The present technology relates to multifunctionalized thiol conductor compounds which can be grafted onto polymers, and methods for making same. In certain embodiments, the compounds of the present technology can be grafted onto polymers having low Tg to synthesize single-ion conducting polymer electrolytes having improved conductivity. The multifunctionalized thiol conductor compounds of the present technology generally comprise more than one sulfonamide anion covalently attached to a substitutable core (A) via a sulphide bond, a thiol functional group and optionally a hydrocarbon side chain (L) attached to the substitutable core (A).
C07C 311/48 - Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups having nitrogen atoms of sulfonamide groups further bound to another hetero atom
H01B 1/12 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of other non-metallic substances organic substances
H01M 6/18 - Cells with non-aqueous electrolyte with solid electrolyte
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
2.
THIOL FUNCTIONALIZED CONDUCTOR COMPOUND AND METHOD FOR MAKING SAME
The present technology relates to thiol functionalized conductors which can be grafted onto polymers and methods for making same. In certain embodiments, the thiol functionalized conductors can be grafted onto polymers with low Tg to synthesize single-ion conducting polymer electrolytes (SIPE) having improved conductivity. The thiol functionalized conductor compound comprises a covalently attached sulfonimide anion on one end, which is associated with a monovalent cation; 1-3 hydrocarbon chains as the linker (L); 0-2 functional groups (R); and a thiol group on the other end of the compound.
C07C 311/48 - Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups having nitrogen atoms of sulfonamide groups further bound to another hetero atom
C07C 321/04 - Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
C07C 323/52 - Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
H01B 1/12 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of other non-metallic substances organic substances
H01M 4/137 - Electrodes based on electro-active polymers
H01M 6/18 - Cells with non-aqueous electrolyte with solid electrolyte
H01M 10/0565 - Polymeric materials, e.g. gel-type or solid-type
3.
SINGLE ION CONDUCTING POLYMERS AND METHOD OF MAKING SAME
The present technology relates to a method for producing a single-ion conducting polymer comprising grafting a thiol functionalized conductor compound onto a polymer compound to obtain the single-ion conducting polymer. In certain embodiments, the thiol functionalized conductor compound can be grafted onto polymers having low Tg which result in single-ion conducting polymers having improved conductivity.
The present technology relates to methods for the synthesis of a lithium single-ion monomer which comprises simultaneously reacting a sulfonyl chloride compound with i) a fluorinated sulfonamide compound and ii) a compound that is suitable to act as a quenching base and a lithium cation source. The simultaneous reaction of sulfonyl chloride with the fluorinated sulfonamide compound and the compound that is suitable to act as a quenching base and a lithium cation source yields the single-ion monomer.
C07C 311/48 - Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups having nitrogen atoms of sulfonamide groups further bound to another hetero atom
The present disclosure provides a coiled capacitor comprising a coil formed by a flexible multilayered tape, and a first terminating electrode and a second terminating electrode which are located on butts of the coil. The flexible multilayered tape contains the following sequence of layers: first metal layer, a layer of a plastic, second metal layer, a layer of energy storage material. The first metal layer forms ohmic contact with the first terminating electrode and the second metal layer forms ohmic contact with the second terminating electrode. The energy storage material comprises material selected from the list comprising rylene fragments, doped oligoaniline and p-oligo-phenylene, supramolecular structures, colloidal composite with dispersion (suspension) of electro-conductive anisometric particles in an insulator matrix, material comprises a surfactant.
A metadielectric composite oligomeric organic material according to the formula:
wherein C is a linear chain oligomeric polarizable core with a system of conjugated multiple and single bonds wherein the linear chain oligomeric polarizable core possesses at least two different monomers with differing electron affinity, and the different monomers are positioned within the linear chain oligomeric polarizable core such that an electron affinity gradient is present, and the differing monomers have a low HOMO-LUMO bandgap between them, and there is at least one electron-donor group, D, attached to the linear chain oligomeric polarizable core, there is at least one electron-acceptor group, A, is attached to the linear chain oligomeric polarizable core, p′ and q′ represent the number of electron-donor and electron-acceptor groups present, respectively, and are any integer greater than zero, and at least one resistive insulating group is covalently attached to the molecular structure at any location.
H01G 4/18 - Organic dielectrics of synthetic material, e.g. derivatives of cellulose
C08F 20/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
C08G 69/08 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from amino carboxylic acids
C08G 69/32 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
A composite polymeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a hydrocarbon chain linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite polymeric material may be used to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.
where Core is a polarizable conductive anisometric core, having conjugated π-systems, and characterized by a longitudinal axis, D and H are insulating substituents, and p and q are numbers of the D and H substituents accordingly. And Core possesses at least one dopant group that enhances polarizability.
H01G 4/40 - Structural combinations of fixed capacitors with other electric elements not covered by this subclass, the structure mainly consisting of a capacitor, e.g. RC combinations
H01L 29/00 - SEMICONDUCTOR DEVICES NOT COVERED BY CLASS - Details of semiconductor bodies or of electrodes thereof
H02J 7/34 - Parallel operation in networks using both storage and other DC sources, e.g. providing buffering
A plasma electric propulsion device includes a capacitive energy storage device as a power source for an engine configured to heat and/or ionize and/or accelerate a propellant due to action of an electric field and/or magnetic field. The energy storage device has a first electrically conductive electrode, a second electrically conductive electrode, and at least one metadielectric layer located between the first and second conductive electrodes. The metadielectric layer comprises at least one organic compound with at least one electrically resistive substituent and at least one polarizable unit. The polarizable unit is selected from intramolecular and intermolecular polarizable units. The organic compound is selected from the list comprising compounds with rigid electro-polarizable organic units, composite organic polarizable compounds, composite electro-polarizable organic compounds, composite non-linear electro-polarizable compounds, Sharp polymers, Furuta co-polymers, para- Furuta polymers, YanLi polymers, and any combination thereof.
wherein C is a linear chain oligomeric polarizable core with a system of conjugated multiple and single bonds wherein the linear chain oligomeric polarizable core possesses at least two different monomers with differing electron affinity, and the different monomers are positioned within the linear chain oligomeric polarizable core such that an electron affinity gradient is present, and the differing monomers have a low HOMO-LUMO bandgap between them, and there is at least one electron-donor group, D, attached to the linear chain oligomeric polarizable core, there is at least one electron-acceptor group, A, is attached to the linear chain oligomeric polarizable core, p′ and q′ represent the number of electron-donor and electron-acceptor groups present, respectively, and are any integer greater than zero, and at least one resistive insulating group is covalently attached to the molecular structure at any location.
H01G 4/18 - Organic dielectrics of synthetic material, e.g. derivatives of cellulose
C08F 20/18 - Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
C08G 69/08 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from amino carboxylic acids
C08G 69/32 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
A metadielectric composite oligomeric organic material according to the formulae: ( D )p`-[ C ]-( A )q` or ( D )p`-[C]-( D )q` wherein C is a linear chain oligomeric polarizable core, wherein the linear chain oligomeric polarizable core possesses at least two different monomers with differing electron affinity, and the different monomers are positioned such that an electron affinity gradient is present, and there is either at least one electron-donor group or electron-rich monomer, D, and at least one electron-acceptor group or electron-poor monomer, A, or electron-donor group or electron-rich monomer, D, attached at each end of the oligomeric polarizable core, p' and q' represent the number of electron-donor and electron-acceptor groups present, respectively, and are any integer greater than zero, and at least one resistive insulating group is covalently attached to the molecular structure at any location.
C07D 409/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
C07D 417/14 - Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group containing three or more hetero rings
H01G 4/00 - Fixed capacitorsProcesses of their manufacture
The present disclosure provides a plasma electric propulsion device comprising a capacitive energy storage device as a power source for an engine configured to heat and/or ionize and/or accelerate a propellant due to action of an electric field and/or magnetic field. The energy storage device comprises: a first electrically conductive electrode, a second electrically conductive electrode; and at least one metadielectric layer located between the first and second conductive electrodes. The metadielectric layer comprises at least one organic compound with at least one electrically resistive substituent and at least one polarizable unit. The polarizable unit is selected from intramolecular and intermolecular polarizable units. The organic compound is selected from the list comprising compounds with rigid electro-polarizable organic units, composite organic polarizable compounds, composite electro-polarizable organic compounds, composite non-linear electro-polarizable compounds, Sharp polymers, Furuta co-polymers, para-Furuta polymers, YanLi polymers, and any combination thereof.
An electro-polarizable compound has a general formula: (I) Aromatic polycyclic conjugated molecule Core1self-assembles to form supramolecular structures; m donor groups R1 and m' of acceptor groups R1' connect to Core1; m and m' = 0, 1, 2, 3, 4, 5 or 6, but cannot both be 0; p=0, 1, 2, 3 or 4 substituents R2 (one or more ionic groups) connect to Core1 directly or via connecting group. Fragment NLE has a nonlinear polarization effect. A number n of self-assembling electro-conductive oligomers Core2 can be 0, 2, or 4; s=0, 1, 2, 3, or 4 ionic groups R3 connect to Core 2; k=0, 1, 2, 3, 4, 5, 6, 7 or 8 resistive substituents R4 that electrically insulate the supramolecular structures.
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
A composite oligomeric material includes one or more repeating backbone units. One or more polarizable units are incorporated into or connected to one or more of the one or more repeating backbone units. One or more resistive tails are connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit. The composite oligomer material may be polymerized to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.
H01G 7/06 - Capacitors in which the capacitance is varied by non-mechanical meansProcesses of their manufacture having a dielectric selected for the variation of its permitivity with applied voltage, i.e. ferroelectric capacitors
H01B 3/30 - Insulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of organic substances plasticsInsulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of organic substances resinsInsulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of organic substances waxes
An electro-polarizable compound has the following general formula:
where Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule, which is tetrapirolic macro-cyclic fragment, R1 is an dopant group connected to Core1, m is number of R1 which is equal to 1, 2, 3 or 4, R2 is a substituent comprising one or more ionic groups, p is number of R2 which is equal to 0, 1, 2, 3 or 4. The fragment marked NLE containing the Core1 with at least one R1 has a nonlinear effect of polarization. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, n is number of Core2 which is equal to 2, or 4, R3 is a substituent comprising one or more ionic groups, s is number of R3 which is equal to 0, 1, 2, 3 or 4. R4 is a non-polar resistive substituent, k is a number of R4 which is equal to 0, 1, 2, 3, 4, 5, 6, 7 or 8.
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
C07B 47/00 - Formation or introduction of functional groups not provided for in groups
H01G 4/18 - Organic dielectrics of synthetic material, e.g. derivatives of cellulose
The present disclosure provides an organic compound characterized by electronic polarizability and having a following general structural formula:
2 are selected from hydrogen and electrophilic groups (acceptors).
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
An electro-polarizable compound having the following formula (I):
where Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule comprising one or more rylene fragments, R1 is an electron donor group connected to Core1 and R1′ is an electron acceptor group connected to the Core1, m is number of acceptor group R1, m′ is a number of donor group R′, m and m′ are equal to 0, 1, 2, 3, 4, 5 or 6, wherein m and m′ are not both equal to 0, R2 is a substituent comprising one or more ionic groups from a class of ionic compounds that form ionic liquids connected to the Core1-directly or via a connecting group, p is a number of ionic groups R2 which is equal to 0, 1, 2, 3 or 4; wherein the fragment marked NLE containing the Core1 with at least one group R1 and/or R1′ has a nonlinear effect of polarization, wherein Core2 is an electro-conductive oligomer, n is a number equal to 0, 2, or 4, R3 is a substituent comprising one or more ionic groups from a class of ionic compounds that form ionic liquids connected to the Core2 directly or via a connecting group, s is a number of the ionic groups R3 which is equal to 0, 1, 2, 3 or 4; wherein R4 is a non-conjugate cyclic or polycyclic resistive substituent electrically insulating the column-like supramolecules from each other and connected to the aromatic polycyclic conjugated molecule (Core1) and/or to the Core2 directly or via a connecting group, k is a number of substituents R4 which is equal to 1, 2, 3, 4, 5, 6, 7 or 8.
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
H01G 7/06 - Capacitors in which the capacitance is varied by non-mechanical meansProcesses of their manufacture having a dielectric selected for the variation of its permitivity with applied voltage, i.e. ferroelectric capacitors
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
The present disclosure provides an energy storage molecular material, crystal dielectric layer and capacitor which may solve a problem of the further increase of volumetric and mass density of reserved energy associated with some energy storage devices, and at the same time reduce cost of materials.
C07D 519/00 - Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups or
The present disclosure provides a coiled capacitor comprising a coil formed by a flexible multilayered tape, and a first terminating electrode and a second terminating electrode which are located on butts of the coil. The flexible multilayered tape contains the following sequence of layers: first metal layer, a layer of a plastic, second metal layer, a layer of energy storage material. The first metal layer forms ohmic contact with the first terminating electrode and the second metal layer forms ohmic contact with the second terminating electrode. The energy storage material comprises material selected from the list comprising rylene fragments, doped oligoaniline and p-oligo-phenylene, supramolecular structures, colloidal composite with dispersion (suspension) of electro-conductive anisometric particles in an insulator matrix, material comprises a surfactant.
The present disclosure provides an unmanned vehicle comprising a device to be powered; a capacitor energy storage system (CESS) and controller board for at least temporarily powering and operating the device to powered. Further, the CESS includes one or more metacapacitors as an energy storage medium. Additionally, the disclosure provides a capacitor energy storage cell composed of the at least one metacapacitor and a DC-voltage conversion device, where the output voltage of the metacapacitor is the input voltage of the DC-voltage conversion device. Still further, the CESS may be comprised of a module of said capacitor energy storage cells, or a system of modules of said capacitor energy storage cells.
H01G 4/18 - Organic dielectrics of synthetic material, e.g. derivatives of cellulose
B64C 39/02 - Aircraft not otherwise provided for characterised by special use
H02M 3/158 - Conversion of DC power input into DC power output without intermediate conversion into AC by static converters using discharge tubes with control electrode or semiconductor devices with control electrode using devices of a triode or transistor type requiring continuous application of a control signal using semiconductor devices only with automatic control of output voltage or current, e.g. switching regulators including plural semiconductor devices as final control devices for a single load
H02M 3/156 - Conversion of DC power input into DC power output without intermediate conversion into AC by static converters using discharge tubes with control electrode or semiconductor devices with control electrode using devices of a triode or transistor type requiring continuous application of a control signal using semiconductor devices only with automatic control of output voltage or current, e.g. switching regulators
B64D 27/24 - Aircraft characterised by the type or position of power plants using steam or spring force
H01G 11/56 - Solid electrolytes, e.g. gelsAdditives therein
H02J 7/34 - Parallel operation in networks using both storage and other DC sources, e.g. providing buffering
H02K 11/00 - Structural association of dynamo-electric machines with electric components or with devices for shielding, monitoring or protection
23.
Multilayered electrode and film energy storage device
The present disclosure provides a multilayered electrode comprising an electro-conductive layer and at least one protective layer located on one side of the electro-conductive layer and selected from the list comprising a field-planarization layer, a tunneling injection blocking layer and a coulomb blocking layer.
H01B 1/12 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of other non-metallic substances organic substances
C08G 73/06 - Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromoleculePolyhydrazidesPolyamide acids or similar polyimide precursors
C09D 165/00 - Coating compositions based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chainCoating compositions based on derivatives of such polymers
24.
MULTILAYERED ELECTRODE AND FILM ENERGY STORAGE DEVICE
The present disclosure provides a multilayered electrode comprising an electro-conductive layer and at least one protective layer located on one side of the electro-conductive layer and selected from the list comprising a field-planarization layer, a tunneling injection blocking layer and a coulomb blocking layer.
H01L 27/28 - Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including components using organic materials as the active part, or using a combination of organic materials with other materials as the active part
H01L 29/43 - Electrodes characterised by the materials of which they are formed
25.
Hein electro-polarizable compound and capacitor thereof
An electro-polarizable compound has the following general formula:
Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and that self-assembles to form supramolecular structures. R1 are electron donor groups connected to Core1 and R1′ are electron acceptor groups connected to Corel, m is number of acceptor groups R1, m′ is a number of donor groups R′. The numbers m and m′ are equal to 0, 1, 2, 3, 4, 5 or 6, but both m and m′ are not both equal to 0. R2 is a substituent comprising one or more ionic groups connected to Core1 directly or via a connecting group; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear effect of polarization. Core2 is a self-assembling electro-conductive oligomer, a number n of the such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent electrically insulating the supramolecular structures from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
C07F 7/08 - Compounds having one or more C—Si linkages
C09K 19/32 - Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
C09K 19/34 - Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
C09K 19/22 - Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and nitrogen atoms as chain links, e.g. Schiff bases
H01G 4/18 - Organic dielectrics of synthetic material, e.g. derivatives of cellulose
C09K 19/30 - Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
26.
Solid multilayer structure as semiproduct for meta-capacitor
The present disclosure provides solid multilayer structure having m polarization layers, and m+1 insulating layers disposed in a repeating sequence with the polarization layers, At least one polarization layer is comprised of materials selected from non-linear polarizable composite compounds and side chain polymers with non-linear polarizable pendants, and m is a number greater than or equal to 1. The insulating layer has a breakdown voltage greater than or equal to 0.01 volts (V) per nanometer (nm), and the polarization layer has a dielectric permittivity greater than or equal to 100. The solid multilayer structure may be used as a dielectric layer between two electrodes in capacitor.
The present invention relates generally to the fields of electrical engineering and electronics. More specifically, the present invention relates to passive components of electrical circuitry and more particularly to energy storage devices and method of production thereof.
A composite polymeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a hydrocarbon chain linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite polymeric material may be used to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.
where Core is a polarizable conductive anisometric core, having conjugated π-systems, and characterized by a longitudinal axis, D and H are insulating substituents, and p and q are numbers of the D and H substituents accordingly. And Core possesses at least one dopant group that enhances polarizability.
H01G 4/40 - Structural combinations of fixed capacitors with other electric elements not covered by this subclass, the structure mainly consisting of a capacitor, e.g. RC combinations
H01L 29/00 - SEMICONDUCTOR DEVICES NOT COVERED BY CLASS - Details of semiconductor bodies or of electrodes thereof
H02J 7/34 - Parallel operation in networks using both storage and other DC sources, e.g. providing buffering
30.
YANLI MATERIAL AND DIELECTRIC AND CAPACITOR THEREOF
A composite oligomeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a handle linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite oligomer material may be polymerized to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.
C07D 519/00 - Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups or
A composite organic compound characterized by polarizability and resistivity that has a general structural formula (I) where C is a chromophore fragment, P is an optionally connected rylene fragment, D and A are electron donating and accepting groups respectively, and R represents resistive substituents optionally connected via dopant connecting groups.
An electro-polarizable compound has a general formula: _ _ | ____________ | | | | | | | [R1]m | | <-NLE | | | | | | | | [ Core1 ]-----|-[Core2]n |-[R4]k (I) | |___ |_______| | | | | | | | [R2]p [R3]s | |_ _| Core1 is an two-dimensional flat aromatic polycyclic conjugated molecule, R1 is a dopant group of which there are m=1, 2, 3 or 4. R2 is an ionic substituent, of which there are p=0, 1, 2, 3 or 4. Fragment NLE has a nonlinear polarization effect. Core2 is an electro-conductive oligomer, of which there are n=0, 2, or 4. R3 is an ionic substituent of which there are s=0, 1, 2, 3 or 4. R4 is a resistive substituent, of which there are k=0, 1, 2, 3, 4, 5, 6, 7 or 8.
An electro-polarizable compound has a general formula: (I) Core1 is an aromatic polycyclic conjugated molecule. R1 and R1' are electron donor and acceptor groups, respectively; m, m' can be 0, 1, 2, 3, 4, 5, 6, but not m=m'=0. R2 is an ionic substituent, of which there are p=0, 1, 2, 3, 4. Fragment NLE has a nonlinear effect of polarization. Core2 is a self-assembling electro-conductive oligomer, of which there are n=0, 2, or 4. R3 is an ionic substituent, of which there are s=0, 1, 2, 3, 4. R4 is a resistive substituent, of which there are k=0, 1, 2, 3, 4, 5, 6, 7, 8.
An electro-polarizable compound has the following general formula:
Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule. R1 are electron donor groups connected to Core1 and R1′ are electron acceptor groups connected to Core1, m is number of acceptor groups R1, m′ is a number of donor groups R′. The numbers m and m′ are equal to 0, 1, 2, 3, 4, 5 or 6, but both m and m′ are not both equal to 0. R2 is a substituent comprising one or more ionic groups connected to Core1 directly or via a connecting group; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear effect of polarization. Core2 is a self-assembling electro-conductive oligomer, a number n of the such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent providing solubility of the compound in a solvent and electrically insulating the column-like supramolecules from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
C09B 5/62 - Cyclic imides or amidines of peri-dicarboxylic acids of the anthracene, benzanthrene, or perylene series
An electro-polarizable compound has the following general formula:
Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule, R1 is a dopant group connected to Core1; a number m of R1 groups is 1, 2, 3 or 4. R2 is a substituent comprising one or more ionic groups connected to Core1; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear polarization effect. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, a number n of such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent providing solubility of the compound in a solvent and electrically insulating the column-like supramolecules from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.
C07D 471/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed systems contains four or more hetero rings
C09K 19/22 - Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and nitrogen atoms as chain links, e.g. Schiff bases
C07F 7/08 - Compounds having one or more C—Si linkages
C09K 19/34 - Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
C09K 19/32 - Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
The present disclosure provides an energy storage cell comprising at least one capacitive energy storage device and a DC-voltage conversion device. The capacitive energy storage device comprises at least one meta-capacitor. The output voltage of the capacitive energy storage device is the input voltage of the DC-voltage conversion device. The present disclosure also provides a capacitive energy storage module and a capacitive energy storage system.
An organic polymeric compound called a para-Furuta polymer is characterized by polarizability and resistivity has t repeating units of a general structural formula having a backbone structure include structural unit P, on which are n Tail repeat units and m L-Q repeat units. P is selected from acrylate, methacrylate, polypropylene repeat units, polyethylene repeat units, siloxane, and polyethylene terephthalate repeat units. Tail repeat units are resistive substitutes that are oligomers of polymeric material. The L-Q repeat units have j ionic functional groups Q connected to the structural unit P via a linker group L. The ionic functional groups Q comprise one or more ionic liquid ions, zwitterions, polymeric acids, or any combination thereof. The compound includes s counter ions B that supply an opposite charge to balance a charge of the compound.
B32B 15/08 - Layered products essentially comprising metal comprising metal as the main or only constituent of a layer, next to another layer of a specific substance of synthetic resin
C08F 10/00 - Homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
C08F 20/00 - Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
C08G 77/00 - Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon
A meta-dielectric film usable in a capacitor includes composite molecules with a resistive envelope built with alkyl oligomeric single chain or branched chain oligomers having carbo-hydrogen or carbo-fluoro composition and a polarizable core molecular fragment inside the resistive envelope. The polarizable core has an electronic or ionic type of polarizability provided by electronic conductivity of the core molecular fragment or limited mobility of ionic parts of the core molecular fragment.
The present disclosure provides an energy storage cell comprising at least one capacitive energy storage device and a DC-voltage conversion device. The capacitive energy storage device comprises at least one meta-capacitor. The output voltage of the capacitive energy storage device is the input voltage of the DC-voltage conversion device. The present disclosure also provides a capacitive energy storage module and a capacitive energy storage system.
H02J 7/02 - Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries for charging batteries from AC mains by converters
H02J 7/04 - Regulation of the charging current or voltage
H01G 11/08 - Structural combinations, e.g. assembly or connection, of hybrid or EDL capacitors with other electric components, at least one hybrid or EDL capacitor being the main component
H01G 11/18 - Arrangements or processes for adjusting or protecting hybrid or EDL capacitors against thermal overloads, e.g. heating, cooling or ventilating
H01G 15/00 - Structural combinations of capacitors or other devices covered by at least two different main groups of this subclass with each other
An organic co-polymeric compound characterized by polarizability and resistivity has a backbone structure with randomly repeating units of first type (P1-Tail) that repeat n times and repeat units of second type (P2-L-Q) that repeat m times. P1 and P2 may be acrylic acid, methacrylate, -repeat units for polypropylene (PP) (-[CH2-CH(CH3)]-), repeat units for polyethylene (PE) (-[CH2]-), siloxane, or repeat units for polyethylene terephthalate (-CH2-CH2-O-CO-C6H4-CO-O-). The numbers n and m may range from 3 to 100 000. The ratio n:m may range from 10:1 and 1:10. Tail is an oligomer of polymeric material that may have a HOMO-LUMO gap no less than 2 eV. Q is an ionic functional group connected to the P2 unit via a linker group L. The compound includes s counter ions B that supply an opposite charge to balance a charge of the co-polymer.
B32B 15/08 - Layered products essentially comprising metal comprising metal as the main or only constituent of a layer, next to another layer of a specific substance of synthetic resin
C08F 10/00 - Homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
C08F 20/00 - Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
C08G 77/00 - Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon
A capacitive energy storage module (CESM) is provided under a floor panel of an electric vehicle. The CESM is a pack of capacitive energy storage cells (CESCs) which are themselves one or more capacitive energy storage devices (CESDs) comprising one or more metacapacitors. The CESM is arranged between a pair of right and left side members. The CESM is provided with a CESM case. The CESM case includes a tray member and cover member. Electric components are contained in the CESM case. Beam members made of metal are attached to the tray member. Both end portions of these beam members are supported by the side members. The tray member includes a resin and insert members made of metal provided inside the resin. The insert members include metal plates arranged on the front side and rear side of the electric components.
A capacitor based energy storage system (CBESS) and methods of using it are disclosed. The CBESS uses meta-capacitors in its capacitive energy storage devices (CESD) to configure capacitive energy storage cells (CESC), which are used to configure capacitive energy storage modules (CESM) to achieve the CBESS's function as an uninterruptible power supply. The CBESS is connected to a power generation system (PGS), a load, and a power grid. When the grid is in an abnormal state, the CESM is simultaneously charged with power from the PGS and used to supply power to the load. If a remaining amount of power of a CESM is less than a predetermined level, the CESM is charged with power from PGS or grid. The CBESS interfaces with a computer system or network to buy or sell electricity to the grid depending on grid electricity cost and CESD charging states.
The present disclosure provides an energy storage system comprising at least one capacitive energy storage device and a DC-voltage conversion device. The capacitive energy storage device comprises at least one metacapacitor. The output voltage of the capacitive energy storage device is the input voltage of the DC-voltage conversion device. The capacitive energy storage system is capable of being charged from a power generation system and/or an electrical grid and discharging energy to a load and/or electrical grid. The capacitive energy storage system is configurable to supply external power as an operating power in a first state in which the external power is applied and/or to supply power as the operating power in a second state in which the external power is not applied.
H02J 7/02 - Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries for charging batteries from AC mains by converters
H02J 7/04 - Regulation of the charging current or voltage
H01G 11/08 - Structural combinations, e.g. assembly or connection, of hybrid or EDL capacitors with other electric components, at least one hybrid or EDL capacitor being the main component
H02G 11/00 - Arrangements of electric cables or lines between relatively-movable parts
The present disclosure provides an organic compound characterized by electronic polarizability and having a following general structural formula: where Core is an aromatic polycyclic conjugated molecule, R1 is group providing solubility of the organic compound in an organic solvent, n is 1, 2, 3, 4, 5, 6, 7 or 8, R2 is substitute located in apex positions, R3 and R4 are substitutes located in side (lateral) positions and, the core has flat anisometric form and the R2 substitutes are selected from hydrogen and electrophilic groups (acceptors) and R3 substitutes and R4 substitutes are independently selected from hydrogen and nucleophilic groups (donors) or vice versa R3 substitutes and R4 substitutes are independently selected from hydrogen and nucleophilic groups (donors) and R2 substitutes are selected from hydrogen and electrophilic groups (acceptors), and the substitutes R2, R3 and R4 cannot all be hydrogen.
The present disclosure provides a coiled capacitor comprising a coil formed by a flexible multilayered tape, and a first terminating electrode (a first contact layer) and a second terminating electrode (a second contact layer) which are located on butts of the coil. The flexible multilayered tape contains the following sequence of layers: first metal layer, a layer of a plastic, second metal layer, a layer of energy storage material. The first metal layer forms ohmic contact with the first terminating electrode (the first contact layer) and the second metal layer (the second contact layer) forms ohmic contact with the second terminating electrode.
C08G 73/10 - PolyimidesPolyester-imidesPolyamide-imidesPolyamide acids or similar polyimide precursors
C08G 69/32 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H01B 3/30 - Insulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of organic substances plasticsInsulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of organic substances resinsInsulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of organic substances waxes
The present disclosure provides a coiled capacitor comprising a coil formed by a flexible multilayered tape, and a first terminating electrode (a first contact layer) and a second terminating electrode (a second contact layer) which are located on butts of the coil. The flexible multilayered tape contains the following sequence of layers: first metal layer, a layer of a plastic, second metal layer, a layer of energy storage material. The first metal layer forms ohmic contact with the first terminating electrode (the first contact layer) and the second metal layer (the second contact layer) forms ohmic contact with the second terminating electrode.
The present disclosure provides an energy storage molecular material, crystal dielectric layer and capacitor which may solve a problem of the further increase of volumetric and mass density of reserved energy associated with some energy storage devices, and at the same time reduce cost of materials.
C07D 519/00 - Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups or
The present disclosure provides an energy storage molecular material, crystal dielectric layer and capacitor which may solve a problem of the further increase of volumetric and mass density of reserved energy associated with some energy storage devices, and at the same time reduce cost of materials.
C07D 471/02 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups in which the condensed system contains two hetero rings
C07D 487/22 - Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups in which the condensed system contains four or more hetero rings
49.
Energy storage devices and methods of production thereof
m-A, wherein, A is an insulating layer and B is a polarization layer comprising a colloidal composite with a micro-dispersion of electro-conductive nano-particles in an insulator matrix, and ‘m’ is a number greater than or equal to 1. Layer A can have a breakdown voltage of at least about 0.05 volts per nanometer (nm), and layer B can have a dielectric permittivity of at least about 100.
C08L 33/02 - Homopolymers or copolymers of acidsMetal or ammonium salts thereof
C08L 79/00 - Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups
A self-healing capacitor comprises a first electrode, a second electrode, and a dielectric layer disposed between said first and second electrodes and having first surface faced the first electrode and second surface faced the second electrode. At least one of the electrodes can include metal foam. The dielectric layer can have electrically conductive channels that each has an exit point located on the first surface of the dielectric layer and another exit point located on the second surface of the dielectric layer. The electrodes can include local contact breakers each of which is located within the electrode at an interface between the dielectric layer and the electrode and opposite at least one exit point of each electrically conductive channel in the dielectric layer. The local contact breakers can prevent electric current through the conductive channels in dielectric layer.
A self-healing capacitor comprises a first electrode, a second electrode, and a dielectric layer disposed between said first and second electrodes and having first surface faced the first electrode and second surface faced the second electrode. At least one of the electrodes can include metal foam. The dielectric layer can have electrically conductive channels that each has an exit point located on the first surface of the dielectric layer and another exit point located on the second surface of the dielectric layer. The electrodes can include local contact breakers each of which is located within the electrode at an interface between the dielectric layer and the electrode and opposite at least one exit point of each electrically conductive channel in the dielectric layer. The local contact breakers can prevent electric current through the conductive channels in dielectric layer.
C09D 151/00 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bondsCoating compositions based on derivatives of such polymers
C08G 69/32 - Polyamides derived from amino carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
The present disclosure provides an energy storage device comprising a first electrode, a second electrode, and a solid multilayer structure disposed between said first and second electrodes. The solid multilayer structure can be in contact with said first and second electrodes. The solid multilayer structure can include layers disposed parallel to said electrodes, the layers have a sequence (A-B)m-A, wherein, A is an insulating layer and B is a polarization layer comprising a colloidal composite with a micro-dispersion of electro-conductive nano-particles in an insulator matrix, and 'm' is a number greater than or equal to 1. Layer A can have a breakdown voltage of at least about 0.05 volts per nanometer (nm), and layer B can have a dielectric permittivity of at least about 100.
The present invention relates generally to the fields of electrical engineering and electronics. More specifically, the present invention relates to passive components of electrical circuitry and more particularly to energy storage devices and method of production thereof.
The present invention relates generally to the fields of electrical engineering and electronics. More specifically, the present invention relates to passive components of electrical circuit and more particularly to a capacitor intended for energy storage and method of production thereof.
The present invention relates generally to the fields of electrical engineering and electronics. More specifically, the present invention relates to passive components of electrical circuit and more particularly to a capacitor intended for energy storage and method of production thereof.
The present invention relates generally to the fields of electrical engineering and electronics. More specifically, the present invention relates to passive components of electrical circuitry and more particularly to energy storage devices and method of production thereof. The present invention provides an energy storage device comprising a first electrode, a second electrode, and a solid multilayer structure disposed between said first and second electrodes. Said electrodes are flat and planar and positioned parallel to each other, and said solid multilayer structure comprises m homogeneous insulating and conductive layers.
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