SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Lan, Dawei
Yang, Weimin
Wang, Zhendong
Li, Xiangcheng
Liu, Chuang
Li, Junjie
Wang, Wennian
Abstract
A hydrogenation-acid catalysis bifunctional catalyst, based on the mass of the catalyst, contains 80-99.8% of a silica-alumina molecular sieve component, 0.2-2% of a metal component with hydrogenation activity supported on the molecular sieve, and 0-20% of a hydrocarbyl modifying component. The hydrogenation active metal is selected from ruthenium, platinum, palladium, copper, nickel, or a combination thereof. The hydrocarbyl modifying component is a C1-20 hydrocarbyl. The catalyst has dual functions of hydrogenation and acid catalysis, and is suitable for benzene hydroalkylation reaction and alkane hydroisomerization reaction. It can be used in the benzene hydroalkylation to produce cyclohexylbenzene with high benzene conversion rate, high product selectivity, and less by-product cyclohexane.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Zhao, Shengli
Qiao, Jian
Yuan, Zhiqing
Wang, Zhendong
Fu, Wenhua
Tao, Weichuan
Abstract
A SCM-38 molecular sieve and preparation process and use thereof are provided. The SCM-38 molecular sieve is a phosphorus-aluminium or silicon-phosphorus-aluminium molecular sieve, which has the following diffraction peak feature in its XRD spectrum: X-ray diffraction peaks appear at 2θ of 7.20±0.1, 10.81±0.1, 11.60±0.1, 14.32±0.1, 21.39±0.1, 21.83±0.1, 27.31±0.1, 28.72±0.1. The most intense peak appears at 2θ of 7.20±0.1.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Wang, Zhendong
Ma, Duozheng
Liu, Songlin
Liu, Chuang
Li, Xiangcheng
Yuan, Zhiqing
Abstract
A silicon-aluminum zeolite SCM-36, a manufacturing method therefor and an application thereof are provided. The zeolite has a silicon/aluminum ratio n≥5, and has a distinctive XRD diffraction spectrum. The SCM-36 zeolite can be used as an adsorbent, a catalyst, or a catalyst carrier.
C01B 39/48 - Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
B01J 29/70 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups
C07C 2/86 - Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
4.
ETHYLBENZENE DEHYDROGENATION CATALYST, PREPARATION METHOD THEREFOR, AND USE THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zeng, Tieqiang
Miao, Changxi
Song, Lei
Wei, Chunling
Zhu, Min
Zhang, Zhengpai
Xu, Yongfan
Zha, Kaiwen
Abstract
An ethylbenzene dehydrogenation catalyst, a preparation method therefor, and the use thereof are provided. The catalyst includes Fe2O3, K2O, CeO2, MoO3 and CaO. The exposed crystal face area of CeO2 (100) accounts for 60% or more of the total exposed crystal face area of CeO2. The catalyst is used in a reaction for preparing styrene by means of dehydrogenating ethylbenzene at a low water ratio, and has high activity and stability.
B01J 23/76 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups
B01J 35/00 - Catalysts, in general, characterised by their form or physical properties
B01J 35/70 - Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
B01J 37/00 - Processes, in general, for preparing catalystsProcesses, in general, for activation of catalysts
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Li, Jun
Wang, Zhendong
Wang, Xiaofei
Lan, Dawei
Zhang, Daoming
Xue, Haoliang
Zhou, Sifei
Abstract
A separator for a lithium-sulfur battery, a method for preparing the same and a lithium-sulfur battery containing the same are provided. The separator includes a polymeric substrate film and a composite layer on one surface of the polymeric substrate film. The composite layer has a SCM molecular sieve and a conductive carbon material. The SCM molecular sieve is selected from SCM-14 and SCM-15. The SCM molecular sieve further contains cobalt. The separator in accordance can effectively suppress the shuttle of polysulfides in lithium-sulfur batteries, and thereby reduce side reactions within the batteries, lower the self-discharge rate of lithium-sulfur batteries, and improve the cycling performances, rate performances, and storage life of the batteries.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Xiaohong
Qi, Guozhen
Yu, Zhinan
Peng, Fei
Wang, Hongtao
Zheng, Yijun
Abstract
A short contact reaction system for preparing ethylene and propylene from methanol includes an MTO short contact reactor, a riser reactor, a dense bed, and a stripper. The MTO short contact reactor has the following components coaxially distributed from inside to outside: a methanol feeding pipeline, a filter pipe wall, a product gas channel, and a catalyst distributor arranged at the top of the reactor, and a seal pipe arranged at the bottom of the reactor. The seal pipe is located in the stripper. The diameter at the top of the product gas channel is smaller than the diameter at the bottom of the product gas channel. Methanol is in crossflow contact with the descending coked catalyst II in the MTO short contact reactor.
B01J 8/12 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with moving particles moved by gravity in a downward flow
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
B01J 8/08 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with moving particles
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
7.
Hydrocarbyl tetralin polyethersulfonate, preparation method therefor and use thereof
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Bao, Xinning
Li, Yingcheng
Zhang, Weidong
Jin, Jun
Meng, Yong
Zhang, Li
Abstract
A hydrocarbyl tetralin polyethersulfonate, preparation method therefor and use thereof are provided. The hydrocarbyl tetralin polyethersulfonate is of formula (I-0),
A hydrocarbyl tetralin polyethersulfonate, preparation method therefor and use thereof are provided. The hydrocarbyl tetralin polyethersulfonate is of formula (I-0),
A hydrocarbyl tetralin polyethersulfonate, preparation method therefor and use thereof are provided. The hydrocarbyl tetralin polyethersulfonate is of formula (I-0),
The hydrocarbyl tetralin polyethersulfonate has a high surface and interface activity, can be used in an oil reservoir exploitation, especially in a high-temperature and high-salt oil reservoir exploitation, to improve crude oil recovery.
C08G 65/326 - Polymers modified by chemical after-treatment with inorganic compounds containing sulfur
C07C 213/04 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
C07C 303/32 - Preparation of esters or amides of sulfuric acidsPreparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
C09K 8/584 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
8.
ONE-POT PROCESS FOR CATALYTICALLY CONVERTING BIOMASS TO PREPARE 2,5-HEXANEDIONE
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Li, Xiangcheng
Wang, Zhendong
Han, Xiao
Feng, Xinqiang
Yuan, Zhiqing
Qiao, Jian
Liu, Chuang
Lan, Dawei
Abstract
A biphasic solvent system for converting biomass to prepare 2,5-hexanedione and a one-pot process for catalytically converting biomass to prepare 2,5-hexanedione with said biphasic solvent system are provided. The process includes the steps of contacting and reacting a biomass raw material with a hydrogenation catalyst using hydrogen gas as a hydrogen source in a heterogeneous system formed from an organic solvent, an inorganic salt and water to obtain 2,5-hexanedione. The hydrogenation catalyst includes a hydrogenation active component and a support. The support is selected from one or more of hydrophobic active carbon and graphene. The process can achieve efficient conversion of biomass without the participation of acid catalysts, and have a very high selectivity for the product 2,5-hexanedione.
C07C 29/17 - Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
9.
Method for Preparing P-Xylene by Biomass Conversion
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Li, Xiangcheng
Wang, Zhendong
Feng, Xinqiang
Han, Xiao
Xu, Rui
Liu, Chuang
Yuan, Zhiqing
Qiao, Jian
Abstract
A method for preparing paraxylene by biomass conversion includes the following steps: (1) contacting a biomass starting material with a hydrogenation catalyst for reaction in a multiphase system formed by an organic solvent, an inorganic salt and water, in the presence of hydrogen as a hydrogen source, and separating the resulting product to obtain an organic phase comprising 2,5-hexanedione; and (2) contacting the organic phase comprising 2,5-hexanedione obtained in the step (1) and ethylene with a molecular sieve catalyst for reaction to obtain paraxylene. The molecular sieve catalyst is at least one selected from the group consisting of aluminophosphate molecular sieves and SCM-14 molecular sieves.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zong, Hongyuan
Qi, Guozhen
Gao, Pan
Li, Xiaohong
Cao, Jing
Yu, Zhinan
Wang, Yanxue
Peng, Fei
Abstract
A fluidized bed reactor, a device for preparing low-carbon olefin, and a method for preparing low-carbon olefin are provided. The reaction zone of the fluidized bed reactor is sequentially, from bottom to top, provided with a raw material first distributor, a raw material second distributor and a catalyst distributor; the catalyst distributor is connected with the catalyst second feeding inlet; a dense-phase zone is formed between the raw material first distributor and the raw material second distributor, and the area where the catalyst distributor is located is formed as a catalyst distribution zone connected with the dense-phase zone; and at least one catalyst first feeding inlet(s) is provided on the side wall of reactor of the dense-phase zone. The distribution of the catalyst and the full contact of the catalyst with the raw materials can be achieved using the fluidized bed reactor and the device.
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
B01J 8/26 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
C07C 1/24 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by elimination of water
11.
LITHIUM BATTERY POSITIVE ELECTRODE MATERIAL PRECURSOR AND ITS PREPARATION METHOD AND APPLICATION
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zhang, Tongbao
Zhang, Yu
Wang, Biwei
Zhu, Ye
Chen, Fang
Gao, Huanxin
Abstract
A lithium battery positive electrode material precursor and its preparation method and application are provided. The positive electrode material precursor has the chemical formula NixCoyMzTp(OH)q and contains secondary particles in the form of microspheres formed by agglomeration of primary particles. The microspheres have a three-layer structure from the inside to the outside, namely an inner core layer, a middle layer and an outermost layer. The ratio of the intensity of the (110) and (102) crystal planes diffraction peaks expressed as peak height in the XRD diffraction pattern of the inner core layer of the microsphere is 1.0-8.0. The positive electrode material prepared by using the positive electrode material precursor has high discharge specific capacity and good cycle stability and can be used in high-performance lithium batteries.
H01M 4/02 - Electrodes composed of, or comprising, active material
H01M 4/505 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M 4/525 - Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Sun, Sai
Zhang, Siyu
Dong, Wenqian
Gao, Huanxin
Abstract
A graphene powder, its preparation method and application are provided. The graphene powder is a stack of graphene sheets. The graphene powder involves in its Raman spectrum a D peak and a G peak with peak heights of ID and IG respectively, where ID/IG is 0.10 or less. The graphene powder can be applied in conductive composite materials, anti-corrosion coatings, heat dissipation composite materials. In particular, when used in lithium-ion batteries, it can significantly reduce electrode internal resistance and improve battery stability at any current rates.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhao, Le
Wu, Lianghua
Abstract
A heat removal tube set, a method for increasing reaction load by using the heat removal tube set, and application of the same in the production of unsaturated nitrile are provided. The heat removal tube set has at least 10 heat removal tubes, and in at least one and at most 88% of the total of the heat removal tubes of the heat removal tube set, an angle formed between an extended line of the central axis of at least one connecting fitting and an extended line of the central axis of other connecting fitting is greater than 0° and less than 180°. By arranging such a heat removal tube set, the heat removal capability and fluidization efficiency of the fluidized bed reactor is improved, so that the demand for increasing the reaction load can be fully satisfied.
C07C 253/26 - Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
14.
HEAT REMOVAL TUBE SET, METHOD FOR CONTROLLING REACTION TEMPERATURE AND METHOD FOR PRODUCING UNSATURATED NITRILE
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhao, Le
Wu, Lianghua
Abstract
A heat removal tube set, a method for controlling reaction temperature using the heat removal tube set, and a method for producing an unsaturated nitrile are provided. The heat removal tube set has at least one first heat removal tube and at least one second heat removal tube. The number of all straight pipes a of the first heat removal tube is the same as that of all straight pipes b of the second heat removal tube. The ratio of the total circumference Lb of the outer contours of all of the straight pipes b of the second heat removal tube on the cross section to the total circumference La of the outer contours of all of the straight pipes a of the first heat removal tube on the cross section is 1.25-2. When the first heat removal tube and the second heat removal tube are switched coordinatively in a paired manner, a fine adjustment of the reaction temperature can be realized.
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
15.
HEAT REMOVAL TUBE SET AND APPLICATION THEREOF IN TEMPERATURE CONTROL OF FLUIDIZED BED REACTOR AND PRODUCTION OF UNSATURATED NITRILE
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhao, Le
Wu, Lianghua
Abstract
A heat removal tube set, and application of the same for controlling the temperature of a fluidized bed reactor and for producing an unsaturated nitrile are provided. The heat removal tube set has at least one first heat removal tube and at least one second heat removal tube, wherein the ratio of the total circumference Lb of the outer contours of all of the straight pipes b of the second heat removal tube on the cross section to the total circumference La of the outer contours of all of the straight pipes a of the first heat removal tube on the cross section is greater than 1 and less than 1.25. When the first heat removal tube and the second heat removal tube are switched coordinatively in a paired manner, the reaction temperature can be maintained substantially constant.
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
C07C 253/26 - Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Wang, Xiaofei
Lan, Dawei
Li, Jun
Wang, Zhendong
Xue, Haoliang
Zhang, Daoming
Zhou, Sifei
Abstract
The present invention relates to a composite separator, a preparation method therefor, and the use thereof, and further relates to a lithium-sulfur battery containing the composite separator. The composite separator comprises a polymer base film and a composite layer distributed on the surface of the polymer base film, the composite layer comprising a molecular sieve and a conductive carbon material, and the molecular sieve containing cobalt and, optionally, lithium. Compared with existing separators, the surface of the composite separator of the present invention has a composite layer containing a molecular sieve containing cobalt and, optionally, lithium, thereby greatly improving the rate capability and the cycling stability of a battery.
H01M 50/451 - Separators, membranes or diaphragms characterised by the material having a layered structure comprising layers of only organic material and layers containing inorganic material
17.
PROCESS FOR REFINING GLYCOLIDE AND GLYCOLIDE OBTAINED THEREFROM
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Xiong, Wentao
Wang, Rui
Zhou, Fen
Xiong, Jingen
Abstract
A process for refining glycolide includes a step of extracting impurities from a crude glycolide with solvent A, and then a step of recrystallizing with solvent B. Solvent A includes at least two solvents and the solvents are miscible each other. In the process, two types of polar solvents are used for the refining of crude glycolide. The process has a good extraction effect on acidic impurities such as glycolic acid oligomers. The solvents are easily fully removed during the solid-liquid separation and the drying process. Glycolide obtained using this process may have a low free acid content.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Liu, Chang
Wang, Yangdong
Xie, Zaiku
Liu, Su
Zhou, Haibo
Su, Junjie
Jiao, Wenqian
Zhang, Lin
Abstract
A catalyst contains a metal oxide, and a molecular sieve, in a crystal form, having a topological pore structure. The metal oxide is centrally distributed on the surface of the molecular sieve. Grains of the molecular sieve are exposed to at least three families of crystal planes. The family of crystal plane with the largest pore size in topology is occupied by the metal oxide by no more than 30%, preferably no more than 20%, or no more than 10%.
C01B 39/02 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereofDirect preparation thereofPreparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactantsAfter-treatment thereof
C01B 39/36 - Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
C01B 39/40 - Type ZSM-5 using at least one organic template directing agent
C07C 1/04 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of carbon from carbon monoxide with hydrogen
19.
Method and System for Processing Gasoline Fractions
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Jingqiu
Kong, Dejin
Li, Xuguang
Wang, Zongshuang
Li, Huaying
Tong, Weiyi
Abstract
A method for processing a gasoline fraction includes the steps of: a) reacting the gasoline fraction in an aromatization unit, and separating the resulting reaction product to obtain a C4− component, a C5 component, a C6-C7 component, a C8 component and a C9+ component; b) reacting the resulting C6-C7 component and the C9+ component in a cracking and aromatics conversion unit, and separating the resulting reaction product to obtain a C4− component, a C5 component, a C6-C7 component, a C8 component and a C9+ component; and c) recycling at least a part of at least one of the C6-C7 component and the C9+ component from step b) to the cracking and aromatics conversion unit of step b) for further reaction. The method can convert the gasoline fraction into C8 aromatic hydrocarbon(s) and produce light olefins and a high-quality light gasoline as byproducts.
C10G 63/04 - Treatment of naphtha by at least one reforming process and at least one other conversion process plural serial stages only including at least one cracking step
B01J 29/48 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
20.
SILICON-ALUMINUM MOLECULAR SIEVE CATALYST, AND PREPARATION AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Wang, Darui
Sun, Hongmin
Liu, Wei
Huan, Mingyao
Xue, Mingwei
He, Junlin
Abstract
An aluminosilicate molecular sieve catalyst, its preparation and application thereof are provided. The catalyst shows a desorption curve having three peaks P1, P2 and P3 in its NH3-TPD pattern. The desorption temperatures corresponding to the summits of the three peaks P1, P2 and P3 are respectively in a range of 180-220° C., 250-290° C. and 370-410° C. The catalyst shows a higher activity, selectivity and stability when used for producing alkylaromatic hydrocarbons by gas-phase alkylation of aromatics with olefins.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Jingqiu
Kong, Dejin
Li, Xuguang
Wang, Zongshuang
Li, Huaying
Abstract
A method for processing a hydrocarbon-containing mixture includes the steps of: I) separating the hydrocarbon-containing mixture into a light fraction and a heavy fraction; II) reacting the light fraction from step I) in an aromatization unit and separating the resulting reaction product into a C5− component and a C6+ component; III) reacting the heavy fraction from step I) and optionally the C6+ component from step II) in an aromatics conversion unit and separating the resulting reaction product into a C5− component, a C6-C7 component, a C8 component, and a C9+ component; and IV) optionally, steam cracking or catalytic cracking one or both of the C5− component from step II) and the C5− component from step III). The method can convert low-value hydrocarbon mixtures into C8 aromatic hydrocarbons and cracking raw materials, and improve the product value. A system for practicing this method is also provided.
C10G 55/06 - Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zheng, Junlin
Jiang, Xiangdong
Gao, Huanxin
Li, Cheng
Song, Qi
Kong, Dejin
Abstract
A chemical-type hydrocracking catalyst contains the following components: a) a β zeolite, b) a layered MWW-type zeolite with a lamellar thickness of 2-12 nm, c) a metal functional component, d) a binder, and optionally e) a metal function regulating component. The catalyst can be used in hydrocracking reactions of feedstock oils rich in polycyclic aromatics for producing light aromatics and light alkanes.
B01J 29/78 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J 35/10 - Solids characterised by their surface properties or porosity
B01J 37/02 - Impregnation, coating or precipitation
B01J 37/18 - Reducing with gases containing free hydrogen
C10G 47/20 - Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
23.
POLYACRYLAMIDE-BASED SYMMETRIC BRANCHED POLYMER SURFACTANT AND A PROCESS FOR PREPARING THE SAME AND USE THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Su, Zhiqing
Li, Yingcheng
Xia, Yanmin
Sun, Hui
Xu, Hui
Zhu, Yixing
Wang, Lan
Abstract
A polyacrylamide-based symmetric branched polymer surfactant and a process for preparing the same and use thereof are provided. The surfactant has an acrylamide structure unit, an anionic monomer structure unit, an optional non-ionic monomer structure unit, a branched structure unit, and an optional cationic monomer structure unit. The branched structure unit has at least one of structures represented by formula (1) or formula (2):
A polyacrylamide-based symmetric branched polymer surfactant and a process for preparing the same and use thereof are provided. The surfactant has an acrylamide structure unit, an anionic monomer structure unit, an optional non-ionic monomer structure unit, a branched structure unit, and an optional cationic monomer structure unit. The branched structure unit has at least one of structures represented by formula (1) or formula (2):
A polyacrylamide-based symmetric branched polymer surfactant and a process for preparing the same and use thereof are provided. The surfactant has an acrylamide structure unit, an anionic monomer structure unit, an optional non-ionic monomer structure unit, a branched structure unit, and an optional cationic monomer structure unit. The branched structure unit has at least one of structures represented by formula (1) or formula (2):
The polymer surfactant can realize both the high viscosity of the aqueous solution and the low oil water interfacial tension, and can be used as the oil displacement agent in the tertiary oil recovery.
C09K 8/588 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Dong, Jing
Liu, Su
Wang, Yangdong
Abstract
An integrated catalyst can be used in an olefin disproportionation reaction. The integrated catalyst contains a plurality of different integrated active phases. The relative positions among different active phases remain substantially unchanged during the olefin disproportionation reaction. The effective distance between respective bisecting planes of two adjacent different active phases is 0.5-5 mm, preferably 1-3 mm.
B01J 29/03 - Catalysts comprising molecular sieves not having base-exchange properties
B01J 29/78 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J 21/10 - MagnesiumOxides or hydroxides thereof
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Tu, Yunbao
Zong, Hongyuan
Liu, Zhongneng
Xu, Xiaoqing
Bai, Xue
Liu, Xu
Fu, Wei
Wang, Yanhong
Abstract
A catalyst for producing dibasic amine by hydrogenation of dibasic nitrile contains the following components or reaction product thereof: a) an active component, wherein the active component comprises Ni and/or an oxide thereof; b) an auxiliary, wherein the auxiliary comprises one or more of Mg, Cu, Co, Zn, Zr, Mo and/or oxides thereof; C) support, wherein the relative content of α-NiO in the catalyst is less than 2.0 a.u. A process for producing dibasic amine by hydrogenation of dibasic nitrile is also provided.
B01J 23/78 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with alkali- or alkaline earth metals or beryllium
C07C 209/48 - Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
26.
IRON-POTASSIUM-CERIUM-BASED COMPOSITE OXIDE CATALYST, AND PREPARATION AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Song, Lei
Miao, Changxi
Zhu, Min
Wei, Chunling
Xu, Yongfan
Abstract
An iron-potassium-cerium-based composite oxide catalyst, its preparation and application thereof are provided. The catalyst has metal elements Fe, K and Ce, as well as a metal element M that is at least one selected from the group consisting of Group IIA metal elements, Group VIB metal elements other than Cr and Group IVA metal elements. The catalyst has a total alkali content of 0.32-0.46 mmol/g, and a strong alkali content of 0.061-0.082 mmol/g. When used for dehydrogenation of alkyl aromatics, the catalyst shows high selectivity, high catalytic activity and high stability, provides less by-products, and has the characteristics of low material consumption and low power consumption, even at a low dehydrogenation temperature and an ultralow steam-to-oil ratio.
B01J 23/83 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with rare earths or actinides
B01J 23/78 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with alkali- or alkaline earth metals or beryllium
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zong, Hongyuan
Li, Xiaohong
Qi, Guozhen
Jin, Yongming
Gao, Pan
Wang, Yanxue
Abstract
A mixing device for mixing at least two particulate materials has a first riser used for loading first particles and a second riser surrounding and being coaxial with the riser and used for loading second particles. The upper part of the first riser extending beyond the top of the second riser. At least a part of the upper part of the first riser and at least a part of the upper part of the second riser being located inside a mixing zone container, such that the first and second particles are delivered to the inside of the mixing zone container by means of the first and second risers respectively and mixed.
B01J 8/08 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with moving particles
28.
ADSORBENT COMPOSITION, AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Jia, Yinjuan
Gao, Huanxin
Wu, Shuang
Wang, Can
Yang, Heqin
Jing, Mengmeng
Liu, Zhicheng
He, Limin
Abstract
An adsorbent composition contains molecular sieves, hydrated alumina and alumina. The adsorbent composition is particularly suitable for removing polar compounds from low-carbon olefins.
B01J 20/08 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group comprising aluminium oxide or hydroxideSolid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group comprising bauxite
B01J 20/28 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof characterised by their form or physical properties
B01J 20/30 - Processes for preparing, regenerating or reactivating
B01D 15/00 - Separating processes involving the treatment of liquids with solid sorbentsApparatus therefor
29.
DISPROPORTIONATION AND TRANSALKYLATION CATALYST, AND PREPARATION AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Jingqiu
Ding, Jian
Wu, Yanan
Kong, Dejin
Abstract
A disproportionation and transalkylation catalyst can be used in the catalytic conversion of alkyl aromatic hydrocarbons. The catalyst contains an acidic molecular sieve, a first metal component immobilized on the acidic molecular sieve and an oxide additive. The first metal contained in the first metal component is at least one selected from the group of Group VB metals, Group VIB metals and Group VIIB metals, the catalyst has a mediate strong acid content of 0.05-2.0 mmol/g of catalyst, and a ratio of the mediate strong acid content to the total acid content of 60-99%. When used in the catalytic conversion of alkyl aromatic hydrocarbons, the catalyst exhibits high reaction activity, low aromatic hydrocarbon loss rate.
B01J 29/26 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the mordenite type containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J 29/78 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Qiao, Jian
Yuan, Zhiqing
Wang, Zhendong
Teng, Jiawei
Tao, Weichuan
Fu, Wenhua
Liu, Songlin
Abstract
A SCM-34 molecular sieve, preparation method therefor and use thereof are provided. The SCM-34 molecular sieve contains aluminum, phosphorus, oxygen and optionally silicon. In the XRD diffraction data of the molecular sieve, a 2θ degree of the strongest peak within the range of 5-50° is 7.59±0.2. The SCM-34 molecular sieve has a new skeleton structure and can be used to prepare a metal-containing AFI type molecular sieve or an SAPO-17 molecular sieve.
C01B 39/54 - Phosphates, e.g. APO or SAPO compounds
C07C 1/04 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of carbon from carbon monoxide with hydrogen
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
C07C 1/247 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by splitting of cyclic ethers
31.
Conductive Composite Material of Graphene, Preparation Method Therefor, Use Thereof and Lithium-ion Battery
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Sun, Sai
Zhang, Siyu
Dong, Wenqian
Gao, Huanxin
Abstract
A conductive composite material of graphene contains graphene nano-sheets and conjugated copolymers. The conjugated copolymers has alkynyl groups and are in a linear structure and grafted to the graphene nano-sheets. The preparation of conductive composite material includes the steps of: pretreating the graphene nano-sheets with 4-bromobenzenediazonium tetrafluoroborate, and forming the conjugated copolymers in the presence of the pretreated graphene nano-sheets. The conductive composite material of graphene can be uniformly dispersed in an electrode slurry, reduce the internal resistance of an electrode, and improve the electrical conductivity of an electrode. At the same time, the flexible structure associated with the graphene nano-sheets can buffer the volume expansion of the silicon-containing negative materials during charge-discharge cycling. Such a composite material can be in a lithium-ion battery.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zong, Hongyuan
Li, Xiaohong
Qi, Guozhen
Wang, Hongtao
Yu, Zhinan
Zheng, Yijun
Wang, Li
Abstract
A device for mixing at least two granular materials has a first lifting tube used for loading first particles and a second lifting tube surrounding and coaxial to the first lifting tube and used for loading second particles. The upper part of said first lifting tube extends beyond the top of said second lifting tube, and at least part of the upper part of the first lifting tube and at least part of the upper part of the second lift tube are located inside a fast bed precipitator, allowing the first and second particles to be transported by means of the first and second lifting tubes to the interior of said fast bed precipitator and mixed.
C07C 1/22 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by reduction
B01J 8/26 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
33.
Alkylaniline polyether benzenesulfonate and process of producing same
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Yingcheng
Bao, Xinning
Zhang, Weidong
Sha, Ou
Wu, Xinyue
Jin, Jun
Abstract
A process for the conversion of methanol to olefins includes the steps of passing a feedstock comprising methanol to a fluidized bed reactor in contact with a catalyst to produce an olefin product, wherein the process at least partially deactivates the catalyst to form an at least partially deactivated catalyst; and passing spent catalyst from said at least partially deactivated catalyst to a regenerator for regeneration thereby forming regenerated catalyst and returning activated catalyst from said regenerated catalyst to said reactor via a regenerated catalyst line. An oxygen volume content in the gas-phase component at the outlet of the regenerated catalyst pipeline is controlled to be less than 0.1 percent, preferably less than 0.05% and more preferably less than 0.01% on the regenerated catalyst pipeline.
C09K 8/584 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
C08G 65/26 - Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
C08G 65/326 - Polymers modified by chemical after-treatment with inorganic compounds containing sulfur
C09K 8/588 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers
34.
SCM-33 MOLECULAR SIEVE, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
SHANGHAI RESEREARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Fu, Wenhua
Wang, Zhendong
Yuan, Zhiqing
Teng, Jiawei
Qiao, Jian
Tao, Weichuan
Abstract
A SCM-33 molecular sieve has a schematic chemical composition as shown in the formula “SiO2·1/x XO1.5·m MO0.5”, wherein X is a framework trivalent element, the Si/X molar ratio x is ≥5, M is a framework equilibrium cation, and the M/Si molar ratio is 0
C01B 39/48 - Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
C01B 39/06 - Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements
B01J 29/70 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups
B01J 29/72 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups containing iron group metals, noble metals or copper
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/34 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles
C07C 1/24 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by elimination of water
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zong, Hongyuan
Qi, Guozhen
Cao, Jing
Wang, Hongtao
Yu, Zhinan
Zheng, Yijun
Abstract
The present invention relates to a process of converting methanol to olefins, comprising: feeding a feedstock comprising methanol to a fluidized bed reactor to contact with catalysts to produce an olefin product, wherein the process at least partially deactivates the catalysts to format least partially deactivated catalysts; feeding spent catalysts from the at least partially deactivated catalysts to a regenerator for regeneration, thereby forming regenerated catalysts, and returning the activated catalysts from the regenerated catalysts to the reactor via a regenerated catalyst line; characterized in that on the regenerated catalyst line, the oxygen content by volume in the gas phase component at the outlet of the regenerated catalyst line is controlled to be less than 0.1%, preferably less than 0.05%, and more preferably less than 0.01%.
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
B01J 38/06 - Gas or vapour treatingTreating by using liquids vaporisable upon contacting spent catalyst using steam
B01J 8/26 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
37.
HYDROGENATION-ACID CATALYSIS BIFUNCTIONAL CATALYST, AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Lan, Dawei
Yang, Weimin
Wang, Zhendong
Li, Xiangcheng
Liu, Chuang
Li, Junjie
Wang, Wennian
Abstract
1-201-20 hydrocarbyl group. The catalyst has dual functions of hydrogenation and acid catalysis, and is suitable for a benzene hydroalkylation reaction and an alkane hydroisomerization reaction. Moreover, when the catalyst is used in benzene hydroalkylation to produce cyclohexylbenzene, the catalyst has the characteristics of a high benzene conversion rate, good product selectivity, and less byproduct cyclohexane.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Teng, Jiawei
Ren, Liping
Zhao, Guoliang
Shi, Jing
Xie, Zaiku
Abstract
2233 is 80-1500, and the micropore volume can account for 70%-92% of the total pore volume. When the catalyst of the present invention is used for preparing propylene and ethylene by means of catalytic cracking of olefins, the catalyst has the characteristics of low reaction hydrogen transfer index, high stability, high raw material olefin conversion rate, and high propylene and ethylene selectivity.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Zhao, Shengli
Qiao, Jian
Yuan, Zhiqing
Wang, Zhendong
Fu, Wenhua
Tao, Weichuan
Abstract
The present invention discloses an SCM-38 molecular sieve, a preparation method therefor, and the use thereof. The SCM-38 molecular sieve is a phosphorus-aluminum or silicon-phosphorus-aluminum molecular sieve, and the the XRD spectrum of the SCM-38 molecular sieve shows the following diffraction peak characteristics: X-ray diffraction peaks appear at 2θ being 7.20 ± 0.1, 10.81 ± 0.1, 11.60 ± 0.1, 14.32 ± 0.1, 21.39 ± 0.1, 21.83 ± 0.1, 27.31 ± 0.1, and 28.72 ± 0.1, wherein 2θ is the strongest peak at 7.20 ± 0.1. The SCM-38 molecular sieve of the present invention can be used in a catalyst.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Qi, Guozhen
Cao, Jing
Li, Xiaohong
Wang, Hongtao
Wang, Li
Wang, Yanxue
Abstract
The invention relates to a process of converting methanol in a fluidized bed reactor comprising feeding a methanol-containing feedstock into a fluidized bed reactor, contacting the feedstock with a catalyst, to produce a product comprising ethylene and propylene under effective conditions; the fluidized bed reactor comprises a diluent-phase zone and a dense-phase zone, wherein the diluent-phase temperature difference between any regions of the diluent-phase zone having a methanol concentration of more than 0.1 wt % (preferably more than 0.01 wt %) in the fluidized bed reactor is controlled to be less than 20° C., and the dense-phase temperature difference between any regions in the dense-phase zone having a methanol concentration of more than 0.1 wt % (preferably more than 0.01 wt %) in the fluidized bed reactor is controlled to be less than 10° C.
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Wei
Zhou, Yaxin
Wu, Libin
Wang, Yuemei
Hou, Min
Abstract
Disclosed is an olefin conversion catalyst, a preparation method therefor and an application thereof. The catalyst comprises the following components, in parts by mass: a) 50-90 parts of a molecular sieve having a structure that has twelve-membered rings or more; b) in terms of oxides, 0.1-10 parts of an added component selected from among group IA metal elements, group IIA metal elements, or a combination thereof; c) in terms of oxides, 0.1-10 parts of a modified component selected from among silicon, germanium, bismuth, tin, boron, gallium, or a combination thereof; and d) 10-49 parts of a carrier component. When the catalyst is used for the conversion of a small amount of olefins in aromatic-rich distillate oil, same has the characteristics of high activity, stability, a long service life and effective utilization of olefins.
B01J 29/70 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of types characterised by their specific structure not provided for in groups
B01J 29/08 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the faujasite type, e.g. type X or Y
B01J 29/18 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the mordenite type
C10G 25/03 - Refining of hydrocarbon oils, in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
42.
Process for producing lower olefins from oxygenates
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Qi, Guozhen
Cao, Jing
Li, Xiaohong
Wang, Hongtao
Jin, Yongming
Gao, Pan
Abstract
A process for producing lower olefins from oxygenates includes the steps of contacting a feedstock comprising oxygenates with molecular sieve catalyst in fluidized bed reaction zone under effective conditions, to produce product including ethylene and/or propylene; the effective conditions include that in the fluidized bed reaction zone, the weights of catalysts having various carbon deposition amounts are controlled, calculated as the weight of the molecular sieve in the catalysts, to have the following proportions based on the total weight of the catalysts in the fluidized bed reaction zone: the proportion of the weight of the catalyst having a coke deposition amount of less than 3 wt % is 1-20 wt %; the catalyst having a coke deposition amount of from 3 wt % to less than 5 wt % represents 10 to 70 wt %; and the catalyst having a coke deposition amount from 5 wt % to 10 wt % represents 10 to 88 wt %.
C07C 1/22 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by reduction
B01D 45/16 - Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by the winding course of the gas stream
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
43.
SILICON-ALUMINUM MOLECULAR SIEVE SCM-36, MANUFACTURING METHOD THEREFOR AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Wang, Zhendong
Ma, Duozheng
Liu, Songlin
Liu, Chuang
Li, Xiangcheng
Yuan, Zhiqing
Abstract
A silicon-aluminum molecular sieve SCM-36, a manufacturing method therefor and an application thereof. The silicon-to-aluminum ratio n of the molecular sieve is greater than or equal to 5, and the molecular sieve has a unique XRD diffraction spectrogram. The SCM-36 molecular sieve is a novel molecular sieve, and can be taken as an adsorbent, a catalyst or a catalyst carrier.
C01B 39/48 - Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zeng, Tieqiang
Miao, Changxi
Song, Lei
Wei, Chunling
Zhu, Min
Zhang, Zhengpai
Xu, Yongfan
Zha, Kaiwen
Abstract
23223222. The catalyst of the present invention is used in a reaction for preparing styrene by means of dehydrogenating ethylbenzene at a low water ratio, and has high activity and stability.
B01J 23/78 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with alkali- or alkaline earth metals or beryllium
B01J 23/83 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with rare earths or actinides
B01J 37/00 - Processes, in general, for preparing catalystsProcesses, in general, for activation of catalysts
C07C 5/32 - Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Li, Xiaohong
Qi, Guozhen
Yu, Zhinan
Peng, Fei
Wang, Hongtao
Zheng, Yijun
Abstract
The present invention provides a short-contact reaction system in the preparation of ethylene and propylene from methanol. The system comprises: a methanol-to-olefin short-contact reactor, a riser reactor, a double-dense bed, and a stripper. The methanol-to-olefin short-contact reactor is used to convert methanol to olefin-rich products. The methanol-to-olefin short-contact reactor comprises a methanol feed pipeline, a filter pipe wall and a product gas channel coaxially distributed from the inside to the outside, a catalyst distributor provided at the top part of the reactor, and a material seal pipe provided at the bottom part of the reactor. The material seal pipe is located inside of the stripper. The diameter of the top part of the product gas channel is larger than the diameter of the bottom part of the product gas channel. In the present invention, methanol is in cross-flow contact with downward coking catalyst II in the methanol-to-olefin short-contact reactor, and the cross-flow contact reaction between the methanol and the catalyst under the condition of a very short contact time may obtain a product having high selectivity of ethylene and propylene. The present invention better solves the problem of low selectivity of ethylene and propylene, and may be used in MTO industrial production.
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
46.
SEPARATOR FOR LITHIUM-SULFUR BATTERY, METHOD FOR PREPARING SAME AND LITHIUM-SULFUR BATTERY CONTAINING SAME
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Li, Jun
Wang, Zhendong
Wang, Xiaofei
Lan, Dawei
Zhang, Daoming
Xue, Haoliang
Zhou, Sifei
Abstract
Disclosed are a separator for a lithium-sulfur battery, a method for preparing same and a lithium-sulfur battery containing same. The separator comprises: a polymer matrix film; and a composite layer distributed on a side surface of the polymer matrix film, wherein the composite layer comprises an SCM molecular sieve and a conductive carbon material, the SCM molecular sieve is selected from SCM-14 and SCM-15, and preferably, the SCM molecular sieve further contains cobalt. The separator of the present invention can effectively inhibit the shuttling of polysulfides in the lithium-sulfur battery, thereby reducing side reactions inside the battery, decreasing the self-discharge rate of the lithium-sulfur battery, and improving the cycle performance, rate capability and storage life of the battery.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Xiaohong
Qi, Guozhen
Yu, Zhinan
Peng, Fei
Wang, Hongtao
Zheng, Yijun
Abstract
The present invention provides a short-contact reaction system in the preparation of ethylene and propylene from methanol. The system comprises: a methanol-to-olefin short-contact reactor, a riser reactor, a double-dense bed, and a stripper. The methanol-to-olefin short-contact reactor is used to convert methanol to olefin-rich products. The methanol-to-olefin short-contact reactor comprises a methanol feed pipeline, a filter pipe wall and a product gas channel coaxially distributed from the inside to the outside, a catalyst distributor provided at the top part of the reactor, and a material seal pipe provided at the bottom part of the reactor. The material seal pipe is located inside of the stripper. The diameter of the top part of the product gas channel is larger than the diameter of the bottom part of the product gas channel. In the present invention, methanol is in cross-flow contact with downward coking catalyst II in the methanol-to-olefin short-contact reactor, and the cross-flow contact reaction between the methanol and the catalyst under the condition of a very short contact time may obtain a product having high selectivity of ethylene and propylene. The present invention better solves the problem of low selectivity of ethylene and propylene, and may be used in MTO industrial production.
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
48.
HYDROCARBYL TETRALIN POLYETHERSULFONATE, PREPARATION METHOD THEREFOR AND USE THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Bao, Xinning
Li, Yingcheng
Zhang, Weidong
Jin, Jun
Meng, Yong
Zhang, Li
Abstract
Provided in the present invention are a hydrocarbyl tetralin polyethersulfonate, a preparation method therefor and the use thereof. The hydrocarbyl tetralin polyethersulfonate is represented by formula (I-0). The hydrocarbyl tetralin polyethersulfonate of the present invention has a high surface/interfacial activity, and may be used in reservoir production, especially in the production of high temperature high salt reservoirs, with an improved crude oil recovery rate.
C08G 65/334 - Polymers modified by chemical after-treatment with organic compounds containing sulfur
C09K 8/584 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
C09K 23/42 - Ethers, e.g. polyglycol ethers of alcohols or phenols
49.
HYDROCARBYL TETRALIN POLYETHERSULFONATE, PREPARATION METHOD THEREFOR AND USE THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Bao, Xinning
Li, Yingcheng
Zhang, Weidong
Jin, Jun
Meng, Yong
Zhang, Li
Abstract
Provided in the present invention are a hydrocarbyl tetralin polyethersulfonate, a preparation method therefor and the use thereof. The hydrocarbyl tetralin polyethersulfonate is represented by formula (I-0). The hydrocarbyl tetralin polyethersulfonate of the present invention has a high surface/interfacial activity, and may be used in reservoir production, especially in the production of high temperature high salt reservoirs, with an improved crude oil recovery rate.
C09K 8/584 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
C07C 213/04 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
C07C 303/32 - Preparation of esters or amides of sulfuric acidsPreparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
50.
Gas Distribution Plate, Fluidizing Device and Reaction Method
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhao, Le
Wu, Lianghua
Abstract
Disclosed is a gas distribution plate, comprising a metal plate, central openings and peripheral openings, wherein a ratio D1/D1′ of the aperture diameter D1 (expressed in a unit of mm) of the central opening to the aperture diameter D1′ (expressed in a unit of mm) of the peripheral opening satisfies the relation of 1.10≥D1/D1′>1.00. A fluidizing device comprising the gas distribution plate and application of the fluidizing device in an oxidation or ammoxidation reaction process are also disclosed. The gas distribution plate has an advantage of uniform gas distribution.
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhao, Le
Wu, Lianghua
Abstract
Disclosed is a fluidized bed reactor and a heat removal water pipe and application thereof in acrylonitrile production. The fluidized bed reactor comprises at least a reaction cooling section and a vertical inner component provided in the reaction cooling section. Where, at a cross section transverse and perpendicular to a central axis of the fluidized bed reactor, an area of the cross section of the reaction cooling section is designated as S1 (expressed in a unit of m2) and an outer contour circumference of the cross section of the vertical inner component is designated as L1 (expressed in a unit of m), L1/S1=2.0-4.3 m−1. The fluidized bed reactor can promote the breaking of bubbles as early as possible and effectively limit the growth of the bubbles.
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
52.
GAS-LIQUID BUBBLING BED REACTOR, REACTION SYSTEM, AND PROCESS FOR SYNTHESIZING CARBONATE ESTER
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Liu, Yinchuan
Yang, Weisheng
Li, Na
Sun, Dizong
He, Wenjun
Abstract
The present invention discloses a gas-liquid bubbling bed reactor, comprising a liquid distributor, a gas distributor located below the liquid distributor, a catalyst bed layer and a catalyst support plate, and an optional interception screen, wherein the top of the reactor is provided with a gas outlet, the reactor is provided with a feed inlet connected to the liquid distributor, a gas inlet connected to the gas distributor, the bottom is provided with a discharge outlet. The present invention further provides a reaction system, which comprises the gas-liquid bubbling bed reactor as the main reactor and a sub-reactor. Through the system and the process of the present invention, the problems of the low conversion rate, the gas binding of the circulating pump, the unstable operation, the low yield of electronic-grade products, and the like in the carbonate synthesis process are solved purposedly targetedly, and the present invention can be applied to related industrial production.
B01J 8/08 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with moving particles
B01J 8/10 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles
B01J 8/02 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with stationary particles, e.g. in fixed beds
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zong, Hongyuan
Qi, Guozhen
Gao, Pan
Li, Xiaohong
Cao, Jing
Yu, Zhinan
Wang, Yanxue
Peng, Fei
Abstract
A fluidized bed reactor, and a device and method for preparing low-carbon olefin. A reaction area of the fluidized bed reactor is sequentially, from bottom to top, provided with a raw material first distributor (8), a raw material second distributor (11), and a catalyst distributor (16). The catalyst distributor (16) is in communication with a catalyst second feed inlet (27). A dense-phase area (28) is formed between the raw material first distributor (8) and the raw material second distributor (11). The area where the catalyst distributor (16) is located is formed as a catalyst distribution area (29) in communication with the dense-phase area (28). At least one catalyst first feed inlet (24) is provided on the side wall of a reactor of the dense-phase area (28).
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Yingcheng
Zhang, Weidong
Jin, Jun
Shen, Zhiqin
Bao, Xinning
Sha, Ou
Abstract
A heteroatom-containing alkoxy polyether based anionic-nonionic surfactant has the following molecular formula (I):
A heteroatom-containing alkoxy polyether based anionic-nonionic surfactant has the following molecular formula (I):
R1—O-(Poly)n-X—Ya−.a/bMb+ (I).
A heteroatom-containing alkoxy polyether based anionic-nonionic surfactant has the following molecular formula (I):
R1—O-(Poly)n-X—Ya−.a/bMb+ (I).
In formula (I), R1 is any one of C1-C50 aliphatic group and aromatic group; each occurrence of group Poly, equal to or different from each other, is independently selected from the group represented by formula (Ru—O)m; n is a number from greater than 0 to 300; for each type of group (Ru—O), m is independently a number from greater than 0 to 100; X is any one of alkylene, alkenylene and arylene containing 1-10 carbon atoms; Y is an anionic group; and M is a cation or a cationic group.
C09K 8/584 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
55.
Negative Electrode Material, Preparation Method Therefor, and Application Thereof, and Lithium Ion Battery Comprising Same
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Sun, Sai
Zhang, Siyu
Gao, Huanxin
Abstract
A silicon-based negative electrode material, a preparation method therefor, and an application thereof in a lithium ion battery are provided. A lithium ion battery contains the silicon-based negative electrode material. The negative electrode material contains a silicon-containing material and a phosphorus-containing coating layer at the surface of the silicon-containing material. The phosphorus-containing coating layer contains a polymer that has polycyclic aromatic hydrocarbon structural segments. The negative electrode material exhibits improved initial coulombic efficiency, reversible charging specific capacity, cycle charging capacity retention and conductivity. When used in the lithium ion battery, the negative electrode material may improve the energy density of the battery.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICALTECHNOLOGY, SINOPEC (China)
Inventor
Zhang, Tongbao
Wang, Biwei
Zhu, Ye
Gao, Huanxin
Abstract
A lithium battery positive active material precursor, a preparation method therefor and the use thereof are provided. The precursor has a chemical formula of NixCoyMz(OH)2, wherein M is at least one metal selected from the group consisting of Fe, Cr, Cu, Ti, Mg, W, Mo, Nb, Zn, Sn, Zr, Ga, Mn and Al, 0.3≤x≤1, 0
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Zhang, Tongbao
Zhang, Yu
Wang, Biwei
Zhu, Ye
Chen, Fang
Gao, Huanxin
Abstract
A lithium battery positive electrode material precursor, a preparation method therefor and the application thereof. The positive electrode material precursor has the chemical formula NixCoyMzTp(OH)q. The positive electrode material precursor contains secondary particles in the form of a microsphere that is formed by the agglomeration of primary particles. The microsphere has a structure of three layers from inside to outside, i.e. an inner core layer, an intermediate layer and an outermost layer, wherein the ratio of intensities of crystal plane diffraction peaks (110) and (102), which are represented by peak heights, in an XRD diffraction pattern of the inner core layer of the microsphere is 1.0-8.0. A positive electrode material prepared by using the positive electrode material precursor has a high specific discharge capacity and good cycle stability, and can be used in a high-performance lithium battery.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zhang, Tongbao
Zhang, Yu
Wang, Biwei
Zhu, Ye
Chen, Fang
Gao, Huanxin
Abstract
xyzpqq. The positive electrode material precursor contains secondary particles in the form of a microsphere that is formed by the agglomeration of primary particles. The microsphere has a structure of three layers from inside to outside, i.e. an inner core layer, an intermediate layer and an outermost layer, wherein the ratio of intensities of crystal plane diffraction peaks (110) and (102), which are represented by peak heights, in an XRD diffraction pattern of the inner core layer of the microsphere is 1.0-8.0. A positive electrode material prepared by using the positive electrode material precursor has a high specific discharge capacity and good cycle stability, and can be used in a high-performance lithium battery.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Li, Xiangcheng
Wang, Zhendong
Han, Xiao
Feng, Xinqiang
Yuan, Zhiqing
Qiao, Jian
Liu, Chuang
Lan, Dawei
Abstract
Disclosed in the present invention are a biphasic solvent system for converting a biomass to prepare 2, 5-hexanedione and a method for using same to prepare 2, 5-hexanedione by catalyzing and converting a biomass by one-pot synthesis. The method comprises: in a multiphase system formed of an organic solvent, an inorganic salt, and water, using hydrogen as a hydrogen source, and making a biomass feedstock in contact with a hydrogenation catalyst for reaction to obtain 2, 5-hexanedione. The hydrogenation catalyst comprises a hydrogenation active component and a carrier, wherein the carrier is selected from one or more of hydrophobic activated carbon and graphene. According to the method of the present invention, high-efficiency conversion of the biomass can be achieved in the absence of an acid catalyst, and the selectivity of the product 2, 5-hexanedione is very high.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Li, Xiangcheng
Wang, Zhendong
Feng, Xinqiang
Han, Xiao
Xu, Rui
Liu, Chuang
Yuan, Zhiqing
Qiao, Jian
Abstract
Disclosed in the present invention is a method for preparing p-xylene (pX) by biomass conversion. The method comprises: (1) in a multi-phase system formed by an organic solvent, an inorganic salt, and water, by using hydrogen gas as a hydrogen source, making a biomass raw material contact a hydrogenation catalyst for reaction, and separating the obtained product to obtain an organic phase containing 2,5-hexanedione; (2) making the organic phase containing 2,5-hexanedione obtained in step (1) and ethylene contact a molecular sieve catalyst for reaction to obtain pX, wherein the molecular sieve catalyst is selected from at least one of an aluminophosphate molecular sieve and an SCM-14 molecular sieve. The method is simple to operate, has the advantages of high product selectivity, good catalyst stability, easy product separation, less reaction steps, and short time, and achieves green and efficient conversion of biomass to pX.
C07C 2/86 - Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Meng, Yong
Li, Yingcheng
Zhang, Weidong
Sha, Ou
Bao, Xinning
Jin, Jun
Wu, Xinyue
Abstract
The present invention relates to a biological and chemical composite blockage removing agent and preparation process and use thereof, and mainly solves the problems that the existing blockage removing agents have poor blockage removal effect on organic blockages, cause damage to formations and oil-wells, produce serious environmental pollution, and corrode the equipment, pipelines, and the like. The problems can be well solved by using a technical solution of a biological and chemical composite blockage removing agent, which contains the following components in parts by mass: A. 10-50 parts of a biosurfactant; B. 5-20 parts of a chemical surfactant; wherein the chemical surfactant is an anionic-nonionic surfactant, and said technical solution can be used in the industrial production for removing the blockage in the oilfield, and reducing the injection pressure and increasing the injection.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yu, Fengping
He, Wenjun
Jin, Ming
Abstract
The present invention provides a catalyst for an addition reaction of alkylene oxide, the catalyst comprises a nanocomposite ion-exchange resin having a structural formula of P-Im+-M−, wherein P is a nanocomposite resin matrix, Im+ is a cation derived from 5-6 membered heterocycle containing at least one nitrogen atom such as imidazolium cation, pyrazolium cation, pyrrolidinium cation, piperidinium cation, piperazinium cation, pyrimidinium cation, pyrazinium cation, pyridazinium cation, triazinium cation, and M− is an anion. The catalyst of the present invention can be used in the addition reaction of alkylene oxide and carbon dioxide. The catalyst has high wear resistance, high swelling resistance, and high activity. The products after the reaction are easy to separate, and the catalyst can be used continuously many times.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Sun, Sai
Zhang, Siyu
Dong, Wenqian
Gao, Huanxin
Abstract
The present invention relates to a graphene material. Disclosed are a graphene powder, and a preparation method therefor and the application thereof. The graphene powder is a deposit of graphene sheets. There is a D-peak and a G-peak in the Raman spectrum of the graphene powder, wherein the peak heights thereof are respectively ID and IG, and ID/IG is less than 0.10. The graphene powder of the present invention can be applied to a conductive composite material, an anti-corrosion coating and a heat dissipation composite material, and can significantly reduce the internal resistance of an electrode and improve the rate stability of a battery when applied to a lithium ion battery in particular.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Sun, Sai
Zhang, Siyu
Dong, Wenqian
Gao, Huanxin
Abstract
DGDGG is less than 0.10. The graphene powder of the present invention can be applied to a conductive composite material, an anti-corrosion coating and a heat dissipation composite material, and can significantly reduce the internal resistance of an electrode and improve the rate stability of a battery when applied to a lithium ion battery in particular.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Liu, Zhongneng
Zhao, Duo
Lv, Yuhao
Ma, Wendi
Gu, Guoyao
Abstract
Described are a catalyst for producing isopropylbenzene and the production method and use thereof. The catalyst includes a support and an active component supported on the support, wherein the support comprises a support substrate and a modifying auxiliary component supported on the support substrate, wherein the active component includes metal palladium and/or an oxide thereof, and the modifying auxiliary component is phosphorus and/or an oxide thereof; optionally, the active component further includes metal copper and/or an oxide thereof; the catalyst further includes a sulfur-containing compound.
B01J 23/89 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with noble metals
B01J 31/02 - Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
B01J 31/28 - Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups of the platinum group metals, iron group metals or copper
C07C 1/22 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms by reduction
66.
HEAT REMOVAL PIPE GROUP, METHOD FOR CONTROLLING REACTION TEMPERATURE, AND METHOD FOR FABRICATING UNSATURATED NITRILES
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhao, Le
Wu, Lianghua
Abstract
A heat removal pipe group, a method for controlling the reaction temperature by using the heat removal pipe group, and a method for fabricating unsaturated nitriles. The heat removal pipe group comprises at least one first heat removal pipe (10) and at least one second heat removal pipe (20). The number of all straight pipes (5)a of the first heat removal pipe (10) is the same as the number of all straight pipes (5)b of the second heat removal pipe (20). Furthermore, the ratio of the total outer contour perimeter Lb on the cross sections of all the straight pipes (5)b of the second heat removal pipe (20) to the total outer contour perimeter La on the cross sections of all the straight pipes (5)a of the first heat removal pipe (10) is 1.25-2. The first heat removal pipe (10) and the second heat removal pipe (20) are linked and switched in a paired manner for the fine adjustment of the reaction temperature.
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
C07C 253/26 - Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
67.
COOLING COIL SET, METHOD FOR INCREASING REACTION LOAD, AND METHOD FOR PREPARING UNSATURATED NITRILE
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhao, Le
Wu, Lianghua
Abstract
A cooling coil set, a method for increasing reaction load using the cooling coil set, and an application thereof in preparation of an unsaturated nitrile. The cooling coil set comprises ten cooling coils, and among at least one cooling coil which reaches at most 88% of the total number of cooling coils in the cooling coil set, an included angle between the central axis extension line of at least one connecting pipe and the central axis extension line of another connecting pipe is greater than 0° and less than 180°.
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
C07C 253/18 - Preparation of carboxylic acid nitriles by reaction of ammonia or amines with compounds containing carbon-to-carbon multiple bonds other than in six-membered aromatic rings
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhao, Le
Wu, Lianghua
Abstract
A heat removal pipe group, a fluidized-bed reactor (1) provided with the heat removal pipe group, a method for using the heat removal pipe group to control the temperature of the fluidized-bed reactor (1), and a method for fabricating unsaturated nitriles. The heat removal pipe group comprises: at least one first heat removal pipe (10), which comprise n1 straight pipes a and n1-1 connecting pipe fittings for fluid communication between two adjacent straight pipes a; and at least one second heat removal pipe (20), which comprises n2 straight pipes b and n2-1 connecting pipe fittings for fluid communication between two adjacent straight pipes b. In a transverse plane along the direction perpendicular to the central axis of the fluidized-bed reactor (1), more than 50% of the straight pipes a in the first heat removal pipe (10) are within the range of a central part of the cross section, while less than 50% of the straight pipes b in the second heat removal pipe (20) is within the range of the central part of the cross section. Furthermore, the ratio of the total outer contour perimeter Lb on the cross sections of all the straight pipes b of the second heat removal pipe (20) and the total outer contour perimeter La on the cross sections of all the straight pipes a of the first heat removal pipe (10) is greater than 1 and less than 1.25.
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
C07C 253/26 - Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zheng, Junlin
Jiang, Xiangdong
Song, Qi
Kong, Dejin
Abstract
Provided are a full conversion process and a device thereof for producing light aromatic hydrocarbon from LCO. The process includes the steps of: subjecting LCO stream to hydrofining and impurity separation, then performing selective conversion reaction, and separating the mixed aromatic hydrocarbons generated to sequentially separate out light aromatic hydrocarbons such as benzene-toluene and xylene, C9A aromatic hydrocarbons, C10A aromatic hydrocarbons and a bottom heavy tail oil; feeding the bottom heavy tail oil into a post-saturation selective reactor, subjecting to high-selectivity hydrogenation saturation under the conditions of low temperature and low pressure to provide a product having one benzene ring, and then returning the product back to the selective conversion reactor. The full-cut conversion of producing light aromatic hydrocarbon from LCO is achieved, resulting in the technical effects of high yields of monocyclic aromatic hydrocarbons such as benzene-toluene, xylene, C9A aromatic hydrocarbons, C10A aromatic hydrocarbons and the like.
C10G 67/14 - Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including at least two different refining steps in the absence of hydrogen
C10G 45/54 - Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
C10G 65/12 - Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
70.
Silicon-and germanium-based SCM-25 molecular sieve, preparation process and use thereof
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Yang, Weimin
Fu, Wenhua
Yuan, Zhiqing
Wang, Zhendong
Teng, Jiawei
Tao, Weichuan
Zhao, Shengli
Abstract
30. The molecular sieve has a unique X-ray diffraction pattern. It can be used in adsorptive separation, ion exchange, and catalytic conversion of organic compounds.
C01B 39/48 - Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
71.
SILICON-ALUMINUM MOLECULAR SIEVE CATALYST, AND PREPARATION AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Yang, Weimin
Wang, Darui
Sun, Hongmin
Liu, Wei
Huan, Mingyao
Xue, Mingwei
He, Junlin
Abstract
Disclosed are a silicon-aluminum molecular sieve catalyst, and the preparation and application thereof. The desorption curve of NH3-TPD spectrum of the catalyst shows three peaks P1, P2 and P3, and the peak positions of the three peaks P1, P2 and P3 respectively correspond to desorption temperatures in the ranges of 180-220?, 250-290? and 370-410?. The catalyst has high activity, selectivity and stability when used in the gas phase alkylation reaction of an aromatic hydrocarbon and an olefin to prepare an alkyl aromatic hydrocarbon.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Xiong, Wentao
Wang, Rui
Zhou, Fen
Xiong, Jingen
Abstract
The present invention provides a method for refining glycolide and glycolide obtained using same. The method comprises the steps of using a solvent A to extract impurities from crude glycolide and then using a solvent B to perform recrystallization, wherein the solvent A comprises at least two solvents and the solvents are mutually soluble. In the method of the present invention, two types of polar solvents are used for the refining of crude glycolide, having a good extraction effect on acidic impurities such as glycolic acid oligomers, and the solvents being easily fully removed during solid-liquid separation and drying, thereby solving the problem of solvent residues in the refined product and achieving the technical effect of low free acid content in the product. The technical solution of the present invention has the technical advantages of easy solvent recovery and low free acid content in the product.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Su, Zhiqing
Li, Yingcheng
Xia, Yanmin
Sun, Hui
Xu, Hui
Zhu, Yixing
Wang, Lan
Abstract
Disclosed are a polyacrylamide-based symmetrically branched polymer type surfactant, a preparation method therefor and an application thereof. The surfactant comprises an acrylamide structural unit, an anionic monomeric structural unit, an optional non-ionic monomeric structural unit, a branched structural unit and an optional cationic monomeric structural unit; and the branched structural unit has at least one among the structures represented by formula (1) or formula (2). The polymer type surfactant may simultaneously achieve high viscosity of an aqueous solution and low oil-water interfacial tension, and may be used as an oil displacing agent in tertiary oil recovery.
C08G 65/326 - Polymers modified by chemical after-treatment with inorganic compounds containing sulfur
C09K 8/588 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Wang, Darui
Sun, Hongmin
Liu, Wei
Huan, Mingyao
Xue, Mingwei
He, Junlin
Abstract
33-TPD spectrum of the catalyst shows three peaks P1, P2 and P3, and the peak positions of the three peaks P1, P2 and P3 respectively correspond to desorption temperatures in the ranges of 180-220℃, 250-290℃ and 370-410℃. The catalyst has high activity, selectivity and stability when used in the gas phase alkylation reaction of an aromatic hydrocarbon and an olefin to prepare an alkyl aromatic hydrocarbon.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Xiong, Wentao
Wang, Rui
Zhou, Fen
Xiong, Jingen
Abstract
The present invention provides a method for refining glycolide and glycolide obtained using same. The method comprises the steps of using a solvent A to extract impurities from crude glycolide and then using a solvent B to perform recrystallization, wherein the solvent A comprises at least two solvents and the solvents are mutually soluble. In the method of the present invention, two types of polar solvents are used for the refining of crude glycolide, having a good extraction effect on acidic impurities such as glycolic acid oligomers, and the solvents being easily fully removed during solid-liquid separation and drying, thereby solving the problem of solvent residues in the refined product and achieving the technical effect of low free acid content in the product. The technical solution of the present invention has the technical advantages of easy solvent recovery and low free acid content in the product.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Tu, Yunbao
Zong, Hongyuan
Liu, Zhongneng
Xu, Xiaoqing
Bai, Xue
Liu, Xu
Fu, Wei
Wang, Yanhong
Abstract
Disclosed in the present invention is a catalyst for preparing diamine by hydrogenation of dinitrile, comprising the following components or reaction products thereof: a) active components, which comprise Ni and/or oxides thereof; b) additives, which comprise one or more of Mg, Cu, Co, Zn, Zr, Mo and/or oxides thereof; and c) a carrier, wherein the relative content of α-NiO in the catalyst is lower than 2.0a.u.. Also disclosed in the present invention is a method for preparing diamine by hydrogenation of dinitrile. The catalyst and method in the present invention greatly reduce the generation of by-products of excessive hydrogenation, and improves the overall selectivity of a target product.
B01J 23/78 - Catalysts comprising metals or metal oxides or hydroxides, not provided for in group of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups with alkali- or alkaline earth metals or beryllium
C07C 209/48 - Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
C07C 211/27 - Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring having amino groups linked to the six-membered aromatic ring by saturated carbon chains
77.
CHEMICAL HYDROCRACKING CATALYST, PREPARATION METHOD THEREFOR, AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Zheng, Junlin
Jiang, Xiangdong
Gao, Huanxin
Li, Cheng
Song, Qi
Kong, Dejin
Abstract
A chemical hydrocracking catalyst, a preparation method therefor, and an application thereof. The chemical hydrocracking catalyst comprises the following components: a) ß zeolite; b) layered MWW zeolite, having a flake thickness range of 2-12 nm; c) a metal functional component; d) a binding agent, and optionally e) a metal function regulating component. The catalyst can be used in the hydrocracking reaction of feedstock oil rich in polycyclic aromatic hydrocarbons to produce light aromatic hydrocarbons and light cracking materials, and has the features of a high raw material single-pass conversion rate, high chemical material yield, and good catalyst stability.
C10G 45/12 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
C10G 47/20 - Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
78.
CHEMICAL HYDROCRACKING CATALYST, PREPARATION METHOD THEREFOR, AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zheng, Junlin
Jiang, Xiangdong
Gao, Huanxin
Li, Cheng
Song, Qi
Kong, Dejin
Abstract
A chemical hydrocracking catalyst, a preparation method therefor, and an application thereof. The chemical hydrocracking catalyst comprises the following components: a) β zeolite; b) layered MWW zeolite, having a flake thickness range of 2-12 nm; c) a metal functional component; d) a binding agent, and optionally e) a metal function regulating component. The catalyst can be used in the hydrocracking reaction of feedstock oil rich in polycyclic aromatic hydrocarbons to produce light aromatic hydrocarbons and light cracking materials, and has the features of a high raw material single-pass conversion rate, high chemical material yield, and good catalyst stability.
C10G 47/20 - Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
C10G 45/12 - Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbonsHydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
79.
CATALYST INCLUDING MOLECULAR SIEVE HAVING TOPOLOGICAL PORE STRUCTURE, PREPARATION METHOD THEREFOR AND USE THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Liu, Chang
Wang, Yangdong
Xie, Zaiku
Liu, Su
Zhou, Haibo
Su, Junjie
Jiao, Wenqian
Zhang, Lin
Abstract
Disclosed are a catalyst including a molecular sieve having a topological pore structure. The catalyst includes a metal oxide, and a molecular sieve, in a crystal form, having a topological pore structure, and the metal oxide is centrally distributed on the surface of the molecular sieve, wherein grains of the molecular sieve are exposed to at least three families of crystal planes, and the family of crystal plane with the largest pore size in topology is occupied by the metal oxide by no more than 30%, preferably no more than 20%, or no more than 10%.
C07C 1/04 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of carbon from carbon monoxide with hydrogen
C07C 9/02 - Acyclic saturated hydrocarbons with one to four carbon atoms
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Liu, Chang
Wang, Yangdong
Xie, Zaiku
Liu, Su
Zhou, Haibo
Su, Junjie
Jiao, Wenqian
Zhang, Lin
Abstract
Disclosed are a catalyst including a molecular sieve having a topological pore structure. The catalyst includes a metal oxide, and a molecular sieve, in a crystal form, having a topological pore structure, and the metal oxide is centrally distributed on the surface of the molecular sieve, wherein grains of the molecular sieve are exposed to at least three families of crystal planes, and the family of crystal plane with the largest pore size in topology is occupied by the metal oxide by no more than 30%, preferably no more than 20%, or no more than 10%.
B01J 29/40 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
B01J 29/48 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J 35/60 - Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
B01J 35/70 - Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
C07C 1/04 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of carbon from carbon monoxide with hydrogen
C07C 9/02 - Acyclic saturated hydrocarbons with one to four carbon atoms
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Dong, Jing
Liu, Su
Wang, Yangdong
Abstract
Disclosed is an integrated catalyst used in an olefin disproportionation reaction. The integrated catalyst comprises a plurality of different integrated active phases, and the relative positions among different active phases remain substantially unchanged during the olefin disproportionation reaction. The effective distance between respective bisecting planes of two adjacent different active phases is 0.5-5 mm, preferably 1-3 mm.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Jingqiu
Kong, Dejin
Li, Xuguang
Wang, Zongshuang
Li, Huaying
Tong, Weiyi
Abstract
4567899 +6799 +4567 899 +6799 + component obtained in step b) to the cracking and aromatization unit for continued reaction. The present method and system may effectively convert a gasoline component into C8 aromatics, and co-produce low-carbon olefins and high-quality light gasoline, achieving efficient comprehensive utilization.
C07C 6/12 - Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
C10G 57/00 - Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
83.
IRON-POTASSIUM-CERIUM-BASED COMPOSITE OXIDE CATALYST, AND PREPARATION AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Song, Lei
Miao, Changxi
Zhu, Min
Wei, Chunling
Xu, Yongfan
Abstract
Disclosed are an iron-potassium-cerium-based composite oxide catalyst, and a preparation and application thereof; in addition to the metal elements Fe, K, and Ce, the catalyst also comprises a metal element M, the metal element M being selected from at least one of Group IIA metal elements, non-Cr Group VIB metal elements, and Group IVA metal elements, the total base amount of the catalyst being in the range of 0.32-0.46 mmol/g and the strong base amount being in the range of 0.061-0.082 mmol/g. When used for a dehydrogenation reaction of alkyl aromatic hydrocarbons, even at a lower dehydrogenation reaction temperature and an ultra-low water ratio, the catalyst has high selectivity, catalytic activity, and stability, and few by-products, having the features of low material consumption and low energy consumption.
C07C 5/32 - Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
84.
METHOD AND SYSTEM FOR TREATING HYDROCARBON-CONTAINING MIXTURE
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Jingqiu
Kong, Dejin
Li, Xuguang
Wang, Zongshuang
Li, Huaying
Abstract
55 -66 +66 +55 -67899 +55 -55 - component obtained in step III). The method and system can convert a low-value hydrocarbon mixture into C8 aromatic hydrocarbons and crack raw materials, thereby improving the product value.
C07C 5/27 - Rearrangement of carbon atoms in the hydrocarbon skeleton
C07C 2/00 - Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
C07C 6/12 - Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
C07C 7/00 - Purification, separation or stabilisation of hydrocarbonsUse of additives
C10G 11/00 - Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
85.
ADSORBENT COMPOSITION, AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Jia, Yinjuan
Gao, Huanxin
Wu, Shuang
Wang, Can
Yang, Heqin
Jing, Mengmeng
Liu, Zhicheng
He, Limin
Abstract
The present invention relates to an adsorbent composition, and a preparation method therefor and an application thereof. The adsorbent composition in the present invention comprises a molecular sieve, hydrated alumina, and alumina. The adsorbent composition in the present invention has a considerable adsorption capacity and excellent compressive strength, is easy to regenerate, does not exhibit obvious adsorption heat release, and is especially suitable for removing polar compounds in low-carbon olefins.
B01J 20/30 - Processes for preparing, regenerating or reactivating
C07C 7/13 - Purification, separation or stabilisation of hydrocarbonsUse of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
86.
DISPROPORTIONATION AND TRANSALKYLATION CATALYST, AND PREPARATION AND APPLICATION THEREOF
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Jingqiu
Ding, Jian
Wu, Yanan
Kong, Dejin
Abstract
Disclosed are a disproportionation and transalkylation catalyst and the preparation and application thereof, the catalyst comprising an acidic molecular sieve and a first metal component and an oxide adjuvant loaded on the acidic molecular sieve, a first metal in the first metal component being selected from at least one of group VB metals, group VIB metals, and group VIIB metals, the amount of medium-strong acid of the catalyst being a 0.05-2.0 mmol/g catalyst, and the proportion of medium-strong acid in the total acid amount being 60-99%. When used for the catalytic conversion of alkyl aromatic hydrocarbons, the catalyst has the advantages of high reaction activity and low aromatic hydrocarbon loss.
C07C 6/12 - Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
87.
GRAPHENE CONDUCTIVE COMPOSITE MATERIAL, PREPARATION METHOD THEREFOR, USE THEREOF AND LITHIUM-ION BATTERY
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Sun, Sai
Zhang, Siyu
Dong, Wenqian
Gao, Huanxin
Abstract
Disclosed are a graphene conductive composite material, a preparation method therefor, the use thereof and a lithium-ion battery. The graphene conductive composite material comprises graphene nanosheets and a conjugated copolymer, wherein the conjugated copolymer contains an alkynyl, has a linear structure and is grafted with the graphene nanosheets. The preparation method for the graphene conductive composite material comprises the following steps: pretreating graphene nanosheets with 4-bromobenzenediazonium tetrafluoroborate, and forming a conjugated copolymer in the presence of the pretreated graphene nanosheets. The graphene conductive composite material of the present invention can be uniformly dispersed in an electrode slurry, the internal resistance of an electrode is reduced, and the electrical conductivity of the electrode is improved; in addition, a flexible structure derived from the graphene nanosheets can buffer volume expansion of a silicon-containing negative electrode material during charging and discharging, so that the structural stability of a silicon-containing negative electrode is improved, and when applied to a lithium-ion battery, same can improve the rate capability and cycling stability of the lithium battery.
B32B 33/00 - Layered products characterised by particular properties or particular surface features, e.g. particular surface coatingsLayered products designed for particular purposes not covered by another single class
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Zong, Hongyuan
Li, Xiaohong
Qi, Guozhen
Jin, Yongming
Gao, Pan
Wang, Yanxue
Abstract
The present invention provides a mixing device for at least two particulate materials, comprising a first riser used for loading first particles and a second riser surrounding and coaxial with the riser and used for loading second particles, the upper part of the first riser extending beyond the top of the second riser, and at least a part of the upper part of the first riser and at least a part of the upper part of the second riser being located inside a mixing zone container, such that the first and second particles are delivered to the inside of the mixing zone container by means of the first and second risers respectively and mixed.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zong, Hongyuan
Li, Xiaohong
Qi, Guozhen
Jin, Yongming
Gao, Pan
Wang, Yanxue
Abstract
The present invention provides a mixing device for at least two particulate materials, comprising a first riser used for loading first particles and a second riser surrounding and coaxial with the riser and used for loading second particles, the upper part of the first riser extending beyond the top of the second riser, and at least a part of the upper part of the first riser and at least a part of the upper part of the second riser being located inside a mixing zone container, such that the first and second particles are delivered to the inside of the mixing zone container by means of the first and second risers respectively and mixed.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Zong, Hongyuan
Li, Xiaohong
Qi, Guozhen
Wang, Hongtao
Yu, Zhinan
Zheng, Yijun
Wang, Li
Abstract
The present invention provides a device for mixing at least two granular materials, comprising a first lifting tube used for loading first particles, and a second lifting tube surrounding and coaxial to the first lifting tube and used for loading second particles, the upper part of said first lifting tube extending beyond the top of said second lifting tube, and at least part of said upper part of the first lifting tube and at least part of said upper part of the second lift tube being located inside a fast bed precipitator, allowing the first and second particles to be transported by means of the first and second lifting tubes to the interior of said fast bed precipitator and mixed.
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zong, Hongyuan
Li, Xiaohong
Qi, Guozhen
Wang, Hongtao
Yu, Zhinan
Zheng, Yijun
Wang, Li
Abstract
The present invention provides a device for mixing at least two granular materials, comprising a first lifting tube used for loading first particles, and a second lifting tube surrounding and coaxial to the first lifting tube and used for loading second particles, the upper part of said first lifting tube extending beyond the top of said second lifting tube, and at least part of said upper part of the first lifting tube and at least part of said upper part of the second lift tube being located inside a fast bed precipitator, allowing the first and second particles to be transported by means of the first and second lifting tubes to the interior of said fast bed precipitator and mixed.
C07C 1/20 - Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as hetero atoms
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Qiao, Jian
Yuan, Zhiqing
Wang, Zhendong
Teng, Jiawei
Tao, Weichuan
Fu, Wenhua
Liu, Songlin
Abstract
Disclosed are an SCM-34 molecular sieve, a preparation method therefor and the use thereof. The SCM-34 molecular sieve comprises aluminum, phosphorus, oxygen and optional silicon, wherein the 2θ angle of the strongest peak in the 2θ angle range of 5-50° in XRD diffraction data of the molecular sieve is 7.59±0.2. The SCM-34 molecular sieve has a new skeleton structure, can be used for preparing a metal-containing AFI molecular sieve or SAPO-17 molecular sieve, and meets different requirements for catalysts during chemical production.
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Yingcheng
Gu, Songyuan
Zhang, Weidong
Bao, Xinning
Sha, Ou
Shen, Zhiqin
Yang, Yiqing
Zhai, Xiaodong
Abstract
An anionic-cationic-nonionic surfactant represented by the formula (I)
exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present anionic-cationic-nonionic surfactant, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.
C09K 8/584 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
C07C 213/06 - Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton from hydroxy amines by reactions involving the etherification or esterification of hydroxy groups
C07C 217/08 - Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom
C07C 231/14 - Preparation of carboxylic acid amides by formation of carboxamide groups together with reactions not involving the carboxamide groups
C07C 233/05 - Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
C07C 233/09 - Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to carbon atoms of an acyclic unsaturated carbon skeleton
C07C 233/36 - Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
C07C 237/08 - Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atom of at least one of the carboxamide groups bound to an acyclic carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
C07C 237/40 - Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having the nitrogen atom of the carboxamide group bound to a carbon atom of a six-membered aromatic ring
C07C 303/22 - Preparation of esters or amides of sulfuric acidsPreparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids by reactions not involving the formation of sulfo or halosulfonyl groups
C07C 309/10 - Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing etherified hydroxy groups bound to the carbon skeleton with the oxygen atom of at least one of the etherified hydroxy groups further bound to an acyclic carbon atom
C09K 8/60 - Compositions for stimulating production by acting on the underground formation
94.
Silicoaluminophosphate molecular sieve, its preparation and application thereof
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Yang, Weimin
Yuan, Zhiqing
Teng, Jiawei
Fu, Wenhua
Liu, Songlin
Abstract
3 and is in a range of about 0.7-1.1. The silicoaluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.
B01J 20/02 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Yang, Weimin
Yuan, Zhiqing
Teng, Jiawei
Fu, Wenhua
Liu, Songlin
Abstract
5, in which n represents a phosphorus to aluminum molar ratio, and is in a range of about 0.8-1.2. The aluminophosphate molecular sieve has a unique X-ray diffraction pattern, and can be used as an adsorbent, a catalyst or a catalyst carrier.
C01B 39/04 - Crystalline aluminosilicate zeolitesIsomorphous compounds thereofDirect preparation thereofPreparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactantsAfter-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
B01J 20/02 - Solid sorbent compositions or filter aid compositionsSorbents for chromatographyProcesses for preparing, regenerating or reactivating thereof comprising inorganic material
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Li, Yingcheng
Bao, Xinning
Zhang, Weidong
Sha, Ou
Wu, Xinyue
Jin, Jun
Abstract
An alkylaniline polyether benzene sulfonate oil-displacement surfactant, which has a structure as represented by formula (I). A polyether chain in the structure of the alkylaniline polyether benzene sulfonate oil-displacement surfactant is connected to a benzene ring by means of an N atom. The alkylaniline polyether benzene sulfonate oil-displacement surfactant has high interfacial activity, and can achieve an interfacial tension of 10-3mN/m under conditions of no alkali and high salinity.
C07C 309/49 - Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton the carbon skeleton being further substituted by singly-bound oxygen atoms
C09K 8/584 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
97.
ALKYLANILINE POLYETHER BENZENESULFONATE AND A PROCESS OF PRODUCING SAME
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
CHINA PETROLEUM & CHEMICAL CORPORATION (China)
Inventor
Li, Yingcheng
Bao, Xinning
Zhang, Weidong
Sha, Ou
Wu, Xinyue
Jin, Jun
Abstract
An alkylaniline polyether benzene sulfonate oil-displacement surfactant, which has a structure as represented by formula (I). A polyether chain in the structure of the alkylaniline polyether benzene sulfonate oil-displacement surfactant is connected to a benzene ring by means of an N atom. The alkylaniline polyether benzene sulfonate oil-displacement surfactant has high interfacial activity, and can achieve an interfacial tension of 10-3mN/m under conditions of no alkali and high salinity.
C07C 309/49 - Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton the carbon skeleton being further substituted by singly-bound oxygen atoms
C09K 8/584 - Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
98.
Gas replacement process, gas replacement apparatus, and nitro compound hydrogenation reaction process
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Zhong, Siqing
Xu, Jun
Zhao, Le
Wu, Lianghua
Abstract
A gas replacement process and a gas replacement apparatus are employed, in the nitro compound hydrogenation reaction process. The gas replacement process at least includes a first step of subjecting a stream to be replaced to the gas replacement in presence of a first replacement gas, and then a second step of subjecting to the gas replacement in presence of the second replacement gas. Assuming the superficial velocity of the first replacement gas is V1, and the superficial velocity of the second replacement gas is V2, then V2/V1≥1.5.
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
B01J 23/94 - Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
B01J 35/40 - Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
B01J 38/06 - Gas or vapour treatingTreating by using liquids vaporisable upon contacting spent catalyst using steam
C07C 209/36 - Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings
99.
NITRO COMPOUND HYDROGENATION REACTION PROCESS AND HYDROGENATION REACTION APPARATUS
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC (China)
Inventor
Zhong, Siqing
Xu, Jun
Zhao, Le
Wu, Lianghua
Abstract
The present invention relates to a nitro compound hydrogenation reaction process and hydrogenation reaction apparatus, which can achieve the objects of the continuous reaction of the nitro compound and the long-period run of regeneration and activation. The nitro compound hydrogenation reaction process comprises a hydrogenation step, a regeneration step, an optional activation step and a recycling step. There exists at least one step of degassing the spent catalyst between the hydrogenation step and the regeneration step. According to circumstances, there exists at least one step of degassing the regenerated catalyst between the regeneration step and the activation step.
C07C 209/36 - Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings
B01J 8/24 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique
B01J 8/18 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC (China)
Inventor
Xu, Jun
Zhong, Siqing
Zhao, Le
Wu, Lianghua
Abstract
A fluidized apparatus contains a double-trapezoid structural member. These fluidized apparatuses are used in the nitro compound hydrogenation reaction process. The fluidized apparatus includes a shell, a gas distributor, and an inner chamber defined by an inner wall of said shell and an upper surface of said gas distributor, in the middle region of said inner chamber is disposed a perforated plate, the perforated plate comprise an outer edge region and a center region, assuming the opening rate of the outer edge region is A1 (the unit is %), assuming the opening rate of the center region is A2 (the unit is %), then A1/A2=0-0.95.
B01J 8/00 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes
B01D 45/08 - Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia by impingement against baffle separators
B01D 45/16 - Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces generated by the winding course of the gas stream
B01J 8/34 - Chemical or physical processes in general, conducted in the presence of fluids and solid particlesApparatus for such processes with fluidised particles according to "fluidised-bed" technique with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles
B01J 35/40 - Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
C07C 209/36 - Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings