A print on-demand color shift material which has high reflection, high saturation color and intrinsic, high impact color-shift produced by thermal printing or laser writing for use, for example in security laminates, tax and excise stamps, machine-readable features and banknote foils, and offering a rainbow of colors with full color shifting, producible in full manufacturing scale.
B32B 3/26 - Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layerLayered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shapeLayered products comprising a layer having particular features of form characterised by a layer with cavities or internal voids
B32B 5/16 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer formed of particles, e.g. chips, chopped fibres, powder
B42D 25/21 - Information-bearing cards or sheet-like structures characterised by identification or security featuresManufacture thereof characterised by a particular use or purpose for multiple purposes
B42D 25/41 - Marking using electromagnetic radiation
G02F 1/01 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour
B42D 25/36 - Identification or security features, e.g. for preventing forgery comprising special materials
B82Y 20/00 - Nanooptics, e.g. quantum optics or photonic crystals
B32B 37/24 - Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
2.
MULTILAYER PHOTONIC CRYSTAL-BASED THERMOCHROMIC OPTICAL FILM
A print on-demand color shift material which has high reflection, high saturation color and intrinsic, high impact color-shift produced by thermal printing or laser writing for use, for example in security laminates, tax and excise stamps, machine-readable features and banknote foils, and offering a rainbow of colors with full color shifting, producible in full manufacturing scale.
G02B 6/122 - Basic optical elements, e.g. light-guiding paths
B32B 33/00 - Layered products characterised by particular properties or particular surface features, e.g. particular surface coatingsLayered products designed for particular purposes not covered by another single class
B32B 5/16 - Layered products characterised by the non-homogeneity or physical structure of a layer characterised by features of a layer formed of particles, e.g. chips, chopped fibres, powder
B42D 25/36 - Identification or security features, e.g. for preventing forgery comprising special materials
B42D 25/41 - Marking using electromagnetic radiation
B82Y 20/00 - Nanooptics, e.g. quantum optics or photonic crystals
3.
Methods and systems for thermal printing of photonic crystal materials, and thermally printable photonic crystal materials and assemblies
Methods and systems for thermal printing of thermally printable photonic crystal materials and assemblies. The photonic crystal materials and assemblies are responsive to thermal stimuli, wherein temperatures above a thermal threshold results in an optically detectable change in the appearance of the materials and assemblies. Heat is selectively applied to one or more portions of the materials and assemblies, in order to thermally print a graphic onto the materials and assemblies.
G01K 11/06 - Measuring temperature based on physical or chemical changes not covered by group , , , or using melting, freezing, or softening
G02B 1/02 - Optical elements characterised by the material of which they are madeOptical coatings for optical elements made of crystals, e.g. rock-salt, semiconductors
B41J 2/32 - Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
B41J 3/407 - Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
A tunable photonic crystal device comprising: alternating layers of a first material and a second material, the alternating layers comprising a responsive material, the responsive material being responsive to an external stimulus, the alternating layers having a periodic difference in refractive indices giving rise to a first reflected wavelength; wherein, in response to the external stimulus, a change in the responsive material results in a reflected wavelength of the device shifting from the first reflected wavelength to a second reflected wavelength.
G02F 1/00 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics
G02F 1/01 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour
G02F 1/03 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour based on ceramics or electro-optical crystals, e.g. exhibiting Pockels or Kerr effect
G02F 1/15 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
G02F 1/21 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour by interference
H01L 33/46 - Reflective coating, e.g. dielectric Bragg reflector
H01S 3/08 - Construction or shape of optical resonators or components thereof
B82Y 20/00 - Nanooptics, e.g. quantum optics or photonic crystals
A photonic crystal device including a photonic crystal material and an activation surface. The photonic crystal material exhibits a first reflectance spectrum in an unactivated state, and, in response to mechanical stimulation, exhibits a second reflectance spectrum in an activated state. Application of a force at an activation portion of the activation surface offset from a material-supporting portion of the activation surface causes a deformation of the photonic crystal material sufficient to bring the photonic crystal material to the activated state.
G02F 1/00 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics
G02B 26/00 - Optical devices or arrangements for the control of light using movable or deformable optical elements
G02F 1/01 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour
G02B 6/122 - Basic optical elements, e.g. light-guiding paths
6.
METHODS AND SYSTEMS FOR THERMAL PRINTING OF PHOTONIC CRYSTAL MATERIALS, AND THERMALLY PRINTABLE PHOTONIC CRYSTAL MATERIALS AND ASSEMBLIES
Methods and systems for thermal printing of thermally printable photonic crystal materials and assemblies. The photonic crystal materials and assemblies are responsive to thermal stimuli, wherein temperatures above a thermal threshold results in an optically detectable change in the appearance of the materials and assemblies. Heat is selectively applied to one or more portions of the materials and assemblies, in order to thermally print a graphic onto the materials and assemblies.
B41M 3/00 - Printing processes to produce particular kinds of printed work, e.g. patterns
B41J 2/315 - Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
B41J 2/475 - Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of radiation to a printing material or impression-transfer material for heating selectively
C08J 3/24 - Crosslinking, e.g. vulcanising, of macromolecules
G02B 1/02 - Optical elements characterised by the material of which they are madeOptical coatings for optical elements made of crystals, e.g. rock-salt, semiconductors
The present disclosure provides methods, systems and devices for a photonic crystal combinatorial sensor. The photonic crystal sensor may include an array of photonic crystal materials, wherein each photonic crystal material has a reflected wavelength in a respective initial wavelength range. At least one a first one of the photonic crystal materials may be configured to have a response to an external stimulus different from at least a second one of the photonic crystal materials, the different response resulting in a change in the reflected wavelength of the first photonic crystal material that is an optically detectable difference from the second photonic crystal material. The optically detectable difference may provide an optically detectable response pattern of reflected wavelengths in the array. The sensor may be reversible and reusable.
G01N 21/00 - Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
G01N 21/77 - Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
G01D 5/28 - Mechanical means for transferring the output of a sensing memberMeans for converting the output of a sensing member to another variable where the form or nature of the sensing member does not constrain the means for convertingTransducers not specially adapted for a specific variable using optical means, i.e. using infrared, visible or ultraviolet light with deflection of beams of light, e.g. for direct optical indication
G01N 21/78 - Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
G01N 21/45 - RefractivityPhase-affecting properties, e.g. optical path length using interferometric methodsRefractivityPhase-affecting properties, e.g. optical path length using Schlieren methods
A photonic crystal device including a photonic crystal material and an infiltrating component. The photonic crystal material has an initial reflectance spectrum. An external stimulus causes the infiltrating component to migrate into or out of at least a portion of the photonic crystal material. The migration of the infiltrating component causes a change of at least the portion of the photonic crystal material to shift to a second reflectance spectrum.
A photonic crystal device including a photonic crystal material and an activation surface. The photonic crystal material exhibits a first reflectance spectrum in an unactivated state, and, in response to mechanical stimulation, exhibits a second reflectance spectrum in an activated state. Application of a force at an activation portion of the activation surface offset from a material-supporting portion of the activation surface causes a deformation of the photonic crystal material sufficient to bring the photonic crystal material to the activated state.
G02B 6/122 - Basic optical elements, e.g. light-guiding paths
G02F 1/19 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour based on variable-reflection or variable-refraction elements not provided for in groups
10.
REVERSIBLY RESPONSIVE LIGHT-SCATTERING PHOTONIC MATERIAL
A light-scattering photonic material is disclosed having a matrix defining a plurality of disordered voids. The material may be reversibly responsive to an external stimulus, exhibiting reversible first and second optical effects. The material may be a thin film material.
G02F 1/19 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour based on variable-reflection or variable-refraction elements not provided for in groups
B82Y 20/00 - Nanooptics, e.g. quantum optics or photonic crystals
A tunable photonic crystal composition comprising: tunable photonic crystal particles having a polymer network with a periodic modulation of refractive indices, the polymer network having a reflectance wavelength, wherein the periodic modulation of refractive indices is responsive to an external stimulus and the reflectance wavelength is shifted in response to the external stimulus; and a carrier in which the particles are dispersed.
A tunable photonic crystal device comprising: alternating layers of a first material and a second material, the alternating layers comprising a responsive material, the responsive material being responsive to an external stimulus, the alternating layers having a periodic difference in refractive indices giving rise to a first reflected wavelength; wherein, in response to the external stimulus, a change in the responsive material results in a reflected wavelength of the device shifting from the first reflected wavelength to a second reflected wavelength.
G02F 1/00 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics
G02B 1/10 - Optical coatings produced by application to, or surface treatment of, optical elements
G02B 27/00 - Optical systems or apparatus not provided for by any of the groups ,
G02F 1/15 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
G02F 1/21 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour by interference
G02F 1/01 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour
G02F 1/03 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour based on ceramics or electro-optical crystals, e.g. exhibiting Pockels or Kerr effect
H01L 33/46 - Reflective coating, e.g. dielectric Bragg reflector
H01S 3/08 - Construction or shape of optical resonators or components thereof
B82Y 20/00 - Nanooptics, e.g. quantum optics or photonic crystals
A photonic crystal incandescent light source comprising: a photonic crystal having a structure configured to reflect wavelengths from at least a portion of an infrared spectrum; and an incandescent central filament in the photonic crystal, causing the photonic crystal to transmit wavelengths from at least a portion of a visible spectrum; wherein the light source emits at least a portion of visible wavelengths and suppresses emission of at least a portion of infrared wavelengths.
The present disclosure provides methods, systems and devices for a photonic crystal combinatorial sensor. The photonic crystal sensor may include an array of photonic crystal materials, wherein each photonic crystal material has a reflected wavelength in a respective initial wavelength range. At least one a first one of the photonic crystal materials may be configured to have a response to an external stimulus different from at least a second one of the photonic crystal materials, the different response resulting in a change in the reflected wavelength of the first photonic crystal material that is an optically detectable difference from the second photonic crystal material. The optically detectable difference may provide an optically detectable response pattern of reflected wavelengths in the array. The sensor may be reversible and reusable.
G01D 5/26 - Mechanical means for transferring the output of a sensing memberMeans for converting the output of a sensing member to another variable where the form or nature of the sensing member does not constrain the means for convertingTransducers not specially adapted for a specific variable using optical means, i.e. using infrared, visible or ultraviolet light
G01N 21/00 - Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
G01N 21/77 - Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
A temperature-responsive photonic crystal device comprising having a temperature- responsive photonic crystal material, whereby exposure of the device to a temperature above a predetermined threshold temperature is indicated by a detectable change in the device.
G01K 11/00 - Measuring temperature based on physical or chemical changes not covered by group , , , or
G01K 11/12 - Measuring temperature based on physical or chemical changes not covered by group , , , or using changes in colour, translucency or reflectance
The Governing Council of the University of Toronto (USA)
Opalux Incorporated (USA)
Inventor
Arsenault, Andre
Ozin, Geoffrey Alan
Von Freymann, Georg
Abstract
A compressible photonic crystal comprising a polymer with an ordered array of voids, the photonic crystal having a reflectance in a first wavelength range for light incident to its incident surface and its opposing incident surface; wherein compression against at least a portion of at least one of the surfaces shifts the reflectance to a second wavelength range in at least that portion of that surface. The crystal may be used in authentication devices of various types.
G02B 6/10 - Light guidesStructural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
A security and/or authentication device comprising: a compressible photonic crystal having an ordered array of voids, the photonic crystal having a reflection peak, wherein compression against at least a portion photonic crystal results in a decrease of intensity of the reflection peak in at least that portion.
B42D 15/10 - Identity, credit, cheque or like information-bearing cards (record carriers, e.g. credit or identity cards, for use with machines and with at least a part designed to carry digital markings G06K 19/00)
B44F 1/12 - Securities or banknotes as far as the design or protection against forgery is of importance
G02B 1/04 - Optical elements characterised by the material of which they are madeOptical coatings for optical elements made of organic materials, e.g. plastics
G02B 17/00 - Systems with reflecting surfaces, with or without refracting elements
G07D 7/12 - Visible light, infrared or ultraviolet radiation
A photonic crystal device comprising: a photonic crystal material having an initial ordered structure and a viewing surface, the initial ordered structure giving rise to a first optical effect detectable from the viewing surface; and a removal layer removably attached with the viewing surface or an opposing surface of the photonic crystal material opposite to the viewing surface; wherein mechanical removal of at least a portion of the removal layer results in a structural change in at least a portion of the initial ordered structure of at least a portion of the photonic crystal material respective to the portion of the removed removal layer, thereby resulting in a changed portion different from the initial ordered structure, the changed portion giving rise to a second optical effect detectable from the viewing surface and detectably different from the first optical effect.
G02B 1/02 - Optical elements characterised by the material of which they are madeOptical coatings for optical elements made of crystals, e.g. rock-salt, semiconductors
B42D 15/00 - Printed matter of special format or style not otherwise provided for
B44F 1/12 - Securities or banknotes as far as the design or protection against forgery is of importance
C30B 29/68 - Crystals with laminate structure, e.g. "superlattices"
G02B 1/04 - Optical elements characterised by the material of which they are madeOptical coatings for optical elements made of organic materials, e.g. plastics
G02B 6/122 - Basic optical elements, e.g. light-guiding paths
G07D 7/12 - Visible light, infrared or ultraviolet radiation
A tunable photonic crystal composition comprising: tunable photonic crystal particles having a polymer network with a periodic modulation of refractive indices, the polymer network having a reflectance wavelength, wherein the periodic modulation of refractive indices is responsive to an external stimulus and the reflectance wavelength is shifted in response to the external stimulus; and a carrier in which the particles are dispersed.
A tunable photonic crystal device comprising: alternating layers of a first material and a second material, the alternating layers comprising a responsive material, the responsive material being responsive to an external stimulus, the alternating layers having a periodic difference in refractive indices giving rise to a first reflected wavelength; wherein, in response to the external stimulus, a change in the responsive material results in a reflected wavelength of the device shifting from the first reflected wavelength to a second reflected wavelength.
G02F 1/19 - Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulatingNon-linear optics for the control of the intensity, phase, polarisation or colour based on variable-reflection or variable-refraction elements not provided for in groups
G01R 19/145 - Indicating the presence of current or voltage
G09G 3/20 - Control arrangements or circuits, of interest only in connection with visual indicators other than cathode-ray tubes for presentation of an assembly of a number of characters, e.g. a page, by composing the assembly by combination of individual elements arranged in a matrix
H01L 33/00 - SEMICONDUCTOR DEVICES NOT COVERED BY CLASS - Details thereof
H01S 5/187 - Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities having only horizontal cavities, e.g. horizontal cavity surface-emitting lasers [HCSEL] using Bragg reflection
A photonic crystal electrical property indicator for a battery comprising: an electrically conductive working electrode and an electrically conductive counter electrode; an electrically-responsive photonic crystal material in contact with at least one of said first and second electrically conductive electrodes; an ionically conductive electrolyte provided between the working and counter electrodes; and electrical conductors for connecting the indicator to terminals of the battery; wherein the photonic crystal material has a reflectance spectrum that is responsive to a change in at least one electrical property of the battery, thereby providing an optically detectable indication of the at least one electrical property of the battery.
H01M 10/48 - Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
G02B 6/12 - Light guidesStructural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
G02B 6/13 - Integrated optical circuits characterised by the manufacturing method
H01M 6/50 - Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature
patents
