HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Berube, Gregory
Sgriccia, Matthew
Buzby, Dean
Abstract
The invention relates to an aluminum resistive heater containing, a heat conductive substrate comprising an electrically insulating surface. An aluminum resistive structure is provided on the electrically insulating surface, wherein the aluminum resistive structure comprises, at least one aluminum conductive layer covering at least a part of the electrically insulating surface, wherein the aluminum conductive layer comprises aluminum and at least a first glass. The aluminum resistive structure further comprises at least two terminal contact pads contacting the aluminum conductive layer, wherein the terminal contact pads comprise silver. An overglaze comprising glass covers at least a part of the aluminum resistive structure. Furthermore the invention relates to a method for making the aluminum resistive heater.
H05B 3/12 - Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
H05B 3/14 - Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
H05B 3/26 - Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor mounted on insulating base
H05B 3/10 - Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
H05B 3/16 - Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor the conductor being mounted on an insulating base
H05B 3/36 - Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs heating conductor embedded in insulating material
C23C 16/06 - Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Berube, Gregory
Sgriccia, Matthew
Buzby, Dean
Abstract
The invention relates to an aluminum resistive heater containing, a heat conductive substrate comprising an electrically insulating surface. An aluminum resistive structure is provided on the electrically insulating surface, wherein the aluminum resistive structure comprises, at least one aluminum conductive layer covering at least a part of the electrically insulating surface, wherein the aluminum conductive layer comprises aluminum and at least a first glass. The aluminum resistive structure further comprises at least two terminal contact pads contacting the aluminum conductive layer, wherein the terminal contact pads comprise silver. An overglaze comprising glass covers at least a part of the aluminum resistive structure. Furthermore the invention relates to a method for making the aluminum resistive heater.
H05B 3/16 - Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor the conductor being mounted on an insulating base
H05B 3/08 - Heater elements structurally combined with coupling elements or with holders having electric connections specially adapted for high temperatures
H05B 3/26 - Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor mounted on insulating base
01 - Chemical and biological materials for industrial, scientific and agricultural use
02 - Paints, varnishes, lacquers
Goods & Services
Chemicals for industrial use; chemical preparations and materials for printing; chemical compositions for use in the manufacture of electronic components, in particular microcircuits and resistors; chemical compositions having conductive properties; printing chemicals, chemicals for use in electronic industry, chemicals for use in printing, chemicals used for plating non-conducting surfaces with metals; paste compositions; paste compositions for use in the manufacture of electronic components, in particular microcircuits and resistors. Printing ink; printer paste [ink]; ink for printing, marking and engraving; metallic ink; metallic printing ink; paints [other than insulating] for electronic components; printing ink with electric conductivity; polymeric ink, polymeric ink for surface micromachining; polymeric ink as sacrificial layer and sacrificial underlayer, polymeric ink as etch layer and as etch resistant layer; polymeric ink for encapsulation and protection.
4.
Compositions for the filling of high aspect ratio vertical interconnect access (VIA) holes
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Suh, Seigi
Abstract
A solvent-free electroconductive composition may be used to make electroconductive lines on a surface of a substrate or electroconductive plugs within via holes of a substrate. The solvent-free electroconductive composition is generally made of about 40 to about 95 wt % of a conductive component, about 4 to about 30 wt % of a polymer or oligomer comprising a reactive functional group, up to about 20 wt % of a monomeric diluent comprising a reactive functional group, and up to about 3 wt % of a curing agent. In some instances, the solvent-free electroconductive composition further includes up to about 3 wt % of a lubricating compound. Substrates made using solvent-free electroconductive compositions may be used in printed circuit boards, integrated circuits, solar cells, capacitors, resistors, thermistors, varistors, resonators, transducers, inductors, and multilayer ferrite beads.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Suh, Seigi
Abstract
A solvent-free electroconductive composition may be used to make electroconductive lines on a surface of a substrate or electroconductive plugs within via holes of a substrate. The solvent- free electroconductive composition is generally made of about 40 to about 95 wt% of a conductive component, about 4 to about 30 wt% of a polymer or oligomer comprising a reactive functional group, up to about 20 wt% of a monomeric diluent comprising a reactive functional group, and up to about 3 wt% of a curing agent. In some instances, the solvent-free electroconductive composition further includes up to about 3 wt% of a lubricating compound. Substrates made using solvent-free electroconductive compositions may be used in printed circuit boards, integrated circuits, solar cells, capacitors, resistors, thermistors, varistors, resonators, transducers, inductors, and multilayer ferrite beads.
H01L 25/065 - Assemblies consisting of a plurality of individual semiconductor or other solid-state devices all the devices being of a type provided for in a single subclass of subclasses , , , , or , e.g. assemblies of rectifier diodes the devices not having separate containers the devices being of a type provided for in group
H01L 23/48 - Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads or terminal arrangements
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Chandrasekaran, Vinodh
Hoerteis, Matthias
Abstract
A conductive paste for use in a laser-induced pattern transfer printing process includes a conductive component; a glass component; and an inorganic vehicle, wherein the conductive paste exhibits a light reflectance of no more than 50% across a light wavelength range of about 800 to about 1300 nm and improving the transfer of the paste to the substrate. A process for laser-induced pattern transfer printing includes providing a first substrate comprising a recessed surface and a conductive paste disposed in the recessed surface; orienting the recessed surface of the first substrate toward a second substrate; irradiating the conductive paste with a laser, the laser configured to emit light having a wavelength between about 800 and about 1300 nm; and transferring the irradiate conductive paste from the first substrate to a surface of the second substrate.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Persons, Ryan
Fritzsche, Sebastian
Kass, Steffan
Dickel, Tanja
Abstract
The International Bureau acknowledges receipt of Article 19 amendments received on 12 November 2019 (12.11.2019). Although the applicant appears to have indicated the basis of the amendment in the application as filed in the cover letter submitted together with the mark-up copy of Article 19 amendments, the applicant appears to not have submitted a clean copy of the new set of claims. The applicant is hereby invited to furnish the clean copy of the amended claims within a time limit of ONE MONTH from the date of mailing of this notification or within the time limit under Rule 46.1, whichever expires later.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Persons, Ryan
Fritzsche, Sebastian
Käss, Steffan
Dickel, Tanja
Abstract
wherein the copper paste comprises or consists of (i) 66-99 wt.-% of at least one type of particles selected from the group consisting of copper particles, copper-rich copper/zinc alloy particles, and copper-rich copper/tin alloy particles, (ii) 0-20 wt.-% of at least one type of solder particles selected from the group consisting of tin particles, tin-rich tin/copper alloy particles, tin-rich tin/silver alloy particles, and tin-rich tin/copper/silver alloy particles, and (iii) 1-20 wt.-% of a vehicle.
B23K 1/08 - Soldering by means of dipping in molten solder
H01L 23/00 - Details of semiconductor or other solid state devices
H05B 3/12 - Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
B23K 1/00 - Soldering, e.g. brazing, or unsoldering
9.
A SEED LAYER FOR IMPROVED CONTACT ON A SILICON WAFER
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Chandrasekaran, Vinodh
Abstract
The invention provides a seed layer paste for contacting a solar cell electrode with a low silver laydown and yet provides a higher voltage and a comparable solar efficiency. The seed layer paste includes: 1) a silver particle at 0.1-50 wt%; 2) at least one glass frit at 5-70 wt%; and 3) an organic vehicle at 20-95 wt%. The invention also provides a method of forming a solar cell by applying the seed layer paste of the invention to a surface of a silicon wafer to form a seed layer; applying on top of the seed layer a second composition containing a silver particle, at least one glass frit, and an organic vehicle; and firing the silicon wafer with the seed layer paste and the second composition.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Yan, Li
Chandrasekaran, Vinodh
Wang, Lei
Chen, Chi Long
Jiang, Lin
Guo, Cuiwen
Zhang, Weiming
Han, Jing (crystal)
Abstract
The invention provides a method of preparing a metallization structure on a solar cell. The method includes patterning a first composition on a surface of a semiconductor substrate; and applying a second composition over the first composition. An area covered by the first composition is 5-95% of an area covered by the second composition. The semiconductor substrate is then subjected to firing conditions. The invention also provides a metallization structure formed using the method described herein.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Garcia, Virginia C.
Persons, Ryan
Berube, Gregory
Sgriccia, Matthew
Abstract
505050), a glass frit comprising at least bismuth oxide and silicon oxide, and boron oxide, at least one adhesion promoting additive comprising bismuth oxide, zinc oxide, titanium oxide, cerium oxide, or combinations thereof, and an organic vehicle.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Raskar, Devidas
Zhai, Guang
Schulz, Gerd
Yang, Yi
Kazemzadeh Dehdashti, Maryam
Abstract
The invention relates to an electroconductive paste composition with reduced etching characteristics. The electroconductive paste composition includes metallic particles, at least one glass frit, and an organic vehicle. The at least one glass frit is lead-free and includes about 65-95 wt% of at least SiO2, B2O3, and Bi2O3, based upon 100% total weight of the at least one glass frit, about 5-20 wt% of at least one alkaline oxide, and about 3-10 wt% of molybdenum oxide.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Raskar, Devidas
Yang, Yi
Song, Lixin
Zhai, Guang
Abstract
The invention relates to a passivated emitter rear solar cell, comprising a silicon substrate having a front and back surface, a rear passivation layer on the back surface of the silicon substrate having a plurality of open holes formed therein, an aluminum back contact layer formed in the open holes of the rear passivation layer, and at least one backside soldering tab on the back surface of the silicon substrate. The backside soldering tab is formed from an electroconductive paste composition comprising conductive metallic particles, at least one lead-free glass frit, and an organic vehicle comprising at least one silicone oil.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Peters, Brian
Hobbs, Chris
England, Todd
Taylor, Jimmy
Winkler, Holger
Bauer-Siebenlist, Bernhard
Abstract
A process for the incineration of activated coal-supported PGM catalysts, the process comprising a joint incineration of a multilayer arrangement, wherein the multilayer arrangement includes (i) a top layer of particulate activated coal-supported PGM catalyst, (ii) a layer of coarse charcoal located beneath said top layer and, optionally, (iii) a layer of particulate coke located beneath the charcoal layer, and wherein an upward flow of oxidizing gas is homogeneously passed through said multilayer arrangement during the incineration.
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Shahbazi, Samson
Grabey, Steven
Challingsworth, Mark
Persons, Ryan
Abstract
A dielectric tape suitable for use in an electronic device is provided. A dielectric slip composition comprises an organic vehicle and a dielectric glass composition comprising at least about 20 wt % and no more than about 50 wt % silicon dioxide, based upon 100% total weight of the glass composition, at least about 10 wt % and no more than about 50 wt % alkali metal oxides, based upon 100% total weight of the glass composition, and at least about 1 wt % and no more than about 10 wt % of at least one transition metal oxide. A method of forming an electronic device is also provided. The method includes the steps of applying at least one dielectric tape to at least one non-planar surface of a substrate, and subjecting the at least one dielectric tape to one or more thermal treatment steps to form a dielectric layer.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Schulz, Gerd
Mayberry, Ryan
Holzmann, Daniel Winfried
Jung, Christian
Hörteis, Matthias
Berube, Gregory
Abstract
In general, the invention relates to a paste comprising : i) silver particles; ii) a particulate lead-silicate glass comprising iia) at least one oxide of silicon; iib) at least one oxide of lead; iic) at least one chloride; iid) optionally at least one further oxide being different from components iia) and iib); iii) an organic vehicle. The invention also relates to a solar cell precursor, to a process for the preparation of a solar cell, to a solar cell obtainable by this process, to a module comprising such a solar cell and to the use of a particulate lead-silicate glass as a component in a silver paste that can be used for the formation of an electrode.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Raskar, Devidas
Yang, Yi
Song, Lixin
Zhai, Guang
Abstract
The invention relates to a passivated emitter rear solar cell, comprising a silicon substrate having a front and back surface, a rear passivation layer on the back surface of the silicon substrate having a plurality of open holes formed therein, an aluminum back contact layer formed in the open holes of the rear passivation layer, and at least one backside soldering tab on the back surface of the silicon substrate. The backside soldering tab is formed from an electroconductive paste composition comprising conductive metallic particles, at least one lead-free glass frit, and an organic vehicle comprising at least one silicone oil.
H01L 31/18 - Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
B05D 1/02 - Processes for applying liquids or other fluent materials performed by spraying
B05D 1/18 - Processes for applying liquids or other fluent materials performed by dipping
B05D 1/28 - Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
B05D 1/30 - Processes for applying liquids or other fluent materials performed by gravity only, i.e. flow coating
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
19.
POLY-SILOXANE CONTAINING ORGANIC VEHICLE FOR ELECTROCONDUCTIVE PASTES
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Song, Lixin
Zhang, Yi
Abstract
The invention relates to an electroconductive paste composition comprising conductive metallic particles comprising silver, at least one glass frit, and an organic vehicle comprising at least about 0.5 wt% and no more than about 50 wt% of at least one poly-siloxane compound, based upon 100% total weight of the organic vehicle.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Shahbazi, Samson
Grabey, Steven
Challingsworth, Mark
Persons, Ryan
Abstract
A dielectric tape suitable for use in an electronic device is provided. A dielectric slip composition comprises an organic vehicle and a dielectric glass composition comprising at least about 20 wt% and no more than about 50 wt% silicon dioxide, based upon 100% total weight of the glass composition, at least about 10 wt% and no more than about 50 wt% alkali metal oxides, based upon 100% total weight of the glass composition, and at least about 1 wt% and no more than about 10 wt% of at least one transition metal oxide. A method of forming an electronic device is also provided. The method includes the steps of applying at least one dielectric tape to at least one non-planar surface of a substrate, and subjecting the at least one dielectric tape to one or more thermal treatment steps to form a dielectric layer.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Song, Lixin
Sng, Toong Joo
Chen, Chi Long
Zhang, Yi
Dua, Vineet
Kapp, David
Yang, Yi
Abstract
An organic vehicle comprising at least about 0.5 wt% and no more than about 45 wt% of at least one of a natural essential oil, based upon 100% total weight of the organic vehicle, at least about 0.5 wt% and no more than about 10 wt% of at least one resin, an organic solvent, and a thixotropic agent is provided. The invention also provides a solar cell and a method of forming a solar cell with the electroconductive paste of the invention.
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01L 51/00 - Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Sgriccia, Matthew
Challingsworth, Mark
Shahbazi, Samson
Persons, Ryan
Grabey, Steven
Abstract
50) of the glass composition is no more than about 5 μm, and (iii) the glass composition has a coefficient of thermal expansion of at least about 10 ppm/K and no more than about 25 ppm/K, is provided.
C03C 8/02 - Frit compositions, i.e. in a powdered or comminuted form
C03C 8/24 - Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metalGlass solders
C03C 3/062 - Glass compositions containing silica with less than 40% silica by weight
C03C 3/083 - Glass compositions containing silica with 40% to 90% silica by weight containing aluminium oxide or an iron compound
H01B 3/08 - Insulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of inorganic substances quartzInsulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of inorganic substances glassInsulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of inorganic substances glass woolInsulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of inorganic substances slag woolInsulators or insulating bodies characterised by the insulating materialsSelection of materials for their insulating or dielectric properties mainly consisting of inorganic substances vitreous enamels
H01C 17/065 - Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thick-film techniques, e.g. serigraphy
23.
Solderable conductive polymer thick film composition
Heracus Precious Metals North America Conshohocken LLC (USA)
Inventor
Shahbazi, Samson
Grabey, Steven
Abstract
A conductive polymer thick film composition suitable for lead-free soldering comprising metallic particles and an organic vehicle comprising at least one phenolic resin and a solvent is provided. A method of soldering to the conductive polymer thick film composition of the invention is also provided. An article comprising a substrate and a cured polymer film on a surface of the substrate formed of the conductive polymer thick film composition of the invention is provided.
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H05K 3/34 - Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by soldering
B23K 35/30 - Selection of soldering or welding materials proper with the principal constituent melting at less than 1550°C
B23K 35/36 - Selection of non-metallic compositions, e.g. coatings, fluxesSelection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
B23K 35/02 - Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
B23K 1/00 - Soldering, e.g. brazing, or unsoldering
B23K 35/32 - Selection of soldering or welding materials proper with the principal constituent melting at more than 1550°C
B23K 35/365 - Selection of non-metallic compositions of coating materials either alone or conjoint with selection of soldering or welding materials
24.
Lead-bismuth-tellurium-silicate inorganic reaction system having improved adhesion properties
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Kapp, David, C.
Smith, George, T.
Berube, Gregory, M.
Guo, Cuiwen
Jiang, Lin
Patel, Krupali
Abstract
An electroconductive paste composition for manufacturing a solar cell including conductive metallic particles, glass frit, and an organic vehicle which includes an organic solvent and an acrylic resin lacking an active hydrogen functionality, is provided. The electroconductive paste composition is capable of being screen printed through screen openings having a diameter of about 40 µm or less.
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Jiang, Hong
Shaikh, Aziz S.
Abstract
Electrically conductive polymeric compositions adapted for use in forming electronic devices are disclosed. The compositions are thermally curable at temperatures less than about 250° C. Compositions are provided which may be solvent-free and so can be used in processing or manufacturing operations without solvent recovery concerns. The compositions utilize (i) fatty acid modified epoxy acrylate and/or methacrylate monomer(s) and/or oligomer(s), (ii) fatty acid modified polyester acrylate and/or methacrylate monomer(s) and/or oligomer(s), or combinations of (i) and (ii). Also described are electronic assemblies such as solar cells using the various compositions and related methods.
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
27.
ELECTROCONDUCTIVE PASTE WITH ADHESION PROMOTING GLASS
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Kurtz, Eric
Karpowich, Lindsey A.
Zhang, Weiming
Abstract
An electroconductive paste composition for use in forming backside soldering pads on a solar cell including metallic particles, glass frit including Bi2O3, Al2O3, SiO2, B2O3 and at least one of Li2O or Li3PO4, and an organic vehicle is provided. The invention also provides a solar cell comprising a silicon wafer having a front side and a backside, and a soldering pad formed on the silicon wafer produced from an electroconductive paste according to the invention. The invention further provides a solar cell module comprising electrically interconnected solar cells according to the invention. A method of producing of a solar cell, comprising the steps of providing a silicon wafer having a front side and a backside, applying an electroconductive paste composition according to the invention onto the backside of the silicon wafer, and firing the silicon wafer according to an appropriate profile, is also provided.
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Shahbazi, Samson
Grabey, Steven
Challingsworth, Mark
Abstract
3, and about 10-20 wt % of organic vehicle, based upon 100% total weight of the paste, wherein the organic vehicle includes at least one viscosity-modifying component in an amount sufficient to provide the electroconductive hole plug paste with a viscosity of about 800-1,500 kcPs, is provided. A ceramic substrate assembly for an implantable medical device having the electroconductive hole plug paste of the invention, and a method of forming the same, are also provided.
B32B 3/24 - Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. apertured or formed of separate pieces of material characterised by an apertured layer, e.g. of expanded metal
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Garcia, Virginia C.
Sgriccia, Matthew
Challingsworth, Mark
Abstract
The invention provides an electroconductive paste comprising 50-90 wt. % of copper particle, 0.5-10 wt. % of a glass frit, 0.1-5% wt. % of adhesion promoter, which is at least one selected member from the group consisting of cuprous oxide, titanium oxide, zirconium oxide, boron resinate, zirconium resinate, amorphous boron, lithium phosphate, bismuth oxide, aluminum oxide, and zinc oxide, and 5-20 wt. % of an organic vehicle. An article comprising an aluminum nitride substrate and electroconductive paste of the invention is also provided. A method of forming an electroconductive circuit comprising is also provided.
H05K 1/09 - Use of materials for the metallic pattern
H05K 3/12 - Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using printing techniques to apply the conductive material
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Jiang, Hong
Shaikh, Aziz S.
Abstract
Electrically conductive polymeric compositions adapted for use in forming electronic devices are disclosed. The compositions are thermally curable at temperatures less than about 250° C. Compositions are provided which may be solvent-free and so can be used in processing or manufacturing operations without solvent recovery concerns. Core-shell conductive particles provide the conductivity of the compositions and devices contemplated herein.
C09D 151/08 - Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bondsCoating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
C09D 175/16 - Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
H01L 31/0376 - SEMICONDUCTOR DEVICES NOT COVERED BY CLASS - Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including amorphous semiconductors
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Garcia, Virginia C.
Sgriccia, Matthew
Challingsworth, Mark
Abstract
50 of at least about 5 μm and no more than about 8 μm, and an organic vehicle. The invention further provides an article comprising a glass substrate comprising a transparent conductive oxide coating and a conductive electrode formed by applying aforementioned conductive paste on said glass substrate, and a method of producing such an article.
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
32.
Single component, low temperature curable polymeric composition and related method
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Jiang, Hong
Shaikh, Aziz S.
Abstract
Electrically conductive polymeric compositions curable at temperatures below 250° C. are disclosed. The compositions are particularly well suited for forming electrodes used in association with certain solar cells.
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H01L 21/64 - Manufacture or treatment of solid-state devices other than semiconductor devices, or of parts thereof, not specially adapted for a single type of device provided for in subclasses , , or
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
C08L 63/00 - Compositions of epoxy resinsCompositions of derivatives of epoxy resins
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Kurtz, Eric
Karpowich, Lindsey, A.
Zhang, Weiming
Abstract
The present invention relates to an electroconductive paste useful in the manufacture of silicon solar cells and solar cell modules, especially for the backside of the silicon wafer. The electroconductive paste comprises metallic particles, glass frit, organic vehicle, and an adhesion enhancer. The adhesion enhancer comprises a metal or a metal oxide, or any other metal compound that will convert to metal or metal oxide at firing temperature. The adhesion enhancer comprises at least one metal selected from the group consisting of tellurium, tungsten, molybdenum, vanadium, nickel, antimony, magnesium, zirconium, silver, cobalt, cerium, and zinc, or oxides thereof.
Heracus Precious Metals North America Conshohocken LLC (USA)
Inventor
Yang, Yi
Shaikh, Aziz S.
Sridharan, Srinivasan
Abstract
Paste compositions, methods of making a paste composition, and methods of making a solar cell contact are disclosed. The paste composition can contain silver, a glass frit, a metal additive and an organic vehicle system. The metal additive is at least one selected from the group consisting of yttrium, an organo-vanadium compound, organo-antimony compound, organo-phosphorus compound, and an organo-yttrium compound. The paste can be used for making a solar cell contact.
H01B 1/02 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of metals or alloys
H01B 1/12 - Conductors or conductive bodies characterised by the conductive materialsSelection of materials as conductors mainly consisting of other non-metallic substances organic substances
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Khatri, Himal
Shaikh, Aziz, S.
Sridharan, Srinivasan
Kunze, Klaus
Abstract
Paste compositions, methods of making a paste composition, and methods of making a solar cell contact are disclosed. The paste composition can contain a nickel intermetallic compound such as nickel silicide, nickel boride or nickel phosphide, a glass frit, a metal additive and an organic vehicle system. The paste can be used for making a solar cell contact.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC. (USA)
Inventor
Yang, Yi
Shaikh, Aziz, S.
Mcvicker, Kristina
Kunze, Klaus
Sridharan, Srinivasan
Abstract
Silicon solar cells and contacts thereof are printed in at least a two stage printing process where the busbars and fingerlines may be printed separately. A reduction in silver content in busbars and fingerlines through use of the techniques of the invention have been realized, including the use of certain base metals, while maintaining low contact resistance similar to silver pastes.
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Wang, Lei
Hörteis, Matthias
Zhang, Weiming
Abstract
This disclosure relates to electroconductive paste formulations useful in solar panel technology. In one aspect, the disclosure relates to an inorganic reaction system for use in electroconductive paste compositions, wherein the inorganic reaction system comprises a lead containing matrix composition and a tellurium containing matrix composition. In another aspect, the disclosure relates to an electroconductive paste composition comprising a conductive metal component, an inorganic reaction system and an organic vehicle. Another aspect of the disclosure relates to a solar cell produced by applying an electroconductive paste composition of the invention to a silicon wafer. Yet another aspect relates to a solar cell module assembled using solar cells produced by applying an electroconductive paste composition to a silicon wafer, wherein the electroconductive paste composition comprises an conductive metal component, an inorganic reaction system and an organic vehicle.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Yang, Yi
Sridharan, Srinivasan
Shaikh, Aziz, S.
Clark, Kenneth, A.
Abstract
Paste compositions, methods of making paste compositions, contacts, and methods of making contacts are disclosed. The paste compositions include a solid portion and a vehicle system. The solid portion includes a conductive metal component and a glass binder. The vehicle system includes organometallic compound containing zinc. The organometallic compounds containing zinc can be dissolved in the vehicle system and the vehicle system does not include particles that contain zinc. The paste compositions can be used to form contacts in solar cells or other related components.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Cruz, Ben, E.
Shaikh, Aziz, S.
Graddy, George, E., Jr.
Sridharan, Srinivasan
Khatri, Himal
Merchant, Nazarali
Abstract
This invention relates an aluminum (Al) conductor paste formulation and its method of application on rear side passivated locally laser fired contacts (LFC). Such Back Surface Passivated (BSP) Si-solar cells include aluminum conductor paste formulations and methods of application on rear side passivated locally opened vias; dot or line geometry or combination thereof employing laser ablation or chemical etching methods. Such Back Surface Passivated Si- solar cells include dielectric layers of A1203, SiNx, Si02, SiC, α-Si, Si02/SiNx, A1203/SiNx, SiO2A12/SiNx. The Al-conductor paste of this invention achieves; (i) non-degradation of passivation stack, (ii) defect free surfaces and void free vias, (iii) a strong and uniform Back Surface Field (BSF) layer within dot vias and line vias.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Khadilkar, Chandrashekhar S.
Khatri, Himal
Sridharan, Srinivasan
Graddy, George E., Jr.
Shaikh, Aziz S.
Merchant, Nazarali
Abstract
This invention relates an aluminum conductor paste formulation and its method of application on rear side passivated locally opened vias; dot or line geometry or combination thereof employing laser ablation or chemical etching methods. Such Back Surface Passivated Si-solar cells include dielectric layers of A1203, SiNx, Si02, SiC, a-Si, Si02/SiNx, A1203/SiNx, Si02/A1203/SiNx. The Al-conductor paste of this invention achieves; (i) non-degradation of passivation stack, (ii) defect free surfaces and void free vias, (iii) a strong and uniform Back Surface Field (BSF) layer within dot vias and line vias.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC. (USA)
Inventor
Yang, Yi
Sridharan, Srinivasan
Kumar, Umesh
Shaikh, Aziz, S.
Abstract
Paste compositions, methods of making a paste composition, solar cells, and methods of making a solar cell contact are disclosed. The paste composition can include a conductive metal component, a glass component, and a vehicle. The glass component can include SiO2 at about 3 mole % or more and about 65 mole % or less of the glass component and one or more transition metal oxides at about 0.1 mole % or more and about 25 mole % or less of the glass component. The metal of the transition metal oxide is selected from the group consisting of Mn, Fe, Co, Ni, Cu, Ti, V, Cr, W, Nb, Ta, Hf, Mo, Zr, Rh, Ru, Pd, and Pt.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Jiang, Hong
Shaikh, Aziz, S.
Abstract
Electrically conductive polymeric compositions adapted for use in forming electronic devices are disclosed. The compositions are thermally curable at temperatures less than about 250°C. Compositions are provided which may be solvent- free and so can be used in processing or manufacturing operations without solvent recovery concerns. Core-shell conductive particles provide the conductivity of the compositions and devices contemplated herein.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Jiang, Hong
Shaikh, Aziz, S.
Abstract
Electrically conductive polymeric compositions adapted for use in forming electronic devices are disclosed. The compositions are thermally curable at temperatures less than about 250°C. Compositions are provided which may be solvent-free and so can be used in processing or manufacturing operations without solvent recovery concerns. The compositions utilize (i) ethylenically unsaturated monomers or oligomers with hydroxyl groups, and (ii) blocked isocyanates with unblocking temperatures below 200°C. Also described are electronic assemblies such as solar cells using the various compositions and related methods.
C08G 18/67 - Unsaturated compounds having active hydrogen
C08G 18/70 - Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
C08G 18/77 - Polyisocyanates or polyisothiocyanates having hetero atoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
B05D 5/12 - Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
H01B 1/22 - Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Seyedmohammadi, Shahram
Khatri, Himal
Sridharan, Srinivasan
Shaikh, Aziz S.
Abstract
Solar cell conductor formulations made are from two silver powders having different particle size distributions, an aluminum powder, and two frit glass compositions having softening points in the range of 250-700 °C and whose softening points differ by at least 10 °C.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Zhang, Dongshe
Shaikh, Aziz
Sridharan, Srinivasan
Khatri, Himal
Jiang, Hong
Graddy, George, E.
Abstract
Paste compositions, methods of making a paste composition, photovoltaic cells, and methods of making a photovoltaic cell contact are disclosed. The paste composition can include a conductive metal component such as aluminum, phosphate glass, phosphorus compounds such as alky! phosphate, and a vehicle. The contact can be formed on a passivation layer on a silicon wafer by applying the paste on the passivation layer and firing the paste. During firing, the metal component can fire through the passivation layer, thereby electrically contacting the silicon substrate.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Zhang, Weiming
Moyer, Jerome
Pham, Tung, Thanh
Abstract
Electroconductive paste compositions, particularly for solar cells, contain electroconductive metal particles, glass particles, and an organic vehicle. The electroconductive metal particles are provided as a mixture of silver powder particles and at least one selected from nickel powder, tin (IV) oxide powder, and core-shell particles having a silver shell and a core of nickel and/or tin (IV) oxide. The pastes may be used in the manufacture of contacts or electrodes for the front side or back side of solar cells.
Heraeus Precious Metals North America Conshohocken LLC (USA)
Inventor
Sridharan, Srinivasan
Pham, Tung
Khadilkar, Chandrashekhar S.
Shaikh, Aziz S.
Kim, Steve S.
Abstract
Formulations and methods of making solar cells are disclosed. In general, the invention presents a solar cell contact made from a mixture wherein the mixture comprises a solids portion and an organics portion, wherein the solids portion comprises from about 85 to about 99 wt % of a metal component, and from about 1 to about 15 wt % of a lead-free glass component. Both front contacts and back contacts arc disclosed.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC. (USA)
Inventor
Yang, Yi
Shaikh, Aziz, S.
Sridharan, Srinivasan
Abstract
Paste compositions, methods of making a paste composition, and methods of making a solar cell contact are disclosed. The paste composition can contain silver, a glass frit, a metal additive and an organic vehicle system. The metal additive is at least one selected from the group consisting of yttrium, an organo- vanadium compound, organo-antimony compound, organo-phosphorus compound, and an organo-yttrium compound. The paste can be used for making a solar cell contact.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Pham, Tung, Thanh
Zhang, Weiming
Abstract
An electroconductive paste composition, particularly for solar cells, contains silver particles, glass particles, an organic vehicle, and at least one additive. The additive may be tantalum pentoxide or fine, electrically conductive, metal particles, such as gold and/or platinum group metals. When used to form an electrical contact on a solar cell, such a paste provides for enhanced adhesion of the contact to the cell and improved electron transmission.
HERAEUS PRECIOUS METALS NORTH AMERICA CONSHOHOCKEN LLC (USA)
Inventor
Sridharan, Srinivasan
Pham, Tung
Khadilkar, Chandrashekhar S.
Shaikh, Aziz S.
Kim, Steve S.
Abstract
Formulations and methods of making solar cells are disclosed. In general, the invention presents a solar cell contact made from a mixture wherein the mixture comprises a solids portion and an organics portion, wherein the solids portion comprises from about 85 to about 99 wt % of a metal component, and from about 1 to about 15 wt % of a lead-free glass component. Both front contacts and back contacts are disclosed.