The invention relates to the use of at least one compound corresponding to the following formula: R-O-(-CH2-CH(-CH3)-O-)m-(-CH2-CH2-O-)n-H where: R is a hydrocarbon-based group comprising from 6 to 40 carbons; m ranges from 0 to 20; n, which is greater than m, ranges from 5 to 40, in order to inhibit the phenomena of retention of anionic surfactants within an oil-bearing reservoir, in particular within a carbonate or clay reservoir.
C09K 8/584 - Compositions pour les méthodes de récupération assistée pour l'extraction d'hydrocarbures, c.-à-d. pour améliorer la mobilité de l'huile, p. ex. fluides de déplacement caractérisées par l'utilisation de tensio-actifs spécifiques
The described invention discloses an innovative hydroconversion-processing configuration for converting bitumen or heavy oils to produce a transportable synthetic crude oil (SCO). The innovative processing scheme disclosed herein maximizes the synthetic crude oil yield at a minimal investment compared to currently known methods.
C10G 47/00 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur
3.
Process for stabilizing the performances of a catalyst for Fischer Tropsch reaction
Modular reactor for exothermic/endothermic chemical reactions which take place in three-phase systems, comprising a series of modules, superimposed with respect to each other, fixed to each other by means of coupling flanges, each module consisting of an external cylindrical body and a series of tube bundles, for the circulation of a thermal-exchange fluid, positioned inside said body.
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées
F27B 15/00 - Fours à lit fluidiséAutres fours utilisant ou traitant des matières finement divisées en dispersion
B01J 19/00 - Procédés chimiques, physiques ou physico-chimiques en généralAppareils appropriés
B01J 8/00 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés
B01J 8/04 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés avec des particules immobiles, p. ex. dans des lits fixes le fluide passant successivement à travers plusieurs lits
A logging probe supporting device includes a connector that can be plugged in at the bottom of the well with a logging cable contained in the inner space of rods to which the supporting device is fastened and fluid communicating openings provided between the inner space of the rods and the outside of the supporting device, the openings being arranged between the probe and connector. The device includes, between the openings and the connector, a shutoff such as check valves allowing fluid circulation from the inside towards the outside and preventing circulation from the outside towards the inside of the supporting device.
B01D 53/14 - Séparation de gaz ou de vapeursRécupération de vapeurs de solvants volatils dans les gazÉpuration chimique ou biologique des gaz résiduaires, p. ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols par absorption
Rotodynamic machine for compressing a multiphase fluid comprising at least one gas phase and one liquid phase.
The machine comprises at least one mobile wheel 6 rotating around an axis A-A′, mounted in a housing 1, and at least one fixed wheel 7 secured to housing 1. Mobile wheel 6 comprises a hub fitted with at least two blades 20 so as to form at least two channels delimited by hub 8, housing 1 and two of said blades 20. The channels have a centrifugal part.
The length of one of the channels defined as the ratio of the volume of a channel to the maximum orthoradial area of said channel, measured in a plane perpendicular to the axis of rotation, ranges between 10 cm and 20 cm, and the ratio of the area of the largest orthoradial channel cross-section to the area of the smallest orthoradial channel cross-section is less than or equal to 3.
An improved process for heavy oil conversion and upgrading and a combined method for heavy oil conversion and vacuum gas-oil treatment are described herein. The method utilizes the creation and recycle of a separate product from the vacuum still, which is thereafter recycled back to the heavy oil conversion reactor. The result is the production of a higher quality medium gas oil product relative to the overall vacuum gas oil product which is acceptable for use in a typical vacuum gas oil treatment process. Additionally, there is a higher diesel yield selectivity from the heavy oil conversion unit.
A method of deacidizing a gaseous effluent comprising acid compounds where the gaseous effluent is contacted in C1 with an adsorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. These two fractions are then separated in BS1. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution.
B01D 53/14 - Séparation de gaz ou de vapeursRécupération de vapeurs de solvants volatils dans les gazÉpuration chimique ou biologique des gaz résiduaires, p. ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols par absorption
10.
PROCESS FOR STABILIZING THE PERFORMANCES OF A CATALYST FOR FISCHER TROPSCH REACTION
Process for maintaining the stability of performances of a catalyst for Fischer-Tropsch reaction, performed in a slurry bubble column reactor under a triphase system, which comprises gradually increasing the P H20/P H2 ratio and the P H20/Z ratio, during the start-up phase, with Z = P0 .cndot.(T/T1)4 .cndot. e- (k2/(t.cndot.k3)) from 0.4 to 0.8, for a period of time not shorter than 100- 150 hrs and not longer than 200-300 hours and, at the end of the start-up phase, maintaining the P H20/PH2 and P H20/Z ratios substantially equal to or lower than 0.8.
C07C 1/06 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir d'oxydes de carbone à partir de monoxyde de carbone avec de l'hydrogène en présence de composés organiques, p. ex. d'hydrocarbures
11.
PROCESS FOR STABILIZING THE PERFORMANCES OF A CATALYST FOR FISCHER TROPSCH REACTION
Process for maintaining the stability of performances of a catalyst for Fischer-Tropsch reaction, performed in a slurry bubble column reactor under a triphase system, which comprises gradually increasing the PH20/PH2 ratio and the PH20/Z ratio, during the start-up phase, with Z = P0 • (T/T1)4 • e-(K2/(t •K3)) from 0.4 to 0.8, for a period of time not shorter than 100-150 hrs and not longer than 200-300 hours and, at the end of the start-up phase, maintaining the PH20/PH2 and PH20/Z ratios substantially equal to or lower than 0.8.
C07C 1/04 - Préparation d'hydrocarbures à partir d'un ou plusieurs composés, aucun d'eux n'étant un hydrocarbure à partir d'oxydes de carbone à partir de monoxyde de carbone avec de l'hydrogène
The invention relates to agglomerated zeolitic adsorbents based on faujasite X zeolite powder having a low silica content and small crystals, said zeolite being exchanged with barium, or based on faujasite X zeolite having a low silica content and small crystals, this zeolite being exchanged both with barium and potassium. The invention also relates to the method of preparing said agglomerated zeolitic adsorbents and to the uses thereof in the separation of sugars, polyhydric alcohols, substituted-toluene isomers and cresols or in the recovery of very-pure paraxylene.
B01J 20/28 - Compositions absorbantes ou adsorbantes solides ou compositions facilitant la filtrationAbsorbants ou adsorbants pour la chromatographieProcédés pour leur préparation, régénération ou réactivation caractérisées par leur forme ou leurs propriétés physiques
C07C 7/13 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par adsorption, c.-à-d. purification ou séparation d'hydrocarbures à l'aide de solides, p. ex. à l'aide d'échangeurs d'ions par la technique du tamis moléculaire
C07C 37/82 - SéparationPurificationStabilisationEmploi d'additifs par traitement physique par traitement solide-liquideSéparationPurificationStabilisationEmploi d'additifs par traitement physique par absorption-adsorption chimique
The present invention relates to agglomerated zeolitic adsorbents based on X zeolite and LSX zeolite powders. These adsorbents are particularly well suited for the separation of C8 aromatic isomers and especially xylenes, for the separation of sugars, for the separation of polyhydric alcohols, for the separation of substituted-toluene isomers, such as nitrotoluene, diethyltoluene and toluenediamine, for the separation of cresols and for the separation of dichlorobenzenes.
B01J 20/28 - Compositions absorbantes ou adsorbantes solides ou compositions facilitant la filtrationAbsorbants ou adsorbants pour la chromatographieProcédés pour leur préparation, régénération ou réactivation caractérisées par leur forme ou leurs propriétés physiques
C07C 7/13 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par adsorption, c.-à-d. purification ou séparation d'hydrocarbures à l'aide de solides, p. ex. à l'aide d'échangeurs d'ions par la technique du tamis moléculaire
C07C 37/82 - SéparationPurificationStabilisationEmploi d'additifs par traitement physique par traitement solide-liquideSéparationPurificationStabilisationEmploi d'additifs par traitement physique par absorption-adsorption chimique
G01N 25/02 - Recherche ou analyse des matériaux par l'utilisation de moyens thermiques en recherchant les changements d'état ou de phaseRecherche ou analyse des matériaux par l'utilisation de moyens thermiques en recherchant le frittage
16.
Method and device for separating constituents of a liquid feed by liquid-liquid centrifugal chromatography
The invention relates to a method for separating constituents of a liquid feed by liquid-liquid centrifugal chromatography and to a device for implementing it. Constituents (A, B) having different partition coefficients such that they are respectively carried along at unequal velocities by a light solvent (l) and a heavier solvent (L), the feed is continuously injected at an intermediate point of a separation column (col), successive cycles comprising alternately a heavy solvent injection stage and a light solvent injection stage are carried out respectively at the two ends of the column consisting of the interconnection in series of at least one set of separation cells, and the separated solvents (FA, FB) are collected during each one of said stages at the column ends opposite the solvent injection points.
Process for separating paraxylene with a purity that is at least equal to 99.5% by weight from an aromatic feedstock F in a single adsorption stage in a simulated moving bed (SMB), comprising different numbers of beds, allocated to a zone 1 between the supply of the desorbent D and the draw-off of the extract E; a zone 2 between the draw-off of the extract E and the supply of the feedstock F; a zone 3 between the supply of the feedstock and the draw-off of the raffinate R; a zone 4 between the draw-off of the raffinate R and the supply of the desorbent D, wherein an SMB of 12 adsorbent beds has bed configuration (2, 5, 3, 2), an SMB of 15 adsorbent beds has bed configuration (3, 6, 4 , 2), or an SMB of 19 adsorbent beds has bed configuration (4, 7, 6, 2), wherein the desorbent in this latter case is paradiethylbenzene.
C07C 7/12 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par adsorption, c.-à-d. purification ou séparation d'hydrocarbures à l'aide de solides, p. ex. à l'aide d'échangeurs d'ions
The invention relates to a logging probe (2) holding device (3) comprising connection means (4) that can be plugged in at the bottom of the well and comprise a logging cable contained inside the rods (7) to which the holding device is fixed, and fluidic communication means arranged between the inside of the rods and the outside of the holding device, the communication means being located between the probe and the connection means. The device comprises closing means such as check valves, between the communication means and the connection means, said closing means authorising the circulation of the fluid from the inside towards the outside, and preventing the circulation from the outside towards the inside of the holding device.
E21B 23/08 - Introduction ou circulation d'outils par pression de fluide, p. ex. systèmes d'outils mis en place par un courant de fluide
E21B 47/01 - Dispositifs pour supporter des instruments de mesure sur des trépans, des tubes, des tiges ou des câbles de forageProtection des instruments de mesure dans les trous de forage contre la chaleur, les chocs, la pression ou similaire
19.
Methods of hydrotreating a mixture made up of oils of animal or vegetable origin and of petroleum cuts with quench injection of the oils on the last catalyst bed
A hydrotreating method uses two catalyst beds with the introduction, on the last catalyst bed, of oils of animal or vegetable origin for co-treating a mixture made up of oils of vegetable or animal origin and of petroleum cuts (gas oil cuts (GO) and middle distillates) in order to produce gas oil effluents meeting specifications with an improved cetane number. The first catalyst bed is dedicated to only the deep desulfurization reactions (HDS1) of a petroleum type feed. The effluents of the first catalyst bed having an effluent sulfur content below or equal to 50 mg/kg are separated into two streams. The first stream, which is predominant, is sent to the gas oil pool. The second stream is mixed with oils of vegetable or animal origin. The resultant oil-petroleum cut mixture is then subjected to a milder hydrotreatment (HDT2). The effluents obtained at the outlet of the second catalyst bed can optionally be mixed with the predominant stream from the first bed. The process economy, the tolerance to the specifications relative to oils of animal or vegetable origin and the quality of the products obtained are thus greatly improved.
The invention relates to a measuring method and system for a shaft including an essentially horizontal portion, said system including at least a measuring probe (2) attached to a probe carrier (3) connected to the lower end of a rod packing, the carrier including a member for electric connection with an electric connection cable provided with means to be plugged on said connection member, and a connector with a lateral input (8) integrated in the rod packing. The system includes a first occlusion means (20) in the vicinity of the lower end of the rod packing, and a second occlusion means (21) above the connector with a lateral input, the occlusion means being of the check-type for an upward fluid flow inside the rods, and the first means being open when the electric connection is established.
E21B 21/10 - Aménagements des vannes dans les systèmes de circulation des fluides de forage
E21B 23/14 - Appareils pour déplacer, mettre en place, verrouiller, libérer ou retirer, les outils, les packers ou autres éléments dans les trous de forage pour déplacer un câble ou un outil manœuvré par câble, p. ex. pour les opérations de diagraphie ou de perforation dans les puits déviés
E21B 47/01 - Dispositifs pour supporter des instruments de mesure sur des trépans, des tubes, des tiges ou des câbles de forageProtection des instruments de mesure dans les trous de forage contre la chaleur, les chocs, la pression ou similaire
21.
METHOD FOR CONVERTING LOADS FROM RENEWABLE SOURCES FOR PRODUCING DIESEL FUEL BASES HAVING LOW-SULPHUR AND ENHANCED-KETANE CONTENTS
The invention relates to a method for processing heavy petroleum loads in order to produce a diesel cut having a sulphur content lower than 50 ppm, preferably 10 ppm, that comprises the following steps: soft fixed-bed hydro-cracking of the catalyst; separation of the hydrogen sulphide, of a distillate cut including the diesel fraction and of a fraction heavier than diesel; c) hydro-processing by contact with at least one catalyst of at least one portion of said distillate cut obtained in step b) and including the diesel fraction mixed with a raw or refined load from a renewable source; d) separating a diesel cut with less than 50 ppm of sulphur. Advantageously, the method uses additional hydrogen fed during step c) and, most advantageously, all the additional hydrogen is fed during step c). The invention also relates to an equipment used for implementing said method.
C10G 45/02 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage
C10G 45/08 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage caractérisé par le catalyseur utilisé contenant du nickel ou du cobalt, ou leurs composés en combinaison avec du chrome, du molybdène ou du tungstène, ou leurs composés
C10G 65/12 - Traitement des huiles d'hydrocarbures, uniquement par plusieurs procédés d'hydrotraitement uniquement par plusieurs étapes en série comprenant des étapes de craquage et d'autres étapes d'hydrotraitement
C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p. ex. huiles, acides gras
22.
METHOD FOR CONVERTING LOADS FROM RENEWABLE SOURCES INTO GOOD-QUALITY DIESEL FUEL BASES
The invention to a method for processing loads from renewable sources in order to produce excellent quality diesel fuel bases. The loads used may consist of raw vegetal oils or vegetal oils previously submitted to a pre-refining step, of animal fats, or mixtures of such loads. The invention also relates to a method for obtaining diesel-bases high yields from such loads.
C10G 3/00 - Production de mélanges liquides d'hydrocarbures à partir de matières organiques contenant de l'oxygène, p. ex. huiles, acides gras
C10G 45/08 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage caractérisé par le catalyseur utilisé contenant du nickel ou du cobalt, ou leurs composés en combinaison avec du chrome, du molybdène ou du tungstène, ou leurs composés
C10G 45/62 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour changer la structure du squelette de certains hydrocarbures sans craquer les autres hydrocarbures présents, p. ex. pour abaisser le point d'écoulementHydrocraquage sélectif des paraffines normales caractérisé par le catalyseur utilisé contenant des métaux du groupe du platine ou leur composés
C10G 65/04 - Traitement des huiles d'hydrocarbures, uniquement par plusieurs procédés d'hydrotraitement uniquement par plusieurs étapes en série ne comprenant que des étapes de raffinage
23.
MODULAR REACTOR FOR EXOTHERMIC/ENDOTHERMIC CHEMICAL REACTIONS
Modular reactor for exothermic/endothermic chemical reactions which take place in three-phase systems, comprising a series of modules, superimposed with respect to each other, fixed to each other by means of coupling flanges, each module consisting of an external cylindrical body and a series of tube bundles, for the circulation of a thermal-exchange fluid, positioned inside said body.
B01J 8/00 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées
B01J 8/22 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées l'agent fluidisant étant un liquide du gaz étant introduit dans le liquide
24.
MODULAR REACTOR FOR EXOTHERMIC/ENDOTHERMIC CHEMICAL REACTIONS
Modular reactor for exothermic/endothermic chemical reactions which take place in three-phase systems, comprising a series of modules, superimposed with respect to each other, fixed to each other by means of coupling flanges, each module consisting of an external cylindrical body and a series of tube bundles, for the circulation of a thermal-exchange fluid, positioned inside said body.
B01J 8/00 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés
B01J 8/18 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées
B01J 8/22 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées l'agent fluidisant étant un liquide du gaz étant introduit dans le liquide
25.
CATALYST BASED ON A SILICON-CONTAINING MATERIAL WITH HIERARCHICAL POROSITY AND METHOD FOR THE HYDROCRACKING/HYDROCONVERSION AND HYDROPROCESSING OF HYDROCARBON FEEDSTOCKS
The invention relates to a catalyst including at least one silicon-containing material with hierarchical porosity and at least one hydro-dehydrogenating element from the VIB group and/or the VIII group of the periodic table. The silicon-containing material with hierarchical porosity is formed by at least two spherical elementary particles each comprising zeolitic nanocrystals having a pore size of between 0.2 and 2 nm and a mesostructured silicon-oxide-based matrix having a pore size of between 1.5 and 30 nm and having amorphous walls with a thickness of between 1 and 30 nm, said spherical elementary particles having a maximum diameter of 100 &mgr;m. The silicon-oxide-based matrix can contain aluminium. The catalyst can also optionally contain a controlled amount of at least one dopant selected from among phosphorous, boron and silicon, at least one element from the VB group of the periodic table of elements and an element from the VIIA group. The invention also relates to hydrocracking/hydroconversion and hydroprocessing methods using said catalyst.
B01J 29/076 - Zéolites aluminosilicates cristallinesLeurs composés isomorphes contenant de l'arsenic, de l'antimoine, du bismuth, du vanadium, du niobium, du tantale, du polonium, du chrome, du molybdène, du tungstène, du manganèse, du technétium ou du rhénium
The present invention relates to agglomerated zeolitic adsorbents based on zeolite X with an Si/Al ratio such that 1.15 < Si/Al £ 1.5, consisting of crystals with a mean diameter of 1.7 mm or less and of an inert binder, at least 90% of the exchangeable cationic sites of the zeolite X being occupied by barium ions. They may be obtained by agglomerating zeolite X powder having a mean diameter of 1.7 mm or less with a binder, followed by zeolitization of the binder, exchange of the zeolite ions with barium (and potassium) ions and activation of the adsorbents thus exchanged. These adsorbents exhibit, simultaneously, excellent selectivity, reduced mass transfer resistance and excellent mechanical strength and are particularly suitable for the adsorption of the paraxylene contained in C8 aromatic hydrocarbon fractions in liquid phase in processes of the simulated moving bed type and especially for the separation of paraxylene of C8 aromatic hydrocarbon fractions by adsorption, but also for the separation of sugars, polyhydric alcohols, cresols, and substitute toluene isomers.
Process for preparing at least one cobalt and/or nickel salt of at least one Anderson heterpolyanion combining molybdenum and cobalt or nickel in its structure
b) introducing at least one cobalt precursor and/or at least one nickel precursor into the solution from step a) to form a solution comprising at least said salt in which the (Co+Ni)/Mo mole ratio is in the range 0.25 to 0.85.
The present invention relates to agglomerated zeolitic adsorbents based on zeolite X with an Si/Al ratio such that 1.15 < Si/Al 絛 1.5, consisting of crystals with a mean diameter of 1.7 mm or less and of an inert binder, at least 90% of the exchangeable cationic sites of the zeolite X being occupied by barium ions. They may be obtained by agglomerating zeolite X powder having a mean diameter of 1.7 mm or less with a binder, followed by zeolitization of the binder, exchange of the zeolite ions with barium (and potassium) ions and activation of the adsorbents thus exchanged. These adsorbents exhibit, simultaneously, excellent selectivity, reduced mass transfer resistance and excellent mechanical strength and are particularly suitable for the adsorption of the paraxylene contained in C8 aromatic hydrocarbon fractions in liquid phase in processes of the simulated moving bed type and especially for the separation of paraxylene of C8 aromatic hydrocarbon fractions by adsorption, but also for the separation of sugars, polyhydric alcohols, cresols, and substitute toluene isomers.
This present invention describes a novel type of internal exchanger intended to carry out Fischer-Tropsch synthesis. This exchanger has a modular design and comprises a central tube with partitions allowing at the same time the supply of coolant to the hairpins of the module and the recovery of the partially vaporized fluid from these same hairpins.
F28D 7/00 - Appareils échangeurs de chaleur comportant des ensembles de canalisations tubulaires fixes pour les deux sources de potentiel calorifique, ces sources étant en contact chacune avec un côté de la paroi d'une canalisation
F28D 1/00 - Appareils échangeurs de chaleur comportant des ensembles de canalisations fixes pour une seule des sources de potentiel calorifique, les deux sources étant en contact chacune avec un côté de la paroi de la canalisation, dans lesquels l'autre source de potentiel calorifique est une grande masse de fluide, p. ex. radiateurs domestiques ou de moteur de voiture
F28D 7/10 - Appareils échangeurs de chaleur comportant des ensembles de canalisations tubulaires fixes pour les deux sources de potentiel calorifique, ces sources étant en contact chacune avec un côté de la paroi d'une canalisation les canalisations étant disposées l'une dans l'autre, p. ex. concentriquement
F28F 9/22 - Dispositions pour diriger les sources de potentiel calorifique dans des compartiments successifs, p. ex. aménagement des plaques de guidage
B01J 8/04 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés avec des particules immobiles, p. ex. dans des lits fixes le fluide passant successivement à travers plusieurs lits
B01J 10/00 - Procédés chimiques généraux faisant réagir un liquide avec des milieux gazeux autrement qu'en présence de particules solidesAppareillage spécialement adapté à cet effet
30.
Use of the stationary state of energy-exchanging cellular automata for modelling sedimentary architectures
The invention allows construction of the architecture of sedimentary layers deposited on a topographic surface as a result of the passage of sedimentary currents, using cellular automata. The topographic surface is discretized into a set of cellular automata. Then, for each current and each automaton, a stationary physical state resulting from an iterative process wherein intermediate physical states are constructed by material and energy exchanges between the automata is determined. These automata are thus constructed so as to be representative of the action of the sedimentary currents on the construction of the sedimentary architecture. A set of geologic variables allowing the architecture of the sedimentary layers to be reconstructed is thus deduced from these stationary physical states. Preferred fields of application of the method are oil exploration and production and reservoir characterization.
The invention concerns a process for the hydrodesulphurization of gasoline cuts for the production of gasolines with a low sulphur and mercaptans content. Said process comprises at least two hydrodesulphurization steps, HDS1 and HDS2, operated in parallel on two distinct cuts of the gasoline constituting the feed. The flow rate of hydrogen in the hydrodesulphurization step HDS2 is such that the ratio between the flow rate of hydrogen and the flow rate of feed to be treated is less than 80% of the ratio of the flow rates used to desulphurize in the hydrodesulphurization step HDS1.
C10G 51/06 - Traitement des huiles d'hydrocarbures, en l'absence d'hydrogène, uniquement par plusieurs procédés de craquage uniquement par plusieurs étapes en parallèle
C10G 47/00 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur
C10G 47/02 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur caractérisé par le catalyseur utilisé
C10G 45/60 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour changer la structure du squelette de certains hydrocarbures sans craquer les autres hydrocarbures présents, p. ex. pour abaisser le point d'écoulementHydrocraquage sélectif des paraffines normales caractérisé par le catalyseur utilisé
C07C 5/00 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant le même nombre d'atomes de carbone
C07C 5/373 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant le même nombre d'atomes de carbone par déshydrogénation avec formation d'hydrogène libre avec isomérisation simultanée
B01J 27/047 - Sulfures avec du chrome, du molybdène, du tungstène ou du polonium
32.
FUSION PROTEINS BETWEEN PLANT CELL-WALL DEGRADING ENZYMES AND A SWOLLENIN, AND THEIR USES
VTT TECHNICAL RESEARCH CENTRE OF FINLAND (Finlande)
INSTITUT NATIONAL DE LA RECHERCHE AGRONOMIQUE (France)
UNIVERSITE DE PROVENCE (France)
Inventeur(s)
Record, Eric
Levasseur, Anthony
Soloheimo, Markku
Navarro, David
Andberg, Born Blomster, Martina
Monot, Frédéric
Nakari-Setälä, Tiina
Asther, Marcel
Abrégé
The invention relates to fusion proteins comprising at least a swollenin and at least a plant cell-wall degrading enzyme, said swollenin, and plant cell-wall degrading enzyme, being recombinant proteins corresponding to native proteins in fungi, or mutated forms thereof. The invention also relates to the use of fusion proteins as defined above, for carrying out processes of plant cell-wall degradation in the frame of the preparation, from plants or vegetal by-products, of compounds of interest located in plant cell- wall, or in the frame of the bleaching of pulp and paper, or for biofuel production, or food industries.
Process and installation for conversion of heavy petroleum fractions in a boiling bed with integrated production of middle distillates with a very low sulfur content
A catalyst is described which comprises at least one zeolite of structural type EUO, at least one zeolite selected from zeolite IM-5 and the zeolites of structural types MFI, MOR, BEA and MTW, at least one group VIII metal, at least one group IVA metal, and at least one porous inorganic matrix. The catalyst according to the invention is used in a process for isomerizing a feedstock comprising aromatic compounds having 8 carbon atoms per molecule.
A process is described for preparing a catalyst containing at least one modified zeolite, the said zeolite prior to modification having a maximum pore opening diameter of less than or equal to 7 Å, the said process comprising at least a) a step of introducing at least one metal selected from the metals of groups VIB and VIII of the periodic classification of the elements onto a support based on a protonated zeolite, b) a step of treating the said zeolite in the presence of at least one molecular compound containing at least one silicon atom, the said compound having a diameter greater than the maximum opening diameter of the pores of the said zeolite, and c) at least one step of heat treatment.
B01J 29/064 - Zéolites aluminosilicates cristallinesLeurs composés isomorphes contenant des métaux du groupe du fer, des métaux nobles ou du cuivre
C07C 2/12 - Procédés catalytiques avec des alumino-silicates cristallins, p. ex. avec des tamis moléculaires
C10G 50/00 - Production de mélanges d'hydrocarbures liquides à partir d'hydrocarbures à nombre inférieur d'atomes de carbone, p. ex. par oligomérisation
36.
IRREGULARLY SHAPED, NON-SPHERICAL SUPPORTED CATALYST AND PROCESS FOR HYDROCONVERSION OF HEAVY PETROLEUM FRACTIONS
The present invention relates to a hydrotreating and/or hydroconversion catalyst for heavy hydrocarbon feedstocks containing metals, the said catalyst comprising a support in the form of alumina-based agglomerates, the majority of which are irregular and non-spherical, whose specific form results from a crushing step, and the catalyst containing at least one catalytic metal or a compound of catalytic metal from group VIB and/or from group VIII (groups 8, 9 and 10 in the new notation of the Periodic Table of the Elements), optionally at least one doping element selected from the group consisting of phosphorus, boron, silicon (or silica, which is not part of the silica which might be present in the selected support) and halogens, the said catalyst being composed essentially of a plurality of adjacent agglomerates each formed by a plurality of acicular platelets, the platelets in each agglomerate being oriented generally radially with respect to one another and in relation to the centre of the agglomerate. The specific form of the catalyst endows it with enhanced performance properties in the context of its use for the hydroconversion/hydrotreating of heavy hydrocarbon feedstocks containing metals. The invention likewise relates to the use of the said catalyst, alone or in a mixture, in a fixed-bed or ebullated-bed reactor.
B01J 35/02 - Catalyseurs caractérisés par leur forme ou leurs propriétés physiques, en général solides
B01J 37/00 - Procédés de préparation des catalyseurs, en généralProcédés d'activation des catalyseurs, en général
B01J 37/10 - Traitement thermique en présence d'eau, p. ex. de vapeur d'eau
B01J 23/40 - Catalyseurs contenant des métaux, oxydes ou hydroxydes métalliques non prévus dans le groupe des métaux nobles des métaux du groupe du platine
C10G 45/04 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage caractérisé par le catalyseur utilisé
C10G 45/08 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage caractérisé par le catalyseur utilisé contenant du nickel ou du cobalt, ou leurs composés en combinaison avec du chrome, du molybdène ou du tungstène, ou leurs composés
C10G 47/10 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur caractérisé par le catalyseur utilisé avec des catalyseurs déposés sur un support
B01J 35/10 - Catalyseurs caractérisés par leur forme ou leurs propriétés physiques, en général solides caractérisés par leurs propriétés de surface ou leur porosité
37.
CATALYST COMPRISING AN EUO ZEOLITE, A 10 MR ZEOLITE AND A 12 MR ZEOLITE AND ITS USE IN THE ISOMERISATION OF AROMATIC C8 COMPOUNDS
A catalyst is described, comprising at least one zeolite of EUO structural type, at least one zeolite exhibiting channels whose aperture is defined by a ring with 10 oxygen atoms (10 MR), at least one zeolite exhibiting channels whose aperture is defined by a ring with 12 oxygen atoms (12 MR) and at least one porous mineral matrix. Said catalyst optionally contains in addition at least one metal from group VIII. The catalyst according to the invention is used in an isomerisation process for a charge comprising aromatic compounds with 8 carbon atoms per molecule.
A process for preparing 2,3-dimethylbut-1-ene (2,3-DMB-1) comprises a step (a) of selective dimerization of propylene, in which the propylene is contacted with a catalyst composition comprising at least one nickel compound (constituent A) which is mixed or complexed with at least one tertiary phosphine (constituent B), at least one aromatic hydrocarbon consisting at least partly of mesitylene (constituent C), at least one non-aqueous ionic medium (constituent D) resulting from the mixing of at least one quaternary ammonium halide or of at least one quaternary phosphonium halide (constituent Y) with at least one aluminium halide (constituent Z), and optionally at least one organometallic aluminium compound (constituent T); this step (a) may be followed by a step (b) of distillation of the mixture formed, to give 2,3-DMB-1 in a high purity.
The present invention describes a device allowing secondary filtration of catalyst particles contained in a process effluent comprising a reactor operated in three-phase mode.
B01D 29/00 - Filtres à éléments filtrants stationnaires pendant la filtration, p. ex. filtres à aspiration ou à pression, non couverts par les groupes Leurs éléments filtrants
C10G 2/00 - Production de mélanges liquides d'hydrocarbures de composition non définie à partir d'oxydes de carbone
40.
DEVICE FOR REDISTRIBUTING THE CATALYST IN FCC RISERS
The present invention discloses a device for improving the distribution of the catalyst in the charge injection zone of FCC risers so as to improve the conversion.
B01J 8/24 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés les particules étant fluidisées selon la technique du "lit fluidisé"
C10G 11/18 - Craquage catalytique, en l'absence d'hydrogène, des huiles d'hydrocarbures avec catalyseurs solides mobiles préchauffés selon la technique du "lit fluidisé"
41.
METHOD FOR DEACIDIFYING A GAS WITH A FRACTIONALLY-REGENERATED ABSORBENT SOLUTION WITH CONTROL OF THE WATER CONTENT OF THE SOLUTION
The present invention relates to a method for deacidifying a gaseous effluent, in which the following steps are carried out: a) the gaseous effluent is brought into contact with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being chosen for its property of forming two separable phases when it absorbs an amount of acid compounds; b) the absorbent solution laden with acid compounds is separated into two fractions: a first fraction of absorbent solution depleted in acid compounds and a second fraction of absorbent solution enriched with acid compounds; c) the second fraction is regenerated so as to release some of the acid compounds; d) a set amount of water is mixed with the first absorbent solution fraction obtained in step b) or with the regenerated absorbent solution fraction obtained in step c); then e) the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution.
B01D 53/14 - Séparation de gaz ou de vapeursRécupération de vapeurs de solvants volatils dans les gazÉpuration chimique ou biologique des gaz résiduaires, p. ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols par absorption
42.
Device for mixing and distributing a gas and a liquid upstream from a granular bed
The invention relates to a device for mixing and distributing a gas and a liquid, arranged upstream from a granular bed. The device includes a substantially horizontal lower plate, said lower plate being equipped with a plurality of risers evenly distributed over the surface of said plate, each riser having an upper part and a lower end communicating with the underside of said plate, the upper part of the risers being provided with at least one lateral orifice. A substantially horizontal upper plate is provided above which the gas and the liquid are supplied, wherein said upper plate rests on risers extending upwardly from the lower plate.
Method for determining acid gas storage capacities of an underground geologic medium by means of a multiphase reactive transport model.
The geologic medium is divided into a set of sub-volumes for which connections are defined. A multiphase reactive transport model is then defined by dividing, according to a transfer rate principle, the phenomena involved in the behaviour of said geologic medium into two parts. A first part is treated by a first sub-model of “compositional multiphase reservoir” type allowing the transfer rates linked with the gas phase to be determined. A second part is treated by a model of “single-phase reactive transport” type allowing the transfer rates linked with the water and the solid to be determined. The model is initialized by means of data acquired in the field or in the laboratory. The acid gas storage capacities of the medium are determined from the reactive transport model.
Application: acid gas storage in a natural reservoir.
An organic/inorganic hybrid material (OIHM) consisting of elementary spherical particles is described, each of said spherical particles consisting of a mesostructured matrix based on silicon oxide and of organic groups having reactive terminal functions linked covalently to the inorganic structure, said mesostructured matrix having a pore size between 1.5 and 30 nm and having amorphous walls with a thickness between 1 and 20 nm. Said elementary spherical particles have a maximum diameter of 10 쎽m. The silicon-oxide-based matrix may contain aluminium, titanium, zirconium and cerium. Two methods of preparing said material are also described.
A new EUO-structural-type zeolite that comprises at least one tetravalent element X that is selected from among silicon, tin, titanium and germanium and optionally at least one trivalent element T that is selected from among aluminum, iron, boron, indium and gallium is described. This new zeolite is characterized in that it contains, in its crude synthesis form, the nitrogen-containing organic cation of formula N,N-dimethyl-N,N-di(3,3-dimethylbutyl)ammonium. A method for the preparation of this zeolite is also described.
C01B 33/36 - Silicates ayant des propriétés d'échangeurs de base, mais n'ayant pas de propriétés de tamis moléculaires
C01B 39/04 - Zéolites aluminosilicates cristallinesLeurs composés isomorphesLeur préparation directeLeur préparation à partir d'un mélange réactionnel contenant une zéolite cristalline d'un autre type, ou à partir de réactants préformésLeur post-traitement utilisant au moins un agent structurant organique, p. ex. un composé d'ammonium quaternaire ionique ou un composé aminé
B01J 21/00 - Catalyseurs contenant les éléments, les oxydes ou les hydroxydes du magnésium, du bore, de l'aluminium, du carbone, du silicium, du titane, du zirconium ou du hafnium
B01J 29/00 - Catalyseurs contenant des tamis moléculaires
46.
METHOD FOR QUANTITATIVELY EVALUATING FLUID PRESSURES AND FOR DETECTING EXCESS PRESSURES OF AN UNDERGROUND MEDIUM
The invention relates to a method for evaluating fluid pressures in an underground area with the help of seismic data and of wells. The area of study is divided into a number of time analysis intervals. For each of these intervals, a stratigraphic inversion is realized before the summation of the seismic data, while using a priori geological information, and a lithoseismic facies cube is determined by lithoseismic analysis. For each facies, relationships linking the seismic impedances of wells to differential pressures of wells, during each of the analysis intervals. Lastly, a differential pressure cube is determined by using the preceding relationships as well as to a containment pressure cube for determining the fluid pressures underground by the simple difference between these two cubes. The invention is for use in the petroleum industry for detecting areas of excess pressure during drilling, for example.
The invention relates to a method and to a device for direct measurement of isotopic ratios of trace elements in organic matrices. The invention comprises a mixture of two aerosols, one of which is produced from a sample which is organic, or which has an organic matrix.
H01J 49/04 - Dispositions pour introduire ou extraire les échantillons devant être analysés, p. ex. fermetures étanches au videDispositions pour le réglage externe des composants électronoptiques ou ionoptiques
48.
METHOD FOR THE SYNTHESIS OF A CATALYST BASED ON ANISOTROPIC METAL NANOPARTICLES, IN THE PRESENCE OF A REDUCING AGENT
The invention relates to a method for the preparation of metal nanoparticles having an anisotropic nature, using two different reducing agents which preferably have different reducing powers, on a source of a metal which is selected from columns 8, 9 or 10 of the periodic table of elements.
B22F 9/24 - Fabrication des poudres métalliques ou de leurs suspensionsAppareils ou dispositifs spécialement adaptés à cet effet par un procédé chimique avec réduction de mélanges métalliques à partir de mélanges métalliques liquides, p. ex. de solutions
C01B 3/00 - HydrogèneMélanges gazeux contenant de l'hydrogèneSéparation de l'hydrogène à partir de mélanges en contenantPurification de l'hydrogène
C10G 2/00 - Production de mélanges liquides d'hydrocarbures de composition non définie à partir d'oxydes de carbone
C10G 35/085 - Réformage catalytique caractérisé par le catalyseur utilisé contenant des métaux du groupe du platine ou leurs composés
C10G 45/00 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène
C10G 45/40 - Hydrogénation sélective des composés dioléfiniques ou acétyléniques caractérisée par le catalyseur utilisé contenant des métaux du groupe du platine ou leurs composés
C10G 45/52 - Hydrogénation des hydrocarbures aromatiques caractérisée par le catalyseur utilisé contenant des métaux du groupe du platine ou leurs composés
B01J 23/40 - Catalyseurs contenant des métaux, oxydes ou hydroxydes métalliques non prévus dans le groupe des métaux nobles des métaux du groupe du platine
This invention describes a method for determining the content of conjugated diolefins by means of the measurement of the MAV of a sample of catalytic cracking gasoline or thermal cracking gasoline, from its NIR (near-infrared) spectrum, and the application of said method for monitoring a unit for selective hydrogenation of the cracking gasolines.
G06F 19/00 - Équipement ou méthodes de traitement de données ou de calcul numérique, spécialement adaptés à des applications spécifiques (spécialement adaptés à des fonctions spécifiques G06F 17/00;systèmes ou méthodes de traitement de données spécialement adaptés à des fins administratives, commerciales, financières, de gestion, de surveillance ou de prévision G06Q;informatique médicale G16H)
50.
USE OF POLYAMIDE 11 FOR INTERNAL COATING OF A GAS PIPELINE FOR REDUCING PRESSURE DROPS
F16L 11/12 - Manches, c.-à-d. tuyaux flexibles en caoutchouc ou en matériaux plastiques flexibles avec agencements pour usages particuliers, p. ex. spécialement profilés, avec couche protectrice, chauffés, conducteurs d'électricité
F16L 9/12 - Tuyaux rigides en plastique avec ou sans armature
51.
CIRCUIT FOR SUPPLYING A SUPERCHARGED ENGINE WITH AT LEAST ONE FLUID AND METHOD OF SUPPLYING SUCH AN ENGINE WITH AT LEAST ONE FLUID
The invention relates to a circuit for supplying an internal combustion engine, particularly a diesel engine, with at least one fluid. The invention consists of: a circuit for supercharging air (20) at the intake of the engine, which is equipped with a supercharging pipe (36), a supercharging device (28) comprising a compression stage (26) and a radiator (38) for cooling the compressed air; and a circuit for recirculating the exhausts gases (22) at the intake of the engine, comprising an exhaust gas recirculation pipe (40) and an exhaust gas cooler (46). According to the invention, the supply circuit comprises a connecting line (50) which is used to connect the air supercharging circuit (20) and the exhaust gas recirculation circuit (22) upstream of the cooler (46).
The invention concerns a method for eliminating the fuel contained in the lubricating oil of an internal combustion engine comprising a cylinder block (10) with an air intake circuit for an air-fuel mixture, a burnt gas exhaust circuit, an oil pan (44) and means for pumping (48) the oil contained in the pan. The invention is characterized in that the method consists in eliminating, after pumping the oil, the fuel diluted in the oil.
F01M 11/08 - Séparation du lubrifiant de l'air ou du mélange air-carburant avant introduction dans le cylindre
F16N 39/00 - Dispositions pour conditionner des lubrifiants dans les circuits de lubrification
53.
METHOD FOR CONTROLLING SELF-IGNITION OF AN AIR-FUEL MIXTURE, IN PARTICULAR FOR A DIESEL-TYPE INTERNAL COMBUSTION ENGINE, AND ENGINE USING SUCH A METHOD
The invention concerns a method for controlling self-ignition of an air-fuel mixture, in particular for a Diesel-type internal combustion engine which consists in: providing, in at least one combustion chamber (14) of the engine, an air-fuel mixture with a fuel and at least one fluid to obtain a homogeneous combustion via self-ignition. The invention is characterized in that the method consists in: a) defining the desired scheme for the combustion by self-ignition of the air-fuel mixture; b) adapting the hexadecane index of the fuel used for the mixture to that of the fuel, thereby obtaining the desired combustion scheme.
F02D 41/00 - Commande électrique de l'alimentation en mélange combustible ou en ses constituants
F02D 41/30 - Commande de l'injection de combustible
F02D 35/02 - Commande non électrique des moteurs en fonction des conditions extérieures ou intérieures aux moteurs, non prévue ailleurs des conditions intérieures
F02B 1/12 - Moteurs caractérisés par la compression d'un mélange air-combustible avec allumage par compression
54.
RISER COMPRISING AUXILIARY DUCTS WHICH ARE MOUNTED TO JOURNALS
The invention relates to a riser segment comprising: a main tube (2), at least one auxiliary duct element (3) which is essentially parallel to the main tube (2), and at least two fixing means (7, 8) which connect the ends of the element (3) to the main tube (2). The segment is characterised in that the fixing means (7, 8) can be used to transmit longitudinal stresses from the element (3) to the main tube (2) and in that at least one fixing means (7, 8) authorises at least one rotational movement of the element (3) in relation to the main tube (2), said rotational movement being performed about an axis that is perpendicular to the plane that cuts through the axis (4) of the main shaft and the axis of the auxiliary duct element (3).
The invention relates to a riser segment comprising a main tube (2) and at least one auxiliary duct element (3) which is disposed essentially parallel to the tube (2). The invention is characterised in that the ends of the main tube (2) comprise connection means (8) which can be used to transmit longitudinal stresses and in that the ends of the auxiliary duct element (3) comprise connection means (5-6) which can be used to transmit longitudinal stresses.
The invention relates to an oxycombustion method comprising the capture of the CO2 produced. According to the invention, a mixer (M) supplies a chamber (CC) with a mixture of oxygen originating from a unit (O) and with recycled fumes originating from a storage tank (SG). The chamber (CC) is supplied with oxidant from the mixer (M) and with fuel that arrives through a duct (8). All of the combustion fumes are directed towards the water condensation unit (CT) and subsequently introduced into the storage tank (SG). Moreover, the part of the fumes containing all of the CO2 produced by combustion is compressed at up to 60 bars, subsequently cooled and partially liquefied at approximately 15 °C in the liquefaction unit (LI) and finally stored in the tank (SM). According to the invention, the partially liquefied CO2 is compressed using a multiphase pump in order to be discharged through a duct (16) and stored in an underground tank.
F23J 15/06 - Aménagement des dispositifs de traitement de fumées ou de vapeurs des appareils de refroidissement
F23L 7/00 - Alimentation du foyer en liquides ou gaz non combustibles autres que l'air, p. ex. oxygène, vapeur d'eau
B01D 53/00 - Séparation de gaz ou de vapeursRécupération de vapeurs de solvants volatils dans les gazÉpuration chimique ou biologique des gaz résiduaires, p. ex. gaz d'échappement des moteurs à combustion, fumées, vapeurs, gaz de combustion ou aérosols
F04D 31/00 - Pompage simultané de liquides et de fluides compressibles
F17C 1/00 - Récipients sous pression, p. ex. bouteilles de gaz, réservoirs de gaz, cartouches échangeables
57.
METHOD FOR PRODUCING A HOT GAS BY OXIDATION COMPRISING A DELAY PRIOR TO SCAVENGING
The invention concerns an optimized method for producing a hot gas by oxidizing an active material having a oxidized form and a reduced form using a rotary reactor, or a simulated rotation reactor. The invention is characterized in that the production cycle includes an interruption of flow between an oxidizing phase and a scavenging phase.
The invention concerns a method for estimating in real time the instantaneous speed produced by each of the cylinders of an internal combustion engine, based on a measurement of the instantaneous speed at the end of the engine transmission system. The method consists in constructing a physical model representing in real time the dynamics of the transmission system based on the crankshaft angle and coefficients of a serial Fourier decomposition of the instantaneous speed produced by each of the cylinders; in determining in real time said coefficients based on a coupling between the model and an adaptive type non-linear estimator; deducing therefrom said coefficients of the instantaneous speed produced by each of the cylinders. The average torque produced by each cylinder may also be deduced therefrom. The invention is applicable to engine controls.
F02D 41/14 - Dispositions de circuits pour produire des signaux de commande introduisant des corrections à boucle fermée
F02D 41/34 - Commande de l'injection de combustible du type à basse pression avec des moyens pour commander la synchronisation ou la durée de l'injection
59.
IMPROVED METHOD FOR MAKING ETHYL ESTERS FROM NATURAL FATS
The invention concerns a method for obtaining quasi-quantitative fatty acid ethyl esters useful as diesel oil substitutes, from natural, vegetable or animal, oils or fats, or other mixtures of glycerides, including the following successive steps: a step (a) which consists in transesterifying the oil, fat or the mixture of glycerides with ethanol using a soluble catalyst, or a catalyst becoming soluble during the reaction; a step (b) which consists in decanting and eliminating the formed glycerin, without resorting to evaporation of excess ethanol; a step (c) which consists in performing a second transesterification reaction to obtain a product whereof the ester content is at least 97 wt. %; a step (d) which consists in evaporating excess ethanol in the presence of a catalyst in conditions adapted to avoid inverse reaction of transesterification, the ethanol obtained being practically anhydrous (it may be recycled in the process without being rectified); a step (e) which consists in purifying the ester by washing sequences with water; and a step (f) which consists in drying the mixture of ester under reduced pressure.
The invention concerns reconstituted non-asphaltene oil Pa, comprising at least 28 wt. % of naphtha N, having a ratio R not less than 1,5 and a gasoline potential POTe ranging between 47 and 70, with: R = (0.9 N + 0.5 VGO+) / (MD + 0.1 VGO+), POTe = 0.9 N + 0.5 VGO+, wherein, in wt. %: N = naphtha [300C / 1700C]; MD = middle distillates: ]170 °C / 360 °C] and VGO+ = fraction boiling above 360 °C. R represents the relative gasoline potential of a non-residual oil relative to the middle distillates, upon being subsequently refined.
C10G 45/14 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage avec des particules solides en mouvement
C10G 47/24 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur avec des particules solides en mouvement
C10G 65/18 - Traitement des huiles d'hydrocarbures, uniquement par plusieurs procédés d'hydrotraitement uniquement par plusieurs étapes en parallèle ne comprenant que des étapes de craquage
C10G 67/04 - Traitement des huiles d'hydrocarbures, uniquement par au moins un procédé d'hydrotraitement et au moins un procédé de raffinage en l'absence d'hydrogène uniquement par plusieurs étapes en série comprenant une extraction par solvant comme étape de raffinage en l'absence d'hydrogène
61.
IMPROVED METHOD FOR MAKING ETHYL ESTERS FROM NATURAL FATS
The invention concerns a method for obtaining quasi-quantitative fatty acid ethyl esters useful as diesel oil substitutes, from natural, vegetable or animal, oils or fats, or other mixtures of glycerides, including the following successive steps: a step (a) which consists in transesterifying the oil, fat or the mixture of glycerides with ethanol using a soluble catalyst, or a catalyst becoming soluble during the reaction; a step (b) which consists in decanting and eliminating the formed glycerin, without resorting to evaporation of excess ethanol; a step (c) which consists in performing a second transesterification reaction to obtain a product whereof the ester content is at least 97 wt. %; a step (d) which consists in controlled neutralizing of the catalyst; a step (e) which consists in eliminating by distillation excess ethanol; a step (f) which consists in purifying the ester by washing sequences with water; and a step (g) which consists in drying the mixture of ester under reduced pressure.
Process for the charging of a catalyst and for the running of a reactor in which reactions take place in multiphase systems, wherein a gaseous phase prevalently consisting of CO and H2 is bubbled into a suspension of a solid in the form of particles (catalyst) in a liquid (prevalently reaction product), according to the Fischer-Tropsch technology.
The invention concerns a method for making linear monocarboxylic acid ethyl esters of 6 to 26 carbon atoms from acid or neutral, virgin or recycled vegetable or animal oils. The method is characterized in that it includes: a step (1) which consists in reacting said vegetable or animal oil, with methanol, in the presence of a heterogeneous catalyst comprising a combination formed between at least one metal oxide and alumina or a combination formed between at least two oxides and optionally with alumina; and a step (2) which consists in reacting the product derived from step (1), with ethanol in the presence of a heterogeneous catalyst such as the heterogeneous catalyst defined for use in step (1). Said method enables a mixture of fatty acid esters rich in fatty acid ethyl esters and a high purity glycerin to be obtained from vegetable or animal oils.
C11C 3/10 - Graisses, huiles ou acides gras obtenus par transformation chimique des graisses, huiles ou acides gras, p. ex. ozonolyse par estérification des graisses ou des huiles par interestérification
C07C 67/03 - Préparation d'esters d'acides carboxyliques par réaction d'un groupe ester avec un groupe hydroxyle
C07C 69/24 - Esters d'acides acycliques monocarboxyliques saturés dont le groupe carboxyle est lié à un atome de carbone acyclique ou à l'hydrogène avec au moins trois atomes de carbone dans la partie acide estérifiés par des composés monohydroxylés
C07C 69/52 - Esters d'acides acycliques carboxyliques non saturés dont le groupe carboxyle estérifié est lié à un atome de carbone acyclique
64.
CO2 EMISSION-FREE ENERGY PRODUCTION BY GAS TURBINE
The invention concerns a method for reducing CO2 rate present in fumes released by a power generator burning a mixture of oxidant and fuel containing hydrocarbons, which consists in expanding the combustion fumes, compressing a gas mixture comprising the oxidant and the fumes, eliminating at least part of the CO2 present in a first part of the compressed mixture and recycling a second part of the compressed mixture so as to carry out combustion. The invention also concerns a device for implementing the method.
F02C 3/34 - Ensembles fonctionnels de turbines à gaz caractérisés par l'utilisation de produits de combustion comme fluide de travail avec recyclage d'une partie du fluide de travail, c.-à-d. cycles semi-fermés comportant des produits de combustion dans la partie fermée du cycle
65.
METHOD FOR THE DESULPHURISATION OF OLEFINIC GASOLINES, COMPRISING SULPHUR COMPOUND WEIGHTING WITH CATALYST REGENERATION
The invention relates to a method for the desulphurisation of olefinic gasolines, consisting of a sulphur compound weighting reaction comprising alkylation on the olefins in the feedstock, using an acid catalyst and comprising regeneration of the catalyst which may be performed sequentially or continuously.
C10G 25/05 - Élimination des composés autres que des hydrocarbures, p. ex. des composés soufrés
C10G 57/00 - Traitement des huiles d'hydrocarbures, en l'absence d'hydrogène, par au moins un procédé de craquage ou de raffinage et au moins un autre procédé de conversion
66.
FILTER PLATE FOR A FIXED-BED REACTOR WITH A CO-CURRENT GAS-LIQUID DOWNFLOW
The invention relates to a device for trapping clogging particles contained in the liquid charge used to feed a reactor with a co-current gas-liquid downflow, using a specific feed plate comprising a filter medium. The invention is particularly suitable for the selective hydrogenation treatment of charges containing diene and acetylene compounds.
C10G 49/00 - Traitement des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, non prévu dans un seul des groupes , , , ou
B01J 8/02 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés avec des particules immobiles, p. ex. dans des lits fixes
B01J 8/04 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés avec des particules immobiles, p. ex. dans des lits fixes le fluide passant successivement à travers plusieurs lits
67.
FUSION PROTEINS BETWEEN PLANT CELL-WALL DEGRADING ENZYMES, AND THEIR USES
INSTITUT NATIONAL DE LA RECHERCHE AGRONOMIQUE (France)
INSTITUT FRANCAIS DU PETROLE (France)
Inventeur(s)
Levasseur, Anthony
Navarro, David
Punt, Peter
Belaïch, Jean-Pierre
Asther, Marcel
Monot, Frédéric
Record, Eric
Abrégé
The invention relates to the use of fusion proteins between at least two plant cell-wall degrading enzymes, said enzymes being such that they do not contain a C-terminal carbohydrate-binding-molecule (CBM), and optionally a CBM, said enzymes and CBM being recombinant proteins corresponding to native proteins in fungi, or mutated forms thereof, for carrying out processes of plant cell-wall degradation in the frame of the preparation, from plants or vegetal by-products, of compounds of interest located in plant cell-wall, or in the frame of the bleaching of pulp and paper.
The invention relates to a gasoline desulfurization method consisting of a step in which the gasoline is fractionated into a light fraction comprising thiophenic compounds, such as thiophene or methylthiophenes, and a heavy fraction concentrating the heaviest aromatic sulfur compounds. The heavy fraction is treated by hydrodesulfurization, while the light fraction is brought into contact with a solid adsorbent that can be used to eliminate at least part of the light thiophenic compounds, said solid adsorbent being regenerated by a flux within the method.
C10G 67/16 - Traitement des huiles d'hydrocarbures, uniquement par au moins un procédé d'hydrotraitement et au moins un procédé de raffinage en l'absence d'hydrogène uniquement par plusieurs étapes en parallèle
69.
Process for desulphurizing gasoline by converting sulphur-containing compounds to higher boiling point compounds
C10G 25/05 - Élimination des composés autres que des hydrocarbures, p. ex. des composés soufrés
C07C 2/54 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant un plus petit nombre d'atomes de carbone par addition d'hydrocarbures non saturés à des hydrocarbures saturés, ou à des hydrocarbures contenant un cycle aromatique à six chaînons ne comportant pas d'autre insaturation que celle du cycle aromatique
70.
Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process using a multifunctional guard bed
The process of producing middle distillates from effluents obtained by a Fischer-Tropsch synthesis, comprises a step for hydro-treatment and purification and/or decontamination by passage over a multi-functional guard bed prior to a step of hydrocracking/hydroisomerization. The guard bed reduces the amount of unsaturated compounds, oxygen-containing compounds, particulate mineral solids, and organometallic compounds.
C10G 65/00 - Traitement des huiles d'hydrocarbures, uniquement par plusieurs procédés d'hydrotraitement
C10G 69/00 - Traitement des huiles d'hydrocarbures par au moins un procédé d'hydrotraitement et au moins un autre procédé de conversion
C10G 47/00 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur
71.
METHOD FOR PRODUCING MIDDLE DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF FEEDS DERIVED FROM A FISCHER-TROPSCH PROCESS USING A MULTIFUNCTIONAL GUARD BED
The invention concerns a method for producing middle distillates from effluents obtained by Fischer-Tropsch synthesis, including a step of hydrotreatment and purification and/or decontamination on a multifunctional guard bed. The invention also concerns an installation.
C10G 2/00 - Production de mélanges liquides d'hydrocarbures de composition non définie à partir d'oxydes de carbone
C10G 45/38 - Hydrogénation sélective des composés dioléfiniques ou acétyléniques caractérisée par le catalyseur utilisé contenant du nickel ou du cobalt, ou leurs composés en combinaison avec du chrome, du molybdène ou du tungstène, ou leurs composés
C10G 47/14 - Supports inorganiques le catalyseur contenant des métaux du groupe du platine ou leurs composés
72.
POLYPEPTIDES HAVING AN ACTIVITY IN THE MTBE DEGRADATION PATH AND USES THEREOF
The invention concerns an isolated or purified polypeptide having an activity in the MTBE degradation path, and/or at least one of the catabolic intermediates of MTBE, preferably selected from the group consisting of tert-butyl alcohol (TBA), 2-methyl 1,2-propanediol (2 -M1, 2-PD), hydroxyisobutyraldehyde, hydroxyiso-butyric acid (HIBA), said polypeptide being selected from the group consisting of: a) a polypeptide comprising a sequence of amino acids selected from the group consisting of SEQ ID NO:2, SEQ ID NO:4, SEQ ID NO:6, SEQ ID NO:8 or SEQ ID NO:10; b) a polypeptide comprising a sequence of amino acids having at least 70 % identity, preferably 75 %, 80 %, 90 %, 95 %, 98 % or 99 % with the sequence of amino acids of a polypeptide as defined in a); a polypeptide as defined in a) or b) whereof the sequence of amino acids comprises a substitution, deletion, insertion, addition or mutation of one or several amino acids over its entire length.
C07K 14/35 - Peptides ayant plus de 20 amino-acidesGastrinesSomatostatinesMélanotropinesLeurs dérivés provenant de bactéries provenant de Mycobacteriaceae (F)
C12N 9/02 - Oxydoréductases (1.), p. ex. luciférase
C12N 9/04 - Oxydoréductases (1.), p. ex. luciférase agissant sur des groupes CHOH comme donneurs, p. ex. oxydase de glucose, déshydrogénase lactique (1.1)
C12N 15/63 - Introduction de matériel génétique étranger utilisant des vecteursVecteurs Utilisation d'hôtes pour ceux-ciRégulation de l'expression
C12Q 1/68 - Procédés de mesure ou de test faisant intervenir des enzymes, des acides nucléiques ou des micro-organismesCompositions à cet effetProcédés pour préparer ces compositions faisant intervenir des acides nucléiques
C12N 15/11 - Fragments d'ADN ou d'ARNLeurs formes modifiées
73.
PROCESS FOR THE PREPARATION OF FISCHER-TROPSCH CATALYSTS WITH A HIGH MECHANICAL, THERMAL AND CHEMICAL STABILITY
The preparation is described of a Fischer-Tropsch catalytic precursor based on cobalt supported on alumina, optionally containing up to 10% by weight of silica, which comprises: a) treatment of the alumina with a silicon compound selected from those having general formula (I) Si(OR)4-nR'n (I) wherein n ranges from 1 to 3 wherein R' is selected from primary hydrocarbyl radicals having from 1 to 20 carbon atoms; wherein R is selected from primary hydrocarbyl radicals having from 1 to 6 carbon atoms ; b) drying and subsequent calcination of the modified carrier obtained at the end of step (a) thus obtaining a silanized carrier; c) subsequent deposition of cobalt on the silanized carrier obtained at the end of step (b) ; d) drying and subsequent calcination of the supported cobalt obtained at the end of step (c) thus obtaining the final catalytic precursor; the above final catalytic precursor having a content of SiO2 deriving from the compound having general formula (I) ranging from 4.5 to 10% by weight.
C10G 2/00 - Production de mélanges liquides d'hydrocarbures de composition non définie à partir d'oxydes de carbone
B01J 31/02 - Catalyseurs contenant des hydrures, des complexes de coordination ou des composés organiques contenant des composés organiques ou des hydrures métalliques
B01J 37/02 - Imprégnation, revêtement ou précipitation
74.
Process for preparing a gas oil by oligomerization
C07C 2/00 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant un plus petit nombre d'atomes de carbone
75.
METHOD OF PRODUCING MIDDLE DISTILLATES, COMPRISING THE HYDROISOMERISATION AND HYDROCRACKING OF FEEDSTOCKS RESULTING FROM THE FISCHER-TROPSCH METHOD, USING A DOPED CATALYST BASED ON MESOPOROUS ALUMINA-SILICA HAVING A CONTROLLED MACROPORE CONTENT
The invention relates to a method of producing middle distillates from a paraffinic feedstock produced by means of Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerisation catalyst comprising: at least one hydro-dehydrogenating element which is selected from the group containing the elements from group VIB and group VII of the periodic table of elements, between 0.01 and 6 % phosphorus as a doping element, and a non-zeolitic support based on mesoporous alumina-silica.
B01J 27/00 - Catalyseurs contenant les éléments halogènes, soufre, sélénium, tellure, phosphore ou azote ou leurs composésCatalyseurs contenant des composés du carbone
B01J 23/40 - Catalyseurs contenant des métaux, oxydes ou hydroxydes métalliques non prévus dans le groupe des métaux nobles des métaux du groupe du platine
C10G 45/02 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage
C10G 65/14 - Traitement des huiles d'hydrocarbures, uniquement par plusieurs procédés d'hydrotraitement uniquement par plusieurs étapes en parallèle
76.
METHOD FOR THE TREATMENT OF A SMALL- AND/OR MEDIUM-PORE ZEOLITE AND USE THEREOF IN THE OLIGOMERISATION OF LIGHT OLEFINS
The invention relates to a method for the treatment of at least one zeolite having a pore size of less than or equal to 7 Å, comprising at least a) a step involving the dealumination of the zeolite, b) a step involving cation exchange with at least one cation other than H+, c) a step involving the treatment of the zeolite obtained in step (b) in the presence of at least one molecular compound containing at least one silicon atom, and d) at least one heat treatment step. The invention also relates to the preparation of a catalyst containing the zeolite treated using the inventive treatment method and to the use of said catalyst in a method for the oligomerisation of an olefin feed containing hydrocarbon molecules having between 2 and 12 carbon atoms per molecule.
C01B 39/00 - Composés ayant des propriétés de tamis moléculaires et d'échangeurs de base, p. ex. zéolites cristallinesLeur préparationPost-traitement, p. ex. échange d'ions ou extraction de l'aluminium
77.
EUO STRUCTURAL TYPE ZEOLITE CONTAINING THE CATION N,N- DIMETHYL-N,N-DI(3,3-DIMETHYLBUTYL)AMMONIUM, AND THE PRODUCTION METHOD THEREOF
The invention relates to a novel EUO structural type zeolite containing at least one tetravalent element X selected from silicon, tin, titanium and germanium and optionally at least one trivalent element T selected from aluminium, iron, boron, indium and gallium. Said novel zeolite is characterised in that it contains, in the raw synthesis form thereof, the nitrogenated organic cation of formula N,N-dimethyl-N,N-di(3,3-dimethylbutyl)ammonium. The invention also relates to a method for producing said zeolite.
C01B 39/48 - Autres types caractérisés par leur diagramme de diffraction des rayons X et par leur composition définie utilisant au moins un agent structurant organique
78.
SOFT HYDROCRACKING METHOD INCLUDING DILUTION OF THE FEEDSTOCK
The invention concerns an FCC pretreatment method by soft hydrocracking of a hydrocarbon feedstock comprising a distillate fraction under vacuum or a deasphalted oil or a mixture of those two fractions, called main feedstock, to produce diesel oil and an effluent having an initial boiling point higher than 320 °C, said effluent (FCC feedstock) being then subjected to a catalytic cracking; method whereby at least 85 wt. % of said main feedstock boils above 375 °C and at least 95 wt. % of said main feedstock boils below 650 °C, the soft hydrocracking being carried out under an absolute pressure of 2 to 12 MPa's and at a temperature ranging between 300 and 500 °C. Said method is characterized in that the hydrocarbon feedstock further comprises a lighter hydrocarbon fraction, called secondary feedstock, whereof at least 50 wt. % boils below 375 °C and at least 80 wt. % boils above 200 °C.
C10G 47/00 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur
C10G 69/04 - Traitement des huiles d'hydrocarbures par au moins un procédé d'hydrotraitement et au moins un autre procédé de conversion uniquement par plusieurs étapes en série comprenant au moins une étape de craquage catalytique en l'absence d'hydrogène
79.
INORGANIC MATERIAL COMPRISING METAL NANOPARTICLES TRAPPED IN A MESOSTRUCTURED MATRIX
The invention concerns an inorganic material consisting of at least two elementary spherical particles, each of said spherical particles including metal nanoparticles of size ranging between 1 and 300 nm and a mesostructured matrix based on oxide of at least one element X selected among the group consisting of aluminum, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium, said matrix having a size of pores ranging between 1.5 and 30 nm and having amorphous walls of thickness ranging between 1 and 30 nm, said elementary spherical particles having a maximum diameter of 10 νm. Said material may also contain zeolite nanocrystals trapped inside said mesostructured matrix.
C01B 39/00 - Composés ayant des propriétés de tamis moléculaires et d'échangeurs de base, p. ex. zéolites cristallinesLeur préparationPost-traitement, p. ex. échange d'ions ou extraction de l'aluminium
80.
MESOSTRUCTURED MATERIAL WITH HIGH ALUMINUM CONTENT
The invention concerns a mesostructured material consisting of at least two elementary spherical particles, each of said particle including a mesotructured matrix based on aluminum oxide, having a size of pores ranging between 1.5 and 30 nm, an aluminum oxide content representing more than 46 wt. % based on the weight of said matrix, which has amorphous walls of thickness ranging between 1 and 20 nm, said elementary spherical particles having a maximum diameter or 10 νm. Said mesostructured matrix may also contain silicon oxide. Each of the spherical particles of the mesostructured material may also contain zeolite nanocrystals so as to form a material with mixed porosity of both mesostructured and zeolitic-type porosity. The invention also concerns the preparation of said material.
C01B 39/00 - Composés ayant des propriétés de tamis moléculaires et d'échangeurs de base, p. ex. zéolites cristallinesLeur préparationPost-traitement, p. ex. échange d'ions ou extraction de l'aluminium
81.
METHOD FOR ANALYSING A GAS HYDRATE FORMATION KINETICS IN FLUIDS
The invention relates to a method for determining a gas hydrate formation kinetics in a water-containing fluid consisting in providing a fluid sample in the form of a stable water-in-oil emulsion, in carrying out DSC measurements on the sample in such a way that at least one peak corresponding to the gas hydrate conversion energy in water drops of said emulsion is obtainable and in deriving kinetic characteristics of the hydrate formation in the fluid from said peak.
G01N 25/14 - Recherche ou analyse des matériaux par l'utilisation de moyens thermiques en utilisant la distillation, l'extraction, la sublimation, la condensation, la congélation ou la cristallisation
82.
Method of sedimentologic interpretation by estimation of various chronological scenarios of sedimentary layers deposition
A method having application for the development of oil reservoirs for automatically extracting from a seismic image pertinent information for sedimentologic interpretation by using estimations of realistic chronological scenarios of sedimentary layers deposition. The method includes iterative estimation of a first and of a second chronological scenario of the deposition of sedimentary layers, assuming that each reflector settles at the earliest and at the latest possible moment during the sedimentary depositional process. A chronological level number is assigned to a group of initial reflectors. Then a chronological level number is incremented by one and decremented by one which numbers are assigned to the reflectors including pixels located above and respectively below the initial reflectors and above and respectively below no other reflector. An interpretation of these two chronological scenarios is eventually carried out so as to reconstruct the depositional conditions of the sedimentary layers.
G06F 19/00 - Équipement ou méthodes de traitement de données ou de calcul numérique, spécialement adaptés à des applications spécifiques (spécialement adaptés à des fonctions spécifiques G06F 17/00;systèmes ou méthodes de traitement de données spécialement adaptés à des fins administratives, commerciales, financières, de gestion, de surveillance ou de prévision G06Q;informatique médicale G16H)
83.
METHOD FOR PRE-REFINING CRUDE OIL WITH A MULTISTEP MODERATED HYDROCONVERSION OF VIRGIN ASPHALT IN THE PRESENCE OF A DILUENT
The invention relates to a method for prerefining crude oil P during which P is fractionated into a number of fractions, typically, certain fractions are hydrotreated, hydrocracked or hydroconverted. These fractions are then recomposed and, in general, at least two pre-refined oils Pa and Pc are produced, Pa being a high-quality non-asphaltenic oil, and Pc being a residual oil. The method typically involves at least one initial distillation and a deasphalting SDA with a solvent having a molecular weight of at least 50 for separating a deasphalted oil DAO from a flow of virgin asphalt AS. AS is hydroconverted in at least two series-connected ebullated-bed reactors with a moderated conversion of less than 56 %, mixed with a virgin diluent containing light fractions. The DAO is typically hydrocracked with a conversion limited to less than 80 %.
C10G 67/04 - Traitement des huiles d'hydrocarbures, uniquement par au moins un procédé d'hydrotraitement et au moins un procédé de raffinage en l'absence d'hydrogène uniquement par plusieurs étapes en série comprenant une extraction par solvant comme étape de raffinage en l'absence d'hydrogène
C10G 65/18 - Traitement des huiles d'hydrocarbures, uniquement par plusieurs procédés d'hydrotraitement uniquement par plusieurs étapes en parallèle ne comprenant que des étapes de craquage
84.
METHOD FOR PRODUCING MIDDLE DISTILLATES BY THE HYDROISOMERIZATION AND HYDROCRACKING OF FEEDSTOCKS OBTAINED FROM THE FISCHER-TROPSCH METHOD
The invention relates to a method for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis using a hydrocracking/ hydroisomerization catalyst that comprises 0.2 to 2.5 % by weight of oxide of a doping element selected among boron, phosphorous, silicon, at least one hydro-dehydrogenating element selected from the group formed by the noble elements of group VIII of the periodic table, a non-zeolitic support based on silica-alumina containing a quantity greater than 5 % by weight and less than or equal to 95 % by weight of silica (SiO2), an average pore diameter, measured by mercury porosimetry, ranging from 20 to 140 Å, a total pore volume, measured by mercury porosimetry, ranging from 0.1 ml/g to 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, ranging from 0.1 to 0.6 ml/g, a BET specific surface area ranging form 100 to 550 m2/g, a pore volume, measured by mercury porosimetry, in the pores having a diameter greater than 140 Å and less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, in the pores having a diameter greater than 160 Å less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, in the pores having a diameter greater than 200 Å less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, in the pores having a diameter greater than 500 Å less than 0.1 ml/g and an X-ray diffraction pattern that contains at least the principal lines characteristic of at least one of the transition aluminas contained in the group composed of the alpha, rho, chi, eta, gamma, kappa, theta and delta aluminas.
C10G 45/10 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage caractérisé par le catalyseur utilisé contenant des métaux du groupe du platine ou leurs composés
85.
METHOD FOR PRE-REFINING CRUDE OIL FOR PRODUCING AT LEAST TWO NON-ASPHALTENIC OILS PA, PB AND AN ASPHALTENIC OIL PC
The invention relates to a method for prerefining crude oil P during which P is fractionated into a number of fractions, typically, certain fractions are hydrotreated, hydrocracked or hydroconverted. These fractions are then recomposed, and at least three pre-refined oils Pa, Pb, Pc, are produced, Pc being a residual asphaltenic oil, and Pa and Pb being two non-asphaltenic oils having different R ratios with: R = (0.9 N + 0.5 VGO+) / (MD + 0.1 VGO+), in which: N = naphta [30 °C / 170 °C]; MD = middle distillates: [170 °C / 360 °C] and VGO+ = boiling fraction above 360 °C, and; R translates the relative potential of a non-residual oil into gasoline with regard to the middle distillates during its subsequent refining.
C10G 45/14 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage avec des particules solides en mouvement
C10G 47/24 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur avec des particules solides en mouvement
86.
METHOD AND DEVICE FOR EVALUATING FLOWING AND ELECTRIC PARAMETERS OF A POROUS MEDIUM
The invention relates to a method and device for simultaneously and with the same equipment evaluating the electric resistivity and flowing parameters of a porous medium according to experimental measurements obtainable from at least one multi-flow displacement experiment. The inventive method consists in continuously measuring over time a differential pressure between two ends of said sample, the electric resistivity thereof, at least two values of a displaced fluid production volume for each stabilisation step and in subsequently calculating the production volume continuous curve which is used for evaluating flowing parameters with the aid of a digital flow simulator. Said invention can be used, for example, in oil field operation.
G01N 15/08 - Recherche de la perméabilité, du volume des pores ou de l'aire superficielle des matériaux poreux
G01N 27/04 - Recherche ou analyse des matériaux par l'emploi de moyens électriques, électrochimiques ou magnétiques en recherchant l'impédance en recherchant la résistance
The invention relates to a method for producing a motor gasoline having a low-sulphur content and an olefin controlled content comprising an olefin feed oligomerisation stage (stage i), a stage (ii) consisting in mixing a branched olefin motor gasoline produced at the stage (i) with a sulphur and olefin-rich motor gasoline, a stage (iii) for the hydrodesulfurisation of said mixture and a stage (iv) for separating the thus formed H2S.
C10G 45/08 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage caractérisé par le catalyseur utilisé contenant du nickel ou du cobalt, ou leurs composés en combinaison avec du chrome, du molybdène ou du tungstène, ou leurs composés
C10G 67/08 - Traitement des huiles d'hydrocarbures, uniquement par au moins un procédé d'hydrotraitement et au moins un procédé de raffinage en l'absence d'hydrogène uniquement par plusieurs étapes en série comprenant un traitement acide comme étape de raffinage en l'absence d'hydrogène
88.
METHOD FOR OLIGOMERISING OLEFINS BY USING A MEMBRANOUS SEPARATION
The invention relates to a method for oligomerising olefins containing from 2 to 6 carbon atoms comprising at least a) one reaction step for recovering a first flow containing oligomers, paraffins and unreacted olefins, b) a separation step for separating a part of oligomers contained in a mixture flow comprising oligomers, paraffins and unreacted olefins, c) a step for recycling the portion of said mixture at the reaction step, d) a membranous separation step for separating the other portion of the mixture in such a way that a permeate comprising at least 70 % by weight olefins and a retentate comprising paraffins and oligomers are withdrawn from and e) a step for recovering oligomers on the retantate.
A raw natural gas is dioxide in a units (DA, DH). The processed gas is subsequently purified by adsorbing mercaptans in the first chamber (AI). A part of the purified gas is heated in an EI, afterwards is introduced into a second chamber A2 in such a way that a water adsorbed by an adsorption material contained therein is removed. A stream rich in heavy hydrocarbon vapours is introduced into a third chamber (A3) containing a mercaptan-charged adsorption material. In the A3, the mercaptans are desorbed and substituted by the heavy hydrocarbons.
The invention relates to a device for mixing and distributing a gas and a liquid, which is disposed upstream of a granular bed (2). The inventive device comprises a means for feeding (3) the gas and the liquid and an essentially-horizontal lower plate (21) which is equipped with a plurality of funnels (22) that are uniformly distributed on the surface thereof. Each of the aforementioned funnels comprises an upper part (23) and a lower end (25) which are communicated with the underside of the plate, said upper part being equipped with at least one lateral hole (26). The improvement provided by the invention lies in the fact that the above-mentioned feed means comprises an essentially-horizontal upper plate (5), above which the gas and liquid are supplied, said upper plate being provided with means for conveying (6) the liquid to the lower plate and means (7) for separating and conveying the gas.
B01J 8/02 - Procédés chimiques ou physiques en général, conduits en présence de fluides et de particules solidesAppareillage pour de tels procédés avec des particules immobiles, p. ex. dans des lits fixes
B01D 53/18 - Unités d'absorptionDistributeurs de liquides
C10G 45/00 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène
91.
METHOD FOR COMBINED PRODUCTION OF PARAXYLENE AND BENZENE WITH IMPROVED PRODUCTIVITY
The invention concerns a method for combined production of paraxylene and benzene, including: separating by adsorption in simulated mobile bed (SMB) a first feed, to produce an extract (E) rich in paraxylene and at least one raffinate (R) poor in paraxylene; converting a secondary toluene feed by selective disproportionation to produce benzene and xylenes, a) initially, producing a supplementary amount of paraxylene in a crystallizing unit fed by the xylenes derived from disproportionation, d) finally, when the adsorbent has aged, separating the distillated extract (E) into a first fraction (Ea) and a second complementary fraction (Eb); replacing the initial crystallizing feed with the current Ea, and recycling the xylenes from the disproportionation to the SMB. The invention enables production of paraxylene and benzene to be maintained in spite of the aging of the SMB adsorbent.
C07C 6/12 - Préparation d'hydrocarbures à partir d'hydrocarbures contenant un nombre différent d'atomes de carbone par des réactions de redistribution par conversion d'une liaison carbone-carbone saturée exclusivement dans les hydrocarbures contenant un cycle aromatique à six chaînons
C07C 7/00 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs
92.
INTERNAL COMBUSTION ENGINE, IN PARTICULAR WITH DIRECT INJECTION, WITH A PISTON PROVIDED WITH A TROUGH COMPRISING A DOG POINT
The invention concerns an internal combustion engine, in particular with direct injection comprising at least one cylinder (10), one piston (30) sliding in said cylinder, a combustion chamber (26) delimited on one side by the upper side of the piston including a concave trough (32) wherein is arranged a dog point (34) with apex angle (a2) and a fuel injector (22) for injecting fuel at a spray angle (a1) not greater than 2 Arctg CD/2f where CD is the diameter of the cylinder (10) and F the distance between the point of origin of the fuel jets derived from the injector and the position of the piston (30) corresponding to a crankshaft angle of 50° relative to the upper dead center. The invention is characterized in that the apex angle (a2) of the dog point is greater than the spray angle (a1) by an angle ranging between 30° and 60°.
F02B 23/06 - Autres moteurs caractérisés par des chambres de combustion d'une forme ou d'une structure particulières pour améliorer le fonctionnement avec allumage par compression l'espace de combustion étant disposé dans le piston moteur
93.
METHOD OF PREPARING MULTIMETALLIC CATALYSTS THAT CAN BE USED IN HYDROCARBON CONVERSION REACTIONS
The invention relates to a method of preparing a catalyst, comprising the following steps consisting in: a) preparing a colloidal suspension of oxide of a first metal M1, involving the neutralisation of a basic solution with a mineral acid solution containing the precursor of metal M1; b) bringing the precursor of promoter M2, either directly in the crystallised form thereof or after dissolution in aqueous phase, into contact with the colloidal suspension obtained in step a); c) bringing the colloidal suspension obtained in step b) into contact with the support; and d) drying same at a temperature of between 30 °C and 200 °C under an air flow. The invention also relates to a method for the treatment of an olefinic cut, using the catalyst that has been prepared using said preparation method.
C10G 45/40 - Hydrogénation sélective des composés dioléfiniques ou acétyléniques caractérisée par le catalyseur utilisé contenant des métaux du groupe du platine ou leurs composés
C07C 7/163 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par traitement provoquant une modification chimique d'au moins un composé par hydrogénation
The invention relates to a plant for regasification of liquefied natural gas (GNL), comprising a liquefied gas storage reservoir (10) and a regasification device (12) for the GNL through which the natural gas and a heat transfer medium flow. According to the invention, the plant comprises a loop circuit (16) in which the heat transfer medium circulates in the form of a low-viscosity organic liquid with a low crystallisation point and the regasification device (12) comprises at least two exchangers (60, 62).
The invention relates to a method for control of fuel injection for an internal combustion engine, in particular with direct fuel injection, comprising at least one cylinder (10), one piston (30) running in said cylinder, with a projection (34) arranged in a concave bowl (32), a fuel injector (22) and a combustion chamber (26). According to the invention, during high engine loads, a first amount of fuel is injected at a piston (30) position of between 35 and 70 ° before the top dead centre position of said piston, followed by an injection of at least one second amount of fuel, the first amount of fuel being less than the second amount and the fuel is injected into said combustion chamber by means of an injector (22) with a cone angle (a1) less than or equal to 2Arctg CD/2F where CD is the diameter of the cylinder (10) and F the distance between the points of origin of the fuel jets from the injector (22) and the position of the piston corresponding to a crankshaft angle of 50 ° with relation to the top dead centre (PMH) of the piston.
F02B 23/06 - Autres moteurs caractérisés par des chambres de combustion d'une forme ou d'une structure particulières pour améliorer le fonctionnement avec allumage par compression l'espace de combustion étant disposé dans le piston moteur
F02B 23/10 - Autres moteurs caractérisés par des chambres de combustion d'une forme ou d'une structure particulières pour améliorer le fonctionnement avec allumage commandé avec admission séparée de l'air et du combustible dans le cylindre
F02D 41/40 - Commande de l'injection de combustible du type à haute pression avec des moyens pour commander la synchronisation ou la durée de l'injection
F02M 45/04 - Appareils d'injection caractérisés par une variation périodique de la pression ou du débit chaque injection du cycle étant fractionnée en plusieurs décharges la première décharge étant faible
96.
CEMENTING MATERIAL COMPRISING POLYMER PARTICLES, METHOD FOR TREATING SAID PARTICLES, AND CEMENT SLURRY
The invention relates to a cementing material, a production method, and cement slurry comprising polymer particles coated by at least one powder mineral additive.
Process for the production of cellulolytic and hemicellulolytic enzymes using distillation residues from the ethanolic fermentation of enzymatic hydrolyzates of (ligno)cellulosic materials
C12P 7/06 - Éthanol en tant que produit chimique et non en tant que boisson alcoolique
C12P 7/10 - Éthanol en tant que produit chimique et non en tant que boisson alcoolique préparé comme sous-produit, ou préparé à partir d'un substrat constitué par des déchets ou par des matières cellulosiques d'un substrat constitué par des matières cellulosiques
C12P 19/14 - Préparation de composés contenant des radicaux saccharide préparés par action d'une carbohydrase, p. ex. par action de l'alpha-amylase
C12N 9/42 - Hydrolases (3.) agissant sur les composés glycosyliques (3.2) agissant sur les liaisons bêta-glucosidiques-1, 4, p. ex. cellulase
The invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with low macropore content and hydrocracking/hydroconversion and hydrotreatment methods using same. The catalyst comprises at least one hydro-dehydrogenating element selected in the group consisting of elements of group VIB and of group VIII of the periodic table and a doping element in controlled amount selected among phosphorus, boron and silicon and a Y zeolite-based support defined by a crystalline parameter of the elementary mesh ranging between 24.40 x 10-10 m and 24.15 x 10-10 m and of silica-alumina containing an amount ranging between 5 wt. % and 95 wt. % of silica (SiO2).
B01J 29/08 - Zéolites aluminosilicates cristallinesLeurs composés isomorphes du type faujasite, p. ex. du type X ou Y
B01J 29/18 - Zéolites aluminosilicates cristallinesLeurs composés isomorphes du type mordénite
B01J 29/70 - Zéolites aluminosilicates cristallinesLeurs composés isomorphes de types caractérisés par leur structure spécifique non prévus dans les groupes
C10G 45/06 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage caractérisé par le catalyseur utilisé contenant du nickel ou du cobalt, ou leurs composés
C10G 45/12 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène pour éliminer des hétéro-atomes sans modifier le squelette de l'hydrocarbure mis en œuvre et sans craquage en hydrocarbures à point d'ébullition inférieurHydrofinissage caractérisé par le catalyseur utilisé contenant des alumino-silicates cristallins, p. ex. des tamis moléculaires
C10G 47/02 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur caractérisé par le catalyseur utilisé
99.
Method for the production of middle distillates by hydroisomerisation et hydrocracking of charges arising from the Fischer-Tropsch method
The invention relates to a process for preparing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises at least one hydrodehydrogenating element chosen from the group formed by the noble elements of Group VIII of the periodic table, a silica-alumina-based non-zeolitic support obtained from wherein the non-zeolitic silica-alumina based support was obtained from a process comprising starting from a mixture of a partially soluble alumina compound in an acid medium with a totally soluble silica compound or with a totally soluble combination of alumina and hydrated silica, the resultant moldable mixture is concentrated to form a moldable mixture, the resultant mixture is molded and the resultant molded article is subjected to a hydrothermal or thermal treatment.
C10G 47/10 - Craquage des huiles d'hydrocarbures, en présence d'hydrogène ou de composés donneurs d'hydrogène, pour obtenir des fractions à point d'ébullition inférieur caractérisé par le catalyseur utilisé avec des catalyseurs déposés sur un support
2 content, preferably comprised between 5 and 200 ppmv. Most often, the CO content is comprised between 1 and 20 ppmv. The process typically makes it possible to hydrorefine an olefinic gasoline by more or less eliminating the diolefins and sulphur compounds.
C07C 7/163 - Purification, séparation ou stabilisation d'hydrocarburesEmploi d'additifs par traitement provoquant une modification chimique d'au moins un composé par hydrogénation
C10G 45/00 - Raffinage des huiles d'hydrocarbures au moyen d'hydrogène ou de composés donneurs d'hydrogène