MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Zha, Charles
Beetge, Jan
Abrégé
Some implementations of the present disclosure prevent, reduce or at least slow equipment fouling using passivation as a treatment prior to contacting metallic components with hydrocarbon containing fluid, that is, an environment where fouling occurs. For example, one implementation includes a method of passivating heat exchangers in a SAGD process or system using the compositions and compounds of the present disclosure. The composition may be applied to a component prior to its first inclusion in an online system or following placing the system offline for maintenance. The composition may be used to treat metallic equipment surface(s), for example, via contacting them with a suspension or solution of the composition described herein, prior placing the system online. The method may further include treatment of the process fluid, for example, via injection or batch treatment of the composition with the compositions described herein into the process fluid.
C07D 233/04 - Composés hétérocycliques contenant des cycles diazole-1, 3 ou diazole-1, 3 hydrogéné, non condensés avec d'autres cycles comportant une liaison double entre chaînons cycliques ou entre chaînon cyclique et chaînon non cyclique
C07D 233/08 - Composés hétérocycliques contenant des cycles diazole-1, 3 ou diazole-1, 3 hydrogéné, non condensés avec d'autres cycles comportant une liaison double entre chaînons cycliques ou entre chaînon cyclique et chaînon non cyclique avec uniquement des atomes d'hydrogène ou des radicaux ne contenant que des atomes d'hydrogène et de carbone, liés directement aux atomes de carbone du cycle avec des radicaux alkyle, contenant plus de quatre atomes de carbone, liés directement aux atomes de carbone du cycle
C07D 233/12 - Composés hétérocycliques contenant des cycles diazole-1, 3 ou diazole-1, 3 hydrogéné, non condensés avec d'autres cycles comportant une liaison double entre chaînons cycliques ou entre chaînon cyclique et chaînon non cyclique avec uniquement des atomes d'hydrogène ou des radicaux ne contenant que des atomes d'hydrogène et de carbone, liés directement aux atomes de carbone du cycle avec des radicaux alkyle, contenant plus de quatre atomes de carbone, liés directement aux atomes de carbone du cycle avec des radicaux hydrocarbonés substitués, liés aux atomes d'azote du cycle
2.
NOVEL ALKYLPHENOL RESINS AND A METHOD OF PREPARING THEREOF
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Reddy, Ashok, T.
Willman, Justyne, Marie
Abrégé
Compositions, methods, and resins using alkyl aldehydes and phenols are provided herein. In one embodiment, a composition comprising an alkylphenol resin can be prepared by condensing at least one phenolic monomer selected from the group consisting of phenol, cresol, resorcinol, xylenol, ethyl phenol, alkylresorcinols, and combinations thereof; and at least one alkyl aldehyde having from 5 to 12 carbon atom alkyl groups. The alkylphenol resins of the application are free of octylphenol or nonylphenol monomers. In one embodiment, the alkylphenol resins may be prepared using formaldehyde, and alternatively, in another embodiment, the alkylphenol resins may be prepared without the use of formaldehyde. The process to make these new alternative alkylphenol resins is a cost effective process and easy to scale-up.
C08K 5/09 - Acides carboxyliquesLeurs sels métalliquesLeurs anhydrides
C08G 8/10 - Polymères de condensation obtenus uniquement à partir d'aldéhydes ou de cétones avec des phénols d'aldéhydes de formaldéhyde, p. ex. de formaldéhyde formé in situ avec du phénol
C08L 21/00 - Compositions contenant des caoutchoucs non spécifiés
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Lai, Zhen
Jacobson, Richard, R.
Saboia, Gilberto, Edson Ferreira
Nuila, Carlos
Abrégé
A diesel fuel and additive mixture is useful for reducing particulate matter emissions while improving or at least not aggravating oxidative stability during combustion. The additive includes at least one compound having a general formula selected from the group consisting of : (1) and combinations thereof, wherein: R is a saturated or unsaturated hydrocarbon having from about 1 to about 6 carbons. The additive is effective in diesel at concentrations as low as from about 50 to about 1000 ppm by weight.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Dowden, Adam, Daniel
Wren, Harden, Christopher
Miller, Todd, Ross
Abrégé
Polymeric materials and methods for making the polymeric materials utilizing bisphenolic stillbottoms, lignosulfonates, or both are disclosed. In one embodiment, a polymer is provided that includes a condensate of bisphenolic stillbottoms, an optional phenolic compound independent of bisphenolic stillbottoms, an aldehyde, and a lignosulfonate compound. The condensate may further include an amino compound, a catalyst, or combinations thereof. Alternatively, the polymer may be free of a phenolic compound independent of bisphenolic stillbottoms. The polymers may be used in the manufacture of articles including composites, laminates and paper products.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Shirrell, Charles, David
Abrégé
A thermosettable epoxy resin composition having, as components: (1) an epoxy resin; (2) an epoxidized cycloaliphatic dicyclopentadiene phenolic resin; (3) a liquid oligomeric butadiene homopolymer; and (4) a curing agent including one or more alkylphenol novolac resins or alkyphenol co-novolac resins, and one or more poly(2,6-dimethyl-1,4-phenylene oxides), which resin composition may be used to prepare composites, prepregs, or laminates.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Guo, Jong, S.
Abrégé
Disclosed are pressure sensitive adhesive compositions having enhanced water resistance and adhesion properties, which compositions include 70-99 wt% of an acrylic polymer dispersion and 1-30 wt% of a polyolefm dispersion. The acrylic polymer dispersion includes (1) one or more acrylic acid ester or (meth)acrylate acid ester(s), (2) one or more hydrocarbon monomer(s), (3) one or more ethylenically unsaturated carboxylic acid(s), (4) one or more nitrile(s) or amide(s) of an ethylenically unsaturated carboxylic acid(s), (5) one or more vinyl ester(s) of a carboxylic acid(s), optionally (6) one or more nitrogen containing acetoacetoxy functional compound(s), and optionally (7) one or more mercaptan chain transfer agent(s), and the polyolefm dispersion includes one or more polyolefins, which may or may not contain acid functionality.
C09J 133/00 - Adhésifs à base d'homopolymères ou de copolymères de composés possédant un ou plusieurs radicaux aliphatiques non saturés, chacun ne contenant qu'une seule liaison double carbone-carbone et l'un au moins étant terminé par un seul radical carboxyle, ou ses sels, anhydrides, esters, amides, imides ou nitrilesAdhésifs à base de dérivés de tels polymères
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Wantling, Steven, J.
Abrégé
Disclosed are bonding or binding compositions useful in stabilizing or modifying soil as a sub-base. Specifically, bonding or binding agent compositions of the invention include a first emulsion containing a wax, and a second emulsion containing a film forming polymer.
C09D 129/04 - Alcool polyvinyliqueHomopolymères ou copolymères partiellement hydrolysés d'esters d'alcools non saturés avec des acides carboxyliques saturés
C09D 131/04 - Homopolymères ou copolymères de l'acétate de vinyle
8.
AQUEOUS POLYURETHANE DISPERSION DERIVED FROM TERTIARY ALKYL GLYCIDYL ESTERS
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Steinbrecher, Christophe
Heymans, Denis
Erdem, Bedri
O'Shaughnessy, Mike
Blaisdell, Jeff (habb Co)
Mueller, Gerhard
Abrégé
This invention relates to a Waterborne Polyurethane Dispersions (WPU) derived from the reaction products of tertiary alkyl glycidyl esters based hydroxyl terminal polyester polyols with polyisocyanates and chain extended with poly-functional amines and dispersed in water have shown the surprising inherent ability for self-coalescence. Furthermore the cured films have shown improved hardness and abrasion resistance over these benchmarks with a significant reduction in coalescing solvent needed to accomplish film formation.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Wantling, Steven, J.
Abrégé
Disclosed are wax emulsion compositions for curing or sealing concrete and cement formulations, methods for preparing and processes for using the same. The modifiers are applicable to curing or sealing membranes, used in roadways, highways, parking lots and other freshly placed or poured concrete surfaces to retain moisture and achieve high compressive strengths. This invention also relates to materials used to coat, spray, brush, roll, etc. on conventional Portland cement concrete mix designs or other applied concrete mixes in formed structural shapes and transport road mix designs, providing an effective layer that controls and minimizes moisture loss from the mix to enable proper curing and achievement of desired compressive strengths.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heine, Françoise M L
Van Poppel, Karin
Rans, Marc, J.
Wauters, Nathalie
Abrégé
The process to prepare a storage stable aqueous co-dispersion of epoxy resins and at least a silane oligomer is given. This aqueous co-dispersion of epoxy resins with a silane as part A, of a curable paint composition in which the part B comprises a hardener and optionally pigments and additives. This epoxy resins with the silane provide equal performance even after several months' storage.
C08J 3/05 - Production de solutions, dispersions, latex ou gel par d'autres procédés que ceux utilisant les techniques de polymérisation en solution, en émulsion ou en suspension dans un milieux aqueux à partir de polymères solides
C08J 3/07 - Production de solutions, dispersions, latex ou gel par d'autres procédés que ceux utilisant les techniques de polymérisation en solution, en émulsion ou en suspension dans un milieux aqueux à partir de solutions de polymères
C09D 163/00 - Compositions de revêtement à base de résines époxyCompositions de revêtement à base de dérivés des résines époxy
C09D 183/06 - Polysiloxanes contenant du silicium lié à des groupes contenant de l'oxygène
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Loy, Terry D.
Abrégé
Composites and methods for manufacturing composites are provided herein. In one embodiment, a composite structure is provided including a resin composite material and a surface layer disposed on the resin composite material, wherein the surface layer comprises a phenolic resin. In another embodiment, a vessel comprising a composite overwrapped vessel may be improved in regard to high temperature performance by applying thereto a surface layer comprising a phenolic resin.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Reddy, Ashok, T.
Wentworth, Joseph, E.
Abrégé
Polymeric materials, methods for making the polymeric materials, and photoresist formulations utilizing the polymeric materials are disclosed. In one aspect, a polymeric material is provided including a condensation product of a reaction mixture comprising an aldehyde with a phenolic monomer composition comprising m-cresol, p-cresol, 3,5- dimethyl phenol, and 2,5-dimethyl phenol. The polymeric material may be further contacted with a photoactive compound and a solvent to form a photoresist fomiulation.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Zhang, Yingchao
Subrayan, Raman, C.
Malhotra, Vinay
Snover, David, A.
Abrégé
Polyester materials, methods for making polyesters materials, and uses of the polyester materials in binder materials and articles of manufacture are disclosed. In one embodiment, a process is provided for preparing a polyester solution, including mixing monomers of at least one organic acid containing at least three carboxylic groups and at least one multi-hydroxyl alcohol containing at least three hydroxyl groups to form a reaction mixture, heating the reaction mixture to a first temperature, polymerizing the monomers at the first temperature until reaching an acid value from about 200 to about 400 mg KOH/g, adjusting the temperature to a second temperature less than the first temperature, and forming the polyester solution. The polyester materials may be mixed with cross-linking materials to form binder materials. The binder material may then be used to form articles of manufacture.
C08F 283/04 - Composés macromoléculaires obtenus par polymérisation de monomères sur des polymères prévus par la sous-classe sur des polycarbonamides, des polyesteramides ou des polyimides
C08G 63/12 - Polyesters dérivés soit d'acides hydroxycarboxyliques, soit d'acides polycarboxyliques et de composés polyhydroxylés dérivés d'acides polycarboxyliques et de composés polyhydroxylés
C08G 64/14 - Polycarbonates aromatiques ne contenant pas d'insaturations aliphatiques contenant un agent d'arrêt de chaîne ou un agent de réticulation
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Zhang, Yingchao
Subrayan, Raman, C.
Malhotra, Vinay
Snover, David, A.
Abrégé
Polyester materials, methods for making polyesters materials, and uses of the polyester materials in binder materials and articles of manufacture are disclosed. In one embodiment, a process is provided for preparing a polyester solution, including mixing monomers of at least one organic acid containing at least three carboxylic groups and at least one multi-hydroxyl alcohol containing at least three hydroxyl groups to form a reaction mixture, heating the reaction mixture to a first temperature, polymerizing the monomers at the first temperature until reaching an acid value from about 200 to about 400 mg KOH/g, adjusting the temperature to a second temperature less than the first temperature, and forming the polyester solution. The polyester materials may be mixed with cross-linking materials to form binder materials. The binder material may then be used to form articles of manufacture.
C08G 63/12 - Polyesters dérivés soit d'acides hydroxycarboxyliques, soit d'acides polycarboxyliques et de composés polyhydroxylés dérivés d'acides polycarboxyliques et de composés polyhydroxylés
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Develder, Helga
Leroy, Alain
Riviere, Jean
Ruehle, Eckard
Abrégé
This invention relates to epoxy resin formulations for preforms to be used in molding processes, especially resin transfer molding processes and to methods for preparing the performs. The epoxy formulation is based on liquid or solid epoxy resins blended, with medium to high molecular weight, phenoxy resins. These formulations are highly compatible with epoxy curable injection resins, and more over are reacted in the polymeric matrix, without reducing the glass transition temperature (Tg) of the cured composite material.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BEIGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Abrégé
The invention relates to epoxy compositions comprising a mixture of α,α-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is maximum 55%, preferably below 40%, and most preferably below 30% weight on total composition.
C08G 59/36 - Composés époxydés contenant au moins trois groupes époxyde en mélange avec des composés mono-époxydés
C08G 65/22 - Éthers cycliques possédant en dehors du cycle au moins un atome autre que le carbone et l'hydrogène
C07D 303/16 - Composés contenant des cycles oxirane avec des radicaux hydrocarbonés, substitués par des atomes d'oxygène liés par des liaisons simples ou doubles par des radicaux hydroxyle estérifiés
C08L 63/00 - Compositions contenant des résines époxyCompositions contenant des dérivés des résines époxy
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Abrégé
The invention relates to epoxy compositions comprising a mixture of α,α-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.
C07D 303/16 - Composés contenant des cycles oxirane avec des radicaux hydrocarbonés, substitués par des atomes d'oxygène liés par des liaisons simples ou doubles par des radicaux hydroxyle estérifiés
C08G 59/36 - Composés époxydés contenant au moins trois groupes époxyde en mélange avec des composés mono-époxydés
C08G 59/00 - Polycondensats contenant plusieurs groupes époxyde par moléculeMacromolécules obtenues par réaction de polycondensats polyépoxydés avec des composés monofonctionnels à bas poids moléculaireMacromolécules obtenues par polymérisation de composés contenant plusieurs groupes époxyde par molécule en utilisant des agents de durcissement ou des catalyseurs qui réagissent avec les groupes époxyde
C08L 63/00 - Compositions contenant des résines époxyCompositions contenant des dérivés des résines époxy
C08G 65/22 - Éthers cycliques possédant en dehors du cycle au moins un atome autre que le carbone et l'hydrogène
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Abrégé
The invention relates to compositions of hydroxyl functional acrylic resins (acrylic polyols) comprising a mixture of α,α- branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Abrégé
The invention relates to compositions of polyester polyol resins comprising a mixture of α,α-branched alkane carboxylic acids glycidyl esters with a defined isomeric composition where the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.
C08L 67/00 - Compositions contenant des polyesters obtenus par des réactions créant une liaison ester carboxylique dans la chaîne principaleCompositions contenant des dérivés de tels polymères
20.
BONDING AGENTS FOR FUEL PRODUCTS, METHODS OF THEIR PREPARATION AND PRODUCTS PRODUCED THEREWITH
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Wantling, Steven, J.
Cargill, Kenneth
Wren, Harden, Christopher
Keating, Eileene
Abrégé
Disclosed are bonding agents useful in the production of pelletized or briquetted fuels. The bonding agents may be incorporated into a feed containing the fuel material, providing both adhesion and cohesion of the fines to produce a uniform and predictable pellet or briquette. Specifically, the bonding composition contains a solubulized starch, a sugar source and/or a diol or polyol compound, and optionally a polymer selected from polyvinyl alcohol (PVOH), PVOH copolymers, polyvinyl acetate (PVA), polyvinyl acetate copolymers (PVAc), ethylene vinyl acetate (EVAc or VAE) or any subset or combination of such polymers. Also disclosed are methods of preparing the bonding agents and to densified and/or torrefied biomass products prepared therewith.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Abrégé
The invention relates to compositions of hydroxyl functional acrylic resins (acrylic polyols) comprising a mixture of α,α-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is maximum 55%, preferably below 40%, and most preferably below 30% weight on total composition.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BEIGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Abrégé
The invention relates to compositions of polyether polyol resins (hydroxyfunctional oligo or poly ether) comprising a mixture of α,α-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is maximum 55%, preferably below 40%, and most preferably below 30% weight on total composition.
C08G 65/22 - Éthers cycliques possédant en dehors du cycle au moins un atome autre que le carbone et l'hydrogène
C08L 71/00 - Compositions contenant des polyéthers obtenus par des réactions créant une liaison éther dans la chaîne principaleCompositions contenant des dérivés de tels polymères
C08L 67/00 - Compositions contenant des polyesters obtenus par des réactions créant une liaison ester carboxylique dans la chaîne principaleCompositions contenant des dérivés de tels polymères
C09D 171/00 - Compositions de revêtement à base de polyéthers obtenus par des réactions créant une liaison éther dans la chaîne principaleCompositions de revêtement à base de dérivés de tels polymères
C09D 167/00 - Compositions de revêtement à base de polyesters obtenus par des réactions créant une liaison ester carboxylique dans la chaîne principaleCompositions de revêtement à base de dérivés de tels polymères
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Abrégé
The invention relates to compositions of polyether polyol resins (hydroxyfunctional oligo or poly ether) comprising a mixture of α,α-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.
C08L 67/00 - Compositions contenant des polyesters obtenus par des réactions créant une liaison ester carboxylique dans la chaîne principaleCompositions contenant des dérivés de tels polymères
C08G 65/00 - Composés macromoléculaires obtenus par des réactions créant une liaison éther dans la chaîne principale de la macromolécule
24.
PROPPANT MATERIALS AND METHODS OF TAILORING PROPPANT MATERIAL SURFACE WETTABILITY
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGUIM S.A. (Belgique)
Inventeur(s)
Green, John, William
Terracina, John, Mario
Borges, Jerry, Francis
Spillars, Scott, Edward
Mah, Samantha, Huixian
Abrégé
Embodiments of the invention are directed to materials suitable for use as proppant materials. Proppant materials, and methods for making proppant materials, are provided. In one embodiment, the proppant material comprises a substrate material, a polymeric material disposed on the substrate material and a surface wettability modifier disposed on the polymeric material. Methods of making and using the proppant materials are also disclosed.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Wantling, Steven, J.
Holder, Jason, L.
Wren, Harden, Christopher
Abrégé
Emulsions, and processes for making the emulsions, useful for imparting water resistance to gypsum products are disclosed. Process for making the emulsion and gypsum products made from the emulsion are also disclosed. The emulsions of the invention include at least one paraffin wax and a hydrophilic metallic salt. The emulsions of the invention may further include a saponifiable wax substitute for montan wax. The emulsions of the invention may further include a biocide.
C04B 20/00 - Emploi de matières comme charges pour mortiers, béton ou pierre artificielle prévu dans plus d'un groupe et caractérisées par la forme ou la répartition des grainsTraitement de matières spécialement adapté pour renforcer leur propriétés de charge dans les mortiers, béton ou pierre artificielle prévu dans plus d'un groupe de Matières expansées ou défibrillées
26.
COMPOSITIONS, EMULSIONS, AND METHODS FOR MAKING COMPOSITIONS AND EMULSIONS
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Romero-Nochebuena, Eduardo
Sheth, Paresh Jaswantlal
Holder, Jason Lee
Wren, Harden Christopher
Danvers, Michael Bruce
Abrégé
Compositions and methods for making compositions useful for imparting water resistance to gypsum products are disclosed. Processes for making gypsum products made from an emulsion of the composition are also disclosed. The compositions of the invention include at least one paraffin wax, a saponifiable wax, and a styrene-maleic anhydride copolymer. The composition may further include water and be in the form of an emulsion.
C04B 20/00 - Emploi de matières comme charges pour mortiers, béton ou pierre artificielle prévu dans plus d'un groupe et caractérisées par la forme ou la répartition des grainsTraitement de matières spécialement adapté pour renforcer leur propriétés de charge dans les mortiers, béton ou pierre artificielle prévu dans plus d'un groupe de Matières expansées ou défibrillées
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Wantling, Steven, J.
Holder, Jason, L.
Wren, Harden, Christopher
Romero Nochebuena, Eduardo
Abrégé
Compositions for dust suppression, methods for forming the compositions, and methods for using the compositions are provided. In one embodiment, the composition includes at least a binding agent. The composition may be in the form of an emulsion. The compositions may be applied to an exposed surface of a substrate to suppress or mitigate fugitive dust therefrom.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Kapellen, Mark
Van Den Berg, Bart
Muppa, Prasad
Haesakkers, Paul
Abrégé
Apparatus and methods are provided for forming and processing multiphasic systems. In one embodiment, the invention provides a process for the manufacture of an epoxide, including reacting an olefinically unsaturated compound with an oxidant in the presence of a buffer component and a water-soluble manganese complex disposed in an aqueous phase having a first pH level in a first multiphasic system, adjusting the pH of the aqueous phase to a second pH level less than the first pH level, isolating at least a portion of the aqueous phase from the first multiphasic system, adjusting the pH of the at least a portion of the aqueous phase to a third pH level greater than the second pH level, and introducing the at least a portion of the aqueous phase into a second multiphasic system.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Havaux, Nathalie
Simal, François
Kameneva, Olga
Abrégé
This invention relates to a copolymer composition comprising vinyl ester of 2-ethyl hexanoic acid (VEHA), and particularly to pressure-sensitive adhesive compositions based on VEHA reacted with (meth) acrylate monomers. The present adhesive compositions provide a film with high cohesion and adhesion values, and more particularly to pressure-sensitive adhesive compositions based on VEHA reacted with (meth) acrylate monomers and VeoVa 10. The present adhesive compositions provide a film with high cohesion and adhesion values with Peel on Teflon of at least 2N/inch.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Abrégé
The invention relates to a process for the manufacture of α,α- branched carboxylic acids vinyl esters comprising the following steps: - isomerising and converting an olefin feed with CO and water under Koch reaction conditions to make an acid with a ratio of Non Blocking isomers (NB) versus Blocking isomers (B) of NB/B above 1.5, wherein a blocking isomer has always a tertiary carbon atom in alpha position of the carboxylic acid and in the beta position of the carboxylic acid, whereas a non-blocking isomer has primary carbon atoms in the beta position of the carboxylic acid - converting the resulting acid into a vinyl ester.
C07C 51/14 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par réaction avec du monoxyde de carbone sur une liaison non saturée carbone-carbone d'un composé organique
C07C 67/04 - Préparation d'esters d'acides carboxyliques par réaction d'acides carboxyliques ou d'anhydrides symétriques sur des liaisons carbone-carbone non saturées
C07C 69/24 - Esters d'acides acycliques monocarboxyliques saturés dont le groupe carboxyle est lié à un atome de carbone acyclique ou à l'hydrogène avec au moins trois atomes de carbone dans la partie acide estérifiés par des composés monohydroxylés
C07C 53/128 - Acides contenant au moins cinq atomes de carbone le groupe carboxyle étant lié à un atome de carbone lié lui-même à plusieurs autres atomes de carbone, p. ex. néo-acides
C08F 8/00 - Modification chimique par post-traitement
C08F 18/10 - Esters vinyliques d'acides monocarboxyliques contenant au moins trois atomes de carbone
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Briner, Gregory, D.
Romero, Eduardo
Nuila, Carlos, E.
Abrégé
A wax extender may be employed in the manufacture of particle board, and oriented strand board to reduce the content of the wax in favor of a copolymer prepared by copolymerizing vinyl acetate with a hydrophobic reactive comonomer. The hydrophobic reactive comonomer may have the general formula (I): wherein R1 is a hydrophobic group having from about 4 to about 25 carbons; and R2, R3 and R4 are independently hydrogen or a methyl group subject to the limitation that at least one of these is hydrogen.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Simal, François
Vanaken, David
Wang, Jijun
Abrégé
Polymer compositions for elastomeric coatings or sealants provide excellent balance properties between elongation to break, early water resistance, alkaline resistance and adhesion on unpolar substrates. The composition is free of volatile and toxic monomer such as acrylonitrile, or substituted acrylonitrile.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Van'T Sand, Robert
Heymans, Denis
Kotlewska, Aleksandra
Abrégé
The invention relates to compositions of a, a-branched alkane carboxylic acids glycidyl esters with a defined isomeric composition where the sum of the concentration of the blocked and of the highly branched isomers is maximum 55% preferably below 40%, and most preferably below 30%. The mixture of neononanoic acid glycidyl esters comprising at least 2,2-dimethyl heptanoic acid glycidyl ester and 2- methyl 2-ethyl hexanoic acid glycidyl ester and 2-methyl 2-ethyl 3-methyl pentanoic acid glycidyl esters.
C07D 303/16 - Composés contenant des cycles oxirane avec des radicaux hydrocarbonés, substitués par des atomes d'oxygène liés par des liaisons simples ou doubles par des radicaux hydroxyle estérifiés
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Steinbrecher, Christophe
Le Fevere De Ten Hove, Cédric
Van'T Sand, Robert
Heymans, Denis
Kotlewska, Aleksandra
Abrégé
The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters with a define isomeric composition where the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.
C07D 303/16 - Composés contenant des cycles oxirane avec des radicaux hydrocarbonés, substitués par des atomes d'oxygène liés par des liaisons simples ou doubles par des radicaux hydroxyle estérifiés
C08G 18/00 - Polymérisats d'isocyanates ou d'isothiocyanates
C09D 163/00 - Compositions de revêtement à base de résines époxyCompositions de revêtement à base de dérivés des résines époxy
35.
IMPROVED EPOXY SYSTEMS AND AMINE POLYMER SYSTEMS AND METHODS FOR MAKING THE SAME
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Elmore, Jim, D.
Corley, Larry, Steven
Hite, Jerry, R.
Abrégé
Compositions and methods for forming surfactants, aqueous dispersions, and curing agents are provided. In one aspect, the invention relates to improved epoxy functional surfactants prepared by reaction of an epoxy composition and an amidoamine composition formed from a blend of acid-terminated polyoxyalkylene polyols. The improved epoxy functional surfactants may be reacted with an excess of epoxy composition and water to result in an aqueous dispersion. The amidoamone composition may be a reaction mixture of a diamine compound and an acid terminated polyoxyalkylene composition formed from two or more polyoxyalkylene polyol compounds. The epoxy functional surfactant may be reacted with amine compounds to form a compound suitable as a curing agent.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Elmore, Jim, D.
Corley, Larry, Steven
Hite, Jerry, R.
Abrégé
Compositions and methods for forming surfactants, aqueous dispersions, and curing agents are provided. In one aspect, the invention relates to improved epoxy functional surfactants prepared by reaction of an epoxy composition and an amidoamine composition formed from a blend of acid-terminated polyoxyalkylene polyols. The improved epoxy functional surfactants may be reacted with an excess of epoxy composition and water to result in an aqueous dispersion. The amidoamone composition may be a reaction mixture of a diamine compound and an acid terminated polyoxyalkylene composition formed from two or more polyoxyalkylene polyol compounds. The epoxy functional surfactant may be reacted with amine compounds to form a compound suitable as a curing agent.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Le Fevere De Ten Hove, Cédric
Heymans, Denis
Steinbrecher, Christophe
Kotlewska, Aleksandra
Van'T Sand, Robert
Abrégé
The invention relates to a manufacturing process for the preparation of α,α-branched alkane carboxylic acids providing glycidyl esters with an improved softness or hardness of the coatings derived thereof. In which the mixture of neononanoic acid providing a high hardness is a mixture where the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75%. In which a mixture of neononanoic acids providing soft polymers is a mixture where the concentration of blocked and highly branched isomers is maximum 55%, preferably below 40% and most preferably below 30%.
C07C 51/14 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par réaction avec du monoxyde de carbone sur une liaison non saturée carbone-carbone d'un composé organique
C07C 67/08 - Préparation d'esters d'acides carboxyliques par réaction d'acides carboxyliques ou d'anhydrides symétriques avec le groupe hydroxyle ou O-métal de composés organiques
C07C 53/128 - Acides contenant au moins cinq atomes de carbone le groupe carboxyle étant lié à un atome de carbone lié lui-même à plusieurs autres atomes de carbone, p. ex. néo-acides
C07C 69/24 - Esters d'acides acycliques monocarboxyliques saturés dont le groupe carboxyle est lié à un atome de carbone acyclique ou à l'hydrogène avec au moins trois atomes de carbone dans la partie acide estérifiés par des composés monohydroxylés
C07C 51/15 - Préparation d'acides carboxyliques, de leurs sels, halogénures ou anhydrides par réaction de composés organiques avec l'anhydride carbonique, p. ex. synthèse de Kolbe-Schmitt
38.
NOVEL COMPOSITIONS AND METHODS TO PRODUCE TRIAZINE-ARYLHYDROXY-ALDEHYDE CONDENSATES WITH IMPROVED SOLUBILITY
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A (Belgique)
Inventeur(s)
Viswanathan, Ganapathy, S.
Subrayan, Raman, C.
Malhotra, Vinay
Abrégé
Compositions and methods for forming condensates and resin compositions are provided. In one embodiment, a condensate is formed from a reaction mixture including a triazine monomer, an arylhydroxy monomer, an aldehyde monomer and an acid catalyst having a pKa value of greater than 3.8. The condensates contain up to 28 wt.% of nitrogen and have a melt viscosity of 3,000 cps or less at 175 °C. The condensates may have a solubility of at least 80 wt.% solids dissolved in an organic solvent for 120 hours or greater. Also disclosed are methods for the manufacture of the condensate as well as the condensate's use in fire-retardant epoxy resin compositions suitable for the manufacture of laminates for electronic applications. There is also disclosed a glycidylated triazine- arylhydroxy-aldehyde condensate of this invention.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
CASE WESTERN RESERVE UNIVERSITY (USA)
Inventeur(s)
Ishida, Hatsuo
Agag, Tarek
Abrégé
Disclosed are benzoxazine compositions where oxazine rings are part of the polymer main-chain. The benzoxazine oligomers are prepared by the reaction of a bisphenol and an aldehyde, such as formaldehyde or paraformaldehyde, with one or more diamines or polyamines, and optionally with one or more monofunctional amines or monofunctional phenols. Also disclosed are benzoxazine monomers prepared from a bisphenol, an aldehyde, such as formaldehyde or paraformaldehyde, and a monofunctional amine, which benzoxazine monomers may be optionally used as reactive diluents. Further disclosed are benzoxazine monomers are prepared from a diamine, and aldehyde, such as formaldehyde or paraformaldehyde, and a monofunctional phenol, which benzoxazine monomers may also be optionally used as reactive diluents.
C08G 14/06 - Polymères de condensation d'aldéhydes ou de cétones et de plusieurs autres monomères couverts par au moins deux des groupes d'aldéhydes avec des phénols et des monomères contenant de l'hydrogène fixé sur l'azote
40.
STORAGE STABLE WATER BASED EPOXY-AMINE CURABLE SYSTEMS
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Elmore, Jim
Claeys-Bouuaert, Pascale
Heine, Francoise
Abrégé
The invention relates to non aqueous curing agents for water dispersed epoxy resins. The curing agent composition offers a binder pot life of several hours, and in the presence of a metal, such as zinc, nearly no hydrogen generation is observed. The present curing composition can be mixed with a metal powder to provide a storage stable paste. The curing agent composition and/or paste is fully compatible with an epoxy water based resin. After low shear blending, the epoxy curing agent and metal system is storage stable for several hours working pot life that provides for cured coatings having good performance.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Muppa, Prasad
Postma, Ron
Van Den Berg, Bart
Stock, Juergen
Wiederhold, Holger
Rausch, Hans
Schallenberg, Jörg
Bernhardt, Stefan
Abrégé
Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Muppa, Prasad
Postma, Ron
Schoolderman, Caspar
Rens, Sandra
Stoitsas, Kostas
Abrégé
The invention relates to a process for the manufacture of an epoxyethyl carboxylate or glycidyl carboxylate, including reacting a vinyl carboxylate or an allyl carboxylate using an oxidant and a water-soluble manganese complex in an aqueous reaction medium, and the water-soluble manganese complex comprises an oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (I): [LMnX3]Y, or a binuclear species of the general formula (II): [LMn(μ-X)3MnL]Yn, wherein Mn is a manganese; L is a ligand and each L is independently a polydentate ligand, each X is independently a coordinating species and each μ-X is independently a bridging coordinating species, Y is a non-coordinating counter ion, and wherein the epoxidation is carried out at a pH in the range of from 1.0 to 7.0.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
C07D 303/16 - Composés contenant des cycles oxirane avec des radicaux hydrocarbonés, substitués par des atomes d'oxygène liés par des liaisons simples ou doubles par des radicaux hydroxyle estérifiés
43.
MANUFACTURE OF EPOXYETHYL ETHERS OR GLYCIDYL ETHERS
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Muppa, Prasad
Postma, Ron
Schoolderman, Caspar
Rens, Sandra
Stoisas, Kostas
Abrégé
Processes are provided for the formation of an epoxyethyl ether or a glycidyl ether, hi one embodiment, a process is provided for the manufacture of an epoxyethyl ether or glycidyl ether including reacting a vinyl ether or an allyl ether with an oxidant in the presence of a water-soluble manganese complex in an aqueous reaction medium, wherein the water-soluble manganese complex comprises an oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear complex of the general formula (I): [LMnX3]Y (I), or a binuclear complex of the general formula (II): [LMn(μ-X)3MnL](Y)n (II), wherein Mn is a manganese; L or each L independently is a polydentate ligand, each X independently is a coordinating species and each μ-X independently is a bridging coordinating species, Y is a non-coordinating counter ion, and wherein the epoxidation is carried out at a pH in the range of from 1.0 to 6.0. The invention also relates to epoxyethyl ethers.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Muppa, Prasad
Kapellen, Mark
Schoolderman, Caspar
Abrégé
Processes and compositions are provided for epoxidizing an olefinically unsaturated compound. In one embodiment, a process is provided for reacting an olefinically unsaturated compound with an oxidant in the presence of a catalyst at acidic conditions, wherein the catalyst is activated prior to the reaction at a pH that is higher than the pH during the reaction.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
45.
COMPOSITIONS USEFUL FOR PREPARING COMPOSITES AND COMPOSITES PRODUCED THEREWITH
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Shirrell, Charles, David
Abrégé
A composite prepared using a thermosettable epoxy resin composition having, as components: (1) an epoxy resin; (2) an epoxidized cycloaliphatic dicyclopentadiene phenolic resin; (3) an optional epoxidized bisphenol-A novolac resin; (4) an optional oligomeric butadiene; (5) an optional organic solvent; and (6) an alkylphenol novolac resin, the alkylphenol novolac resin serving as a curing agent. The composite so prepared may have good physical properties and superior a electrical properties as compared to conventional composites, such as laminates. The prepregs used to make the laminates may have a better surface appearance as well.
C21D 1/72 - Revêtements temporaires ou matériaux d'enrobage appliqués avant ou pendant le traitement thermique au cours du changement chimique de surface
C21D 9/52 - Traitement thermique, p. ex. recuit, durcissement, trempe ou revenu, adapté à des objets particuliersFours à cet effet pour fils métalliquesTraitement thermique, p. ex. recuit, durcissement, trempe ou revenu, adapté à des objets particuliersFours à cet effet pour bandes métalliques
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM SA (Belgique)
MOMENTIVE SPECIALITY CHEMICALS INC. (USA)
Inventeur(s)
Muppa, Prasad
Schoolderman, Caspa
Rens Van Der Lee, Sandra
Postma, Ron
Abrégé
A process for the manufacture of propylene oxide ("PO") by catalytic oxidation of propylene with an oxidant wherein the catalytic oxidation is performed in an aqueous reaction medium, comprising water with less than 10% by volume of cosolvents, wherein a water-soluble manganese complex is used as oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (I): [LMnX3]Y (I) or a binuclear species of the general formula (II): [LMn( μ-X)3MnL]Y2 (II) wherein Mn is a manganese; L or each L independently is a polydentate ligand, each X independently is a coordinating species and each μ-X independently is a bridging coordinating species, whereas Y is an non-coordinating counterion, and wherein the catalytic oxidation is carried out at a pH in the range of from 1.5 to 6.0.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
47.
CURING OR SEALING COMPOSITIONS FOR CONCRETE AND CEMENT FORMULATIONS AND PROCESSES FOR USING THE SAME
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Wantling, Steven, J.
Abrégé
Disclosed are wax emulsion compositions for curing or sealing concrete and cement formulations, methods for preparing and processes for using the same. The modifiers are applicable to curing or sealing membranes, used in roadways, highways, parking lots and other freshly placed or poured concrete surfaces to retain moisture and achieve high compressive strengths. This invention also relates to materials used to coat, spray, brush, roll etc. on conventional Portland cement concrete mix designs or other applied concrete mixes in formed structural shapes and transport road mix designs, providing an effective layer that controls and minimizes moisture loss from the mix to enable proper curing and achievement of desired compressive strengths. The compositions of the invention further provide for concrete and cement formulations having lower water soluble chloride content.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Gouman, Jan
Rens, Sandra
Van'T Sand, Robert
Abrégé
Accordingly, the invention relates to a process for the preparation of a glycidyl ester of a branched monocarboxylic acid by reacting an aliphatic monocarboxylic acid of the formula R1R2R3COOH, wherein R1, R2, and R3 each independently represent an alkyl radical of normal or branched structure containing from 1 to 20 carbon atoms and an epoxyalkyl halide containing from 3 to 13 carbon atoms in the presence of a catalyst, wherein a greater than stoichiometric amount of epoxyalkyl halide is reacted with the acid (e.g., preferably in the molar ratio of epoxyalkyl halide to acid that is in the range of from 1.02:1 to 1.50:1) to form an intermediate reaction product comprising a halohydrin, the epoxyalkyl halide is added to the acid with appropriate cooling of the reactants and/or the reaction mixture to keep the temperature of the reaction mixture below 80°C, whereupon the epoxyalkyl halide and the acid are reacted at a temperature below 80°C (preferably in the range of from 55 to 75°C) for a time sufficient to reduce the amount of acid to no more than 2 wt% but no less than 0.1 wt% calculated on the initial amount of acid, optionally removing any excess epoxyalkyl halide from the reaction product prior to the ring closure reaction, subjecting the reaction product to a ring closure reaction (DHC) and optionally to one or more after treatments (ADHC) for removal of any remaining halo functionality.
C07D 303/16 - Composés contenant des cycles oxirane avec des radicaux hydrocarbonés, substitués par des atomes d'oxygène liés par des liaisons simples ou doubles par des radicaux hydroxyle estérifiés
49.
METHODS FOR MAKING AND USING UV/EB CURED PRECURED PARTICLES FOR USE AS PROPPANTS
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Xu, Liang
Green, John, W.
Mccrary, Avis, Lloyd
Abrégé
Disclosed herein are methods of making free flowing coated particles and low temperature including a step of curing the coating with UV light or electron beam. Each particle has a precured coating disposed upon a substrate. Methods of using the particles are also disclosed.
B32B 5/16 - Produits stratifiés caractérisés par l'hétérogénéité ou la structure physique d'une des couches caractérisés par le fait qu'une des couches est formée de particules, p. ex. de copeaux, de fibres hachées, de poudre
50.
PROCESS TO PREPARE LOW TEMPERATURE CURABLE WATERBORNE POLYURETHANE COATINGS
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
HEXION SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Heymans, Denis
Le Fevere De Ten Hove, Cedric
Steinbrecher, Christophe
Abrégé
The invention relates to a process to prepare ambient curable waterborne polyurethane coatings by which the isocyanate and the polyols are mixed thoroughly before their emulsification in water, by low shear mixing at room temperature. The polyol resins composition suitable for the present invention are polyacrylate resins having a hydroxyl value of from 60 to 180 mg of KOH/g of solids, an acid value of from 10 to 30 mg of KOH/g of solids, and a calculated glass transition temperature of from -40°C to +65°C.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Christiansen, Walter, H.
Ash, Carlton, E.
Langemeier, Paul, W.
Abrégé
Disclosed is a toughened film forming agent for use in a fiber sizing, a finish coating or a binder composition, where the toughened film forming agent includes a film forming polymer and a toughening agent both dispersed in water. The toughening agent may be core shell polymers, rubber, thermoplastic materials, nanomaterials, nanofibers, including any combination or subset thereof. The film forming polymer may be epoxy resins, polyurethane resins, epoxy-polyurethane resins, polyester resins, epoxy-polyester resins, polyvinylacetate resins, polypropylene resins, including any combination or subset thereof.
B32B 17/04 - Produits stratifiés composés essentiellement d'une feuille de verre ou de fibres de verre, de scorie ou d'une substance similaire sous forme de fibres ou filaments collés ou enrobés dans une substance plastique
52.
TRIGLYCERIDE COMPOSITIONS USEFUL FOR PREPARING COMPOSITE PANELS AND APPLICATIONS THEREOF
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Wantling, Steven, J.
Abrégé
Composite panels may be prepared using a moisture resistance additive having a formulation that includes a triglyceride having a saponification value of at least 150 and an iodine value of at least 35. The additive may be used in the form of a water emulsion. The water emulsion may be prepared by dispersing the components of the additive formulation under conditions sufficient to at least partially saponify the triglyceride. The moisture resistance additive can impart resistance to moisture absorption and thickness swelling to composite panels prepared therewith.
B32B 23/04 - Produits stratifiés composés essentiellement de substances cellulosiques plastiques comprenant de telles substances comme seul composant ou comme composant principal d'une couche adjacente à une autre couche d'une substance spécifique
B32B 23/06 - Produits stratifiés composés essentiellement de substances cellulosiques plastiques comprenant de telles substances comme seul composant ou comme composant principal d'une couche adjacente à une autre couche d'une substance spécifique de papier ou de carton
B32B 29/00 - Produits stratifiés composés essentiellement de papier ou de carton
B05D 1/36 - Applications successives de liquides ou d'autres matériaux fluides, p. ex. sans traitement intermédiaire
B05D 7/00 - Procédés, autres que le flocage, spécialement adaptés pour appliquer des liquides ou d'autres matériaux fluides, à des surfaces particulières, ou pour appliquer des liquides ou d'autres matériaux fluides particuliers
53.
TRIGLYCERIDE COMPOSITIONS USEFUL FOR PREPARING COMPOSITE PANELS
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Wantling, Steven, J.
Wren, Harden, Christopher
Holder, Jason, L.
Abrégé
Composite panels may be prepared using a moisture resistance additive having a formulation that includes a triglyceride having a saponification value of at least 150 and an iodine value of at least 35. The additive may be used in the form of a water emulsion. The water emulsion may be prepared by dispersing the components of the additive formulation under conditions sufficient to at least partially saponify the triglyceride. The moisture resistance additive can impart resistance to moisture absorption and thickness swelling to composite panels prepared therewith.
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Postma, Ron
Abrégé
The invention provides a process for the preparation of an allyl aryl ether comprising the O-allylation of an aromatic hydroxyl containing compound with an allyl source in the presence of a catalyst, wherein the catalyst is a transition metal complex with a bidentate diphosphine ligand, and wherein the bidentate diphosphine ligand has 2 to 4 bridging atoms between the phosphorus atoms and wherein at least one of the bridging atoms is substituted. This invention further provides novel transition metal complexes that may be used in the above process. This invention further provides a process for the preparation of epoxy resins wherein as intermediate use is made of the allyl aryl ethers prepared by the process of the invention.
C07C 41/09 - Préparation d'éthers par déshydratation de composés contenant des groupes hydroxyle
C07C 43/215 - Éthers une liaison sur l'oxygène de la fonction éther étant sur un atome de carbone d'un cycle aromatique à six chaînons avec une insaturation autre que celle des cycles aromatiques à six chaînons
C07F 17/02 - Metallocènes de métaux des groupes 8, 9 ou 10 du tableau périodique
55.
PROCESS FOR THE PREPARATION OF AN ALLYL ARYL ETHER BY CATALYTIC O-ALLYLATION
MOMENTIVE SPECIALTY CHEMICAL RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Postma, Ron
Abrégé
The invention provides a process for the preparation of an allyl aryl ether comprising the O-allylation of an aromatic hydroxyl containing compound with an allyl source in the presence of a catalyst, wherein the catalyst is a transition metal complex with a phosphine ligand, and wherein the phosphine ligand is either a monodentate phosphine P(X)3, wherein each X independently is a an aliphatic substituent having from 1 to 9 carbon atoms, a cycloaliphatic substituent having from 5 to 9 carbon atoms or aromatic substituent having from 6 to 9 carbon atoms, or wherein two substituents X together form a divalent alkylene group, with from 3 up to 6 carbon atoms, or a bidentate diphosphine X2P-R-PX2 wherein each X has the same meaning as defined for the monodentate phosphine, wherein the divalent alkylene group is attached to the same or different phosphorus atom(s), and R is a bridging group having at least 4 bridging atoms between the phosphorus atoms, wherein the O-allylation is carried out in the presence of an acid in an amount of at least 0.1 mol% calculated on the aromatic hydroxyl containing compound. This invention further provides a process for the preparation of epoxy resins wherein as intermediate use is made of the allyl aryl ethers prepared by the process of the invention.
C07C 41/09 - Préparation d'éthers par déshydratation de composés contenant des groupes hydroxyle
C07C 43/215 - Éthers une liaison sur l'oxygène de la fonction éther étant sur un atome de carbone d'un cycle aromatique à six chaînons avec une insaturation autre que celle des cycles aromatiques à six chaînons
C07F 17/02 - Metallocènes de métaux des groupes 8, 9 ou 10 du tableau périodique
56.
PROCESS FOR THE PREPARATION OF AN ALLY ALKYL EHTER BY CATALYTIC ALLYATION
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
Inventeur(s)
Postma, Ron
Abrégé
The invention provides a process for the preparation of an allyl alkyl ether comprising the allylation of an aliphatic hydroxyl containing compound with an allyl source in the presence of a catalyst, wherein the catalyst is a transition metal complex with a phosphine ligand, wherein the allylation is carried out in the presence of an acid in an amount of at least 0.1 mol% calculated on the aliphatic hydroxyl containing compound. This invention further provides a process for the preparation of epoxy resins wherein as intermediate use is made of the allyl alkyl ethers prepared by the process of the invention.
C07C 43/18 - Éthers une liaison sur l'oxygène de la fonction éther étant sur un atome de carbone d'un cycle autre que ceux d'un cycle aromatique à six chaînons
C07C 43/15 - Éthers non saturés ne contenant que des liaisons doubles carbone-carbone non aromatiques
C07F 17/02 - Metallocènes de métaux des groupes 8, 9 ou 10 du tableau périodique
57.
POWDER COATING COMPOSITIONS FOR LOW TEMPERATURE CURING AND HIGH FLOW
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Beccaria, Damiano
Bejko, Lmir
Capra, Andrea
Panero, Irene
Munari, Alessandro
Abrégé
The present invention relates to powder coating compositions and to components and ingredients for incorporation therein, suitable for low temperature curing schedule and with excellent resistance to outside aging. The powder coating composition can be cured at a temperature from 140 °C to lead to a coating with excellent flow and high gloss.
C08G 63/48 - Polyesters modifiés chimiquement par estérification par des huiles d'acides gras supérieurs non saturés ou leurs acidesPolyesters modifiés chimiquement par estérification par des acides résiniques
C09D 167/08 - Polyesters modifiés soit par des huiles grasses supérieures ou leurs acides, soit par des résines naturelles ou des acides résiniques
58.
PROCESS FOR THE MANUFACTURE OF EPICHLOROHYDRIN USING HYDROGEN PEROXIDE AND A MANGANESE COMPLEX
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Postma, Ron
Muppa, Prasad
Abrégé
The invention relates to a process for the manufacture of epichlorohydrin ("ECH") by catalytic oxidation of allyl chloride ("AC") with an oxidant wherein the catalytic oxidation is performed in an aqueous reaction medium, wherein a water-soluble manganese complex is used as oxidation catalyst, followed by the isolation of epichlorohydrin.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques
MOMENTIVE SPECIALTY CHEMICALS RESEARCH BELGIUM S.A. (Belgique)
MOMENTIVE SPECIALTY CHEMICALS INC. (USA)
Inventeur(s)
Postma, Ron
Muppa, Prasad
Abrégé
The invention relates to a process for the manufacture of a 1, 2- epoxide by catalytic oxidation of a terminal olefin with hydrogen peroxide wherein the catalytic oxidation is performed in a biphasic system comprising an organic phase and an aqueous reaction medium, wherein a water-soluble manganese complex is used as oxidation catalyst, wherein a terminal olefin is used with a solubility at 20°C of at least 0,01 to 100 g in 1 liter water, and wherein the molar ratio of terminal olefin to hydrogen peroxide is in the range of from 1:0.1 to 1:2.
C07D 301/12 - Synthèse du cycle de l'oxirane par oxydation de composés non saturés, ou de mélanges de composés non saturés et de composés saturés par le peroxyde d'hydrogène ou par des peroxydes ou peracides inorganiques