PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Singtee, Apipornchai
Abstract
The present invention relates to a catalyst for light olefins production from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms, wherein said catalyst has core-shell structure comprising zeolite core selected from ferrierite, ZSM-5, or mixture thereof, and silicalite shell having MFI structure, and said catalyst has the following characteristics:
a) the weight ratio of shell to core greater than 0 but less than 4;
b) the mole ratio of silica to alumina (SiO2/Al2O3) from 60 to 550;
c) the hierarchical pores comprising micropores having pore size in the range of 0.1 to 2 nm, mesopores having pore size in the range of 2 to 50 nm, and macropores having pore size greater than 50 nm, wherein the proportion of volume of mesopores and macropores to the total pore volume is in the range from 0.35 to 0.90, and said mesopores comprise pores having pore size from 2 to 5 nm, wherein the proportion of volume of pores having pore size from 2 to 5 nm to the total pore volume is in the range from 0.08 to 0.30.
The present invention relates to a catalyst for light olefins production from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms, wherein said catalyst has core-shell structure comprising zeolite core selected from ferrierite, ZSM-5, or mixture thereof, and silicalite shell having MFI structure, and said catalyst has the following characteristics:
a) the weight ratio of shell to core greater than 0 but less than 4;
b) the mole ratio of silica to alumina (SiO2/Al2O3) from 60 to 550;
c) the hierarchical pores comprising micropores having pore size in the range of 0.1 to 2 nm, mesopores having pore size in the range of 2 to 50 nm, and macropores having pore size greater than 50 nm, wherein the proportion of volume of mesopores and macropores to the total pore volume is in the range from 0.35 to 0.90, and said mesopores comprise pores having pore size from 2 to 5 nm, wherein the proportion of volume of pores having pore size from 2 to 5 nm to the total pore volume is in the range from 0.08 to 0.30.
The catalyst according to the invention provides high conversion of the reactant and especially high selectivity to light olefins. Moreover, this invention also relates to the process of light olefins production by using the catalyst thereof.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Tang-Amornsuksan, Suchada
Pengpanich, Sitthiphong
Pornsuriyasak, Papapida
Abstract
The present invention relates to a catalyst for cumene hydroperoxide decomposition, wherein said catalyst has good efficacy, provides good decomposition of cumene hydroperoxide and good selectivity to main products, provides high yield percentage of alpha methyl styrene, and reduces the formation of unwanted byproducts. Said catalyst comprises zeolite beta, wherein said catalyst has the following characteristics: a) the mole ratio of silica to alumina is from 30 to 100; and b) the peak area ratio obtained from the analysis using 27Al magic angle spinning-nuclear magnetic resonance (27Al MAS-NMR) technique according to the following relation: (A+C+D)/B is from 0.1 to 0.3; wherein A, B, C, and D are the peak area at the peak position from 44 but less than 54 ppm, the peak area at the peak position from 54 to 58 ppm, the peak area at the peak position greater than 58 to 64 ppm, and the peak area at the peak position from −10 to 5 ppm, respectively, by the peak deconvolution analysis with Lorentz/Gauss function under the condition that the minimum distance between peaks for independent integration (AZFW) is equal to 0.5 ppm. Moreover, this invention relates to a preparation process of the catalyst comprising the step of contacting zeolite beta with polycarboxylic acid solution and calcination at the temperature in the range from 400 to 700° C., wherein said polycarboxylic acid has the pKa of the first dissociation from 1.5 to 3.5 and has the molecular structure with at least one side having size larger than 6 Å. This invention also relates to a process for cumene hydroperoxide decomposition using said catalyst or catalyst prepared from said preparation process of the catalyst.
B01J 29/70 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups
C01B 39/02 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereofDirect preparation thereofPreparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactantsAfter-treatment thereof
C07C 37/08 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
3.
CATALYST FOR AROMATIZATION OF ALKANES HAVING 4 TO 7 CARBON ATOMS, PROCESS OF MAKING, AND PROCESS OF AROMATICS PREPARATION BY USING THEREOF
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Chareonpanich, Metta
Donphai, Waleeporn
Sangteantong, Pariyawalee
Wongnongwa, Yutthana
Jungsuttiwong, Siriporn
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Abstract
The present invention relates to a catalyst for aromatization of alkanes having 4 to 7 carbon atoms, especially alkanes having carbon atoms. Said catalyst has the efficacy in the aromatics production with high conversion and high selectivity of aromatics or high yield of aromatics, wherein said catalyst comprises zeolite, at least 1 transition metal from group VIII transition metal in a range of 0.1 to 2% by weight based on the total weight of the catalyst, and at least 1 metal from group IIIA metal in a range of 0.1 to 5% by weight based on the total weight of the catalyst. Said catalyst is treated and dried with a microwave at a power in a range from 400 to 1,000 watts after step of contacting with a solution comprising at least 1 transition metal salt from group VIII transition metal and after step of contacting with a solution comprising at least 1 group IIIA metal salt. Moreover, this invention also relates to a process for preparing said catalyst and a process of aromatics preparation using said catalyst.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Phomphrai, Khamphee
Chumsaeng, Phongnarin
Yimthachote, Supajittra
Potisatityuenyong, Anupat
Pitakchatwong, Chutamart
Abstract
The present invention relates to a preparation method of double metal cyanide catalyst for producing a polycarbonate-ether from epoxide and carbon dioxide, wherein said process comprises the following steps: (a) mixing of a metal salt selected from zinc (II) metal salt, iron (II) metal salt, cobalt (II) metal salt, nickel (II) metal salt, metal cyanide salt, and the first complexing agent selected from alcohol compounds, ketone and diketone compounds, ketone-ester compounds, ether compounds, or a mixture thereof at predetermined time and temperature to obtain double metal cyanide catalyst precursor; and (b) subjecting the double metal cyanide catalyst precursor obtained from step (a) to react with the second complexing agent selected from aliphatic carbonyl compound, aliphatic ester ether compound, or a mixture thereof in water or organic solvent at a predetermined time and temperature to obtain the double metal cyanide catalyst.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Potisatityuenyong, Anupat
Pitakchatwong, Chutamart
Chanprasert, Narakorn
Kosoljitkul, Pawanna
Abstract
The present invention relates to a process for preparing an aqueous-based biodegradable polymer dispersions composition, comprising the following steps: (a) mixing biopolymer, plasticizer, stabilizer, and aqueous solution in a stir tank reactor at the temperature from 90 to 150 °C and pressure from 3 to 5 bars until the biodegradable polymer composition becomes homogeneous; (b) subjecting mixture in step (a) to reflux pressurization system to disperse said mixture into small particles and reflux back to the stir tank reactor; and (c) reducing the temperature of the stir tank reactor down to the temperature from 25 to 40 °C to obtain the stable aqueous-based biodegradable polymer dispersions composition.
C08J 3/07 - Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from polymer solutions
C08L 101/16 - Compositions of unspecified macromolecular compounds the macromolecular compounds being biodegradable
C08L 67/02 - Polyesters derived from dicarboxylic acids and dihydroxy compounds
C09D 167/02 - Polyesters derived from dicarboxylic acids and dihydroxy compounds
6.
METHOD AND SYSTEM FOR OPTIMIZING AN ALKANE DEHYDROGENATION OPERATION
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Chatthammanat, Songphon
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Lertlukkanasuk, Noppon
Abstract
The present invention relates to a method for optimizing an alkane dehydrogenation operation. The method comprises the steps of obtaining historical data of a plurality of production parameter data, filtering abnormal data of the said historical data, developing a product yield prediction model and a coking rate prediction model, and processing the product yield prediction model and the coking rate prediction model, and determining optimum production parameter data based on the predicted product yield and the predicted coking rate. The present invention further relates to a system for optimizing an alkane dehydrogenation operation which comprises a production data detecting and storage unit and a processor configured to obtain historical data of the production parameter data, filter abnormal data of the historical data of the production parameter data, develop a product yield prediction model and a coking rate prediction model, and provide a process efficiency analysis model with a machine learning processing unit for processing the product yield prediction model and the coking rate prediction model to predict a product yield and a coking rate, and determine optimum production parameter data based on the predicted product yield and the predicted coking rate.
G05B 19/4155 - Numerical control [NC], i.e. automatically operating machines, in particular machine tools, e.g. in a manufacturing environment, so as to execute positioning, movement or co-ordinated operations by means of programme data in numerical form characterised by programme execution, i.e. part programme or machine function execution, e.g. selection of a programme
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Chuencheep, Worawat
Phichitsurathaworn, Nitipat
Abstract
The present invention relates to a process to control the molecular weight distribution of polyethylene and to reduce the smoke quantity during the formation of polyethylene, wherein the process for preparing polyethylene having narrow molecular weight distribution, comprising the following steps:
a) continuously polymerizing ethylene by subjecting ethylene stream, hydrogen, solvent, Ziegler-Natta catalyst comprising titanium, co-catalyst, external electron donor selected from alkoxysilane compound into the reactor to produce polymer slurry;
b) removing residue reaction gas from the polymer slurry stream obtained from a) and
c) separating polymer stream in b) from the solvent.
C08F 4/646 - Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group
C08F 4/642 - Component covered by group with an organo-aluminium compound
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Singtee, Apipornchai
Abstract
The present invention relates to a catalyst for light olefins production from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms, wherein said catalyst has core-shell structure comprising zeolite core selected from ferrierite, ZSM-5, or mixture thereof, and silicalite shell having MFI structure, and said catalyst has the following characteristics: a) the weight ratio of shell to core greater than 0 but less than 4; b) the mole ratio of silica to alumina (SiO2/Al2O3) from 60 to 550; c) the hierarchical pores comprising micropores having pore size in the range of 0.1 to 2 nm, mesopores having pore size in the range of 2 to 50 nm, and macropores having pore size greater than 50 nm, wherein the proportion of volume of mesopores and macropores to the total pore volume is in the range from 0.35 to 0.90, and said mesopores comprise pores having pore size from 2 to 5 nm, wherein the proportion of volume of pores having pore size from 2 to 5 nm to the total pore volume is in the range from 0.08 to 0.30. The catalyst according to the invention provides high conversion of the reactant and especially high selectivity to light olefins. Moreover, this invention also relates to the process of light olefins production by using the catalyst thereof.
01 - Chemical and biological materials for industrial, scientific and agricultural use
17 - Rubber and plastic; packing and insulating materials
Goods & Services
Plastic unprocessed; chemical products used in the plastic industry, namely, unprocessed polyethylene resins Semi-processed plastics in the form of pellets, films, sheets, tubes, bars or rods; synthetic resins in semi-processed form in the form of pellets
10.
CATALYST FOR CUMENE HYDROPEROXIDE DECOMPOSITION AND PROCESS FOR PREPARATION THEREOF
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Tang-Amornsuksan, Suchada
Pengpanich, Sitthiphong
Pornsuriyasak, Papapida
Abstract
The present invention relates to a catalyst for cumene hydroperoxide decomposition, wherein said catalyst has good efficacy, provides good decomposition of cumene hydroperoxide and good selectivity to main products, provides high yield percentage of alpha methyl styrene, and reduces the formation of unwanted byproducts. Said catalyst comprises zeolite beta, wherein said catalyst has the following characteristics: a) the mole ratio of silica to alumina is from 30 to 100; and b) the peak area ratio obtained from the analysis using 27Al magic angle spinning-nuclear magnetic resonance (27Al MAS-NMR) technique according to the following relation: (A+C+D)/B is from 0.1 to 0.3; wherein A, B, C, and D are the peak area at the peak position from 44 but less than 54 ppm, the peak area at the peak position from 54 to 58 ppm, the peak area at the peak position greater than 58 to 64 ppm, and the peak area at the peak position from -10 to 5 ppm, respectively, by the peak deconvolution analysis with Lorentz/Gauss function under the condition that the minimum distance between peaks for independent integration (AZFW) is equal to 0.5 ppm. Moreover, this invention relates to a preparation process of the catalyst comprising the step of contacting zeolite beta with polycarboxylic acid solution and calcination at the temperature in the range from 400 to 700 °C, wherein said polycarboxylic acid has the pKa of the first dissociation from 1.5 to 3.5 and has the molecular structure with at least one side having size larger than 6 Å. This invention also relates to a process for cumene hydroperoxide decomposition using said catalyst or catalyst prepared from said preparation process of the catalyst.
C07C 37/08 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
B01J 29/70 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups
G01N 24/12 - Investigating or analysing materials by the use of nuclear magnetic resonance, electron paramagnetic resonance or other spin effects by using double resonance
C01B 39/02 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereofDirect preparation thereofPreparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactantsAfter-treatment thereof
11.
Process for removing arsine from hydrocarbon mixture
B01J 20/22 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising organic material
B01D 53/02 - Separation of gases or vapoursRecovering vapours of volatile solvents from gasesChemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases or aerosols by adsorption, e.g. preparative gas chromatography
B01J 20/30 - Processes for preparing, regenerating or reactivating
C07C 7/12 - Purification, separation or stabilisation of hydrocarbonsUse of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
12.
A CATALYST FOR PRODUCING LIGHT OLEFINS FROM CATALYTIC CRACKING OF HYDROCARBON HAVING 4 TO 7 CARBON ATOMS AND A PROCESS FOR PRODUCING LIGHT OLEFINS BY USING A CATALYST THEREOF
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Wattanakit, Chularat
Rodaum, Chadatip
Thivasasith, Anawat
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Abstract
The present invention relates to a catalyst for producing light olefins from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms, wherein said catalyst comprises zeolite having the ring arrangement of 8 to 10 silicon atoms and hierarchical zeolite comprising 0.1 to 2 nm of micropore, 2 to 50 nm of mesopore, and greater than 50 nm of macropore, wherein the mesopore and macropore are greater than or equal to 40% when comparing to total pore volume, and said catalyst comprises element having 2+ to 4+ oxidation state with 0.1 to 3% by weight of the catalyst.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Prasitchoke, Phatthanon
Poomsila, Natthawut
Kittisuriyanont, Kraileark
Kaewsuwan, Narong
Techanan, Wikanda
Abstract
Kluyveromyces sp. yeast cell comprising at least a genetic modification that inactivates or deletes a nucleotide sequence encoding for transcription factor SEQ ID No. 2, particularly Haa1. The genetically engineered yeast cell according to this invention has an improvement of lactic acid tolerance, lactic acid production or a combination thereof as compared to the parental.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Vongnam, Kunnigar
Thavornsin, Nopparat
Sae-Ung, Pornpen
Kaeothip, Sophon
Euapermkiati, Anucha
Phomphrai, Khamphee
Abstract
The present invention relates to catalyst composition for cyclic carbonate production from CO2 and olefins using halohydrin agent as the co-reactant under mild conditions, which can effectively catalyze the cyclic carbonate synthesis and provides good selectivity to cyclic carbonate, wherein said catalyst composition comprising:
a) the metal complex as shown in structure (I):
The present invention relates to catalyst composition for cyclic carbonate production from CO2 and olefins using halohydrin agent as the co-reactant under mild conditions, which can effectively catalyze the cyclic carbonate synthesis and provides good selectivity to cyclic carbonate, wherein said catalyst composition comprising:
a) the metal complex as shown in structure (I):
wherein,
M represents transition metal atom;
R1, R2, and R3 represent independent group selected from hydrogen atom, halogen atom, alkyl group, alkenyl group, alkynyl group, alkoxy group, amine group, phenyl group, benzyl group, cyclic hydrocarbon group comprising hetero atom, perfluoroalkyl group, or nitro group;
R4 represents group selected from alkylene group, cycloalkylene group, or phenylene group;
X represents group selected from halogen atom, acetate group, or triflate group;
b) the halohydrin agent in at least one solvent; and
c) at least one base.
01 - Chemical and biological materials for industrial, scientific and agricultural use
17 - Rubber and plastic; packing and insulating materials
Goods & Services
Plastics, unprocessed; Unprocessed plastics in all forms; Unprocessed polyethylene resins. Semi-processed plastics; Semi-processed synthetic resins; Semi-processed plastics in the form of sheets, films, pellets, bars, rods and tubes; Artificial resins in the form of pellets for use in manufacture.
16.
CATALYST COMPOSITION FOR CYCLIC CARBONATE PRODUCTION FROM CO2 AND EPOXIDES
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Kiriratnikorn, Jiraya
Vongnam, Kunnigar
Thavornsin, Nopparat
Sae-Ung, Pornpen
Kaeothip, Sophon
Euapermkiati, Anucha
Phomphrai, Khamphee
Abstract
The present invention relates to catalyst composition for cyclic carbonate production from CO2 and epoxides under mild conditions, which can effectively catalyze the cyclic carbonate synthesis and provides good selectivity to cyclic carbonate, wherein said catalyst composition comprising:
a) the metal complex as shown in structure (I):
The present invention relates to catalyst composition for cyclic carbonate production from CO2 and epoxides under mild conditions, which can effectively catalyze the cyclic carbonate synthesis and provides good selectivity to cyclic carbonate, wherein said catalyst composition comprising:
a) the metal complex as shown in structure (I):
wherein,
M represents transition metal atom;
R1, R2, and R3 represent independent group selected from hydrogen atom, halogen atom, alkyl group, alkenyl group, alkynyl group, alkoxy group, amine group, phenyl group, benzyl group, cyclic hydrocarbon group comprising hetero atom, perfluoroalkyl group, or nitro group;
R4 represents group selected from alkylene group, cycloalkylene group, or phenylene group;
X represents group selected from hydrogen atom, acetate group, or triflate group; and
b) the organic compound as the co-catalyst selected from compound containing nitrogen, compound of quaternary ammonium salts, or compound of iminium salts.
C07D 317/44 - Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
17.
AN ISOMERIZATION PROCESS OF PRODUCT OBTAINED FROM BISPHENOL PREPARATION FROM A CONDENSATION REACTION OF KETONE AND PHENOL
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Pornsuriyasak, Papapida
Lunvongsa, Sarawut
Tang-Amornsuksan, Suchada
Abstract
The present invention relates to an isomerization process of product obtained from bisphenol preparation from a condensation reaction of ketone and phenol comprising contacting the product obtained from bisphenol preparation from a condensation reaction of ketone and phenol with the ion exchange resin in aqueous condition for the isomerization of the undesired product and separating the product having higher bisphenol content, wherein said ion exchange resin is aromatic polymer having the sulfonic acid group modified with at least one promoter selected from the compound shown in the structure (I):
The present invention relates to an isomerization process of product obtained from bisphenol preparation from a condensation reaction of ketone and phenol comprising contacting the product obtained from bisphenol preparation from a condensation reaction of ketone and phenol with the ion exchange resin in aqueous condition for the isomerization of the undesired product and separating the product having higher bisphenol content, wherein said ion exchange resin is aromatic polymer having the sulfonic acid group modified with at least one promoter selected from the compound shown in the structure (I):
C07C 37/20 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
C07C 37/82 - SeparationPurificationStabilisationUse of additives by physical treatment by solid-liquid treatmentSeparationPurificationStabilisationUse of additives by physical treatment by chemisorption
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Chareonpanich, Metta
Donphai, Waleeporn
Sangteantong, Pariyawalee
Wongnongwa, Yutthana
Jungsuttiwong, Siriporn
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Abstract
The present invention relates to a catalyst for aromatization of alkanes having 4 to 7 carbon atoms, especially alkanes having carbon atoms. Said catalyst has the efficacy in the aromatics production with high conversion and high selectivity of aromatics or high yield of aromatics, wherein said catalyst comprises zeolite, at least 1 transition metal from group VIII transition metal in a range of 0.1 to 2 % by weight based on the total weight of the catalyst, and at least 1 metal from group IIIA metal in a range of 0.1 to 5 % by weight based on the total weight of the catalyst. Said catalyst is treated and dried with a microwave at a power in a range from 400 to 1,000 watts after step of contacting with a solution comprising at least 1 transition metal salt from group VIII transition metal and after step of contacting with a solution comprising at least 1 group IIIA metal salt. Moreover, this invention also relates to a process for preparing said catalyst and a process of aromatics preparation using said catalyst.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Chuencheep, Worawat
Phichitsurathaworn, Nitipat
Abstract
The present invention relates to a process to control the molecular weight distribution of polyethylene and to reduce the smoke quantity during the formation of polyethylene, wherein the process for preparing polyethylene having narrow molecular weight distribution, comprising the following steps: a) continuously polymerizing ethylene by subjecting ethylene stream, hydrogen, solvent, Ziegler-Natta catalyst comprising titanium, co-catalyst, external electron donor selected from alkoxysilane compound into the reactor to produce polymer slurry; b) removing residue reaction gas from the polymer slurry stream obtained from a) and c) separating polymer stream in b) from the solvent.
C08F 4/6592 - Component covered by group containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
20.
AN ADSORBENT FOR SEPARATING ORGANOCHLORIDE COMPOUND FROM LIQUID HYDROCARBON AND A PROCESS THEREOF
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Vongachariya, Yanee
Pengpanich, Sitthiphong
Chareonpanich, Metta
Donphai, Waleeporn
Witoon, Thongthai
Ruengrung, Preeyaporn
Abstract
The present invention relates to the adsorbent for separating organochloride compound from liquid hydrocarbon and a process thereof, wherein said adsorbent is the silica and aluminosilicate composite having infiltrate structure subjected to the modification of the surface property with small metal having high electronegativity.
B01J 20/28 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof characterised by their form or physical properties
B01D 15/08 - Selective adsorption, e.g. chromatography
21.
MICROBIAL STRAINS ENGINEERED FOR IMPROVED FRUCTOSE UTILIZATION
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Dole, Sudhanshu Vijay
Schmid, Joel Stewart
Yocum, R. Rogers
Hermann, Theron
Udani, Russell Lizardo
Regan, Sean Joseph
Sheff, Mark Andrew
Spencer, Michelle
Sillers, Ryan
Prasitchoke, Phatthanon
Poomsila, Natthawut
Abstract
The present invention discloses a genetically engineered Kluyveromyces sp. yeast strain that is capable of producing lactic acid from carbon source selected from glucose, fructose, sucrose or a mixture thereof wherein the genetically engineered yeast comprises at least one heterologous DNA cassette that confers production of a protein functioning as a fructose importer. The genetically engineered yeast strain according to this invention has an improvement of fructose utilization and use fructose as a faster rate than conventional strain, allowing for shorter fermentation times and improved economics.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Suwan, Puttipong
Chindapon, Suepsakun
Simakajonkiat, Sitthipol
Katinhom, Nattawat
Abstract
The present invention relates to an olefins-paraffins separation process in feed stream containing hydrocarbons with 2 to 4 carbon atoms by facilitated transport membrane specific to olefins, comprising a step (a) of feeding the feed stream containing hydrocarbons with 2 to 4 carbon atoms into distillation column and at least 1 stage of membrane unit connected to distillation column at the feed of distillation column and at least 1 stage of membrane unit connected to the side draw of distillation column and a step (b) of separating a portion of feed stream that is passed from the membrane unit, at least 1 stream is the product stream that mostly comprising olefins and at least 1 stream that mostly comprising paraffins.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Wattanakit, Chularat
Rodaum, Chadatip
Thivasasith, Anawat
Pengpanich, Sitthiphong
Abstract
The present invention relates to a catalyst for producing light olefins from C4-C7 hydrocarbons from catalytic cracking reaction and the production process of light olefins from said catalyst, wherein said catalyst has core-shell structure comprising a zeolite core with mole ratio of silicon to aluminium (Si/Al) between 2 to 250 and layered double hydroxide shell (LDH). The catalyst according to the invention provides high percent conversion of substrate to products and high selectivity to light olefins product.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Laokroekkiat, Salinthip
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Abstract
The present invention relates to a process for removing arsine from hydrocarbon mixture having 2 to 4 carbon atoms. Said process comprises the contact of the hydrocarbon mixture having 2 to 4 carbon atoms with the adsorbent, wherein said adsorbent is the metal organic frameworks (MOFs) comprising: a) at least 1 transition metal selected from group IB metal, group 2B metal, and group 4B metal, and b) the organic ligand selected from dicarboxylic acid compound or tricarboxylic acid compound, and wherein said adsorbent is subjected to the treatment with alcohol.
B01D 53/64 - Heavy metals or compounds thereof, e.g. mercury
B01J 20/02 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material
B01J 20/06 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group
25.
A PROCESS FOR REMOVING ARSINE FROM HYDROCARBON MIXTURE
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Laokroekkiat, Salinthip
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Abstract
The present invention relates to a process for removing arsine from hydrocarbon mixture having 2 to 4 carbon atoms. Said process comprises the contact of the hydrocarbon mixture having 2 to 4 carbon atoms with the adsorbent, wherein said adsorbent is the metal organic frameworks (MOFs) comprising: a) at least 1 transition metal selected from group IB metal, group 2B metal, and group 4B metal, and b) the organic ligand selected from dicarboxylic acid compound or tricarboxylic acid compound, and wherein said adsorbent is subjected to the treatment with alcohol.
B01D 53/64 - Heavy metals or compounds thereof, e.g. mercury
B01J 20/02 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material
B01J 20/06 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group
26.
Muconic acid production from genetically engineered microorganisms
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Sillers, Ryan
Hermann, Theron
Spencer, Michelle
Udani, Russell
Yocum, R. Rogers
Abstract
The subject of this invention is improvements in the yield and titer of biological production of muconic acid by fermentation. Increased activity of one or more enzymes involved in the muconic acid pathway leads to increased production of muconic acid.
PTT Global Chemical Public Company Limited (Thailand)
PTT Public Company Limited (Thailand)
Inventor
Tarapoom, Nattapong
Sompech, Kawisra
Sirimungkalakul, Nichaporn
Abstract
A microchannel heat exchanger comprising: at least one high temperature heat exchanging plate and at least one low temperature heat exchanging plate stacked in an alternating sequence, wherein an inlet of high temperature fluid and an outlet of high temperature fluid are disposed in order to pass the high temperature fluid through each said high temperature heat exchanging plate, and an inlet of low temperature fluid and an outlet of low temperature fluid are disposed in order to pass the low temperature fluid through each said low temperature heat exchanging plate, wherein the high temperature heat exchanging plate comprising the high temperature microchannel and the low temperature heat exchanging plate comprising the low temperature microchannel, wherein said channels have a length extending in the flow direction of fluids, and the side wall of each said channel has a symmetric wavy pattern with the center line of each said channel as a symmetric axis, wherein the high temperature heat exchanging plate and the low temperature heat exchanging plate are arranged in the pattern in which the high temperature microchannel and the low temperature microchannel are aligned.
F28D 9/00 - Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
F28F 3/04 - Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element
28.
Waterborne sizing composition for treating natural fibers and a process to treat natural fibers by said composition
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Losiriwat, Takul
Euapermkiati, Anucha
Abstract
The present invention relates to a waterborne sizing composition for treating natural fibers to be used as reinforcing material in thermoplastic, comprising: (a) a polymeric material having structure (I) wherein, R represents an alkyl group, X represents a reversible covalently bonded crosslinkable group, p, q, and r represent order on a main polymer chain, wherein the total sum of order greater than 50; (b) a water-soluble metal complex having an antimicrobial property; and (c) a redox active water-soluble compound.
D06M 13/50 - Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials with non-macromolecular organic compoundsSuch treatment combined with mechanical treatment with organometallic compoundsTreating fibres, threads, yarns, fabrics or fibrous goods made from such materials with non-macromolecular organic compoundsSuch treatment combined with mechanical treatment with organic compounds containing boron, silicon, selenium or tellurium atoms
C08J 5/04 - Reinforcing macromolecular compounds with loose or coherent fibrous material
C08J 5/06 - Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
C08J 5/10 - Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Wattanakit, Chularat
Rodaum, Chadatip
Thivasasith, Anawat
Pengpanich, Sitthiphong
Thavornprasert, Kaew-Arpha
Abstract
The present invention relates to a catalyst for producing light olefins from catalytic cracking of hydrocarbon having 4 to 7 carbon atoms, wherein said catalyst comprises zeolite having the ring arrangement of 8 to 10 silicon atoms and hierarchical zeolite comprising 0.1 to 2 nm of micropore, 2 to 50 nm of mesopore, and greater than 50 nm of macropore, wherein the mesopore and macropore are greater than or equal to 40 % when comparing to total pore volume, and said catalyst comprises element having 2+to 4+ oxidation state with 0.1 to 3 % by weight of the catalyst.
C07C 1/22 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by reduction
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Vongnam, Kunnigar
Thavornsin, Nopparat
Sae-Ung, Pornpen
Kaeothip, Sophon
Euapermkiati, Anucha
Phomprai, Khamphee
Abstract
212344 represents group selected from alkylene group, cycloalkylene group, or phenylene group; X represents group selected from halogen atom, acetate group, or triflate group; b) the halohydrin agent in at least one solvent; and c) at least one base.
C07F 17/02 - Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
C08F 4/44 - MetalsMetal hydridesMetallo-organic compoundsUse thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
C08F 4/60 - MetalsMetal hydridesMetallo-organic compoundsUse thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides together with refractory metals, iron group metals, platinum group metals, manganese, technetium, rhenium, or compounds thereof
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Kiriratnikorn, Jiraya
Vongnam, Kunnigar
Thavornsin, Nopparat
Sae-Ung, Pornpen
Kaeothip, Sophon
Euapermkiati, Anucha
Phomprai, Khamphee
Abstract
212344 represents group selected from alkylene group, cycloalkylene group, or phenylene group; X represents group selected from hydrogen atom, acetate group, or triflate group; and b) the organic compound as the co-catalyst selected from compound containing nitrogen, compound of quaternary ammonium salts, or compound of iminium salts.
C07F 17/02 - Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
C08F 4/44 - MetalsMetal hydridesMetallo-organic compoundsUse thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
C08F 4/60 - MetalsMetal hydridesMetallo-organic compoundsUse thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides together with refractory metals, iron group metals, platinum group metals, manganese, technetium, rhenium, or compounds thereof
32.
Aspergillus aculeatus for producing cellulase and xylanase and preparation method thereof
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Champreda, Verawat
Suwannarangsee, Surisa
Arnthong, Jantima
Siamphan, Chatuphon
Poonsrisawat, Aphisit
Ketsub, Napong
Phinyo, Mahattanee
Techanan, Wikanda
Poomsila, Natthawut
Prasitchoke, Phatthanon
Abstract
Aspergillus aculeatus E14-292 and a genetic modification process of said strain, wherein the mutant strain according to this invention can produce cellulase and xylanase more than the BCC199 (wild type). Moreover, the obtained enzymes can be used to digest the pretreatment bagasse to further produce sugars effectively.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Tachaapaikoon, Chakrit
Ratanakhanokchai, Khanok
Pason, Patthra
Waeonukul, Rattiya
Ketbot, Prattana
Techanan, Wikanda
Kittisuriyanont, Kraileark
Kaewsuwan, Narong
Abstract
Clostridium thermocellum M2_15-C8 and a genetic modification process of said bacteria, wherein the mutant strain according to this invention can produce cellulase and xylanase more than the wild type. Moreover, the obtained enzymes can be used to digest the pretreated bagasse to further produce sugars effectively.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Dole, Sudhanshu Vijay
Hermann, Theron
Regan, Sean Joseph
Sheff, Mark Andrew
Udani, Russell Lizardo
Yocum, R. Rogers
Abstract
Yeast strains and fermentation process for producing D-lactic acid and L-lactic acid are disclosed with higher titer, higher yield, shorter time, lower pH, and higher average specific productivity.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pornsuriyasak, Papapida
Lunvongsa, Sarawut
Tang-Amornsuksan, Suchada
Abstract
The present invention relates to an isomerization process of product obtained from bisphenol preparation from a condensation reaction of ketone and phenol comprising contacting the product obtained from bisphenol preparation from a condensation reaction of ketone and phenol with the ion exchange resin in aqueous condition for the isomerization of the undesired product and separating the product having higher bisphenol content, wherein said ion exchange resin is aromatic polymer having the sulfonic acid group modified with at least one promoter selected from the compound shown in the structure (I):
C07C 37/20 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
C07C 39/15 - Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings
C07C 39/12 - Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
C07C 37/68 - SeparationPurificationStabilisationUse of additives
C07C 39/14 - Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with at least one hydroxy group on a condensed ring system containing two rings
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Suwan, Puttipong
Chindapon, Suepsakun
Simakajonkiat, Sitthipol
Katinhom, Nattawat
Abstract
The present invention relates to an olefins-paraffins separation process in feed stream containing hydrocarbons with 2 to 4 carbon atoms by facilitated transport membrane specific to olefins, comprising the following step: a. feeding the feed stream containing hydrocarbons with 2 to 4 carbon atoms into distillation column and at least 1 stage of membrane unit connected to distillation column at the feed of distillation column and at least 1 stage of membrane unit connected to the side draw of distillation column; and b. separating a portion of feed stream that is passed from the membrane unit, at least 1 stream is the product stream that mostly comprising olefins and at least 1 stream that mostly comprising paraffins.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Wattanakit, Chularat
Yutthalekha, Thittaya
Thivasasith, Anawat
Wannapakdee, Wannaruedee
Dugkhuntod, Pannida
Suttipat, Duangkamon
Abstract
3) ratio more than 120 and group X metal(s) in a range of 0.3 to 5% by weight. The catalyst according to the conversion of precursor to yields and high olefins selectivity.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Vongachariya, Yanee
Pengpanich, Sitthiphong
Chareonpanich, Metta
Donphai, Waleeporn
Witoon, Thongthai
Ruengrung, Preeyaporn
Abstract
The present invention relates to the adsorbent for separating organochloride compound from liquid hydrocarbon and a process thereof, wherein said adsorbent is the silica and aluminosilicate composite having infiltrate structure subjected to the modification of the surface property with small metal having high electronegativity.
C07C 7/13 - Purification, separation or stabilisation of hydrocarbonsUse of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
C07C 7/12 - Purification, separation or stabilisation of hydrocarbonsUse of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
B01D 15/16 - Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to the conditioning of the fluid carrier
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Wattanakit, Chularat
Rodaum, Chadatip
Thivasasith, Anawat
Pengpanich, Sitthiphong
Abstract
The present invention relates to a catalyst for producing light olefins from C4-C7 hydrocarbons from catalytic cracking reaction and the production process of light olefins from said catalyst, wherein said catalyst has core-shell structure comprising a zeolite core with mole ratio of silicon to aluminium (Si/Al) between 2 to 250 and layered double hydroxide shell (LDH). The catalyst according to the invention provides high percent conversion of substrate to products and high selectivity to light olefins product.
B01J 35/00 - Catalysts, in general, characterised by their form or physical properties
B01J 35/10 - Solids characterised by their surface properties or porosity
C01B 39/02 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereofDirect preparation thereofPreparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactantsAfter-treatment thereof
C10G 11/05 - Crystalline alumino-silicates, e.g. molecular sieves
44.
Copper aluminium oxide catalyst for preparing furfuryl alcohol from furfural and a preparation of said catalyst
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Faungnawakij, Kajornsak
Luadthong, Chuleeporn
Songtawee, Siripit
Ratanatawanate, Chalita
Abstract
2/g; wherein said catalyst is prepared from a process comprising the following steps: (i) dissolving copper salt and aluminium salt in a solvent; (ii) adding organic acid into mixture obtained from step (i); (iii) heating mixture obtained from step (ii) at the temperature higher than 150° C. until said mixture is combusted into solid; and (iv) calcining the solid obtained from step (iii) at the temperature in the range from 700 to 1,000° C. The catalyst according to the invention gives a high conversion of furfural to furfuryl alcohol and high furfuryl alcohol yield.
PTT GLOBAL CHEMICAL PUBLIC COMPANY Limited (Thailand)
Inventor
Junkasem, Jirawut
Kaabbuathong, Narin
Thammongkol, Vivan
Paiboolsuk, Janjira
Hemmood, Supattra
Abstract
This invention discloses a bioplastic composition comprising biomass as a component comprising a plastic compound resin comprising polybutylene succinate (PBS), polylactic acid (PLA), and additives selected from biomass from the coffee roasting processes, i.e. silver skin of coffee (SSC); and/or at least one fluoropolymer or fluoropolymer derivative as a friction reducing agent. This invention also relates to a process of pretreating the silver skin coffee for using as an additive for bioplastic resin to produce various products or using as a natural color masterbatch together with other plastics via extrusion, injection molding, compression and thermoforming processes in the industrial level.
C08G 18/62 - Polymers of compounds having carbon-to-carbon double bonds
C09D 4/06 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups
C08G 18/67 - Unsaturated compounds having active hydrogen
C08G 18/75 - Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
C08G 63/553 - Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
C09D 151/08 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bondsCoating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C09D 167/06 - Unsaturated polyesters having carbon-to-carbon unsaturation
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
48.
A CHAIN EXTENDER AND A PROCESS FOR PREPARING A SELF-HEALING POLYURETHANE AND POLYURETHANE THEREOF
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Wongmahasirikun, Phonpimon
Sae-Ung, Pornpen
Piromjitpong, Parichat
Phomphrai, Khamphee
Kaeothip, Sophon
Euapermkiati, Anucha
Abstract
The present invention relates to a chain extender for preparing a self-healing polyurethane, comprising double bond group, hydroxyl group, and carboxyl group as shown in structure (I) or derivatives thereof.
Bacillus genus bacteria to obtain a seed culture; (b) increasing cell number of bacteria by inoculating the seed culture contained from step (a) into a fermenter containing an initial carbon source under an aerobic condition; (c) fermenting the seed culture obtained from step (b) in the fermenter under a microaerobic condition to obtain lactic acid or its salts; wherein the step (b) comprising at least one addition of the carbon source under any one of the following conditions, where are independent to each other, to increase a concentration of the carbon source:
when the concentration of the carbon source in the fermenter reduces to 50 % or less comparing to the initial concentration.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Dole, Sudhanshu, Vijay
Schmid, Joel, Stewart
Yocum, R., Rogers
Hermann, Theron
Udani, Russell, Lizardo
Regan, Sean, Joseph
Sheff, Mark, Andrew
Spencer, Michelle
Sillers, Ryan
Prasitchoke, Phatthanon
Poomsila, Natthawut
Abstract
Kluyveromyces spKluyveromyces sp. yeast strain that is capable of producing lactic acid from carbon source selected from glucose, fructose, sucrose or a mixture thereof wherein the genetically engineered yeast comprises at least one heterologous DNA cassette that confers production of a protein functioning as a fructose importer. The genetically engineered yeast strain according to this invention has an improvement of fructose utilization and use fructose as a faster rate than conventional strain, allowing for shorter fermentation times and improved economics.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
PTT PUBLIC COMPANY LIMITED (Thailand)
Inventor
Tarapoom, Nattapong
Sompech, Kawisra
Sirimungkalakul, Nichaporn
Abstract
A microchannel heat exchanger comprising: at least one high temperature heat exchanging plate and at least one low temperature heat exchanging plate stacked in an alternating sequence, wherein an inlet of high temperature fluid and an outlet of high temperature fluid are disposed in order to pass the high temperature fluid through each said high temperature heat exchanging plate, and an inlet of low temperature fluid and an outlet of low temperature fluid are disposed in order to pass the low temperature fluid through each said low temperature heat exchanging plate, wherein the high temperature heat exchanging plate comprising the high temperature microchannel and the low temperature heat exchanging plate comprising the low temperature microchannel, wherein said channels have a length extending in the flow direction of fluids, and the side wall of each said channel has a symmetric wavy pattern with the center line of each said channel as a symmetric axis, wherein the high temperature heat exchanging plate and the low temperature heat exchanging plate are arranged in the pattern in which the high temperature microchannel and the low temperature microchannel are aligned.
F28F 13/12 - Arrangements for modifying heat transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media by creating turbulence, e.g. by stirring, by increasing the force of circulation
F28F 3/08 - Elements constructed for building-up into stacks, e.g. capable of being taken apart for cleaning
F28F 3/02 - Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
F28F 3/12 - Elements constructed in the shape of a hollow panel, e.g. with channels
F28D 9/00 - Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
52.
Genetically modified yeast with increased succinic acid production
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Sillers, Ryan
Abstract
Improved yeast cell with increased succinic acid production based on yield and titer. Increased activity of one or more enzymes involved in the pentose phosphate pathway, reducing flux through phosphoglucose isomerase, increasing flux to cytoplasmic acetyl-CoA, installation of a malic enzyme, and/or installation of a formate dehydrogenase leads to increased production of succinic acid.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Terwillegar, Arne Matthew
Tosukhowong, Thidarat
Denniston, Charliss
Jamonnak, Nuttara
Abstract
This invention relates to hybrid polyols useful in the manufacture of polyurethane. The hybrid polyols of the present invention is derived by copolymerizing or grafting a traditional polyester polyol onto a natural oil polyol. In the preferred embodiment of the present invention, the traditional polyester polyol grafted onto natural oil polyol contains a high level of bio-renewable content. The hybrid polyols of the present invention with high level of bio-renewable content is useful in the manufacture of polyurethane either alone or in combination with polyester polyol or polyether polyol derived from petrochemical sources.
C08G 18/18 - Catalysts containing secondary or tertiary amines or salts thereof
C08G 63/91 - Polymers modified by chemical after-treatment
C07C 69/675 - Esters of carboxylic acids having esterified carboxyl groups bound to acyclic carbon atoms and having any of the groups OH, O-metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
C08G 18/24 - Catalysts containing metal compounds of tin
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/76 - Polyisocyanates or polyisothiocyanates cyclic aromatic
C08J 9/12 - Working-up of macromolecular substances to porous or cellular articles or materialsAfter-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
54.
Method of producing succinic acid and other chemicals using facilitated diffusion for sugar import
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Yocum, R. Rogers
Collard, Andrew Christopher
Hermann, Theron
Yu, Xiaohui
Gong, Wei
Abstract
This invention relates to the production of succinic acid and other chemicals derived from phosphoenolpyruvate (PEP) by fermentation with a microorganism in which the fermentation medium contains one or more sugars, and in which one or more of the sugars is imported into the cell by facilitated diffusion. As a specific example, succinic acid is produced from a glucose-containing renewable feedstock through fermentation using a biocatalyst. Examples of such a biocatalyst include microorganisms that have been enhanced in their ability to utilize glucose as a carbon and energy source. The biocatalysts of the present invention are derived from the genetic manipulation of parental strains that were originally constructed with the goal to produce one or more chemicals (for example succinic acid and/or a salt of succinic acid) at a commercial scale using feedstocks that include, for example, glucose, fructose, or sucrose. The genetic manipulations of the present invention involve the introduction of exogenous genes involved in the transport and metabolism of glucose or fructose into the parental strains. The genes involved in the transport and metabolism of glucose or fructose can also be introduced into a microorganism prior to developing the organism to produce a particular chemical. The genes involved in the transport and metabolism of sucrose can also be used to augment or improve the efficiency of sugar transport and metabolism by strains already known to have some ability for glucose utilization in biological fermentations.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Euapermkiati, Anucha
Abstract
The present invention relates to a waterborne sizing composition for treating natural fibers to be used as reinforcing material in thermoplastic, comprising: (a) a polymeric material having structure (I) wherein, R represents an alkyl group, X represents a reversible covalently bonded crosslinkable group, p, q, and r represent order on a main polymer chain, wherein the total sum of order greater than 50; (b) a water-soluble metal complex having an antimicrobial property; and (c) a redox active water-soluble compound.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Terwillegar, Arne Matthew
Denniston, Charliss
Abstract
This invention provides a process for manufacturing high performance polyester polyols with high proportion of renewable content derived from biological sources. The polyester polyols with high content of renewable biological materials produced according to the present invention display no color or odor issues and are used in the manufacture of two component polyurethanes, thermoplastic urethanes, polyurethane dispersions and polyester and polyester/urethane acrylates with outstanding physical properties.
C08G 18/42 - Polycondensates having carboxylic or carbonic ester groups in the main chain
C08G 18/28 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
C08G 18/12 - Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
58.
Process for preparing a catalyst for alkane aromatization
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Pengpanich, Sitthiphong
Abstract
characterized in that the solution of salt in step (b) comprising a glycol solvent as a reducing agent under a basic condition, and step (b) is operated at the temperature higher than 120° C.
C07C 2/76 - Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
59.
MICROORGANISMS AND PROCESSES FOR LACTIC ACID PRODUCTION
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Dole, Sudhanshu, Vijay
Hermann, Theron
Regan, Sean, Joseph
Sheff, Mark, Andrew
Udani, Russell, Lizardo
Yocum, R., Rogers
Abstract
Improved yeast strains and fermentation process for producing D-lactic acid and L- lactic acid are disclosed. The improvement lead to higher titer, higher yield, shorter time, lower pH, and higher average specific productivity.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Thongyai, Supakanok
Pornsuriyasak, Papapida
Tang-Amornsuksan, Suchada
Lunvongsa, Sarawut
Uprijit, Montira
Ounkaew, Siriwanna
Abstract
2 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; m is an integer from 1 to 15; and n is an integer from 1 to 10.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Pornsuriyasak, Papapida
Abstract
This invention relates to a composition for a preparation of polyurethane dispersion, comprising bio-based polyol as shown in structure (I) and polyhydroxy fatty acid compound as shown in structure (II): wherein, R represents a polyhydric alcohol unit that is selected from aliphatic polyhydric alcohol, alicyclic polyhydric alcohol, cyclic polyhydric alcohol, aromatic polyhydric alcohol, or optionally, cyclic polyhydroxyl having heteroatom; R\ represents a hydrocarbon unit obtained from a molecular chain of unsaturated fatty acid having 14-24 carbon atoms and having from 1-6 pairs of vicinal diol group per one molecular chain of such unsaturated fatty acid; n represents an integer from 2 to 8 of an ester group obtained from a reaction of polyhydric alcohol and unsaturated fatty acid; wherein said composition is prepared from a process comprising the steps of: i. mixing fatty acid comprising unsaturated fatty acid and polyhydric alcohol at a ratio of 1 mole equivalent or more of carboxylic group from unsaturated fatty acid per a hydroxy group from polyhydric alcohol; ii. adding organic acid and peroxide compound into the mixture from step i.; iii. adding nucleophilic substance into the mixture from step ii. under acidic condition.
C07C 69/73 - Esters of carboxylic acids having esterified carboxyl groups bound to acyclic carbon atoms and having any of the groups OH, O-metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
C08G 18/36 - Hydroxylated esters of higher fatty acids
C08G 18/24 - Catalysts containing metal compounds of tin
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Wongmahasirikun, Phonpimon
Chotchatchawankul, Sucheewin
Phomphrai, Khamphee
Kaeothip, Sophon
Abstract
This invention relates to a catalyst composition for a producing process of an unsaturated carboxylic acid salt and its derivatives from carbon dioxide and olefin, wherein the catalyst composition in the present invention has been proved to be effective in catalyzing the carboxylation of carbon dioxide and olefin, wherein said catalyst composition comprises: a) a palladium metal complex as shown in structure (I); {formula (I)} wherein, R1, R2, R3, and R4independently represents a group selected from hydrogen atom, halogen atom, alkyl group, alkyl halide group, alkoxy group, amine group, optionally from alkenyl group, alkynyl group, phenyl group, benzyl group, or cylic hydrocarbon group comprising hetero atom; R5 represents group selected from alkyl group or phenyl group; b) a ligand selected from organophosphorus compound; c) a base selected from sodium tert-butoxide, sodium isopropoxide, sodium 2,6-dimethylphenolate, sodium 2,6-difluorophenolate, sodium 2-methylphenolate, or sodium 2-fluorophenolate); and d) a reducing agent.
C08C 19/36 - Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups with carboxy radicals
63.
A CATALYST FOR PRODUCING OLEFINS FROM DEHYDROGENATION OF ALKANE AND A METHOD FOR PRODUCING OLEFINS USING SAID CATALYST
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Wattanakit, Chularat
Yuttthalekha, Thittaya
Thivasasith, Anawat
Wannapakdee, Wannaruedee
Dugkhuntod, Pannida
Suttipat, Duangkamon
Abstract
2233) ratio more than 120 and group X metal(s) in a range of 0.3 to 5% by weight. The catalyst according to the conversion of precursor to yields and high olefins selectivity.
PTT Global Chemical Public Company Limited (Thailand)
Inventor
Pimolsiriphol, Vorapong
Prai-In, Yingrak
Panyathanmaporn, Thammarat
Abstract
The present invention relates to a coalescing agent and a coating composition containing the coalescing agent as represented in structure (I);
2 independently represents group selected from alkyl, alkenyl, alkynyl, phenyl, or benzyl groups; and X represents group selected from hydroxy or amine. The coalescing agent according to this invention contains low amount of volatile organic compounds, has no pungent odour, and environmental friendly. Moreover, it provides good efficacy when being used as coating component.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Yocum, R., Rogers
Grabar, Tammy
Hermann, Theron
Martin, Christopher Joseph
Sillers, Ryan
Yu, Xiaohui
Zhou, Xiaomei
Abstract
The invention provides processes for identifying and tracking genomic duplications that can occur during classical strain development or during the metabolic evolution of microbial strains originally constructed for the production of a biochemical through specific genetic manipulations, processes that stabilize the copy number of desirable genomic duplications using appropriate selectable markers, and non-naturally occurring microorganisms with stabilized copy numbers of a functional DNA sequence.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Vacharanukrauh, Treerat
Tarapoom, Nattapong
Sompech, Kawisra
Bumroongsri, Pornchai
Duangsri, Siwaporn
Jaherng, Thanyalak
Abstract
A device for multi-stage rotating fluidized bed comprising at least two annular chambers stacking in center axis disposed with a most outer wall and a most inner wall, wherein said most outer wall disposed with fluid feeding part comprising an inlet opening in a direction of an angle to a tangent line in order to inject fluid to said annular chambers, wherein said annular chambers is separated by a chamber wall and disposed with a solid inlet part and a solid outlet part; and wherein said most inner wall is disposed with a fluid discharging part for discharging fluid from the device. Moreover, the chamber wall is disposed with a means for transferring fluid and solid from one annular chamber to another annular chamber in a direction of from large to small chamber diameter.
B01F 5/00 - Flow mixers; Mixers for falling materials, e.g. solid particles
B01J 8/04 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
B01J 8/38 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation
F28D 11/02 - Heat-exchange apparatus employing moving conduits the movement being rotary, e.g. performed by a drum or roller
B01D 24/28 - Filters comprising loose filtering material, i.e. filtering material without any binder between the individual particles or fibres thereof with the filter bed moving during the filtration
67.
Ion exchange resin for producing bisphenol, and a method for producing bisphenol using said ion exchange resin
PTT GLOBAL CHEMICAL PUBLIC COMPANY Limited (Thailand)
Inventor
Pengpanich, Sitthiphong
Pornsuriyasak, Papapida
Tang-Amornsuksan, Suchada
Abstract
This invention relates to an ion exchange resin for producing bisphenol with high percent conversion and high percent selectivity to bisphenol, especially 4,4′ isopropyhdenediphenol, wherein said ion exchange resin comprising aromatic polymer having sulfonic acid group modified with at least one promoter selected from compounds shown in the structure (I), (II), (III), (IV) or its amine salt: wherein R represents hydrocarbon unit with 1 to 6 carbon atoms selected from alkyl group, alkenyl group, alkynyl group, phenyl group, or optionally hydrocarbon containing carbonyl group having 1 to 6 carbon atoms; X represents heteroatom; n is an integer number from 1 to 4.
B01J 39/00 - Cation exchangeUse of material as cation exchangersTreatment of material for improving the cation exchange properties
C07C 37/20 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
C08F 8/34 - Introducing sulfur atoms or sulfur-containing groups
C08F 8/30 - Introducing nitrogen atoms or nitrogen-containing groups
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Tachaapaikoon, Chakrit
Ratanakhanokchai, Khanok
Pason, Patthra
Waeonukul, Rattiya
Ketbot, Prattana
Techanan, Wikanda
Kittisuriyanont, Kraileark
Kaewsuwan, Narong
Abstract
Clostridium thermocellumClostridium thermocellum M2_15-C8 and a genetic modification process of said bacteria, wherein the mutant strain according to this invention can produce cellulase and xylanase more than the wild type. Moreover, the obtained enzymes can be used to digest the pretreated bagasse to further produce sugars effectively.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pornsuriyasak, Papapida
Kaeothip, Sophon
Abstract
The present invention relates to a new diethanolamine derivative chelating agent having a high water solubility, a good chelating property, and biological degradation. The said new chelating agent can be prepared from reaction of diethanolamine and cyclic anhydride compound using lewis acid as the catalyst. The said process is uncomplicated, and does not use a severe condition, and also reduces the use of harmful chemicals.
C07C 233/16 - Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
C07C 233/30 - Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by doubly-bound oxygen atoms
70.
ASPERGILLUS ACULEATUS FOR PRODUCING CELLULASE AND XYLANASE AND PREPARATION METHOD THEREOF
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Champreda, Verawat
Suwannarangsee, Surisa
Arnthong, Jantima
Siamphan, Chatuphon
Poonsrisawat, Aphisit
Ketsub, Napong
Phinyo, Mahattanee
Techanan, Wikanda
Poomsila, Natthawut
Prasitchoke, Phatthanon
Abstract
Aspergillus aculeatus Aspergillus aculeatus E14-292 and a genetic modification process of said strain, wherein the mutant strain according to this invention can produce cellulase and xylanase more than the BCC199 (wild type). Moreover, the obtained enzymes can be used to digest the pretreatment bagasse to further produce sugars effectively.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Terwillegar, Arne Matthew
Denniston, Charliss
Jamonnak, Nuttara
Tosukhowong, Thidarat
Abstract
This invention relates to a thermally and/or high-energy radiation curable waterborne or 100% solid coating with high bio-based content. The coating formulation according to the present invention is derived or partially derived from melt polycondensation of a carboxylic acid and a diol with dicyclopentadiene-maleic acid half-ester or nadic acid-maleic acid half-ester or methyl nadic acid-maleic acid half-ester.
C09D 167/07 - Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
C09D 167/06 - Unsaturated polyesters having carbon-to-carbon unsaturation
C09D 4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
C08G 63/40 - Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
C08G 63/685 - Polyesters containing atoms other than carbon, hydrogen, and oxygen containing nitrogen
C09D 11/101 - Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Suriyachai, Nopparat
Champreda, Verawat
Laosiripojana, Navadol
Abstract
This invention aims to develop a process for fractionation of lignocellulosic biomass by contacting lignocellulosic biomass with treatment liquid in close system at temperature not over 200° C. and pressure of 5 to 20 bars, wherein said treatment liquid comprises water-miscible part that comprising formic acid, alcohol, and water and water-immiscible part that comprising alkyl acetate. The lignocellulosic biomass may be selected from rice straw, bagasse, corncobs, corn stem, palm waste, grass, pineapple shell, bamboo, or mixture thereof.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
PTT PUBLIC COMPANY LIMITED (Thailand)
Inventor
Tarapoom, Nattapong
Vacharanukrauh, Treerat
Sompech, Kawisra
Srithammarat, Wannawijit
Klannark, Supawish
Sirimungkalakul, Nichaporn
Sornchamni, Thana
Chuvaree, Rungroj
Abstract
A heat exchanger for exchanging heat of fluids having different temperatures, comprising: at least one smooth heat exchanging plate; at least one high temperature heat exchanging plate; and at least one low temperature heat exchanging plate stacked in an alternating sequence, wherein an inlet of high temperature fluid and an outlet of high temperature fluid are disposed in order to pass a high temperature fluid through each said high temperature heat exchanging plate, and an inlet of low temperature fluid and an outlet of low temperature fluid are disposed in order to pass a low temperature fluid through each said low temperature heat exchanging plate, wherein said high temperature heat exchanging plate and said low temperature the heat exchanging plate comprising a high temperature channel and a low temperature channel, wherein said channels have a length extending in a flow direction of said fluids and a side wall of each said channel has a symmetric wavy pattern with the center line of said channel.
F28F 13/12 - Arrangements for modifying heat transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media by creating turbulence, e.g. by stirring, by increasing the force of circulation
F28D 9/00 - Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
F28D 9/02 - Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the heat-exchange media travelling at an angle to one another
F28F 3/00 - Plate-like or laminated elementsAssemblies of plate-like or laminated elements
F28F 3/02 - Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
F28F 3/08 - Elements constructed for building-up into stacks, e.g. capable of being taken apart for cleaning
F28F 3/12 - Elements constructed in the shape of a hollow panel, e.g. with channels
74.
A CATALYST COMPOSITION FOR A PRODUCTION PROCESS OF δ- LACTONE FROM CARBON DIOXIDE AND 1,3-BUTADIENE
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Chotchatchawankul, Sucheewin
Wongmahasirikun, Phonpimon
Kaeotip, Sophon
Phomphrai, Khamphee
Abstract
This present invention relates to a catalyst composition for a production process of δ-lactone from carbon dioxide and 1,3 -butadiene that can efficiently catalyze the synthesis reaction of δ-lactone with good selectivity of δ-lactone, wherein said catalyst composition comprising: a) palladium metal complexes as shown in structure (I) [Formula should be inserted here] wherein, R1, R2, R3 and R4 independently represents a group selected from a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an amine group, or optionally an alkenyl group, an alkynyl group, a phenyl group, a benzyl group, or a cyclic hydrocarbon group comprising a hetero atom; and b) phosphorus compound selected from a phosphine group having a general formula [Formula should be inserted here], wherein R5 is selected from an alkyl group, a cycloalkyl group, or an aryl group.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Ozmeral, Cenan
Dasari, Rajesh
Singh, Ramnik
Noda, Yu
Rioux, Robert M.
Roman-Leshkov, Yuriy
Abstract
Described herein are solid acid catalysts and the methods for catalytically preparing α,β-unsaturated carboxylic acids and/or esters thereof. In one aspect, a zeolite catalyst may be used. The catalyst may, in certain embodiments, be modified to improve the selectivity and/or conversion of a reaction. For instance, a catalyst may be modified by ion exchange to achieve a desirable acidity profile in order to achieve high level of conversion of reactants and selectivity for desirable products of the catalytic reaction. In another aspect, a variety of feed stocks (e.g., starting compositions) may be used including an α-hydroxycarboxylic acid, an α-hydroxycarboxylic acid ester, a β-hydroxycarboxylic acid, a β-hydroxycarboxylic acid ester, cyclic esters thereof (e.g., lactide), and combinations thereof.
C07C 51/377 - Preparation of carboxylic acids or their salts, halides, or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groupsPreparation of carboxylic acids or their salts, halides, or anhydrides by reactions not involving formation of carboxyl groups by hydrogenolysis of functional groups
C07C 45/54 - Preparation of compounds having C=O groups bound only to carbon or hydrogen atomsPreparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
B01J 29/08 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the faujasite type, e.g. type X or Y
B01J 29/40 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
B01J 29/60 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the type L
B01J 29/70 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups
B01J 35/00 - Catalysts, in general, characterised by their form or physical properties
B01J 29/18 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the mordenite type
B01J 37/02 - Impregnation, coating or precipitation
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Prasitchoke, Phatthanon
Kittisuriyanont, Kraileark
Kaewsuwan, Narong
Poomsila, Natthawut
Thongchul, Nuttha
Abstract
This invention relates to a fermentation process for producing D-lactic acid or its salts. The said process comprises the following steps: cultivating of Sporolactobacillus laevolacticus bacteria strain by fermentation with sugarcane juice in order to obtain the seed culture; fermenting of the obtained seed culture in sugarcane juice, wherein the cultivation step is operated for the time that the final concentration of Sporolactobacillus laevolacticus strain in the cultivation step is in a range of 400 to 1,600 mg of dry cell per liter. The said process according to the invention can provide high productivity and yield of the D-lactic acid with a high optical purity. Moreover, the said process can be easily done and reduces the complicate steps.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Kaeothip, Sophon
Pornsuriyasak, Papapida
Pimolsiriphol, Vorapong
Abstract
The present invention relates to a coalescing agent as represented in structure (I); wherein; n is integer from 1 to 8; R1and R2 independently represent group selected from hydrogen atom, alkyl, alkenyl, alkynyl, phenyl, benzyl groups, or optionally cyclic hydrocarbon containing heteroatom; and Y represents group selected from alkyl, alkenyl, alkynyl, phenyl, benzyl groups, or cyclic hydrocarbon containing heteroatom. The said coalescing agent can be used in coating application with efficacy to provide smooth consistent film with chemical and scratch resistant and has no pungent odour, wherein the preparation method of this compound is simplify and employs less harmful chemicals.
C07D 317/24 - Radicals substituted by singly bound oxygen or sulfur atoms esterified
C07D 317/30 - Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
C07D 407/12 - Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group containing two hetero rings linked by a chain containing hetero atoms as chain links
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Terwillegar, Arne, Matthew
Tosukhowong, Thidarat
Denniston, Charliss
Jamonnak, Nuttara
Abstract
This invention relates to hybrid polyols useful in the manufacture of polyurethane. The hybrid polyols of the present invention is derived by copolymerizing or grafting a traditional polyester polyol onto a natural oil polyol. In the preferred embodiment of the present invention, the traditional polyester polyol grafted onto natural oil polyol contains a high level of bio- renewable content. The hybrid polyols of the present invention with high level of bio-renewable content is useful in the manufacture of polyurethane either alone or in combination with polyester polyol or polyether polyol derived from petrochemical sources.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Faungnawakij, Kajornsak
Luadthong, Chuleeporn
Songtawee, Siripit
Ratanatawanate, Chalita
Abstract
The present invention relates to a copper aluminium oxide catalyst for preparing a furfuryl alcohol from a furfural, comprising a copper-alumina spinel structure and having surface area in the range from 0.5 to 5 m2 /g; wherein said catalyst is prepared from a process comprising the following steps: (i) dissolving copper salt and aluminium salt in a solvent; (ii) adding organic acid into mixture obtained from step (i); (iii) heating mixture obtained from step (ii) at the temperature higher than 150 °C until said mixture is combusted into solid; and (iv) calcining the solid obtained from step (iii) at the temperature in the range from 700 to 1,000 °C. The catalyst according to the invention gives a high conversion of furfural to furfuryl alcohol and high furfuryl alcohol yield.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
CHULALONGKORN UNIVERSITY (Thailand)
Inventor
Thongchul, Nuttha
Kodama, Kentaro
Nantarajit, Paphawee
Techanan, Wikanda
Prasitchoke, Phatthanon
Abstract
The present invention relates to a novel Bacillus aerolacticus BC-001 species and a method for producing lactic acid or its salts using said bacteria, wherein the novel bacteria species can produce L-lactic acid or its salts with high optical purity from carbohydrate carbon sources, including oligosaccharide, disaccharide and monosaccharide, wherein said bacteria can grow well under an aerobic condition, tolerate to high temperature in a range of 45 to 60°C.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pimolsiriphol, Vorapong
Prai-In, Yingrak
Panyathanmaporn, Thammarat
Abstract
The present invention relates to a coalescing agent and a coating composition containing the coalescing agent as represented in structure (I); wherein; n is integer from 1 to 8; R1 and R2 independently represents group selected from alkyl, alkenyl, alkynyl, phenyl, or benzyl groups; and X represents group selected from hydroxy or amine. The coalescing agent according to this invention contains low amount of volatile organic compounds, has no pungent odour, and environmental friendly. Moreover, it provides good efficacy when being used as coating component.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Kruenate, Jittiporn
Baiagern, Silapong
Tangchantra, Nantavat
Thongprachan, Napawon
Abstract
The present invention relates to a method for preparing a blend composition of flour and polyolefin by using twin screw extruder, wherein said method comprising the following steps: (a) adding flour containing protein, fiber, and lipid in the range from 5 to 25 % by dry weight into position 1 of said twin screw extruder; (b) adding plasticizer into position 2 of said twin screw extruder; (c) adding polyolefin into position 3 of said twin screw extruder; wherein distance between position 1 and position 2 is in the range from 0 to 0.2 times of total length of extruder, and distance between position 2 and position 3 is in the range from 0.1 to 0.3 times of total length of extruder; and wherein overall temperature of said twin screw extruder is in the range from 90 to 210 °C, and screw speed of said twin screw extruder is in the range from 200 to 500 rpm.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Denchokpraguy, Naphatsaya
Champreda, Verawat
Laosiripojana, Navadol
Abstract
The present invention relates to a pretreatment process of lignocellulosic biomass, comprising contacting lignocellulosic biomass with pretreatment solution in a temperature ranging from an ambient temperature to 100° C. and a pressure of at least 20 bars, wherein the pretreatment solution comprising water, water-miscible organic solvent and alkali having a concentration of 5 to 15% w/v if the alkali is solid or 5 to 15% v/v if the alkali is liquid. Said pretreatment process operates in mild condition or at low temperature to be specified with the removing of lignin but not destroying cellulose and increasing desired sugar yield.
D21C 3/02 - Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
D21C 3/20 - Pulping cellulose-containing materials with organic solvents
C13K 1/02 - GlucoseGlucose-containing syrups obtained by saccharification of cellulosic materials
C12P 7/64 - FatsFatty oilsEster-type waxesHigher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl groupOxidised oils or fats
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Thongyai, Supakanok
Pornsuriyasak, Papapida
Tang-Amornsuksan, Suchada
Lunvongsa, Sarawut
Uprijit, Montira
Ounkaew, Siriwanna
Abstract
The present invention relates to a method for preparing poly(carbonate- etherimide) compound comprising polycarbonate segment as shown in the structure (A) and polyetherimide segment as shown in the structure (B). Said method does not contain a highly toxic phosgene in its operation, can be performed easily, and can be operated at not high temperature. wherein R1 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; R2 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; m is an integer from 1 to 15; and n is an integer from 1 to 10.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pengpanich, Sitthiphong
Pornsuriyasak , Papapida
Tang-Amornsuksan, Suchada
Abstract
This invention relates to an ion exchange resin for producing bisphenol with high percent conversion and high percent selectivity to bisphenol, especially 4,4' isopropyhdenediphenol, wherein said ion exchange resin comprising aromatic polymer having sulfonic acid group modified with at least one promoter selected from compounds shown in the structure (I), (II), (III), (IV) or its amine salt: wherein R represents hydrocarbon unit with 1 to 6 carbon atoms selected from alkyl group, alkenyl group, alkynyl group, phenyl group, or optionally hydrocarbon containing carbonyl group having 1 to 6 carbon atoms; X represents heteroatom; n is an integer number from 1 to 4.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Suriyachai, Nopparat
Champreda. Verawat
Laosiripojana, Navadol
Abstract
This invention aims to develop a process tor fractionation of lignocellulosic biomass by contacting lignocelluIosic biomass with treatment liquid in close system at temperature not over 200 °C and pressure of 5 to 20 bars, wherein said treatment liquid comprises water-miscible part that comprising formic acid, alcohol, and water and water-immiscible part that comprising alkyl acetate. The lignocellulosic biomass may be selected from rice straw, bagasse, corncobs, corn stem, palm waste, grass, pineapple shell, bamboo, or mixture thereof.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Yunyongwattanakorn, Jintana
Kositchaiyong, Apisit
Suppaibulsuk, Bunthita
Kunanuruksapong, Ruksapong
Abstract
The present invention relates to a thermoplastic composition with improved mechanical properties in order to broaden applications of this composition, especially outdoor application. Said thermoplastic composition comprising 60 to 80 parts by weight of aromatic polycarbonate and 20 to 40 parts by weight of acrylonitrile-styrene- acrylate polymer, characterized in that said aromatic polycarbonate has linear structure and its molecular weight is in a range of 20,000 to 35,000 g/mol; and said acrylonitrile-styrene-acrylate polymer comprising 60 wt % or more of rubber grafted with styrene and acrylonitrile polymer and 40 wt % or less of styrene and acrylonitrile polymer.
C08L 33/06 - Homopolymers or copolymers of esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
C08L 51/04 - Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bondsCompositions of derivatives of such polymers grafted on to rubbers
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
CHULALONGKORN UNIVERSITY (Thailand)
Inventor
Thongchul Nuttha
Tolieng Vasana
Prasitchoke, Phatthanon
Abstract
This invention relates to a process for producing lactic acid or its salts that can be performed easily, reduce complicated steps, and provide high lactic acid yield and high productivity, wherein said process comprising the following steps: (a) cultivating thermotolerance Bacillus genus bacteria to obtain a seed culture; (b) increasing cell number of bacteria by inoculating the seed culture obtained from step (a) into a fermenter containing an initial carbon source under an aerobic condition; (c) fermenting the seed culture obtained from step (b) in the fermenter under a microaerobic condition to obtain lactic acid or its salts; wherein the step (b) comprising at least one addition of the carbon source under any one of the following conditions, which are independent to each other, to increase a concentration of the carbon source: - when the concentration of carbon source in the fermenter reduces to 50 % or less comparing to the initial concentration.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pornsuriyasak, Papapida
Abstract
This invention relates to a composition for a preparation of polyurethane dispersion, comprising bio-based polyol as shown in structure (I) and polyhydroxy fatty acid compound as shown in structure (II): wherein, R represents a polyhydric alcohol unit that is selected from aliphatic polyhydric alcohol, alicyclic polyhydric alcohol, cyclic polyhydric alcohol, aromatic polyhydric alcohol, or optionally, cyclic polyhydroxyl having heteroatom; R\ represents a hydrocarbon unit obtained from a molecular chain of unsaturated fatty acid having 14 - 24 carbon atoms and having from 1 - 6 pairs of vicinal diol group per one molecular chain of such unsaturated fatty acid; n represents an integer from 2 to 8 of an ester group obtained from a reaction of polyhydric alcohol and unsaturated fatty acid; wherein said composition is prepared from a process comprising the steps of: i. mixing fatty acid comprising unsaturated fatty acid and polyhydric alcohol at a ratio of 1 mole equivalent or more of carboxylic group from unsaturated fatty acid per a hydroxy group from polyhydric alcohol; ii. adding organic acid and peroxide compound into the mixture from step i.; iii. adding nucleophilic substance into the mixture from step ii. under acidic condition.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Hermann, Theron
Reinhardt, James
Yu, Xiaohui
Udani, Russell
Staples, Lauren
Abstract
This invention relates to improvements in the fermentation process used in the production of organic acids from biological feedstock using bacterial catalysts. The improvements in the fermentation process involve providing a fermentation medium comprising an appropriate form of inorganic carbon, an appropriate amount of aeration and a biocatalyst with an enhanced ability to uptake and assimilate the inorganic carbon into the organic acids. This invention also provides, as a part of an integrated fermentation facility, a novel process for producing a solid source of inorganic carbon by sequestering carbon released from the fermentation in an alkali solution.
01 - Chemical and biological materials for industrial, scientific and agricultural use
17 - Rubber and plastic; packing and insulating materials
Goods & Services
Plastic unprocessed; chemical products used in the plastic industry, namely, unprocessed polyethylene resins Semi-processed plastics in the form of pellets, films, sheets, tubes, bars or rods; synthetic resins in semi-processed form in the form of pellets
92.
Process for manufacturing acrylic acid, acrylonitrile and 1,4-butanediol from 1,3-propanediol
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Gnanadesikan, Vijay
Singh, Ramnik
Dasari, Rajesh
Alger, Montgomery
Abstract
The present invention is in the field of producing bio-based commodity organic chemicals such as bio-acrylic acid, bio-acrylonitrile, and bio-1,4-butanediol using renewable carbon sources as feedstock. In the first stage of the present invention, bio-1,3-propanediol is derived from renewable carbon sources through microbial fermentation. In the second stage of the present invention, bio-1,3-propanediol is converted into bio-acrylic acid or bio-acrylonitrile or bio-1,4-butanediol.
C07C 51/27 - Preparation of carboxylic acids or their salts, halides, or anhydrides by oxidation with oxides of nitrogen or nitrogen-containing mineral acids
C07C 29/60 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of hydroxy groups, e.g. by dehydration
C07C 51/285 - Preparation of carboxylic acids or their salts, halides, or anhydrides by oxidation with peroxy-compounds
C07C 209/16 - Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
C07C 253/26 - Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
C07C 29/44 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon double or triple bond
C07C 51/16 - Preparation of carboxylic acids or their salts, halides, or anhydrides by oxidation
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Tang-Amornsuksan, Suchada
Potisatityuenyong, Anupat
Abstract
This invention relates to a biodegradable copolyester composition, comprising: a) from 40 to 60 mol %, based on total mole of a) and b), of aromatic dicarboxylic acid selected from benzene dicarboxylic acid or ester derivative of said acid; b) from 40 to 60 mol %, based on total mole of a) and b), of a mixture of aliphatic dicarboxylic acid, wherein b) comprising: bl) from 20 to 80 mol %, based on mole of b), of at least one aliphatic dicarboxylic acid having 2 to 6 carbon atoms; and b2) from 20 to 80 mol %, based on mole of b), of at least one aliphatic dicarboxylic acid having 7 to 14 carbon atoms; c) at least one mole equivalent, based on total mole of a) and b), of diol having 2 to 6 carbon atoms; and d) from 0.1 to 2.0 mole % based on total mole of a), b), c), and d), of alcohol with at least 3 hydroxyl groups. The biodegradable copolyester composition according to this invention has improved thermal property, mechanical property, and biodegradability.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pengpanich, Sitthiphong
Losiriwat, Takul
Abstract
The present invention relates to a process for improving stability of zeolite catalyst to use in cumene production by alkylation of benzene with isopropyl alcohol comprising contacting zeolite catalyst with silane compound in a certain condition. This results in the zeolite catalyst which is stable to water which is by-product of the reaction, providing longer ability to catalyze alkylation reaction.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Pornsuriyasak, Papapida
Potisatityuenyong, Anupat
Abstract
This invention relates to a method for preparing diethanolamine derivatives having the structure (I): Formula (I); wherein Formula (II); R1 represents structure (II) R2 represents hydrogen or structure (II); X represents hydrogen, alkali or alkaline earth metal; by reacting diethanolamine with maleic anhydride, butenedioic acid or butenedioic acid salts in the presence of alkali or alkaline earth metal hydroxide.
C07C 227/16 - Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof by reactions not involving the amino or carboxyl groups
C07C 229/24 - Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having more than one carboxyl group bound to the carbon skeleton, e.g. aspartic acid
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Denchokpraguy, Naphatsaya
Champreda, Verawat
Laosiripojana, Navado
Abstract
The present invention relates to a pretreatment process of lignocellulosic biomass, comprising contacting lignocellulosic biomass with pretreatment solution in a temperature ranging from an ambient temperature to 100 °C and a pressure of at least 20 bars, wherein the pretreatment solution comprising water, water-miscible organic solvent and alkali having a concentration of 5 to 15% w/v if the alkali is solid or 5 to 15% v/v if the alkali is liquid.. Said pretreatment process operates in mild condition or at low temperature to be specified with the removing of lignin but not destroying cellulose and increasing desired sugar yield.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Grabar, Tammy
Gong, Wei
Yocum, R. Rogers
Abstract
This invention relates to the metabolic evolution of a microbial organism previously optimized for producing an organic acid in commercially significant quantities under fermentative conditions using a hexose sugar as sole source of carbon in a minimal mineral medium. As a result of this metabolic evolution, the microbial organism acquires the ability to use pentose sugars derived from cellulosic materials for its growth while retaining the original growth kinetics, the rate of organic acid production and the ability to use hexose sugars as a source of carbon. This invention also discloses the genetic change in the microorganism that confers the ability to use both the hexose and pentose sugars simultaneously in the production of commercially significant quantities of organic acids.
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Samingprai, Sutheerawat
Kangwanwong, Tienkul
Phetrak, Nared
Abstract
The present invention relates to a method for preparing a high activity olefin polymerization catalyst, which is easy to be produced, reducing complicated steps, and can be produced at low temperature, wherein said method comprising the following steps: • (a) adding a magnesium halide into an alcohol solvent; • (b) precipitating the solution obtained from (a) in a solution of an organic solvent containing an organo compound of group III element; • (c) adding a titanium compound into the mixture obtained from (b) to obtain a catalyst; • (d) treating the catalyst obtained from (c) with an organoaluminium compound at a temperature ranging from 0 to 60 °C for 2 to 5 hours, wherein the mole ratio of aluminium to titanium (Al/Ti) for treatment is in a range of 1 to 30.
Bio-based polymer additive, a process for preparing the bio-based polymer additive and a biodegradable polymer composition comprising said bio-based polymer additive
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Prasitchoke, Phatthanon
Jong-Anurakkun, Nilubon
Jamsak, Wasana
Chandavasu, Chaya
Pleekhunt, Montree
Abstract
The present invention disclosed a bio-based polymer additive, its preparation process and a biodegradable polymer composition comprising the said bio-based polymer additive for use in manufacturing of biodegradable plastic. The said additive is prepared from the biomass of broken microorganism cell such as microalgae, yeast or other microorganisms. In particular, the bio-based polymer additive is for enhancing rheological properties and/or biodegradability of a polymer. In particular, the additive is for use as a pigment.
C08L 67/00 - Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chainCompositions of derivatives of such polymers
C08L 89/00 - Compositions of proteinsCompositions of derivatives thereof
C08L 99/00 - Compositions of natural macromolecular compounds or of derivatives thereof not provided for in groups or
C08L 101/16 - Compositions of unspecified macromolecular compounds the macromolecular compounds being biodegradable
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C07C 13/28 - Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
C07D 311/04 - Benzo [b] pyrans, not hydrogenated in the carbocyclic ring
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
C08K 5/3417 - Five-membered rings condensed with carbocyclic rings
100.
MOLECULAR WEIGHT ENHANCING AGENT OF POLYESTER COMPRISING AMIDOALKYLIDENE MALONATE, A PROCESS OF ENHANCING MOLECULAR WEIGHT AND POLYESTER OBTAINED FROM SAID MOLECULAR WEIGHT ENHANCING AGENT
PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED (Thailand)
Inventor
Losiriwat, Takul
Potisatityuenyong, Anupat
Abstract
The present invention relates to a molecular weight enhancing agent of polyester comprising amido alkylidene malonate, a process for enhancing molecular weight and polyester obtained from the molecular weight enhancing agent. The molecular weight enhancing agent contains alkylidene malonate group having amido electron withdrawing group in the structure at alpha-carbon position. The molecular weight enhancing agent has high reactivity and can be used at low temperature, thus is suitable for polyester, especially, low melting point polyester and reduces energy consumption during the process.