The subject of the invention is a process for the hydrogenation of hydrogen carbonate in an aqueous reaction system, where the process ensures that the hydrogen carbonate, hydrogen and catalyst come into contact with each other while carbon dioxide is present in the gas space. In this phase of the process, formate is produced. The subject of the invention is also a process for the catalytic decomposition of formate in an aqueous reaction system and the hydrogenation of hydrogen carbonate produced in the same reaction system according to the invention, where the reactants and the reaction products are formed in a reversible reaction cycle using the reaction system according to the invention, and this reaction cycle is repeated in the required number of times. In the mentioned formate mg decomposition process, the formate and the catalyst come into contact, so that hydrogen gas and hydrogen carbonate free of COX by-products are produced as the product of the reaction. Further subject of the invention is a hydrogen storage system based on the method according to the invention, preferably a hydrogen accumulator. Further subject of the invention is a hydrogen storage system according to the invention, preferably the use of a hydrogen accumulator for the storage of hydrogen required for the operation of a fuel cell (or other equipment requiring H2) and, where appropriate, for its release in as needed.
C01B 3/00 - Hydrogène; Mélanges gazeux contenant de l'hydrogène; Séparation de l'hydrogène à partir de mélanges en contenant; Purification de l'hydrogène
B01J 23/46 - Ruthénium, rhodium, osmium ou iridium
C07C 51/41 - Préparation de sels d'acides carboxyliques par conversion de ces acides ou de leurs sels en sels ayant la même partie acide carboxylique
2.
HYDROGEN STORAGE BASED ON AQUEOUS FORMATE-BICARBONATE (HYDROGEN CARBONATE) EQUILIBRIUM
The subject of the invention is a process for the hydrogenation of hydrogen carbonate in an aqueous reaction system, where the process ensures that the hydrogen carbonate, hydrogen and catalyst come into contact with each other while carbon dioxide is present in the gas space. In this phase of the process, formate is produced. The subject of the invention is also a process for the catalytic decomposition of formate in an aqueous reaction system and the hydrogenation of hydrogen carbonate produced in the same reaction system according to the invention, where the reactants and the reaction products are formed in a reversible reaction cycle using the reaction system according to the invention, and this reaction cycle is repeated in the required number of times. In the mentioned formate decomposition process, the formate and the catalyst come into contact, so that hydrogen gas and hydrogen carbonate free of COX by-products are produced as the product of the reaction. Further subject of the invention is a hydrogen storage system based on the method according to the invention, preferably a hydrogen accumulator. Further subject of the invention is a hydrogen storage system according to the invention, preferably the use of a hydrogen accumulator for the storage of hydrogen required for the operation of a fuel cell (or other equipment requiring H2) and, where appropriate, for its release in as needed.
C01B 3/00 - Hydrogène; Mélanges gazeux contenant de l'hydrogène; Séparation de l'hydrogène à partir de mélanges en contenant; Purification de l'hydrogène
B01J 31/18 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des complexes de coordination contenant de l'azote, du phosphore, de l'arsenic ou de l'antimoine
The subject of the invention is a process for the hydrogenation of hydrogen carbonate in an aqueous reaction system, where the process ensures that the hydrogen carbonate, hydrogen and catalyst come into contact with each other while carbon dioxide is present in the gas space. In this phase of the process, formate is produced. The subject of the invention is also a process for the catalytic decomposition of formate in an aqueous reaction system and the hydrogenation of hydrogen carbonate produced in the same reaction system according to the invention, where the reactants and the reaction products are formed in a reversible reaction cycle using the reaction system according to the invention, and this reaction cycle is repeated in the required number of times. In the mentioned formate decomposition process, the formate and the catalyst come into contact, so that hydrogen gas and hydrogen carbonate free of COX by-products are produced as the product of the reaction. Further subject of the invention is a hydrogen storage system based on the method according to the invention, preferably a hydrogen accumulator. Further subject of the invention is a hydrogen storage system according to the invention, preferably the use of a hydrogen accumulator for the storage of hydrogen required for the operation of a fuel cell (or other equipment requiring H2) and, where appropriate, for its release in as needed.
C01B 3/00 - Hydrogène; Mélanges gazeux contenant de l'hydrogène; Séparation de l'hydrogène à partir de mélanges en contenant; Purification de l'hydrogène
B01J 31/18 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des complexes de coordination contenant de l'azote, du phosphore, de l'arsenic ou de l'antimoine
A geothermal well is provided including a first tube including at least one opening in a first depth; a second tube having a closed bottom in a second depth; and a third tube having a closed bottom in a third depth. The first tube is inside the second tube, which is inside the third tube, wherein the first tube has at least one opening in fluid communication with a first interspace between the first tube and the second tube; wherein the third depth and the first depth are smaller than the second depth. Through-holes are formed in the second tube above the bottom of the third tube, which allow fluid communication between the first interspace and a second interspace between the second tube and the third tube. A first sealing element and a heat insulating material are disposed in the first interspace above the through-holes.
F03G 4/00 - Dispositifs produisant une puissance mécanique à partir d'énergie géothermique
F24T 10/17 - Collecteurs géothermiques avec circulation des fluides vecteurs dans des conduits souterrains, les fluides vecteurs n’entrant pas en contact direct avec le sol utilisant des assemblages de conduits adéquats pour l’insertion dans des trous forés dans le sol, p.ex. sondes géothermiques utilisant des conduits fermés à une extrémité, c. à d. du type à retour
E21B 36/00 - Aménagements pour le chauffage, le refroidissement, l'isolation, dans les trous de forage ou dans les puits, p.ex. pour être utilisés dans les zones de permagel
5.
GEOTHERMAL WELL, METHOD OF ESTABLISHING THEREOF AND METHOD FOR GEOTHERMAL ENERGY PRODUCTION
The object of the invention is a geothermal well, which comprises in a wellbore formed in the Earth's crust: a fist tube (1) comprising at least one opening in a first depth and having a first inner diameter, a first outer diameter, and a side wall which is thermally insulated at least in a portion thereof; a second tube (2) having a closed bottom in a second depth, a second inner diameter larger than the first outer diameter, and a second outer diameter; a third tube (3) having a closed bottom in a third depth, a third inner diameter larger than the second outer diameter, and a third outer diameter, wherein the first tube (1) is inside the second tube (2), a first interspace (20) is present between the first tube (1) and the second tube (2), wherein the first tube (1) has at least one opening in fluid communication with the first interspace (20), wherein the second tube (2) is inside the third tube (3), a second interspace (30) is present between the second tube (2) and the third tube (3); wherein the third depth is smaller than the second depth and the first depth is smaller than the second depth, furthermore through-holes (21) are formed in the second tube (2) above the bottom of the third tube (3), which allow fluid communication between the first interspace (20) and the second interspace (30), a first sealing element (22) is disposed in the first interspace (20) above the through-holes (21) for preventing upward flow of fluid in the first interspace (20), and a heat insulating material is disposed in at least a portion of the first interspace (20) above the through-holes (21). In a further aspect, the object of the invention is a method for establishing such a geothermal well and a method for geothermal energy production by said geothermal well.
E21B 36/00 - Aménagements pour le chauffage, le refroidissement, l'isolation, dans les trous de forage ou dans les puits, p.ex. pour être utilisés dans les zones de permagel
F24T 10/17 - Collecteurs géothermiques avec circulation des fluides vecteurs dans des conduits souterrains, les fluides vecteurs n’entrant pas en contact direct avec le sol utilisant des assemblages de conduits adéquats pour l’insertion dans des trous forés dans le sol, p.ex. sondes géothermiques utilisant des conduits fermés à une extrémité, c. à d. du type à retour
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