solid circulating fluidized bed reactor is used to replace a traditional stirred tank reactor, such that the heat and mass transfer rate between liquid and solid phases is enhanced in the reactor, the back mixing degree in the reactor is reduced, the reaction rate is greatly increased, the reaction time is shortened, side reactions are inhibited, and the effective utilization rate of hydrogen peroxide and the selectivity of epichlorohydrin are increased. The present invention provides a brand-new process for the production of epichlorohydrin, and is beneficial for reducing the production cost of epichlorohydrin.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
C07D 303/08 - Composés contenant des cycles oxirane avec des radicaux hydrocarbonés substitués par des atomes d'halogènes, des radicaux nitro ou des radicaux nitroso
B01J 8/28 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération superposés
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées
21.
BISMUTH-COPPER SINGLE-ATOM ALLOY MATERIAL, AND PREPARATION METHOD THEREFOR AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Fuxiang
Cao, Yucheng
Abrégé
A bismuth-copper single-atom alloy material, and a preparation method therefor and a use thereof. A catalyst comprises copper nanoparticles and bismuth atoms; the copper nanoparticles are of a polycrystalline structure; the bismuth atoms are dispersed in the copper nanoparticles in the form of single atoms. The catalyst is prepared by means of thermal decomposition of a metal complex and a subsequent in-situ electroreduction method. The preparation method for the bismuth-copper single-atom alloy is simple, the content of single-atom bismuth is adjustable, and the content of single-atom bismuth can be controlled by changing a reaction condition. By loading bismuth atoms isolated from each other on copper nanoparticles and adjusting the electronic state of copper atoms, the capability of the bismuth-copper single-atom alloy to catalyze carbon-carbon coupling is improved, thereby obtaining high selectivity for electrocatalytic reduction of carbon dioxide to multi-carbon products, and providing a new way for efficient conversion of carbon dioxide.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Hao, Jinkai
Shao, Zhigang
Zhang, Hongjie
Yu, Hongmei
Abrégé
The present invention belongs to the field of water electrolysis for hydrogen production. Disclosed are a PEM water electrolysis bipolar plate and a manufacturing method. The present invention uses a stainless steel plate as a substrate. The substrate is provided with through hole structures which have the same structure as flow channel ridges and positions of which match positions of the flow channel ridges. The upper surface and the lower surface of the substrate are both provided with a titanium layer, and the titanium layers fill the through hole structures so as to enable the upper titanium layer and the lower titanium layer to be connected. A spherical dehydrogenated titanium powder layer and a functional coating are successively provided on the surface of each of the titanium layers. The functional coatings form the flow channel ridges, flow disturbing pillars and a hydrogen-oxygen frame of the bipolar plate. The pore diameter of the spherical dehydrogenated titanium powder layers is 100 nm to 10 μm; and the titanium layers, the spherical dehydrogenated titanium powder layers and the functional coatings all contain titanium powders. The present invention can improve the conductivity of the bipolar plate while using a low-cost stainless steel plate, thus improving the overall properties of the water electrolysis bipolar plate.
C25B 11/036 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par la configuration ou la forme Électrodes bipolaires
C25B 11/04 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par le matériau
C25B 1/04 - Hydrogène ou oxygène par électrolyse de l'eau
C23C 4/08 - Matériaux métalliques ne contenant que des éléments métalliques
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Khalit, Siti Hajar Bt
Quek, Ven Chian
Rostani, Khairul B
Cao, Yiming
Kang, Guodong
Abrégé
A method for removing acidic gases from a post combustion process stream, the method comprising the steps of: receiving the post combustion process stream into hollow fibres of at least one MBC cell, each hollow fibre gas permeable, liquid impermeable; passing a lean solvent in contact with an external surface of said hollow fibres; exchanging said acidic gas into the solvent through the hollow fibre; venting a treated lean gas stream; exiting an acidic gas rich solvent.
B01D 53/14 - SÉPARATION Épuration chimique ou biologique des gaz résiduaires, p.ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols par absorption
B01D 53/22 - SÉPARATION Épuration chimique ou biologique des gaz résiduaires, p.ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols par diffusion
B01D 53/96 - Régénération, réactivation ou recyclage des réactifs
24.
CIRCULATING FLUIDIZED BED REACTION REGENERATION DEVICE AND USE METHOD
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
CHINA SHENHUA COAL TO LIQUID AND CHEMICAL CO., LTD. (Chine)
Inventeur(s)
Zhang, Tao
Ye, Mao
Yan, Guochun
Liu, Zhongmin
Zhang, Jinling
Zhang, Jiming
Zhang, Cheng
Wen, Liang
Tang, Hailong
Yin, Tian
Jia, Jinming
Lin, Huadong
Wang, Xiangao
Ma, Xiangang
Wang, Jing
Gao, Mingbin
Li, Xue
Xu, Shuliang
Li, Hua
Li, Chenggong
Abrégé
A circulating fluidized bed reaction regeneration device and a use method. The device comprises a fluidized bed reactor (1), a fluidized bed regenerator (2) and a riser reactor (3). The fluidized bed reactor (1) is used for introducing a naphtha raw material and a methanol raw material, wherein the naphtha raw material is brought into contact with a catalyst from the riser reactor (3), so as to perform a reaction to generate a BTX-containing product gas stream and a spent catalyst, and the methanol raw material undergoes a methylation reaction with benzene and toluene in the BTX-containing product gas stream to generate p-xylene; the product gas stream is subjected to gas-solid separation, the separated product gas is conveyed to a downstream section, unconverted naphtha is returned as a raw material to the fluidized bed reactor, part of a low-carbon alkane is returned as a raw material to the riser reactor (3), and the spent catalyst is introduced into the fluidized bed regenerator (2); and an inlet of the riser reactor (3) is connected to the fluidized bed regenerator (2), and an outlet of the riser reactor (3) is connected to the fluidized bed reactor (1). The use method comprises: preparing an aromatic hydrocarbon by using a circulating fluidized bed reaction regeneration device and a metal molecular sieve bifunctional catalyst.
B01J 8/26 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
CHINA SHENHUA COAL TO LIQUID AND CHEMICAL CO., LTD. (Chine)
Inventeur(s)
Ye, Mao
Zhang, Tao
Zhang, Jiming
Liu, Zhongmin
Zhang, Jinling
Yan, Guochun
Wang, Xiangao
Zhang, Tingbin
Jia, Jinming
Wu, Qiong
Tang, Hailong
Jiao, Yanzhong
Zhang, Cheng
Ma, Xiangang
Wang, Jing
Gao, Mingbin
Li, Xue
Xu, Shuliang
Li, Hua
Li, Chenggong
Abrégé
3455 hydrocarbons obtained by means of separation of the product gas enter the light hydrocarbon aromatization reactor (3) to be further converted into components such as aromatic hydrocarbons.
B01J 8/26 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération
C07C 2/00 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant un plus petit nombre d'atomes de carbone
C07C 5/393 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant le même nombre d'atomes de carbone par déshydrogénation avec formation d'hydrogène libre avec isomérisation simultanée avec cyclisation en un cycle aromatique à six chaînons, p.ex. déshydrogénation du n-hexane en benzène
DALIAN INSTITUTE OF CHEMICALS PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Khalit, Siti Hajar Bt
Quek, Ven Chian
Rostani, Khairul B
Cao, Yiming
Kang, Guodong
Abrégé
A method for removing acidic gases from a post combustion process stream, the method comprising the steps of: receiving the post combustion process stream into hollow fibres of at least one MBC cell, each hollow fibre gas permeable, liquid impermeable; passing a lean solvent in contact with an external surface of said hollow fibres; exchanging said acidic gas into the solvent through the hollow fibre; venting an acidic gas lean stream; exiting an acidic gas rich solvent.
B01D 53/22 - SÉPARATION Épuration chimique ou biologique des gaz résiduaires, p.ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols par diffusion
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
CHINA SHENHUA COAL TO LIQUID AND CHEMICAL CO., LTD. (Chine)
Inventeur(s)
Ye, Mao
Zhang, Tao
Zhang, Jiming
Liu, Zhongmin
Zhang, Jinling
Yan, Guochun
Tang, Hailong
Wen, Liang
Jia, Jinming
Cao, Bonan
Zhang, Cheng
Zhang, Xiulong
Wang, Xiangao
Ma, Xiangang
Wang, Jing
Gao, Mingbin
Li, Xue
Xu, Shuliang
Li, Hua
Li, Chenggong
Abrégé
The present application discloses a naphtha and methanol based aromatic hydrocarbon preparation and olefin co-production fluidized bed device and a method. By using the device, under the action of a catalyst, naphtha reacts with methanol to generate product gas using aromatic hydrocarbon and low-carbon olefin as main components. According to the method of the present application, straight-chain and branched-chain aliphatic hydrocarbon can be highly selectively converted into aromatic hydrocarbon efficiently, production of para-xylene is increased by means of the methylation reaction of aromatic hydrocarbon, and the content of para-xylene in a xylene mixture can reach 75 wt%. According to a naphtha and methanol based aromatic hydrocarbon preparation reactor in the present application, production of para-xylene is increased by controlling the process of a cascade reaction (naphtha→benzene and toluene→para-xylene); in addition, by means of the methylation reaction of benzene, toluene, and methanol, heat is provided in situ for a naphtha and methanol based aromatic hydrocarbon preparation reaction, so that self-heat balance is achieved.
C07C 2/86 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant un plus petit nombre d'atomes de carbone par condensation d'un hydrocarbure et d'un non-hydrocarbure
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
B01J 8/26 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération
28.
FLUIDIZED BED DEVICE AND METHOD FOR PREPARING AROMATIC HYDROCARBONS FROM NAPHTHA
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
CHINA SHENHUA COAL TO LIQUID AND CHEMICAL CO., LTD. (Chine)
Inventeur(s)
Zhang, Tao
Ye, Mao
Yan, Guochun
Liu, Zhongmin
Zhang, Jinling
Zhang, Jiming
Jia, Jinming
Wen, Liang
Ma, Xiangang
Lin, Huadong
Tang, Hailong
Ma, Zhichao
Zhang, Cheng
Wang, Xiangao
Wang, Jing
Gao, Mingbin
Li, Xue
Xu, Shuliang
Li, Hua
Li, Chenggong
Abrégé
Disclosed in the present application are a fluidized bed device and method for preparing aromatic hydrocarbons from naphtha. The device at least comprises a light hydrocarbon aromatization reactor and a naphtha-to-aromatics reactor, which are connected in series. A high-temperature regenerated catalyst first enters the light hydrocarbon aromatization reactor, is cooled and then enters the naphtha-to-aromatics reactor. The method of the present application comprises: preparing aromatic hydrocarbons by using the device and a metal molecular sieve bifunctional catalyst, wherein naphtha can be converted into a product gas containing components such as aromatic hydrocarbons and light alkanes under the action of the catalyst, and the light alkanes, etc., separated from the product gas enter the light hydrocarbon aromatization reactor to be further converted into aromatic hydrocarbons and other components. The method of the present application can realize efficient high-selectivity conversion of linear and branched aliphatic hydrocarbons into aromatic hydrocarbons, and the content of p-xylene in a xylene mixture is greater than 50 wt%.
C10G 69/04 - Traitement des huiles d'hydrocarbures par au moins un procédé d'hydrotraitement et au moins un autre procédé de conversion uniquement par plusieurs étapes en série comprenant au moins une étape de craquage catalytique en l'absence d'hydrogène
C10G 11/18 - Craquage catalytique, en l'absence d'hydrogène, des huiles d'hydrocarbures avec catalyseurs solides mobiles préchauffés selon la technique du "lit fluidisé"
DALIAN INSTITUTE OF CHEMICAL PHYSICS , CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Cao, Hujun
Zou, Ren
Chen, Ping
Abrégé
Disclosed in the present application are an alkali metal hydride, a preparation method and the use. The preparation method at least comprises: subjecting raw materials including an alkali metal, an organic solvent and hydrogen to ball milling in an inactive atmosphere, so as to obtain the alkali metal hydride. The alkali metal hydride disclosed in the present invention has a uniform particle size, and has wide application prospects in the fields of hydrogen storage, heat storage and catalytic synthesis; and the method involves a simple preparation process, is suitable for large-scale and low-cost amplification and has very good development prospects and practical application value.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Chen, Ping
Zhang, Weijin
Cao, Hujun
Cui, Jirong
Wang, Shangshang
Abrégé
xx, where RE represents a rare earth metal and x ranges from 1-10. The described hydrogen anion conductor has excellent room temperature and even low temperature conductivity properties.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Fuxiang
Fan, Wenjun
Mehmood, Rashid
Abrégé
The present invention relates to the technical fields of electrocatalysis and chemical industry, and specifically relates to an electrocatalytic water oxidation homogeneous diatomic catalyst, and a preparation method therefor and a use thereof. The catalyst comprises a carrier and a homogeneous diatomic active site having an adjacency structure, and the active site is anchored in the carrier; the carrier is one or more than two of an oxide, a hydroxide, and an oxyhydroxide of a 3d transition metal; a coordination structure is formed between the two atoms and the carrier. The intrinsic activity of a diatomic dispersed catalytic material prepared by the method in an electrocatalytic water oxidation reaction is equivalent to that of the existing natural photosynthetic system II having the highest efficiency, the water oxidation initial potential is merely 170 mV, and the stability is kept for 650 hours under a current density of 20 mA cm-2-; and the preparation method is simple and has low cost.
C25B 11/091 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par le matériau Électrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau électro-catalytique formé de plusieurs éléments catalytiques ou composés catalytiques
C25B 11/075 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par le matériau Électrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau électro-catalytique formé d’un seul élément catalytique ou composé catalytique
C25B 11/067 - Composé inorganique, p.ex. oxyde d'indium-étain, silice ou oxydes de titane
C25B 11/069 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par le matériau Électrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau du substrat ou du support formé de plusieurs composés
C25B 1/04 - Hydrogène ou oxygène par électrolyse de l'eau
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Wang, Qianru
Qin, Chao
Gou, Jianping
Chen, Ping
Abrégé
The present application provides a synthesis method for lithium carbodiimide, comprising the following steps: reacting lithium hydride and a carbon source substance in a nitrogen atmosphere to obtain lithium carbodiimide. The present invention uses abundant and cheap nitrogen molecules as a nitrogen source to prepare lithium carbodiimide. The prepared lithium carbodiimide has high purity. The preparation process is simple, easy to scale u, and does not require further separation and purification.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ni, Youming
Zhu, Wenliang
Liu, Zhongmin
Abrégé
A method for preparing glycolic acid through hydrolysis of alkoxyacetate is provided. The method includes: subjecting raw materials including the alkoxyacetate and water to a reaction in the presence of an acidic molecular sieve catalyst to produce the glycolic acid, where the alkoxyacetate is at least one selected from the group consisting of compounds with a structural formula shown in formula I; and in formula I, R1 and R2 each are independently any one selected from the group consisting of C1-C5 alkyl groups. The glycolic acid production method in the present application can be implemented by a traditional fixed-bed reactor under an atmospheric pressure, which is very suitable for continuous production.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ni, Youming
Zhu, Wenliang
Liu, Zhongmin
Abrégé
A method for preparing glycolic acid and methyl glycolate through hydrolysis of methyl methoxyacetate and methoxyacetic acid is provided. The method includes allowing raw materials including methyl methoxyacetate, methoxyacetic acid, and water to contact and react with a catalyst to produce glycolic acid and methyl glycolate, where the catalyst is at least one selected from the group consisting of a solid acid catalyst, a liquid acid catalyst, a solid base catalyst, and a liquid base catalyst. The method for preparing glycolic acid and methyl glycolate in the present application can be implemented by a traditional fixed-bed reactor, tank reactor, or catalytic distillation reactor under an atmospheric pressure, which is very suitable for continuous production.
C07C 51/377 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par des réactions ne créant pas de groupes carboxyle par hydrogénolyse de groupes fonctionnels
C07C 67/31 - Préparation d'esters d'acides carboxyliques par modification de la partie acide de l'ester sans introduction d'un groupe ester par introduction de groupes fonctionnels avec de l'oxygène lié uniquement par liaison simple
35.
NEW PROTECTIVE FILM, BATCH PREPARATION METHOD THEREFOR AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Hao, Jinkai
Zhang, Hongjie
Shao, Zhigang
Abrégé
A protective film sequentially includes a release film, a low-viscosity silica gel layer, a high-viscosity silica gel layer and a substrate from top to bottom. A high-viscosity organosilicon adhesive, a hydroxyl-terminated polydimethylsiloxane, a curing agent, an additive and a solvent are coated on a polyester film. A low-viscosity organosilicon adhesive, the hydroxyl-terminated polydimethylsiloxane, the curing agent, the additive and the solvent are mixed and costed on the polyester film complex, which is pressed with the release film to obtain a silica gel protective film for fuel cells. A proton exchange membrane is coated with a catalyst to form a first catalyst layer, the protective film is adhered to the surface of the first catalyst layer, the second side of the proton exchange membrane is coated, and the silica gel protective film is peeled off after the coating is finished to obtain a CCM for a fuel cell.
C09J 7/25 - Matières plastiques; Matières plastiques métallisées à base de composés macromoléculaires obtenus par des réactions autres que celles faisant intervenir uniquement des liaisons non saturées carbone-carbone
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Huang, Jiahui
Liu, Yingchun
Su, Xin
He, Guse
Long, Huayun
He, Peng
Wang, Changyun
Li, Xinju
Abrégé
Disclosed is a process for producing epoxypropane by using an HPPO method of a liquid-solid circulating fluidized bed reaction-regeneration system, which belongs to the technical field of epoxypropane production. In the present invention, by means of the liquid-solid circulating fluidized bed reaction-regeneration system, hydrogen peroxide is used to directly oxidize propylene to prepare epoxypropane. The liquid-solid circulating fluidized bed reaction-regeneration system mainly comprises a catalyst regenerator, a feeding inclined pipe, a lifting pipe reactor, a liquid-solid separator, a return inclined pipe and other components. In the process, the liquid-solid circulating fluidized bed reaction-regeneration system is used for replacing a traditional tubular fixed bed reactor, the liquid-solid interphase heat transfer and mass transfer rate is enhanced in the reactor, the reaction rate is greatly increased, the reaction time is shortened, side reactions are inhibited, and the effective utilization rate of hydrogen peroxide and the selectivity of epoxypropane are increased. The present invention provides a brand-new process for the production of epoxypropane, which is beneficial to reducing the production cost of epoxypropane.
C07D 303/04 - Composés contenant des cycles oxirane contenant uniquement des atomes d'hydrogène et de carbone en plus des atomes d'oxygène des cycles
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ye, Mingliang
Li, Kejia
Abrégé
Disclosed in the present invention is a method for detecting a protein having changes in an energy state, and affinity of a ligand to a protein. Specifically, after the energy state of a protein changes, the tolerance to enzyme cleavage destruction changes, the structure of the protein in a low-energy state is also destroyed under a non-denaturation condition by using a large amount of enzymes, and a small peptide fragment which has a molecular weight of less than 5 KDa and can be directly used for bottom-top mass spectrometry analysis is directly generated. The method has extremely high sensitivity, and quantitative proteomics is used to find enzyme cleavage differential peptide fragments, and proteins to which the differential peptide fragments belong and the positions in the proteins are analyzed, so that a protein having changes in an energy state, and a change region can be determined in the whole proteome range. If the energy state of the protein changes due to addition of a ligand, the method can determine a binding protein and a binding region of the ligand; and the output of a quantitative result on the peptide fragment level further enables the method to determine the local affinity of binding of the ligand to the protein.
G01N 33/68 - Analyse chimique de matériau biologique, p.ex. de sang ou d'urine; Test par des méthodes faisant intervenir la formation de liaisons biospécifiques par ligands; Test immunologique faisant intervenir des protéines, peptides ou amino-acides
G01N 27/62 - Recherche ou analyse des matériaux par l'emploi de moyens électriques, électrochimiques ou magnétiques en recherchant les décharges électriques, p.ex. l'émission cathodique
C12P 21/06 - Préparation de peptides ou de protéines préparés par hydrolyse d'une liaison peptidique, p.ex. hydrolysats
G16B 35/00 - TIC spécialement adaptées aux bibliothèques combinatoires in silico d’acides nucléiques, de protéines ou de peptides
38.
METHOD FOR PREPARING AROMATIC HYDROCARBONS FROM METHANOL AND/OR DIMETHYL ETHER
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Chen, Zhiyang
Zhu, Wenliang
Liu, Zhongmin
Abrégé
The present invention provides a method for preparing aromatic hydrocarbons from methanol and/or dimethyl ether. The method comprises: making a material containing methanol and/or dimethyl ether contact a catalyst for reaction to obtain aromatic hydrocarbons, wherein the catalyst is a metal-modified molecular sieve catalyst, and the pressure of the reaction is 7-15 MPa. Compared with the prior art, the reaction of methanol and dimethyl ether to aromatic hydrocarbons under high-pressure atmosphere in the method provided by the present application can improve and stabilize the selectivity of aromatic hydrocarbons, especially BTX, and prolong the single-pass life of the catalyst.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Ning
Zou, Zhufan
Li, Guangyi
Zhang, Tao
Wang, Aiqin
Wang, Xiaodong
Cong, Yu
Abrégé
xyzz composite metal oxide catalyst, so as to synthesize a target product, i.e., methylcyclopentadiene. The present invention has a simple process line, is convenient for catalyst preparation, is environmentally friendly, and achieves direct conversion from cyclopentanone and methanol to high value-added methylcyclopentadiene.
C07C 13/15 - Hydrocarbures monocycliques ou leurs dérivés hydrocarbonés acycliques à cycle à cinq chaînons à cycle du cyclopentadiène
C07C 1/207 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes à partir de composés carbonylés
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Ning
Zou, Zhufan
Li, Guangyi
Zhang, Tao
Wang, Aiqin
Wang, Xiaodong
Cong, Yu
Abrégé
xyzz type composite metal oxide catalyst, the target product cyclopentadiene is synthesized by means of hydrodeoxygenation and dehydrogenation reactions in series. The present invention has a simple process route and is environment-friendly, and the catalyst is convenient to prepare, thereby providing a new and effective way for synthesizing cyclopentadiene by means of cyclopentanone.
C07C 1/207 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes à partir de composés carbonylés
C07C 13/15 - Hydrocarbures monocycliques ou leurs dérivés hydrocarbonés acycliques à cycle à cinq chaînons à cycle du cyclopentadiène
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Hao, Jinkai
Zhang, Hongjie
Shao, Zhigang
Abrégé
A preparation process of composite membrane for fuel cells uses an expanded polytetrafluoroethylene microporous base membrane as a skeleton. The base membrane is subjected to an impregnation treatment of mixed solutions having different concentrations from low to high. Specifically, the treatment tank I is provide with a mixed solution of a 0.1 wt. %-1 wt. % perfluorosulfonic acid resin solution, a water-retaining agent and a free radical quencher, the treatment tank II is provided with a mixed solution of a 2 wt. %-6 wt. % perfluorosulfonic acid resin solution, a water-retaining agent and a free radical quencher, and the treatment tank III is provided with a mixed solution of a 7 wt. %-20 wt. % perfluorosulfonic acid resin solution and a sulfonated polyetheretherketone solution. The resulting proton exchange composite membrane does not generate pore residues and avoids hydrogen permeation when in use.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Hongjie
Hao, Jinkai
Shao, Zhigang
Abrégé
A roll-to-roll continuous coater for CCM preparation, and a coiled material connection method are provided. The coater has a coiled material connection mechanism that includes an upper rack (2) and a lower rack (3). A vacuum suction plate I (2-3) provided with a driving device for achieving displacement and a vacuum suction plate II (3-1) provided with a solid glue spraying device (3-3) are respectively disposed on the bottom of the upper rack (2) and the top of the lower rack (3). An optical fiber sensor I (2-4) and an optical fiber sensor II (3-2) are respectively disposed in the vacuum suction plate I (2-3) and the vacuum suction plate II (3-1). A tension detection device (4) is disposed between the lower rack (3) and a driving roller assembly (1).
B65H 23/18 - Positionnement, tension, suppression des à-coups ou guidage des bandes longitudinal en commandant ou régulant le mécanisme d'avance de la bande, p.ex. le mécanisme agissant sur la bande courante
B05C 5/02 - Appareillages dans lesquels un liquide ou autre matériau fluide est projeté, versé ou répandu sur la surface de l'ouvrage à partir d'un dispositif de sortie en contact, ou presque en contact, avec l'ouvrage
43.
METHOD FOR PREPARING ORGANIC SOLVENT-ACTIVATED NANO MAGNESIUM POWDER
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Cao, Hujun
Zou, Ren
Chen, Ping
Abrégé
A method for preparing an organic solvent-activated nano magnesium powder, which method belongs to the technical fields of nano material preparation, hydrogen storage materials and hydrogen storage application. The method for preparing an organic solvent-activated nano magnesium powder comprises the following steps: reacting a mixture containing a magnesium source and an organic solvent to obtain an activated nano magnesium powder, wherein the mass ratio of the magnesium source to the organic solvent is 1 : 0.1 to 1 : 1. By means of the method, the magnesium powder is significantly reduced from millimeter scale to micron scale or even nanoscale, and the chemical adsorption of the organic solvent on the surface of the magnesium powder greatly improves the surface activity; the prepared nano magnesium powder can significantly absorb hydrogen at room temperature, and can be quickly hydrogenated into magnesium hydride with high economic value under mild conditions; and the method has a simple and feasible process and is suitable for large-scale amplified production.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Shao, Zhigang
Lv, Bo
Abrégé
A composite high-temperature proton exchange membrane for a fuel cell is prepared using materials include PBI and composite A@B and phosphoric acid. A is nanoparticles with a free radical quenching function and B is C3N4 having a nanosheet structure. The mass fraction of composite A@B is 0.05-2 wt. % and the mass ratio of A to B in A@B is 1:1-1:20. Composite A@B is firstly prepared, and A@B is then ultrasonically dispersed with a strong polar aprotic solvent to obtain a dispersion S1. PBI solution S2 is obtained from PBI and a strong polar aprotic solvent. S1 and S2 are uniformly mixed and stirred to obtain a casting solution S3, which is cast on plate glass with a groove. The membrane is then soaked in phosphoric acid after dying to obtain a composite membrane for a high-temperature proton fuel cell.
H01M 8/1048 - Additifs conducteurs ioniques, p.ex. particules conductrices ioniques, hétéro polyacides, phosphates métalliques ou polybenzimidazoles comprenant de l’acide phosphorique
H01M 8/103 - Matériaux d’électrolyte polymère caractérisés par la structure chimique de la chaîne principale du polymère conducteur ionique comprenant de l’azote, p.ex. des polybenzimidazoles sulfonés [S-PBI], des polybenzimidazoles comprenant de l’acide phosphorique, des polyamides sulfonés [S-PA] ou des polyphosphazènes sulfonés
H01M 8/1067 - Matériaux d’électrolyte polymère caractérisés par leurs propriétés physiques, p.ex. la porosité, la conductivité ionique ou l’épaisseur
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Liu, Yanting
Bo, Xin
Shu, Yunmao
Abrégé
A compact portable oxyhydrogen generator has a housing, an end cover fastened on the upper end of the housing for discharging gas, and a bottom cover fastened at the lower end of the housing. A battery module for supplying power, an electrolytic cell module for generating hydrogen/oxygen mixture, a water filtration cell for filtering moisture, and a multi-stage filter baffle for further filtering the gas are sequentially arranged in the housing from bottom to top. A flame retardant core is provided between the filter baffle at the top layer and a gas outlet provided in the end cover. The multi-stage filter baffle is provided according to requirements of a gas filtering index. Water is used as a reaction raw material and an inorganic salt can be used as an electrolyte, such that a normal-pressure hydrogen/oxygen mixture may be to directly generated, and can be produced when needed.
C25B 11/091 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par le matériau Électrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau électro-catalytique formé de plusieurs éléments catalytiques ou composés catalytiques
C25B 1/04 - Hydrogène ou oxygène par électrolyse de l'eau
C25B 11/031 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par la configuration ou la forme perforées ou foraminées Électrodes poreuses
47.
INTEGRATED ELECTRODE FRAME AND PREPARATION METHOD AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Xianfeng
Shi, Dingqin
Zhang, Huamin
Abrégé
An integrated electrode frame and preparation method and use thereof is provided. The integrated electrode frame includes a positive electrode frame, a negative electrode frame, and a membrane. Each of the positive electrode frame and the negative electrode frame is a flat plate with a central through-hole. The membrane is placed between the positive electrode frame and the negative electrode frame, and the membrane is located at the through-hole and hermetically connected to a peripheral edge of the through-hole. A peripheral edge of the positive electrode frame is hermetically connected to a peripheral edge of the negative electrode frame. A material composition of a connecting part of the positive electrode frame and the negative electrode frame contains at least one material which is the same as that of the positive electrode frame or the negative electrode frame. The structures and materials of the electrode frames and the membrane are optimized.
H01M 8/0273 - Moyens d’étanchéité ou de support autour des électrodes, des matrices ou des membranes avec des moyens d’étanchéité ou de support sous forme d’un cadre
H01M 8/18 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Éléments à combustible; Leur fabrication Éléments à combustible à régénération, p.ex. batteries à flux REDOX ou éléments à combustible secondaires
H01M 8/242 - Groupement d'éléments à combustible, p.ex. empilement d'éléments à combustible avec électrolytes solides ou supportés par une matrice comprenant des électrodes encadrées ou des joints intermédiaires en forme de cadre
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Weizhen
Zhang, Jingcai
Zhang, Tao
Abrégé
A burner includes a housing, a fan, a burning head and an ignition mechanism. An air inlet of the housing and an input end of the burning head form a pressure equalizing cavity. The ignition mechanism is arranged at an output end of the burning head. The burning head includes a main frame and at least one stable burning isolation strip, an interior of the main frame is divided into at least two ventilation areas by the stable burning isolation strip in a gas channel direction. A plurality of separation mechanisms is arranged in each ventilation area and divide the ventilation area into a plurality of through holes arranged in the gas channel direction, the through holes are used for allowing mixed gas to pass through and strengthening the mixing effect. The burning flame of a burning surface of the main frame can be divided into mutually independent flames by the stable burning isolation strip. The burner can be used in gas stoves, low-nitrogen combustion engines for a gas boiler, gas water heaters and gas heating water heaters.
F23D 14/02 - Brûleurs à gaz avec prémélangeurs, c. à d. dans lesquels le combustible gazeux est mélangé à l'air de combustion en amont de la zone de combustion
F23C 6/02 - Appareils à combustion caractérisés par la combinaison d'au moins deux chambres de combustion disposées parallèlement
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Cunyao
Yan, Li
Ding, Yunjie
Ding, Yulong
Jiang, Miao
Ma, Lei
Ji, Guangjun
Qian, Leilei
Abrégé
Disclosed in the present invention are an eggshell-type catalyst, and a preparation method therefor, and the use thereof in a propylene hydroformylation reaction. In the eggshell-type catalyst, phosphine ligand resin pellets with developed pore structures are used as a carrier, and one, two or more of metals Rh, Co, Ir, Ru and Pd are used as active components. The spatial distribution of the metal active components in the resin pellets is effectively regulated by finely regulating the pore structure of the resin carrier pellets and adding a method of competitive adsorption coordination, such that the prepared eggshell-type catalyst has the characteristics of relatively high activity in the propylene hydroformylation reaction and good n-butyraldehyde selectivity in the product aldehyde.
B01J 31/06 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques contenant des polymères
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Yang, Liping
Xing, Jiacheng
Yuan, Danhua
Xu, Yunpeng
Liu, Zhongmin
Abrégé
An adsorbent and a use thereof are provided. The adsorbent is a metal-organic framework (MOF) MIL-125; the MOF MIL-125 has an external specific surface area (SSA) of 160 m2/g to 220 m2/g; and the MOF MIL-125 includes a micropore with an area of 1,000 m2/g to 1,500 m2/g. The external SSA of the MOF MIL-125 is much higher than an external SSA of the traditional MIL-125, which has promising application prospects in the adsorptive separation of xylene isomers and exhibits high selectivity for p-xylene.
B01J 20/22 - Compositions absorbantes ou adsorbantes solides ou compositions facilitant la filtration; Absorbants ou adsorbants pour la chromatographie; Procédés pour leur préparation, régénération ou réactivation contenant une substance organique
B01J 20/28 - Compositions absorbantes ou adsorbantes solides ou compositions facilitant la filtration; Absorbants ou adsorbants pour la chromatographie; Procédés pour leur préparation, régénération ou réactivation caractérisées par leur forme ou leurs propriétés physiques
B01D 15/20 - Adsorption sélective, p.ex. chromatographie caractérisée par des caractéristiques de structure ou de fonctionnement relatives au conditionnement de la matière adsorbante ou absorbante
B01D 15/18 - Adsorption sélective, p.ex. chromatographie caractérisée par des caractéristiques de structure ou de fonctionnement relatives aux différents types d'écoulement
B01D 15/42 - Adsorption sélective, p.ex. chromatographie caractérisée par le mode de développement, p.ex. par déplacement ou par élution
51.
METAL-ORGANIC FRAMEWORK (MOF) MIL-125 AND PREPARATION METHOD AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Xing, Jiacheng
Yang, Liping
Yuan, Danhua
Xu, Yunpeng
Liu, Zhongmin
Abrégé
A metal-organic framework (MOF) MIL-125 and a preparation method and a use thereof are provided. The MOF MIL-125 is a round cake-like crystal and has an external specific surface area (SSA) of 160 m2/g to 220 m2/g. The MOF MIL-125 provided in the present application has a large number of microporous structures, a large external SSA, and a high catalytic activity in oxidation.
B01J 31/16 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des complexes de coordination
B01J 35/10 - Catalyseurs caractérisés par leur forme ou leurs propriétés physiques, en général solides caractérisés par leurs propriétés de surface ou leur porosité
B01J 35/02 - Catalyseurs caractérisés par leur forme ou leurs propriétés physiques, en général solides
C07D 301/19 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par des hydroperoxydes organiques
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Xing, Jiacheng
Yuan, Danhua
Xu, Yunpeng
Liu, Zhongmin
Abrégé
A preparation method of a porous oxide is provided, which includes: preparing the porous oxide with a polyester polyol as a raw material. The porous oxide prepared by the preparation method in the present application has characteristics such as uniform and adjustable pore sizes and controllable distribution of mesopores, micropores, and macropores.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Yuan, Danhua
Xu, Yunpeng
Liu, Zhongmin
Abrégé
Disclosed in the present application is a method for preparing 1,2-dichloroethane. The method comprises reacting raw materials containing ethylene glycol diacetate and hydrogen chloride in the presence of a catalyst to obtain 1,2-dichloroethane. By means of the method, ethylene glycol diacetate can be efficiently converted into 1,2-dichloroethane, and the yield of 1,2-dichloroethane is very high.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ma, Lei
Yan, Li
Ding, Yunjie
Yu, Tingting
Abrégé
2322322. The carrier is modified by an alkali metal or an alkaline-earth metal before use, wherein the alkali metal is one or a combination of Na and K. The reduced and activated catalyst is subjected to a high-temperature treatment in an ammonia atmosphere. The catalyst prepared by using the method is used for the hydroamination of monoethanolamine and ethylenediamine, has the advantages of high yield, good stability, high activity, etc. of polyethylene polyamine, and has broad industrial prospects.
C07C 209/16 - Préparation de composés contenant des groupes amino liés à un squelette carboné par substitution de groupes fonctionnels par des groupes amino par substitution de groupes hydroxy ou de groupes hydroxy éthérifiés ou estérifiés avec formation de groupes amino liés à des atomes de carbone acycliques ou à des atomes de carbone de cycles autres que des cycles aromatiques à six chaînons
C07C 209/68 - Préparation de composés contenant des groupes amino liés à un squelette carboné à partir d'amines, par des réactions n'impliquant pas de groupes amino, p.ex. réduction d'amines non saturées, aromatisation ou substitution du squelette carboné
C07C 211/14 - Amines contenant des groupes amino liés à au moins deux groupes aminoalkyle, p.ex. diéthylènetriamines
C07D 295/13 - Composés hétérocycliques contenant des cycles polyméthylène imine d'au moins cinq chaînons, des cycles aza-3 bicyclo [3.2.2] nonane, piperazine, morpholine ou thiomorpholine, ne comportant que des atomes d'hydrogène liés directement aux atomes de car avec des radicaux hydrocarbonés substitués liés aux atomes d'azote du cycle substitués par des atomes d'azote liés par des liaisons simples ou doubles avec les atomes d'azote du cycle et les atomes d'azote substituants liés à la même chaîne carbonée, qui n'est pas interrompue par des cycles carbocycliques à une chaîne acyclique saturée
B01J 35/10 - Catalyseurs caractérisés par leur forme ou leurs propriétés physiques, en général solides caractérisés par leurs propriétés de surface ou leur porosité
B01J 37/18 - Réduction avec des gaz contenant de l'hydrogène libre
B01J 23/89 - Catalyseurs contenant des métaux, oxydes ou hydroxydes métalliques non prévus dans le groupe du cuivre ou des métaux du groupe du fer combinés à des métaux nobles
B01J 23/78 - Catalyseurs contenant des métaux, oxydes ou hydroxydes métalliques non prévus dans le groupe du cuivre ou des métaux du groupe du fer en combinaison avec des métaux, oxydes ou hydroxydes prévus dans les groupes avec des métaux alcalins ou alcalino-terreux ou du béryllium
55.
CATALYTIC REFORMING CATALYST PREPARATION METHOD AND CATALYTIC REFORMING CATALYST
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Peng
Zhang, Xiaomin
Han, Xiaolin
Xu, Lei
Lv, Zhi
Lu, Yuying
Li, Zhichun
Cui, Jia
Wang, Zongbao
Xiao, Haicheng
Abrégé
The present application provides a catalytic reforming catalyst preparation method and a catalytic reforming catalyst. The catalytic reforming catalyst preparation method of the present application comprises the following steps: 1) adding a platinum group metal precursor to a system comprising a first silicon source and an aluminum source for mixing, and then adding a second silicon source, so as to obtain a silicon-aluminum precursor coated with platinum group metals, the first silicon source comprising a silane compound containing aminopropyl; and 2) performing steam assisted crystallization on the silicon-aluminum precursor coated with the platinum group metal, so as to obtain the catalytic reforming catalyst. The catalytic reforming catalyst prepared by the preparation method of the present application has excellent stability and smaller molecular sieve grain size, and has excellent aromatics selectivity, aromatics yield, and carbon deposition resistance when used in catalytic reforming reaction.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Chen, Guangwen
Liu, Zhikai
Abrégé
An ultrasonic micromixer having millisecond mixing performance. The ultrasonic micromixer comprises a micromixer (1), an ultrasonic transducer (2), and an ultrasonic generator (3); the wavelength of a sound wave in air corresponding to the working frequency of the ultrasonic transducer (2) is 4-68 times the hydraulic diameter of a microchannel in the micromixer (1). By means of matching between the hydraulic diameter of the microchannel and the wavelength of the sound wave, vigorous and highly controllable ultrasonic cavitation is generated in the microchannel, the density of cavitation bubbles can reach one cavitation bubble per cubic millimeter, a large number of cavitation bubbles generated in the microchannel rapidly stir a fluid like a stirrer, so that millisecond-level mixing in the microchannel is implemented, and the shortest mixing time can reach 0.2 ms.
B01F 31/80 - Mélange au moyen de vibrations à haute fréquence supérieures à 1 kHz, p.ex. de vibrations ultrasoniques
B01F 31/87 - Mélange au moyen de vibrations à haute fréquence supérieures à 1 kHz, p.ex. de vibrations ultrasoniques transmettant l'énergie vibratoire au moyen d'un fluide, p.ex. au moyen d'ondes de choc aériennes
B01J 19/10 - Procédés utilisant l'application directe de l'énergie ondulatoire ou électrique, ou un rayonnement particulaire; Appareils à cet usage utilisant des vibrations de fréquences audibles ou des ultrasons
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Weizhen
Zhang, Jingcai
Zhang, Tao
Abrégé
A burner contains a burner component. The burner component includes a main frame and at least one stable burning isolation strip. An interior of the main frame is divided into at least two ventilation areas by the stable burning isolation strip in a gas channel direction. Several separation mechanisms are arranged in each ventilation area and divide the ventilation area into several through holes distributed in the gas channel direction. The through holes are used for a mixed gas of fuel gas and air to pass through and enhancing a mixing effect of the fuel gas and the air. The flame of a burning surface of the main frame can be divided into independent flames by the stable burning isolation strip so that the burning is more stable and fewer pollutants are emitted.
F23D 14/04 - Brûleurs à gaz avec prémélangeurs, c. à d. dans lesquels le combustible gazeux est mélangé à l'air de combustion en amont de la zone de combustion du type à induction, p.ex. becs Bunsen
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Yongjin
Zhang, Lei
Chen, Ruibing
Abrégé
Provided in the present application are a method for improving the SAM cofactor supply of Saccharomyces cerevisiae, an engineered yeast and the use thereof. The method comprises: introducing an MET6 gene, a cMTFHR gene, a LiMETK1 gene, an SAH1 gene and an ADO1 gene into Saccharomyces cerevisiae. The method can solve the problem of the insufficient supply of endogenous auxiliary factors in the synthesis process of methylation products such as ferulic acid, thereby increasing the synthesis efficiency thereof.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhou, Yongjin
Cao, Xuan
Abrégé
Provided are a construction method of engineering bacteria, engineering bacteria obtained by means of construction and use of same in the preparation of sclareol. The construction method comprises the following steps: a DNA fragment I which comprises a promoter, a fusion gene and a terminator in sequence from upstream to bottom is introduced into a saccharomyces cerevisiae host strain. The fusion gene comprises in sequence from upstream to bottom: a TPS gene, a coding gene for a linker peptide I and an LPPS gene. The construction method optimizes the sclareol synthetase of the host strain, thereby facilitating an increase in sclareol yield.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Yin, Heng
Zhang, Xiaojing
Abrégé
The present invention relates to the technical field of biology. Disclosed are a β-1,3-glucanase and a preparation method therefor and an application thereof. According to the present invention, by means of genetic engineering techniques, a gene of endo-β-1,3-glucanase CcGluE-CDMΔH1 is obtained from cellulosimicrobium cellulans, and the gene of the endo-β-1,3-glucanase CcGluE-CDMΔH1 is cloned to an Escherichia coli expression vector to obtain an Escherichia coli recombinant strain capable of heterologously expressing the enzyme. The endo-β-1,3-glucanase prepared by heterologous expression of the strain can produce gluco-oligosaccharides having different polydispersities at different pHs, and thus can be widely used in the fields of agriculture, food, feed addition, medicine, gluco-oligosaccharide preparation and the like.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ni, Youming
Zhu, Wenliang
Liu, Zhongmin
Abrégé
22-COOH, where R is a methoxy or hydroxyl; and the methyl ester compound comprises at least one of methyl methoxyacetate and methyl glycolate. A method for preparing the methyl glycolate comprises the steps of: a) subjecting methylal and carbon monoxide to a carbonylation reaction to obtain methyl methoxyacetate; b) subjecting the methyl methoxyacetate and water to a hydrolysis reaction to obtain the methyl glycolate; and c) subjecting glycolic acid and methoxyacetic acid, as well as methanol and dimethyl ether, to an esterification reaction to obtain the methyl glycolate. The method can greatly simplify the separation process, can save the energy consumption, and provides a new synthesis route for synthesizing a methyl ester compound, especially methyl glycolate.
C07C 67/08 - Préparation d'esters d'acides carboxyliques par réaction d'acides carboxyliques ou d'anhydrides symétriques avec le groupe hydroxyle ou O-métal de composés organiques
C07C 67/24 - Préparation d'esters d'acides carboxyliques par réaction d'acides carboxyliques ou de leurs dérivés avec une liaison éther carbone-oxygène, p.ex. acétal, tétrahydrofuranne
C07C 67/31 - Préparation d'esters d'acides carboxyliques par modification de la partie acide de l'ester sans introduction d'un groupe ester par introduction de groupes fonctionnels avec de l'oxygène lié uniquement par liaison simple
C07C 69/675 - Esters d'acides carboxyliques dont le groupe carboxyle estérifié est lié à un atome de carbone acyclique et dont l'un des groupes OH, O-métal, —CHO, céto, éther, acyloxy, des groupes , des groupes ou des groupes se trouve dans la partie acide d'acides saturés d'acides hydroxycarboxyliques saturés
C07C 67/37 - Préparation d'esters d'acides carboxyliques par réaction avec du monoxyde de carbone ou des formiates obtenus par réaction d'éthers avec l'oxyde de carbone
B01J 29/70 - Zéolites aluminosilicates cristallines; Leurs composés isomorphes de types caractérisés par leur structure spécifique non prévus dans les groupes
B01J 29/08 - Zéolites aluminosilicates cristallines; Leurs composés isomorphes du type faujasite, p.ex. du type X ou Y
B01J 29/40 - Zéolites aluminosilicates cristallines; Leurs composés isomorphes du type pentasil, p.ex. types ZSM-5, ZSM-8 ou ZSM-11
B01J 29/65 - Zéolites aluminosilicates cristallines; Leurs composés isomorphes du type ferriérite, p.ex. types ZSM-21, ZSM-35 ou ZSM-38
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Yuan, Danhua
Xu, Yunpeng
Liu, Zhongmin
Abrégé
Disclosed is a method for preparing 1,2-dichloroethane. The method comprises the following steps: reacting raw materials containing ethylene glycol monomethyl ether, hydrogen chloride and a catalyst, obtaining the 1,2-dichloroethane. According to the method, ethylene glycol monomethyl ether and hydrogen chloride are used as the raw materials for reaction, and the ethylene glycol monomethyl ether can be efficiently converted, obtaining a relatively high 1,2-dichloroethane yield.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Xianfeng
Xie, Congxin
Abrégé
The present application discloses an aqueous iodine-based battery based on multi-electron transfer, the main structure of which comprises a positive electrode, a negative electrode, a current collector, an electrolyte solution, a separator, etc. At both sides of the positive electrode and the negative electrode, a porous carbon felt is used as an electrode material, and a polymer film is used as a film material. Positive and negative electrolyte solutions are both stored in the porous carbon felt electrodes. Both the positive and negative electrolyte solutions are an acidic mixed solution containing I-and Cd2+; during charging, the I-322 to achieve an electrochemical reaction of six-electron transfer, and the negative electrode involves the deposition of the Cd2+as a Cd metal; and the process is reversed during discharging. The energy density of the battery calculated on the basis of the volume of the positive electrolyte solution can reach approximately 1100 Wh/L. In order to improve the dynamics and reversibility during the multi-electron transfer process, other additives need to be added to the solution so as to improve the electrochemical reversibility of the whole reaction. Therefore, the battery can achieve an energy efficiency of more than 77% at a current density of 80 mA/cm2, and can stably operate for more than 500 cycles.
H01M 8/18 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Éléments à combustible; Leur fabrication Éléments à combustible à régénération, p.ex. batteries à flux REDOX ou éléments à combustible secondaires
65.
AMINE-BROMINE TWO-ELECTRON ELECTROLYTE OF FLOW BATTERY AND USE THEREOF, AND FLOW BATTERY
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Xianfeng
Xu, Yue
Xie, Congxin
Abrégé
The present invention discloses an amine-bromine two-electron electrolyte of a flow battery and the use thereof, and a flow battery, which belong to the field of flow batteries. In the electrolyte, an amino compound having an electron-withdrawing group at the ortho-position of an amino is used to react with bromine charged to a positive valence so as to form an amine-bromine compound, such that positive-valence bromine is stabilized, and a reversible two-electron transfer reaction from a bromine ion to the amino compound is achieved. Amino compounds with different substituents have different solubilities and generate different voltages, and thus have extensive adjustability and applicability, and can be used in acidic, neutral and weakly alkaline flow battery systems. A flow battery assembled from the electrolyte which is prepared by means the reaction has the advantages of a low cost and a high energy density, and can obtain a relatively long cycle life and a relatively high battery efficiency.
H01M 8/18 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Éléments à combustible; Leur fabrication Éléments à combustible à régénération, p.ex. batteries à flux REDOX ou éléments à combustible secondaires
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
JINKAI INSTRUMENT (DALIAN) CO., LTD (Chine)
Inventeur(s)
Deng, Dehui
Liu, Yanting
Yang, Xiao
Fan, Jinchang
Zhao, Qiang
Zhao, Xiaoqi
Abrégé
A portable hydrogen-oxygen generator includes a housing having a detachable upper cover and a bottom cover. An electrolytic cell module is arranged in the housing. The electrolytic cell module has a hydrogen generation chamber and an oxygen generation chamber. A cathode electrode plate and an anode electrode plate are respectively arranged in the hydrogen generation chamber and the oxygen generation chamber, and the bottoms of the two generation chambers are communicated for electrolyte circulation. A hydrogen outlet part and an oxygen outlet part detachably arranged on the upper cover and respectively corresponding to the hydrogen generation chamber and the oxygen generation chamber. A filtering film for removing water is arranged between the hydrogen/oxygen outlet part and the electrolytic cell module. A power supply module is arranged on the bottom cover of the housing to supply electric energy to the cathode electrode plate and the anode electrode plate.
C25B 9/01 - Configuration ou forme des cellules électrolytiques
H01M 50/247 - Montures; Boîtiers secondaires ou cadres; Bâtis, modules ou blocs; Dispositifs de suspension; Amortisseurs; Dispositifs de transport ou de manutention; Supports spécialement adaptés aux dispositifs portatifs, p.ex. aux téléphones portables, aux ordinateurs, aux outils à main ou aux stimulateurs cardiaques
H01M 50/284 - Montures; Boîtiers secondaires ou cadres; Bâtis, modules ou blocs; Dispositifs de suspension; Amortisseurs; Dispositifs de transport ou de manutention; Supports comprenant l’insertion de cartes de circuits, p.ex. de cartes de circuits imprimés
H01M 50/298 - Montures; Boîtiers secondaires ou cadres; Bâtis, modules ou blocs; Dispositifs de suspension; Amortisseurs; Dispositifs de transport ou de manutention; Supports caractérisés par le câblage des blocs de batterie
C25B 15/08 - Alimentation ou vidange des réactifs ou des électrolytes; Régénération des électrolytes
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Weizhen
Zhang, Jingcai
Zhang, Tao
Abrégé
A gas-air mixing structure and a burner, comprising an external supporting structure (2) arranged in a housing (1) and a gas array pipe connected to the external supporting structure (2). An air inlet is connected to one end of the housing (1). A gas mixing channel is provided between the gas array pipe and a mixed gas outlet. The gas array pipe consists of multiple gas pipes (3) arranged in an array, the gas pipes (3) are provided with gas inlets and gas outlets (4), and the gas outlets (4) are arranged on the leeward surfaces of the gas pipes (3). A gas inlet pipe is arranged on the air channel and gas outlet holes (4) are spaced apart on the leeward surfaces of the gas pipes (3) to uniformly mix the gas ejected from the gas outlet holes (4) by utilizing a Coanda effect of air upon a circular pipe.
F23D 14/02 - Brûleurs à gaz avec prémélangeurs, c. à d. dans lesquels le combustible gazeux est mélangé à l'air de combustion en amont de la zone de combustion
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Weizhen
Zhang, Jingcai
Zhang, Tao
Abrégé
A gas-air mixing structure and a burner, comprising an external supporting structure (2) arranged in a housing (1) and a gas array pipe connected to the external supporting structure (2). An air inlet is connected to one end of the housing (1). A gas mixing channel is provided between the gas array pipe and a mixed gas outlet. The gas array pipe consists of multiple gas pipes (3) arranged in an array, the gas pipes (3) are provided with gas inlets and gas outlets (4), and the gas outlets (4) are arranged on the leeward surfaces of the gas pipes (3). A gas inlet pipe is arranged on the air channel and gas outlet holes (4) are spaced apart on the leeward surfaces of the gas pipes (3) to uniformly mix the gas ejected from the gas outlet holes (4) by utilizing a Coanda effect of air upon a circular pipe.
F23D 14/02 - Brûleurs à gaz avec prémélangeurs, c. à d. dans lesquels le combustible gazeux est mélangé à l'air de combustion en amont de la zone de combustion
69.
METHOD FOR GENERATING AROMATIC HYDROCARBON BY COUPLING ALKANE AND CARBON DIOXIDE
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Wei, Changcheng
Liu, Zhongmin
Li, Jinzhe
Abrégé
Disclosed in the present application is a method for producing aromatic hydrocarbon by coupling alkane and carbon dioxide. A mixture containing alkane and carbon dioxide is in contact with a solid acid catalyst in a reactor to react to obtain an aromatic hydrocarbon compound. The alkane is selected from at least one of C2-C6 alkanes. The solid acid catalyst comprises a zeolite molecular sieve and/or a modified zeolite molecular sieve. The modified zeolite molecular sieve is a silane-modified zeolite molecular sieve. The carbon dioxide is widely derived from factory fumes, light alkane is widely derived from byproducts of petrochemical plants, the effect of turning waste into wealth is achieved, and meanwhile the pressure of carbon dioxide emission is relieved. The H/C ratio of the C2-C6 alkane products is regulated and controlled by adjusting the partial pressure of carbon dioxide, such that the purpose of high-selectivity generation of the aromatic hydrocarbon is achieved, and the high BTX selectivity and PX selectivity are obtained by modifying the outer surface of the molecular sieve with silane.
C07C 2/86 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant un plus petit nombre d'atomes de carbone par condensation d'un hydrocarbure et d'un non-hydrocarbure
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Liu, Yanting
Shu, Yunmao
Bo, Xin
Abrégé
A hydrogen-oxygen mixed gas preparation device capable of adjusting hydrogen content and a method therefor. The hydrogen-oxygen mixed gas preparation device comprises a shell for accommodating an oxygen production device, a hydrogen production device, a control module (14), and a power supply module (19), wherein the power supply module (19) is configured to supply power to each device; the oxygen production device is configured to separate oxygen from air and store the oxygen for later use; the hydrogen production device is configured to generate hydrogen or hydrogen-oxygen mixed gas for later use by means of a water electrolysis principle; the control module (14) is configured to control and adjust the flow of the oxygen, measure the concentration of the oxygen, and adjust the flow of the hydrogen-oxygen mixed gas and the hydrogen content to a preset range; and the oxygen generated by the oxygen production device and the hydrogen generated by the hydrogen production device or the hydrogen-oxygen mixed gas are or is converged to a gas outlet (17) of the hydrogen-oxygen mixed gas preparation device through a pipeline and then discharged after humidification or discharged directly. Further disclosed is a method for using the device. The advantages such as long service life, adjustable hydrogen content, adjustable flow of the hydrogen-oxygen mixed gas are achieved.
C25B 9/00 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Éléments de structure des cellules; Assemblages d'éléments de structure, p.ex. assemblages d'électrode-diaphragme; Caractéristiques des cellules relatives aux procédés
C25B 1/044 - Hydrogène ou oxygène par électrolyse de l'eau produisant un mélange de gaz d'hydrogène et d'oxygène, p.ex. oxyhydrogène
C25B 1/04 - Hydrogène ou oxygène par électrolyse de l'eau
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Xianfeng
Xu, Pengcheng
Yuan, Zhizhang
Abrégé
The present application relates to the technical field of flow batteries, and discloses an alkaline negative electrode electrolyte and an alkaline zinc-iron flow battery assembled by same. An alkaline negative electrode electrolyte, wherein the negative electrode electrolyte comprising zinc ions, a complexing agent, and alkali. The complexing agent is selected from at least one of ethylenediamine tetraacetic acid, ethylene glycol diethyl ether diamine tetraacetic acid, cyclohexane tetraacetic acid, and ethylenediamine tetrapropionic acid; a molar ratio of the zinc ions to the complexing agent is 1:1; and a molar ratio of the complexing agent to the alkali is 1:(3-4). The zinc ions in the negative electrode electrolyte are in a complex state form, the negative electrode electrolyte is used as a negative electrode electrolyte, and the alkaline zinc-iron flow battery is obtained by means of assembly, so that the problem of electrolyte migration in the alkaline zinc-iron flow battery is solved, and the battery cycle stability is improved, moreover, the low-temperature performance of the battery is improved, and a working temperature range of the alkaline zinc-iron flow battery is widened.
H01M 8/04186 - Dispositions pour la commande des paramètres des réactifs, p.ex. de la pression ou de la concentration des réactifs chargés en liquide ou en électrolyte
H01M 8/18 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Éléments à combustible; Leur fabrication Éléments à combustible à régénération, p.ex. batteries à flux REDOX ou éléments à combustible secondaires
72.
EFFICIENT OXYHYDROGEN GENERATION DEVICE FOR MEDICAL CARE, AND METHOD THEREFOR
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Liu, Yanting
Bo, Xin
Shu, Yunmao
Abrégé
An efficient oxyhydrogen generation device for medical care. The efficient oxyhydrogen generation device mainly comprises a shell (20), an upper cover (1) and a bottom cover (33) which form a main body frame, wherein the shell (20) is composed of a front shell body and a rear shell body, the bottom cover (33) is fastened at the bottom of the shell body, and a formed space is used for accommodating an electrolytic tank (27), a water supply tank (23), a water supply tank upper cover (18) and a secondary water tank (26); the upper cover (1) is fastened on the upper part of the shell body and is provided with an atomization gas circulation part, a supply part used for filling the water supply tank with water, and a control panel (4) used for controlling an electrolytic water hydrogen and oxygen generator to operate; and oxyhydrogen generated by electrolysis of the electrolytic tank (27) sequentially enters the water supply tank (23) and the secondary water tank (26) by means of a gas guide plate (13) and is cleaned, and the cleaned gas is discharged from a gas circulation part.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Xiaozhe
Ding, Fei
Cheng, Qiong
Gu, Xiaosong
Liang, Xinmiao
Bai, Yunpeng
Yao, Dengbing
Yuan, Ying
Wang, Caiping
Yang, Jian
Yu, Shu
Abrégé
A multi-disulfide-bond long-chain peptide with neuroprotective activity can reduce cellular calcium influx by inhibiting glutamate receptors to protect cortical neurons from excitotoxicity induced by glutamate. It can be an effective neuroprotective agent.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Tao
Ye, Mao
Zhang, Jinling
Xu, Shuliang
Tang, Hailong
Wang, Xiangao
Zhang, Cheng
Jia, Jinming
Wang, Jing
Li, Hua
Li, Chenggong
Liu, Zhongmin
Abrégé
A regeneration device, a device for preparing low-carbon olefins, and a use thereof are provided. The regeneration device includes a first regenerator and a second regenerator; a first activation zone of the first regenerator is connected to the second regenerator through a pipeline, such that a catalyst in the first activation zone is able to be delivered to the second regenerator; and the second regenerator is connected to a gas-solid separation zone of the first regenerator through a pipeline, such that a catalyst in the second regenerator is able to be delivered to the gas-solid separation zone. The regeneration device can adjust the coke content, coke content distribution, and coke species in a dimethyl ether/methanol to olefins (DMTO) catalyst to control an operation window of the DMTO catalyst, which improves the selectivity for low-carbon olefins and the atomic economy of a methanol-to-olefins (MTO) technology.
B01J 38/06 - Traitement avec un gaz ou une vapeur; Traitement avec des liquides vaporisables au contact du catalyseur épuisé avec de la vapeur d'eau
B01J 38/14 - Traitement avec un gaz contenant de l'oxygène libre en réglant la teneur en oxygène dans le gaz d'oxydation
B01J 38/16 - Traitement avec un gaz contenant de l'oxygène libre le gaz d'oxydation étant essentiellement de la vapeur d'eau et de l'oxygène
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
B01J 8/28 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération superposés
B01J 8/00 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés
B01J 8/34 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" le lit fluidisé comportant un matériau de remplissage fixe, p.ex. matériaux fragmentés, anneaux métalliques, chicanes
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées
B01J 38/18 - Traitement avec un gaz contenant de l'oxygène libre suivi d'un traitement par un gaz réactif
75.
PALLADIUM MONATOMIC CATALYST, PREPARATION METHOD THEREFOR, AND APPLICATION THEREOF IN SUZUKI COUPLING REACTION
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Qiao, Botao
Guo, Yalin
Min, Xiangting
Jiang, Xunzhu
Zhang, Tao
Abrégé
The present invention relates to the technical field of catalysts, and relates to a magnesium oxide-loaded palladium monatomic catalyst, a preparation method therefor, and an application thereof in Suzuki coupling reaction. Metal active component palladium is dispersed on a carrier magnesium oxide in a monatomic form by using an impregnation method, the palladium monatomic catalyst of which the palladium monatomic loading amount is 0.01-5% of the total mass of the catalyst is obtained by roasting, and the preparation method is simple, convenient, safe, green, environment-friendly, and suitable for large-scale production. The obtained palladium monatomic catalyst has excellent catalytic performance on various Suzuki coupling reaction raw materials, has the remarkable advantages such as a high precious metal atom utilization rate, good stability, and low costs, and has good application prospects.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liu, Zhongmin
Yu, Zhengxi
Yang, Yue
Abrégé
2222 making contact with the modified molecular sieve catalyst in a reactor for reaction to form benzene, toluene, and p-xylene. The method overcomes the defects of limited hydrogen resources and high costs in the existing technology.
C07C 2/86 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant un plus petit nombre d'atomes de carbone par condensation d'un hydrocarbure et d'un non-hydrocarbure
C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p.ex. huiles, acides gras
C10G 35/095 - Réformage catalytique caractérisé par le catalyseur utilisé contenant des alumino-silicates cristallins, p.ex. des tamis moléculaires
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Tao
Ye, Mao
Zhang, Jinling
Xu, Shuliang
Tang, Hailong
Wang, Xiangao
Zhang, Cheng
Jia, Jinming
Wang, Jing
Li, Hua
Li, Chenggong
Liu, Zhongmin
Abrégé
A coke control reactor, a device for preparing low-carbon olefins from an oxygen-containing compound, and a use thereof are provided. The coke control reactor includes a riser reactor and a bed reactor; the bed reactor includes a bed reactor shell, and the bed reactor shell encloses a reaction zone I, a transition zone, and a gas-solid separation zone I from bottom to top; a bed reactor distributor is arranged in the reaction zone I; a coke controlled catalyst delivery pipe is arranged outside the reaction zone I; an upper section of the riser reactor penetrates through a bottom of the bed reactor and is axially inserted in the bed reactor; and an outlet end of the riser reactor is located in the transition zone. The coke control reactor can control the conversion and generation of coke species in a catalyst.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées
B01J 8/22 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées l'agent fluidisant étant un liquide du gaz étant introduit dans le liquide
B01J 8/26 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération
79.
CARBON DIOXIDE HYDROGENATION-BASED METHANOL PREPARATION CATALYST, AND PREPARATION METHOD THEREFOR AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Hu, Jingting
Abrégé
A carbon dioxide hydrogenation-based methanol preparation catalyst, and a preparation method therefor and the use thereof. A defect-rich thin-layer two-dimensional metal sulfide is synthesized by using a high-temperature and high-pressure solvothermal coupling reduction method for carbon dioxide hydrogenation-based methanol preparation, and rich defects enable the metal sulfide to have high carbon dioxide hydrogenation-based methanol preparation activity. The carbon dioxide hydrogenation-based methanol preparation catalyst can obtain relatively high activity and selectivity, and good stability, and has good industrial application prospects.
B01J 37/18 - Réduction avec des gaz contenant de l'hydrogène libre
C07C 29/153 - Préparation de composés comportant des groupes hydroxyle ou O-métal liés à un atome de carbone ne faisant pas partie d'un cycle aromatique à six chaînons par réduction exclusivement des oxydes de carbone avec de l'hydrogène ou des gaz contenant de l'hydrogène caractérisée par le catalyseur utilisé
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ye, Mao
Zhang, Tao
Zhang, Jinling
Xu, Shuliang
Tang, Hailong
Wang, Xiangao
Zhang, Cheng
Jia, Jinming
Wang, Jing
Li, Hua
Li, Chenggong
Liu, Zhongmin
Abrégé
A fluidized bed reactor, a device, and a method for producing low-carbon olefins from oxygen-containing compound are provided. The fluidized bed reactor includes a reactor shell, a reaction zone, a coke control zone and a delivery pipe, where there are n baffles arranged in the coke control zone, and the n baffles divide the coke control zone into n sub-coke control zones which include a first sub-coke control zone, a second sub-coke control zone, and an nth sub-coke control zone; at least one catalyst circulation hole is provided on each of the n-1 baffles, so that the catalyst flows in an annular shape in the coke control zone, where n is an integer. The device and method can be adapted to a new generation of DMTO catalyst, and the unit consumption of production ranges from 2.50 to 2.58 tons of methanol/ton of low-carbon olefins.
C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p.ex. huiles, acides gras
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées
C07C 1/24 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes par élimination d'eau
B01J 31/06 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques contenant des polymères
B01D 45/16 - Séparation de particules dispersées dans des gaz ou des vapeurs par gravité, inertie ou force centrifuge en utilisant la force centrifuge produite par le mouvement hélicoïdal du courant gazeux
81.
Coke control reactor, and device and method for preparing low-carbon olefins from oxygen-containing compound
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Tao
Ye, Mao
Zhang, Jinling
Xu, Shuliang
Tang, Hailong
Wang, Xiangao
Zhang, Cheng
Jia, Jinming
Wang, Jing
Li, Hua
Li, Chenggong
Liu, Zhongmin
Abrégé
A coke control reactor, and a device and method for preparing low-carbon olefins from an oxygen-containing compound are provided. The coke control reactor includes a coke control reactor shell, a reaction zone I, and a coke controlled catalyst settling zone; a cross-sectional area at any position of the reaction zone I is less than that of the coke controlled catalyst settling zone; n baffles are arranged in a vertical direction in the reaction zone I; the n baffles divide the reaction zone I into m reaction zone I subzones; and a catalyst circulation hole is formed in each of the baffles, such that a catalyst flows in the reaction zone I in a preset manner. A catalyst charge in the present coke control reactor can be automatically adjusted, and an average residence time of a catalyst in the coke control reactor can be controlled by changing process operating conditions.
B01J 8/00 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées
B01J 8/22 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées l'agent fluidisant étant un liquide du gaz étant introduit dans le liquide
B01J 8/26 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération
C07C 1/22 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes par réduction
C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p.ex. huiles, acides gras
82.
CATALYST FOR PYROLYSIS OF 1,2-DICHLOROETHANE (DCE) TO PREPARE VINYL CHLORIDE (VC) AND PREPARATION METHOD, USE, AND REGENERATION METHOD THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Liu, Guangye
Yuan, Danhua
Xu, Yunpeng
Liu, Zhongmin
Liu, Yanan
Bai, Changmin
Huang, Wei
Chen, Zhaoan
Li, Shiying
Abrégé
A catalyst for pyrolysis of 1,2-dichloroethane (1,2-DCE) to prepare vinyl chloride monomer (VCM), a preparation method, a use, and a regeneration method thereof are provided. The catalyst for pyrolysis of 1,2-DCE to prepare VCM includes a silicon-aluminum molecular sieve. The catalyst for pyrolysis of 1,2-DCE to prepare VCM has high reaction activity and excellent selectivity and solves the problem that the pyrolysis of 1,2-DCE to prepare VCM in the prior art involves high reaction temperature and large energy consumption and is prone to coking and carbon deposition.
B01J 29/08 - Zéolites aluminosilicates cristallines; Leurs composés isomorphes du type faujasite, p.ex. du type X ou Y
B01J 29/18 - Zéolites aluminosilicates cristallines; Leurs composés isomorphes du type mordénite
B01J 29/70 - Zéolites aluminosilicates cristallines; Leurs composés isomorphes de types caractérisés par leur structure spécifique non prévus dans les groupes
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ye, Mao
Zhang, Tao
Zhang, Jinling
Xu, Shuliang
Tang, Hailong
Wang, Xiangao
Zhang, Cheng
Jia, Jinming
Wang, Jing
Li, Hua
Li, Chenggong
Liu, Zhongmin
Abrégé
A fluidized bed reactor includes a main shell and a coke control zone shell; the main shell includes an upper shell and a lower shell; the upper shell encloses a gas-solid separation zone, and the lower shell encloses a reaction zone; the reaction zone axially communicates with the gas-solid separation zone; the coke control zone shell is circumferentially arranged on an outer wall of the main shell; the coke control zone shell and the main shell enclose an annular cavity, and the annular cavity is a coke control zone; n baffles are radially arranged in the coke control zone, and the n baffles divide the coke control zone into n coke control zone subzones, where n is an integer; the coke control zone subzones are provided with a coke control raw material inlet; and a catalyst circulation hole is formed in each of n−1 of the baffles.
B01J 8/26 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées
B01J 8/00 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés
C07C 1/22 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes par réduction
C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p.ex. huiles, acides gras
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ye, Mao
Zhang, Tao
Zhang, Jinling
Xu, Shuliang
Tang, Hailong
Wang, Xiangao
Zhang, Cheng
Jia, Jinming
Wang, Jing
Li, Hua
Li, Chenggong
Liu, Zhongmin
Abrégé
A fluidized bed regenerator, a device for preparing low-carbon olefins, and a use thereof are provided. The fluidized bed regenerator includes a second activation zone, a first activation zone, and a gas-solid separation zone from bottom to top; the second activation zone axially communicates with the gas-solid separation zone; the first activation zone is arranged on a periphery of a junction between the second activation zone and the gas-solid separation zone; the first activation zone is an annular cavity; n baffles are radially arranged in the first activation zone, and the n baffles divide the first activation zone into n first activation zone subzones; and a catalyst circulation hole is formed in each of n−1 of the baffles such that a catalyst entering the first activation zone flows in an annular direction.
B01J 8/26 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé" comportant au moins deux lits fluidisés, p.ex. installations de réaction et de régénération
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solides; Appareillage pour de tels procédés les particules étant fluidisées
B01J 38/34 - Traitement avec un gaz contenant de l'oxygène libre en suspension gazeuse, p.ex. lits fluidisés avec plusieurs étapes distinctes de combustion, en série
C07C 1/22 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes par réduction
86.
MONATOMICALLY DISPERSED PALLADIUM-BASED CATALYST, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ding, Yunjie
Feng, Siquan
Song, Xiangen
Li, Xingju
Abrégé
The present application discloses a monatomically dispersed palladium-based catalyst, a preparation method therefor and an application thereof. The monatomically dispersed palladium-based catalyst comprises a main catalytic active component and a carrier; the main catalytic active component is a palladium element; the carrier is activated carbon having a surface to which a sulfur-containing functional group is linked; the palladium element is monatomically dispersed in the palladium-based catalyst in the form of a mononuclear complex, and the mononuclear complex is anchored to the surface of the activated carbon by means of the sulfur-containing functional group. Because the noble metal Pd in the catalyst provided by the present invention is monatomically dispersed, the prepared catalyst has a very high utilization rate of metal atoms, can be used for preparing a but(ene)dioic acid diester, and has good catalytic activity and stability.
C07C 67/38 - Préparation d'esters d'acides carboxyliques par réaction avec du monoxyde de carbone ou des formiates par addition à une liaison non saturée carbone-carbone
C07C 57/02 - Composés non saturés comportant des groupes carboxyle liés à des atomes de carbone acycliques ne contenant que des liaisons doubles carbone-carbone comme insaturation
C07C 51/14 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par réaction avec du monoxyde de carbone sur une liaison non saturée carbone-carbone d'un composé organique
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Xianfeng
Xie, Congxin
Zhang, Huamin
Abrégé
The neutral zinc manganese battery includes a neutral zinc manganese flow battery and a power battery. The flow battery includes positive electrode, negative electrode, electrolyte and membrane. The corresponding flow battery includes positive and negative pumps, pipelines and storage tanks. For the power battery, the electrolyte is stored in the porous electrode, while for the flow battery, the positive and negative electrolyte flows through the positive and negative electrodes through the pump and pipeline and finally returns to the storage tank to realize the circulation of electrolyte in the electrode chamber and storage tank. In addition, the positive and negative electrode electrolyte is a neutral solution of zinc salt and manganese salt with specific composition. During charging, MnO2 of the positive electrode can be oxidized directly to α-MnO2. During discharge, MnO2 dissolves into Mn2+.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Tian, Peng
Zhu, Dali
Liu, Zhongmin
Wang, Linying
Zhang, Jianming
Zhao, Xuebin
Abrégé
Disclosed in the present application is a high-silica Y molecular sieve having FAU topology. The anhydrous chemical constitution of the molecular sieve is as shown in formula I: kM.mR1.nR2.(SixAly)O2 Formula I; wherein, M is at least one of alkali metal elements; R1 and R2 represent organic templating agent agents; k represents the numbers of moles of the alkali metal element corresponding to per mole of (SixAly)O2, k=0˜0.20; m and n represent the numbers of moles of templating agents R1 and R2 corresponding to per mole of (SixAly)O2, m=0˜0.20, n=0.01˜0.20; x, y respectively represents the mole fraction of Si and Al, 2x/y=7-40, and x+y=1; R1, R2 are independently selected from one of nitrogen-containing heterocyclic compounds and their derivatives, and quaternary ammonium compounds. Also disclosed in the present application is a synthesis method for the high-silica Y molecular sieve having FAU topology.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ye, Mingliang
Zhang, Xiaolei
Hu, Lianghai
Abrégé
A method of solvent-induced protein precipitation (SIP) for detecting the interaction of ligands with proteins in a complex protein sample. After the equal amount of solvent is added to the protein samples with and without a ligand to denature and precipitate the proteins, the protein abundances in supernatant and/or precipitate in the ligand group and the control group are measured by quantitative technology. The target protein(s) of a ligand is/are determined by comparing the differences of protein abundances in the ligand group and the control group. The affinity between a ligand and its targets can be evaluated by dose dependent experiments. This method does not require the chemical modification of the ligand and has the feature of high specificity. Furthermore, in certain embodiments, the targets identified by SIP method are complementary to those identified by thermal proteome profiling (TPP) method.
G01N 33/68 - Analyse chimique de matériau biologique, p.ex. de sang ou d'urine; Test par des méthodes faisant intervenir la formation de liaisons biospécifiques par ligands; Test immunologique faisant intervenir des protéines, peptides ou amino-acides
G01N 33/58 - Analyse chimique de matériau biologique, p.ex. de sang ou d'urine; Test par des méthodes faisant intervenir la formation de liaisons biospécifiques par ligands; Test immunologique faisant intervenir des substances marquées
90.
Method for partially regenerating catalyst for methanol and/or dimethyl ether-to-olefin and method for methanol and/or dimethyl ether-to-olefin
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Jinling
Ye, Mao
Liu, Zhongmin
Zhou, Jibin
Zhang, Tao
Wang, Xiangao
Tang, Hailong
Wang, Jing
Abrégé
Disclosed is a method for partially regenerating a catalyst for methanol and/or dimethyl ether-to-olefin. The method comprises: introducing a mixed gas into a regenerated region containing a catalyst to be regenerated, and subjecting same to a partial regeneration reaction to obtain a regenerated catalyst, wherein the mixed gas contains water vapor and air; and in the regenerated catalyst, the coke content of at least part of the regenerated catalyst is greater than 1%. The method utilizes the coupling of a mixed gas of water vapor and air to activate a deactivated catalyst, selectively eliminate part of a coke deposit in the catalyst to be regenerated, and obtain a partially regenerated catalyst for methanol-to-olefin. Another aspect of the present invention is that further provided is a method for methanol and/or dimethyl ether-to-olefin by using the partially regenerated catalyst for methanol-to-olefin regenerated by means of the method.
C07C 1/20 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir de composés organiques ne renfermant que des atomes d'oxygène en tant qu'hétéro-atomes
91.
NICKEL-IRON CATALYTIC MATERIAL, PREPARATION METHOD THEREFOR, AND USE THEREOF IN HYDROGEN PRODUCTION THROUGH WATER ELECTROLYSIS AND PREPARATION OF LIQUID SOLAR FUEL (LSF)
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Li, Can
An, Xiurui
Yao, Tingting
Wang, Jijie
Abrégé
A nickel-iron catalytic material, a preparation method thereof, and a use thereof in the hydrogen production through water electrolysis and the preparation of a liquid solar fuel (LSF) are provided. The nickel-iron catalytic material is prepared by using a soluble iron salt as a raw material and growing on a modified nickel substrate under mild conditions, and the nickel-iron catalytic material can be used in the industrial alkaline water electrolysis under harsh conditions. The nickel-iron catalytic material includes a nickel metal substrate and a catalytically-active layer with iron and nickel. When used to promote a water splitting reaction, the nickel-iron catalytic material can reduce the energy consumption per m3 of hydrogen production through industrial alkaline water electrolysis from 4.4 kWh to 4.01 kWh, thereby increasing the conversion of solar energy to methanol by 9.7%.
C25B 11/054 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par le matériau Électrodes comportant des électro-catalyseurs sur un substrat ou un support Électrodes comportant des électro-catalyseurs sur un support
C25B 1/04 - Hydrogène ou oxygène par électrolyse de l'eau
C25B 15/08 - Alimentation ou vidange des réactifs ou des électrolytes; Régénération des électrolytes
C25B 11/091 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Électrodes; Leur fabrication non prévue ailleurs caractérisées par le matériau Électrodes comportant des électro-catalyseurs sur un substrat ou un support caractérisées par le matériau électro-catalytique formé de plusieurs éléments catalytiques ou composés catalytiques
C07C 29/151 - Préparation de composés comportant des groupes hydroxyle ou O-métal liés à un atome de carbone ne faisant pas partie d'un cycle aromatique à six chaînons par réduction exclusivement des oxydes de carbone avec de l'hydrogène ou des gaz contenant de l'hydrogène
92.
METHOD FOR PREPARING GLYCOLIC ACID THROUGH HYDROLYSIS OF ALKOXYACETATE
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ni, Youming
Zhu, Wenliang
Liu, Zhongmin
Abrégé
The present application discloses a method for preparing glycolic acid through hydrolysis of alkoxyacetate. The method includes: subjecting raw materials including the alkoxyacetate and water to a reaction in the presence of an acidic molecular sieve catalyst to produce the glycolic acid, where the alkoxyacetate is at least one selected from the group consisting of compounds with a structural formula shown in formula I; and in formula I, Ri and R2 each are independently any one selected from the group consisting of C1-C5 alkyl groups. The glycolic acid production method in the present application can be implemented by a traditional fixed-bed reactor under an atmospheric pressure, which is very suitable for continuous production.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ni, Youming
Zhu, Wenliang
Liu, Zhongmin
Abrégé
Disclosed is a method for preparing glycolic acid and methyl glycolate by hydrolysis of methyl methoxyacetate and methoxyacetic acid. The method comprises: contacting a raw material comprising methyl methoxyacetate, methoxyacetic acid, and water with a catalyst, and reacting same to obtain glycolic acid and methyl glycolate, the catalyst being selected from at least one of a solid acid catalyst, a liquid acid catalyst, a solid base catalyst, and a liquid base catalyst. The production method for glycolic acid and methyl glycolate of the present application can be realized by using a conventional fixed bed reactor, a kettle reactor or a catalytic rectification reactor under normal pressure, and is very suitable for continuous production. According to the method of the present application, dimethoxymethane reaction is carried out by condensation of methanol and formaldehyde, and dimethoxymethane carbonylation is combined with methyl methoxyacetate, so that the product methanol on a coal chemical platform can be converted into glycolic acid and methyl glycolate in an efficient, green, and economic manner.
C07C 51/09 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides à partir de lactones ou d'esters d'acides carboxyliques
C07C 67/08 - Préparation d'esters d'acides carboxyliques par réaction d'acides carboxyliques ou d'anhydrides symétriques avec le groupe hydroxyle ou O-métal de composés organiques
C07C 69/145 - Esters d'acide acétique de composés monohydroxylés d'alcools non saturés
C07C 69/675 - Esters d'acides carboxyliques dont le groupe carboxyle estérifié est lié à un atome de carbone acyclique et dont l'un des groupes OH, O-métal, —CHO, céto, éther, acyloxy, des groupes , des groupes ou des groupes se trouve dans la partie acide d'acides saturés d'acides hydroxycarboxyliques saturés
94.
METHOD FOR PREPARING GLYCOLIC ACID BY HYDROLYSIS OF ALKOXYACETATE
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Ni, Youming
Zhu, Wenliang
Liu, Zhongmin
Abrégé
12155 alkyl groups. The glycolic acid production method in the present invention can be implemented by using a traditional fixed bed reactor under normal pressure, and is quite suitable for continuous production.
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
FORMOSA PLASTICS CORPORATION (Chine)
Inventeur(s)
Fan, Sisi
Xu, Jinming
Huang, Yanqiang
Duan, Hongmin
Zhang, Tao
Cheng, Ming-Hung
Hung, Wan-Tun
Chen, Yu-Cheng
Wu, Chien-Hui
Cheng, Ya-Wen
Wen, Ming-Hsien
Chang, Chao-Chin
Huang, Tsao-Cheng
Yeh, Lu-Chen
Abrégé
A regeneration method of a nitrogen-containing carbon catalyst includes the following steps: roasting the nitrogen-containing carbon catalyst in a nitrogen-containing atmosphere to obtain a regenerated nitrogen-containing carbon catalyst. The method is a universal method, which is suitable for nitrogen-doped carbon catalysts and can be used to regenerate a nitrogen-containing carbon catalyst for producing vinyl chloride (VC) through 1,2-dichloroethane cracking. The method can greatly reduce the production cost of the catalyst and increase the service life of the catalyst, and a regeneration process thereof is fast, simple, and controllable, and does not require high temperatures.
B01J 38/08 - Traitement avec un gaz ou une vapeur; Traitement avec des liquides vaporisables au contact du catalyseur épuisé avec de l'ammoniac ou ses dérivés
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Wang, Suli
Xia, Zhangxun
Sun, Gongquan
Abrégé
An electrode material of a fibrous structure, has a platinum-based electrocatalytic material, an electrospinning polymer material, and an oxide material and/or one or more organophosphorus acid material with ion conduction. In the micromorphology has the structure of nanofibers, but also has porous morphological characteristics, the electrode material of this structure is prepared by electrostatic spinning technology, can be used as a high-temperature polymer electrolyte membrane fuel cell porous electrode.
H01M 4/86 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Électrodes Électrodes inertes ayant une activité catalytique, p.ex. pour piles à combustible
D01F 9/08 - Filaments, ou similaires, faits par l’homme, formés d’autres substances; Leur fabrication; Appareils spécialement adaptés à la fabrication de filaments de carbone de matière inorganique
D01D 5/00 - Formation des filaments, fils ou similaires
97.
COIL-TO-COIL CONTINUOUS COATING MACHINE FOR CCM PREPARATION, AND COILED MATERIAL JOINING METHOD
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Zhang, Hongjie
Hao, Jinkai
Shao, Zhigang
Abrégé
A coil-to-coil continuous coating machine for CCM preparation, and a coiled material joining method. The coating machine comprises a coiled material joining mechanism. The coiled material joining mechanism comprises an upper stage (2) and a lower stage (3), wherein a vacuum suction plate I (2-3), which is provided with a driving device for achieving displacement, and a vacuum suction plate II (3-1), which is provided with a solid adhesive spraying device (3-3), are respectively disposed on the bottom portion of the upper stage (2) and the top portion of the lower stage (3); an optical fiber sensor I (2-4) and an optical fiber sensor II (3-2) are respectively disposed in the vacuum suction plate I (2-3) and the vacuum suction plate II (3-1); and a tension force measurement device (4) is disposed between the lower stage (3) and a transmission roll assembly (1).
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Hao, Jinkai
Zhang, Hongjie
Shao, Zhigang
Abrégé
Disclosed in the present invention is a CCM coating process for realizing swelling resistance by using a protective back membrane, comprising: coating a first surface of a proton exchange membrane with a catalyst slurry, and performing drying to form a first catalyst layer; preparing a protective membrane having a flexible carrier layer, attaching a layer of protective membrane having the flexible carrier layer to the first surface of the proton exchange membrane containing the first catalyst layer, and laminating the protective membrane and the proton exchange membrane; coating a second surface of the proton exchange membrane with a catalyst slurry, and performing drying to form a second catalyst layer, so as to obtain a membrane electrode having a temporary protective membrane; and finally, performing heat treatment or ultraviolet (UV) irradiation on the membrane electrode having the temporary protective membrane, and stripping the temporary protective layer to obtain the membrane electrode, if the heat treatment is selected, a nano oxide solution needing to be sprayed on the surface of the first catalyst layer before the first catalyst layer is dried. According to the present invention, the swelling of the proton exchange membrane is effectively avoided in the membrane electrode preparation process, the preparation process is simple, the production efficiency is high, and the battery performance is excellent.
B82Y 40/00 - Fabrication ou traitement des nanostructures
B82Y 30/00 - Nanotechnologie pour matériaux ou science des surfaces, p.ex. nanocomposites
H01M 8/1004 - PROCÉDÉS OU MOYENS POUR LA CONVERSION DIRECTE DE L'ÉNERGIE CHIMIQUE EN ÉNERGIE ÉLECTRIQUE, p.ex. BATTERIES Éléments à combustible; Leur fabrication Éléments à combustible avec électrolytes solides caractérisés par les ensembles membrane-électrodes [MEA]
99.
NEW PROTECTIVE FILM, BATCH PREPARATION METHOD THEREFOR AND USE THEREOF
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Hao, Jinkai
Zhang, Hongjie
Shao, Zhigang
Abrégé
Disclosed are a new protective film, a batch preparation method therefor and the use thereof in a fuel cell. The protective film sequentially comprises a release protective film, a low-viscosity silica gel layer, a high-viscosity silica gel layer and a substrate from top to bottom. A high-viscosity organosilicon adhesive, a hydroxyl-terminated polydimethylsiloxane, a curing agent, an additive and a solvent are taken and stirred until uniform, and a polyester thin film is coated with same; a low-viscosity organosilicon adhesive, the hydroxyl-terminated polydimethylsiloxane, the curing agent, the additive and the solvent are taken and stirred until uniform, and the polyester thin film complex is coated with same; same is pressed with the release protective film to obtain a silica gel protective film for a fuel cell. A proton exchange membrane is coated with a catalyst to form a first catalyst layer, the protective film is adhered to the surface of the first catalyst layer, the second side of the proton exchange membrane is coated, and the silica gel protective film is stripped after the coating is finished to obtain a CCM for a fuel cell. The protective film prepared in the present invention has a simple production process and a high production efficiency, and the integrity of the catalyst layer cannot be damaged during stripping.
C09J 7/25 - Matières plastiques; Matières plastiques métallisées à base de composés macromoléculaires obtenus par des réactions autres que celles faisant intervenir uniquement des liaisons non saturées carbone-carbone
C09J 7/30 - Adhésifs sous forme de films ou de pellicules caractérisés par la composition de l’adhésif
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES (Chine)
Inventeur(s)
Deng, Dehui
Liu, Yanting
Bo, Xin
Shu, Yunmao
Abrégé
Provided is a compact portable oxyhydrogen device, comprising a housing, an end cover fastened on the upper end of the housing and used for discharging gas, and a bottom cover fastened at the lower end of the housing. A battery module used for supplying power, an electrolytic cell module used for generating a hydrogen/oxygen gas mixture, a water filtration cell used for filtering moisture, and a multi-stage filtering baffle for further filtering the gas are sequentially arranged in the housing from bottom to top. A flame retardant core is provided between the filtering baffle at the top layer and a gas outlet provided in the end cover, wherein the multi-stage filtering baffle is provided according to requirements of a gas filtering index. In the present invention, water is used as a reaction raw material, an inexpensive inorganic salt is used as an electrolyte, such that an atmospheric-pressure hydrogen/oxygen mixed gas may be directly generated, and can be produced when needed. The present solution is high in safety and has characteristics such as small volume, light weight, low energy consumption, low costs, safe and noise free, and is simple in structure, high in practicability, and is portable.
C25B 1/044 - Hydrogène ou oxygène par électrolyse de l'eau produisant un mélange de gaz d'hydrogène et d'oxygène, p.ex. oxyhydrogène
B01D 46/00 - Filtres ou procédés spécialement modifiés pour la séparation de particules dispersées dans des gaz ou des vapeurs
B01D 50/00 - Combinaisons de procédés ou de dispositifs pour la séparation de particules de gaz ou de vapeurs
C25B 9/00 - PROCÉDÉS ÉLECTROLYTIQUES OU ÉLECTROPHORÉTIQUES POUR LA PRODUCTION DE COMPOSÉS ORGANIQUES OU MINÉRAUX, OU DE NON-MÉTAUX; APPAREILLAGES À CET EFFET Éléments de structure des cellules; Assemblages d'éléments de structure, p.ex. assemblages d'électrode-diaphragme; Caractéristiques des cellules relatives aux procédés